KR101815753B1 - Self heat supply dehydrogenation reactor with heat source plate inside catalyst layer - Google Patents
Self heat supply dehydrogenation reactor with heat source plate inside catalyst layer Download PDFInfo
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- KR101815753B1 KR101815753B1 KR1020160021123A KR20160021123A KR101815753B1 KR 101815753 B1 KR101815753 B1 KR 101815753B1 KR 1020160021123 A KR1020160021123 A KR 1020160021123A KR 20160021123 A KR20160021123 A KR 20160021123A KR 101815753 B1 KR101815753 B1 KR 101815753B1
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- reactor
- heat source
- dehydrogenation
- heat
- screen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0292—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds with stationary packing material in the bed, e.g. bricks, wire rings, baffles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0278—Feeding reactive fluids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
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- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
The present invention relates to a method for producing a polymer electrolyte fuel cell, which comprises a housing defining an inside of a reactor, a catalyst inlet formed at an upper end of the housing to store and input a catalyst, a reactor inlet formed at an upper side of the housing, A dehydrogenation catalyst layer disposed on the inside of the housing coaxially with the housing and defined by an inner screen and an outer screen, the dehydrogenation catalyst layer being filled with a dehydrogenation catalyst therein and undergoing a dehydrogenation reaction of the source gas, Wherein at least a portion of the one end of the one end is in contact with the inner screen and at least a portion of the other end of the one end is in contact with the outer screen and the other end is in contact with the outer screen, And is supplied into the dehydrogenation catalyst layer It relates to a self-heating dehydrogenation reactor containing a plurality of ten won plates to heat the charge gas, according to the present invention through the heat exchange plate of the heat source can supply the additional heat in the reactor can significantly reduce the preheating temperature.
Description
The present invention relates to a dehydrogenation reactor useful for dehydrogenating various hydrocarbon raw materials, and more particularly, to a dehydrogenation reactor useful for dehydrogenating various hydrocarbons by using a heat source plate mounted inside a dehydrogenation catalyst layer, Dehydrogenation reactor.
The dehydrogenation of propane with propylene and isobutane with isobutene produces olefins which are more reactive than alkane feedstocks and which are easy to form coke at high temperatures used for dehydrogenation. The dehydrogenation reactor is a very large, long columnar vertical structure with a width of about 5 to 30 feet and a length of 10 to 100 feet or more. The general structure of this reactor is to inject a reactive gas into the inlet located at the bottom center of the vertical reactor where the gas flows up through the annular zone and passes radially outward through a porous catalyst bed or other suitable dehydrogenation catalyst Passes upwardly through the outer annular zone to be discharged from the top of the reactor outer part. These reactors are often referred to as "radial" reactors because the reactant gas flow through the catalyst bed is radial.
Generally, the radial flow reaction zone consists of cylindrical zones having various nominal cross-sectional areas, which are arranged vertically and coaxially to form reaction zones. Typically, the radial flow reaction zone includes a cylindrical reaction vessel having a cylindrical outer catalyst containing screen and a cylindrical inner catalyst containing screen coaxially disposed with the reaction vessel. The inner screen has a nominal inner cross-sectional area smaller than the outer screen and has a nominal inner cross-sectional area smaller than the reaction vessel. The reaction gas stream is introduced into an annular space present between the inner wall of the reaction vessel and the outer surface of the outer screen. The reaction gas stream passes radially through an annular space present between the outer screen and the inner screen through the outer screen and then through the inner screen. The collected stream into the cylindrical space inside the inner screen is withdrawn from the reaction vessel.
The propane dehydrogenation reaction is a process for producing propylene by separating a part of hydrogen from propane. This process is based on an endothermic reaction (ΔH 0 298 = +124 kJ / mole) and sufficient energy must be supplied during the reaction process in order for the reaction to proceed properly. The theoretical equilibrium conversion of propane increases with increasing reaction temperature. In order to increase the equilibrium conversion rate, the reaction gas is heated to 650 ° C or higher and an endothermic reaction proceeds.
Various techniques have been developed and applied in practice as an energy source for the propane dehydrogenation process, and the most common method is a fired heater. The furnace is installed upstream of the reactor to supply a certain amount of energy for the dehydrogenation process of the endothermic reaction. Propane, which is the main reaction gas, is injected into the high temperature heating furnace together with hydrogen before being introduced into the catalytic reactor, and is heated to a proper temperature through a heat exchange process.
