KR101806886B1 - Anti-glare coating composition and anti-glare film using the same - Google Patents

Abstract

The present invention relates to a composition for anti-glare coating and an antiglare film using the same. More particularly, the present invention relates to a composition for anti-glare coating, The present invention relates to an anti-glare coating-forming composition and an anti-glare film using the same, wherein the anti-glare coating composition includes satisfactory light scattering spherical particles.

Description

TECHNICAL FIELD [0001] The present invention relates to a composition for antiglare coating and an antiglare film using the composition. [0002]

The present invention relates to a composition for anti-glare coating and an anti-glare film using the same, and more particularly, to a composition for anti-glare coating capable of improving the visibility of a laser pointer and an anti-glare film using the same.

Conventionally, in a presentation such as a meeting or a presentation, it has been often done to project a data image on a screen or a wall using a projector. At this time, the presenter generally uses a laser pointer for projecting laser light at any place on the presentation image, and performs presentation while pointing to a screen or the like. However, in the case of the screen projection using the projector, there is a problem that the contrast is lowered or the image quality is deteriorated in the projected image.

In recent years, a liquid crystal display (LCD) or a plasma display (PDP) has been made larger than 70 inches, and it is possible to display a picture directly on the display itself .

However, when the presentation is performed by direct display using such a display, there is a problem that the visibility of the pointer is poor when the laser pointer is used because the display is self-luminous. In addition, when the display property of the display itself is improved, the reflectivity of the projected light of the laser pointer is suppressed if the scattering property of the display surface is improved, so that there arises a problem that the visibility of the laser pointer is not improved.

Recently, as disclosed in Japanese Patent Application Laid-Open No. 2001-236181, there is also a possibility that the laser pointer may be used as a pointing device for performing screen display manipulation on a display, and the visibility becomes even more important.

Patent Document 1: JP-A-2001-236181

The present invention provides a composition for anti-glare coating capable of improving the visibility of a laser pointer as well as having excellent anti-glare properties and an antiglare film using the same.

Further, the present invention provides an image display apparatus having the above-mentioned antiglare film.

1. An antiglare coating-forming composition comprising light scattering spherical particles having a cavity therein, wherein the sum (St) of the external surface area (S1) and the internal cavity surface area (S2) satisfies the following formula:

[Equation 1]

1.75 * (4? R ² )? St <10.75 * (4? R ² )

(Where r is the radius of the light scattering spherical particles).

2. The antiglare coating-forming composition of claim 1, wherein the internal cavity has a diameter of from 100 to 300 nm.

3. The antiglare coating-forming composition according to item 1, wherein the radius of the light scattering spherical particles is 0.1 to 10 mu m.

4. The antiglare coating-forming composition according to item 1 above, wherein the light scattering spherical particles further comprise a porous structure on the outer surface.

5. The antiglare coating-forming composition according to item 1 above, wherein the light scattering spherical particles are formed of silica or a polymer.

6. The antiglare coating-forming composition according to item 1 above, wherein the light scattering spherical particles are formed by incorporating a photoluminescent material.
7. The antiglare coating-forming composition according to item 1 above, which is used in the production of a film for improving laser pointer visibility.

8. Substrate; And an antiglare coating formed on the substrate, the antiglare coating being formed from the composition of any one of claims 1 to 7.

9. The antiglare film according to the above 8, wherein the antiglare coating has irregularities on its surface by the light scattering spherical particles.

10. The antiglare film according to the above 8, wherein the antiglare film is attached to a polarizing plate or retarder.

11. An image display apparatus comprising the anti-glare film of the above item 8.

The anti-glare coating-forming composition of the present invention includes light scattering spherical particles having cavities therein with a specific surface area ratio, thereby maximizing the scattering of the laser light as well as the scattering property, thereby remarkably improving the visibility of the laser pointer.

Therefore, the antiglare film formed from the composition of the present invention is applied to an image display apparatus, and can be usefully used when a laser pointer is directly irradiated to an image display apparatus to perform a presentation.

In addition, the light scattering spherical particles to be applied to the composition of the present invention may further have a porous structure on the outer surface, thereby further improving the visibility and retardation of the laser pointer.

