KR102067824B1 - Total residual oxidant measuring apparatus with improved accuracy - Google Patents

Abstract

The present invention provides a sampling pipe for sampling a sample to be measured from a main pipe through which a sample flows; A concentration sensor for measuring a concentration of a sample introduced into the sampling pipe; And stationary means installed at the front end of the concentration measuring sensor in the sampling pipe, and allowing the sample introduced into the sampling pipe to settle for a predetermined time, and then supplying the sample to the concentration measuring sensor. It relates to a residual chlorine concentration measuring apparatus.

Description

Total residual oxidant measuring apparatus with improved accuracy

The present invention relates to an apparatus for measuring residual chlorine concentration with improved accuracy capable of accurately measuring the residual chlorine concentration of a sample killed by a water treatment apparatus such as a ballast water treatment system.

The ballast water is the water that is filled in the vessel to maintain the balance of the vessel when unloading the cargo of the vessel, and the ballast water is collected in the storage tank without loading the cargo in a certain area, and then the cargo is loaded. After discharge, the ballast water is discharged from the ballast water storage tank, which is usually drained to an area with a completely different ecological environment than the intake. At this time, marine life in a certain area contained in the ballast water to be taken may move to another area and be exposed to a new environment. Invasive species are introduced into indigenous species, which destroys the marine ecosystem and causes environmental and economic losses. It also causes human harm by various pathogens.

For this reason, in 2004, the International Maritime Organization (IMO) enacted an agreement on the management of ballast water and sediment in ships to prevent ecosystem destruction and pollution. From September 2019, after a two-year grace period, all ballast water treatment systems must be mandatory.

In general, ballast water treatment systems use oxidants to kill microorganisms contained in ballast water, to ensure that the oxidant maintains an appropriate concentration for effective microbial killing (e.g., concentrations of 5-15 ppm, Exhaust oxidant should be checked below 0.1ppm). To monitor this, residual chlorine concentration measuring sensor (TRO sensor) is installed on the ballast water inlet and outlet lines.

However, most of the conventional TRO sensors are made for water purification plants or onshore, and it is difficult to measure high concentrations of oxidizing agents of 10 ppm or more, and accurate measurement is possible even in high turbidity conditions such as seawater or raw water containing fluids such as organic matter, aquatic organisms and mud. This was not easy.

In addition, for ballast water treatment systems, at least one liter per second to as many hundreds of liters of sample per second (ship ballast water) pass through the pipe. Conventional TRO sensors typically have a single measurement time (measurement cycle) of 110 seconds. It takes about 10 minutes. That is, the existing TRO sensor can measure the water quality with a measurement interval of about 110 seconds to 10 minutes. In ballast water treatment systems, at least tens of liters per second up to as many as hundreds of liters of water (ship ballast water) will pass through the main piping, and samples passing during the measurement cycle will not be able to measure the concentration by the TRO sensor. As a result, only a few samples of the total ballast water are measured, and large amounts of ballast water flow out without monitoring the water quality. For this reason, if the concentration of a large amount of sample, such as ballast water, should be measured / monitored in real time, structural improvement of the measurement system is necessary so that no sample flows out without monitoring.

Prior Art Document 1: Korean Patent Registration Publication No. 10-1566518 (2015.11.05.)

Prior Art Document 2: Korean Patent Registration Publication No. 10-1303349 (2013.09.03.)

The present invention was invented to solve the above problems, and an object of the present invention is to provide an apparatus for measuring residual chlorine concentration with improved accuracy, which can accurately measure TRO concentration regardless of a measurement cycle.

In addition, an object of the present invention is to provide an apparatus for measuring residual chlorine concentration with improved accuracy, which can accurately measure TRO concentration by improving turbidity of a sample.

In addition, an object of the present invention is to provide a residual chlorine concentration measuring device with improved accuracy that can accurately measure the TRO concentration by supplying a quantitative reagent to the sample.

In order to achieve the above object, the present invention includes a sampling pipe for sampling the sample to be measured from the main pipe flowing the sample; A concentration sensor for measuring a concentration of a sample introduced into the sampling pipe; And stationary means installed at the front end of the concentration measuring sensor in the sampling pipe and allowing the sample introduced into the sampling pipe to settle for a predetermined time, and then supplying the sample to the concentration measuring sensor.

