KR102042875B1 - Method for manufacturing conducting substrate and conducting substrate manufactured the same - Google Patents
Method for manufacturing conducting substrate and conducting substrate manufactured the same Download PDFInfo
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- KR102042875B1 KR102042875B1 KR1020150185370A KR20150185370A KR102042875B1 KR 102042875 B1 KR102042875 B1 KR 102042875B1 KR 1020150185370 A KR1020150185370 A KR 1020150185370A KR 20150185370 A KR20150185370 A KR 20150185370A KR 102042875 B1 KR102042875 B1 KR 102042875B1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B5/00—Non-insulated conductors or conductive bodies characterised by their form
- H01B5/14—Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/136—Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
Abstract
The present specification relates to a method for manufacturing a conductive substrate, a conductive substrate manufactured thereby, and a single-sided single-sheet touch panel and display device including the same.
Description
The present specification relates to a method of manufacturing a conductive substrate and a conductive substrate produced thereby.
The display apparatus is a term referring to a TV, a computer monitor, and the like, and includes a display element for forming an image and a case for supporting the display element.
With respect to display devices, as the spread of smart phones, tablet PCs, and IPTVs is accelerated, there is an increasing need for a touch function in which a human hand directly inputs devices without a separate input device such as a keyboard or a remote controller. In addition, a multi-touch function capable of writing as well as a specific point recognition is required.
A touch panel used in such a display is generally formed by forming conductive patterns on upper and lower substrates, and laminating them through an insulating layer. As the conductive pattern, an ITO-based conductive film is used a lot. However, when the ITO is applied to a large area touch panel, the recognition speed is low due to its own RC delay.
In order to overcome this problem, attempts have been made to introduce additional compensation chips, but this has a problem that the price is increased.
Therefore, many attempts have been made to replace the conventional ITO pattern with a metal pattern. However, when the metal pattern is used, it is difficult to make a fine pattern with high precision that is inconspicuous in terms of visibility, and when the photolithography method is used, the process The problem is that it is very complicated and the process cost is very high.
An object of the present disclosure is to provide a conductive substrate, a touch panel including the same, and a display device including the same.
One embodiment of the present specification
Forming a first conductive pattern on the substrate, the first conductive pattern including two or more conductive pattern rows including a first groove portion and a first conductive layer provided in the first groove portion;
A second conductive layer provided in the second groove portion and the second groove portion on the same surface as the surface on which the first conductive pattern is provided, but spaced apart from the first conductive pattern, Forming a second conductive pattern including two or more conductive pattern regions provided with one or more conductive pattern rows of the first conductive pattern interposed therebetween;
Treating the surface of the substrate provided with the first conductive pattern and the second conductive pattern with a substrate soluble material; And
Electrically connecting conductive pattern regions of the second conductive pattern across at least one conductive pattern column of the first conductive pattern, the conductive bridge being spaced apart from the first conductive layer of the first conductive pattern; It provides a method for producing a conductive substrate comprising.
In addition, an exemplary embodiment of the present specification provides a conductive substrate manufactured by the manufacturing method.
In addition, an exemplary embodiment of the present specification
materials;
A first conductive pattern including two or more conductive pattern rows including a first groove provided on the substrate and a first conductive layer provided in the first groove;
A second groove portion provided on the same surface as the surface on which the first conductive pattern is provided, and a second conductive layer provided in the second groove portion, and spaced apart from the first conductive pattern, A second conductive pattern including two or more conductive pattern regions provided with one or more conductive pattern rows of the first conductive pattern interposed therebetween; And
A conductive bridge electrically connecting conductive pattern regions of the second conductive pattern across at least one conductive pattern row of the first conductive pattern, the conductive bridge being spaced apart from the first conductive layer of the first conductive pattern,
At least one width of the first groove portion or the second groove portion provides a conductive substrate narrower than the width of the lower portion in the thickness direction.
In addition, an exemplary embodiment of the present specification provides a single-sided single-sheet touch panel including the conductive substrate.
In addition, an exemplary embodiment of the present disclosure provides a display device including the conductive substrate.
According to an exemplary embodiment of the present specification, the production cost is reduced as compared to the existing two-sheet touch panel reduced to one sheet.
In addition, according to one embodiment of the present specification, since the alignment process of the Tx film and the Rx film required in the case of the conventional two-sheet touch panel is unnecessary, there is an effect of ease of the process and a yield increase.
In addition, according to one embodiment of the present specification, the insulation process can be eliminated compared to the conventional single-sheet touch screen, thereby reducing the cost.
1 is a schematic diagram showing an arrangement of a first conductive pattern and a second conductive pattern according to an exemplary embodiment of the present specification.
2 illustrates an arrangement of the first conductive pattern and the second conductive pattern according to one embodiment of the present specification.
3 is a view schematically showing a second conductive pattern according to an exemplary embodiment of the present specification.
4 is a view schematically showing a first conductive pattern according to an exemplary embodiment of the present specification.
5 is a schematic diagram showing a groove in a conductive substrate manufactured according to one embodiment of the present specification.
Advantages and features of the present application, and a method of achieving them will be apparent with reference to the embodiments described below in detail in conjunction with the accompanying drawings. However, the present application is not limited to the exemplary embodiments disclosed below, but may be implemented in various forms, and the exemplary embodiments only allow the disclosure of the present application to be complete and the general knowledge in the technical field to which the present application belongs. It is provided to fully convey the scope of the invention to those skilled in the art, and the present application is only defined by the scope of the claims.
Unless otherwise defined, all terms including technical and scientific terms used herein may be used in a sense that can be commonly understood by those of ordinary skill in the art to which this application belongs. In addition, the terms defined in the commonly used dictionaries are not ideally or excessively interpreted unless they are specifically defined clearly.