In addition, when the light scattering spherical particles to be applied to the composition of the present invention include light luminescent particles that emit light by itself, light scattering particles are emitted by a laser used as a pointer, thereby further improving the visibility of the pointer , In which case the light scattering particles with cavities inside can further maximize the visibility of the laser pointer.

The present invention relates to an antiglare coating composition which has an inside cavity and includes a light scattering spherical particle in which a sum (St) of an external surface area (S1) and a surface area (S2) And an antiglare film using the composition.

Hereinafter, the present invention will be described in more detail.

The anti-glare coating-forming composition for enhancing laser pointer visibility of the present invention comprises light scattering spherical particles having cavities therein.

The light scattering spherical particles according to the present invention can improve the scattering effect of the incident laser light by having cavities therein. Particularly, the light scattering spherical particle of the present invention can maximize the laser light scattering effect by satisfying the following expression (1), that is, the sum (St) of the external surface area S1 and the surface area S2 of the internal cavity.

[Equation 1]

1.75 * (4? R ² )? St <10.75 * (4? R ² )

(Where r is the radius of the light scattering spherical particles).

If the sum (St) of the surface areas is less than or more than the above range, the visibility of the laser pointer is lowered and haze is lowered. In this respect, it is more preferable that St is 2.5 * (4πr ² ) to 4 * (4πr ² ).

In the present invention, the number of internal cavities of the light scattering spherical particles is not particularly limited, and may be, for example, a single cavity or two or more multiple cavities. When a plurality of cavities are formed, the surface area S2 is a surface area of the entire inner cavity.

The light scattering spherical particles may have various radii depending on the thickness of the desired antiglare coating or the specific application. For example, 0.1 to 10 占 퐉. In order to improve the visibility of the laser pointer and improve the anti-scattering property, it is preferable to form the surface roughness in the above range.

The size of the internal cavity of the light scattering spherical particle is appropriately selected according to the size of the light scattering spherical particle. For example, the inner cavity may be 100 to 300 nm in diameter. In the above range, the value can be selected to satisfy the expression (1), and the effect of improving the visibility of the laser pointer in the above range can be maximized.

In the present invention, if necessary, the light scattering spherical particles may further have a porous structure on the outer surface. By providing a porous structure on the outer surface, not only the scattering effect of the laser light can be doubled, but also the anti-glare property can be further improved.

The light scattering spherical particles may be formed of silica or a polymer, and the polymer used in the art may be used without any particular limitation. Examples of the polymer include acrylic, polystyrene, and melamine resins, which may be used alone or in combination of two or more.

In the present invention, if necessary, the light scattering spherical particles may be formed including a light luminescent material. The light-luminescent material according to the present invention refers to a substance stimulated by light and emits light. The light-scattering spherical particle includes a photo-luminescent material, and thus the light-receiving region receives the laser light of the curable liquid- The visibility of the pointer can be remarkably improved through the photoluminescence reaction in which the light is emitted. The light-scattering spherical particles according to the present invention may be formed of a photoluminescent material itself depending on the type of the photoluminescent material, and the photoluminescent material may be formed or coated by mixing with other materials .

The luminous luminescent material according to the present invention may be appropriately selected according to the wavelength of laser light used, for example, a luminous luminescent pigment, a luminous luminescent dye or a mixture thereof. More specific examples include lanthanide complexes, organic phosphors, inorganic phosphors, and photoluminescence quantum dots. These may be used alone or in combination of two or more.

The lanthanide complex of the present invention is a compound containing a lanthanide series metallic element. The lanthanide series metallic element is not particularly limited, and examples thereof include europium, terbium, dysprosium and samarium, It can be europium.

Examples of the europium complex include tris (dibenzoylmethane) mono (1,10-phenanthroline) europium (III) (Eu (DBM) ₃ Phen); Tris (dynaphthylmethane) mono (1,10-phenanthroline) europium (III) (Eu (dnm) ₃ phen); BaMgAl ₁₀ O ₁₇ : Eu, Mn; Sr ₁₀ (PO ₄ ) ₆ Cl ₂ : Eu.

The luminous luminescence quantum dot particles according to the present invention may be quantum dot particles, quantum dot containing particles or a mixture thereof.

The quantum dot is a nano-sized semiconductor material. The atoms form molecules, and the molecules form a cluster of small molecules called clusters to form nanoparticles. These nanoparticles are called quantum dots, especially when they have semiconductor properties.

