KR101694380B1 - Apparatus for generating electrolysis reduction water - Google Patents

Abstract

The present invention relates to an electrolytic reduced water producing device capable of concentrating a pipe having a pipe-rod type electrode for separating and collecting hydrogen-rich water and oxygen-rich water using electrolysis and a rod having a through hole capable of flowing ions to the electrode.
An electrolytic reduced water producing device according to an aspect of the present invention includes a pipe-shaped structure having both ends penetrated, and a plurality of electrolytic reduced water generating units disposed in the pipe-shaped structure, .

Description

[0001] APPARATUS FOR GENERATING ELECTROLYSIS REDUCTION WATER [0002]

The present invention relates to an electrolytic reduced water producing device for separating, concentrating and collecting hydrogen-rich water and oxygen-rich water using electrolysis.

Water is an absolute element for all life on Earth to sustain life. About 70% of the human body consists of water, and about 80% of the infant body consists of water, about 83% of the blood, and about 86% of the lungs and liver. Therefore, when the water becomes insufficient, waste and toxins accumulate in the body to cause various diseases, and water plays a role of helping the exhaustion of waste in the human body and the intake of cellular nutrients.

A person consumes about 2.5 liters of water per day on average, about 0.4 liters in breathing, about 1.4 liters in urine, about 0.1 liters in feces, and about 0.6 liters in sweat. Therefore, about 2.5 liters of water should be supplied daily to a person, about 1 liter of food, about 0.3 liters as a by-product of nutrients converted into energy when synthesized in the body, and about 1.2 liters of water are supplied.

In this way, the water consumed by human beings must be clean water without pollution in order to prevent the generation of pollution and waste products. Also, since water plays a role in filtering out other wastes, the unclean water consumed by humans can not properly perform the function of filtering waste materials in the body. Therefore, drinking clean water without contamination is absolutely necessary to maintain health.

The human life in the outdoors is expanding due to the development of the leisure industry. Outdoor activities such as travel, vacation, mountain climbing, camping, exploring and taking pictures, overseas missions, outdoor work, outdoor sports, leisure, military operations, combat, terrorist attacks etc. . In addition, according to trends in frequency and intensity of various natural disasters such as global warming due to droughts, floods, earthquakes, typhoons, volcanic eruptions, tsunamis, tsunamis, storms, hurricanes, and tornadoes, It is isolated from the environment, or is inevitably subjected to human casualties.

In the situation where even emergency facilities and disaster preparedness equipments are not available, it is necessary to wait for rescue, to escape crisis situation, to powerless life, and even to survival facilities, human beings must drink a minimum amount of water , Second infections, etc., in order to prevent damage to the personal hygiene itself must be maintained or expected to escape. However, in the event of such an extreme crisis, it is inevitable that human beings are forced to eat and drink insecure food and water, and there must be a scene in the movie.

In other words, there may be various kinds of water even in various disasters. Even if it seems visually safe, there is a need to remove risk factors for drinking water. It is possible to prevent various diseases and to preserve life by removing various viruses, bacteria, protozoa, parasitic eggs, waterborne pathogens and the like present in the water. However, in order to survive, humans take risks depending on the situation and drink inappropriate water as drinking water. However, it is very likely that drinking contaminating water to modern people, infants, children, pregnant women, the elderly, and patients with weak resistance is very lethal. In order to solve such problems, a conventional technology for home, office and personal climbing has been introduced which destroys bacteria and viruses in water by using ultraviolet rays.

However, in comparison with this conventional technique, hydroxide ion (OH-) obtained by electrolysis of water is 180 times of UVC ultraviolet ray, 2000 times of ozone (O3), about 2 times of chlorine (Cl2) It has strong sterilization power of about 1.57 times more than hydrogen peroxide (H2O2) which is a disinfectant. In addition, hydroxide ions are safe because they are natural substances that are harmless to human body.

Hydrogen-rich water (electrolytic reduced water) has been known to have an antioxidative effect, and oxygen-rich water (acidic ionized water) is known to have an excellent sterilizing effect. Vitamin C Ascorbic acid is known to have antioxidant action, but oxidative reduction is a simultaneous and cascading reaction, so ascorbic acid is oxidized by active oxygen during the reduction of active oxygen. There is a problem that ascorbic acid is generated and damages the gene.

Since the antioxidants are subjected to a series of oxidation and reduction chain reactions, there is a risk that they may cause side effects.

However, the hydrogen of the hydrogen rich water (electrolytic reduced water) is combined with the active oxygen to reduce and remove the active oxygen, and finally it turns into water, and it is reported to the academic society as being safe to human body.

For example, a kidney, one of the organs of the human body, filters about 180 liters of water a day, with most of the filtered water being reabsorbed and part of the urine being discharged. The reason why kidneys can filter a large amount of water is because there is a channel called aquaporin, which can selectively transmit water to kidney cell membranes. Because the size of these water channel channels is very small, from 0.3 to 1.3 nanometers in diameter (one nanometer is one billionth of a meter), water 0.3 nanometers in diameter can pass through the water channel, but larger than the diameter of the water channel Materials with a diameter can not pass through. The size of the active hydrogen (hydrogen atom) is 0.1 nanometers and the size of the metallic nanocolloid (minerals) that carry active hydrogen is 1 nanometer or less, so it is possible to pass through the water channel, whereas vitamin C and beta carotene Because the molecular weight is about 10 to 30 times larger than water, it can not pass through the water channel. That is, even if the antioxidant having a reducing action such as vitamin or carotene can not enter the cell, the hydrogen-rich water can pass through the channel easily and can be discharged by replacing the active oxygen adhering to the cell with safe water.

