KR102065356B1 - A method of manufacturing of vanilla extract using Gastrodia elata BLUME as catalyst - Google Patents

Abstract

The present invention relates to a method for preparing vanilla extract using cheonma as a catalyst, and specifically, by extracting vanilla bean and cheonma powder by leaching 30-30% ethanol or 20-40 alcohol (1) to increase the efficiency of the vanilla indicator component. And (2) reduce vanilla extraction costs, and (3) prepare vanilla extract with enhanced flavor.

Description

A method of manufacturing of vanilla extract using Gastrodia elata BLUME as catalyst}

The present specification relates to a method for preparing a vanilla extract using a cheonma catalyst, a vanilla extract prepared by the method and a food composition comprising the vanilla extract.

Vanilla Planifolia has been used as a spice since ancient times as the fruit of the orchid family native to tropical America Mexico. Vanilla fruit is obtained through artificial insemination by man, which itself has no taste and aroma. The use of vanilla as a spice requires a process of steaming and drying the vanilla bean several times, typically three to six months. It is only after this processing that a vanilla processing bean with a distinctive black scent is produced.

Cheonma is a perennial herb that grows in the deep mountains of Korea. It grows in damp stone gaps and in oak trees in shades or shades. According to the herbaceous tree, Dongbobom, Chunma is known to have an excellent antioxidant effect, and is effective in adult diseases such as hypertension, headache, paralysis, neurological disease and diabetes. It contains gastrodin, vanillyl alcohol, citosterol, vanillin, coumarin, p-hydroxybenzoic acid, vanillic acid, and p-hydroxy benzaldehyde. Although indicators such as vanilla are included, deeper systematic studies have not been conducted as they are listed intermittently and fragmentarily in the papers of China.

Due to the recent rise in labor costs associated with worsening weather in vanilla and cultivation through artificial insemination and increasing demand for vanilla worldwide, confectionery, bakery, and food industries are facing new challenges such as supply instability, deterioration in quality, and rising prices in vanilla beans. have. Vanilla extract is generally finely chopped vanilla processing bin within 1cm and immersed in alcohol or ethanol to make the extract, the quality depends on the varieties, production time, production location, moisture content and processing method of vanilla. In addition, even when the quality is the same, the quality of the extract depends on the type and composition of the extraction solvent, the extraction temperature, the extraction period and the like.

In Korean Patent Application Publication No. 10-1291181, a method for preparing a functional beverage using cheonma extract is known.

In Korean Patent Application Publication No. 2016-0072700, a method for preparing an extract using vanilla gourd is known.

Korea Patent Publication KR 10-1291181 Korean Patent Publication KR 2016-0072700

The present invention seeks to provide a new method of preparing vanilla extracts having a richer flavor as well as increasing the content of indicator components present in vanilla by deriving extracts using cheonma as catalysts rather than simple extracts of vanilla beans.

One aspect of the present invention is to provide a method for producing a vanilla extract using the cheonma as a catalyst.

Another aspect of the present invention is to provide a vanilla extract prepared using the cheonma as a catalyst.

Another aspect of the present invention, to provide a food composition comprising a vanilla extract prepared by the above method.

One aspect of the present invention is a method for producing a vanilla extract,

The method includes the step of extracting a mixture of vanilla in the vanilla (Vanilla), the cheonma provides a method for producing a vanilla extract, characterized in that acts as a catalyst in vanilla extraction.

In one aspect of the invention, the cheonma provides a method for producing a vanilla extract, which is mixed with 5 to 50 parts by weight based on 100 parts by weight of vanilla.

In one aspect of the invention, the cheonma provides a method for producing a vanilla extract, which is mixed with 25 to 35 parts by weight based on 100 parts by weight of vanilla.

In one aspect of the invention, the vanilla is vanilla bean (vanilla bean), the vanilla bean is broken up to 1 cm or less in diameter, the cheonma provides a method of producing a vanilla extract in powder form.

