KR101717117B1 - Process for coating polyketone yarn - Google Patents

Abstract

The present invention relates to a method of coating a polyketone yarn, and more particularly, to a method of coating a polyketone yarn by coating an industrial polyketone fiber yarn with a polyketone yarn using an extruder for coating yarn, The present invention also relates to a method of coating a polyketone yarn, which is capable of improving the mechanical properties and imparting excellent functionality for expanding the application.

Description

{PROCESS FOR COATING POLYKETONE YARN}

The present invention relates to a method for coating a polyketone yarn, and more particularly, to a method of coating a polyketone yarn by coating an industrial polyketone yarn on a surface of a yarn using an extruder for yarn coating, The present invention relates to a method of coating a polyketone yarn with improved UV and fastness due to the addition of a functional additive.

Although polyketone materials, which have not yet been commercialized globally, have not yet been in demand, there is a market share of 10 ~ 30% of the existing super-materials market share when raw materials are mass-produced, and 80 ~ 90% It is expected that there will be a lot of demand companies because it shows the physical properties but the interfacial adhesion rate is higher and it can be used for tire cords, MRG and other industrial and life use applications due to low cost.

Therefore, it is necessary to develop technologies for the commercialization of polyketone fibers for the first time in the world, and to develop technology and technology related to process technology to develop customized applications.

In the case of polyketone fiber materials, development possibilities have been steadily recognized due to unique properties and cost performance. Many technical DBs are accumulated in scale form. However, most of the companies are still in mass production because they are investing in high production facilities and infrastructure in comparison with excellent physical properties and cost performance.

In addition to the complexization of existing textile technology in Korea, the new process technology for new materials and the fusion of new technologies derived from other industries, it is necessary to develop processing technology for polyketone materials only. In addition to industrial textile products, In order to develop, new material processing technology is required through upgrading of mechanical properties and functionality.

Polyketone material is able to develop into substitute materials for automobile parts and electronic parts by taking advantage of excellent chemical resistance and high strength, and it has strength of about 80 ~ 90% as compared with reference super material, but based on high interface adhesion rate It is judged that it can be used as high quality MRG and Tire code material, and its price competitiveness is also lower than that of aramid and other super fibers, so expectation for use expansion as low-priced super fiber is getting bigger. It has the advantage of being able to cope with high initial investment cost thanks to the establishment of completely new advanced technology and a high share of the world market can be expected.

The object of the present invention is to provide a material having excellent functionality and mechanical properties by expanding the application through the use of raw coating extrusion using a polyketone fiber material aiming at mass production for the first time in the world.

The present invention relates to a polyketone fiber which is capable of enhancing mechanical properties and imparting excellent functionality for expanding the use of the polyketone material by complementing the drawbacks of color, UV vulnerability, and fastness of the polyketone material by using an extruder for coating yarn, It is an object of the present invention to provide a method for coating a polyketone yarn.

In order to accomplish the above object, the present invention provides a method for producing a yarn, comprising the steps of: injecting a polyvinyl chloride coating agent or a thermoplastic polyurethane coating agent into an extruder for coating yarn; And applying a coating agent to the surface of the polyketone yarn by the extruder for coating a yarn.

At this time, the step of applying the coating agent is performed at a temperature of 160 ° C. or less and a processing speed of 500 mpm or less, and it is preferable that the coating agent is applied to the polyketone yarn at 0.400 g / m 2 or less.

In addition, the coating may further comprise a UV stabilizer or a color master batch chip.

In addition, after the step of applying the coating agent, the method may further include at least one post-processing process selected from the group consisting of a weaving process, a functionalizing process, a coating process, and a laminating process of the polyketone yarn.

The present invention is a method of coating polyketone yarn using a yarn coating technique, and imparting aesthetic characteristics and various functions of the yarn through PVC and TPU coating serve as main mechanisms.

When the yarn coating process is performed, the physical properties of the polyketone yarn material depend on the type of the coating agent to be used and the functional pigment to be added. This technology is capable of expanding the use of high strength polyketone fibers through appropriate functional processing for industrial and commercial use of polyketone yarns.

In addition, it is possible to substitute high strength PET, Nylon material and super fiber material, which are widely used as industrial fiber materials, by utilizing the excellent mechanical properties such as high strength and elongation of polyketone fiber material aiming for commercialization for the first time in the world , And the utilization of polyketone materials will be enhanced through the processing technology of yarn.

In addition, various functions such as color, UV stability, fastness and the like can be realized in aesthetic effect of an industrial material, which has been regarded as a weak point of existing industrial textile materials. .

Fig. 1 schematically shows a method for coating a polyketone yarn according to the present invention.
FIG. 2 is a photograph showing a cross section and a surface of a polyketone coated yarn which has undergone a yarn coating process according to the present invention.
Fig. 3 shows the tensile strength comparison data before and after the weathering test after the yarn coating according to the present invention.
Figure 4 shows height comparison data before and after the weathering test after the yarn coating process according to the present invention.

Hereinafter, the present invention will be described.

Unless defined otherwise, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Terms such as those defined in commonly used dictionaries are to be interpreted as having a meaning consistent with the contextual meaning of the related art and are to be interpreted as either ideal or overly formal in the sense of the present application Do not.