The quantum dots emit energy according to the corresponding energy bandgap when they reach the excited state from the outside.

The quantum dot particles can be synthesized by a wet chemical process, an organometallic chemical vapor deposition process, or a molecular beam epitaxy process. A wet chemical process is a method of growing particles by adding a precursor material to an organic solvent. When the crystal grows, the organic solvent is naturally coordinated on the surface of the quantum dot crystal to act as a dispersing agent to control crystal growth. Therefore, the metal organic chemical vapor deposition (MOCVD) or molecular beam epitaxy (MBE) epitaxy), it is possible to control the growth of nanoparticles through an easier and less expensive process.

The quantum dot particle according to the present invention is not particularly limited as long as it is a quantum dot particle capable of emitting light by stimulation with light, for example, a II-VI group semiconductor compound; III-V semiconductor compound; Group IV-VI semiconductor compounds; Group IV elements or compounds containing them; And combinations thereof. &Lt; Desc / Clms Page number 7 &gt;

Wherein the II-VI group semiconductor compound is selected from the group consisting of CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, ZnO, HgS, HgSe, HgTe, and mixtures thereof; Trivalent compounds selected from the group consisting of CdSeS, CdSeTe, CdSTe, ZnSeS, ZnSeTe, ZnSTe, HgSeS, HgSeTe, HgSTe, CdZnS, CdZnSe, CdZnTe, CdHgS, CdHgSe, CdHgTe, HgZnS, HgZnSe, HgZnTe and mixtures thereof; And a gallium nitride compound selected from the group consisting of CdZnSeS, CdZnSeTe, CdZnSTe, CdHgSeS, CdHgSeTe, CdHgSTe, HgZnSeS, HgZnSeTe, HgZnSTe, , GaP, GaAs, GaSb, AlN, AlP, AlAs, AlSb, InN, InP, InAs, InSb, and mixtures thereof; A trivalent compound selected from the group consisting of GaNP, GaNAs, GaNSb, GaPAs, GaPSb, AlNP, AlNAs, AlNSb, AlPAs, AlPSb, InNP, InNAs, InNSb, InPAs, InPSb, GaAlNP and mixtures thereof; And a silicate compound selected from the group consisting of GaAlNAs, GaAlNSb, GaAlPAs, GaAlPSb, GaInNP, GaInNAs, GaInNSb, GaInPAs, GaInPSb, InAlNP, InAlNAs, InAlNSb, InAlPAs, InAlPSb, , The IV-VI group semiconductor compound is selected from the group consisting of SnS, SnSe, SnTe, PbS, PbSe, PbTe, and mixtures thereof; Ternary compounds selected from the group consisting of SnSeS, SnSeTe, SnSTe, PbSeS, PbSeTe, PbSTe, SnPbS, SnPbSe, SnPbTe, and mixtures thereof; And a silane compound selected from the group consisting of SnPbSSe, SnPbSeTe, SnPbSTe, and mixtures thereof. The Group IV element or a compound containing the Group IV element may be selected from the group consisting of Si, Ge, &Lt; / RTI &gt; And these elemental compounds selected from the group consisting of SiC, SiGe, and mixtures thereof.

The quantum dots may have a homogeneous single structure or a dual structure of a core-shell. In the latter case, the material forming each core and the shell may be a homogeneous single structure or a core- And may be made of other semiconductor compounds. However, the energy band gap of the shell material may be larger than the energy band gap of the core material. For example, when a quantum dot having a core-shell structure of CdSe / ZnS is to be obtained, (CH ₃ ) ₂ Cd (dimethyl cadmium), TOPSe (trioctylphosphine selenide) are added to an organic solvent using TOPO (trioctylphosphine oxide) The precursor material corresponding to the core (CdSe) is injected to generate crystals. After maintaining the crystal at a high temperature for a predetermined time to grow crystals to a predetermined size, a precursor material corresponding to the shell (ZnS) CdSe / ZnS quantum dots capped with TOPO can be obtained by forming a shell on the surface of the core.

The quantum dot containing particles according to the present invention include inorganic core particles or at least one quantum dot particle bonded to the surface of the polymer core particles.

The number of quantum dot particles introduced into the surface of the core particles of the quantum dot containing particles according to the present invention is not particularly limited and may be, for example, 1 to 8,200,000, preferably 10 to 640,000.