Hereinafter, the present invention will be described in detail.
One embodiment of the present specification
Forming a first conductive pattern on the substrate, the first conductive pattern including two or more conductive pattern rows including a first groove portion and a first conductive layer provided in the first groove portion;
A second conductive layer provided in the second groove portion and the second groove portion on the same surface as the surface on which the first conductive pattern is provided, but spaced apart from the first conductive pattern, Forming a second conductive pattern including two or more conductive pattern regions provided with one or more conductive pattern rows of the first conductive pattern interposed therebetween;
Treating the surface of the substrate provided with the first conductive pattern and the second conductive pattern with a substrate soluble material; And
Electrically connecting conductive pattern regions of the second conductive pattern across at least one conductive pattern column of the first conductive pattern, the conductive bridge being spaced apart from the first conductive layer of the first conductive pattern; It provides a method for producing a conductive substrate comprising.
In the case of the conventional two-sheet touch panel, more processes are required than the single-sheet touch panel, and the Tx film and the Rx film require an axis alignment process separately, which results in a complicated process and a high production cost. In addition, in the case of the conventional single-sided single-sided touch panel, since a separate insulating layer is provided to insulate between the first conductive pattern and the second conductive pattern, an insulation process is required and the process is complicated.
Accordingly, the present inventors have developed a single-sided single-sheet touch panel and a conductive substrate used therein, which have an effect of reducing production cost compared to the conventional two-sheet touch panel, and also compared to the conventional single-sheet touch panel and the conductive substrate. A single-sheet touch panel without an insulating layer and a conductive substrate used therein have been developed.
Specifically, according to the exemplary embodiments of the present specification, as compared with the conventional two-sheet touch panel, the production cost is reduced by reducing to one sheet, and in the case of the conventional two-sheet touch screen, Tx film and Rx film required Since there is no need for the alignment process, there is an effect of increasing the ease of the process and yield.
In addition, since the single-sided single-sheet touch panel according to the exemplary embodiments of the present specification can eliminate the existing insulation process, it is possible to expect an effect of cost reduction.
According to an exemplary embodiment of the present specification, when there is a difference in the width and / or the depth of the first groove portion of the first conductive pattern and the second groove portion of the second conductive pattern, the substrate having the first groove portion and the second groove portion is formed. It provides a method for producing a conductive substrate to wipe the surface of the substrate with a material that can be.
In the present specification, the substrate is formed with a first groove portion and a second groove portion, and may also be referred to as a resin pattern layer.
That is, according to the exemplary embodiment of the present specification, the first and second conductive patterns include a resin pattern layer and a groove portion, and the resin pattern layer is dissolved by the substrate soluble material, and the first conductive pattern is dissolved resin. The insulation is completely covered with the pattern layer, and the second conductive pattern is not completely insulated by the difference in width and / or depth of the groove portion.
Therefore, by the above method, even without a separate insulating layer, it is possible to insulate between the first conductive pattern and the second conductive pattern, the second conductive pattern that is not completely insulated by using a conductive bridge Can be electrically connected.
In case of the conventional insulation process, since the insulation material must be applied to the exact coordinates, the process has a complicated problem. However, according to the present invention, there is no need to make such an effort in the insulation process, thereby simplifying the process.
According to one embodiment of the present specification, the substrate soluble material may be used without limitation as long as it is a material capable of melting the resin pattern layer forming the conductive pattern. As for the material of the resin pattern layer forming the conductive pattern, the content of the resin pattern layer described later may be equally applied.
According to one embodiment of the present specification, the base soluble material may be an alkaline solution, may include an alcohol, or may be an alcohol.
For example, the alcohol includes methanol, ethanol, propanol, butanol, pentanol, hexanol, heptanol, octanol, nonanol, decanol, undecanol, dodecanol, tridecanol, tetradecanol, penta. Decanol, hexadecanol, 2-methylpropan-1-ol, 3-methylbutan-1-ol, propan-2-ol, 2-methylbutan-1-ol, cyclohexanol, 2-methylpropane-2 -Ol, 2-methylbutan-2-ol, 2-methylpentan-2-ol, 2-methylhexane-2-ol, 2-methylheptan-2-ol, 3-methylpentan-3-ol, 3- Methyl octan-3-ol etc. can be used.
According to one embodiment of the present specification, a method of treating the surface of the substrate provided with the first conductive pattern and the second conductive pattern with a substrate soluble material is not particularly limited, and forms the first conductive pattern and the second conductive pattern. Any method that can melt the resin pattern layer to be used can be used without limitation. Specifically, the method of treating the substrate soluble material on the first conductive pattern and the second conductive pattern may include spraying, coating, dipping, dropping, coating, and the like.
According to an exemplary embodiment of the present disclosure, the step of treating the surface of the substrate provided with the first conductive pattern and the second conductive pattern with a substrate soluble material, the substrate soluble material to form the first conductive pattern and the second conductive pattern By melting the resin, the surface of the first conductive pattern may be completely insulated, and the surface of the second conductive pattern may not be completely insulated.
That is, according to the exemplary embodiment of the present specification, through the step of treating the surface of the substrate provided with the first conductive pattern and the second conductive pattern with a substrate soluble material, the first conductive pattern is a whole surface of the conductive pattern It is coated with a resin pattern layer material to be formed, and the second conductive pattern may be coated with a resin pattern layer material to form only a conductive pattern on a part of the surface.
