KR101924555B1 - Multilayered polyvinyl acetal film and laminated glass comprising same - Google Patents

Abstract

The present invention relates to a multilayered polyvinyl acetal film and a laminated glass including the multilayered polyvinyl acetal film, wherein the laminate does not deteriorate the physical properties such as penetration resistance, while exhibiting excellent sound insulation for reducing noise in a wide temperature range.

Description

TECHNICAL FIELD [0001] The present invention relates to a multilayered polyvinyl acetal film and a laminated glass including the multilayered polyvinyl acetal film,

The present invention relates to a multilayered polyvinyl acetal film which has excellent sound insulation for reducing noise in a wide temperature range and does not deteriorate physical properties such as ductility and impact resistance, and a laminated glass including the multilayered polyvinyl acetal film.

Plasticized polyvinyl acetals (especially polyvinyl butyral) are commonly used in the production of polymer sheets for use as interlayers in light-transmitting laminates such as bonded glass (safety glass) or polymer laminates. The laminated glass usually refers to a transparent laminate comprising a polyvinyl butyral sheet sandwiched between two sheets of glass. Laminated glass is commonly used to provide transparent barriers in buildings and automotive openings. The primary function of the laminated glass is to absorb the energy, such as caused by a blow from the object, without allowing penetration through the opening, thereby minimizing damage or injury to objects or people in the transparent barrier. The polyvinyl butyral sheet generally includes an adhesion-modifying agent as an additive during manufacture to improve adhesion of the sheet to glass. As a result, the adherence of the sheet can be maintained at an appropriate level, and it is possible to prevent the glass from being broken and to provide an appropriate energy absorbing property against the impact. In addition, the interlayer sheet can be improved to provide additional beneficial effects of the laminated glass, such as reducing acoustic noise, reducing UV and / or IR light transmission, or improving the aesthetics of window opening.

Particularly, as a film used for glass such as automobiles and buildings, a film improved in car sound is being developed. The car sound is defined as the amount of transmission loss due to the change in frequency. Particularly, the range of 1,000 to 6,000 Hz, which is in the range of the loudness curve, is more important than the sound insulation performance in other areas because it has high sensitivity in human hearing. The spliced glass using the conventional interlayer film has sufficient scattering prevention effect, but it can not sufficiently reduce the coincidence effect, which is the resonance effect caused by the glass plate, at 2,000 Hz, and thus it is difficult to exhibit desired sound insulation performance.

For example, Japanese Patent No. 3,335,436 discloses a laminated glass having an anti-scattering performance and a sound insulation performance with an interlayer between a pair of glass plates. However, since the sound insulation performance of the interlayer formed between the laminated glasses is specified only at room temperature, the effect of the sound insulation performance is limited in an actual field FIELD where a temperature change occurs in the morning / evening or in the season.

Korean Patent Registration No. 10-0458923 discloses an interlayer for laminating glass and a laminated glass including the same, which exhibit sound insulation performance over a wide temperature range. However, the interlayer is manufactured by blending a polyvinyl acetal resin having a different degree of polymerization, and exhibits improved sound insulation performance with temperature dependency, but it is still insufficient to exhibit good sound insulation performance over a wide temperature range.

Accordingly, there is still a demand for the development of a film for an interlayer film of a laminated glass which exhibits good sound insulation performance over a wide temperature range.

Japanese Patent No. 3,335,436 Korean Patent No. 10-0458923

Accordingly, an object of the present invention is to provide a multilayer polyvinyl acetal film excellent in sound insulation, ductility and impact resistance even in various external environments, and a laminated glass bonded by the multilayer polyvinyl acetal film.

In order to achieve the above object,

An A layer comprising a first polyvinyl acetal resin wherein the acetal group has 4 to 6 carbon atoms and the content of acetal groups in the main chain is less than 1% by weight, and 24 to 30% by weight of a plasticizer;

A second polyvinyl acetal resin wherein the acetal group has 4 to 6 carbon atoms and the acetal group content in the main chain is 8 to 14% by weight, and 28 to 38% by weight of a plasticizer; And

Layer polyvinyl acetal film comprising a first polyvinyl acetal resin, a second polyvinyl acetal resin and a plasticizer, wherein the plasticizer content level differs by more than 2% by weight from the plasticizer content level of the B-layer.

