KR102023658B1 - Apparatus for reducing nitrogen oxide in exhaust gas of engine and method for reducing nitrogen oxide by using the same - Google Patents

Abstract

Provided are an apparatus for reducing nitrogen oxides and a method for reducing exhaust gas, which can minimize the reduction of engine fuel consumption due to low energy consumption while effectively reducing nitrogen oxides from harmful exhaust gases of an engine. The apparatus for reducing nitrogen oxides of the engine exhaust gas includes: a nanopulse streamer processor for applying a high voltage nanopulse directly to the exhaust gas to generate a nanopulse streamer discharge; A high voltage nanopulse generator for generating a high voltage nanopulse having a width of 1 to 100ns by using a diode switch and providing the same to a nanopulse streamer processor; A selective catalytic reduction unit for performing a selective catalytic reduction reaction on the exhaust gas passing through the nanopulse streamer processor; And a reducing agent supply for providing a reducing agent to the selective catalytic reducing unit.

Description

Apparatus for reducing nitrogen oxide in exhaust gas of engine and method for reducing nitrogen oxide by using the same}

The present invention relates to a nitrogen oxide reduction device and a reduction method, and more particularly, to a device and a method for reducing the nitrogen oxide contained in the exhaust gas of the engine.

Diesel engines are attracting much attention worldwide because of their high torque and excellent fuel economy. In addition, assuming that the same amount of exhaust gas consumes less than the gasoline engine, the amount of harmful exhaust gas is less. However, due to the inherent characteristics of diesel fuel, organic materials emitted from diesel engines are becoming a bigger social issue than gasoline engines.

Hazardous substances mainly generated in diesel engines include carbon monoxide (CO), hydrocarbons (HC), particulate matter (PM), commonly known as soot, and nitrogen oxides (NOx). Among them, inhalation of carbon monoxide easily binds to hemoglobin and inhibits oxygen transport in the body, causing poisoning or death due to hypoxia of the tissue. Nitrogen oxides can cause photochemical reactions with hydrocarbons to cause smog and ozone. Nitrogen oxides, along with sulfur oxides, also cause acid rain, and particulate matter has recently been identified as a cause of lung cancer.

One of the most environmental issues among the harmful gases of these diesel engines is nitrogen oxides. Recently, Euro 6 (EURO 6) for the emission control of diesel vehicles has been implemented worldwide, and compared with the previous Euro 5 (EURO 5), the reduction of nitrogen oxide emissions from 0.18 g / km to 0.08 g / km is more than half. I'm asking. The diesel automobile industry is developing a number of treatments to reduce harmful emissions, especially nitrogen oxides, because it is prohibited to produce or import cars unless they pass Euro 6 standards.

In the related art, a selective catalytic reduction (SCR) device has been used to reduce nitrogen oxides for medium and large diesel vehicles. The SCR device operates on the principle of converting nitrogen oxides (NOx) into nitrogen (N ₂ ) and water vapor (H ₂ O) using a catalyst. The conventional SCR device is known to have a good treatment efficiency with respect to nitrogen dioxide (NO ₂ ) but a poor treatment efficiency with respect to nitrogen monoxide (NO). On the other hand, representative nitrogen oxides included in the exhaust gas of diesel engines include nitrogen monoxide (NO) and nitrogen dioxide (NO ₂ ), and the concentration of nitrogen monoxide (NO) is much higher than that of nitrogen dioxide (NO ₂ ). 90%). Therefore, the conventional SCR device does not process a large amount of nitrogen monoxide, there is a problem that the denitrification efficiency is substantially lowered. The problem is that the problem of nitrogen oxides in the exhaust gas is not only limited to diesel engines, but also to gas engines (CNG engines, LNG engines, etc.) using gas fuel.

The problem to be solved by the present invention is to provide an apparatus for reducing nitrogen oxides of exhaust gas which can minimize the reduction of engine fuel consumption due to low energy consumption while effectively reducing nitrogen oxides from harmful exhaust gas of the engine.

Another problem to be solved by the present invention is to provide a method for reducing nitrogen oxides of engine exhaust gas using such an abatement device.

Problems to be solved by the present invention are not limited to the above-mentioned problems, and other problems not mentioned will be clearly understood by those skilled in the art from the following description.