In one aspect of the invention, after mixing the cheonma and the vanilla, it provides a method for producing a vanilla extract, extracted using water, C ₁ -C ₅ alcohol or C ₁ -C ₅ alcohol aqueous solution.

In one aspect of the invention, the extraction is to extract for 1 to 7 days at a temperature of 20 to 50 ℃, provides a method for producing a vanilla extract.

Another aspect of the present invention provides a vanilla extract prepared by the method according to any one of the above.

In another aspect of the invention, the vanilla extract provides a vanilla extract comprising any one or more of the following active ingredients:

(a) p-hydroxy benzoic acid whose p-hydroxy benzoic acid is 62.3 ppm or more based on the total weight of the extract,

(b) vanillic acid having vanillic acid of at least 206 ppm with respect to the total weight of the extract,

(c) p-hydroxy benzaldehyde whose p-hydroxy benzaldehyde is 150 ppm or more based on the total weight of the extract, and

(d) Vanillin (Vanillin) is 2150 ppm or more based on the total weight of the extract.

Another aspect of the present invention provides a food composition comprising a vanilla extract prepared by the manufacturing method according to any one of the above.

Vanilla extract according to an aspect of the present invention can be applied to a variety of confectionery products by adjusting the mixing ratio because it increases the vanilla flavor while increasing the components of p-hydroxybenzoic acid, vanillic acid, p-hydroxybenzaldeyde, vanillin.

1 is a result of grouping whether the vanilla extract is organoleptically similar even when using cheonma as a result according to Experimental Example 2 of the present invention.

Objects, other objects, features and advantages of the present invention will be readily understood through the following preferred embodiments associated with the accompanying drawings. However, the present invention is not limited to the embodiments described herein and may be embodied in other forms. Rather, the embodiments introduced herein are provided so that the disclosure may be made thorough and complete, and to fully convey the spirit of the invention to those skilled in the art.

In this specification, terms such as "comprise" or "have" are intended to indicate that there is a feature, number, step, operation, component, part, or combination thereof described on the specification, one or more other features. It is to be understood that the present invention does not exclude the possibility of the presence or the addition of numbers, steps, operations, components, parts, or combinations thereof.

Unless otherwise stated, all numbers, values, and / or expressions expressing amounts of components, reaction conditions, compositions, and combinations used herein are measurements of what these numbers occur inherently in obtaining these values, among others. Since these are approximations that reflect various uncertainties of, it should be understood that in all cases they are modified by the term "about." Also, where numerical ranges are disclosed herein, these ranges are continuous and include all values from the minimum to the maximum including the maximum, unless otherwise indicated. Furthermore, where such ranges refer to integers, all integers are included, including the minimum to the maximum including the maximum unless otherwise indicated.

In the present specification, when a range is described for a variable, it will be understood that the variable includes all values within the described range including the listed endpoints of the range. For example, the range "5 to 10" includes any subrange such as 6 to 10, 7 to 10, 6 to 9, 7 to 9, as well as values of 5, 6, 7, 8, 9, and 10. And any value between integers that are within the scope of the described ranges such as 5.5, 6.5, 7.5, 5.5-8.5, 6.5-9, and the like. Also for example, the range of “10% to 30%” may range from 10% to 15%, 12% to 10%, 11%, 12%, 13%, etc. as well as all integers including up to 30%. It will be understood to include any subranges such as 18%, 20% to 30%, etc., and any value between reasonable integers within the range of the stated range, such as 10.5%, 15.5%, 25.5% and the like.

The present invention provides a vanilla extraction method using cheonma as a catalyst.

One aspect of the present invention is a method for producing a vanilla extract,

The method includes a step of extracting a mixture of cheonma in vanilla ( vanilla ), the cheonma provides a method of producing a vanilla extract, characterized in that acts as a catalyst in vanilla extraction.

Vanilla as used herein is Vanilla planifolia It may be a plant, and vanilla, which is used as a raw material in the preparation of the extract, may use soybean, which is a fruit of vanilla, as a raw material.

