KR101771941B1 - Maskpack including multu-diameter polyurethane nanofiber and and its manufacturing method - Google Patents
Maskpack including multu-diameter polyurethane nanofiber and and its manufacturing method Download PDFInfo
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- KR101771941B1 KR101771941B1 KR1020150057958A KR20150057958A KR101771941B1 KR 101771941 B1 KR101771941 B1 KR 101771941B1 KR 1020150057958 A KR1020150057958 A KR 1020150057958A KR 20150057958 A KR20150057958 A KR 20150057958A KR 101771941 B1 KR101771941 B1 KR 101771941B1
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D44/00—Other cosmetic or toiletry articles, e.g. for hairdressers' rooms
- A45D44/002—Masks for cosmetic treatment of the face
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D44/00—Other cosmetic or toiletry articles, e.g. for hairdressers' rooms
- A45D44/22—Face shaping devices, e.g. chin straps; Wrinkle removers, e.g. stretching the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/4318—Fluorine series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/4358—Polyurethanes
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
- D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Nonwoven Fabrics (AREA)
Abstract
The present invention relates to a mask pack comprising a nanofiber and a method of manufacturing the same, and relates to a mask pack in which first and second polyurethane nanofiber layers having different diameters on a substrate are laminated, It is possible to suppress the desorption phenomenon as much as possible and to improve the skin adhesion property due to the presence of the nano fiber layer and to have a high impregnation efficiency of the moisturizing component and various influential components and to excel the diffusion effect through the skin.
Description
The present invention relates to a mask pack including a nanofiber and a method of manufacturing the same, and more particularly, to a mask pack including a polyurethane nanofiber layer having a different diameter on a substrate and a method of manufacturing the same.
As society is modernized, interest in the environment, welfare, and health is increasing, and interest in health is increasing day by day due to increase in income.
Recently, environmental pollution caused by industrialization has caused a sudden increase in atopic skin patients and side effects such as skin damage due to exposure to ultraviolet rays due to destruction of the ozone layer.
Therefore, in order to remove wastes from damaged skin as described above, or to remove unnatural substances such as cucumber, citrus, aloe, carrot, wormwood, seaweed, carrot, ginseng, red ginseng, Potatoes, cacti, mesyl, vitamins, etc.) and minerals (elvan) have already been commercialized and marketed.
Generally, in the conventional mask pack manufacturing method, a face-type nonwoven fabric or a corresponding paper sheet is folded by hand and folded with a nonwoven fabric, and then the packaging material is manually inserted, filled, sealed, and then commercialized. In this case, the nonwoven fabric or the nonwoven fabric used as the packaging material and the packaging material used are not sterilized, and even if the sterilization is performed, there is a problem that the possibility of contamination with microorganisms is very high in subsequent steps. In addition, the contents are filled in the wrapper as they are after cooling.
However, the above-mentioned mask pack is thick (15 to 50), has a small surface area per volume, and can be detached from facial skin tissue even with slight facial movements. To solve the above problem, Japanese Patent Application Laid-Open No. 2007-70347 discloses a nonwoven fabric for skin attachment and a facial mask pack. This document discloses a nonwoven laminate for skin attachment comprising a nonwoven layer and a nanofiber layer used as a skin attachment surface.
However, the nanofiber-coated non-woven mask packs are problematic in that the adhesion between the nanofibers and the nonwoven is dependent solely on electrostatic forces and can easily undergo layer separation (nanofiber delamination) when impregnated with a liquid cosmetic formulation .
SUMMARY OF THE INVENTION The present invention has been conceived to solve the above problems, and it is an object of the present invention to provide a polyurethane nanofiber layer on a substrate, wherein the polyurethane nanofiber layer has a different diameter, And the adhesive layer is formed by spinning the low melting point polymer between the fibrous layers, and a method for producing the same.
In order to solve the above problems,
A substrate;
A first nanofiber layer having a diameter of 80 to 150 nm formed by electrospunning polyurethane;
A second nanofiber layer having a diameter of 150 to 300 nm formed by electrospunning polyurethane; Including,
The adhesion between the base material and the first nanofiber layer and between the first nanofiber layer and the second nanofiber layer is bonded through an adhesive layer formed by electrospinning a low melting point polymer solution. do.