Further, in order to accomplish the above other objects, the present invention provides a bonded glass bonded by the above-mentioned multi-layered polyvinyl acetal film.

The multilayer polyvinyl acetal film of the present invention exhibits excellent sound insulation performance even in a wide temperature range, and is excellent in endurance and impact resistance, so that it can be used as a bonding film for automobiles, buildings and the like to exhibit excellent performance .

1 shows the structure of a polyvinyl acetal film according to the present invention.

A layer comprising a first polyvinyl acetal resin wherein the acetal group has 4 to 6 carbon atoms and the content of acetal groups in the main chain is less than 1% by weight, and 24 to 30% by weight of a plasticizer; A second polyvinyl acetal resin wherein the acetal group has 4 to 6 carbon atoms and the acetal group content in the main chain is 8 to 14% by weight, and 28 to 38% by weight of a plasticizer; And a second polyvinyl acetal resin and a plasticizer, wherein the content of the plasticizer is in the range of 2% by weight or more of the content of the plasticizer in the B layer.

The multilayer polyvinyl acetal film according to the present invention is a multilayer film in which three or more layers having different glass transition temperatures are laminated, and each layer is suitable for realizing sound insulation performance because it lowers the coincidence effect at a certain temperature range. Therefore, the multilayer polyvinyl acetal film according to the present invention can exhibit high sound insulation performance over a wide temperature range.

Further, since the multilayer polyvinyl acetal film of the present invention has relatively high tensile strength and modulus as compared with other layers, at least one layer can stably maintain the penetration performance of the multilayer polyvinyl acetal film.

The polyvinyl acetal resin has a relatively low acetal group content and a high alcohol group content, which is easy to realize the glass bonding performance, and is suitable for stably implementing the impact resistance of the multilayer polyvinyl acetal film.

Hereinafter, the multilayer polyvinyl acetal film according to the present invention will be described in detail.

The multilayer polyvinyl acetal film according to the present invention comprises an A layer comprising a first polyvinyl acetal resin and a plasticizer.

The first polyvinyl acetal resin may have an acetal group having 4 to 6 carbon atoms and an acetal group content in the main chain of less than 1% by weight, specifically 0.5% by weight or less, an acetalization degree of 70 to 88% by weight, specifically 80 To 88% by weight.

The first polyvinyl acetal resin may be a polyvinyl acetal resin obtained by acetalizing polyvinyl alcohol having a degree of polymerization of 1,600 to 3,000 with aldehyde. In order to improve the mechanical properties such as penetration resistance of the produced film, the degree of polymerization of the polyvinyl alcohol is preferably more than 1,600, more preferably 1,700 or more.

The first polyvinyl acetal resin may be contained in an amount of 70 to 76% by weight, specifically 70 to 74% by weight, based on the total weight of the layer A.

The first polyvinyl acetal resin may be a synthesized polyvinyl alcohol and an aldehyde, and the aldehyde is not particularly limited. For example, it may be selected from the group consisting of n-butylaldehyde, isobutylaldehyde, n-barrel aldehyde, 2-ethylbutylaldehyde, n-hexylaldehyde and blend resins thereof. Specifically, the resin produced by using n-butylaldehyde has a small refractive index difference with glass and has excellent bonding strength to glass.

The plasticizer of the A layer may be contained in an amount of 24 to 30% by weight, specifically 26 to 29% by weight based on the total weight of the A layer. It is preferable that the plasticizer is contained in the above-mentioned content range in view of the improvement of the impact strength and the bonding force of the film.

The glass transition temperature (Tg) of the A layer can be determined by the plasticizer content to be added, but may be 15 to 25 캜, specifically 17 to 20 캜, as measured by differential scanning calorimetry (DSC). As a result, the film of the present invention can exhibit excellent sound insulation performance at room temperature.

Examples of the plasticizer include triethylene glycol bis 2-ethylhexanoate (3G8), tetraethylene glycol diheptanoate (4G7), triethylene glycol bis 2-ethylbutyrate (3GH), triethylene glycol bis 2- (DBA), dibutyl sebacate (DBS), bis-2-hexyl adipate (DHA), and mixtures thereof. , And specifically may be triethylene glycol bis 2-ethylhexanoate (3G8).