According to an exemplary embodiment of the present disclosure, the step of treating the surface of the substrate provided with the first conductive pattern and the second conductive pattern with a substrate soluble material is a resin pattern layer in which all of the surface of the first conductive pattern forms a conductive pattern Coating with a material and coating with a resin pattern layer material wherein a portion of the surface of the second conductive pattern forms a conductive pattern.
According to the exemplary embodiment of the present specification, as the material of the resin pattern layer forming the conductive pattern, resins known in the art may be used, and the content of the resin pattern layer described below may be equally applied.
That is, according to one embodiment of the present specification, the material of the resin pattern layer forming the conductive pattern may be at least one selected from the group consisting of an active energy ray curable resin, a thermosetting resin, a conductive polymer resin, and a combination thereof. Include. More specifically, urethane acrylate, epoxy acrylate, ester acrylate, polydimethyl siloxane, polyacetylene, poly paraphenylene, poly aniline, polypyrrole and the like, but may not be limited thereto.
In the present specification, the expression “conductive pattern” includes a groove portion and a conductive layer provided in the groove portion, and includes a case in which a pattern shape is formed in a specific shape instead of the front layer. The conductive pattern may include two or more conductive pattern regions to be described later, or two or more conductive pattern rows. In the present invention, a metal pattern may be applied as the conductive pattern. Here, the metal pattern is interpreted to include not only the case where the conductive layer is made of metal but also an additive other than the metal in the structure consisting of the groove part and the conductive layer provided in the groove part. The first conductive pattern includes a structure in which two or more conductive pattern rows to be described later are disposed, and the second conductive pattern means that two or more conductive pattern regions to be described later are arranged in a predetermined direction.
In the present specification, descriptions of only the conductive patterns and not the expressions such as the first or the second may be applied to both the first conductive pattern and the second conductive pattern. 1 is a unit constituting the conductive pattern, the conductive pattern consisting of the first groove portion and the first conductive layer has a form of a row extending in one direction, the conductive pattern included in the column is connected to each other electrically Have The conductive pattern rows may be disposed parallel to each other on a substrate.
In the present specification, the conductive pattern region is a unit constituting the second conductive pattern, and includes a case in which a conductive pattern including a second groove portion and a second conductive layer is formed to have a predetermined area, and the conductive pattern provided within the area. They have a structure electrically connected to each other. Two or more conductive pattern regions are disposed with one or more conductive pattern rows of the first conductive pattern interposed therebetween. The shape of the region having a predetermined area is not particularly limited, and may have a shape of a circle, a polygon, or the like, but the shape may be designed as necessary. The areas having a predetermined area do not necessarily have to be arranged in a straight line, and they need to be arranged in a specific direction so that they can be electrically connected by the conductive bridge.
In addition, according to one embodiment of the present specification, the conductive pattern may be electrically connected to an external power source by a conductive line through a printed circuit board.
The arrangement of the conductive pattern according to the exemplary embodiment of the present specification is shown in FIG. 1. That is, the first
According to one embodiment of the present specification, an insulating layer may not be provided between the conductive bridge, the first conductive pattern, and the second conductive pattern. In addition, according to one embodiment of the present specification, an insulating layer may not be provided between the conductive bridge and the first conductive pattern.
That is, according to the exemplary embodiment of the present specification, the conductive bridge and the first conductive pattern may be spaced apart from each other without physically contacting each other. In addition, according to the exemplary embodiment of the present specification, the conductive bridge and the first conductive pattern may be spaced apart from each other and may not be electrically connected.
According to one embodiment of the present specification, an air layer may be included between the conductive bridge and the first conductive pattern. That is, the air layer may mean a layer containing only air without including a separate insulating layer.
Specifically, according to one embodiment of the present specification, the conductive bridge may be provided on the first conductive pattern and the second conductive pattern.
That is, according to the exemplary embodiment of the present specification, the conductive bridge is provided on the first conductive pattern and the second conductive pattern, and electrically connects the conductive pattern regions of the second conductive pattern to each other. It may be provided spaced apart from the first conductive layer.
Specifically, according to the exemplary embodiment of the present specification, the conductive bridge is provided on the first conductive pattern and the second conductive pattern, and electrically connects the second conductive layers of the second conductive pattern to each other. The first conductive layers of the pattern may be spaced apart from each other.
According to the exemplary embodiment of the present specification, the conductive bridge provided on the first conductive pattern may contact only at least one edge of the first groove portion disposed below the conductive bridge, and may not contact the first conductive layer. .
In contrast, according to one embodiment of the present specification, the conductive bridge provided on the second conductive pattern may contact two second conductive layers provided in the second groove to electrically connect two or more conductive pattern regions.
According to one embodiment of the present specification, the conductive pattern rows of the first conductive pattern may be arranged in the longitudinal direction, and the conductive pattern regions of the second conductive pattern connected by the conductive bridge may be arranged in the horizontal direction. The longitudinal direction and the lateral direction are expressions for indicating directions relative to each other, and when one direction is determined, the other direction may be determined with respect to the direction. This is because when the touch panel is rotated, the horizontal direction and the vertical direction are not absolute. For example, the longitudinal direction may mean left and right directions, may mean up and down directions, or may have a diagonal or other direction. The longitudinal direction and the transverse direction are not necessarily at right angles to each other, but may be at an angle that is acceptable in the art. For example, an angle formed between the longitudinal direction and the transverse direction may be 80 degrees to 100 degrees.
Specifically, the angle formed by the conductive pattern row of the first conductive pattern and the conductive pattern region of the second conductive pattern connected by the conductive bridge is not particularly limited as long as the touch panel can be driven, but may be 80 degrees to 100 degrees. It may be 90 degrees.
According to one embodiment of the present specification, the entire conductive pattern including the first conductive pattern and the second conductive pattern may be designed in a range in which the touch panel can be driven, and the conductive pattern may be formed on the substrate according to the designed pattern. Can be formed.
