KR101778204B1 - Asphalt wateproofing composition, method for producing the same and construction method using the same. - Google Patents

Asphalt wateproofing composition, method for producing the same and construction method using the same. Download PDF

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KR101778204B1
KR101778204B1 KR1020160003148A KR20160003148A KR101778204B1 KR 101778204 B1 KR101778204 B1 KR 101778204B1 KR 1020160003148 A KR1020160003148 A KR 1020160003148A KR 20160003148 A KR20160003148 A KR 20160003148A KR 101778204 B1 KR101778204 B1 KR 101778204B1
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waterproof layer
asphalt
waterproof
nonwoven fabric
weight
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KR20170083813A (en
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양재봉
최영식
서용환
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한국석유공업 주식회사
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/53Phosphorus bound to oxygen bound to oxygen and to carbon only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof

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Abstract

The method for producing a high-adhesion asphalt waterproofing composition according to the present invention comprises: an initial mixing step of transferring oil and vegetable oil to a reforming tank at a temperature of 50 to 60 ° C, mixing and then charging asphalt at 130 to 150 ° C; A reforming agent mixing step of adding and dissolving a rubber-based polymer modifier maintained at 180 to 190 ° C; A pressure-sensitive adhesive mixing step of injecting and dissolving an adhesive; Adding a polyphosphoric acid to dissolve the polyphosphoric acid; A coupling agent for injecting and dissolving a coupling agent; A filler-carbon black mixing step of continuously charging and mixing a filler and carbon black; And a flowable additive mixing step of adding the flowable additive.
The method for manufacturing the waterproof sheet of the present invention using the high-adhesion asphalt waterproofing composition of the present invention comprises a first waterproof layer 110 formed of any one of PP nonwoven fabric, PET nonwoven fabric, film, release film, Talc or Sand; A second waterproof layer (120) formed on the top surface of the first waterproof layer (110) and formed of any one of asphalt and high adhesion asphalt waterproof compositions; A third waterproof layer 130 formed on the upper surface of the second waterproof layer 120, the third waterproof layer 130 being formed of one of PP nonwoven fabric and PET nonwoven fabric; A fourth waterproof layer 140 formed as an asphalt on the upper surface of the third waterproof layer 130; And a fifth waterproof layer 150 formed on the upper surface of the fourth waterproof layer 140, such as PET nonwoven fabric, PP nonwoven fabric, film, high adhesion asphalt waterproofing agent, talc, sand or aggregate.
The high-adhesion asphalt waterproofing composition of the present invention uses environmentally friendly materials, so that environmental pollution can be minimized.
In addition, since the waterproof sheet of the present invention can be applied in the field without heating equipment, it is easy to construct, can shorten the construction period, and is excellent in adhesion even in the presence of moisture, foreign matter and latency on the waterproof surface.

Description

Technical Field [0001] The present invention relates to a high-adhesion asphalt waterproofing composition, a high-adhesion asphalt waterproofing composition, and a waterproof sheet using the same. BACKGROUND ART

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a construction material field, and more particularly, to an asphalt waterproofing composition, a manufacturing method thereof, and a waterproof sheet using the same.

During the early curing process, concrete is hydrated due to hydration reaction of cement and water, and drying shrinkage occurs due to hydration heat.

Dry shrinkage of concrete induces cracks in concrete, and water penetration through cracks causes deterioration of concrete and corrosion of steel bars.

Particularly, concrete structures exposed to the outside or in contact with water are subject to rapid deterioration and corrosion unless waterproofing is performed separately.

The waterproofing of concrete structures is an important factor for extending the life of the structure, and waterproofing and waterproofing are widely used.

The coating waterproofing method and the sheet waterproofing method cause a great difference in waterproof quality depending on the degree of removal of moisture, foreign matter, and latency of concrete waterproofing surface.

However, it is practically impossible to completely remove moisture, foreign matter and rattens in the field.

In addition, the coating waterproofing method and the sheet waterproofing method are problematic in terms of environmental pollution during construction because many volatile industrial solvents are used.

The coating waterproofing method has an excellent ductility of the material and excellent thermal deformation and elongation, but the rigidity of the waterproof layer is weak and the deterioration rapidly occurs when exposed to atmosphere for a certain period of time.

