KR102034560B1 - Guss asphalt composition using modified asphalt - Google Patents

Guss asphalt composition using modified asphalt Download PDF

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KR102034560B1
KR102034560B1 KR1020190040806A KR20190040806A KR102034560B1 KR 102034560 B1 KR102034560 B1 KR 102034560B1 KR 1020190040806 A KR1020190040806 A KR 1020190040806A KR 20190040806 A KR20190040806 A KR 20190040806A KR 102034560 B1 KR102034560 B1 KR 102034560B1
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asphalt
weight
butyl
wax
goose
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KR1020190040806A
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Korean (ko)
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양재봉
이진호
박지용
차동화
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한국석유공업 주식회사
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/26Bituminous materials, e.g. tar, pitch
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/04Carboxylic acids; Salts, anhydrides or esters thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2623Polyvinylalcohols; Polyvinylacetates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2676Polystyrenes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/36Bituminous materials, e.g. tar, pitch
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction

Abstract

The present invention provides a guss asphalt composition using modified asphalt, which comprises: 56-95 wt% of straight asphalt; 1-10 wt% of an elastomer; 1-10 wt% of a thermoplastic resin; 1-10 wt% of petroleum PITCH; 1-10 wt% of amide wax; and 0.1-5 wt% of a thermal stabilizer. By not mixing natural asphalt, the present invention can maintain a uniform mixing ratio, reduce odor and smoke emission at high temperatures, and enable efficient process management, while enhancing characteristics such as road pavement durability, thermal stability, plastic deformation resistance, weather resistance, and wear resistance.

Description

개질 아스팔트를 이용한 구스 아스팔트 조성물{GUSS ASPHALT COMPOSITION USING MODIFIED ASPHALT}Goose asphalt composition using modified asphalt {GUSS ASPHALT COMPOSITION USING MODIFIED ASPHALT}

본 발명은 건설 재료에 관한 것으로서, 상세하게는 개질 아스팔트를 이용한 구스 아스팔트에 관한 것이다.The present invention relates to construction materials, and in particular, to goose asphalt using modified asphalt.

구스 아스팔트(guss asphalt)는 석회, 석분, 천연 아스팔트 분말을 주재료로 하는 특수 아스팔트 포장재를 말하며, 매스틱 아스팔트(mastic asphalt), 아스팔트 꿀레(asphalt coule) 등으로 불리운다.Goose asphalt (guss asphalt) refers to a special asphalt pavement mainly made of lime, stone powder, natural asphalt powder, and is called mastic asphalt, asphalt coules and the like.

이는 위 주재료가 적절한 비율로 배합된 혼합액, 골재, 모래, 석분 등을 고온(170~250℃)에서 혼합한 후 포설하는 방식으로 시공되는데, 구스 아스팔트 포장의 특징은 유동성, 불투수성, 충격 저항성과 내구성 그리고 휨에 대한 추종성(Compatibility)을 바탕으로 강상판의 교통하중에 대한 변형에 저항하도록 하고 있기 때문에, 골재의 맞물림을 하중 전달의 기본 개념으로 하고 있는 일반 아스팔트 혼합물 포장과는 상당히 다른 거동을 보인다.It is constructed by mixing and mixing mixed liquid, aggregate, sand, stone powder, etc. mixed in the appropriate ratio at high temperature (170 ~ 250 ℃), and the characteristics of goose asphalt pavement are fluidity, impermeability, impact resistance and durability. In addition, it is very different from the general asphalt mixture pavement, which uses aggregate engagement as the basic concept of load transfer, because it is resistant to deformation of the steel plate based on its compatibility with bending.

구스 아스팔트 혼합물의 불투수성으로 휨에 대한 적용성이 높기 때문에 일반적으로 강상판 포장 등의 교면포장에 많이 사용된다.Due to the impermeability of the goose asphalt mixture, its applicability to warpage is high, so it is generally used for cross-section paving such as steel plate pavement.

종래의 구스 아스팔트는 시공성의 개선이나 고온시의 내유동성을 위하여, 일반적으로 석유 아스팔트에 천연 아스팔트를 첨가하여 사용하며, 천연 아스팔트의 함량은 아스팔트 함량의 20~30% 정도이다.Conventional goose asphalt is generally used by adding natural asphalt to petroleum asphalt for improving workability or fluid resistance at high temperatures, and the content of natural asphalt is about 20 to 30% of the asphalt content.

