KR101946418B1 - Recycled thermoplastic polyolefin multilayer root barrier sheet and root-proofing method using that - Google Patents

Abstract

The present invention relates to a recycled thermoplastic polyolefin multilayer root barrier sheet, and more specifically, to a root barrier sheet in a multilayer structure and a root barrier construction method using the same, wherein a center material is arranged between upper and lower sheets containing recycled thermoplastic polyolefin. By using recycled thermoplastic polyolefin with excellent tensile strength, weather resistance, and UV stability, eco-friendliness is guaranteed through utilizing a recycled resource, and physical performance of the root barrier sheet such as tensile strength and tear resistance is enhanced. Moreover, in the recycled thermoplastic polyolefin multilayer root barrier sheet according to the present invention, a multilayer structure is adopted such that the center material is arranged between the upper and lower sheets containing recycled thermoplastic polyolefin, thereby improving surface hardness and root barrier performance.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a recyclable thermoplastic polyolefin multi-

The present invention relates to a regenerated thermoplastic polyolefin multi-layered carrousel sheet, and more particularly, to a multi-layered carousel sheet having a center material disposed between upper and lower sheets containing a regenerated thermoplastic polyolefin, To a multi-layered carrousel sheet excellent in anticorrosion performance and a method of anticorrosion using the same.

Recently, we are promoting projects for low-carbon green growth in all industries with the aim of improving and preserving the global environment and improving the quality of human life. The construction sector is also made of concrete as part of introducing new schemes and technologies to pursue the green environment. We are actively introducing projects to improve the environment of urban and complex space by planting plants on artificial ground. These green spaces on the artificial grounds can provide resting places for people in the city to relax in, as well as provide an ecological environment in which insects can grow and plants can grow in the city.

Since the artificial ground greening is different from the natural planting environment, it has a function of draining the water supplied to the soil so that the plant can grow and a function of preventing the root of the plant from penetrating the ground, Waterproofing and anti-rusting functions are required.

In addition, the blind spot is in contact with plants, so it should not contain any harmful components to the plant, and it is required that components that adversely affect the environment or plant growth due to continuous contact with water are not eluted.

However, conventional wake-up boards are only being used for greening or landscaping applications on building rooftops because of the complexity of the installation process, low economic efficiency, and inferior mobility performance.

Examples of such a translucent sheet include sheets using a polyethylene terephthalate (PET) film. The PET film has excellent tensile strength, tear strength, tear strength, abrasion resistance and heat resistance, but has poor cold resistance, . As another example, the polyvinyl chloride (PVC) resin used as the main material of the antiseptic sheet is thermoplastic and excellent in workability, but there is a risk of emitting environmentally harmful substances such as organic volatile compounds and a high price.

Registration No. 10-0872187 (registered on November 28, 2008) Registration No. 10-1130828 (registered on March 20, 2012)

The present invention relates to a regenerated thermoplastic polyolefin multi-layered carrousel sheet comprising upper and lower sheets containing a regenerated thermoplastic polyolefin and a center material disposed between the upper and lower sheets, wherein the regenerated thermoplastic polyolefin is used to ensure environmental friendliness The present invention provides a regenerated thermoplastic polyolefin multi-layered carpet sheet exhibiting excellent physical performance and anticorrosion performance, and a route construction method using the same.

In order to achieve the above-mentioned object, an embodiment of the present invention includes an upper sheet 130, a center member 120 disposed below the upper sheet 130, Wherein the upper sheet 130 and the lower sheet 110 each comprise 51 to 72.5 weight percent of recycled thermoplastic polyolefin, 4.5 to 15.5 weight percent of synthetic rubber, To 11 wt%, process oil 5 to 14.5 wt%, inorganic additive 11 to 27.5 wt%, and aging inhibitor 0.9 to 4.5 wt%, based on the total weight of the recycled thermoplastic polyolefin multi-

The regenerated thermoplastic polyolefin is preferably a polyolefin recycled from a reactor thermoplastic polyolefin (R-TPO) used as an automobile interior material.

The center material 120 may include polypropylene or polyester and the synthetic rubber may be selected from the group consisting of EPDM (Ethylene Propylene Diene Monomer), SBS (Styrene Butadiene Styrene) and SEBS (Styrene Ethylene Butadiene Styrene) And may include at least any one or more of them.