In addition, the sheet waterproofing method is to maximize adhesiveness by heating the waterproof paper made in a certain area in the field. At this time, there is a risk of fire due to the heating equipment used in the field.

SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and it is an object of the present invention to provide a waterproof sheet made of a high-adhesion asphalt waterproofing composition and capable of being installed on site without heating equipment.

In addition, a waterproof sheet which is excellent in adhesion to watery surfaces and which can minimize environmental pollution by using environmentally friendly materials is proposed.

In order to solve the above problems, the high-adhesion asphalt waterproofing composition of the present invention comprises 40 to 60% by weight of asphalt; 4 to 6% by weight of oil; 12 to 16 wt% vegetable oil; 3 to 7% by weight of a rubber-based polymer modifier; 7 to 11% by weight of an adhesive; 5 to 9% by weight filler; 1 to 5% by weight of carbon black; 1 to 5% by weight of a coupling agent; 0.5 to 1.5% by weight of polyphosphoric acid (PPA); And 1 to 5 wt% of a flowable additive.

Preferably, the asphalt is an asphalt having an intrusion degree of 60 to 100 and a softening point of 42 to 52 ° C.

The asphalt is preferably an asphalt having an intrusion degree of 0 to 40 and a softening point of 65 to 130 ° C.

It is preferable that the oil is any one of paraffin, naphthenic, aromatic and oils of Vacco High Boiling Point Gas Oil (VHGO).

Preferably, the vegetable shell oil is extracted from a natural plant, which is a phenol-based monomer compound composed of a mixture of cardadol, cardol, and anacarboxylic acid.

The rubber-based polymer modifier may be at least one member selected from the group consisting of styrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS), styrene-butadiene-RUBBER (SBR), styrene-butadiene (SB), styrene- It is preferably any one of chloroprene rubber (CR) and butyl rubber.

Preferably, the pressure-sensitive adhesive is any one of olefinic and aromatic black-brown thermoplastic resins, polybutene, and natural liquid rubber.

The filler is calcium carbonate having a specific gravity of 2.7, a particle size of 1 to 50 占 퐉, a thermal conductivity of 0.006 to 0.008 cal / cm < 2 > Magnesium oxide having a specific gravity of 3.4, a particle size of 200 to 325 mesh, a thermal conductivity of 0.0002 to 0.0005 cal / cm < 2 > And bentonite having a surface area of 50 to 120 m < 2 > / g per unit weight, a moisture content of 10% or less, and a degree of swelling of 10 ml / Or a mixture of two or more of them.
The carbon black is extracted by incomplete combustion or pyrolysis of Fluid Catalytic Cracking-oil (FCC-oil) or Creosote and is adsorbed at 50 to 56 mg / g of iodine adsorption; DBP adsorption 65-72 ml / g; BET Surface Area 55 ~ 60 ㎡ / g; Tinting Strength 40 ~ 50%; Pour Density 350 to 360 kg / m 2; , And the Ash content is preferably 11.3 to 14.6 wt% based on the weight of the carbon black.

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The coupling agent is a chemical substance having two different reactors, organic and inorganic, in the same molecule, and has a molecular weight of 200 to 400; Boiling Point 200 ~ 220 ℃; Active content is 99%; Refracive Index (25 캜) 1.42 ~ 1.43; , A density of 0.94 to 0.95 mg / m 3; Zirconate type, Chromium type, and Silane type.

The polyphosphoric acid (PPA) has a viscosity of at least 800 cPs at room temperature, a P 2 O 5 content of 80% or more, a H 3 PO 4 content of 100 to 120%, a moisture content of 0.001 to 0.01%, a molecular weight of 250 Or more.

The fluidity additive has a specific gravity (15/4 ° C) of 0.83 to 0.92, a flash point of 200 ° C, a pour point of -30 to -10 ° C, a Paraffin type (CnH 2n +2 ) and a Naphtene (C 2 H 2n ) Mixture.

The olefin-based or thermoplastic resin pressure-sensitive adhesive is preferably prepared by polymerizing an unsaturated hydrocarbon in a high-temperature pyrolysis oil as an acidic catalyst.

The aromatic black brown thermoplastic resin is preferably any one of C5 hydrocarbon resin, C9 petroleum resin, C9 hydrogenated resin, C5 and C9 copolymer resin and Polyterpene hydrocarbon resin.