An apparatus for reducing nitrogen oxides in an exhaust gas of an engine by using a high voltage nanopulse according to an embodiment of the present invention for achieving the above object is, by applying a high voltage nanopulse directly to the exhaust gas nano pulse streamer discharge Nano pulse streamer processor for generating a; A high voltage nanopulse generator for generating the high voltage nanopulse having a width of 1 to 100ns using a diode switch and providing the same to the nanopulse streamer processor; A selective catalytic reduction unit for performing a selective catalytic reduction reaction on the exhaust gas passing through the nanopulse streamer processor; And a reducing agent supply unit for providing a reducing agent to the selective catalytic reducing unit.

The nanopulse streamer processor may decompose or synthesize O ₂ in the exhaust gas into O or O ₃ , and convert nitrogen monoxide in the exhaust gas into nitrogen dioxide.

The high voltage nanopulse generator may include a first charging unit configured to generate a charging voltage from a power source; An on-off switch connected to one end of the first charging unit and converting the charging voltage into a pulse signal while performing an on-off operation according to a high frequency signal; A pulse transformer for boosting the pulse signal to a high voltage; A pulse width compression unit for compressing a pulse width of the high voltage pulse signal boosted by the pulse transformer; A second charging unit configured to charge the compressed high voltage pulse signal; And a diode switch that operates as a diode when the second charging unit is charged and outputs high voltage nanopulses during a reverse recovery time when the second charging unit is discharged.

The on-off switch may include an IGBT circuit, and may further include a second pulse transformer for further boosting the high voltage pulse signal between the pulse width compression unit and the second charging unit.

The voltage of the high voltage nanopulse may be 5 to 200kV.

The high voltage nanopulse generator may control the magnitude of the applied voltage of the high voltage nanopulse according to the exhaust cycle of the exhaust gas.

The high voltage nanopulse generator may control an application period of the high voltage nanopulse according to the exhaust cycle of the exhaust gas.

The apparatus may further include a magnetic field applying unit configured to apply a magnetic field to the exhaust gas in the nanopulse streamer processor while generating the nanopulse streamer discharge.

According to an aspect of the present invention, there is provided a method for reducing nitrogen oxides of an engine exhaust gas, the method comprising: generating the high voltage nanopulse having a width of 1 to 100 ns using a diode switch; Applying the high voltage nanopulse directly to the exhaust gas to produce a nanopulse streamer discharge; Increasing the concentration of nitrogen dioxide in the nitrogen oxides in the exhaust gas using the nanopulse streamer discharge; Supplying a reducing agent to the exhaust gas; And performing a selective catalytic reduction reaction on the exhaust gas and the reducing agent.

Increasing the concentration of nitrogen dioxide may include: decomposing or synthesizing O ₂ in the exhaust gas into O or O ₃ ; And converting nitrogen monoxide in the exhaust gas into nitrogen dioxide.

The high voltage nanopulse voltage may be 5 to 200 kV.

The method may further include applying a magnetic field to the exhaust gas while generating the nanopulse streamer discharge.

The magnitude of the applied voltage of the high voltage nanopulse may vary according to the exhaust cycle of the exhaust gas.

The application period of the high voltage nanopulse may vary according to the exhaust cycle of the exhaust gas.

In the generating of the high voltage nanopulse, when the charging voltage is generated from a power source, the charging voltage is converted into a pulse signal by an on / off switch and then boosted to a high voltage by a pulse transformer to generate a high voltage pulse signal, and the high voltage pulse. By reducing the rise time of the signal, the pulse width of the high voltage pulse signal may be compressed, and the high voltage nanopulse may be output during the reverse recovery time by the diode switch when the compressed high voltage pulse signal is charged and then discharged.

Details of other embodiments are included in the detailed description and drawings.

As described above, the nitrogen oxide reduction apparatus and the reduction method of the engine exhaust gas according to the present invention have the following excellent effects.

First, the concentration of nitrogen dioxide in the exhaust gas can be increased by applying a high voltage nanopulse directly to the exhaust gas. That is, it is used for NO-NO ₂ conversion as soon as oxygen gas in exhaust gas is decomposed or synthesize | combined with O or O ₃ by high voltage nanopulse.

Second, since the high-voltage nanopulse is applied only in nanoseconds, the energy consumption is low, thereby minimizing the decrease in engine fuel efficiency.

