KR101749565B1 - Measurement Apparatus for differential spectral responsivity on photovoltaic cells - Google Patents
Measurement Apparatus for differential spectral responsivity on photovoltaic cells Download PDFInfo
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/28—Investigating the spectrum
- G01J3/2803—Investigating the spectrum using photoelectric array detector
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
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- G01R31/26—Testing of individual semiconductor devices
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- G01R31/2632—Circuits therefor for testing diodes
- G01R31/2635—Testing light-emitting diodes, laser diodes or photodiodes
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- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/08—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
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Abstract
The present invention provides an apparatus for measuring the spectral responsivity derivative and a method of measuring the same. The apparatus comprises: a probe light source for providing monochromatic probe light having intensity modulation with a predetermined intensity modulation frequency to an optoelectronic device; A bias light source for providing a bias light having a broad spectral range to the photoelectric device, the bias light source having a radiation flux greater than the radiation flux of the probe light; A bias light source driving unit for supplying and operating a current to the bias light source; A current sink connected to an output terminal of the photoelectric device to provide a predetermined target DC current; And a control unit connected to an output terminal of the photoelectric device and the current sink to control the bias light source driving unit to receive the difference between the output current of the photoelectric device and the target DC current, do.
Description
The present invention relates to an apparatus and method for evaluating a photoelectric device, and more particularly, to an apparatus for measuring photoelectric conversion efficiency of a solar cell including feedback control.
Spectral responsivity is a measure of the output of a photovoltaic conversion device or of an electrical signal to the irradiance, expressed as a function of wavelength, corresponding to an SI unit traceability spectral response characterization . Generally, the wavelength can be changed to measure the spectral sensitivity, but a reference detector that can measure the spectral light source and thus the radiation output or the radiation intensity is required, and is generally made by DC method. However, in the case of solar cells, since it is necessary to measure spectral response characteristics under a high irradiance condition of 1 kW / m 2 , direct measurement by the DC method is very difficult.
Disclosure of Invention Technical Problem [8] The present invention provides a device for measuring the spectral sensitivities of solar cells with a high signal-to-noise ratio. Specifically, when a circuit for measuring the spectral sensitivity derivative is constructed, a large direct current due to a strong bias light is induced in the solar cell. The monochromatic probe light whose intensity is modulated with a predetermined intensity modulation frequency is irradiated to the solar cell simultaneously with the bias light. In this case, the intensity-modulated monochromatic probe light induces a very small photocurrent of the modulated frequency component in the solar cell. A method is provided for efficiently and stably amplifying and measuring the induced modulated frequency component photocurrent. This extraction of the stable modulated frequency component photocurrent can be provided by stabilizing the output of the bias light with the DC component of the short circuit current of the solar cell as a control variable
A spectroscopic sensitivity derivative measurement apparatus according to an embodiment of the present invention includes: a probe light source that provides intensity-modulated monochromatic probe light with a predetermined intensity modulation frequency to an optoelectronic device; A bias light source for providing a bias light having a broad spectral range to the photoelectric device, the bias light source having a radiation flux greater than the radiation flux of the probe light; A bias light source driving unit for supplying and operating a current to the bias light source; A current sink connected to an output terminal of the photoelectric device to provide a predetermined target DC current; And a control unit connected to an output terminal of the photoelectric device and the current sink to control the bias light source driving unit to receive the difference between the output current of the photoelectric device and the target DC current, do.
In one embodiment of the present invention, the controller includes: a current-voltage converter for converting a current difference between the output current of the photoelectric element and the target DC current into a voltage signal; An inverter amplifier for changing a sign of an output signal of the current-voltage converter and outputting the sign; And an integrator for outputting an output signal of the inverter amplifier. The bias light source driving unit may provide a driving current proportional to an output signal of the integrator to the bias light source.
In one embodiment of the present invention, the bias light source may be a series-connected LED.
In one embodiment of the present invention, a lock-in amplifier for extracting an intensity-modulated frequency component from an output signal of the current-voltage converter or an output signal of the inverter amplifier; And an auxiliary controller for processing an output signal of the lock-in amplifier.
In one embodiment of the present invention, the probe light source includes a broadband light source having a wide spectral range; An intensity modulator for intensity modulating the output of the wideband light source to a predetermined intensity modulation frequency; A spectroscope for spectroscopically modulating the intensity-modulated light according to a wavelength to output monochromatic light; A beam splitter for separating the monochromatic light into two paths; And a reference photodetector disposed in one of the separated beams. And the other one of the separated beams from the beam splitter may be provided as the monochromatic probe light to the photoelectric element.