The inorganic core particles may be silica, alumina _{(Al 2 O 3, AlO 2} ), titanium dioxide or zinc dioxide. Alternatively, the polymer core particles may be polystyrene or polymethylmethacrylate. The diameter of the core particles is not particularly limited, and may be, for example, 2 to 1,000 mu m.

The core particles and the quantum dot particles may be bonded by covalent bonding, ionic bonding or physical adsorption. At this time, the covalent bond may be formed by a functional group that includes at least one atom of sulfur, nitrogen, or phosphor that binds to the quantum dot particle on one side and binds to the core particle on the other side. The functional group may be a silane group, an amino group, a sulfonic group, a carboxyl group or a hydroxy group.

The maximum excitation wavelength or absorption wavelength for emitting light by the luminous luminescent material according to the present invention may vary depending on the material to be used and therefore can not be collectively limited.

For example, the maximum excitation wavelength of the lanthanide complex, the organic phosphor and the inorganic phosphor is not particularly limited and may be, for example, not in the visible light range, more specifically 450 nm or less, and preferably 420 nm or less. This is related to the laser light of the used laser pointer and the light source of the display. If the wavelength of the light is more than 450 nm, the light source is a light source in the visible light region. Since the excitation wavelength is not limited to the visible light region, the lower limit of the excitation wavelength is not particularly limited. For example, the excitation wavelength may be 350 nm. However, the excitation wavelength may vary depending on the material used.

It is also preferable that the absorption wavelength of the luminous luminescence quantum dot particle is not the wavelength of the visible light region, for example, 350 to 450 nm in order to suppress the light luminescence layer from emitting light by the light source of the display.

In another aspect of the present invention, even if the absorption wavelength of the luminous luminescence quantum dot particle is a wavelength in the visible light region, it is acceptable if the light emission by the light source of the display does not hinder the visibility of the laser pointer. To 650 nm.

The light scattering spherical particles may be contained in an amount of 0.1 to 30% by weight, preferably 0.1 to 10% by weight, based on the total weight of the anti-glare coating composition. If the content is less than 0.1% by weight, improvement in laser visibility and retardation may not be sufficiently exhibited, and it may be difficult to ensure sufficient surface hardness of the antiglare coating. When the content exceeds 30% by weight, And the like.

The antiglare coating composition of the present invention may contain, in addition to the above-mentioned light-scattering spherical particles, components used in the production of a diaphragm film commonly used in the art. For example, it may further include a polymerizable compound, a photopolymerization initiator, and a solvent.

The polymerizable compound may be a photopolymerizable (meth) acrylate oligomer, a (meth) acrylate monomer, or a mixture thereof, which is known in the art as a component for forming a binder resin of an antiglare coating and improving surface hardness .

Examples of the (meth) acrylate oligomer include polyester (meth) acrylates which can be obtained by esterifying a polyhydric alcohol, a polyvalent carboxylic acid and / or an anhydride thereof with acrylic acid; Urethane (meth) acrylate obtained by reacting a polyhydric alcohol, a polyvalent isocyanate and a hydroxyl group-containing (meth) acrylate; Polysiloxane poly (meth) acrylate; May be used alone or in combination of two or more.

