KR102018803B1 - Adhesive composition for touch screen panel, adhesive film and touch screen panel - Google Patents
Adhesive composition for touch screen panel, adhesive film and touch screen panel Download PDFInfo
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- KR102018803B1 KR102018803B1 KR1020140122865A KR20140122865A KR102018803B1 KR 102018803 B1 KR102018803 B1 KR 102018803B1 KR 1020140122865 A KR1020140122865 A KR 1020140122865A KR 20140122865 A KR20140122865 A KR 20140122865A KR 102018803 B1 KR102018803 B1 KR 102018803B1
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- meth
- acrylate
- touch screen
- adhesive composition
- pressure
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
- G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
Abstract
(Meth) acrylic acid ester monomer and a crosslinkable monomer comprising a photocurable acrylic copolymer resin, wherein the crosslinkable monomer is a (meth) acrylate having a substituent of C3-C10 hydroxyalkyl group, the photocurable acrylic copolymer resin Provided is a pressure-sensitive adhesive composition for a touch screen panel in which the sum of the content of the crosslinkable monomer in the total monomers is 10 to 25% by weight.
Description
It relates to an adhesive composition for a touch screen panel, an adhesive film and a touch screen panel.
In recent years, electronic devices such as PDAs, mobile communication terminals, or vehicle navigation systems are forming a large market. In such an electronic device, the technical aims pursued are mainly thinner, lighter, lower power consumption, higher resolution, and higher brightness.
On the other hand, in an electronic device provided with a touch screen or a touch panel switch in an input operation unit, a transparent conductive plastic film is used for light weight and prevention of cracking. Examples thereof include a film based on a polyethylene terephthalate (PET) film, and a conductive layer such as indium tin oxide (ITO) formed on one surface thereof, and the film is conductive by an adhesive layer. It is laminated | stacked on glass, a reinforcing material, or a decoration film.
The pressure-sensitive adhesive layer is required for various physical properties such as touch sensitivity and durability.
One embodiment of the present invention provides a pressure-sensitive adhesive composition for a touch screen panel that is excellent in sensitivity to touch and can suppress the problem of cloudiness.
Another embodiment of the present invention provides an adhesive film prepared from the adhesive composition for the touch screen panel.
Another embodiment of the present invention provides a touch screen panel to which an adhesive film prepared from the pressure-sensitive adhesive composition for the touch screen panel is applied.
In one embodiment of the present invention, a (meth) acrylic acid ester monomer and a photocurable acrylic copolymer resin of a crosslinkable monomer, wherein the crosslinkable monomer is a (meth) acrylate having a substituent of C3-C10 hydroxyalkyl group It provides a pressure-sensitive adhesive composition for a touch screen panel in which the sum of the content of the crosslinkable monomer in the total monomers constituting the photocurable acrylic copolymer resin is 10 to 25% by weight.
Specifically, the crosslinkable monomer may include hydroxypropyl (meth) acrylate, hydroxybutyl (meth) acrylate, or both.
The adhesive composition for the touch screen panel may have a hydroxyl value of 60 to 100 mg KOH / g.
The (meth) acrylic acid ester monomer may be alkyl (meth) acrylate, and the alkyl of the alkyl (meth) acrylate may be linear or branched C1-C30 alkyl.
In one embodiment, the alkyl of the alkyl (meth) acrylate may be linear or branched C6-C18 alkyl.
The (meth) acrylic acid ester monomer is methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl (meth) acrylate, n-butyl (meth) acrylate, t- Butyl (meth) acrylate, sec-butyl (meth) acrylate, pentyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, 2-ethylbutyl (meth) acrylate, n-octyl (meth) acrylic And isooctyl (meth) acrylate, isobonyl (meth) acrylate, isononyl (meth) acrylate, and combinations thereof.
The crosslinkable monomer may further include a nitrogen-containing monomer.
In another embodiment, the crosslinkable monomer does not comprise hydroxyethyl (meth) acrylate.
The pressure-sensitive adhesive composition for the touch screen panel may further include a photoinitiator.