In one embodiment of the present invention, the auxiliary control unit provides a DC target current control signal to change a DC target current of the current sink, and the auxiliary control unit supplies a wavelength change control signal to the DC current source so as to change the wavelength of the monochromatic probe light. Can be provided to the probe light source.
According to an embodiment of the present invention, there is provided a spectroscopic sensitivity derivative measurement method, comprising: providing a photoelectric device with monochromatic probe light whose intensity is modulated on / off at a predetermined intensity modulation frequency; Providing a bias light having a broad spectral range to the photoelectric device with a radiation flux greater than the radiation flux of the probe light; Controlling the bias light source driving unit to generate the photocurrent by receiving the monochromatic probe light and the bias light and to remove the current difference by receiving a current difference between the photocurrent and the set target DC current of the current sink; Generating a bias light by providing a driving current of the bias light source driving unit to a bias light source; And extracting the intensity modulated frequency component from a difference in current between the photocurrent and a set target DC current of the current sink.
In one embodiment of the present invention, there is provided a method of modifying a wavelength of a monochromatic probe light, And changing the target DC current.
In one embodiment of the present invention, the step of controlling the bias light source driving unit to remove the current difference may include at least one of proportional control, integral control, proportional-integral control, or proportional-integral-differential control .
According to an embodiment of the present invention, by controlling the bias light source in a feedback manner, the intensity of the bias light can be kept constant and the DC component of the output current of the solar cell can be kept constant. The signal-to-noise ratio (SNR) of the measurement signal can be improved by sinking only the DC component current which is kept constant as the DC component of the output current of the solar cell is kept constant, and then passing the DC component current through the front-
FIG. 1 is a conceptual diagram for explaining a spectroscopic sensitivity derivative measurement apparatus according to an embodiment of the present invention.
2 is a view for explaining a feedback loop of the spectroscopic sensitivity derivative measurement apparatus of FIG.
3 is a detailed view showing a circuit of the spectroscopic sensitivity derivative measuring apparatus of FIG.
4 is a diagram showing signals of the spectroscopic sensitivity measuring apparatus of FIG.
5 is a block diagram illustrating a method for measuring spectral sensitivity according to an embodiment of the present invention.
The spectral responsivity is a function of the response current i (unit: A) with respect to the radiation flux? (Unit: W) of the incident light of a predetermined wavelength (?) In a photoelectric conversion element such as a solar cell or a photodiode When this occurs, the photoelectric conversion ratio of the photoelectric device is quantified as a function of wavelength, such as R = i / Φ (unit: A / W), which is closely related to the power generation performance.
Since the spectroscopic sensitivity varies depending on the radiation flux (?) Or intensity of incident light, it is generally expressed as R = R (?;?). Normally, the spectral sensitivity is obtained by measuring the output current of the photoelectric conversion element after the monochromatic light whose intensity is known is made incident on the photoelectric conversion element. In general, since the light output of a monochromatic light source is limited, measurements can only be made under the condition that monochromatic light of about WW or less is irradiated.
It is not appropriate to use the spectral sensitivity measured at several μW to measure the power generation performance of the solar cell operating under the condition of irradiating light of 100 mW or more.
In order to quantify the power generation performance of a photoelectric conversion element under a condition where a strong light such as a solar cell is irradiated using the spectral sensitivity, the spectral sensitivity should be measured as monochromatic light with high output. However, it is practically impossible to raise the output of a monochromatic light source to several tens mW or more. To solve this problem, the measured amount is the spectral sensitivity. The spectral sensitivity derivative can be defined as:
When the incident light of an arbitrary spectrum enters the photoelectric conversion element (or the photoelectric element) with the radiation ray flux?, The output current of the photoelectric element is represented by i and the radiation ray flux of the light of the wavelength? Let ΔΦi be the output current when the sum Φ + ΔΦ is added. The differential spectral responsivity (DSR; R '(?;?)) At the wavelength? And the radiation flux? Of the incident light is given as follows.
At this time, the light output by the radiation flux? Of the incident light does not need to be monochromatic light, but monochromatic light may be added by ?? only. Therefore, it is possible to measure the spectral responsivity derivative even with monochromatic light having a weak intensity of about μW. The spectral responsivity derivative is measured in turn while increasing the radiation flux (?) Of the incident light.
In this way, the functional relationship of R '(Φ; λ) is determined by measuring the spectral responsivity derivative against the photocathode generation (Φ) of incident light of several intensities, The efficiency (or sensitivity) can be calculated. Since the efficiency of a solar cell is generally evaluated under a standardized solar light spectrum (AM1.5 spectrum), it is generalized so that light known as a relative spectrum S (?) Is irradiated on the solar cell, out , calculate the sensitivity as a function of the output current i out .