천연 아스팔트는 아스팔트의 점도 증가, 내산화성의 향상, 응집체와의 밀착성 및 필링 저항의 개선, 고온 및 장기 조건에서도 접착력의 향상 등의 장점이 있다.Natural asphalt has advantages such as increasing the viscosity of the asphalt, improving the oxidation resistance, improving the adhesion to the aggregates and the peeling resistance, improved adhesion even at high temperature and long-term conditions.

그러나 함유된 미네랄의 함량이 일정하지 않아 구스 아스팔트 혼합물에 대한첨가 시 균일한 배합비율을 유지할 수 없다는 점, 200℃가 넘는 고온에서 구스 아스팔트 시공 시 발생되는 유증기에 의한 냄새 및 연기 배출이 심하다는 점, 구스 아스팔트 혼합물 쿠커에서 별도로 천연 아스팔트를 투입하는 공정이 추가되어야 한다는 점 등의 단점이 있다.However, since the content of minerals is not constant, it is not possible to maintain a uniform mixing ratio when adding to the goose asphalt mixture, and the odor and smoke emission due to the vapor generated during goose asphalt construction at a high temperature of more than 200 ° C are severe. However, there is a disadvantage in that a process of adding natural asphalt separately from the goose asphalt mixture cooker has to be added.

따라서 천연 아스팔트의 혼입 없이 구스 아스팔트를 제조하기 위한 연구가 진행되어 왔다.Therefore, research has been conducted to manufacture goose asphalt without incorporation of natural asphalt.

본 발명은 상기와 같은 문제점을 해결하기 위하여 도출된 것으로서, 천연 아스팔트를 혼입하지 않음에 따라, 균일한 배합비율을 유지할 수 있고, 고온에서의 냄새 및 연기 배출을 저하시킬 수 있으며, 효율적인 공정관리가 가능하면서도, 도로포장의 내구성, 열안정성, 소성변형 저항성, 내후성, 내마모성 등의 특성을 향상시킬 수 있도록 하는 개질 아스팔트를 이용한 구스 아스팔트를 제시하는 것을 그 목적으로 한다.The present invention has been derived to solve the above problems, by not mixing natural asphalt, it is possible to maintain a uniform mixing ratio, to reduce the emission of odors and smoke at high temperatures, and efficient process management It is an object of the present invention to provide a goose asphalt using modified asphalt which can improve the characteristics of road pavement durability, thermal stability, plastic deformation resistance, weather resistance, abrasion resistance and the like.

상기 과제의 해결을 위하여, 본 발명은 스트레이트 아스팔트 56-95 중량%; 탄성중합체 1-10 중량%; 열가소성 수지 1-10 중량%; 석유계 PITCH 1-10 중량%; 아미드 왁스 1-10 중량%; 열안정제 0.1-5 중량%; 를 포함하는 것을 특징으로 하는 개질 아스팔트를 이용한 구스 아스팔트 조성물을 제시한다.In order to solve the above problems, the present invention is 56-95% by weight of straight asphalt; 1-10% by weight elastomer; 1-10% by weight of thermoplastic resin; 1-10% by weight of petroleum PITCH; Amide wax 1-10% by weight; Heat stabilizer 0.1-5% by weight; It proposes a goose asphalt composition using a modified asphalt comprising a.

상기 탄성중합체는, 폴리스티렌 18-21 중량부, 산화방지제 0.5-1.0 중량부를 포함하는 스티렌 이소프렌 부타디엔 폴리스티렌(SIBS-Styrene, isoprene and butadiene with a polystyrene)인 것이 바람직하다.The elastomer is preferably styrene isoprene butadiene polystyrene (SIBS-Styrene, isoprene and butadiene with a polystyrene) containing 18-21 parts by weight of polystyrene and 0.5-1.0 parts by weight of antioxidant.

상기 열가소성 수지는 EBA(EnBA, Ethylene butylacrylate), 또는 EVA(Ethylene Vinylacetate)인 것이 바람직하다.The thermoplastic resin is preferably EBA (EnBA, Ethylene butylacrylate), or EVA (Ethylene Vinylacetate).

상기 석유계 PITCH는 Solvent De-Asphalting 공정에서 생산된 PITCH인 것이 바람직하다.The petroleum-based PITCH is preferably a PITCH produced in the Solvent De-Asphalting process.