The photoinitiator may include one selected from the group consisting of a benzoin initiator, a hydroxy ketone initiator, an amino ketone initiator caprolactam, and a combination thereof.
In another embodiment of the present invention, there is provided an adhesive film comprising an adhesive layer including a photocured product of the adhesive composition for a touch screen panel.
The dielectric constant k value measured at a frequency of 100 kHz of the adhesive film may be 3.0 or less.
In another embodiment of the present invention, a conductive plastic film layer having a conductive layer formed on one surface; The adhesive film laminated on the conductive layer; It provides a touch screen panel comprising a; cover window layer laminated on the adhesive film.
The conductive plastic film may be a polyethylene terephthalate film having a conductive metal oxide layer formed on one surface thereof.
The cover window may be a transparent glass replacement plastic film or tempered glass.
The pressure-sensitive adhesive film prepared from the pressure-sensitive adhesive composition for a touch screen panel has excellent sensitivity to touch while suppressing cloudiness.
1 is a schematic cross-sectional view of a touch screen panel according to an embodiment of the present invention.
Hereinafter, embodiments of the present invention will be described in detail. However, this is presented as an example, by which the present invention is not limited and the present invention is defined only by the scope of the claims to be described later.
A photocurable acrylic copolymer resin of the (meth) acrylic acid ester monomer and the crosslinkable monomer of the present invention, wherein the crosslinkable monomer is a (meth) acrylate having a substituent of a C3-C10 hydroxyalkyl group, and the photocurable acrylic system Provided is a pressure-sensitive adhesive composition for a touch screen panel in which the sum of the content of the crosslinkable monomer in the total monomers constituting the copolymer resin is about 10 to about 25% by weight.
When manufacturing a touch screen panel of a display device such as a mobile or tablet PC, an adhesive film used as a bonding medium for bonding a conductive plastic film layer having a conductive layer formed on one surface and a cover window layer may be manufactured from the pressure-sensitive adhesive composition for the touch screen panel. Can be.
The pressure-sensitive adhesive composition for a touch screen panel is formed into an adhesive film by photocuring the photocurable acrylic copolymer resin, and the pressure-sensitive adhesive film is optically transparent to be applied to a touch screen panel, and has a low dielectric constant. As such, the adhesive film having a low dielectric constant is useful for applying to a touch screen panel due to increased sensitivity to touch. In addition, the pressure-sensitive adhesive film can implement a low dielectric constant at the same time while the occurrence of cloudiness is suppressed.
The (meth) acrylic acid ester monomer may be, for example, alkyl (meth) acrylate, but is not limited thereto. Alkyl of the alkyl (meth) acrylate may be linear or branched C1-C30 alkyl, specifically C6-C18 alkyl. The dielectric constant of the pressure-sensitive adhesive film prepared from the pressure-sensitive adhesive composition for a touch screen panel using an alkyl (meth) acrylate having a relatively long alkyl chain in the carbon number range can be effectively lowered.
Specifically, the (meth) acrylic acid ester monomer is methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl (meth) acrylate, n-butyl (meth) acryl Late, t-butyl (meth) acrylate, sec-butyl (meth) acrylate, pentyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, 2-ethylbutyl (meth) acrylate, n-octyl It may include one selected from the group consisting of (meth) acrylate, isooctyl (meth) acrylate, isobornyl (meth) acrylate, isononyl (meth) acrylate and combinations thereof.
The crosslinkable monomer means a monomer further comprising a functional functional group as well as a copolymerizable functional group (eg, carbon-carbon double bond) in a molecular structure.
The content of the crosslinkable monomer may be adjusted to include a hydroxyl group in an appropriate content ratio in the pressure-sensitive adhesive composition. For example, when the carbon number of the hydroxyalkyl group in the crosslinkable monomer is increased, the content ratio of the hydroxy group in the pressure-sensitive adhesive composition is relatively low, thereby increasing the content of the crosslinkable monomer.