The adhesive resin preferably includes at least one selected from the group consisting of Rosin, Coumarone Resin, Phenol-Terpene Resin and Petroleum Hydrocarbon Resin Do.

The inorganic additive may include at least one selected from the group consisting of calcium carbonate (CaCO ₃ ), talc, clay, and barium sulfate (BaSO ₄ ).

It is preferable that the process oil includes at least one selected from the group consisting of aromatic oil, naphthene oil and paraffin oil.

According to another embodiment of the present invention, there is provided a method of manufacturing a waterproofing sheet, comprising the steps of arranging a base surface, forming a primer layer by applying a primer to the surface of the base layer, attaching a waterproof sheet to the top of the primer layer, A step of adhering a regenerated thermoplastic polyolefin multi-layered carrousel sheet and a step of superimposing a joining portion of the attached multi-layered carnesthetic sheet on top of each other and hot-air fusing to bond the joints between neighboring regenerated thermoplastic polyolefin multi- The nearsheet includes an upper sheet (130); A center member 120 disposed below the upper sheet 130; And a lower sheet 110 disposed below the center member 120. The upper sheet 130 and the lower sheet 110 each comprise 51 to 72.5 weight percent of a thermoplastic polyolefin, Layered carpet sheet comprising 4.5 to 15.5 wt% of synthetic rubber, 4.5 to 11 wt% of adhesive resin, 5 to 14.5 wt% of process oil, 11 to 27.5 wt% of inorganic additive, and 0.9 to 4.5 wt% of antioxidant, It is the method of construction of the used carpet.

The step of adhering the regenerated thermoplastic polyolefin multi-layer carpet sheet may be a step of gluing the waterproof sheet and the regenerated thermoplastic polyolefin multi-layer carpet sheet using a circular patch having an adhesive applied on both sides thereof.

The present invention relates to a recycled thermoplastic polyolefin multi-layered carpet sheet using a recycled thermoplastic polyolefin having excellent tensile strength, weather resistance and UV stability. It can secure eco-friendliness through utilization of circulating resources and can improve physical properties such as tensile strength and tear performance have.

In addition, the multi-layered viscoelastic sheet of the present invention can improve the surface hardness and the antifogging performance by applying the multi-layer structure in which the center material is disposed between the upper and lower sheets including the regenerated thermoplastic polyolefin.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 schematically shows a regenerated thermoplastic polyolefin multi-layer carpet sheet according to the present invention. Fig.
Fig. 2 is a photograph showing an experiment on the performance of a navigation sheet according to Example 1 of the present invention. Fig.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The preferred embodiments of the present invention will now be described in detail with reference to the accompanying drawings. Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. As well as the fact that

Throughout this specification, when a member is located "above " another member, this includes not only when a member is in contact with another member, but also when another member is present between the two members.

Throughout this specification, when an element is referred to as "including" an element, it is understood that it may include other elements as well, without departing from the other elements unless specifically stated otherwise.

Hereinafter, the regenerated thermoplastic polyolefin multi-layered carrousel sheet of the present invention and a carpet construction method using the same will be described in detail with reference to the drawings.

1, the regenerated thermoplastic polyolefin multi-layered carrousel sheet 1 of the present invention comprises an upper sheet 130, a center material 120 disposed below the upper sheet 130, Wherein the upper sheet 130 and the lower sheet 110 each comprise 51 to 72.5 weight percent of recycled thermoplastic polyolefin and 4.5 to 15.5 weight percent of synthetic rubber % Of the adhesive resin, 4.5 to 11 wt% of the adhesive resin, 5 to 14.5 wt% of the process oil, 11 to 27.5 wt% of the inorganic additive, and 0.9 to 4.5 wt% of the antioxidant.

The regenerated thermoplastic polyolefin multi-layered breathing sheet of the present invention is a multi-layered breathable sheet comprising a top sheet 130 and a bottom sheet 110 containing a regenerated thermoplastic polyolefin as a main component and a center material 120 therebetween, and a regenerated thermoplastic polyolefin Can be improved not only by improving the physical properties of the antifogging sheet due to its excellent surface hardness, UV stability, weather resistance, etc., but also by improving the surface hardness and antifogging performance by applying the regenerated thermoplastic polyolefin sheet in two layers.

The recycled thermoplastic polyolefin multi-layered polyester sheet of the present invention uses recycled thermoplastic polyolefin to ensure environmental friendliness through utilization of circulating resources. The regenerated thermoplastic polyolefin is preferably a polyolefin recycled from a reactor thermoplastic polyolefin (R-TPO) used as an automobile interior material.