In this specification, the horse is Gastrodia 　 It may be elata BLUME, cheonma used as a raw material in the preparation of the extract may be a stem of cheonma, but is not limited thereto.

As used herein, the term "extract" includes any material obtained by extracting a component therefrom from a natural product, regardless of the method of extraction or the kind of the component. For example, it is a broad concept including the thing which extracted the component melt | dissolved in a solvent from a natural product using water or an organic solvent, the thing obtained by extracting only the specific component of a natural product, etc. In one embodiment of the present invention, the organic solvent is not particularly limited, C1 ~ C5 lower alcohol, glycerol, ethylene, such as methanol, ethanol, isopropyl alcohol, n-propyl alcohol, n-butanol and isobutanol Polyhydric alcohols such as glycol, propylene glycol, 1,3-butylene glycol, hydrocarbon solvents such as methyl acetate, ethyl acetate, benzene, n-hexane, diethyl ether, dichloromethane, chloroform, petroleum ether, methyl acetate, Non-polar organic solvents such as benzene, hexane, chloroform, methylene chloride, dimethyl ether, ethyl acetate and the like.

In one aspect of the invention, the cheonma provides a method for producing a vanilla extract, which is mixed with 5 to 50 parts by weight based on 100 parts by weight of vanilla.

In one aspect of the invention, the cheonma provides a method for producing a vanilla extract, which is mixed with 25 to 35 parts by weight based on 100 parts by weight of vanilla.

In one embodiment, the cheonma is at least 5 parts by weight, at least 7 parts by weight, at least 9 parts by weight, at least 11 parts by weight, at least 13 parts by weight, at least 15 parts by weight, at least 17 parts by weight, based on 100 parts by weight of vanilla. It may be included in at least part by weight, at least 21 parts by weight, at least 23 parts by weight, at least 25 parts by weight, at least 27 parts by weight or at least 29 parts by weight. In addition, the cheonma 50 parts by weight or less, 45 parts by weight, 40 parts by weight, 38 parts by weight, 37 parts by weight, 35 parts by weight, 33 parts by weight, 31 parts by weight or less based on 100 parts by weight of vanilla Or 30 parts by weight or less. When the weight ratio of vanilla and cheonma satisfies the above range, it is possible to prepare vanilla extract having a richer flavor as well as increasing the content of indicator components present in vanilla.

In one aspect of the invention, the vanilla is vanilla bean (vanilla bean), the vanilla bean is broken up to 1 cm or less in diameter, the cheonma provides a method of producing a vanilla extract in powder form. The vanilla beans may have a diameter of 1.0 cm or less, 0.9 cm or less, 0.8 cm or less, 0.7 cm or less, 0.6 cm or less, or 0.5 cm or less.

In one aspect of the invention, after mixing the cheonma and the vanilla, it provides a method for producing a vanilla extract, extracted using water, C ₁ -C ₅ alcohol or C ₁ -C ₅ alcohol aqueous solution.

In one aspect of the invention, the concentration of the C ₁ -C ₅ alcohol aqueous solution may be 40% to 90% (v / v). In one embodiment, the concentration of the C ₁ -C ₅ alcohol aqueous solution is at least 40%, at least 45%, at least 50%, at least 55%, at least 60%, at least 65%, at least 66%, at least 67%, 68% Or at least 69%, at least 70%, at least 71%, at least 72%, at least 73%, at least 74%, at least 75%, or at least 80%. In addition, the concentration of the C ₁ -C ₅ alcohol aqueous solution is 90% or less, 85% or less, 80% or less, 75% or less, 74% or less, 73% or less, 72% or less, 71% or less, 70% or less, 69 Up to 68%, up to 67%, up to 65%, or up to 60%. When the concentration of the C ₁ -C ₅ alcohol solution is within the above range, it is possible to prepare vanilla extract having a richer flavor as well as increasing the content of indicator components present in vanilla.

In one aspect of the present invention, the C ₁ -C ₅ alcohol, may be used using any one or more selected from the group consisting of methanol, ethanol, isopropyl alcohol, n-propyl alcohol, n-butanol and isobutanol.