In one embodiment, the photocurable acrylic copolymer resin may be a polymerized monomer component consisting of 100 parts by weight of the (meth) acrylic acid ester monomer and about 10 to about 25 parts by weight of the crosslinkable monomer, in another embodiment, The chemical conversion acrylic copolymer resin may be obtained by polymerizing a monomer component including 100 parts by weight of the (meth) acrylic acid ester monomer and about 10 to about 15 parts by weight of the crosslinkable monomer.
The crosslinkable monomer may be, for example, hydroxypropyl (meth) acrylate or hydroxybutyl (meth) acrylate, or may include a combination thereof.
The pressure-sensitive adhesive composition may suppress the turbidity of the pressure-sensitive adhesive film prepared from the composition by lowering the relative content of the hydroxy group in the composition by using a crosslinking monomer having a high electronegativity and polar hydroxyalkyl groups in an appropriate amount. In addition, the dielectric constant can be lowered by copolymerizing a (meth) acrylic acid ester monomer substituted with an alkyl group having a high carbon number together.
In the pressure-sensitive adhesive composition, the total amount of the crosslinkable monomer in the total monomers constituting the photocurable acrylic copolymer resin is prepared to include about 10 wt% to about 25 wt%, thereby realizing excellent touch sensitivity while maximizing cloudiness. It can be suppressed.
The crosslinkable monomer may further include 2-isocyanatoethyl (meth) acrylate, 3-isocyanatopropyl (meth) acrylate, 4-isocyanatobutyl (meth) acrylate, and (meth) acrylic. It may further comprise nitrogen-containing monomers such as amides, N-vinyl pyrrolidone, N-vinyl caprolactam and the like.
The pressure-sensitive adhesive composition for a touch screen panel may contain a photocurable acrylic copolymer resin in which the crosslinkable monomer is copolymerized, thereby reducing cloudiness while reducing the content of hydroxyl groups in the whole composition. For example, the pressure-sensitive adhesive composition for the touch screen panel may have a hydroxyl value of about 60 to about 100 mg KOH / g.
As such, the pressure-sensitive adhesive composition for the touch screen panel may be manufactured to have a low dielectric constant. Specifically, the dielectric constant k value measured at a frequency of 100 kHz may be 3.0 or less. The pressure-sensitive adhesive film prepared from the pressure-sensitive adhesive composition for touch screen panels having a dielectric constant in the above range is excellent in touch sensitivity.
As described above, the pressure-sensitive adhesive composition for the touch screen panel may suppress cloudiness while lowering the relative dielectric constant (for example, may be evaluated by a hydroxyl value) in the composition of the hydroxyl group.
In one embodiment, the crosslinkable monomer is composed of a monomer selected from the group consisting of hydroxypropyl (meth) acrylate, hydroxybutyl (meth) acrylate, and combinations thereof, and hydroxyethyl (meth) acrylate do not include.
The pressure-sensitive adhesive composition for a touch screen panel may further include a photoinitiator to control the degree of polymerization as a photocurable composition. The photoinitiator may be used in an amount of about 0.01 to about 10 parts by weight based on 100 parts by weight of the photocurable acrylic copolymer resin, and the type of the photoinitiator may be used to generate a radical by light irradiation to initiate a polymerization reaction. It is not limited, and may include, for example, one selected from the group consisting of a benzoin initiator, a hydroxy ketone initiator, an amino ketone initiator caprolactam, and a combination thereof.
In addition, the pressure-sensitive adhesive composition for a touch screen panel is composed of an epoxy resin, a crosslinking agent, an ultraviolet stabilizer, an antioxidant, a colorant, a reinforcing agent, a filler, an antifoaming agent, a surfactant, a plasticizer, and a combination thereof. It may further comprise one or more additives selected from the group.
In another embodiment of the present invention, it provides an adhesive film comprising a pressure-sensitive adhesive layer containing a photocurable of the pressure-sensitive adhesive composition for the touch screen panel.
The pressure-sensitive adhesive composition for a touch screen panel may be coated on a substrate layer, and then photocured by light irradiation to prepare an adhesive film. "Light irradiation" refers to the irradiation of electromagnetic waves that can affect the photoinitiator or polymerizable compound to cause a polymerization reaction, wherein the electromagnetic waves are microwaves, infrared rays, ultraviolet rays, X-rays and γ-rays, as well as α-particle beams, Particle beams such as a proton beam, a neutron beam, and an electron beam are used generically.