Third, when the amount of the exhaust gas is actively corresponding to the exhaust cycle of the exhaust gas, the denitrification efficiency can be increased while minimizing the energy consumption by increasing the voltage size of the high voltage nanopulse and lowering the other.

Fourth, when the amount of the exhaust gas to actively respond to the exhaust cycle of the exhaust gas, the denitrification efficiency can be increased while minimizing the energy consumption by increasing the frequency of application of high voltage nanopulse, and lowering the other.

1 is a block diagram showing an apparatus for reducing nitrogen oxides in a diesel engine exhaust gas according to an embodiment of the present invention.
FIG. 2 is a circuit diagram schematically illustrating the configuration of the high voltage nanopulse generator of FIG. 1.
3 is a photograph showing the actual implementation of the high voltage nanopulse generator of FIG. 2.
4A and 4B are schematic views illustrating the nanopulse streamer processor of FIG. 1.
FIG. 5 is a graph schematically showing waveforms of high voltage nanopulses generated by the high voltage nanopulse generator of FIG. 1.
Figure 6 is a block diagram showing a device for reducing nitrogen oxides of the exhaust gas according to another embodiment of the present invention.
7 is a graph showing the amplitude of the high-voltage nanopulse changes according to the amount of exhaust gas in the nitrogen oxide reduction device according to another embodiment of the present invention.
8 is a graph showing the period of the high-voltage nanopulse changes according to the exhaust gas amount in the nitrogen oxide reduction device according to another embodiment of the present invention.

Advantages and features of the present invention and methods for achieving them will be apparent with reference to the embodiments described below in detail with the accompanying drawings. However, the present invention is not limited to the embodiments disclosed below, but will be implemented in various forms, and only the present embodiments are intended to complete the disclosure of the present invention, and the general knowledge in the art to which the present invention pertains. It is provided to fully convey the scope of the invention to those skilled in the art, and the present invention is defined only by the scope of the claims. Like reference numerals refer to like elements throughout.

The present invention can be applied to a diesel engine, a gas engine, and the like, which generate nitrogen oxides (NOx) as exhaust gas. Here, the diesel engine is a reciprocating internal combustion engine that operates according to ignition of light or heavy oil as fuel, and includes, for example, automobiles, trucks, buses, tractors, agricultural vehicles, heavy construction equipment, generators, and the like. In addition, the gas engine includes an engine that uses compressed natural gas (CNG), liquefied natural gas (Liquefied Natural Gas) and the like. For convenience of description, the case where the present invention is applied to a diesel engine will be described as an example.

Hereinafter, a nitrogen oxide reduction apparatus and a reduction method according to embodiments of the present invention will be described in detail with reference to the accompanying drawings.

1 is a block diagram showing an apparatus for reducing nitrogen oxides in a diesel engine exhaust gas according to an embodiment of the present invention. The apparatus for reducing nitrogen oxides 1 of the present invention includes a high voltage nanopulse generator 30, a nanopulse streamer processor 40, a reducing agent supply unit 20, and a selective catalytic reduction unit 50.

Exhaust gas including nitrogen oxides (NOx), oxygen (O ₂ ), water vapor (H ₂ O), etc. flows into the exhaust pipe 10 connected to the diesel engine. Nitrogen oxides are mostly composed of nitrogen monoxide (NO) and nitrogen dioxide (NO ₂ ), and in the exhaust gas, nitrogen monoxide is approximately 95% and nitrogen dioxide is approximately 5%.

The high voltage nanopulse generator 30 generates high voltage nanopulses and provides them to the nanopulse streamer processor 40. The nanopulse serves to convert nitrogen monoxide (NO) contained in the exhaust gas into nitrogen dioxide (NO ₂ ). In order to increase the conversion efficiency, the nanopulse is preferably generated at a high voltage. For example, the voltage of the nanopulse is preferably about 5 to 200 kV. When the voltage of the nanopulse is less than 5kV, the discharge by the nanopulse does not occur in the nanopulse streamer processor 40, and when the voltage is greater than 200kV, device stability may occur due to excessive voltage.