According to one embodiment of the present specification, the material of the substrate may be appropriately selected according to the field to which the conductive pattern is to be applied, and specific examples thereof include glass or inorganic material substrates, plastic substrates or films, or other flexible substrates. It is not limited to this. As the plastic substrate or the film, materials known in the art may be used, and for example, polyethylene terephthalate (PET), polyvinylbutyral (PVB), polyethylene naphthalate (PEN), polyethersulfon (PES), polycarbonate (PC), acetyl celluloid, The film of 80% or more of the same visible light transmittance can be used.
According to one embodiment of the present specification, the thickness of the plastic film may be 12.5 μm to 500 μm, and may be 50 μm to 250 μm. According to one embodiment of the present specification, the conductive pattern may be directly formed on the tempered glass, or may be attached to the tempered glass after being formed on the glass or the film.
According to one embodiment of the present specification, each of the first and second conductive patterns may be made by forming a resin pattern layer and then forming a conductive layer. At this time, the resin pattern layer may be formed by patterning a plurality of grooves using a resin patterning method known in the art, after forming the resin composition layer, the formation method is not particularly limited. In consideration of the simplicity of the process and the manufacturing cost, it is preferable to use an imprinting method.
According to one embodiment of the present specification, each of the first conductive pattern and the second conductive pattern may further include an adhesive layer provided on a surface including a groove of the resin pattern layer.
According to one embodiment of the present specification, the adhesive layer includes an optical clear adhesive (OCA).
According to an exemplary embodiment of the present specification, the adhesive layer is an optically clear adhesive (OCA).
According to one embodiment of the present specification, the conductive pattern may further include a cover layer provided in contact with an adhesive layer on a surface including the groove portion of the resin pattern layer, and the cover layer may be glass or plastic.
According to an exemplary embodiment of the present specification, the groove portion is a space for forming a conductive layer, and includes a stripe-shaped engraved structure including side and bottom surfaces.
According to one embodiment of the present specification, the resin pattern layer may include two or more groove portions, and preferably, a plurality of groove portions extending in one direction and a plurality of groove portions extending in another direction cross each other in a lattice shape. Can be formed. The plurality of grooves may be the same or different from each other. In the present specification, descriptions such as the first or second not used together and described only as grooves may be applied to both the first grooves and the second grooves.
According to one embodiment of the present specification, the shape of a cross section (hereinafter referred to as a vertical cross section) in which the groove part is cut in a direction perpendicular to the plane of the resin pattern layer is not particularly limited, and is rectangular, inverted trapezoidal, curved, or circular. At least one selected from the group consisting of ellipses, polygons, and combinations thereof.
As such, according to the exemplary embodiment of the present specification, the shape of the groove is not particularly limited, but when the width of the upper region of the groove is smaller than the width of the lower region, pattern formation is difficult, so that the width of the upper portion of the groove is It is preferable to form so that it may not become smaller than the width | variety of a lower part. That is, the width of the uppermost surface of the groove portion is preferably equal to the width of the lowermost portion or larger than the width of the lowermost surface.
According to one embodiment of the present specification, the groove portion may have a maximum depth H of 0.2 times to 2 times the maximum width of the groove portion, preferably 0.7 times to 1 times, but is not limited thereto. The maximum depth of the groove can for example be selected within the range of 50 to 2 micrometers.
In the present specification, the maximum width of the groove portion refers to the longest width of the groove portion measured in the horizontal direction with respect to the plane of the resin pattern layer, and the maximum depth of the groove portion is perpendicular to the plane of the resin pattern layer. It means the longest depth of the measured groove depths.
In an exemplary embodiment of the present specification, when the maximum depth H of the groove part satisfies the numerical range, the pattern is easily formed, and the conductive layer in the groove part is removed together in the process of removing the conductive layer in a region other than the groove part. The phenomenon can be prevented.
According to another exemplary embodiment, the groove may have a maximum width of 0.1 μm to 3 μm, but is not limited thereto.
According to the exemplary embodiment of the present specification, when the maximum width of the groove portion is 0.1 μm or more, when the line width of the conductive layer is too small, there is an effect of preventing a problem of reduced conductivity due to resistance, and the maximum width of the groove portion is 3 μm. In the case below, the metal wire is recognized due to the reflection of the conductive layer, thereby preventing the problem of deterioration of the appearance quality of the product.
According to the exemplary embodiment of the present specification, the groove portion has a maximum width of 0.1 μm to 3 μm, and the maximum depth H of the groove portion is 0.2 to 2 times the maximum width of the groove portion.
According to an exemplary embodiment of the present specification, the side surface of the groove portion has an inclination angle of 0 degrees to 15 degrees from the vertical line with respect to the vertical line with respect to the bottom surface of the groove portion, preferably, 0 degrees to 10 degrees, more preferably 1 It may have an inclination angle of 5 to 5 degrees, but is not particularly limited thereto. In the present specification, the groove portion has two side surfaces, wherein the two side surfaces have the same or different inclination angles. If the angle of inclination of the side surface is less than 0 degrees, the width of the lower surface of the groove portion becomes larger than the width of the upper surface, and as a result, the adhesion between the mold and the resin increases in the pattern forming process and the shape is distorted or the process speed decreases. If it exceeds 15 degrees, the amount of metal deposited on the side of the groove in the conductive layer deposition process increases, so that the conductive layer in the groove may be removed together when physically removing the conductive layer. Accordingly, the inclination angle of the groove side surface is not particularly limited.