The method of manufacturing the pressure-sensitive adhesive film by photocuring the pressure-sensitive adhesive composition for touch screen panels is not particularly limited. For example, the pressure-sensitive adhesive film can be produced by applying the above-described composition for a touch screen panel or a coating solution prepared by adding a solvent thereto to a suitable process substrate by a known means such as a bar coater and curing. .
The curing process is carried out after sufficiently removing the bubble-inducing components such as volatile components or reaction residues contained in the pressure-sensitive adhesive composition or the coating solution, to appropriately give the crosslinking density or molecular weight, elastic modulus, etc. of the cured product, The bubbles present in the adhesive interface may be increased to prevent a problem of forming scatterers therein.
In addition, the method of curing the pressure-sensitive adhesive composition for a touch screen panel or a coating liquid thereof is not particularly limited, and for example, ultraviolet rays are irradiated to the coating layer formed by the pressure-sensitive adhesive composition for a touch panel or the coating liquid thereof, or aged under predetermined conditions ( The curing process may be performed through a aging process.
The photocuring can be carried out, for example, by UV irradiation.
UV irradiation performed for the photocuring may be performed for about 10 seconds to about 15 seconds with a metal halide lamp that is commonly used.
The amount of light irradiated with UV is preferably about 0.5 J / cm 2 to about 2.0 J / cm 2 , and more preferably about 1.0 J / cm 2 to about 1.5 J / cm 2 .
The adhesive film 12 may have a thickness of about 50 μm to about 300 μm, specifically about 100 μm to about 200 μm. By allowing the adhesive film to have a thickness in the above range, it can be applied to a thin touch panel or a touch screen, but can implement an adhesive film having excellent durability.
In another embodiment of the present invention, a conductive plastic film layer having a conductive layer formed on one surface; The adhesive film laminated on the conductive layer; And it provides a touch screen panel comprising a cover window layer laminated on the adhesive film.
The cover window layer may use a transparent glass replacement plastic film developed as a material capable of replacing tempered glass or tempered glass. In the case of the glass replacement plastic film may be formed by imparting various functionalities to each layer in a multilayer structure.
1 is a schematic cross-sectional view of the
In FIG. 1, the
The pressure-
A specific kind of the conductive plastic film 130 is not particularly limited, and a conductive film known in the art may be used. For example, the conductive film 130 may be a transparent plastic film having an ITO electrode layer formed as a conductive layer 132 on one surface thereof. Specifically, as the transparent plastic film forming the
Hereinafter, examples and comparative examples of the present invention are described. Such following examples are only examples of the present invention, and the present invention is not limited to the following examples.
( Example )
Example One
85 parts by weight of ethylhexyl acrylate and 15 parts by weight of hydroxypropyl acrylate as a crosslinkable monomer were placed in a 1 liter glass reactor and thermally polymerized to obtain a photocurable acrylic copolymer resin syrup having a viscosity of 35 cP. The calculated hydroxyl value of the photocurable acrylic copolymer resin syrup is 62 mg KOH / g. 0.5 weight part of a, a-methoxy-a-hydroxyacetophenone (Igacure 651, Ciba) as a photoinitiator, and 1,6-hexanedioldi as a crosslinking agent with respect to 100 weight part (solid content basis) of the obtained photocurable acrylic copolymer resin. 0.35 parts by weight of acrylate (HDDA) was mixed and then sufficiently stirred to prepare a pressure-sensitive adhesive composition. Subsequently, the pressure-sensitive adhesive composition was formed into a film with a thickness of 100 μm and photocured to prepare an adhesive film as a cured film.
Example 2
An adhesive film was prepared in the same manner as in Example 1 except that 80 parts by weight of ethylhexyl acrylate and 20 parts by weight of hydroxypropyl acrylate as a crosslinkable monomer were used to prepare a photocurable acrylic copolymer resin. The hydroxyl value of the photocurable acrylic copolymer resin prepared above is 83 mg KOH / g.