상기 아미드 왁스는 에티렌-비스-스테아르아미드(EBS- Ethylene-bis-stearamide) 왁스와 올레 아미드(Oleamide) 왁스, 폴리올레핀(Polyolefine) 왁스, 스테아르아미드(Stearamide) 왁스, Erucamide wax 중 2 이상의 혼합물인 것이 바람직하다.The amide wax is a mixture of two or more of EBS-Ethylene-bis-stearamide wax, oleamide wax, polyolefine wax, stearamide wax, and Erucamide wax. desirable.

상기 열안정제는, 마그네슘 수산화 알루미늄 탄산염(Magnesium Aluminium Hydroxide Carbonate) 90-97 중량%; 포화 지방산(Saturated fatty acids) 3-10 중량%;를 포함하는 것이 바람직하다.The thermal stabilizer, Magnesium Aluminum Hydroxide Carbonate 90-97% by weight; It is preferably included; 3-10% by weight of saturated fatty acids.

상기 열안정제는, 페놀계 열안정제 에틸렌비스(옥시에틸렌)비스[3-(5-t-뷰틸-4-하이드록시-m-톨리)프로피오네이트] Ethylenebis(oxyethylene)bis[3-(5-t-butyl-4-hydroxy-m-toly)propionate], 테트라키스(에틸렌(3,5-다이-삼차뷰틸-4-하이드록시하이드로시남산))메탄 Tetrakis(methylene(3,5-di-tert-butyl-4-hydroxyhydrocinnamate) methane), 옥타데킬 3-(3,5-다이-터트-뷰틸-4-하이드록시페닐) 프로피온염 Octadecyl 3-(3,5-di-t-butyl-4-hydroxy phenyl) propionate 중 하나 또는 2 이상의 혼합물인 것이 바람직하다.The heat stabilizer is a phenolic heat stabilizer ethylene bis (oxyethylene) bis [3- (5-t-butyl-4-hydroxy-m-tolyl) propionate] Ethylenebis (oxyethylene) bis [3- (5- t-butyl-4-hydroxy-m-toly) propionate], tetrakis (ethylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamic acid)) methane Tetrakis (methylene (3,5-di-tert) -butyl-4-hydroxyhydrocinnamate) methane), octadecyl 3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate Octadecyl 3- (3,5-di-t-butyl-4-hydroxy phenyl) propionate, or a mixture of two or more thereof.

본 발명은 천연 아스팔트를 혼입하지 않음에 따라, 균일한 배합비율을 유지할 수 있고, 고온에서의 냄새 및 연기 배출을 저하시킬 수 있으며, 효율적인 공정관리가 가능하면서도, 도로포장의 내구성, 열안정성, 소성변형 저항성, 내후성, 내마모성 등의 특성을 향상시킬 수 있도록 하는 개질 아스팔트를 이용한 구스 아스팔트를 제시한다.The present invention is not mixed with natural asphalt, it is possible to maintain a uniform mixing ratio, to reduce the emission of odors and smoke at high temperatures, and to enable efficient process management, road durability, thermal stability, plasticity The present invention provides a goose asphalt using modified asphalt to improve the properties of deformation resistance, weather resistance, and abrasion resistance.

도 1은 열가소성 수지의 분자식.1 is a molecular formula of a thermoplastic resin.

이하, 첨부도면을 참조하여 본 발명의 실시예에 관하여 상세히 설명한다.Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

본 발명에 의한 구스 아스팔트는 기본적으로, 스트레이트 아스팔트 56-95 중량%; 탄성중합체 1-10 중량%; 열가소성 수지 1-10 중량%; 석유계 PITCH 1-10 중량%; 아미드 왁스 1-10 중량%; 열안정제 0.1-5 중량%;를 포함하여 구성된다.Goose asphalt according to the present invention is basically, 56-95% by weight of straight asphalt; 1-10% by weight elastomer; 1-10% by weight of thermoplastic resin; 1-10% by weight of petroleum PITCH; Amide wax 1-10% by weight; 0.1-5 wt% of a heat stabilizer.

탄성중합체는, 폴리스티렌 18-21 중량부, 산화방지제 0.5-1.0 중량부를 포함하는 스티렌 이소프렌 부타디엔 폴리스티렌(SIBS-Styrene, isoprene and butadiene with a polystyrene)을 적용하였다.As the elastomer, styrene isoprene butadiene polystyrene (SIBS-Styrene, isoprene and butadiene with a polystyrene) including 18-21 parts by weight of polystyrene and 0.5-1.0 parts by weight of an antioxidant was applied.