The R-TPO (Reactor thermoplastic polyolefin) is a thermoplastic polyolefin prepared by a polymerization reaction using a metallocene catalyst in a reactor. The R-TPO is a thermoplastic polyolefin produced by compounding C-TPO (Compound thermoplastic polyolefin ). The thermoplastic polyolefin (TPO) is composed of polypropylene and EPR (Ethylene Propylene Rubber). Depending on the production method, it can be classified into C-TPO (compound thermoplastic polyolefin) and R-TPO (Reactor thermoplastic polyolefin).

In the case of C-TPO (Compound thermoplastic polyolefin), it is a mixture made by simple physical bonding, and the distribution of polypropylene and EPR (Ethylene Propylene Rubber) is irregular because it is not well dispersed during production. As a result, the compound thermoplastic polyolefin (C-TPO) has lower basic properties and weatherability such as tensile strength and tearing property than R-TPO (Reactor thermoplastic polyolefin).

On the other hand, the distribution of polypropylene and EPR (Ethylene Propylene Rubber) is regular since R-TPO (Reactor thermoplastic polyolefin) is produced through polymerization reaction using metallocene catalyst in the reactor. Accordingly, R-TPO has excellent physical properties and little change in physical properties even after regeneration. Due to these excellent physical properties, R-TPO (Reactor thermoplastic polyolefin) is used as an automobile interior material. Particularly, in the case of R-TPO (Reactor thermoplastic polyolefin) used as an automobile interior material, since the contact time with outside air is small, the recyclable thermoplastic polyolefin of the present invention is excellent in weatherability, and R-TPO Reactor thermoplastic polyolefin) as a raw material.

In addition, the regenerated thermoplastic polyolefin is preferably contained in the upper sheet 130 and the lower sheet 110 in an amount of 51 to 72.5% by weight. When the content of the regenerated thermoplastic polyolefin is out of the above range, the properties of the regenerated thermoplastic polyolefin polypropylene sheet such as tensile strength and tear performance are deteriorated.

SBS (Styrene Butadiene Styrene), SIS (Styrene Isoprene Styrene), and SEBS (Styrene Ethylene Butadiene Styrene) are used to impart durability to the stretch ratio, low temperature elasticity and temperature of the antifogging sheet on the basis of rubber tensile properties. And styrene butadiene rubber (SBR), and may be included in the upper sheet 130 and the lower sheet 110 in an amount of 4.5 to 14.5% by weight. If the content of the synthetic rubber is out of the above range, the viscosity is decreased due to the exceeding of the content.

The adhesive resin is used for preventing peeling between materials and for enhancing adhesion between the layers and between the layers and preferably between rosin, coumarone resin, phenol-terpene resin, And petroleum resin (Petroleum Hydrocarbon Resin). More preferably, C-9 petroleum resin and / or C-5 petroleum resin may be used. Such an adhesive resin may be included in the upper sheet 130 and the lower sheet 110 in an amount of 4.5 to 11 wt%. If the amount of the adhesive resin is less than 4.5 wt%, it is difficult to expect the desired physical properties of the product. The flexibility is lowered, the price of the product is increased, and the economical efficiency is lowered.

The process oil is included for imparting waterproof performance and fluidity, and may include at least one or more selected from the group consisting of aromatic oil, naphthenic oil and paraffin oil. Such process oil is preferably contained in the upper sheet 130 and the lower sheet 110 in an amount of 5 to 14.5% by weight.

The inorganic additive is included for improving the hardness and flow stability of the material and preferably includes calcium carbonate (CaCO3), talc, bentonite, mica, clay, lime, cement, Barium sulfate (BaSO4) and the like can be used. Such an inorganic additive may be contained in the upper sheet 130 and the lower sheet 110 in an amount of 11 to 27.5 wt%. When the content of the inorganic additive is out of the above range, the cost saving effect and the strength increase effect are insignificant, Can not be produced.