1 is a schematic diagram showing a general dehydrogenation system in which heat is supplied using a heating furnace. Referring to FIG. 1, propane and hydrogen, which are reaction gases, pass through a heating furnace, are subjected to a heat exchange and heating process, and then are injected into a dehydrogenation catalytic reactor. Conventionally, a heating furnace used as a preheating device is a method of supplying a gas to a U-shaped pipe and heating several burners around the pipe. Since the heating furnace having such a structure can be heated at a high temperature of 600 to 700 ° C. or higher, it is suitable as a preheating device for the dehydrogenation process, but it is difficult to control the temperature and has a high risk in a process using a combustible gas. In addition, selective heating is not possible depending on the position and the area of the reactor, and a temperature gradient is generated between the inside and the outside of the propane pipe, and a locally heated portion is generated, thereby generating a hot spot of 700 ° C or more inside the heating apparatus. Thermal cracking is a side reaction. Methane, ethane, ethylene, etc. are produced by thermal cracking between propane and propylene. This side reaction is one of the most important parameters to control the heating condition of the furnace because it decreases the yield of propylene and is the main cause of reduction of the process performance.
Therefore, as the heating temperature of the heating furnace increases, the conversion of propane increases, but at the same time, the selectivity decreases due to thermal cracking, thereby reducing the yield of propylene and increasing the unit cost of the process. In addition, there is a problem that a huge initial investment cost and maintenance cost for insulation treatment of the pipe connecting the heating furnace and the reactor occur.
In order to overcome the problems of the prior art described above, the object of the present invention is to provide an apparatus and a method for controlling a preheating temperature by supplying a heat source plate inside a catalyst layer in which a catalytic reaction proceeds, And to maintain the entire process to be an isothermal reaction, thereby improving the process yield and reducing the operation, maintenance, and repair costs.
According to one aspect of the present invention for achieving the above object,
A catalyst inlet formed in the upper end of the housing for storing and introducing the catalyst therein, a reactor inlet formed on one side of the upper portion of the housing for supplying a fluid reactant into the reactor, A dehydrogenation catalyst layer disposed on the inside of the housing coaxially with the housing and defined by an inner screen and an outer screen, the dehydrogenation catalyst layer being filled with a dehydrogenation catalyst therein and undergoing a dehydrogenation reaction of the source gas, And a reaction gas outlet for recovering the reactant stream from the reaction gas outlet,
A plurality of heat source plates disposed between the inner screen and the outer screen for heating the source gas supplied into the dehydrogenation catalyst layer by contacting at least a portion of the one end with the inner screen and at least a portion of the other end with the outer screen, source dehydrogenation reactor comprising a source column.
The dehydrogenation reactor for self-heating according to the present invention can supply additional heat to the inside of the reactor through the heat exchange by the heat source plate, so that the preheating temperature can be remarkably lowered. In addition, since the temperature of the reactor is not locally heated and the temperature gradient between the inside / outside of the reactor is small, the heat cracking of the propane can be prevented and the heat lost by the endothermic reaction May be added to the reactor itself to increase the dehydrogenation yield and propylene selectivity. In addition, the manufacturing cost can be reduced by reducing the reaction temperature reduction problem and the heat insulation treatment cost due to the heat loss of the piping and the reactor.
1 is a schematic diagram showing a general dehydrogenation system in which heat is supplied using a heating furnace.
Figure 2 is a schematic longitudinal cross-sectional view of a reactor illustrating a heat source plate disposed within a screen of a reactor according to one embodiment of the present invention.
3 is a partial cross-sectional view of a reactor illustrating a heat source plate disposed within a screen of a reactor according to one embodiment of the present invention.
Figure 4 is a partial cross-sectional view of a reactor illustrating a heat source plate disposed within a screen of a reactor according to another embodiment of the present invention.
Figure 5 is a partial cross-sectional view of a reactor illustrating a heat source plate disposed within a screen of a reactor according to another embodiment of the present invention.
The present invention will now be described in more detail with reference to the accompanying drawings. Although the terms used in the present invention have been selected as general terms that are widely used at present, there are some terms selected arbitrarily by the applicant in a specific case. In this case, the meaning described or used in the detailed description part of the invention The meaning must be grasped. Like reference numerals refer to like elements throughout the specification.
Although the drawings illustrate specific shapes of the dehydrogenation reactor of the present invention, such a dehydrogenation reactor may have various shapes suitable for the specific environment in which it is performed in a particular application, And the like. Moreover, the numbers in the figures represent a simple schematic diagram of the dehydrogenation reactor of the present invention, only major components being shown. Other pumps, moving pipes, valves, hatches, access outlets and other similar components have been omitted.
The use of these components to modify the described dehydrogenation reactor is well known to those skilled in the art and does not depart from the scope and spirit of the appended claims.