Preferably, the stationary means may include a stationary tank having an inlet at a lower portion thereof, an outlet at an upper portion thereof, and storing a sample introduced into the sampling tube from the main pipe; And a discharge tube extending in the vertical direction in the stationary tank, the discharge tube having at least one discharge hole on an outer circumference thereof.

Here, the discharge tube is provided with one discharge hole, the discharge hole is characterized in that located in the lower portion of the stationary tube.

Alternatively, the discharge tube has a plurality of discharge holes, and the discharge holes are characterized by having a diameter gradually increasing from the lower side to the upper side.

Preferably, the stationary means, the stationary tank having a lower inlet on one side, the outlet on the other side, the stationary tank for storing the sample introduced into the sampling pipe from the main pipe; And partitioning the stationary tank into two spaces arranged side by side in a horizontal direction, and including a partition plate formed at a through hole in an upper portion thereof.

In addition, the reagent storage unit for storing the reagent to be supplied to the concentration measuring sensor; A distilled water storage tank storing distilled water mixed with the reagent supplied from the reagent storage unit; And a mixer for mixing the reagent supplied from the reagent storage unit with the distilled water supplied from the distilled water storage tank, and supplying the reagent mixed with the distilled water to the concentration measuring sensor, wherein the reagent stored in the reagent storage unit is a tablet. A purification reagent in a form, and the reagent reservoir is configured to introduce the purification reagent into the mixer one by one by dropping the reagent into the mixer, and the distilled water storage tank is arranged when the purification reagent is introduced into the mixer. A predetermined amount of distilled water is supplied to the mixer.

Residual chlorine concentration measuring device with improved accuracy according to the present invention can collect the samples that were not measured during the measurement cycle of the concentration sensor to periodically measure the concentration, the method of measuring the TRO concentration for each measurement cycle of the conventional TRO sensor More accurate TRO concentration measurements are possible.

In addition, according to the present invention, it is possible to precipitate a material that affects the turbidity change of the sample, such as various elements, nonmetals, metals, compounds, organics, minerals, microorganisms, bacteria, etc. contained in the sample, which is supplied to the concentration By improving the turbidity of the sample, accurate TRO concentration measurement of the sample is possible.

In addition, according to the present invention, it is possible to accurately measure the TRO concentration of the sample by quantitatively adding a reagent to the sample.

1 is a view schematically showing the configuration of the residual chlorine concentration measuring apparatus with improved accuracy according to the present invention,
Figure 2a schematically shows an example of the stationary means of the residual chlorine concentration measuring apparatus with improved accuracy according to the present invention,
2b is a cross-sectional view of the discharge tube of FIG. 2a,
FIG. 2C is an enlarged view of the discharge tube of FIG. 2A, FIG.
3 is a view schematically showing another example of the stationary means of the residual chlorine concentration measuring apparatus having improved accuracy according to the present invention;
4 is a view showing the configuration of the concentration measuring sensor of the residual chlorine concentration measuring apparatus with improved accuracy according to the present invention,
5 is a schematic cross-sectional view of the mixer of FIG. 4.

Hereinafter, with reference to the accompanying drawings will be described a preferred embodiment of the residual chlorine concentration measuring device with improved accuracy according to the present invention. For reference, in the following description of the present invention, terms referring to the components of the present invention are named in consideration of the function of each component, and should not be understood as a meaning of limiting the technical components of the present invention. Will be.

Referring to Figure 1, the residual chlorine concentration measuring device with improved accuracy according to the present invention for measuring the concentration of the sample to be measured, for example, the total residual oxidant (TRO) concentration, as shown in the figure, Ballast Water Treatment System (BWMS) 100.

The ballast water treatment system 100 is connected to a main pipe 10 extending from a seawater inlet to a ballast tank 200, and introduced into the main pipe 10 by a ballast pump 300. An oxidant is injected into the ballast water to sterilize the ballast water.

In addition, the residual chlorine concentration measuring apparatus having improved accuracy according to the present invention is a concentration measuring sensor installed in the sampling pipe 20, the sampling pipe 20 is bypassed from the main pipe 10 and connected to the ballast tank 200. (TRO sensor) 400 and a fixing means 500 for holding the sample to be measured for a predetermined time.

The sampling pipe 20 is branched from the main pipe 10 between the ballast water treatment system 100 and the ballast tank 200 and bypassed to the ballast tank 200 side, and the main pipe using the sampling pump 600. Samples flowing through (10), ie, ballast water, are sampled.