According to the exemplary embodiment of the present specification, the radius of curvature of the upper edge of the side portion is 0.3 times or less of the maximum depth H of the first groove portion. If the radius of curvature of the upper edge exceeds 0.3 times the maximum depth H of the groove, the cracking of the conductive layer may be reduced when removing the conductive layer deposited other than the groove, and thus the removal speed and uniformity may be lowered. The radius of curvature of is not particularly limited.
According to one embodiment of the present specification, the groove portion may have a total surface area of 0.1% to 5% or less of the total cross-sectional area of the resin pattern layer, but is not particularly limited. When the total of the groove bottom surface area exceeds 5%, transparency may be inhibited by the conductive layer, and when the total of the groove bottom surface area is less than 0.1%, sufficient conductivity may not be secured.
According to one embodiment of the present specification, the average height of the conductive layer may be 5% to 60%, preferably 10% to 50% of the depth of the groove, for example, about 0.01 μm to 2 μm, specifically 50 To 300 nm, but is not particularly limited. The average height of the conductive layer means an average of the maximum height in the vertical direction of the conductive layer provided in the groove portion.
In this specification, descriptions such as the first or the second that are not used together and are described only as conductive layers may be applied to both the first conductive layer and the second conductive layer.
According to another exemplary embodiment, the line width of the conductive layer may be 0.1 μm to 3 μm, but is not limited thereto.
According to the exemplary embodiment of the present specification, when the line width of the conductive layer is 0.1 μm or more, the line width of the conductive layer is too small, thereby increasing the resistance and reducing the conductivity, and when the line width is 3 μm or less, Due to the reflection of the conductive layer, the metal wire is recognized, thereby preventing the problem that the appearance quality of the product is reduced.
According to one embodiment of the present specification, the conductive layer has two directions in a length direction and a width direction, and a line width of the conductive layer means a maximum line width in the width direction of the conductive layer provided in the groove portion.
According to the exemplary embodiment of the present specification, the line width of the first conductive layer may be 0.1 μm to 3 μm, and the line width of the second conductive layer may be 0.1 μm to 3 μm.
According to one embodiment of the present specification, the line width of the second conductive layer may be greater than or equal to the line width of the first conductive layer, and the line width of the second conductive layer may be larger than the line width of the first conductive layer. According to FIG. 2, the line width of the second conductive layer is greater than the line width of the first conductive layer. This allows the conductive material of the conductive bridge to be in contact with the second conductive layer but not in contact with the first conductive layer.
Specifically, according to one embodiment of the present specification, the line width of the first conductive layer may be preferably 0.1 μm or more and 1 μm or less, and the line width of the second conductive layer is 110% or more of the line width of the first conductive layer 3 may be up to μm.
The first and second grooves and the scale of the first and second conductive layers first set a desired sheet resistance value on the conductive substrate, and accordingly, the line width of the conductive layer and the design of the conductive pattern are set, and then the thickness of the conductive layer is set. The thickness of the groove may be determined by determining the line width and thickness of the groove according to the desired width and thickness of the conductive layer. One skilled in the art can set the scale of the groove and conductive layer in this manner.
Further, according to one embodiment of the present specification, the thickness of the second conductive layer may be greater than or equal to the thickness of the first conductive layer, and the thickness of the second conductive layer is greater than the thickness of the first conductive layer. It may be.
Further, according to one embodiment of the present specification, the line width of the second conductive layer may be greater than or equal to the line width of the first conductive layer, and the thickness of the second conductive layer is greater than or equal to the thickness of the first conductive layer. May be the same.
Further, according to one embodiment of the present specification, the line width of the second conductive layer may be greater than the line width of the first conductive layer, and the thickness of the second conductive layer may be greater than or equal to the thickness of the first conductive layer. have.
Further, according to one embodiment of the present specification, the line width of the second conductive layer may be greater than or equal to the line width of the first conductive layer, and the thickness of the second conductive layer may be greater than the thickness of the first conductive layer. have.
Further, according to one embodiment of the present specification, the line width of the second conductive layer may be larger than the line width of the first conductive layer, and the thickness of the second conductive layer may be larger than the thickness of the first conductive layer.
Further, according to one embodiment of the present specification, when the line width of the second conductive layer is the same as the line width of the first conductive layer, the thickness of the second conductive layer may be greater than the thickness of the first conductive layer.
That is, according to one embodiment of the present specification, even if the line width of the first conductive layer and the line width of the second conductive layer are the same, when the thickness of the second conductive layer is larger than the thickness of the first conductive layer, More surface of the resin pattern layer material may be coated on the first conductive layer upon surface treatment by the substrate soluble material. As a result, the conductive bridge may not be in contact with the first conductive layer but may only be in contact with the second conductive layer.
In the present specification, the thickness of the first conductive layer and the second conductive layer means the maximum depth in the vertical direction of the conductive layer provided on the bottom surface of the groove.
In addition, according to an exemplary embodiment of the present specification, the width of the first groove portion and the second groove portion may be 0.1 μm to 3 μm, but is not limited thereto.
According to the exemplary embodiment of the present specification, when the width of the first groove portion and the second groove portion is 0.1 μm or more, the width of the groove portion is too small, thereby increasing the resistance and decreasing the conductivity, and thus preventing the problem of the groove portion. If the width is 3μm or less, the metal wire is recognized due to the reflection of the conductive layer provided in the groove, thereby preventing the problem that the appearance quality of the product is reduced.
In the present specification, the width of the groove portion means the maximum width in the horizontal direction of the resin pattern layer.