The polybutene tackifier preferably has a molecular weight of 250 to 2,500, a viscosity of 20 to 7200 cSt, a pour point of -45 to -1 DEG C, a loss of evaporation of 0.04 to 0.8 wt%, and a moisture content of 10 to 40 wtppm.

The natural liquid rubber adhesive preferably has a TSC of 60 to 90%, NH 3 of 0.3 to 1.0%, a pH of 10 to 12, and a viscosity of 500 to 2,200 cPs.

In the method for producing a high-adhesion asphalt waterproofing composition of the present invention, the oil and the vegetable shell oil are transferred to a reforming tank at a temperature of 50 to 60 ° C, mixed and then mixed with the asphalt at 130 to 150 ° C for mixing. A reforming agent mixing step of adding the rubber-based polymer modifier maintained at 180 to 190 ° C to dissolve the modifier; A pressure-sensitive adhesive mixing step of injecting and dissolving the pressure-sensitive adhesive; A polyphosphoric acid mixing step of adding and dissolving the polyphosphoric acid; Introducing a coupling agent to dissolve the coupling agent; A filler-carbon black mixing step of continuously injecting and mixing the filler and the carbon black; And a flowable additive mixing step of adding the flowable additive.

The waterproof sheet 100 of the embodiment using the highly adhesive asphalt waterproofing composition prepared by the method of the present invention for producing a high-adhesion asphalt waterproofing composition of the present invention is a waterproof sheet 100 of the first embodiment, which is made of PP nonwoven fabric, PET nonwoven fabric, film, release film, A waterproof layer 110; A second waterproof layer (120) formed on the upper surface of the first waterproof layer (110), the waterproof layer (120) being formed of either asphalt or the high adhesion asphalt waterproof composition; A third waterproof layer 130 formed on the upper surface of the second waterproof layer 120, the third waterproof layer 130 being formed of either PP nonwoven fabric or PET nonwoven fabric; A fourth waterproof layer 140 formed as an asphalt on the upper surface of the third waterproof layer 130; And a fifth waterproof layer 150 formed on the upper surface of the fourth waterproof layer 140, such as PET nonwoven fabric, PP nonwoven fabric, film, high adhesion asphalt waterproofing agent, Talc, sand or aggregate.

The waterproof sheet 100 of another embodiment using the high-adhesion asphalt waterproofing composition prepared by the method of the present invention for manufacturing a high-adhesion asphalt waterproofing composition is formed on the lower surface of the first waterproof layer 110, A waterproof layer 111; The bottom surface waterproofing layer 112 is formed of a PP nonwoven fabric, a PET nonwoven fabric, a release film, a releasing paper, Talc or Sand on the lower surface of the waterproof layer 111.

The thickness of the waterproof layer 111 is preferably 0.5 to 2.0 mm.

The waterproof sheet 100 according to an embodiment of the present invention preferably has a thickness of 2.0 to 5.0 mm, a width of 1 m, and a length of 10 to 30 m.

The waterproof sheet 100 according to another embodiment of the present invention preferably has a thickness of 2.0 to 5.0 mm, a width of 1 m, and a length of 10 to 30 m.

Since the waterproofing composition of the present invention uses an environmentally friendly material, environmental pollution can be minimized.

In addition, since the waterproof sheet of the present invention can be applied on site without heating equipment, it is easy to construct and the construction period can be shortened.

The waterproof sheet of the present invention is excellent in adhesion even in the presence of moisture, foreign matter and latency on the waterproof surface.

1 is a sectional view of a waterproof sheet according to an embodiment of the present invention;
2 is a sectional view of a waterproof sheet according to another embodiment of the present invention.

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, embodiments of a high-adhesion asphalt waterproofing composition and a waterproof sheet using the same according to the present invention will be described in detail with reference to the accompanying drawings. In the following description with reference to the accompanying drawings, And redundant explanations thereof will be omitted.

It is also to be understood that the terms first, second, etc. used hereinafter are merely reference numerals for distinguishing between identical or corresponding components, and the same or corresponding components are defined by terms such as first, second, no.

In addition, the term " coupled " is used not only in the case of direct physical contact between the respective constituent elements in the contact relation between the constituent elements, but also means that other constituent elements are interposed between the constituent elements, Use them as a concept to cover each contact.