(Meth) acrylate monomers include monofunctional (meth) acrylate monomers known in the art. Specific examples of the (meth) acrylate monomers include (meth) acrylates such as methyl (meth) acrylate, allyl (meth) acrylate, 2- ethoxyethyl (meth) acrylate, isodecyl (Meth) acrylate, hydroxypropyl (meth) acrylate, hydroxybutyl (meth) acrylate, hydroxybutyl (meth) acrylate, (Meth) acrylate, phenoxyethyl (meth) acrylate, stearyl (meth) acrylate, tetrapurfuryl (meth) acrylate, isobonyl Monofunctional monomers such as phenoxybenzyl (meth) acrylate; Butanediol di (meth) acrylate, 1,4-butanediol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, ethylene glycol di (meth) acrylate, bisphenol A- Acrylate, diethylene glycol di (meth) acrylate, diethylene glycol di (meth) acrylate, triethylene glycol di (meth) acrylate, polyethylene glycol di (meth) acrylate, propylene glycol di (Meth) acrylate, ethylene oxide modified di (meth) acrylate, neopentyl glycol di (meth) acrylate, dicyclopentanyl di (meth) acrylate, caprolactone modified dicyclopentenyl (Meth) acrylates such as bis (2-hydroxyethyl) isocyanurate di (meth) acrylate, di (acryloxyethyl) isocyanurate, allylcyclohexyl di (Meth) acrylate, neopentyl glycol-modified trimethylolpropane di (meth) acrylate, adamantanedi (meth) acrylate, and the like Bifunctional monomers; (Meth) acrylate such as trimethylolpropane tri (meth) acrylate, dipentaerythritol tri (meth) acrylate, propionic acid modified dipentaerythritol tri (meth) acrylate, pentaerythritol tri Trifunctional monomers such as tri (meth) acrylate, tris (2-hydroxyethyl) isocyanurate tri (meth) acrylate, tris (acryloxyethyl) isocyanurate, glycerol tri ; Tetrafunctional monomers such as diglycerin tetra (meth) acrylate, pentaerythritol tetra (meth) acrylate, and ditrimethylol propane tetra (meth) acrylate; Pentafunctional monomers such as dipentaerythritol penta (meth) acrylate and propionic acid-modified dipentaerythritol penta (meth) acrylate; And hexafunctional monomers such as dipentaerythritol hexa (meth) acrylate and caprolactone-modified dipentaerythritol hexa (metha) acrylate. These may be used alone or in combination of two or more. In the present invention, (meth) acrylate is a term which simultaneously refers to acrylate, methacrylate or both.

The polymerizable compound may be contained in an amount of 10 to 90% by weight, preferably 20 to 80% by weight, based on the total weight of the anti-glare coating composition. When the content is less than 10% by weight, coating with a desired thickness is difficult, and sufficient surface hardness of the antiglare coating may not be secured. When the content is more than 90% by weight, viscosity of the coating composition may be increased and coating property may be deteriorated.

The photopolymerization initiator is a component for improving the curing efficiency and can be used without any particular limitation as long as it is used in the art. Examples thereof include benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin-n-butyl ether, benzoin isobutyl ether, acetophenone, -Methylacetophenone, 2,2-dimethoxy-2-phenylacetophenone, 2,2-diethoxy-2-phenylacetophenone, 4-chronoloacetophenone, 4,4-dimethoxyacetophenone, Hydroxy-2-methyl-1-phenyl-1-one, 1-hydroxycyclohexyl phenyl ketone, 4-hydroxycyclophenyl ketone, 2 Methyl-1- [4- (methylthio) phenyl] -2-morpholino-propan-1-one, 4- (2-hydroxyethoxy) phenyl- 2- , Benzophenone, p-phenylbenzophenone, 4,4-diaminobenzophenone, 4,4'-diethylaminobenzophenone, dichlorobenzophenone, anthraquinone, 2-methyl anthraquinone, 2- -t-butyl anthraquinone, 2-amino anthraquinone, 2- Thioxanthone, 2-ethylthioxanthone, 2-chlorothioxanthone, 2,4-dimethylthioxanthone, 2,4-diethylthioxanthone, benzyldimethylketal, diphenylketone benzyldimethylketal, acetophenone Dimethylaniline benzoate, oligo [2-hydroxy-2-methyl-1- (4- (1-methylvinyl) phenyl) propanone], 2,4,6-trimethylbenzoyldiphenylphosphine Oxides, fluorenes, triphenylamines, carbazoles, and the like. Further, commercially available products such as Darocur 1173, Igacure 184, Igacure 907 and Igacure 1700 (manufactured by Ciba) can also be used. These may be used alone or in combination of two or more.

The photopolymerization initiator may be included in an amount of 0.05 to 10% by weight based on the total weight of the anti-glare coating composition. If the content is less than 0.05% by weight, the curing rate may be lowered. If the content is more than 10% by weight, cracking may occur in the overbreaking coating.