According to one embodiment of the present specification, the width of the second groove portion may be greater than or equal to the width of the first groove portion, and the width of the second groove portion may be larger than the width of the first groove portion. 3 and 4 illustrate the second conductive pattern and the first conductive pattern, respectively, and the width of the
According to the exemplary embodiment of the present specification, the width of the first groove may be 0.1 μm to 3 μm, and the width of the second groove may be 110% or more and 3 μm or less of the width of the first groove.
In addition, according to one embodiment of the present specification, the depth of the first groove portion may be greater than or equal to the depth of the second groove portion, and the depth of the first groove portion may be greater than the depth of the second groove portion.
Further, according to one embodiment of the present specification, the width of the second groove portion may be greater than or equal to the width of the first groove portion, and the depth of the first groove portion may be greater than or equal to the depth of the second groove portion.
In addition, according to one embodiment of the present specification, the width of the second groove portion may be greater than the width of the first groove portion, and the depth of the first groove portion may be greater than or equal to the depth of the second groove portion.
Further, according to one embodiment of the present specification, the width of the second groove portion may be greater than or equal to the line width of the first groove portion, and the depth of the first groove portion may be greater than the depth of the second groove portion.
Further, according to one embodiment of the present specification, the width of the second groove portion may be greater than the width of the first groove portion, and the depth of the first groove portion may be greater than the depth of the second groove portion.
According to an exemplary embodiment of the present specification, when the width of the second groove portion is equal to the width of the first groove portion, the depth of the first groove portion may be greater than the depth of the second groove portion.
That is, according to one embodiment of the present specification, even if the width of the first groove portion and the width of the second groove portion are the same, when the depth of the first groove portion is larger than the depth of the second groove portion, the above-described substrate soluble substance is treated. By this, the resin pattern layer material constituting the first groove portion can coat more of the first conductive layer in the first groove portion. As a result, the conductive bridge may not be in contact with the first conductive layer provided in the first groove, but only in contact with the second conductive layer provided in the second groove.
According to an exemplary embodiment of the present specification, the opening ratio of the conductive pattern is 95% to 99.9%. That is, it is excellent in transparency. The aperture ratio refers to the ratio of the area of the area where the conductive layer is not formed in the surface area of the conductive pattern, {(the cross-sectional area of the transparent substrate surface minus the sum of the areas of the portions where the conductive layer is formed) / the cross-sectional area of the transparent substrate surface} x May be calculated as 100.
According to another exemplary embodiment, the sheet resistance of the conductive pattern may be 0.01 kPa / square to 100 kPa / square, and the transparency may be excellent when the above range is satisfied, but is not particularly limited thereto.
According to an exemplary embodiment of the present specification, the conductive layer includes a metal layer.
According to one embodiment of the present specification, as the material of the metal layer included in the conductive layer, it is preferable to use at least one of a metal, a metal alloy, a metal oxide, a metal nitride, a metal oxynitride, and the like having excellent electrical conductivity. The specific resistance value of the metal layer material is preferably 1 microOhm · cm or more and 100 microOhm · cm, more preferably 1 microOhm · cm or more and 5 microOhm · cm or less. Specific examples of the metal layer material include aluminum, copper, silver, gold, iron, molybdenum, nickel, carbon nanotubes (CNT), titanium, alloys thereof (Alloy), oxides thereof, nitrides thereof, One or more of these oxynitrides may be used, and aluminum is most preferred in terms of price and conductivity.
According to one embodiment of the present specification, an adhesive force control layer may be further included below the metal layer. The adhesion control layer is to separate the resin pattern layer and the conductive layer to prevent oxidation of the conductive layer by the resin and to facilitate the peeling by controlling the adhesion between the resin pattern layer and the conductive layer, for example, silicon oxide, It may consist of one or more selected from the group consisting of metal oxides, molybdenum, carbon, tin, chromium, nickel and cobalt.
The adhesive force control layer may have a thickness of 0.005 μm to 0.2 μm, preferably 0.005 μm to 0.1 μm, and more preferably 0.01 μm to 0.06 μm. If the thickness is less than 0.005㎛ may not be properly formed thin film, since the sufficient thin film characteristics can be obtained at 0.2㎛ or less, it is not necessary only to increase the process cost only.
The adhesion control layer may be performed by chemical vapor deposition or physical vapor deposition.
According to an exemplary embodiment of the present specification, the conductive layer may further include a blackening layer on at least one of the upper and lower portions of the metal layer. The blackening layer may include at least one selected from the group consisting of silicon oxide, metal oxide, molybdenum, carbon, tin, chromium, nickel and cobalt.
In addition, the blackening layer may have a thickness of 0.005 μm to 0.2 μm, preferably 0.005 μm to 1 μm, and more preferably 0.01 μm to 0.06 μm. If the thickness is less than 0.005㎛ may not be properly formed thin film, since the sufficient thin film characteristics can be obtained at 0.2㎛ or less, it is unnecessary only to increase the process cost.
The composition and thickness of the blackening layer can be variously adjusted according to the desired degree of blackening, and when the blackening layer is formed on both the top and the bottom of the conductive layer, the blackening layer of the upper and lower blackening layer is the composition and / Or the thickness may be the same or different. For example, when the upper blackening layer and the lower blackening layer forming material are different, the degree of blackening is different depending on the thickness, so that the thicknesses of the upper blackening layer and the lower blackening layer may be configured differently.
According to an exemplary embodiment of the present specification, the conductive layer and the conductive bridge may further include a planarization layer on top. The conductive layer is prevented from being oxidized by the planarization layer, the scratch resistance is improved, and light scattering due to the resin shape is reduced.
The planarization layer forming material may be the same as or different from the resin pattern layer forming material. In addition, the planarization layer is preferably formed of a material having a refractive index difference of 0.3 or less from the resin pattern layer forming material. When the difference in refractive index between the planarization layer and the resin pattern layer becomes large, light may be refracted, reflected, or scattered as light passes, resulting in haze, and as a result, transparency may decrease.