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, a high-adhesion asphalt waterproofing composition, a manufacturing method thereof, and a waterproof sheet using the same according to an embodiment of the present invention will be described in detail with reference to the accompanying tables and drawings.

The high-adhesion asphalt waterproofing composition according to the present invention comprises 40 to 60% by weight of asphalt; 4 to 6% by weight of oil; 12 to 16 wt% vegetable oil; 3 to 7% by weight of a rubber-based polymer modifier; 7 to 11% by weight of an adhesive; 5 to 9% by weight filler; 1 to 5% by weight of carbon black; 1 to 5% by weight of a coupling agent; 0.5 to 1.5% by weight of polyphosphoric acid (PPA); And 1 to 5 wt% of a flowable additive.

In this case, environmental pollution can be minimized because an environmentally friendly oil which has a high solid content and can improve the adhesive strength is used.

The oil also has a functional group such as an aliphatic unsaturated carbon, and an alkyl chain can add flexibility to the resin.

Asphalt is preferably an asphalt having an intrusion degree of 60 to 100 and a softening point of 42 to 52 ° C.

Asphalt is preferably an asphalt having an intrusion degree of 0 to 40 and a softening point of 65 to 130 ° C.

The oil is preferably any one of paraffinic, naphthenic, aromatic and oils of Vacco High Boiling Point Gas Oil (VHGO).

In this case, the oil has a high solids content, so that the adhesive strength can be improved.

Preferably, the vegetable envelope oil is extracted from a natural plant, which is a phenolic monomer compound composed of a mixture of cardadole, cardol, and anacarboxylic acid.

In this case, it is eco-friendly because it uses a vegetable oil extracted from a natural plant which is not a volatile industrial solvent.

The rubber-based polymer modifier may be at least one selected from the group consisting of styrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS), styrene-butadiene-RUBBER (SBR), styrene-butadiene (SB), styrene- Rubber (CR), and butyl rubber.

The pressure-sensitive adhesive is preferably any one of olefin-based, aromatic-based black-brown thermoplastic resin, polybutene and Natural liquid rubber.

The filler is calcium carbonate having a specific gravity of 2.7, a particle size of 1 to 50 mu m, a thermal conductivity of 0.006 to 0.008 cal / cm < 2 > Magnesium oxide having a specific gravity of 3.4, a particle size of 200 to 325 mesh, a thermal conductivity of 0.0002 to 0.0005 cal / cm < 2 > And bentonite having a surface area of 50 to 120 m < 2 > / g per unit weight, a moisture content of 10% or less, and a degree of swelling of 10 ml / Or a mixture of two or more of them.

In this case, the filler prevents the flowability and is inexpensive and can improve the economical efficiency.
Carbon black is extracted by incomplete combustion or pyrolysis of Fluid Catalytic Cracking-oil (FCC-oil) or Creosote and is adsorbed at 50-56 mg / g iodine; DBP adsorption 65-72 ml / g; BET Surface Area 55 ~ 60 ㎡ / g; Tinting Strength 40 ~ 50%; Pour Density 350 to 360 kg / m 2; , And the Ash content is preferably 11.3 to 14.6 parts by weight based on the weight of the carbon black.

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In this case, carbon black can be recycled as waste because it extracts FCC-oil (Fluid Catalytic Cracking-oil) or Creosote using waste tire.

Coupling agents are chemicals with two different reactors, organic and inorganic, in the same molecule, with molecular weights ranging from 200 to 400; Boiling Point 200 ~ 220 ℃; 99% by weight active ingredient (active ingredient); Refracive Index (25 캜) 1.42 ~ 1.43; , A density of 0.94 to 0.95 mg / m 3; Zirconate type, Chromium type, and Silane type.

In this case, the coupling agent prevents the bond between the organic polymer and the inorganic filler from disintegrating, thereby enhancing the bonding strength and the adhesive strength of the composition.

Polyphosphoric acid (PPA) has a viscosity of 800 cPs or more at room temperature, a P 2 O 5 content of 80% or more, H 3 PO 4 A content of 100 to 120%, a water content of 0.001 to 0.01%, and a molecular weight of 250 or more.

In this case, polyphosphoric acid acts as a crosslinking agent with asphalt as an organic polymer, so that strength, elasticity, heat resistance and chemical resistance are improved.