The multilayer polyvinyl acetal film according to the present invention comprises a B layer comprising a second polyvinyl acetal resin and a plasticizer.

The second polyvinyl acetal resin may have 4 to 6 carbon atoms in the acetal group and 8 to 14% by weight, specifically 10 to 12% by weight, of acetal groups in the main chain. The degree of acetalization may be 70 to 88 wt%, specifically 77 to 83 wt%.

The second polyvinyl acetal resin may be a polyvinyl acetal resin obtained by acetalizing polyvinyl alcohol having a degree of polymerization of 1,200 to 3,000 with aldehyde. Specifically, polyvinyl alcohol having a degree of polymerization of 1,600 to 2,400 may be acetalized with aldehyde. In order to improve the optical performance and increase the affinity with the plasticizer, a resin having a degree of polymerization of two or more species may be mixed and used.

The second polyvinyl acetal resin may be contained in an amount of 62 to 72% by weight, specifically 65 to 70% by weight based on the total weight of the layer B.

The second polyvinyl acetal resin may be the same component as the first polyvinyl acetal resin, and therefore the specific types thereof are the same as those mentioned above.

The plasticizer of the layer B may be contained in an amount of 28 to 38% by weight, specifically 30 to 35% by weight, based on the total weight of the layer B. It is preferable that the plasticizer is contained in the film within the above-mentioned range in terms of improving the impact resistance and sound insulation of the film.

The glass transition temperature (Tg) of the B layer can also be determined by the plasticizer content added, but can be from minus 15 ° C to image 10 ° C as measured by differential scanning calorimetry (DSC). As a result, the film of the present invention can exhibit excellent sound insulation performance over a wide temperature range.

The plasticizer may be the same component as the plasticizer used in the A layer, and therefore the specific types thereof are the same as those mentioned above. Specifically, triethylene glycol bis 2-ethylhexanoate (3G8) can be used.

In addition, the multilayer polyvinyl acetal film according to the present invention comprises a C layer comprising a second polyvinyl acetal resin and a plasticizer.

In this case, the content of the plasticizer in the C layer may differ from the content of the plasticizer in the B layer by 2% by weight or more, specifically 4 to 9% by weight. In this case, it is preferable to realize a sound insulation performance in a wide temperature range. For example, the content of the plasticizer in the C layer may be 2 wt% or more, or 2 wt% or less, more than the content of the plasticizer in the B layer. The content of the plasticizer in the C layer may be 24 to 46 wt% or more, specifically 28 to 40 wt% based on the total weight of the C layer.

The glass transition temperature (Tg) of the C layer can also be determined by the plasticizer content added, but can be from minus 20 ° C to image 15 ° C as measured by differential scanning calorimetry (DSC). As a result, the film of the present invention can exhibit excellent sound insulation performance over a wide temperature range.

The second polyvinyl acetal resin and the plasticizer used in the C layer are the same as those mentioned in the above B layer.

In the present invention, "glass transition temperature" is a value representing the viscoelastic characteristic of a material, and represents a maximum peak at a temperature at which the ratio of the point / elastic modulus changes most rapidly (transition region) , And the remaining energy is extinguished due to heat and molecular motion, which means that the reduction of the resonance effect is maximized. In other words, the glass transition temperature is a value determined by elasticity and viscosity, and is represented by E "/ E ', which is the same as tan Delta peak, which refers to a loss factor, The region where the transition temperature appears is the point at which the transmission loss is optimized.

The multilayer polyvinyl acetal film according to the present invention includes layers A, B, and C, and the layers A, B, and C may be alternately stacked in three or more layers. Specifically, it may be in the form of three to seven layers, more specifically five layers.

The laminated structure of the multilayer polyvinyl acetal film of the present invention is, for example, a three-layer structure of layer A / layer B / layer C; A layer / B layer / C layer / A layer, A layer / B layer / C layer / B layer or A layer / B layer / A layer / C layer; A layer / B layer / C layer / A layer / B layer, A layer / B layer / C layer / B layer / A layer, A layer / B layer / A layer / C layer / B layer or A layer / B layer / A layer / C layer / A layer, but the present invention is not limited thereto. Specifically A layer / B layer / A layer / C layer / A layer.