열가소성 수지는 EBA(EnBA, Ethylene butylacrylate), 또는 EVA(Ethylene Vinylacetate)를 적용한다(도 1).Thermoplastic resin is applied to EBA (EnBA, Ethylene butylacrylate), or EVA (Ethylene Vinylacetate) (Fig. 1).

이들은 Ethylene Acrylate Copolymer(C2)로서, 아세테이트기(CH3COO)에 의해 결정성이 감소되어 아스팔트와의 혼합이 원활하고, 에스테르기(COO)에 의해 극성이 증대되어 열가소성 고분자의 특성이 증대됨에 따라 아스팔트 조성물의 고강성과 내변형성을 증대시킴과 아울러, 유연성 및 내부 충격에 강한 특성을 부여한다.These are Ethylene Acrylate Copolymer (C2), the crystallinity is reduced by the acetate group (CH3COO) to facilitate mixing with the asphalt, the polarity is increased by the ester group (COO) to increase the properties of the thermoplastic polymer as the asphalt composition In addition to increasing the high rigidity and deformation resistance of the product, it also gives a strong property to flexibility and internal impact.

특히, EBA(EnBA) 개질제의 경우, 아스팔트의 물성의 연화점을 높여 영구변형에 대한 성능과 PI값이 개선되고, 저온균열 특성을 높여 우수한 유연성, 내충격성, 인장강도, 굴곡 강도를 갖도록 하며, 수분 보유 능력이 우수하여 신속한 습윤 및 높은 전단 안정 성능을 부여한다.In particular, in the case of EBA (EnBA) modifiers, the softening point of the asphalt physical properties is improved to improve the performance and PI value for permanent deformation, and to improve the low temperature cracking properties to have excellent flexibility, impact resistance, tensile strength, flexural strength, and moisture Excellent retention gives fast wetting and high shear stability.

석유계 PITCH는 천연아스팔트의 특성을 대체하기 위한 첨가제로서, VTB(Solvent De-Asphalting 공정을 통하여 나온 PITCH) 등을 적용할 수 있다.Petroleum-based PITCH is an additive for replacing the properties of natural asphalt, and may be applied to VTB (PITCH obtained through Solvent De-Asphalting).

VTB는 중질유분에 대한 경질화 공정(고도화 정제공정)에서 배출되는 경질화 부산물로서, 종래의 구스 아스팔트에 사용되는 천연아스팔트(TLA)를 대체하여, 도로포장에 요구되는 강성 및 소성변형에 대한 저항성을 증가시킬 수 있다.VTB is a hardening by-product discharged from the hardening process (advanced refining process) for heavy oil. It replaces the natural asphalt (TLA) used in the conventional goose asphalt, and is resistant to the stiffness and plastic deformation required for road paving. Can be increased.

아미드 왁스는 에티렌-비스-스테아르아미드(EBS- Ethylene-bis-stearamide) 왁스와 올레 아미드(Oleamide) 왁스, 폴리올레핀(Polyolefine) 왁스, 스테아르아미드(Stearamide) 왁스, Erucamide wax 중 2 이상의 혼합물을 적용한다.Amide wax applies a mixture of two or more of EBS-Ethylene-bis-stearamide wax and oleamide wax, polyolefine wax, stearamide wax and Erucamide wax. .

열안정제는, 마그네슘 수산화 알루미늄 탄산염(Magnesium Aluminium Hydroxide Carbonate) 90-97 중량%; 포화 지방산(Saturated fatty acids) 3-10 중량%;의 혼합물을 사용한다.Thermal stabilizers include, but are not limited to, 90-97% by weight of magnesium aluminum hydroxide carbonate; A mixture of saturated fatty acids 3-10% by weight is used.