According to one embodiment of the present specification, the resin pattern layer is selected from the group consisting of resins known in the art, for example, active energy ray curable resins, thermosetting resins, conductive polymer resins, and combinations thereof. Include more than one species. More specifically, it may include, but is not limited to, urethane acrylate, epoxy acrylate, ester acrylate, polydimethylsiloxane, polyacetylene, polyparaphenylene, polyaniline, polypyrrole, and the like.
According to one embodiment of the present specification, the method of manufacturing the conductive pattern may include forming a resin pattern layer including at least one first groove portion and a second groove portion including side and bottom surfaces; Depositing a metal on the resin pattern layer to form a conductive layer; And physically removing the conductive layer present in the region except the groove portion of the resin pattern layer.
The physical method means removing a conductive layer through physical force, and is distinguished from a method of removing a conductive layer through a chemical reaction such as etching. More specifically, the step of physically removing the conductive layer may be performed by a scratching method, a detaching method or a combination thereof.
The scratching method refers to a method of scraping and removing the conductive layer, and the detaching method refers to a method of peeling the conductive layer from the resin pattern layer by applying tension from one end of the conductive layer. In the case of the scratching method, it may be used when the adhesion between the conductive layer and the resin pattern layer is high, and in the case of the detaching method, it may be used when the adhesion between the conductive layer and the resin pattern layer is low. In addition, by performing the scratching method and the detaching method together in one process, the conductive layer of the portion having a relatively high adhesive strength with the resin pattern layer may be removed by the scratching method, and the portion having a relatively low adhesive force may be removed by the detacking method. For example, by scraping a fabric with melamine foam or roughness from one corner of the opening to the other, scraping off the edge of the relatively high adhesion, the central portion of the opening of the relatively low adhesion occurs when the fabric is rubbed. Can be removed using a tension.
When the conductive layer is removed using the physical method as described above, the process is simple and environmentally friendly compared to the method of removing the conductive layer using a conventional chemical method. In the case of removing the conductive layer by a chemical method, the conductive layer of the groove part may be inserted by inserting a separate etching-resistant material on the conductive layer formed on the groove part to selectively remove the conductive layer in a region other than the groove part. Need to protect In this case, a etch resistant material insertion process may be added to affect the process cost and the yield of the product. In contrast, the present invention, which uses a physical method to remove the conductive layer, requires no further processing and is environmentally friendly since it does not use toxic chemicals such as etchant and etch resistant materials. In addition, when using the physical method as described above, since the conductive layer can be removed in a continuous process, there is an advantage that the productivity is improved, and the manufacturing time can be shortened.
The deposition height of the conductive layer can be adjusted by adjusting the traveling speed of the film. For example, when metal evaporation is performed at the same power, that is, when the amount of evaporation per unit time is constant, the deposition height can be adjusted by changing the film traveling speed. Increasing the advancing speed of the film reduces the exposure time to steam, thus increasing the deposition height.
According to the exemplary embodiment of the present specification, the forming of the conductive layer may further include forming an adhesion control layer on the resin pattern layer before the metal deposition, if necessary. Description and formation method for the adhesive force control layer is the same as described above.
According to one embodiment of the present specification, the forming of the conductive layer may further include forming a blackening layer before and / or after the metal deposition, if necessary. The description and forming method for the blackening layer are the same as described above.
According to one embodiment of the present specification, the forming of the resin pattern layer including the groove may be performed by at least one method selected from the group consisting of an imprinting method, a photolithography method, and an electron beam lithography method.
According to one embodiment of the present specification, physically removing the conductive layer may be performed by at least one method selected from the group consisting of a scratching method, a detaching method, and a combination thereof, and more preferably. Preferably, it may be carried out by rubbing off the conductive layer using a melamine foam or a rough door having a rough surface.
According to one embodiment of the present specification, the conductive bridge may connect a second conductive pattern including two or more conductive pattern regions that are not electrically connected.
That is, according to one embodiment of the present specification, the conductive bridge may be electrically conductive so as to electrically connect the second conductive patterns, and the material and shape thereof are not particularly limited.
According to one embodiment of the present specification, the thickness and area (width) of the conductive bridge may be appropriately selected depending on the end use.
According to one embodiment of the present specification, the shape, thickness, width, and the like of the conductive bridge are not particularly limited. Specifically, the conductive bridge according to the exemplary embodiment of the present specification may have various shapes such as polygons such as triangles and squares, spheres, and cylinders.
According to an exemplary embodiment of the present specification, the conductive bridge may include conductive particles.
Specifically, according to one embodiment of the present specification, the particle diameter of the conductive particles may be greater than the width of the first groove portion after the treatment with the above-described substrate soluble material and less than or equal to the width of the second groove portion.
According to an exemplary embodiment of the present specification, the particle diameter of the conductive particles may be greater than the width of the first groove portion after the treatment with the above-described substrate soluble material, and may be smaller than the width of the second groove portion.
According to one embodiment of the present specification, the particle diameter of the conductive particles may be 0.3 μm or more and 5 μm or less.
Specifically, according to one embodiment of the present specification, the conductive particles of the conductive bridge may be spherical. When the conductive particles of the conductive bridge are spherical, the particle diameter of the conductive particles may be greater than the width of the first groove portion after treatment with the above-described substrate soluble material and less than or equal to the width of the second groove portion.