The solvent is not particularly limited and may be a solvent commonly used in the art. Examples of the solvent include alcohol solvents such as methanol, ethanol, isopropanol, butanol, methylcellosolve, and ethylsulosolve; Ethyl acetate, propyl acetate, n-butyl acetate, tertiary butyl acetate, methyl cellosolve acetate, ethyl cellosolve acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, methoxy Acetate solvents such as butyl acetate and methoxypentyl acetate; Ether solvents such as diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol dipropyl ether, diethylene glycol dibutyl ether and propylene glycol monomethyl ether; Ketone solvents such as methyl ethyl ketone, methyl butyl ketone, methyl isobutyl ketone, diethyl ketone, dipropyl ketone, and cyclohexanone; Hexane solvents such as hexane, heptane and octane; And aromatic hydrocarbon solvents such as benzene, toluene and xylene. These may be used alone or in combination of two or more.

The solvent may be included in an amount of 10 to 90% by weight based on the total weight of the anti-glare coating composition. If the content is less than 10% by weight, the viscosity may be high and the workability may be deteriorated. If the content is more than 90% by weight, it may take a long time in the drying and curing process.

The antiglare coating composition of the present invention may further contain at least one additive such as an antioxidant, an ultraviolet absorber, a light stabilizer, a surfactant, a leveling agent, a lubricant and an antifouling agent, if necessary, together with the above components.

The present invention provides an antiglare film produced using the above anti-glare coating composition.

The antiglare film according to the present invention comprises: a substrate; And an antiglare coating formed on the substrate and formed from the composition described above.

The base material is not particularly limited as long as it is a film having excellent transparency. Specifically, polyester resins such as polyethylene terephthalate, polyethylene isophthalate, polyethylene naphthalate and polybutylene terephthalate; Cellulose resins such as diacetylcellulose, triacetylcellulose, acetylcellulose butylate, isobutylester cellulose, propionylcellulose, butyrylcellulose, and acetylpropionylcellulose; Polycarbonate resin; Acrylic resins such as polymethyl (meth) acrylate and polyethyl (meth) acrylate; Styrene resins such as polystyrene and acrylonitrile-styrene copolymer; Polyolefin resins such as polyethylene, polypropylene, polyolefins having a cyclo or norbornene structure, and ethylene-propylene copolymers; Vinyl chloride resin; Amide resins such as nylon and aromatic polyamide; Imide resins such as polyetherimide and polyimide; Polyether sulfone type resin; Sulfone based resin; Polyether ketone resin; Polyether ether ketone resin; A sulfided polyphenylene resin; Ethylene-vinyl acetate resin; Polyvinyl acetal resin; Polyvinyl alcohol-based resin; Vinylidene chloride resins; Vinyl butyral resin; Allylate series resin; Polyoxymethylene type resin; And a film composed of a thermoplastic resin such as an epoxy resin. These may be unstretched, uniaxially or biaxially stretched films. Of these, monoaxially or biaxially stretched polyester films excellent in transparency and heat resistance, triacetylcellulose films having good transparency and no optical anisotropy are preferable.

The thickness of the base material is not particularly limited and may be, for example, 8 to 1,000 μm, preferably 40 to 100 μm.

The antiglare coating formed on one side of the substrate is a layer having antifogging properties and is a layer for improving the visibility of the laser pointer according to the present invention.

The anti-glare coating may preferably be formed with surface irregularities by light scattering spherical particles on the surface not to be bonded to the substrate. It is possible to further improve the retardation and the visibility of the laser pointer by the surface unevenness.

The method of forming the anti-glare coating is not particularly limited. Specifically, the antiglare coating composition may be coated on the substrate, followed by drying and curing. The application may be carried out by a known method such as die coater, air knife, Meyer bar, reverse roll, spray, blade, casting, gravure, spin coating and the like. The coating thickness may be from 1 to 50 mu m or less after drying. The drying can be carried out in such a manner that the volatile components are volatilized at a temperature of 30 to 150 DEG C for 1 second to 2 hours, preferably 5 seconds to 1 hour.

When drying is complete, it is cured by irradiation with ultraviolet rays. For curing, a high-pressure mercury lamp, a non-electrode lamp, a xenon lamp, a metal halide lamp or the like can be used, and the irradiation dose is preferably about 0.01 to 10 J / cm 2, preferably 0.1 to 2 J / cm 2.

(Ra) of 0.05 占 퐉? Ra? 0.3 占 퐉 and an average spacing (Sm) of surface irregularities of 30 占 퐉? Sm? 100 占 퐉 in the case where the antiglare film is provided on the surface of the antiglare film, The average inclination angle [theta] a may be 0.5 [deg.] &Amp;thetas; a &amp;le; 5 DEG. It can exhibit excellent anti-glare properties in the above range.