As used herein, the term "fluid" means a gas, liquid, or gas or liquid containing a dispersed solid or a mixture thereof. The fluid may be in the form of a gas containing dispersed droplets.
As used herein, the term "reaction zone" means the space in the dehydrogenation reactor where the reaction gas is in contact with the catalyst on the catalyst bed.
Herein, the direction of the flow of solids through the device by downward, downward, or gravity directions, i.e., cross-flow gas, is oriented so that the use of the terms 'lower', 'downward', 'upper' and 'upward' As shown in FIG.
As used herein, the term " inner "or" inner "refers to the direction of the radial center of the circle, which is the cross-section perpendicular to the direction of gravity of the annular reactor.
As used herein, the term " outer "or" outer "refers to the direction of the radial circumference of the circle, which is a section cut perpendicular to the gravitational direction of the annular reactor.
The term "screen " herein has a broad meaning, including means suitable for limiting the catalyst to the catalyst bed while permitting flow of the reaction gas stream across the catalyst bed.
The numbers in the figures represent a simplified schematic diagram of the dehydrogenation reactor according to the invention, only the main components being shown. Other pumps, moving pipes, valves, hatches, access outlets, and other similar components have been omitted. The use of these accessories to modify the dehydrogenation reactor described is well known to those skilled in the art and does not depart from the scope and spirit of the appended claims.
FIG. 2 is a schematic longitudinal sectional view of a self-heat supplying dehydrogenation reactor according to an embodiment of the present invention. FIG. Referring to FIG. 2, the self-heat supplying
The
The
The heat transferred to the
As a heat source usable in the present invention, an electric heater, a hot gas, a flame, a metal oxide catalyst-based heat generating material (HMG), or steam may be used, It is not. For example, high-pressure gas or steam may be generated outside the reactor and connected to the upper portion of the
The
3 is a partial cross-sectional view of a reactor illustrating a heat source plate disposed within a screen of a reactor according to one embodiment of the present invention. 3, the
Referring to FIG. 3, the
It is preferable that the number of the
The
For example, in FIG. 3, a plurality of
Figure 4 is a partial cross-sectional view of a reactor illustrating a heat source plate disposed within a screen of a reactor according to another embodiment of the present invention.
4, a plurality of
Figure 5 is a partial cross-sectional view of a reactor illustrating a heat source plate disposed within a screen of a reactor according to another embodiment of the present invention.
5, a plurality of
As described above, the
According to an embodiment of the present invention, the raw material gas is injected into the
The
In addition, the present invention is not limited to the case where the direction of movement of the raw material gas flows from the upper portion of the
The reaction gas introduced into the
As described above, in the self-heat supplying dehydrogenation reactor according to the present invention, the heat source plate is applied to the inside of the screen where the dehydrogenation reaction proceeds, so that there is no locally heated point and the temperature gradient between the inside / It is possible to reduce the production cost by reducing the reaction temperature reduction problem and the heat insulation treatment cost due to the heat loss of the piping and the reactor .
While the invention has been described in connection with various specific embodiments, it is to be understood that various modifications thereof will become apparent to those of ordinary skill in the art upon reading the specification. Accordingly, the invention as described herein is intended to embrace such modifications as fall within the scope of the appended claims.
10: housing 11: source gas inlet
12: reaction gas outlet 20: catalyst inlet
30: dehydrogenation catalyst layer 31: inner screen
32: outer screen 33: catalyst distribution pipe
34: catalyst exhaust pipe 35: dehydrogen catalyst particle
40: heat source plate 50: reaction gas collecting region
Claims (14)
At least a portion of which is in contact with the inner screen and at least a portion of the other end is in contact with the outer screen to heat the source gas supplied into the dehydrogenation catalyst layer, A self heat provision dehydrogenation reactor comprising heat source plates.
Priority Applications (1)
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KR1020160021123A KR101815753B1 (en) | 2016-02-23 | 2016-02-23 | Self heat supply dehydrogenation reactor with heat source plate inside catalyst layer |
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KR1020160021123A KR101815753B1 (en) | 2016-02-23 | 2016-02-23 | Self heat supply dehydrogenation reactor with heat source plate inside catalyst layer |
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KR20170099433A KR20170099433A (en) | 2017-09-01 |
KR101815753B1 true KR101815753B1 (en) | 2018-02-22 |
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KR1020160021123A KR101815753B1 (en) | 2016-02-23 | 2016-02-23 | Self heat supply dehydrogenation reactor with heat source plate inside catalyst layer |
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KR20240059581A (en) * | 2022-10-27 | 2024-05-07 | 주식회사 엘지화학 | Reaction Device |
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