Comparative example One
An adhesive film was prepared in the same manner as in Example 1 except that 85 parts by weight of ethylhexyl acrylate and 15 parts by weight of hydroxyethyl acrylate were used as a crosslinkable monomer to prepare a photocurable acrylic copolymer resin. The hydroxyl value of the photocurable acrylic copolymer resin prepared above is 72 mg KOH / g.
Comparative example 2
An adhesive film was prepared in the same manner as in Example 1 except that 80 parts by weight of ethylhexyl acrylate and 20 parts by weight of hydroxyethyl acrylate were used as a crosslinkable monomer to prepare a photocurable acrylic copolymer resin. The hydroxyl value of the photocurable acrylic copolymer resin prepared above is 96 mg KOH / g.
evaluation
Experimental Example 1: permittivity evaluation
The dielectric constant k was measured after contacting electrodes on both sides of the pressure-sensitive adhesive films prepared in Examples 1-2 and Comparative Examples 1-2 according to the following apparatus and the following conditions.
Instrument: Agilent Technologies E4980A LCR meter
Test Frequencies: 20 Hz-2 MHz
Electrode diameter: 5 mm
Experimental Example 2: White cloud Status assessment
After the laminated structure of glass / adhesive film / glass was prepared using the adhesive films prepared in Examples 1-2 and Comparative Example 1-2, it was left to stand in a thermo-hygrostat (85 ° C./85%RH) for 3 days and then visually Checking whether cloudy or not, the evaluation results are shown in Table 1 below.
(@ 100 kHz)
As can be seen in Table 1, even in the adhesive film of Comparative Example 1-2, it can be confirmed that the cloudy turbidity does not occur using an appropriate amount of the OH-containing crosslinkable monomer as in Example 1-2, crosslinkable monomer The hydroxyalkyl group had a low carbon number and a high dielectric constant. On the other hand, the adhesive films of Example 1-2 all exhibit a low dielectric constant while suppressing the clouding phenomenon.
Although the preferred embodiments of the present invention have been described in detail above, the scope of the present invention is not limited thereto, and various modifications and improvements of those skilled in the art using the basic concepts of the present invention defined in the following claims are also provided. It belongs to the scope of the invention.
100: touch screen panel
110: adhesive film
130: conductive plastic film
131: plastic base layer
132: conductive layer
150: cover window layer
160: transparent substrate
170: liquid crystal display (LCD)
Claims (15)
The pressure-sensitive adhesive composition has a hydroxyl value of 60 to 100 mg KOH / g,
The dielectric constant k value of the pressure-sensitive adhesive film including the pressure-sensitive adhesive layer containing the photocurable product of the pressure-sensitive adhesive composition is 3.0 or less when measured at a frequency of 100 kHz.
Adhesive composition for touch screen panels.
The crosslinkable monomer comprises hydroxypropyl (meth) acrylate, hydroxybutyl (meth) acrylate or both
Adhesive composition for touch screen panels.
The (meth) acrylic acid ester monomer is an alkyl (meth) acrylate, and the alkyl of the alkyl (meth) acrylate is a linear or branched C1-C30 alkyl.
Adhesive composition for touch screen panels.
Alkyl of the alkyl (meth) acrylate is linear or branched C6-C18 alkyl
Adhesive composition for touch screen panels.
The (meth) acrylic acid ester monomer is methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl (meth) acrylate, n-butyl (meth) acrylate, t- Butyl (meth) acrylate, sec-butyl (meth) acrylate, pentyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, 2-ethylbutyl (meth) acrylate, n-octyl (meth) acrylic Containing one selected from the group consisting of latex, isooctyl (meth) acrylate, isobonyl (meth) acrylate, isononyl (meth) acrylate, and combinations thereof
Adhesive composition for touch screen panels.
The crosslinkable monomer further comprises a nitrogen-containing monomer
Adhesive composition for touch screen panels.
The crosslinkable monomer does not contain hydroxyethyl (meth) acrylate.