The low-melting-point polymer solution is characterized in that it is selected from at least one of a low melting point polyester, a low melting point polyurethane, and a low melting point polyvinylidene fluoride.
In order to solve the above problems more effectively,
The low melting point polymer solution may be electrospun on the entire surface or a part of the substrate and the first nanofiber layer, and may be electrospun at a temperature of 50 to 100 ° C.
In addition, in the present invention, when the first nanofiber layer and the second nanofiber layer are electrospun, the basis weight may be different along the longitudinal direction or the transverse direction, and the electrospinning of the low melting point polymer solution for forming the adhesive layer may be performed by, It can be radiated to the whole or a part of the nanofiber layer.
The mask pack manufactured according to the present invention is easier to adhere to the base layer and the polymer electrospinning layer than the conventional mask pack and is not easily removed, and the skin adhesion is greatly improved due to the presence of the nano fiber layer , The moisturizing component and various influential components are highly impregnated, the diffusion effect through the skin is excellent, and the nutritional ingredient and the skin moisturizing ingredient can be maintained for a long time.
1 is a side view schematically showing an electrospinning apparatus according to the present invention;
Fig. 2 is a side sectional view schematically showing a nozzle of a nozzle block installed in a unit of the electrospinning apparatus according to the present invention. Fig.
3 is a view schematically showing a nozzle block installed in a spinning solution unit of an electrospinning apparatus according to the present invention
Fig. 4 is a perspective view schematically showing a state in which an electric heater is installed in a nozzle block installed in each unit of the electrospinning apparatus according to the present invention. Fig.
5 is a cross-sectional view taken along line A-A '
6 is a perspective view schematically showing a nozzle block installed in a low melting point polymer unit of an electrospinning apparatus according to the present invention.
FIGS. 7 to 10 are plan views schematically showing the operation process of the polymer spinning solution being electrospinned on the same plane of the base material through the nozzles of the respective nozzle tubes of the electrospinning device for manufacturing a nanofiber web according to the present invention
FIGS. 11 and 12 are plan views schematically showing an operation process in which the low melting point polymer and the polymer spinning solution are sequentially injected through the arrangement of the nozzle blocks in the low melting point polymer unit as shown in FIG.
13 is a view showing a state in which the nozzle blocks provided in the low melting point polymer unit of the electrospinning apparatus according to the present invention are arranged in different shapes
14 and 15 are diagrams showing an operation process of sequentially injecting the low-melting-point polymer and the polymer spinning solution according to the arrangement of the nozzles as shown in FIG. 13
16 is a view showing a state in which the nozzle blocks provided in the low melting point polymer unit of the electrospinning apparatus according to the present invention are arranged in another form
FIGS. 17 and 18 are diagrams showing an operation process in which the low-melting-point polymer and the polymer spinning solution are sequentially injected according to the arrangement of the same nozzle as shown in FIG.
19 is a front view showing a laminated structure of the mask pack manufactured by the present invention
20 is a perspective view showing the wearing state of the mask pack of the present invention
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. The present invention is not limited to the scope of the present invention, but is merely an example, and various modifications can be made without departing from the technical spirit of the present invention.
1 is a side view schematically showing an electrospinning apparatus for manufacturing a mask pack of the present invention. The electrospinning apparatus 1 according to the present invention comprises a bottom-up electrospinning apparatus 1, wherein at least one low-melting polymer unit 10a, 10c and a spinning liquid unit 10b, Melting polymeric units 10a and 10c and the spinning solution units 10b and 10d are provided separately in the same manner or differently from each other (10c and 10d are not shown), and the low- To prepare a mask pack.
The low-melting-point polymer unit and spinning solution unit may include a main tank 8 in which a low-melting-point polymer or a polymer solution is filled, and a low-melting-point polymer or polymer solution filled in the main tank 8 in a predetermined amount (Not shown) for supplying a low-melting-point polymer or a polymer solution for filling the inside of the main tank 8.