In addition, the width of the nanopulse is preferably 1ns to 1000ns, preferably 1ns to 100ns. If the width of the nanopulse (or the time the nanopulse is applied) is too small, sufficient pulse power for discharge is not produced. If the width of the nanopulse is too large, the pulse power is larger than the amount required for the discharge, causing unnecessary energy consumption, such as raising the ambient temperature in addition to the discharge, thereby lowering the fuel economy of the diesel engine. In addition, as the width of the nanopulse increases, the number of electrons due to the discharge increases, but the rising time of the nanopulse also increases, so the velocity (or energy) of the electron is lowered, and the overall reaction efficiency decreases.

Two factors are needed to effectively convert nitrogen monoxide (NO) to nitrogen dioxide (NO ₂ ) by discharge. First, the electrons generated from the discharge must have high energy (ie, high speed). Second, the number of these electrons should be very large. In the case of the present invention, since a high voltage nanopulse having a high voltage and a pulse width of nano units is discharged, electrons having high energy can be produced in large quantities. The high voltage nanopulse generator 30 of the present invention will be described later in detail.

The nanopulse streamer processor 40 generates a nano-pulse streamer discharge by applying a high voltage nanopulse directly to the exhaust gas contained in the chamber. In other words, when the high voltage nanopulse generator 30 supplies the high voltage nanopulse to the nanopulse streamer processor 40, a streamer discharge occurs near a strong electric field inside the chamber through an electron avalanche. These streamers contain electrons accelerated to high energy by strong electric fields, and these high energy electrons collide with surrounding neutral particles to decompose and form active species. For example, in the case of oxygen molecules, the high-molecular electrons are split into oxygen atoms, and the active species in such an atomic state can easily oxidize surrounding materials because of their high reactivity.

On the other hand, the treatment method using the active species can be divided into direct treatment (remote treatment) and remote treatment (remote treatment) according to the generation position and reaction position of the active species. Direct treatment refers to the manner in which the active species are produced in the same chamber as in the present invention and the target reaction is caused by the active species. Due to the relatively high density of active species, the target reaction rate is also high. On the other hand, the remote treatment method is a case where the target reaction occurs by the active species and the target species are separated, the target reaction can selectively participate only the desired among the active species, but the target reaction rate is low because the active species density is low There is a low problem. The nanopulse streamer processor 40 of the present invention follows a direct treatment method of active species, and generates a reactive species by directly applying high voltage nanopulse directly to the exhaust gas introduced into the chamber, thereby inducing a target reaction and a reaction rate. The efficiency can be improved. Specifically, the target reaction to the exhaust gas is divided into two as follows.

A. NOx Removal Reaction

N ₂ + e → N + N + e (1)

NO + N → N ₂ + O (2)

O ₂ + O → O ₃ (3)

N ₂ + e → e + N ₂ (A) (4)

N ₂ (A) + NO → N ₂ + N + O (5)

N ₂ (A) + N ₂ O → 2N ₂ + O (6)

NO ₂ + N → N ₂ + O ₂ (7)

Here, N ₂ (A) refers to a metastable state of N ₂ .

B. NO-NO ₂ Conversion Reaction

O ₂ + e → O + O + e (8)

NO + O → NO ₂ (9)

O ₂ + O → O ₃ (10)

NO + O ₃ → NO ₂ + O ₂ (11)

As shown in the above scheme, the nanopulse streamer processor 40 directly converts nitrogen oxides in the exhaust gas to nitrogen, but the main reaction is a NO-NO ₂ conversion reaction. According to the NO-NO ₂ conversion reaction, O ₂ in the exhaust gas is decomposed or synthesized into O or O ₃ and converts nitrogen monoxide (NO) in the exhaust gas to nitrogen dioxide (NO ₂ ). Given that the concentration of nitrogen dioxide (NO ₂ ) contained in the exhaust gas of the diesel engine is approximately 5% of the total nitrogen oxides (NOx), the nanopulse streamer processor 40 of the present invention is nitrogen dioxide contained in the exhaust gas. The concentration of (NO ₂ / NOx) can be increased to 30 to 60%.

As such, the nanopulse streamer processor 40 of the present invention serves to promote the subsequent selective catalytic reduction reaction by increasing the nitrogen dioxide (NO ₂ ) content in the exhaust gas. This is because the selective catalytic reduction reaction occurs better for nitrogen dioxide (NO ₂ ) than for nitrogen monoxide (NO). Therefore, the NO-NO ₂ conversion reaction and the subsequent selective catalytic reduction reaction are organically combined to obtain an effect of significantly reducing the nitrogen oxides in the exhaust gas as a whole.