According to the present invention, it is preferable that the B layer and the C layer are laminated so as not to be adjacent to each other. Thus, the A layer can be located as an inner layer between the B layer and the C layer. This is because, if the plasticizer contained in the B layer and the C layer is affected by the external environment, the movement of the plasticizer causes the Tg to be affected thereby, which may also affect the temperature range in which the negative tone is expressed. Therefore, in the present invention, the A-layer is laminated between the B-layer and the C-layer so that the sound insulating layer can be properly implemented.

Further, in the multilayer polyvinyl acetal film of the present invention, it is preferable that the A layer is located in the outermost layer, i.e., the skin layer. This is due to the difference in physical properties such as the strength of the A layer, the strength of the B layer and the strength of the C layer, and workability. The resin constituting the B layer and the C layer is more flexible and less rigid than the resin constituting the A layer, It is preferable that the layer A is located in the outermost layer of the multilayer polyvinyl acetal film.

The multi-layered polyvinyl acetal film of the present invention may have an overall thickness of 0.4 mm or more, specifically 0.4 to 1.6 mm. Since the multilayer polyvinyl acetal film of the present invention is used for laminated glass, the thicker the thickness, the higher the sound insulation performance. However, considering the minimum regulation performance and cost, the thickness range is appropriate.

In the multilayer polyvinyl acetal film of the present invention, the thickness of the A layer may be 13 to 40%, particularly 20 to 40% of the total film thickness. For example, the thickness of the layer A may be 0.06 mm or more, specifically 0.06 to 0.6 mm. When the thickness of the A layer is within the above range, it can be properly performed as a skin layer and as an inner layer between the B layer and the C layer, so that it is suitable to exhibit inner pipe compatibility and sound insulation performance.

The thickness of each of the B layer and the C layer may be 7 to 28%, specifically 10 to 28% of the total thickness of the film. For example, the thickness of each of the B layer and the C layer may be 0.04 mm or more, specifically 0.04 to 0.3 mm. If the thickness of the B layer and the C layer is too small, the sound insulation performance is not effective. If the thickness exceeds 0.3 mm, the rigidity of the entire film is lowered and the penetration performance is lowered. do.

On the other hand, the multilayer polyvinyl acetal film according to the present invention may further contain an additive selected from the group consisting of an antioxidant, a heat stabilizer, a UV absorber, a UV stabilizer, an IR absorber, a glass adhesion regulator and combinations thereof.

The additive may be included in at least one resin layer of the A layer, the B layer, and the C layer. By including the additive, the thermal stability of the film, long term durability such as light stability, and scattering prevention performance can be improved.

The antioxidant may be a hindered amine type or a hindered phenol type. More specifically, a normal hindered phenol antioxidant manufactured by polyvinyl butyral (PVB) which requires a process temperature of 150 ° C or higher is more preferable. As the hindered phenol-based antioxidant, for example, IRGANOX 1076, 1010 of BASF can be used.

The heat stabilizer may be a phosphite-based heat stabilizer in consideration of compatibility with an antioxidant. For example, IRGAFOS 168 from BASF can be used.

The UV absorber may be selected from the group consisting of Chemisorb 12, Chemisolve 79, Chemisolve 74, Chemisolve 102, Tinuvin 328 from BASF, Tinuvin 329, Tinuvin 326 and the like. The UV stabilizer may be tinuvin of BASF. ITO, ATO, AZO and the like can be used as the IR absorber, and a metal salt such as Mg, K, Na, an epoxy-modified Si oil, or a mixture thereof can be used as the glass adhesion force adjusting agent. It is not.

The multilayer polyvinyl acetal film of the present invention can be produced by, for example, (a) preparing an A-layer resin composition, a B-layer resin composition and a C-layer resin composition; And (b) extruding the compositions of the respective layers using a twin extruder and alternately laminating them and then molding them into a sheet form.

The A-layer resin composition is prepared by mixing a first polyvinyl acetal resin having acetal groups of 4 to 6 carbon atoms and an acetal group content in the main chain of less than 1 wt% and 24 to 30 wt% of a plasticizer based on the total weight can do.

The B-layer resin composition is prepared by mixing a second polyvinyl acetal resin having acetal groups of 4 to 6 carbon atoms and acetal groups in the main chain of 8 to 14 wt% and 28 to 38 wt% .