2, the
3 schematically shows a nozzle block installed in a spinning liquid unit of an electrospinning apparatus according to the present invention. As shown in the drawing, the
In the present invention, a substrate selected from cellulose, a binary system, and polyterephthalate is used as the
The polyvinylidene fluoride is preferably selected from polyvinylidene fluoride, a low melting point polyester, and a hydrophobic polyurethane. Needless to say, however, the present invention is not necessarily limited thereto.
The cellulose base material used in the present invention is preferably composed of 100% cellulose, but cellulose having a total mass ratio of 70 to 90: 10 to 30 mass% of polyethylene terephthalate (PET) It is also possible to use a substrate having a cellulose base coated with a flame retardant coating.
The binary substrate may be selected from a sheath-core type, a side by side type, and a C-type type.
The low-melting-point polyurethane uses a low-polymerization polyurethane having a softening temperature of 80-100 ° C.
The low melting point polyester is preferably terephthalic acid, isophthalic acid or a mixture thereof. It is also possible to add ethylene glycol as a diol component to further lower the melting point.
The low melting point polyvinylidene fluoride is a low melting point polyvinylidene fluoride having a weight average molecular weight of 5,000 and a melting point of 80 to 160 ° C.
It is needless to say that the low melting point polyurethane, the low melting point polyester and the low melting point polyvinylidene fluoride may be used singly or in combination of two or more.
Fig. 4 is a perspective view schematically showing a state in which an electric heater is installed in a nozzle block installed in each unit of the electrospinning apparatus according to the present invention, and Fig. 5 is a sectional view taken along the line A-A 'in Fig. As shown in the figure, a temperature control device in the form of a
Due to the above-described temperature control device, the temperature of the electrospinning can be performed at a high temperature (50 to 100 ° C) as compared with a normal temperature. Conventional electrospinning is carried out at room temperature, but there is a problem in that the solute of the polymer solution is insoluble in the solvent at room temperature. Therefore, MEK (methyl ether ketone), THF (tetrahydrofuran), and alcohol diluent are used to easily prepare the polymer solution.
However, in the method using the diluent described above, the concentration of the solute is lowered to lower the efficiency of electrospinning, and problems such as environmental contamination due to the generation of an excessive residual solvent and an increase in the unit cost of production have been caused. In order to solve the problem of electrospinning at room temperature, a temperature control device (60) in the form of a heat ray (41) is formed spirally around the inner periphery of the tube body (40) of the nozzle block (11) ) Was adjusted to the temperature of the polymer spinning solution.
Due to the above-described temperature control device, the temperature of the electrospinning can be performed at a high temperature (50 to 100 ° C) as compared with a normal temperature.
6, 13 and 16 are perspective views schematically showing a nozzle block installed in a low melting point polymer unit of an electrospinning apparatus according to the present invention. The nozzle arranged in the low melting point polymer unit may be applied to the front face portion of the substrate, but is preferably applied to a specific portion of the substrate if necessary. In Fig. 6, the nozzles are divided into five groups of nine nozzles, one at the center in the upper part and two in the lower part, and arranged in the longitudinal direction in Fig. 13 and the widthwise direction in Fig. The arrangement of such nozzle blocks enables electrospinning to only a part of the substrate or the nano fiber layer.
The arrangement of the nozzle and the nozzle block is not limited to this, and it is obvious to those skilled in the art that the nozzle can be appropriately designed and modified in consideration of the number of the nozzles and the amount of the low melting point polymer to be radiated.
FIGS. 7 to 10 are plan views schematically showing an operation process of electrospinning a polymer spinning solution on the same plane of a substrate through nozzles of each nozzle tube of an electrospinning device for manufacturing a nanofiber web according to the present invention. The
The supply of the supplied polymer spinning solution is controlled by an on-off system controlled and controlled.
That is, when the polymer spinning solution is supplied to the
In this way, the basis weight can be adjusted along the length and width direction of the amount of the polymer solution radiated through the spinning solution unit.