Subsequently, the exhaust gas treated by the nanopulse streamer processor 40 flows into the selective catalytic reducer 50, at which time the reducing agent is also introduced from the reducing agent supply unit 20. The reducing agent supply unit 20 uses, for example, an aqueous solution of urea as a reducing agent. The urea is converted into ammonia (NH ₃ ) and carbon dioxide (CO ₂ ) by a hydrolysis reaction and then selectively catalytic reduction reaction. To participate.

The selective catalytic reduction unit 50 converts nitrogen oxides to nitrogen by the following selective catalytic reduction equation.

4NO + 4NH ₃ + O ₂ → 4N ₂ + 6H ₂ O (12)

2NO ₂ + 4NH ₃ + O ₂ → 3N ₂ + 6H ₂ O (13)

NO + NO ₂ + 2NH ₃ → 2N ₂ + 3H ₂ O (14)

According to recent research results, it is known that the reaction rate can be obtained more than 10 times when proceeding to the reaction formula (13) and the reaction formula (14) in terms of reaction kinetics. In the reaction schemes (13) and (14), since nitrogen dioxide (NO ₂ ) is used as the reactant, the nanopulse streamer processor 40 of the present invention is selectively selected by increasing the concentration of nitrogen dioxide (NO ₂ ) in the exhaust gas. The denitrification efficiency of the catalytic reduction unit 50 can be improved.

Hereinafter, the high voltage nanopulse generator 30 according to an embodiment of the present invention will be described in detail with reference to FIGS. 2 and 3. FIG. 2 is a circuit diagram schematically illustrating the configuration of the high voltage nanopulse generator of FIG. 1. 3 is a photograph showing the actual implementation of the high voltage nanopulse generator of FIG. 2.

The high voltage nanopulse generator 30 includes a power supply unit 31, a first charging unit 32, an on / off switch 33, a first pulse transformer 34, a pulse width compression unit 35, and a second pulse transformer 36. And a second charging unit 37 and a diode switch 38.

The first charging unit 32 charges power input from the power supply unit 31 and may be configured of at least one capacitor C1. The on-off switch 33 connected to one end of the first charging unit 32 performs an on-off operation according to a control signal (for example, a high frequency signal of several to several tens of kHz) while charging the charging voltage charged in the first charging unit 32. Convert to pulse signal. The on / off switch 33 controls the generation period of the high voltage nanopulse output by the high voltage nanopulse generator 30. The on-off switch 33 may be made of, for example, a high speed Insulated Gate Bipolar Transistor (IGBT) circuit.

The pulse signal generated by the first charging unit 32 and the on-off switch 33 is boosted to a high voltage by the first pulse transformer 34. For example, the first pulse transformer 34 may boost the pulse signal at a 1:10 ratio.

The pulse width compression unit 35 compresses the pulse width of the high voltage pulse signal boosted primarily from the first pulse transformer 34. The pulse width compression unit 35 compresses the pulse width by reducing the rise time of the first stepped-up high voltage pulse signal, and may include one or more capacitors C2 and one or more inductors L1. The compressed high voltage pulse signal is boosted second by the second pulse transformer 36. For example, the second pulse transformer 36 may boost the compressed high voltage pulse signal at a 1: 6 ratio. In some cases, the second pulse transformer 36 may be omitted.

The secondary boosted high voltage pulse signal is charged in the second charging unit 37 connected to the second pulse transformer 36, and the second charging unit 37 may be configured of one or more capacitors C3. The diode switch 38 connected to the other end of the second charging unit 37 operates as a diode when the second charging unit 37 is charged, and during the reverse recovery time when the second charging unit 37 is discharged. The high voltage nanopulse is output to a load, that is, the nanopulse streamer processor 40. The diode switch 38 second compresses the high voltage pulse signal by using the reverse recovery time of the diode. When the forward voltage is applied to the diode D, the current flows, but when the reverse voltage is applied, the diode is not immediately disconnected. A reverse current flows instantaneously along (D) and is interrupted within a short time, and a compressed high voltage nanopulse is applied to the load 40. When using a fast recovery diode having a short reverse recovery time, the pulse width of the output high voltage nanopulse can be compressed to 1 to 100ns.