The concentration sensor 400 serves to measure the TRO concentration of the sample flowing into the ballast tank 200 through the stationary means 500. Here, the concentration measuring sensor 400 absorbs the light emitted from the light source and passes through the sample to measure the absorbance, and the sensor using the absorbance method that quantifies the concentration of the solution using the correlation between the absorbance and the concentration of the solution. Can be.

The stationary means 500 is installed at the front end of the concentration measuring sensor 400 in the sampling pipe 20, and after the sample flowing into the sampling pipe 20 is left for a predetermined time, the sample is supplied to the concentration measuring sensor 400. It plays a role. By the fixing means 500, the sample can be continuously introduced into and stored in the fixing means 500 even during the measurement cycle of the concentration measuring sensor 400. Then, the sample stored in the stationary means 500 is supplied to the concentration measuring sensor 400 in accordance with the measurement interval of the concentration measuring sensor 400 to perform a periodic concentration measurement.

As described above, the residual chlorine concentration measuring device having improved accuracy according to the present invention may collect the sample which was not measured during the measuring cycle of the concentration measuring sensor 400 and periodically measure the concentration. Since the concentration measuring method has an effect of calculating the average value of the TRO concentration of the ballast water flowing into the ballast tank 200 during the measurement cycle of the concentration measuring sensor 400, the TRO is measured every measurement cycle of the conventional TRO sensor. Compared to the method of measuring the concentration, more accurate TRO concentration measurement is possible.

In addition, by the stationary means 500, substances that affect the turbidity change of the sample, such as various elements, nonmetals, metals, compounds, organics, inorganic substances, microorganisms, bacteria, and the like contained in the sample may be precipitated, and thus concentration The turbidity of the sample fed to the measuring sensor 400 is improved. Therefore, the concentration measuring sensor 400 can measure the precise TRO concentration of the sample.

Referring to FIG. 2A, the fixing unit 500 may include a stationary tank 510 for storing a sample and a discharge tube 520 for discharging a sample of the sampling pipe 20 into the stationary tank 510. have.

The stationary tank 510 includes a sample inlet 511 at a lower center thereof, and a sample outlet 512 at an upper outer side thereof. The stationary tank 510 receives and stores a sample introduced into the sample cooling pipe 20 from the main pipe 10.

The discharge tube 520 is connected to the sample inlet 511 of the stationary tank 510, and is installed to extend in a vertical direction to the center of the inside of the stationary tank 510. The discharge tube 520 is provided with at least one discharge hole 521 on the outer circumference thereof, and supplies a sample into the stationary tank 510 through the discharge hole 521.

Here, the discharge tube 520 may have only one discharge hole. In this case, the discharge hole 521 is preferably located below the discharge tube 520.

With this configuration, the sample flowing into the stationary tank 510 gradually starts to fill up from the bottom of the stationary tank 510 and completely fills the inside of the stationary tank 510 only before the sample outlet 512 on the stationary tank 510 is filled. ) May be supplied to the concentration measurement sensor 400 side.

Therefore, since the sample stored in the stationary tank 510 and left for a predetermined time has an average TRO concentration of ballast water flowing into the ballast tank 200 during the measurement cycle of the concentration measuring sensor 400, Compared to measuring the TRO concentration at each measurement cycle of the TRO sensor, more accurate TRO concentration measurements are possible.

In addition, due to the position of the discharge hole 521 of the discharge tube 520, foreign matter contained in the sample is precipitated inside the stationary tank 510, thereby improving turbidity of the sample, so that the accurate TRO concentration of the concentration measuring sensor 400 is improved. Measurement is possible.

Referring to FIG. 2B, preferably, the discharge tube 520 may have a plurality of discharge holes 521. The discharge holes 521 are disposed to be spaced apart from each other along the circumferential direction of the discharge tube 520. In addition, the discharge holes 521 are disposed to be inclined in an inclined direction that forms a predetermined angle with the radial direction of the discharge tube 520. For example, the discharge holes 521 may be disposed tangentially to the outer circumference of the discharge tube 520. Accordingly, when the sample is discharged from the discharge holes 521, the sample discharged into the stationary tank 510 may rotate about the discharge tube 520.

Referring to FIG. 2C, the discharge holes 521 preferably have a diameter that gradually increases from the lower side to the upper side of the discharge tube 520. Accordingly, the sample may be evenly discharged from the upper and lower sides of the stationary tank 510.