The MD direction used in the present invention means a machine direction, and means a longitudinal direction corresponding to a traveling direction when continuous fabrics such as a film or a nonwoven fabric are produced. A CD direction is a cross direction, and a direction perpendicular to the MD direction do. MD is also referred to as machine direction / longitudinal direction, and CD is referred to as width direction / transverse direction.
Basis Weight or Grammage is defined as the mass per unit area, that is, the preferred unit, grams per square meter (g / m 2). In recent years, for the purpose of making the air mask pack and the unit lighter and more compact, a thinner type is required. If the filter medium having the same filtration area is to be inserted into the unit, the filter medium faces contact each other due to the thickness of the filter medium, There has been a problem in that the pressure loss of the air mask pack unit remarkably increases. To solve this problem, there has been an attempt to reduce the thickness of the filter medium for the air mask pack, that is, to reduce the basis weight. However, such an attempt can solve the pressure loss of the air mask pack unit sufficiently when the basis weight is reduced for a specific portion of the mask pack for each specific industrial field to which the mask pack is applied in a method of reducing the basis weight of the entire mask pack. The strength of the filter medium can be maintained by maintaining or increasing the basis weight of the remaining portion of the filter medium.
Hereinafter, a method for manufacturing the mask pack of the present invention will be described using the electrospinning device.
[Example 1]
Melting point polyurethane is dissolved in a solvent of DMAc (N, N-dimethylaceticamide) to prepare a low melting point polymer solution, which is supplied to the main tank 8 connected to the low melting point polymer units 10a and 10c of the electrospinning apparatus, The low-melting-point polymer solution supplied to the tank 8 is continuously supplied in a constant amount into the plurality of
Next, the polymer spinning solution in which the polyurethane is dissolved in the DMAc solvent is supplied to the main tank 8 connected to the spinning solution units 10b and 10d of the electrospinning apparatus. The polyurethane solution supplied to the main tank 8 connected to the spinning solution unit 10b is electrospun through a
Then, another low melting point polymer solution is discharged from the low melting point polymer unit 10c through the nozzle to form another adhesive layer on the first nanofiber layer, and the solution is supplied to the main tank 8 connected to the spinning solution unit 10d The polyvinylidene fluoride solution is electrospun through the
Then, the substrate is rotated in the low-melting-point polymer unit by rotation of the feeding roller 3 operated by driving of a motor (not shown) and the auxiliary feeding device 16 driven by rotation of the feeding roller 3, And transferred to the solution for use unit, and the above-mentioned process was repeated, and the first and second nano fiber layers were electrospun on the substrate to prepare a mask pack.
[Comparative Example 1] Production of a mask pack in which no adhesive layer was formed
A mask pack was prepared in the same manner as in Example 1 except that no adhesive layer was formed.
[Evaluation Example 1] Separation test of the nanofiber layer
With respect to the mask pack samples prepared in Example 1 and Comparative Example 1, occurrence of the nanofiber decolorized layer was visually observed, and the results are shown in Table 1.
In the mask pack of the present invention, no nanofiber delamination occurred even after 15 days, but in the mask pack without the adhesive layer, nanofiber delamination occurred after three days.
[Evaluation Example 2] Skin adhesion test
The mask pack samples prepared in Example 1 and Comparative Example 1 were applied to skin surfaces of five subjects for 30 minutes to evaluate the degree of skin adhesion (peel resistance). A typical mask pack sample without nanofibers was used as a control and evaluated. The results are shown in Table 2.
From the results shown in Table 2, it can be seen that the mask pack including the nanofiber layer exhibits better skin adhesion than the conventional non-woven mask pack as in the present invention.
[Evaluation Example 3] Skin soothing and moisturizing test
A mask pack was prepared in the same manner as in Example 1 except that hydrophilic polyvinylidene fluoride, polyurethane (PAN), hydrophilic polyurethane (PU) and polyvinyl alcohol (PVA) were used as a polymer spinning solution.
The mask pack thus prepared was impregnated with the skin active component as shown in Table 3 below in weight percent.