In one aspect of the invention, the extraction is to extract for 1 to 7 days at a temperature of 20 to 50 ℃, provides a method for producing a vanilla extract.

In one embodiment, the temperature conditions may be at least 20 ° C, at least 23 ° C, at least 25 ° C, at least 27 ° C, at least 29 ° C, at least 31 ° C, at least 33 ° C, at least 35 ° C or at least 37 ° C. The temperature conditions may be 50 ° C. or less, 48 ° C. or less, 46 ° C. or less, 44 ° C. or less, 42 ° C. or less, or 38 ° C. or less.

Another aspect of the present invention provides a vanilla extract prepared by the method according to any one of the above.

In another aspect of the invention, the vanilla extract provides a vanilla extract comprising any one or more of the following active ingredients:

(a) p-hydroxy benzoic acid whose p-hydroxy benzoic acid is 62.3 ppm or more based on the total weight of the extract,

(b) vanillic acid having vanillic acid of at least 206 ppm with respect to the total weight of the extract,

(c) p-hydroxy benzaldehyde whose p-hydroxy benzaldehyde is 150 ppm or more based on the total weight of the extract, and

(d) Vanillin (Vanillin) is 2150 ppm or more based on the total weight of the extract.

In one embodiment, the p-hydroxy benzoic acid may be at least 62.5ppm, at least 62.7ppm, at least 62.9ppm, at least 63ppm, at least 64ppm, at least 65ppm, at least 66ppm or at least 67ppm, based on the total weight of the extract.

In one embodiment, the vanillic acid may be at least 206 ppm, at least 207 ppm, at least 208 ppm, at least 209 ppm, at least 210 ppm, or at least 211 ppm, based on the total weight of the extract.

In one embodiment, the p-hydroxy benzaldehyde may be at least 150 ppm, at least 151 ppm, at least 152 ppm, at least 153 ppm, at least 154 ppm, at least 155 ppm, at least 156 ppm or at least 157 ppm with respect to the total weight of the extract. .

In one embodiment, the vanillin (Vanillin) is at least 2150 ppm, at least 2160 ppm, at least 2170 ppm, at least 2180 ppm, at least 2190 ppm, at least 2200 ppm, at least 2210 ppm, at least 2220 ppm, 2230 ppm, based on the total weight of the extract. Or 2240 ppm or more.

Another aspect of the present invention provides a food composition comprising a vanilla extract prepared by the manufacturing method according to any one of the above.

In one aspect of the present invention, the composition may be a food composition, and for example, various foods, beverages, gums, teas, dietary supplements, and the like, and may be used in the form of powders, granules, tablets, capsules, or beverages. In addition to the active ingredient, the food composition of each formulation may be suitably selected by a person skilled in the art according to the formulation or purpose of use in addition to the active ingredient, and may be synergistic when applied simultaneously with other raw materials.

In one embodiment, the vanilla bean and cheonma are finely chopped vanilla bean after the ripening step is 0.5 cm or less and the cheonma is purchased as a powder, preferably in a ratio of 1 to 5:10, preferably 3:10 Mixing; Adding 30 to 60% alcohol, preferably 40% of alcohol, in 3 to 6 multiples, extracting 20 to 130 hours at 20 to 50 hours, preferably at 25 conditions for 30 hours; Filtering the extract using a 0.45 μl filter; It can be prepared by.

In one embodiment, the vanilla extract using the cheonma as a catalyst can be used as it is obtained, it can be used after dilution with purified water according to your preference. Vanilla extract of the present invention may comprise about 10 to 40% by weight cheonma powder.

Hereinafter, the present invention will be described in more detail through experimental examples. However, the following examples are only presented to understand the present invention, and the scope of the present invention is not limited to the following experimental examples. Preferred embodiments of the present invention are described in more detail with reference to the following examples.