Referring to FIG. 3, the fixing unit 500 may include a stationary tank 530 for storing a sample and a partition plate 540 for dividing the sample by dividing the stationary tank 530 into two spaces. .

The stationary tank 530 is provided with a sample inlet 531 in the upper portion on one side, and a sample outlet 532 in the upper portion on the other side. The stationary tank 510 receives and stores a sample introduced into the sample cooling pipe 20 from the main pipe 10.

The partition plate 540 partitions the stationary tank 530 into two spaces 530a and 530b. In this case, the two divided spaces 530a and 530b are arranged side by side in the horizontal direction. In addition, the partition plate 540 has a through hole 541 thereon.

Accordingly, the sample introduced into the one side space 530a of the stationary tank 530 stays for a predetermined time by the partition plate 540, and then the other side space 530b of the stationary tank 530 through the through hole 541. Can be introduced into. At this time, the left space 530a of the stationary tank 530 may serve as a settling tank by the arrangement of the through holes 541.

On the other hand, turbulence is generated by the sample falling from the upper inlet 531 to the inner space 530a of the stationary tank 530, this turbulence can prevent the foreign matter contained in the sample precipitate. In order to prevent such turbulence, turbulence preventing partitions are provided in the spaces 530a and 530b of the stationary tank 530.

Specifically, the turbulence prevention partition wall is obliquely left from below the first partition 551 and the through hole 541 of the partition plate 540 extending a predetermined length downward from the upper surface of the left space 530a of the stationary tank 530. The upper surface of the second partition 552 extending downward, the third partition 553 extending downward obliquely rightward from below the through hole 541 of the partition plate 540 and the right space 530b of the stationary tank 530. It may include a fourth partition 554 extending a predetermined length downward from the.

By the partitions 551, 552, 553, and 554, the sample introduced into the stationary tank 530 from the inlet 531 is restricted in the moving range, thereby suppressing the generation of turbulence, and thus, foreign matter contained in the sample. This can precipitate smoothly.

In addition, the bottom of the stationary tank 530 is provided with a drain pipe 560 for discharging the sample containing the foreign matter to the outside. In addition, the drain pipe 560 may be provided with a discharge valve 570 to control the discharge of the sample. The discharge valve 570 may be opened or closed by a user's operation, or automatically opened or closed when the sample is discharged from the measurement cell of the concentration measuring sensor 400.

4 and 5, the residual chlorine concentration measuring apparatus having improved accuracy according to the present invention may further include a configuration for supplying a quantitative reagent to the concentration measuring sensor 400.

Specifically, the concentration measuring sensor 400 includes a measuring cell 420, a reagent storage unit 430, a distilled water storage tank 440 and a mixer 450 into which the ballast water treated from the pretreatment unit 410 flows. . The reagent reservoir 430 stores the reagent to be supplied to the measurement cell 420, and supplies the reagent to the mixer 450. The distilled water storage tank 440 stores distilled water mixed with the reagent supplied from the reagent storage unit 430, and supplies the distilled water to the mixer 450. The mixer 450 mixes the supplied reagent and distilled water and supplies it to the measurement cell 420.

Here, the reagents stored in the reagent storage unit 430 are tablet reagents, and the reagent storage unit 430 drops the reagents into the mixer 450 by dropping the reagents into the mixer 450. It is composed. To this end, the reagent reservoir 430 is preferably positioned directly above the mixer 430 is configured to inject the reagent in a free-fall method by gravity.

In addition, the distilled water storage tank 440 is controlled to supply a predetermined amount of distilled water to the mixer 450 when the purification reagent of the reagent storage unit 430 is introduced into the mixer 450.

The mixer 450 uniformly mixes distilled water and purification reagents using mixing means such as a stirrer, diffuser, and waterjet, and periodically supplies the mixture to the measurement cell 420 to mix the sample and the reagent.

Referring to FIG. 5, the mixer 450 may include a plurality of inlets 451 spaced apart from each other by a predetermined distance along the circumferential direction of the mixer 450. The inlets 451 are disposed obliquely at an angle with a direction toward the center of the mixer 450. Preferably, the inlets 451 may be disposed tangential to the outer circumference of the mixer 450. When distilled water is introduced into the mixer 450 by the arrangement of the inlets 451, the distilled water rotates inside the mixer 450 to form a vortex, and thus, the reagent and the distilled water can be mixed smoothly.