Looking at the overall operation of the high voltage nanopulse generator 30, when a charging voltage is generated from the power supply 31, the charging voltage is converted into a pulse signal by the on-off switch 33 and then the high voltage by the first pulse transformer 34 Is stepped up to generate a high voltage pulse signal. Subsequently, the pulse width compression unit 35 reduces the rise time of the high voltage pulse signal to first compress the pulse width of the high voltage pulse signal, and then secondly boosts the voltage to the high voltage by the second pulse transformer 36. Subsequently, after the first compressed and first boosted high voltage pulse signal is charged in the second charging unit 37, the diode switch 38 outputs the high voltage nanopulse to the load 40 during the reverse recovery time. For example, when 100V power is applied to the high voltage nanopulse generator 30, when the voltage is boosted to 1:10 and 1: 6 over the second stage, the final output voltage of 6kV is obtained, and the pulse compression unit 35 and the diode switch ( The pulse width may be compressed through 38 to output a high voltage nanopulse having a pulse width of several tens of ns.

As described above, it is preferable to carry out the boosting for the second time. In general, as the boost ratio (M or N) increases in the pulse transformer, the number of coils increases, the component size increases, and the inductance of the coil also increases, so that the pulse signal tends not to be properly transmitted. Therefore, in a circuit that needs to boost the pulse signal by at least several tens to hundreds of times to implement the high voltage nanopulse as in the present embodiment, it is preferable to perform the boosting step two times. Furthermore, when two pulse transformers are used, the impedance of the entire circuit Matching is also easy.

In addition, it is preferable that the step-up rate M by the first pulse transformer 34 is greater than or equal to the step-up rate N by the second pulse transformer 36. That is, when the first pulse transformer 34 boosts to 1: M and the second pulse transformer 36 boosts to 1: N, M may be greater than or equal to N. The higher the boost ratio, the more difficult it is to implement the pulse signal in nano units due to the increased inductance of the coil. Therefore, in order to solve this problem, a circuit for compressing the pulse width (that is, the pulse width compression unit 35 and the diode switch 38 )) It is good to boost up as much as possible before. Therefore, it is preferable that the step-up rate M by the first pulse transformer 34 is greater than or equal to the step-up rate N by the second pulse transformer 36.

4A and 4B are schematic views illustrating the nanopulse streamer processor of FIG. 1. While the exhaust gas flows into the chamber through the inlet IN, a high voltage nanopulse is output through the output electrode 114 of the high voltage nanopulse generator 30 and a strong electric field is generated around the output electrode 114 to generate a streamer. Discharge occurs. As such, the nanopulse streamer processor 40 of the present invention directly induces NO-NO ₂ conversion by increasing the density of active species by applying high voltage nanopulse directly to the exhaust gas. Therefore, the concentration of nitrogen dioxide (NO ₂ / NO x) contained in the exhaust gas can be increased to 30 to 60%. As shown in FIGS. 4A and 4B, the chamber constituting the nanopulse streamer processor 40 may be formed of a cylindrical or hexahedron or the like, and the output electrode 114 passes through the chamber to the center where the exhaust gas flows. Can be arranged. As a variant of the invention, one or more of the chambers may be arranged in parallel to treat a large amount of exhaust gas at the same time.

FIG. 5 is a graph schematically showing waveforms of high voltage nanopulses generated by the high voltage nanopulse generator of FIG. 1. The voltage magnitude A of the high voltage nanopulse may be 5 to 200 kV, and the width t of the high voltage nanopulse may be 1 ns to 1000 ns, preferably 1 ns to 100 ns. The pulse width t of the high voltage nanopulse may be controlled by the pulse width compression unit 35 and the diode switch 38. The period T of the high voltage nanopulse may be actively controlled by the on / off switch 33 according to the emission and discharge period of the exhaust gas. In order to increase the energy transfer efficiency of the nanopulse, it is preferable that the rising time of the nanopulse is smaller than 1/3 of the application time t of the nanopulse.

Hereinafter, a method of reducing nitrogen oxides in a diesel engine exhaust gas according to an embodiment of the present invention will be described.

First, the exhaust gas discharged from the diesel engine through the exhaust pipe 10 flows into the nanopulse streamer processor 40. Between the diesel engine and the nanopulse streamer processor 40, various known after-treatment devices, for example, a diesel oxidation catalyst (DOC), a diesel particulate filter (DPF), and the like may be added.