Example  One

The mature vanilla bean purchased from Vanipro Co., Ltd. is finely chopped to 0.5 cm or less and prepared chunky flour purchased from Bluefield. Add 100 parts by weight of chopped vanilla to 100 parts by weight of chopped vanilla and extract for 25 to 30 hours at 40% alcohol.

Example  2 ~ 4

Extraction temperature, time, ratio were carried out in the same manner as in Example 1, except that the addition of the conditions shown in Table 1 below to obtain a vanilla extract with the cheonma as a catalyst.

Condition Comparative Example 1 Example 1 Example 2 Example 3 Example 4 25, 30 hours 100% vanilla
Chunma 0% Vanilla 100% Cheonma 10% 100% vanilla
Chunma 20% 100% vanilla
Chunma 30% 100% vanilla
Chunma 40%

Comparative example  One

The vanilla bean cut to about 0.5 cm is extracted under the same conditions as above without adding cheonma flour.

Experimental Example  One

HPLC analysis was performed to determine the content of the four main indicators (p-hydroxy benzoic acid, vanillic acid, p-hydroxy benzaldehyde, vanillin) of the vanilla extract prepared in Examples 1 to 4 and Comparative Example 1. The X-Bridge-C18 column (150x4.6mm) was used at 5μm with a flow rate of 0.5ml / min, λ 254nm, and a run time of 15 minutes. The results are as shown in Table 2 below.

Temperature / hour Comparative Example 1 Example 1 Example 2 Example 3 Example 4 25 ℃,
30 hours 100% vanilla
Chunma 0% Vanilla 100% Cheonma 10% 100% vanilla
Chunma 20% 100% vanilla
Chunma 30% 100% vanilla
Chunma 40% p-hydroxy
benzoic acid (ppm) 62.21 62.48 63.57 68.20 65.72 Vanillic acid (ppm) 205.74 210.25 211.12 218.94 206.76 p-hydroxy benzaldehyde (ppm) 149.74 155.91 155.98 161.39 155.30 Vanillin (ppm) 2123.27 2231.14 2238.66 2306.16 2251.74

According to the results of Table 2, it was confirmed that Examples 1 to 4 increased all four vanilla index components than Comparative Example 1, cheonma powder acted as a catalyst in vanilla extraction. When comparing the examples, it was best when the ratio of vanilla and cheonma powder was 10: 3, and tended to decrease at higher ratios.

Experimental Example  2

Electronic nose was used to measure the sensory similarity of the extract prepared in Examples 1 to 4 and Comparative Example 1. The result is as shown in FIG. The figure below is a diagram measuring similar groups using Comparative Example 1 as a standard.

As shown in FIG. 1, each difference between Examples 1 to 4 was small, but Example 3 was the most similar and Example 4 was the farthest. It was shown that vanilla extract with cheonma powder as a catalyst has no significant difference in organoleptic sense and is similar to the conventional one.

Claims (9)

In the manufacturing method of the vanilla extract,
The method includes the step of extracting by mixing 25 to 35 parts by weight of cheonma per 100 parts by weight of vanilla ( vanilla ),
The vanilla extract includes at least one of p-hydroxy benzoic acid, vanillic acid, p-hydroxy benzaldehyde, and vanillin as an active ingredient. ,
P-hydroxy benzoic acid is at least 66ppm, vanyl acid is at least 212ppm, p-hydroxy benzaldehyde is at least 156ppm, and vanillin is at least 2260ppm, based on the total weight of vanilla extract.
delete delete The method of claim 1,
The vanilla is vanilla bean (vanilla bean), the vanilla beans are cut to 1 cm or less in diameter,
The cheonma is in the form of a powder, vanilla extract manufacturing method.
The method of claim 1,
After mixing the cheonma and the vanilla, using a water, C ₁ -C ₅ alcohol or C ₁ -C ₅ alcohol aqueous solution, the method of producing a vanilla extract.
The method of claim 1,
The extraction is to extract for 1 to 7 days at a temperature of 20 to 50 ℃, the method of producing a vanilla extract.
delete delete delete

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