The C-layer resin composition may be prepared by the same method as the resin of the B-layer, but adding the plasticizer in an amount of 2% by weight or more.

On the other hand, the present invention provides a laminated glass bonded by the multilayer polyvinyl acetal film.

A method of bonding the multilayer polyvinyl acetal film of the present invention to glass may be a method of bonding a multilayer polyvinyl acetal film to a glass by a preliminary bonding process such as a vacuum bag, a vacuum ring, a nip roll, Thermocompression; Or a laminator can be used.

Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the following examples are for illustrative purposes only and are not intended to limit the scope of the present invention.

[ Example ]

The ingredients used in the following examples and comparative examples are as follows:

- First polyvinyl acetal resin: polyvinyl alcohol having an average degree of polymerization of 1700, an acetate content of 0.1 wt%, an acetalization degree of 83 wt%

- Second polyvinyl acetal resin: average degree of polymerization of polyvinyl alcohol 2000, an acetate content of 12% by weight, an acetalization degree of 78%

- Plasticizer: triethylene glycol bis 2-ethylene hexanoate (3G8) (available from PROVIRON Corporation PROVIST 1766)

Example  1: Multilayer Polyvinyl acetal  Production of film

In order to produce the multilayer film according to the present invention, three twin screw extruders (manufacturer SM Platec) were used. The A layer was used as the first extruder, the B layer was used as the second extruder, and the C layer was used as the third extruder. The resin composition for each layer described below was fed into each of the extruders and extruded at 180 ° C .

Layer A: a composition comprising 73% by weight of a first polyvinyl acetal resin based on the total weight of the composition and 27% by weight of triethylene glycol bis 2-ethylene hexanoate (3G8) as plasticizer.

- layer B: a composition comprising 65% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 35% by weight of 3G8 as a plasticizer.

C layer: a composition comprising 61% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 39% by weight of 3G8 as a plasticizer.

The extruded films were laminated with a film by a feed block, and the layer structure was laminated with A / B / A / C / A.

Formed into a sheet through a die (DIE) of an extruder, and then cooled in a casting roll at 40 DEG C to prepare a multilayer film.

Example  2: Multilayer Polyvinyl acetal  Production of film

A multilayer film was produced in the same manner as in Example 1, except that the resin composition for each layer described below was used.

Layer A: a composition comprising 73% by weight of a first polyvinyl acetal resin based on the total weight of the composition and 27% by weight of triethylene glycol bis 2-ethylene hexanoate (3G8) as plasticizer

Layer B: a composition comprising 65% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 35% by weight of 3G8 as plasticizer

C layer: a composition comprising 70% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 30% by weight of 3G8 as a plasticizer

Example  3: Multilayer Polyvinyl acetal  Production of film

A multilayer film was produced in the same manner as in Example 1, except that the resin composition for each layer described below was used.

Layer A: a composition comprising 73% by weight of a first polyvinyl acetal resin based on the total weight of the composition and 27% by weight of triethylene glycol bis 2-ethylene hexanoate (3G8) as plasticizer

Layer B: a composition comprising 70% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 30% by weight of 3G8 as plasticizer

C layer: a composition comprising 61% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 39% by weight of 3G8 as a plasticizer

Comparative Example  1: Multilayer Polyvinyl acetal  Production of film

A multilayer film was produced in the same manner as in Example 1, except that the resin composition for each layer described below was used.

Layer A: a composition comprising 73% by weight of a first polyvinyl acetal resin based on the total weight of the composition and 27% by weight of triethylene glycol bis 2-ethylene hexanoate (3G8) as plasticizer

Layer B: a composition comprising 65% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 35% by weight of 3G8 as plasticizer

C layer: a composition comprising 64% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 36% by weight of 3G8 as a plasticizer

Comparative Example  2: Multilayer Polyvinyl acetal  Production of film

A multilayer film was produced in the same manner as in Example 1, except that the resin composition for each layer described below was used.

Layer A: a composition comprising 73% by weight of a first polyvinyl acetal resin based on the total weight of the composition and 27% by weight of triethylene glycol bis 2-ethylene hexanoate (3G8) as plasticizer

Layer B: a composition comprising 65% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 35% by weight of 3G8 as plasticizer

C layer: a composition comprising 66% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 34% by weight of 3G8 as plasticizer

Comparative Example  3: Multilayer Polyvinyl acetal  Production of film

A multilayer film was prepared in the same manner as in Example 1, except that the multilayered film had a layered structure of A / B / A / C and the layer thicknesses were adjusted according to the contents shown in Table 1 below.