Subsequently, the high voltage nanopulse generated from the high voltage nanopulse generator 30 is directly applied to the exhaust gas in the nanopulse streamer processor 40. Specifically, the high voltage nanopulse generates a nanopulse streamer discharge around the output electrode 114 to increase the concentration of active species. In this case, the high voltage nanopulse may have a voltage of 5 to 200 kV, and may have a pulse width of 1 ns to 1000 ns.

During the nanopulse streamer discharge, the nitrogen oxide removal reaction and the NO-NO ₂ conversion reaction occur simultaneously. In particular, the NO-NO ₂ conversion reaction decomposes or synthesizes O ₂ in the exhaust gas into O or O ₃ , and converts at least some of the NO in the exhaust gas into NO ₂ . Therefore, the concentration of nitrogen dioxide (NO ₂ ) in the nitrogen oxide contained in the exhaust gas is increased.

The exhaust gas treated by the nanopulse streamer processor 40 is introduced into the selective catalytic reducer 50 together with the reducing agent provided from the reducing agent supply unit 20. The selective catalytic reduction unit 50 converts the nitrogen oxides into nitrogen and water vapor by a selective catalytic reduction reaction.

Hereinafter, a nitrogen oxide reduction apparatus according to another embodiment of the present invention will be described with reference to FIG. 6. Figure 6 is a block diagram showing a device for reducing nitrogen oxides of the exhaust gas according to another embodiment of the present invention. For convenience of description, members having the same function as each member shown in the embodiment of FIG. 1 are denoted by the same reference numerals and description thereof will be omitted, and the following description will focus on differences.

In this embodiment, the magnetic field applying unit 45 is installed in the nanopulse streamer processor 40 to additionally apply a magnetic field when the nanopulse streamer discharge occurs. The streamer produced by the high voltage nanopulse generator 30 is circulated in the circumferential direction by the magnetic field, so that the streamer distribution in the reactor becomes more uniform. Therefore, the interaction area between the exhaust gas and the active species is widened, and thus the nitrogen oxide removal reaction and the NO-NO ₂ conversion reaction occur more easily.

Hereinafter, an apparatus for reducing nitrogen oxides according to still another embodiment of the present invention will be described with reference to FIGS. 7 and 8.

7 is a graph showing the amplitude of the high-voltage nanopulse changes according to the amount of exhaust gas in the nitrogen oxide reduction device according to another embodiment of the present invention. For example, diesel engines have four-stroke engines and two-stroke engines like gasoline engines. Thus, the amount of exhaust gas varies with each stroke or with revolution revolution per minute (rpm) of the engine. In general, the exhaust gas amount 200 is repeatedly raised and lowered at a constant period P. In this embodiment, the magnitude of the applied voltage of the nanopulse is changed according to the exhaust cycle of the exhaust gas. That is, if the exhaust gas amount 200 is low, the voltage applied to the nanopulse 210 is lowered. If the exhaust gas amount 200 is high, the voltage applied to the nanopulse 210 is increased, so that energy consumption is not affected. Maximum denitrification efficiency can be obtained with minimal.

8 is a graph showing the period of the high-voltage nanopulse changes according to the exhaust gas amount in the nitrogen oxide reduction device according to another embodiment of the present invention. Specifically, when the exhaust gas amount 200 is small, the application period of the nanopulse 310 is increased, and when the exhaust gas amount 200 is high, the application period of the nanopulse 310 is reduced, so that the energy consumption is not affected. Maximum denitrification efficiency can be obtained while minimizing

Although the present invention has been described with respect to the present invention to effectively reduce the nitrogen oxides from the harmful exhaust gas of the diesel engine through the above embodiments, the field of application of the present invention is not limited to the diesel engine. It can be applied to any field (eg thermal power plant, etc.) that can reduce nitrogen oxides throughout the industry.

Although embodiments of the present invention have been described above with reference to the accompanying drawings, those skilled in the art to which the present invention pertains may implement the present invention in other specific forms without changing the technical spirit or essential features thereof. I can understand that. Therefore, it should be understood that the embodiments described above are exemplary in all respects and not restrictive.