PVDF
PU
After using the above Example 1 and Comparative Examples 2 to 5 for 10 patients three times, the degree of skin relaxation and moisturizing sensation was evaluated on a scale of 5 points: 5 points: very good, 4 points: slightly better, and 3 points : Average, 2: Poor, 1: Very poor, and the average value of each is shown in Table 4 as a result of skin soothing and moisturizing effect when using the product.
From the above results, it was proved that the mask pack including the multi-diameter polyurethane nano fiber layer of the present invention is remarkably excellent in skin adhesion, skin soothing and moisturizing effect. This is because the polyurethane is different in diameter and can contain the impregnated nutrients more effectively.
1: electrospinning device, 3: feed roller,
5: take-up roller, 7: main control device,
8: Main tank,
10a: low melting point polymer unit 10b: spinning liquid unit
11: nozzle block, 12: nozzle,
13: collector, 14, 14a, 14b: voltage generator,
15, 15a, 15b: long sheet, 16: auxiliary conveying device,
16a: auxiliary belt, 16b: auxiliary belt roller,
18: case, 19: insulating member,
30: Long sheet conveying speed adjusting device, 31: Buffer section,
33, 33 ': support roller, 35: regulating roller,
40: tube body, 41, 42: heat wire,
43: pipe, 60: temperature control device,
70: thickness measuring device, 80: air permeability measuring device,
90: laminating device, 111: nozzle block,
111a: nozzle 112: nozzle tube,
112a, 112b, 112c, 112d, 112e, 112f, 112g, 112h, 112i:
115: substrate, 115a, 115b, 115c: nanofiber web,
200: overflow device,
211, 231: stirring device, 212, 213, 214, 233: valve,
216: second transfer pipe, 218: second transfer control device,
220: intermediate tank, 222: second sensor,
230: regeneration tank, 232: first sensor,
240: supply piping, 242: supply control valve,
250: circulating fluid recovery path, 251: first transfer pipe,
300: VOC recycling apparatus, 310: condensing apparatus,
311, 321, 331, 332: piping, 320: distillation device,
330: solvent storage device, 404: air supply nozzle,
405: nozzle plate, 407: first spinning solution storage plate,
408: second spinning liquid storage plate, 410: overflow liquid temporary storage plate,
411: air storage plate, 412: overflow outlet,
413: air inlet,
414: nozzle support plate for supplying air, 415: overflow removing nozzle,
416: nozzle overflow removing nozzle support plate,
500: multi-tubular nozzle, 501: inner tube,
502: outer tube, 503: distal end.
Claims (6)
A first nanofiber layer having a diameter of 80 to 150 nm formed by electrospunning polyurethane;
A second nanofiber layer having a diameter of 150 to 300 nm formed by electrospunning polyurethane; Including,
The adhesion between the substrate and the first nanofiber layer, between the first nanofiber layer and the second nanofiber layer is bonded through an adhesive layer formed by electrospinning the low melting point polymer solution,
Wherein the low melting point polymer solution is one kind selected from a low melting point polyester, a low melting point polyurethane, and a low melting point polyvinylidene fluoride.
Wherein the low-melting-point polymer solution is electrospinned on the entire surface or a part of the substrate and the first nanofiber layer.
Wherein the first and second nano fiber layers are formed by electrospinning at a temperature of 50 to 100 ° C.
Wherein the first nanofiber layer and the second nanofiber layer are different in basis weight along the longitudinal direction or the transverse direction,
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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KR1020150057958A KR101771941B1 (en) | 2015-04-24 | 2015-04-24 | Maskpack including multu-diameter polyurethane nanofiber and and its manufacturing method |
PCT/KR2015/007145 WO2016171331A1 (en) | 2015-04-24 | 2015-07-09 | Mask pack comprising nanofibers |
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KR1020150057958A KR101771941B1 (en) | 2015-04-24 | 2015-04-24 | Maskpack including multu-diameter polyurethane nanofiber and and its manufacturing method |
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KR20160126645A KR20160126645A (en) | 2016-11-02 |
KR101771941B1 true KR101771941B1 (en) | 2017-08-29 |
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