Comparative Example  4: Multilayer Polyvinyl acetal  Production of film

A multilayer film was produced in the same manner as in Example 2, except that the thicknesses of the layers of the multilayered films were adjusted in accordance with the contents shown in Table 1 below.

Comparative Example  5: Multilayer Polyvinyl acetal  Production of film

A multilayer film was produced in the same manner as in Example 1, except that the resin compositions for the respective layers described below were used and the thicknesses of the layers were adjusted in accordance with the contents shown in Table 1 below.

Layer A: a composition comprising 73% by weight of a first polyvinyl acetal resin based on the total weight of the composition and 27% by weight of triethylene glycol bis 2-ethylene hexanoate (3G8) as plasticizer

Layer B: a composition comprising 65% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 35% by weight of 3G8 as plasticizer

C layer: a composition comprising 61% by weight of a second polyvinyl acetal resin based on the total weight of the composition and 39% by weight of 3G8 as a plasticizer

The plasticizer content, the lamination structure, the layer thicknesses and the total thicknesses in the sound insulating layers (B and C layers) according to the multilayer polyvinyl acetal films prepared in Examples 1 to 3 and Comparative Examples 1 to 5 are shown in Table 1 .

Experimental Example : Car audio and Intrinsic flexibility  evaluation

The laminated polyvinyl acetal film produced in Examples 1 to 3 and Comparative Examples 1 to 5 was bonded to each other to prepare a laminated glass. Then, the louvres and ductility of the laminated glass were measured by the following methods, Respectively.

Measurement of car audio

300 mm x 25 mm 2.1T glass and the multilayer films of Examples 1 to 3 and Comparative Examples 1 to 5 were heated in a laminator at a temperature of 130 DEG C for 15 minutes in a laminated structure of 2.1T glass-multilayer film-2.1T glass The specimens were bonded by pressurization and aged for 1 hour in a constant temperature chamber at 0 ° C, 20 ° C, or 30 ° C.

The vibration specimens were excited by a vibration generator for damping test, the obtained vibration characteristics were amplified by a mechanical impedance amplifier, and the obtained vibration spectrum was analyzed by an FFT (fast Fourier transform) spectrum analyzer to draw a graph. The loss factor at a frequency of about 2,000 to 4,000 Hz was calculated using the 1 dB method.

The higher the loss factor, the better the sound insulation performance and the ordinary sound insulation film has a loss factor of 0.35 at 20 ° C.

Intrinsic  Measure

The penetration resistance of the bonded glass laminated with the polyvinyl acetal film of the present invention was evaluated based on KS L 2007.

A 300 mm x 300 mm 2.1T glass and each of the multilayer films of Examples 1 to 3 and Comparative Examples 1 to 5 was made into a laminated structure of 2.1T glass-multilayer film-2.1T glass and preliminarily bonded to a vacuum, Edge sealing. The bonded specimens were then bonded to each other at 150 ° C for 2 hours using a high-pressure autoclave. Thereafter, a steel ball having a diameter of 2.26 kg was dropped on the bonded specimen, and the height (MBH) at which the specimen was penetrated was measured. In this case, FAIL is indicated when penetration is less than 4 m and PASS is indicated when penetration is more than 4 m.

Measurement of impact resistance

Based on KS L 2007: 2008, we evaluated the loss of glass in polyvinyl acetal film bonded glass. Specifically, a 300 mm × 300 mm 2.1T glass and each of the multilayer films of Examples 1 to 3 and Comparative Examples 1 to 5 was laminated with a laminate structure of 2.1T glass-multilayer film-2.1T glass at a temperature of 150 ° C. in a laminator Followed by heating and pressing for 15 minutes to prepare specimens. The 227 g steel ball was stored at -20 ° C for 4 hours, dropped at 9 m height, and stored at 40 ° C for 4 hours. The steel balls are then fined to the specimen with a 10-m raised through-hole. If the impacted specimen is broken and the glass is scattered or the amount of glass falling from the sheet is greater than 15 g, fail the impacted specimen is not broken, If the amount of glass falling from the sheet is less than 15 g, it is indicated as pass.