The fluidity additive is a mixture of Paraffin system (CnH 2n + 2 ) and Naphtene (C 2 H 2n ) system having specific gravity (15/4 ° C) of 0.83 to 0.92 and a flash point of 200 ° C and a pour point of -30 to -10 ° C .

In this case, since the high molecular hydrocarbons obtained by re-distilling oil fractions having high boiling points and washing and separating the lead fractions after decolorization are used, the present asphalt composition material has excellent fluidity and adhesion at low temperatures.

The olefin-based and thermoplastic resin pressure-sensitive adhesives are preferably produced by polymerizing unsaturated hydrocarbons in high-temperature pyrolysis oil as raw materials and using acidic catalysts.

In this case, the adhesives of the ultrasound fin and the thermoplastic resin improve the adhesion of the high-adhesive sealant.

Preferably, the aromatic black thermoplastic resin is any one of C5 hydrocarbon resin, C9 petroleum resin, C9 hydrogenated resin, C5 and C9 copolymer resin and Polyterpene hydrocarbon resin.

The polybutene tackifier preferably has a molecular weight of 250 to 2,500, a viscosity of 20 to 7200 cst, a pour point of -45 to -1 캜, a loss of evaporation of 0.04 to 0.8% by weight, and a moisture content of 10 to 40 ppm by weight.

In this case, the pressure-sensitive adhesive has excellent chemical stability and oxidation stability due to light or heat is improved.
The natural liquid rubber adhesive preferably has a total solid content (TSC) of 60 to 90% by weight, an NH 3 content of 0.3 to 1.0% by weight, a pH of 10 to 12, and a viscosity of 500 to 2,200 cPs .

delete

In this case, the pressure-sensitive adhesive is excellent in chemical resistance and heat resistance, and elasticity and adhesion are improved.

The method for producing a high-adhesion asphalt waterproofing composition according to the present invention comprises: an initial mixing step of transferring oil and vegetable oil to a reforming tank at a temperature of 50 to 60 ° C, mixing and then charging asphalt at 130 to 150 ° C; A reforming agent mixing step of adding and dissolving a rubber-based polymer modifier maintained at 180 to 190 ° C; A pressure-sensitive adhesive mixing step of injecting and dissolving an adhesive; Adding a polyphosphoric acid to dissolve the polyphosphoric acid; A coupling agent for injecting and dissolving a coupling agent; A filler-carbon black mixing step of continuously charging and mixing a filler and carbon black; And a flowable additive mixing step of adding the flowable additive.

In this case, environment-friendly carbon black obtained by incompletely combusting or pyrolyzing the FCC-OIL or creosote recovered from the petroleum is used, and the adhesive and waterproof performance are secured by using the vegetable outer skin, so that environmentally harmful substances can be minimized.

The chemical composition of the vegetable envelope oil is shown in [Figure 1].

[Figure 1]

Figure 112016002709403-pat00001

The method for manufacturing the waterproof sheet of the present invention using the high-adhesion asphalt waterproofing composition of the present invention comprises a first waterproof layer 110 formed of any one of PP nonwoven fabric, PET nonwoven fabric, film, release film, Talc or Sand; A second waterproof layer (120) formed on the top surface of the first waterproof layer (110) and formed of any one of asphalt and high adhesion asphalt waterproof compositions; A third waterproof layer 130 formed on the upper surface of the second waterproof layer 120, the third waterproof layer 130 being formed of one of PP nonwoven fabric and PET nonwoven fabric; A fourth waterproof layer 140 formed as an asphalt on the upper surface of the third waterproof layer 130; And a fifth waterproof layer 150 formed on the upper surface of the fourth waterproof layer 140, such as PET nonwoven fabric, PP nonwoven fabric, film, high adhesion asphalt waterproofing agent, talc, sand or aggregate.

The method for manufacturing a waterproof sheet of another embodiment using the high-adhesion asphalt waterproofing composition of the present invention comprises a waterproof layer 111 formed on the lower surface of the first waterproof layer 110, the waterproof layer 111 being formed of a highly adhesive asphalt waterproof composition; And a bottom surface waterproofing layer 112 formed on the lower surface of the waterproofing layer 111, the surface waterproofing layer 112 being formed of PP nonwoven fabric, PET nonwoven fabric, release film, release paper, Talc or Sand.