As such, the reagent supplied to the mixer 450 may be quantitatively supplied as a tablet-type purification reagent, and the distilled water storage tank 440 may be controlled to inject distilled water according to the supply of the purification reagent, and the reagent may be supplied through the mixer 450. This may be periodically supplied to the measuring cell 420. Accordingly, the sample and the quantitative reagent are mixed in the measurement cell 420 to color the sample with uniform brightness, and thus accurate TRO concentration measurement is possible.

The embodiments of the present invention described above are merely illustrative of the technical idea of the present invention, and the protection scope of the present invention should be interpreted by the following claims. In addition, one of ordinary skill in the art to which the present invention pertains will be capable of various modifications and variations without departing from the essential characteristics of the present invention, all technical ideas within the scope equivalent to the present invention of the present invention It should be interpreted as being included in the scope of rights.

Claims (9)

A sampling pipe for sampling the sample to be measured from the main pipe through which the sample flows;
A concentration sensor for measuring a concentration of a sample introduced into the sampling pipe; And
And a settling means provided at the front end of the concentration measuring sensor in the sampling pipe, and allowing the sample introduced into the sampling pipe to settle for a predetermined time, and then supplying the sample to the concentration measuring sensor.
A stationary tank having an inlet at a lower portion thereof, an outlet at an upper portion thereof, and storing a sample introduced into the sampling tube from the main pipe; And
Residual chlorine concentration measuring device with improved accuracy, characterized in that it is installed extending in the vertical direction in the stationary tank, the discharge tube having at least one discharge hole in the outer periphery.
The method of claim 1,
The discharge tube is provided with one discharge hole, the discharge hole is a residual chlorine concentration measuring device, characterized in that located in the lower portion of the discharge tube.
The method of claim 1,
The discharge tube has a plurality of discharge holes, the discharge holes are arranged spaced apart from each other along the circumferential direction of the discharge tube, tangential to the outer periphery of the discharge tube is disposed in the fluid inside the stationary tank Residual chlorine concentration measuring device, characterized in that the rotating.
The method of claim 1,
And the discharge tube has a plurality of discharge holes, and the discharge holes have a diameter gradually increasing from the lower side to the upper side.
A sampling pipe for sampling the sample to be measured from the main pipe through which the sample flows;
A concentration sensor for measuring a concentration of a sample introduced into the sampling pipe; And
And a settling means provided at the front end of the concentration measuring sensor in the sampling pipe, and allowing the sample introduced into the sampling pipe to settle for a predetermined time, and then supplying the sample to the concentration measuring sensor.
A stationary tank having an inlet on one side and an outlet on the other side and storing a sample introduced from the main pipe into the sampling pipe; And
And dividing the stationary tank into two spaces arranged side by side in a horizontal direction, and including a partition plate formed in a through hole in an upper portion thereof.
The method of claim 5,
A first partition wall extending a predetermined length downward from an upper surface of a left space of the stationary tank; a second partition wall extending obliquely downward from the bottom of the partition plate; and a right side obliquely below the through hole of the partition plate. An apparatus for measuring residual chlorine concentration with improved accuracy, further comprising a turbulence preventing partition including a third partition extending downward and a fourth partition extending downward from an upper surface of the right space of the stationary tank.
The method according to claim 1 or 5,
The concentration measuring sensor,
A measuring cell into which treated ballast water is introduced;
A reagent storage unit storing a reagent to be supplied to the measurement cell;
A distilled water storage tank configured to store distilled water mixed with a reagent supplied from the reagent storage unit; And
And a mixer for mixing the reagent supplied from the reagent storage unit with the distilled water supplied from the distilled water storage tank, and supplying the reagent mixed with the distilled water to the measuring cell.
The reagent stored in the reagent reservoir is a tablet reagent in tablet form, and the reagent reservoir is configured to introduce the purified reagent into the mixer one by one by dropping reagent into the mixer,
The distilled water storage tank is a residual chlorine concentration measuring device with improved accuracy, characterized in that when the purification reagent is added to the mixer, a predetermined amount of distilled water is supplied to the mixer.
The method of claim 7, wherein
The mixer has a plurality of inlets spaced apart from each other along the circumferential direction, the inlet is disposed in a tangential direction with respect to the outer circumference of the mixer to allow the fluid inside the mixer to rotate when distilled water is introduced Residual chlorine concentration measuring device. delete

Images