Adhesive composition for touch screen panels.
Further comprising a photoinitiator
Adhesive composition for touch screen panels.
The photoinitiator comprises one selected from the group consisting of a benzoin-based initiator, a hydroxy ketone-based initiator, an amino ketone-based initiator caprolactam, and combinations thereof
Adhesive composition for touch screen panels.
An adhesive film according to claim 11 laminated on the conductive layer; And
Cover window layer laminated on the adhesive film
Touch screen panel comprising a.
The conductive plastic film is a polyethylene terephthalate film formed on one surface of a conductive metal oxide layer
Touch screen panel.
The cover window is a transparent glass replacement plastic film or tempered glass
Touch screen panel.
Priority Applications (3)
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KR1020140122865A KR102018803B1 (en) | 2014-09-16 | 2014-09-16 | Adhesive composition for touch screen panel, adhesive film and touch screen panel |
TW104130577A TW201612268A (en) | 2014-09-16 | 2015-09-16 | Adhesive composition for touch screen panel, adhesive film and touch screen panel |
PCT/KR2015/009719 WO2016043518A1 (en) | 2014-09-16 | 2015-09-16 | Adhesive composition for touch screen panel, adhesive film and touch screen panel |
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KR1020140122865A KR102018803B1 (en) | 2014-09-16 | 2014-09-16 | Adhesive composition for touch screen panel, adhesive film and touch screen panel |
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KR102018803B1 true KR102018803B1 (en) | 2019-09-06 |
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KR102044249B1 (en) * | 2016-04-15 | 2019-11-14 | 주식회사 엘지화학 | Multi layered optical adhesive sheet, method preparing multi layered optical adhesive sheet and touch screen panel |
KR102446328B1 (en) * | 2016-09-21 | 2022-09-21 | 동우 화인켐 주식회사 | Adhesive Composition and Adhesive Sheet Using the Same |
KR102455052B1 (en) * | 2020-12-22 | 2022-10-13 | 계명대학교 산학협력단 | Composite materials of Emulsion Polymerization Adhesive for Double-side Tape of OLED Panel and manufacturing method thereof |
TWI765531B (en) * | 2021-01-14 | 2022-05-21 | 大陸商宸美(廈門)光電有限公司 | Touch module |
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WO2012070796A2 (en) * | 2010-11-24 | 2012-05-31 | (주)엘지하우시스 | Adhesive composition for touch panel, adhesive film, and touch panel |
JP2013256559A (en) | 2012-06-11 | 2013-12-26 | Soken Chem & Eng Co Ltd | Method for producing adhesive sheet and method for producing laminate for touch panel |
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TWI447191B (en) * | 2008-07-01 | 2014-08-01 | Lg Chemical Ltd | Pressure-sensitive adhesive composition, polarizer and liquid crystal display |
JP6296674B2 (en) * | 2009-06-18 | 2018-03-20 | 日東電工株式会社 | Optical adhesive sheet |
KR101327584B1 (en) * | 2009-07-03 | 2013-11-12 | (주)엘지하우시스 | Resin composition for touchscreen, pressure-sensitive adhesive film and touchscreen |
JP5725760B2 (en) * | 2010-08-19 | 2015-05-27 | 大同化成工業株式会社 | Acrylic polymer compounds used in pressure-sensitive adhesive compositions for touch panels |
EP2722736B1 (en) * | 2011-07-19 | 2018-07-11 | LG Chem, Ltd. | Touch panel |
KR101393986B1 (en) * | 2011-10-12 | 2014-05-13 | (주)엘지하우시스 | Adhesive film for rework process of touch screen panel |
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- 2014-09-16 KR KR1020140122865A patent/KR102018803B1/en active IP Right Grant
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WO2012070796A2 (en) * | 2010-11-24 | 2012-05-31 | (주)엘지하우시스 | Adhesive composition for touch panel, adhesive film, and touch panel |
JP2013256559A (en) | 2012-06-11 | 2013-12-26 | Soken Chem & Eng Co Ltd | Method for producing adhesive sheet and method for producing laminate for touch panel |
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