In this case, it is general that the first layer of the waterproof sheet is generally a release film. The first layer of the waterproof sheet formed of the release film is attached to the waterproof surface after being removed in the field.

Therefore, the waterproof sheet layer formed of the high-adhesion asphalt composition can be protected from foreign matter until it is transported and adhered to the site to maintain adhesiveness.

In addition, the first waterproof layer 130 facilitates the adjustment of the thickness of the waterproof sheet during production, improves water permeability, and enhances adhesion with the lower highly adhesive asphalt.

The waterproof layer 111 preferably has a thickness of 0.5 to 2.0 mm.

The waterproof sheet 100 according to the embodiment of the present invention preferably has a thickness of 2.0 to 5.0 mm, a width of 1 m, and a length of 10 to 30 m.

In this case, the waterproof sheet is manufactured in the size and thickness to maintain the waterproof performance, so it is easy to carry and install.

In order to verify the effect of vegetable husk oil, the present invention produced a sheet according to the presence or absence of a covering oil and measured the adhesive strength with concrete specimens.

The mixing ratio of the examples in which 10% of the covering oil was added and the blending ratios of the comparative examples were as shown in Table 1 below, and the experiment was conducted in accordance with [KS F 4934].

Mixing ratio division Composition ratio (wt%) Example Comparative Example asphalt 41.65 49 oil 12.75 15 Vegetable envelope oil 15.0 - Modifier 6.8 8 adhesive 8.5 10 Coupling agent 2.55 3 Calcium carbonate 6.8 8 Carbon black 2.55 3 PPA 1.7 2 Flowable additive 1.7 2 The 100 100

Tests were conducted by attaching a sheet prepared by mixing ratios of the above Examples and Comparative Examples to a concrete specimen.

At this time, specimens of dry condition and 95% moisture content of concrete specimens were prepared and subjected to a peel-out test at 25 ° C and an adhesion strength test at 5 ° C to check whether the adhesiveness was maintained at low temperature Respectively.

Table 2 shows the results of the peel-out test at 25 ° C, and it can be confirmed that the adhesive strength of each of Examples is higher than that of Comparative Examples in a dry state and a wet state.

Therefore, the present invention minimizes environmental pollution by using a physical property outer film,

Adhesive strength results Example Comparative Example dry Wet dry Wet Adhesive strength (N / mm 2) 2.1 1.6 1.8 1.4

Table 3 shows the peel-out test results at 5 占 폚. As a result, it can be confirmed that the adhesive strength in the dry state in Examples is superior to that in Comparative Examples.

5 ℃ adhesion strength result Example Comparative Example Adhesion strength (5 占 폚, N / mm2) 2.0 1.6

The sheet using the asphalt waterproofing composition according to the present invention can exhibit the waterproof performance by maintaining the adhesive force even under the environmental condition where the waterproof performance may be lowered.

In particular, when the sheet is produced from the adhesive property of the high-adhesive sealant, the releasability with the lower releasing paper or the release film may be deteriorated.

In particular, when the film is exposed to ultraviolet rays for a long period of time at a high temperature in summer, the temperature rises and it may not be peeled off from the releasing paper and the release film.

Table 4 shows the results of testing the releasability of the waterproof sheet at 30 to 60 ° C. The results were obtained by heating the waterproof sheet using a heater and confirming the releasing performance.

Release performance result Temperature (℃) Whether or not it is 30 Good performance 40 Good performance 50 Good performance 60 Good performance

Further, the asphalt composition according to the present invention is eco-friendly by using vegetable sheath oil and using carbon black extracted from waste tires.

In addition, it is easy to work because it is constructed without special heating device at the time of construction, shortening the working time, and of course there is no risk of topic.