Amount of plasticizer in the sound insulation layer (% by weight) all
thickness
(mm) Lamination composition and thickness per layer
(mm) Depending on measurement temperature
Loss factor Intrinsic flexibility Impact resistance Floor B C layer 0 C 20 ℃ 30 ℃ Example 1 35 39 750 A / B / A / C / A
(0.2 / 0.1 / 0.15 / 0.1 / 0.2) 0.155 0.362 0.150 pass pass Example 2 35 30 750 A / B / A / C / A
(0.2 / 0.1 / 0.15 / 0.1 / 0.2) 0.144 0.364 0.164 pass pass Example 3 30 39 750 A / B / A / C / A
(0.2 / 0.1 / 0.15 / 0.1 / 0.2) 0.148 0.354 0.163 pass pass Comparative Example 1 35 36 750 A / B / A / C / A
(0.2 / 0.1 / 0.15 / 0.1 / 0.2) 0.133 0.355 0.151 pass pass Comparative Example 2 35 34 750 A / B / A / C / A
(0.2 / 0.1 / 0.15 / 0.1 / 0.2) 0.132 0.354 0.153 pass pass Comparative Example 3 35 39 750 A / B / A / C
(0.1 / 0.3 / 0.05 / 0.3) 0.159 0.366 0.150 pass fail Comparative Example 4 35 30 750 A / B / A / C / A
(0.05 / 0.3 / 0.05 / 0.3 / 0.05) 0.130 0.368 0.170 fail - Comparative Example 5 35 39 760 A / B / C / A
(0.28 / 0.1 / 0.1 / 0.28) 0.136 0.364 0.149 pass -

As shown in Table 1, when the plasticizer content of the B layer and the C layer differ by more than 2% by weight, the multilayered film of the comparative example exhibited excellent sound insulation performance in a wide temperature range of 0 to 30 캜 and good penetration resistance appear.

The multilayered films of Examples 1 to 3 having the thickness of the A layer of 0.06 mm or more showed excellent sound insulation performance without lowering the physical properties such as penetration resistance as compared with Comparative Example 4 having the A layer thickness of 0.05 mm.

Further, the multilayer films of Examples 1 to 3, in which the A layer was composed of the skin layer of the multilayer film, were superior in intrinsic permeability as compared with Comparative Example 3.

In the case of Comparative Example 5 in which the B layer and the C layer were in contact with each other, the sound insulating performance at low temperature and high temperature was poorer than in Example 1 in which the A layer was interposed. This is believed to be due to the migration of the plasticizer between the B and C layers.

Claims (10)

An A layer comprising a first polyvinyl acetal resin wherein the acetal group has 4 to 6 carbon atoms and the content of acetal groups in the main chain is less than 1% by weight, and 24 to 30% by weight of a plasticizer;
A second polyvinyl acetal resin wherein the acetal group has 4 to 6 carbon atoms and the acetal group content in the main chain is 8 to 14% by weight, and 28 to 38% by weight of a plasticizer; And
A second polyvinyl acetal resin and a plasticizer, wherein the content of the plasticizer is in the range of 2% by weight or more of the content of the plasticizer in the layer B,
The A layer, the B layer and the C layer are alternately stacked in four to seven layers,
The A layer is laminated between the B layer and the C layer,
Wherein the layer A is located in the outermost layer of the multilayer polyvinyl acetal film.
delete The method according to claim 1,
Wherein the degree of acetalization of the first polyvinyl acetal resin and the second polyvinyl acetal resin is 70 to 88 wt%, respectively.
The method according to claim 1,
Wherein the content of the plasticizer in the C layer is 24 to 46 wt% based on the total weight of the C layer.
The method according to claim 1,
Wherein the total thickness of said multilayer polyvinyl acetal film is from 0.4 mm to 1.6 mm.
The method according to claim 1,
Wherein the thickness of the A layer is 0.06 to 0.6 mm, and the thicknesses of the B layer and the C layer are 0.04 to 0.3 mm, respectively.
delete delete delete A laminated glass bonded by a multilayer polyvinyl acetal film according to any one of claims 1 and 6.

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