First, the sensitivity derivative R '(i) for the bias light having the relative spectrum S (λ) from the spectral sensitivity derivative (R' (φ) of the solar cell) is calculated. That is, this sensitivity derivative means an increase in current when the bias light of the S (?) Relative spectrum (S (?)) Slightly increases the output. The spectral sensitivity derivative can be expressed both as a function of Φ or as a function of i.
When the output current of the solar cell is represented by i out, copy bias light that is incident on the solar cell in this case in flux Φ is given by:
Therefore, the sensitivity (R) for the output current i out to be obtained is given as follows.
(A weak intensity of monochromatic light) of a monochromatic probe light modulated with a predetermined intensity modulation frequency is superimposed on a radiation beam? (Strong intensity bias light) of a bias light having a constant DC light output, . It is also assumed that the radiant flux DELTA phi of the monochromatic probe light can be modulated by using a chopper.
If the photocurrent given to the solar cell by i = 100 mA and the photocurrent given by the photocathode of the monochromatic probe light to the solar cell is Δi = 0.1 μA, the photocurrent given to the solar cell by the photocathode The photocurrent flowing through the photodiode has a value of 100 mA + 0.1 μA and a current of 100 mA.
At this time, if the current difference Δi = 0.1 μA flowing in the solar cell depending on the presence or absence of the monochromatic probe light can be measured and the radiation flux (ΔΦ) of the incident monochromatic probe light can be measured with the reference detector already calibrated, R '(?;?)) Can be measured.
However, since the difference of Δi = 0.1 μA is only about 10 -6 compared to 100 mA, it is impossible to measure with a general front-end amplifier (gain: G), a lock-in amplifier, and a digital voltmeter.
According to an embodiment of the present invention, a feedback loop is operated with respect to the optical output of the bias light source, and the solar cell detects the optical output of the bias light source to generate a photocurrent, And an error, which is the difference between the photocurrent and the target DC current, is provided to the control section. The control unit generates a control signal to control the bias light source driving unit so that the optical output of the bias light source is controlled. The photocurrent of the solar cell is converted into a voltage signal by a current-to-voltage converter and amplified. By controlling the DC input current of the current-to-voltage converter to zero, the gain of the AC input current of the current-to-voltage converter is kept high. Thus, for the AC input current of the current-to-voltage converter, the current / voltage conversion gain can be increased to 10,000 times or more. The current-voltage converter may be implemented through a current-voltage front-end amplifier.
According to an embodiment of the present invention, the DC output photocurrent of the solar cell is kept constant by feedback control so that the intensity of the bias light, which is the output light of the bias light source, is kept constant, and the DC output photocurrent flows through the precise current sink. Therefore, the current-voltage converter can amplify only the AC current signal due to the monochromatic probe light with high gain. Thus, it is possible to measure the spectral sensitivity derivative having strong signal-to-noise ratio and strong against disturbance.
According to an embodiment of the present invention, when the bias light source is a light source in which a plurality of LEDs are connected in series, it is possible to light up the current with less current than when one or several LEDs are connected in parallel, Since the optical output can be stably kept constant, the AC signal component of the solar cell due to the monochromatic probe light intensity-modulated by On / Off can be extracted with a high SNR.
Generally, when measuring the spectral sensitivity derivative (DSR), the photocurrent of the solar cell due to the bias light is about 100 mA, and the AC photocurrent of the solar cell due to the monochromatic probe light is about 1 μA maximum. Therefore, in order to well separate the AC photocurrent component due to the monochromatic probe light, the intensity of the bias light requires a stability of about 1 / 100,000. According to the feedback loop of the present invention, the stability of the bias light can be maintained at 1 / 100,000 or less.
According to an embodiment of the present invention, when an LED connected in series to a bias light source is employed, a stability of about 1/100000 can be obtained by employing a feedback loop.
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. However, the present invention is not limited to the embodiments described herein but may be embodied in other forms. Rather, the embodiments disclosed herein are being provided so that this disclosure will be thorough and complete, and will fully convey the concept of the invention to those skilled in the art. In the drawings, the components have been exaggerated for clarity. Like numbers refer to like elements throughout the specification.
FIG. 1 is a conceptual diagram for explaining a spectroscopic sensitivity derivative measurement apparatus according to an embodiment of the present invention.
2 is a view for explaining a feedback loop of the spectroscopic sensitivity derivative measurement apparatus of FIG.
3 is a detailed view showing a circuit of the spectroscopic sensitivity derivative measuring apparatus of FIG.
4 is a diagram showing signals of the spectroscopic sensitivity measuring apparatus of FIG.
5 is a block diagram illustrating a method for measuring spectral sensitivity according to an embodiment of the present invention.