111: lower waterproof layer 112: bottom waterproof layer
100: waterproof sheet 110: first waterproof layer
120: second waterproof layer 130: third waterproof layer
140: fourth waterproof layer 150: fifth waterproof layer

Claims (22)

40 to 60% by weight of asphalt;
4 to 6% by weight of an oil selected from the group consisting of naphthenic, aromatic and Vacco high boiling point gas oil (VHGO);
12 to 16 wt% vegetable oil;
3 to 7% by weight of a rubber-based polymer modifier which is any one of styrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS), styrene-butadiene-RUBBER (SBR) and chloroprene rubber (CR);
7 to 11% by weight of an adhesive;
5 to 9% by weight filler;
1 to 5% by weight of carbon black;
1 to 5% by weight of a coupling agent;
1 to 5% by weight of a polyphosphoric acid (PPA) additive; And 1 to 5 wt% of a flowable additive.
The method according to claim 1,
The asphalt
Wherein the asphalt is an asphalt having an invasion degree of 60 to 100 and a softening point of 42 to 52 ° C.
The method according to claim 1,
The asphalt has an intrusion degree of 0 to 40,
Wherein the asphalt is an asphalt having a softening point of 65 to 130 占 폚.
delete The method according to claim 1,
The vegetable shell oil
Wherein the composition comprises a mixture of carnauba, caradol, cardol, and anacarboxylic acid.
delete The method according to claim 1,
The pressure-
Wherein the composition is one of an olefinic, aromatic black brown thermoplastic resin, polybutene, and natural liquid rubber.
The method according to claim 1,
The filler
Specific gravity 2.7,
Particle size 1 to 50 탆,
Calcium carbonate having a thermal conductivity of 0.006 to 0.008 cal / cm < 2 >
Specific gravity 3.4,
Particle size 200 ~ 325 mesh,
Magnesium oxide having a thermal conductivity of 0.0002 to 0.0005 cal / cm < 2 > And
A surface area per unit weight of 50 to 120 m < 2 > / g,
Moisture content 10% or less,
Bentonite having a swelling degree of 10 ml / 2 g or more; Or a mixture of two or more of them.
The method according to claim 1,
The carbon black is extracted by incomplete combustion or pyrolysis of Fluid Catalytic Cracking-oil (FCC-oil) or Creosote (Creosote)
Iodine adsorption 50 to 56 mg / g;
DBP adsorption 65-72 ml / g;
BET Surface Area 55 ~ 60 ㎡ / g;
Tinting Strength 40 ~ 50%;
Pour Density 350 to 360 kg / m 2; Lt;
Wherein the ash content is 11.3 to 14.6 wt% based on the weight of the carbon black.
delete delete The method according to claim 1,
The flowable additive
The specific gravity (15/4 DEG C) is 0.83 to 0.92,
The flash point is 200 ° C,
Wherein the mixture is a mixture of Paraffin series (CnH 2n + 2 ) and Naphtene (C 2 H 2n ) systems having a pour point of -30 to -10 ° C.
8. The method of claim 7,
The olefin-based and thermoplastic resin pressure-
Characterized in that the asphalt waterproofing composition is produced by polymerizing unsaturated hydrocarbons in pyrolysis oil as an acidic catalyst.
14. The method of claim 13,
The thermoplastic resin
C5 hydrocarbon resin, C9 petroleum resin, C9 hydrogenated resin, C5 & C9 copolymer resin and polyterpene hydrocarbon resin.
8. The method of claim 7,
The polybutene tackifier
Molecular weight of 250 to 2,500,
Viscosity 20 to 7200 cst,
Pour point -45 to -1 ° C,
0.04 to 0.8% by weight in terms of an evaporation loss,
And a water content of 10 to 40 wt. Ppm.
8. The method of claim 7,
The Natural liquid rubber adhesive
The total solid content (TSC) is 60 to 90% by weight,
NH 3 content of 0.3 to 1.0% by weight,
a pH of 10 to 12,
Wherein the viscosity of the asphalt waterproofing composition is 500 to 2,200 cPs.
A process for producing an asphalt waterproofing composition according to any one of claims 1 to 3, 5, 7 to 9, 12 to 16,
Transferring the oil and the vegetable shell oil to a reforming tank at a temperature of 50 to 60 DEG C, mixing the asphalt at 130 to 150 DEG C, and mixing the mixture;
A reforming agent mixing step of adding the rubber-based polymer modifier maintained at 180 to 190 ° C to dissolve the modifier;
A pressure-sensitive adhesive mixing step of injecting and dissolving the pressure-sensitive adhesive;
A polyphosphoric acid mixing step of adding and dissolving the polyphosphoric acid;
Introducing a coupling agent to dissolve the coupling agent;
A filler-carbon black mixing step of continuously injecting and mixing the filler and the carbon black;
And a flowable additive mixing step of adding the flowable additive to the asphalt waterproofing composition.
A waterproof sheet (100) using the asphalt waterproofing composition prepared by the manufacturing method of claim 17,
A first waterproof layer 110 formed of any one of PP nonwoven fabric, PET nonwoven fabric, film, release film, Talc or Sand;
A second waterproof layer (120) formed on the upper surface of the first waterproof layer (110) and formed of the asphalt waterproof composition;
A third waterproof layer 130 formed on the upper surface of the second waterproof layer 120, the third waterproof layer 130 being formed of either PP nonwoven fabric or PET nonwoven fabric;
A fourth waterproof layer 140 formed as an asphalt on the upper surface of the third waterproof layer 130;
And a fifth waterproof layer (150) formed on the upper surface of the fourth waterproof layer (140), the first waterproof layer (150) being formed of any one of PET nonwoven fabric, PP nonwoven fabric, film, asphalt waterproof composition, talc, sand or aggregate.
19. The method of claim 18,
A waterproof layer 111 formed on the lower surface of the first waterproof layer 110 and formed of the asphalt waterproof composition;
The waterproof sheet according to claim 1, wherein the bottom surface waterproof layer (112) is formed of a PP nonwoven fabric, a PET nonwoven fabric, a release film, a releasing paper, Talc or Sand on the lower surface of the waterproof layer (111).
20. The method of claim 19,
The waterproof sheet according to claim 1, wherein the waterproof layer (111) has a thickness of 0.5 to 2.0 mm.
20. The method of claim 19,
Wherein the waterproof sheet (100) has a thickness of 2.0 to 5.0 mm, a width of 1 m, and a length of 10 to 30 m.
19. The method of claim 18,
Wherein the waterproof sheet (100) has a thickness of 2.0 to 5.0 mm, a width of 1 m, and a length of 10 to 30 m.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102110342B1 (en) * 2019-08-01 2020-05-14 주식회사 대흥산업 Method for jointing waterproof sheet and waterproof sheet jointed by the method
KR102310922B1 (en) * 2020-12-09 2021-10-12 삼성엔지니어링 주식회사 Waterproof sheet, waterproof sheet integrated precast concrete and concrete waterproofing method using the waterproof sheet
KR102327868B1 (en) 2020-09-15 2021-11-18 주식회사 삼송마그마 Self-healing asphalt waterproofing sheet and waterproofing structure method thereof
KR102673800B1 (en) * 2023-08-22 2024-06-10 씨티소재 주식회사 Exposed composite sheet and waterproofing method using the same