또는 열안정제로서, 페놀계 열안정제 에틸렌비스(옥시에틸렌)비스[3-(5-t-뷰틸-4-하이드록시-m-톨리)프로피오네이트] Ethylenebis(oxyethylene)bis[3-(5-t-butyl-4-hydroxy-m-toly)propionate], 테트라키스(에틸렌(3,5-다이-삼차뷰틸-4-하이드록시하이드로시남산))메탄 Tetrakis(methylene(3,5-di-tert-butyl-4-hydroxyhydrocinnamate) methane), 옥타데킬 3-(3,5-다이-터트-뷰틸-4-하이드록시페닐) 프로피온염 Octadecyl 3-(3,5-di-t-butyl-4-hydroxy phenyl) propionate 중 하나 또는 2 이상의 혼합물을 사용할 수도 있다.Or as a heat stabilizer, a phenolic heat stabilizer ethylenebis (oxyethylene) bis [3- (5-t-butyl-4-hydroxy-m-tolyl) propionate] Ethylenebis (oxyethylene) bis [3- (5- t-butyl-4-hydroxy-m-toly) propionate], tetrakis (ethylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamic acid)) methane Tetrakis (methylene (3,5-di-tert) -butyl-4-hydroxyhydrocinnamate) methane), octadecyl 3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate Octadecyl 3- (3,5-di-t-butyl-4-hydroxy phenyl) propionate or mixtures of two or more.

이하, 본 발명에 의한 구스 아스팔트 조성물의 물성을 입증하기 위한 실험내용 및 결과에 관하여 설명한다.Hereinafter, the experimental content and results for demonstrating the physical properties of the goose asphalt composition according to the present invention will be described.

Figure 112019035715500-pat00001
Figure 112019035715500-pat00001

Figure 112019035715500-pat00002
Figure 112019035715500-pat00002

표 1은 본 발명의 5가지 실시예의 구체적인 배합비이고, 표 2는 위 실시예들의 물성을 실험한 결과이다.Table 1 is a specific compounding ratio of the five embodiments of the present invention, Table 2 is a result of the physical properties of the above examples.

표 2의 시험항목 및 기준은 국토교통부 아스팔트 혼합물 시공지침(2017)에 1명시되어 있는 구스 아스팔트의 품질기준이다.The test items and criteria in Table 2 are the quality standards of goose asphalt as specified in the Ministry of Land, Infrastructure and Transport asphalt mixture construction guide (2017).

표 2에 나타난 바와 같이, 본 발명에 의한 구스 아스팔트의 실시예들은 모두 천연 아스팔트를 혼입하지 않았으면서도, 어느 경우나 국토교통부가 정하는 구스 아스팔트의 품질기준을 만족함을 확인할 수 있다.As shown in Table 2, all of the embodiments of goose asphalt according to the present invention can be seen that satisfies the quality standards of goose asphalt determined by the Ministry of Land, Infrastructure, and Transport, in any case.

이상은 본 발명에 의해 구현될 수 있는 바람직한 실시예의 일부에 관하여 설명한 것에 불과하므로, 주지된 바와 같이 본 발명의 범위는 위의 실시예에 한정되어 해석되어서는 안 될 것이며, 위에서 설명된 본 발명의 기술적 사상과 그 근본을 함께 하는 기술적 사상은 모두 본 발명의 범위에 포함된다고 할 것이다.Since the above has been described only with respect to some of the preferred embodiments that can be implemented by the present invention, the scope of the present invention, as is well known, should not be construed as limited to the above embodiments, the present invention described above It will be said that both the technical idea and the technical idea which together with the base are included in the scope of the present invention.

Claims (7)