The antioxidant is included in the regenerated thermoplastic polyolefin multi-layered carrot sheet of the present invention to prevent aging and extend the life of the recycled thermoplastic polyolefin multi-layered carrot sheet. The antioxidant may be selected from the group consisting of Phenyl-α-naphthylamine (PA), Substituted Diphenylamine (DCD), Trimethyl- dihydroquinoline dibutyl dithiocarbamate (SP), styrenated phenol (SP), and tri (nonylated phenyl) phosphate (TNP) may be used, and preferably 0.9 to 4.5 wt% of the upper sheet 130 and the lower sheet 110 may be included. When the antioxidant is less than 0.9 wt%, the regenerated thermoplastic polyolefin multi-layered carpet sheet is aged rapidly, and the price of the regenerated thermoplastic polyolefin multi-layered carpet sheet is increased by more than 4.5 wt% and the economical efficiency is lowered.

The center member 120 disposed between the upper sheet 130 and the lower sheet 110 is excellent in heat resistance, weather resistance, oil resistance, and air permeability and includes fine fibers, so that the upper sheet 130 in the recycled thermoplastic polyolefin multi- Not only the bonding force between the lower sheet 110 and the lower sheet 110 can be improved, but also the tensile force can be improved. The core material 120 is formed at the center of the regenerated thermoplastic polyolefin multi-layer carpet sheet of the present invention, and may include a fiber reinforcement. Preferably, polypropylene or polyester can be selected and used.

Another embodiment of the present invention is a route construction method using such a multi-layered carrousel sheet, comprising the steps of arranging a base surface, applying a primer to the arranged base surface to form a primer layer, Attaching a regenerated thermoplastic polyolefin multi-layered carpet sheet to the top of the attached waterproof sheet, and joining the joined portions of the attached multi-layered carpet sheet to each other by hot air fusing up and down to bond the adjacent multi- . A detailed description of each material constituting the reclaimed thermoplastic polyolefin multi-layered carrousel sheet has already been described above, and will not be described here.

The step of arranging the base surface may include the steps of removing the holes and irregularities formed on the surface of the base surface to be used as a precursor of the air tightness and cleanly removing foreign substances such as dust, rust, sand, etc. using a brush or a blower, The surface of the concrete to be installed on the concrete is dried, and when the water content is less than 10%, the base surface can be arranged and the preparation for the anticorrosion can be prepared.

The step of forming the primer layer may be applied with various commercially available primers, preferably an asphalt, urethane or acrylic primer, in order to increase the adhesion to the base surface.

In the step of adhering the multi-layered carrousel sheet, the waterproof sheet and the regenerated thermoplastic polyolefin multi-layered carrousel sheet can be adhered to each other by using a circular patch having an adhesive on both sides.

The method of the present invention for carrying out the antistatic method using the reclaimed thermoplastic polyolefin multi-layered carrousel sheet according to another embodiment of the present invention is characterized in that a coating material is applied on the primer layer between the step of forming the primer layer and the step of adhering the waterproof sheet, To form a second layer.

Hereinafter, an embodiment of the present invention will be described. However, the scope of the present invention is not limited to the following preferred embodiments, and a person skilled in the art can carry out various modifications of the contents described in the present invention within the scope of the present invention.

[Production Example] Production of recycled thermoplastic polyolefin multi-layer carpet sheet

[Example 1]

(Process oil), 1.2 kg of calcium carbonate (CaCO ₃ ), 1.6 kg of talc (Talc), and 10 g of NB (dibutyl acrylate) dithiocarbamate) were mixed in a Banbury mixer and kneaded at 120 DEG C for 5 minutes. Thereafter, the mixture was kneaded at 180 占 폚 for 10 minutes in a gelling roll, and then kneaded again at 180 占 폚 for 10 minutes in a second-round roll. The kneaded mixture was hot pressed to a thickness of 0.5 to 0.55 mm and then cooled to prepare upper and lower sheets.

A polypropylene nonwoven fabric was disposed as a center material between the upper and lower sheets, and the resultant laminate was thermally fused at 160 캜 to produce a recycled thermoplastic polyolefin multi-layered carpet sheet.

The regenerated thermoplastic polyolefin was a reactor thermoplastic polyolefin (R-TPO) produced by a polymerization reaction using a metallocene catalyst, and a polyolefin regenerated using R-TPO, which was used as an automobile interior material, was used.

 [Experimental Example 1]

Property Evaluation of Recycled Thermoplastic Polyolefin Multilayer Carrier Sheet

The properties of the regenerated thermoplastic polyolefin multi-layered carrous sheet of the present invention prepared in Example 1 were measured according to the test method of KS F 4911: 12.

The test results are summarized in Table 1 below.