That is, according to one embodiment of the present specification, since the particle diameter of the conductive particles included in the conductive bridge is larger than the width of the first groove portion after the treatment with the substrate soluble material described above, the grooves of the first conductive pattern may contain conductive particles. Cannot contact the first conductive layer. In addition, since the particle diameter of the conductive particles is less than or equal to the width of the second groove portion after the treatment with the substrate soluble material described above, the conductive particles enter the groove portion of the second conductive pattern and are in physical contact with the second conductive layer to form the conductive regions. Can be electrically connected.
According to one embodiment of the present specification, a protective layer may be further provided on a surface on which the first conductive pattern, the second conductive pattern, and the conductive bridge are provided. The protective layer may be an adhesive film including an adhesive layer, a glass or a hard coating layer including an adhesive layer.
According to the exemplary embodiment of the present specification, when the protective layer is an adhesive film or a glass including an adhesive layer, the difference between the refractive index of the adhesive layer and the refractive index of the conductive bridge may be 0.05 or less. When within the range of the refractive index difference, it is advantageous to improve the conductive pattern concealment and to achieve a uniform light transmittance.
In addition, an exemplary embodiment of the present specification provides a conductive substrate manufactured by the manufacturing method.
In addition, an exemplary embodiment of the present specification
materials;
A first conductive pattern including two or more conductive pattern rows including a first groove provided on the substrate and a first conductive layer provided in the first groove;
A second groove portion provided on the same surface as the surface on which the first conductive pattern is provided, and a second conductive layer provided in the second groove portion, and spaced apart from the first conductive pattern, A second conductive pattern including two or more conductive pattern regions provided with one or more conductive pattern rows of the first conductive pattern interposed therebetween; And
A conductive bridge electrically connecting conductive pattern regions of the second conductive pattern across at least one conductive pattern row of the first conductive pattern, the conductive bridge being spaced apart from the first conductive layer of the first conductive pattern,
At least one width of the first groove portion and the second groove portion provides a conductive substrate narrower than the width of the lower portion in the thickness direction. 4 illustrates a structure in which at least one width of the groove portion is narrower than the width of the lower portion in the thickness direction thereof.
According to the exemplary embodiment of the present specification, in the conductive substrate, at least one width of the first groove portion and the second groove portion is smaller than the width of the lower portion in the thickness direction thereof, and is greater than the width of the first groove portion. The width of the groove is larger. Such a structure can be formed by treatment with the above-described substrate soluble material. In addition, the above description may be equally applied to the conductive substrate.
In addition, an exemplary embodiment of the present specification provides a single-sided single-sheet touch panel including the conductive substrate. According to an example, the touch panel may further include a wiring part and a printed circuit board bonding part in addition to the first conductive pattern and the second conductive pattern. It can be driven by being connected to an external power source through the wiring portion and the printed circuit board bonding portion. Other configurations of the touch panel may employ those known in the art.
In addition, an exemplary embodiment of the present disclosure provides a display device including the conductive substrate. The conductive substrate may be included as an electrode or a touch panel of the display device.
As described above, according to the exemplary embodiment of the present invention, since the single-sided single-sided touch screen can be provided, the thickness of the touch screen can be minimized and the manufacturing method is easy because all the conductive patterns are formed on the cross-section. . In addition, since it is a single sheet, there is an advantage that the lamination is not required as compared with the prior art formed by using two or more substrates. Moreover, since it is a single sheet | seat type | mold, it is excellent in light transmittance compared with two sheets.
100: conductive bridge
101: first conductive pattern
102: second conductive pattern
200: second conductive layer
201: second groove
300: first conductive layer
301: first groove
400: first or second conductive layer
401: first or second groove portion
Claims (15)
A second groove portion and a second conductive layer provided in the second groove portion on the same surface as the surface on which the first conductive pattern is provided, provided spaced apart from the first conductive pattern, and Forming a second conductive pattern including two or more conductive pattern regions provided with one or more conductive pattern rows of the first conductive pattern interposed therebetween;
Treating the surface of the substrate provided with the first conductive pattern and the second conductive pattern with a substrate soluble material; And
Electrically connecting conductive pattern regions of the second conductive pattern across at least one conductive pattern row of the first conductive pattern, the conductive bridge being spaced apart from the first conductive layer of the first conductive pattern; Including,
The treating with the substrate soluble material may include a material of the resin pattern layer in which the substrate soluble material melts a resin forming the first conductive pattern and the second conductive pattern, and thus the entire surface of the first conductive pattern forms a conductive pattern. Coated, wherein a portion of the surface of the second conductive pattern is coated with the material of the resin pattern layer forming the conductive pattern,
The width of the second groove portion after the treatment with the base material soluble material is larger than the width of the first groove portion,
The conductive bridge comprises conductive particles,
The particle diameter of the said conductive particle is larger than the width | variety of the 1st groove part after the process by the said substrate soluble material, and is smaller than the width of the 2nd groove part.
A first conductive pattern including two or more conductive pattern rows including a first groove provided on the substrate and a first conductive layer provided in the first groove;
A second groove portion provided on the same surface as the surface on which the first conductive pattern is provided, and a second conductive layer provided in the second groove portion, and spaced apart from the first conductive pattern; A second conductive pattern including two or more conductive pattern regions provided with one or more conductive pattern rows of the first conductive pattern interposed therebetween; And
A conductive bridge electrically connecting conductive pattern regions of the second conductive pattern across at least one conductive pattern row of the first conductive pattern, the conductive bridge being spaced apart from the first conductive layer of the first conductive pattern,
At least one width of the first groove portion or the second groove portion is narrower than the width of the lower portion in the thickness direction,
The width of the second groove portion is larger than the width of the first groove portion,
The conductive bridge comprises conductive particles,
The particle size of the conductive particles is larger than the width of the first groove portion, less than the width of the second groove portion conductive substrate.
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