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109593514B (en) * 2018-09-27 2020-11-06 湘潭红星公路材料有限公司 Asphalt sealant and preparation method thereof
CN109912897B (en) * 2019-03-15 2021-09-21 三河市长城橡胶有限公司 Butyl rubber waterproof coiled material and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101023894B1 (en) 2010-02-09 2011-03-22 조명희 Asphalt sealant composition using phyllite powder
KR101117183B1 (en) 2011-05-18 2012-03-07 (주)삼성방수 Double face self-adhesive mastic waterproofing sheet whit polymer modified asphalt composition
KR101427722B1 (en) 2014-02-28 2014-08-07 (주)일우피피씨 Modified-asphalt and modified-asphalt concrete

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101023894B1 (en) 2010-02-09 2011-03-22 조명희 Asphalt sealant composition using phyllite powder
KR101117183B1 (en) 2011-05-18 2012-03-07 (주)삼성방수 Double face self-adhesive mastic waterproofing sheet whit polymer modified asphalt composition
KR101427722B1 (en) 2014-02-28 2014-08-07 (주)일우피피씨 Modified-asphalt and modified-asphalt concrete

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102110342B1 (en) * 2019-08-01 2020-05-14 주식회사 대흥산업 Method for jointing waterproof sheet and waterproof sheet jointed by the method
KR102327868B1 (en) 2020-09-15 2021-11-18 주식회사 삼송마그마 Self-healing asphalt waterproofing sheet and waterproofing structure method thereof
KR102310922B1 (en) * 2020-12-09 2021-10-12 삼성엔지니어링 주식회사 Waterproof sheet, waterproof sheet integrated precast concrete and concrete waterproofing method using the waterproof sheet
KR102673800B1 (en) * 2023-08-22 2024-06-10 씨티소재 주식회사 Exposed composite sheet and waterproofing method using the same

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