From the results of Table 1, it can be seen that the regenerated thermoplastic polyolefin multi-layered breathing sheet of the present invention satisfies all of KS F 4911: 12 of the KS standard. Especially, tensile strength and elongation were higher than tensile strength and tensile strength, respectively, by 329% and 890%, respectively, and the maximum temperature dependence was 660% and the bond tensile performance was 207%.

[ Experimental Example  2]

Navigation performance  Test evaluation

The performance of the recycled thermoplastic polyolefin protective sheet of the present invention prepared in Example 1 was measured according to the test method of KS F 4938: 10. Specifically, a T-shaped joint was formed at the center of the test specimen of 800 x 800 x 200 mm, and the test specimen was mounted on a metal test frame, and the soil and the plant material were placed inside. In this way, six specimens (A to F) were completed and penetration and penetration of the roots of the plant were observed for 24 months.

The test results are shown in FIG. 2, and the results are summarized in Table 2 below.

Item Quality standards Result value Performance evaluation
(24 months) A test body Root penetration and penetration
Not to be clear B test body clear C test body clear D test body clear E test body clear F test body clear

Referring to Table 2 and FIG. 2, it was confirmed that the performance of the mobility was not abnormal in all of the six samples.

[Experimental Example 3]

The regenerated thermoplastic polyolefin multi-layered article according to the content of the regenerated thermoplastic polyolefin Antiperspirant  Property measurement

A regenerated thermoplastic polyolefin multi-layered carrousel sheet was prepared in the same manner as in Example 1 except that the content of regenerated thermoplastic polyolefin in the upper and lower sheets was varied in order to measure the physical properties of the multi-layered carrousel sheet according to the content of the regenerated thermoplastic polyolefin. The compositions of the upper and lower sheets having different regenerated thermoplastic polyolefin contents are shown in Table 3 below.

The properties of the multilayered carrous sheets of Comparative Examples 1 to 5 and Examples 1 to 3 were measured using the test method of KS F 4911: 12 and the simulated needle test evaluation method.

The simulated needle test evaluation was performed using the simulated settlement evaluation method in order to measure the locomotive performance. The simulated needle test evaluation was divided into general part and joint part. In the general part, a specimen was made in a size of 50 x 50 mm and mounted on a test jig. A simulated needle (tip: 0.5 mm Ø, shaft: 3 mm Ø) made of metal was pushed on the specimen at a speed of 1 mm / min to measure the maximum load Were measured. In case of the joint part, a specimen was made with 50 x 100mm (lap joint length 50mm), and mounted on a test jig. Then, a metal simulated needle (tip: 0.5mmØ, shaft: 3mmØ) was pushed at a speed of 1mm / The maximum load was measured.

The test results are summarized in Table 4 below.

From the results of Table 4, it can be seen that the tensile strength, the tear strength and the simulated needle resistance value of Examples 1 to 3 are high, and that the strength is superior to that of Comparative Examples 1 to 5.

Specifically, the tensile strength increased as the content of the regenerated thermoplastic polyolefin increased, particularly in Example 2 in which the content of the regenerated thermoplastic polyolefin was 51.5% by weight. The tensile strength was decreased from 60.1 wt% or more after the regenerated thermoplastic polyolefin content, and significantly decreased in Comparative Example 4 which was 73 wt% of the regenerated thermoplastic polyolefin.

In the case of the tear strength, the content of the regenerated thermoplastic polyolefin was increased as the content of the regenerated thermoplastic polyolefin was increased. However, the content of the regenerated thermoplastic polyolefin was decreased from 60.1 wt% or less, especially in Comparative Example 4 which was 73 wt.% Of the regenerated thermoplastic polyolefin.

On the other hand, in the case of elongation, the content of regenerated thermoplastic polyolefin was decreased as the content of regenerated thermoplastic polyolefin was increased, and the elongation of Comparative Example 2 was the highest.

In the case of simulated needle resistance performance, the content of regenerated thermoplastic polyolefin was increased as the content of regenerated thermoplastic polyolefin was increased, and the content of regenerated thermoplastic polyolefin was greatly increased in Example 2 where the content of regenerated thermoplastic polyolefin was 51.5% by weight. The simulated needle resistance performance value of the recycled thermoplastic polyolefin was 72 wt%, which was the largest in Example 3.

Therefore, the regenerated thermoplastic polyolefin multi-layered viscoelastic sheet of the present invention is excellent in tensile strength, tearing performance and simulated needle resistance performance, and can obtain a good antiperspirant effect.