스트레이트 아스팔트 56-95 중량%;
탄성중합체 1-10 중량%;
열가소성 수지 1-10 중량%;
석유계 PITCH 1-10 중량%;
아미드 왁스 1-10 중량%;
열안정제 0.1-5 중량%;를 포함하고,
상기 열안정제는,
마그네슘 수산화 알루미늄 탄산염(Magnesium Aluminium Hydroxide Carbonate) 90-97 중량%;
포화 지방산(Saturated fatty acids) 3-10 중량%;를
포함하는 것을 특징으로 하는 개질 아스팔트를 이용한 구스 아스팔트 조성물.
Straight asphalt 56-95 wt%;
1-10% by weight elastomer;
1-10% by weight of thermoplastic resin;
1-10% by weight of petroleum PITCH;
Amide wax 1-10% by weight;
0.1-5 wt% of a heat stabilizer;
The heat stabilizer,
90-97 wt% Magnesium Aluminum Hydroxide Carbonate;
3-10% by weight of saturated fatty acids;
Goose asphalt composition using the modified asphalt comprising a.
제1항에 있어서,
상기 탄성중합체는,
폴리스티렌 18-21 중량부, 산화방지제 0.5-1.0 중량부를 포함하는 스티렌 이소프렌 부타디엔 폴리스티렌(SIBS-Styrene, isoprene and butadiene with a polystyrene)인 것을 특징으로 하는 개질 아스팔트를 이용한 구스 아스팔트 조성물.
The method of claim 1,
The elastomer,
Goose asphalt composition using modified asphalt, characterized in that the styrene isoprene butadiene polystyrene (SIBS-Styrene, isoprene and butadiene with a polystyrene) containing 18-21 parts by weight of polystyrene, 0.5-1.0 parts by weight of antioxidant.
제1항에 있어서,
상기 열가소성 수지는 EBA(EnBA, Ethylene butylacrylate), 또는 EVA(Ethylene Vinylacetate)인 것을 특징으로 하는 개질 아스팔트를 이용한 구스 아스팔트 조성물.
The method of claim 1,
The thermoplastic resin is goose asphalt composition using modified asphalt, characterized in that EBA (EnBA, Ethylene butylacrylate), or EVA (Ethylene Vinylacetate).
제1항에 있어서,
상기 석유계 PITCH는 Solvent De-Asphalting 공정에서 생산된 PITCH인 것을 특징으로 하는 개질 아스팔트를 이용한 구스 아스팔트 조성물.
The method of claim 1,
The petroleum-based PITCH is a goose asphalt composition using modified asphalt, characterized in that the PITCH produced in the Solvent De-Asphalting process.
제1항에 있어서,
상기 아미드 왁스는 에티렌-비스-스테아르아미드(EBS- Ethylene-bis-stearamide) 왁스와 올레 아미드(Oleamide) 왁스, 폴리올레핀(Polyolefine) 왁스, 스테아르아미드(Stearamide) 왁스, Erucamide wax 중 2 이상의 혼합물인 것을 특징으로 하는 개질 아스팔트를 이용한 구스 아스팔트 조성물.
The method of claim 1,
The amide wax is a mixture of two or more of ethylene-bis-stearamide wax, oleamide wax, polyolefine wax, stearamide wax, and erucamide wax. Goose asphalt composition using the modified asphalt characterized in that.
삭제delete 제1항에 있어서,
상기 열안정제는,
페놀계 열안정제 에틸렌비스(옥시에틸렌)비스[3-(5-t-뷰틸-4-하이드록시-m-톨리)프로피오네이트] Ethylenebis(oxyethylene)bis[3-(5-t-butyl-4-hydroxy-m-toly)propionate], 테트라키스(에틸렌(3,5-다이-삼차뷰틸-4-하이드록시하이드로시남산))메탄 Tetrakis(methylene(3,5-di-tert-butyl-4-hydroxyhydrocinnamate) methane), 옥타데킬 3-(3,5-다이-터트-뷰틸-4-하이드록시페닐) 프로피온염 Octadecyl 3-(3,5-di-t-butyl-4-hydroxy phenyl) propionate 중 하나 또는 2 이상의 혼합물인 것을 특징으로 하는 개질 아스팔트를 이용한 구스 아스팔트 조성물.
The method of claim 1,
The heat stabilizer,
Phenolic Thermal Stabilizer Ethylenebis (oxyethylene) bis [3- (5-t-butyl-4-hydroxy-m-tolyl) propionate] Ethylenebis (oxyethylene) bis [3- (5-t-butyl-4 -hydroxy-m-toly) propionate], tetrakis (ethylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamic acid)) methane Tetrakis (methylene (3,5-di-tert-butyl-4- hydroxyhydrocinnamate) methane), one of octadecyl 3- (3,5-di-tert-butyl-4-hydroxyphenyl) propion salt Octadecyl 3- (3,5-di-t-butyl-4-hydroxy phenyl) propionate Or a mixture of two or more goose asphalt composition using the modified asphalt.
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KR102222058B1 (en) 2020-09-15 2021-03-03 주식회사 삼송마그마 Sand mastic asphalt mixture and construction method thereof
KR20220089356A (en) * 2020-12-21 2022-06-28 한국석유공업 주식회사 Asphalt composition and construction method for bottom structure
KR102625465B1 (en) * 2023-10-16 2024-01-16 주식회사 페이브테크 Guss asphalt waterproof pavement structure and pavement method installed on top of concrete or steel deck

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KR20160122817A (en) * 2014-05-08 2016-10-24 아사히 가세이 가부시키가이샤 Asphalt composition
KR20170011980A (en) * 2015-07-22 2017-02-02 한국건설기술연구원 Low cost and Hi-performance Asphalt Binder Composition for Asphalt Pavement Using Residue produced during Solvent De-Asphalting Process, And Manufacturing Method thereof
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