The antiglare film of the present invention can be used by being bonded to another optical film. The optical film is not particularly limited. For example, the antiglare film may be a polarizer, a retarder, and the retarder may be a patterned retarder.

The polarizing plate may have a conventional structure in which a polarizer protective film is laminated on at least one side of the polarizer, and the antiglare film may be provided on at least one surface of the polarizing plate having such a structure, that is, on at least one surface of the polarizer or the polarizer protective film.

The retarder may be a conventional structure in which a phase difference layer is laminated on one side of a substrate, and in the case of a patterned retarder, a structure in which a patterned liquid crystal layer is laminated on one side of an orientation film.

The antiglare film according to the present invention may be provided alone or in combination with another optical film such as a polarizing plate or a retarder so as to be embedded in an image display device or attached to a window surface.

An image display device is a liquid crystal display device (LCD) of various driving methods such as a reflection type, a transmission type and a transflective type liquid crystal display (LCD) and a TN type, STN type, OCB type, HAN type, VA type, And may be suitably used for an image display device such as a plasma display device (PDP), a field emission device (FED), an organic light emitting diode device, an inorganic light emitting diode device, and an electronic paper.

It is to be understood that both the foregoing general description and the following detailed description of the present invention are exemplary and explanatory and are intended to be illustrative of the invention and are not intended to limit the scope of the claims. It will be apparent to those skilled in the art that such variations and modifications are within the scope of the appended claims.

Example

A composition for antiglare coating was prepared (H: haze (measured on the basis of JIS-K7361)) with the components and compositions shown in Table 1 below.

Test Example

(One) laser  Pointer visibility evaluation

When an antiglare film was prepared using the coating composition prepared in Examples and Comparative Examples and attached to the upper surface of the display panel and then the display was changed to a white mode and then a 580 nm laser pointer was irradiated on the panel at a 60 degree angle, The visibility of the laser pointer was evaluated at the front of the panel.

&Amp; cir &amp;: The light of the laser pointer is brightly recognized.

A: The position of the laser pointer can be recognized.

?: The position of the laser pointer is recognized but not clear.

X: The position of the laser pointer is not confirmed.

division Laser Pointer Visibility (580nm) Example 1 ◎ Example 2 ◎ Example 3 ◎ Example 4 ○ Comparative Example 1 △ Comparative Example 2 X Comparative Example 3 X Comparative Example 4 △ Comparative Example 5 △

Referring to Table 2, it can be seen that the embodiments have better laser pointer visibility than the comparative examples.

However, in Example 4, it was confirmed that the porous structure (surface unevenness) was not provided on the surface of the light scattering particles, and the visibility of the laser pointer was slightly lowered.

Claims (11)

An antiglare coating forming composition comprising a light scattering spherical particle having a cavity therein and wherein a sum (St) of an outer surface area (S1) and a surface area (S2) of the inner cavity satisfies the following formula:
[Equation 1]
1.75 * (4? R ² )? St <10.75 * (4? R ² )
(Where r is the radius of the light scattering spherical particles).
The anti-glare coating composition of claim 1, wherein the internal cavity has a diameter of 100 to 300 nm.
The antiglare coating forming composition according to claim 1, wherein the radius of the light scattering spherical particles is 0.1 to 10 μm.
The antiglare coating-forming composition of claim 1, wherein the light scattering spherical particles further comprise a porous structure on the exterior surface.
The antiglare coating-forming composition according to claim 1, wherein the light scattering spherical particles are formed of silica or a polymer.
The antiglare coating-forming composition according to claim 1, wherein the light scattering spherical particles are formed by incorporating a photo-luminescent material.
The anti-glare coating-forming composition according to claim 1, used in the production of a film for enhancing laser pointer visibility.
materials; And
An antiglare film formed on the substrate and having an antiglare coating formed from the composition of any one of claims 1 to 7.
The antiglare film according to claim 8, wherein the antiglare coating has irregularities on its surface by the light scattering spherical particles.
The antiglare film according to claim 8, wherein the antiglare film is attached to a polarizing plate or retarder.
An image display apparatus comprising the anti-ghost film of claim 8.