The present invention relates to a process for the production of a yarn, comprising the steps of: injecting a polyvinyl chloride coating or a thermoplastic polyurethane coating into an extruder for yarn coating; And applying a coating agent to the surface of the polyketone yarn by the extruder for coating a yarn.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view of a method for coating a polyketone yarn according to the present invention. FIG. As can be seen from FIG. 1, the fiber yarn can be coated on the polyketone yarn by a process in which the yarn is put into an extruder in which the coating agent melts, coated on the surface of the yarn, and wound through a cooling water tank and a capstan.

At this time, the coating step is carried out at a processing temperature of 160 ° C or less in consideration of the melting point and the heat resistance temperature of the yarn, and the processing speed is preferably 500 mPm or less in accordance with the number of filaments of the polyketone yarn. In order to improve the coating processability, there is a method in which a polyketone yarn material is subjected to processing steps such as ATY and ITY.

Here, the coating agent is preferably applied to the polyketone yarn at 0.400 g / m 2 or less, but is not limited thereto.

In addition, the coating agent may be a PVC coating agent or a TPU coating agent depending on the application, but may be imparted with functionalities to the yarn by mixing various functional pigment coating agents such as a UV stabilizer and a color master batch chip.

Further, after the step of applying the coating agent, the method may further include at least one post-processing process selected from the group consisting of a weaving process, a functionalizing process, a coating process, and a laminating process of the polyketone yarn.

Due to such a process, it is possible to provide a material having excellent functionality and mechanical properties for supplementing the disadvantages of the polyketone material such as color, UV vulnerability, and fastness.

Hereinafter, the present invention will be described concretely with reference to Examples. However, the following Examples and Experimental Examples are merely illustrative of one form of the present invention, and the scope of the present invention is not limited by the following Examples and Experimental Examples .

Example

A polyketone yarn and a PVC coating agent are put into an extruder for customized yarn coating for processing the tanned industrial textile material, and a PVC coating agent is applied on the surface of the polyketone yarn at a process temperature of 160 ° C or less and a process speed of 500mpm or less To prepare a polyketone coated yarn.

The cross-section and the surface photograph of the polyketone-coated yarn thus prepared are shown in FIG.

Experimental Example

In order to examine the characteristics of the polyketone yarn according to the present invention before and after the coating process, the polyketone coated yarn prepared in the examples was extruded at a temperature of 60 DEG C, a humidity of 60%, and a humidity of 60% using a weather resistance tester (Xenon Arc Weather-Ometer Ci5000) w / m ² for 1 ~ 7 days. The results of measuring the tensile strength of yarn based on KS K 0520 after treatment are shown in Table 1 below.

Before processing Before processing 1 day 2 days 3 days 7 days Tenacity (g / d) 17.1 15.48 15.79 13.94 14.64 13.86 Elongation (%) 5.7 4.9 5.3 5 5.2 4.9 Modulus (g / d) 351 405.3 392 373.2 366.5 383.7

Experimental Example 1

FIG. 3 shows the tensile strength comparison data before and after the weathering test after polyketone yarn coating processing.

The tensile strength of the polyketone fiber decreased by about 1.62 g / d after the coating of the yarn, and the tensile strength decreased slightly after 1 day of the weathering test. However, when the weather resistance test results before the polyketone yarn coating were compared, the weather resistance test value after the coating of the yarn was increased.

Experimental Example 2

Figure 4 shows the elongation comparison data before and after the weathering test after polyketone yarn coating processing.

As a result, the polyketone fibers showed more than 85% of the elongation properties of the polyketone fiber before coating after the weathering test. It is believed that the elongation properties of the yarn are not influenced even after the yarn coating process of the polyketone fibers.

Experimental Example 3

Table 1 shows the modulus comparison data before and after the weathering test after polyketone yarn coating processing.

Experimental results show that modulus of polyketone fiber is increased by more than 50g / d after yarn coating, and modulus value is higher than that of fiber before weathering. It is considered that the elastic modulus for tensile is increased due to the coating on the surface of the yarn.

Claims (1)

A polyvinyl chloride coating agent or a thermoplastic polyurethane coating agent in an extruder for coating a yarn; And
And applying a coating agent to the surface of the polyketone yarn by the extruder for coating a yarn,
Wherein the coating step is performed at a temperature of 160 DEG C or less and a processing speed of 500 mPm or less and a coating agent is applied to the polyketone yarn at 0.400 g /
The coating further comprises a UV stabilizer or a color master batch chip,
Further comprising at least one post-processing step selected from the group consisting of a weaving process, a functionalizing process, a coating process, and a laminating process of the polyketone yarn after the step of applying the coating material,
The coating agent is applied poly tensile strength live ketone circle 15.48g / d, elongation of 4.9%, a modulus of 405.3g / d, the polyketone yarns at a temperature of 60 ℃, a humidity of 60% of the amount of power 0.67w / m ² A tensile strength of 13.86 g / d, an elongation of 4.9% and a modulus of 383.7 g / d measured after 7 days of treatment.

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