1: multi-layered carrousel sheet 110:
120: center member 130: upper sheet

Claims (9)

An upper sheet 130;
A center member 120 disposed below the upper sheet 130; And
And a lower sheet (110) disposed under the center material (120)
The upper sheet 130 and the lower sheet 110 each contain 51.5 to 72 wt% of recycled thermoplastic polyolefin, 4.5 to 15.5 wt% of synthetic rubber, 4.5 to 11 wt% of adhesive resin, 5 to 14.5 wt% of process oil By weight, 11 to 27.5% by weight of an inorganic additive, and 0.9 to 4.5% by weight of an antioxidant,
The re-thermoplastic polyolefin is regenerated with R-TPO (Reactor thermoplastic polyolefin) used as a vehicle interior material as a raw material,
The R-TPO (Reactor thermoplastic polyolefin) is produced through a polymerization reaction using a metallocene catalyst in a reactor, and the distribution of polypropylene and EPR (Ethylene Propylene Rubber)
The center material 120 comprises polypropylene or polyester,
The synthetic rubber may be selected from the group consisting of EPDM (Ethylene Propylene Diene Monomer), SBS (Styrene Butadiene Styrene) and SEBS (Styrene Ethylene Butadiene Styrene) And at least one selected from the group consisting of:
Wherein the adhesive resin includes at least one selected from the group consisting of Rosin, Coumarone Resin, Phenol-Terpene Resin and Petroleum Hydrocarbon Resin,
Wherein the inorganic additive includes at least one selected from the group consisting of calcium carbonate (CaCO ₃ ), talc, clay, and barium sulfate (BaSO ₄ )
Wherein the process oil comprises at least one selected from the group consisting of an aromatic oil, a naphthene oil and a paraffin oil.
delete delete delete delete delete delete Arranging the base surface;
Applying a primer to the cleaned surface to form a primer layer;
Coating a coating material on the primer layer to form a coating layer;
Attaching a waterproof sheet to an upper portion of the coating layer;
Attaching a regenerated thermoplastic polyolefin multi-layer carpet sheet to the top of the attached waterproof sheet; And
And joining the joints of the regenerated thermoplastic polyolefin multi-layered carnesty sheets attached to the adjacent regenerated thermoplastic polyolefin multi-layered carnesty sheets together by hot air fusing,
The regenerated thermoplastic polyolefin multi-
An upper sheet 130;
A center member 120 disposed below the upper sheet 130; And
And a lower sheet (110) disposed under the center material (120)
The upper sheet 130 and the lower sheet 110 each contain 51.5 to 72 wt% of recycled thermoplastic polyolefin, 4.5 to 15.5 wt% of synthetic rubber, 4.5 to 11 wt% of adhesive resin, 5 to 14.5 wt% of process oil By weight, 11 to 27.5% by weight of an inorganic additive, and 0.9 to 4.5% by weight of an antioxidant,
The re-thermoplastic polyolefin is regenerated with R-TPO (Reactor thermoplastic polyolefin) used as a vehicle interior material as a raw material,
The R-TPO (Reactor thermoplastic polyolefin) is produced through a polymerization reaction using a metallocene catalyst in a reactor, and the distribution of polypropylene and EPR (Ethylene Propylene Rubber)
The center material 120 comprises polypropylene or polyester,
The synthetic rubber may be selected from the group consisting of EPDM (Ethylene Propylene Diene Monomer), SBS (Styrene Butadiene Styrene) and SEBS (Styrene Ethylene Butadiene Styrene) And at least one selected from the group consisting of:
Wherein the adhesive resin includes at least one selected from the group consisting of Rosin, Coumarone Resin, Phenol-Terpene Resin and Petroleum Hydrocarbon Resin,
Wherein the inorganic additive includes at least one selected from the group consisting of calcium carbonate (CaCO ₃ ), talc, clay, and barium sulfate (BaSO ₄ )
Wherein the process oil comprises at least one selected from the group consisting of an aromatic oil, a naphthene oil, and a paraffin oil.
9. The method according to claim 8, wherein the step of adhering the reconditioning thermoplastic polyolefin multi-layer carnestic sheet comprises the step of adhering the waterproof sheet and the reclaimed thermoplastic polyolefin multi-layered carnest sheet using a circular patch, A method of applying anticorrosion using a thermoplastic polyolefin multilayered carpet sheet.

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