1 to 5, the spectroscopic sensitivity
The spectroscopic sensitivity derivative measurement device must stably extract the intensity modulated frequency component from the photocurrent of the
In the feedback control, the opto-
In the absence of the monochromatic probe light, the DC photocurrent of the photoelectric element is decomposed into the target DC current and the error DC component, and the error DC component is provided to the
On the other hand, in the case of monochromatic probe light, monochromatic probe light whose intensity is modulated with a predetermined intensity modulation frequency (f m ) corresponding to the signal is provided to the photoelectric element in the control circuit. The
The
The current-to-
The current flowing through the
When the bias light source starts operating in the unlit state, the light output of the bias light source gradually increases, so that the magnitude of the photocurrent of the photoelectric device is smaller than the target DC current of the current sink. Therefore, if the sign of the current value of the current sink is set negative, the net current input to the current-
The current-
The output of the operational amplifier OP4 has an AC signal component and an error DC component. The output of the operational amplifier OP4 is branched and connected to a lock-in
The
The bias light source control signal CTRL_V is provided to the bias light
The bias light
The
The
The probe
The
The
The
The bias
The output of the
The
On the other hand, a part of the monochromatic probe light is measured by the
The output signal of the reference current-to-voltage converter is provided to the auxiliary lock-in
The
The
Referring again to FIGS. 4 and 5, the spectroscopic sensitivity measuring method provides monochromatic probe light whose intensity is modulated on / off at a predetermined intensity modulation frequency (f m ) to the
Accordingly, it is possible to calculate the sensitivity of the photoelectric element under an arbitrary spectrum according to Equations (2) to (4).
The step of controlling the bias light source driving unit to remove the current difference may include at least one of a proportional control, an integral control, a proportional-integral control, and a proportional-integral-differential control. Preferably, integral control can be used.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments, And all of the various forms of embodiments that can be practiced without departing from the technical spirit.
110: probe light source
120: bias light source
130: Photoelectric element
140: Current sink
150:
160: bias light source driver
Claims (9)
A bias light source for providing a bias light having a broad spectral range to the photoelectric device, the bias light source having a radiation flux greater than the radiation flux of the probe light;
A bias light source driving unit for supplying and operating a current to the bias light source;
A current sink connected to an output terminal of the photoelectric device to provide a predetermined target DC current; And
And a control unit connected to an output terminal of the photoelectric device and the current sink to control the bias light source driving unit to receive the difference between the output current of the photoelectric device and the target DC current, ,
The control unit includes:
A current-to-voltage converter for converting a current difference between the output current of the photoelectric element and the target DC current into a voltage signal;
An inverter amplifier for changing a sign of an output signal of the current-voltage converter and outputting the sign; And
And an integrator for integrating an output signal of the inverter amplifier,
Wherein the bias light source driving unit supplies a driving current proportional to an output signal of the integrator to the bias light source,
A lock-in amplifier for extracting an intensity modulated frequency component from an output signal of the current-voltage converter or an output signal of the inverter amplifier; And
Further comprising an auxiliary controller for processing an output signal of the lock-in amplifier,
The auxiliary control section provides a DC target current control signal to change the DC target current of the current sink,
Wherein the auxiliary controller supplies a wavelength change control signal to the probe light source to change the wavelength of the monochromatic probe light.
Wherein the bias light source is a series-connected LED.
Wherein the probe light source comprises:
A broadband light source having a wide spectral range;
An intensity modulator for intensity modulating the output of the wideband light source to a predetermined intensity modulation frequency;
A spectroscope for spectroscopically modulating the intensity-modulated light according to a wavelength to output monochromatic light;
A beam splitter for separating the monochromatic light into two paths; And
And a reference photodetector disposed in one of the separated beams,
And the other one of the separated beams from the beam splitter is provided as the monochromatic probe light to the photoelectric device.
Providing a bias light having a broad spectral range to the photoelectric device with a radiation flux greater than the radiation flux of the probe light;
Controlling the bias light source driving unit to generate the photocurrent by receiving the monochromatic probe light and the bias light and to remove the current difference by receiving a current difference between the photocurrent and the set target DC current of the current sink;
Generating a bias light by providing a driving current of the bias light source driving unit to a bias light source; And
Extracting the intensity modulated frequency component from a current difference of the photocurrent and a set target DC current of the current sink,
Changing the wavelength of the monochromatic probe light; And
Further comprising changing the target DC current. ≪ Desc / Clms Page number 22 >
Wherein the step of controlling the bias light source driving unit to remove the current difference includes at least one of a proportional control, an integral control, a proportional-integral control, and a proportional-integral-differential control.
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