1, 2: nitrogen oxide reduction device
10: exhaust pipe
20: reducing agent supply unit
30: high voltage nanopulse generator
31: power supply
32: first charging unit
33: on-off switch
34: first pulse transformer
35: pulse width compression unit
36: second pulse transformer
37: second charging unit
38: diode switch
40: nanopulse streamer processor
45: magnetic field applicator
50: selective catalytic reduction machine
114: output electrode

Claims (12)

A device for reducing nitrogen oxides in the exhaust gas of an engine using high voltage nanopulse:
A nanopulse streamer processor for generating a nanopulse streamer discharge by directly applying a high voltage nanopulse to the exhaust gas;
A high voltage nanopulse generator for generating the high voltage nanopulse having a width of 1 to 100ns using a diode switch and providing the same to the nanopulse streamer processor;
A selective catalytic reduction unit for performing a selective catalytic reduction reaction on the exhaust gas passing through the nanopulse streamer processor; And
Reducing agent supply for providing a reducing agent to the selective catalytic reduction unit,
The high voltage nanopulse generator may include a first charging unit configured to generate a charging voltage from a power source; An on-off switch connected to one end of the first charging unit and converting the charging voltage into a pulse signal while performing an on-off operation according to a high frequency signal; A pulse transformer for boosting the pulse signal to a high voltage; A pulse width compression unit for compressing a pulse width of the high voltage pulse signal boosted by the pulse transformer; A second charging unit configured to charge the compressed high voltage pulse signal; And a diode switch that operates as a diode when the second charging unit is charged and outputs a high voltage nanopulse during a reverse recovery time when discharging the second charging unit. The engine exhaust gas of claim 1, wherein the nanopulse streamer processor decomposes or synthesizes O ₂ in the exhaust gas into O or O ₃ , and converts nitrogen monoxide in the exhaust gas into nitrogen dioxide. Nitrogen oxide reduction device. delete The engine of claim 1, wherein the on / off switch comprises an IGBT circuit, and further includes a second pulse transformer for further boosting the high voltage pulse signal between the pulse width compression unit and the second charging unit. Nitrogen oxide reduction device for exhaust gas. The apparatus for reducing nitrogen oxides of an engine exhaust gas according to claim 1, wherein the voltage of the high voltage nanopulse is 5 to 200 kV. The apparatus of claim 1, wherein the high voltage nanopulse generator controls a magnitude of an applied voltage of the high voltage nanopulse according to a discharge cycle of the exhaust gas. The apparatus of claim 1, wherein the high voltage nanopulse generator controls an application period of the high voltage nanopulse in accordance with an exhaust cycle of the exhaust gas. The apparatus of claim 1, further comprising a magnetic field applying unit configured to apply a magnetic field to the exhaust gas in the nanopulse streamer processor while generating the nanopulse streamer discharge. As a method of reducing nitrogen oxides in the exhaust gas of an engine using high voltage nanopulse:
Generating the high voltage nanopulse having a width of 1 to 100ns using a diode switch;
Applying the high voltage nanopulse directly to the exhaust gas to produce a nanopulse streamer discharge;
Increasing the concentration of nitrogen dioxide in the nitrogen oxides in the exhaust gas using the nanopulse streamer discharge;
Supplying a reducing agent to the exhaust gas; And
Including performing a selective catalytic reduction reaction on the exhaust gas and the reducing agent,
The high voltage nanopulse generator for generating the high voltage nanopulse includes: a first charging unit generating a charging voltage from a power source; An on-off switch connected to one end of the first charging unit and converting the charging voltage into a pulse signal while performing an on-off operation according to a high frequency signal; A pulse transformer for boosting the pulse signal to a high voltage; A pulse width compression unit for compressing a pulse width of the high voltage pulse signal boosted by the pulse transformer; A second charging unit configured to charge the compressed high voltage pulse signal; And a diode switch which operates as a diode when the second charging unit is charged, and outputs a high voltage nanopulse during a reverse recovery time when discharging the second charging unit. The method of claim 9, wherein increasing the concentration of nitrogen dioxide comprises: decomposing or synthesizing O ₂ in the exhaust gas into O or O ₃ ; And converting nitrogen monoxide in the exhaust gas into nitrogen dioxide. 10. The method of claim 9, wherein the high voltage nanopulse voltage is 5 to 200 kV. 10. The method of claim 9, further comprising applying a magnetic field to the exhaust gas while generating the nanopulse streamer discharge.

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