The blood brain barrier is a mechanism that restricts the transfer of drugs, toxins, neurotransmitters, etc. that break down brain cell functions from the blood to the brain. It selectively passes nutrients such as glucose, amino acids, and nucleic acid components . This phenomenon is mainly caused by the action of cerebral vascular endothelial cells, which are easier to pass through the blood brain barrier as the lipid-soluble substance or small-sized substance which is easy to dissolve in oil. Therefore, when an antioxidant that is easy to dissolve in water such as vitamin C is supplied to the brain to protect the brain cells, the particles of the antioxidant are too large to pass through the blood brain barrier. However, all matter circulates through the body in a state of acceptance, and water can also be transferred to the brain or bones through capillaries. That is, if water can impart antioxidative properties, highly effective results can be obtained in improving the oxidation state of the whole body.

When water is electrolyzed, hydrogen-rich water rich in hydrogen and oxygen-rich water rich in oxygen can be obtained in the water. The hydrogen-rich water is called an electrolytic reduced water that obtains electrons and loses oxygen. The oxygen- It can be said to be an oxidized acidic water obtained. It is said that 2% of the oxygen used to make energy in the body by breathing is active oxygen, and 90% of all diseases cause active oxygen. Active hydrogen refers to hydrogen in atomic state, indicated by "H". In general, the hydrogen that we are talking about is molecular hydrogen by "H2". It is also known that active hydrogen easily binds to active oxygen and detoxifies active oxygen causing various diseases. It has been studied through researches that the body condition is improved by drinking the active hydrogen water, and it is proved that it is able to remove sufficient active oxygen quantitatively in the body, and a realistic mechanism for detoxifying active oxygen is explained physicochemically Therefore, advanced countries and large companies are conducting intensive research. According to media reports, the active hydrogen that causes all kinds of diseases to the human body is made harmless by the active hydrogen, and it can be said that the human health can be maintained and the life span can be greatly extended.

Professor Oita Shigeo of the Japanese Medical University published his first paper in the medical journal "Nature Medicine", which scientifically proved that hydrogen molecule (H2) can be used as an antioxidant in the prevention and treatment of various diseases, The molecule selectively protects the cells of the human body from oxidative stress by selectively reducing the most reactive hydroxyl radical (.OH) among active oxygen species. Oxidation stress is an oxidative stress that is generated inside our body, such as active oxygen, which is caused by antioxidant substances such as antioxidant enzymes (SOD, glutathione peroxidase, catalase, etc.) and vitamin C, polabonoids and carotenoids And is said to be removed. Oxidative stress (harmful reactive oxygen) damages DNA or cells in the human body, causing protein denaturation, lipid peroxidation, and deterioration of blood flow, resulting in various cancers, atopy, spots, freckles, obesity, myocardial infarction, diabetes, Cataracts, and aging.

The bactericidal action of hypochlorous acid in hypochlorous acid water is due to the oxidative damage to the in vivo DNA and enzyme of the hydroxyl radical generated by HOCI hypochlorite and hydrogen peroxide present in hypochlorous acid water It is estimated. It is similar to the sterilizing action mechanism that generates and sterilizes active oxygen which acts as an oxidant by oxidizing enzyme (Oxidase) such as NADPH of neutrophil, Neutrophil, which is one of the white blood cells in vivo. For example, the virus that causes food poisoning is immediately sterilized by hypochlorous acid water. It is possible to observe the collapse of the cell membrane and the nucleus and the coagulation of the cytoplasm by the treatment of hypochlorous acid water against Escherichia coli and Candida. Hypochlorous acid water can be observed in Escherichia coli, Yellow staphylococcus aureus, Pseudomonas aeruginosa, Vibrio, Gempro bacterium, It exhibits an excellent sterilizing effect against bacteria such as Streptococcus, Salmonella, Candida, Listeria, Erysinia and Yeast. This hypochlorous acid water shows a strong sterilizing power as compared with other sterilizing agents, and the sterilizing power is 80 times stronger than sodium hypochlorite (lactose) experimentally. When hypochlorous acid water (oxygen-rich water, oxidized acid water) is compared with the time required for 99% sterilization of E. coli by using hypochlorous acid water of 0.1 ppm of effective chlorine and sodium hypochlorite water, the hypochlorous acid water Since sodium (lactus) takes 120 minutes, hypochlorous acid water is estimated to be 80 times stronger than sodium hypochlorite (lactose) in test.

In addition, hypochlorous acid water (oxygen-rich water, oxidized acid water) shows high stability as a result of general toxicity test or mutagenicity test. It has lower bio-toxicity (1/50 ~ 1/100) than commercial sanitizing disinfectant, Is very small, so there is no particular risk even if you misuse it.

The hypochlorous acid water (oxygen-rich water, oxidized acidic water) has a low environmental load because chlorine concentration used is as low as 1/5 to 1/10 of that of general chlorine disinfectant and is easy to decompose and has no persistence. This reacts promptly when contacted with organic matter, resulting in a significant decrease in chlorine concentration and thus loss of activity during the flow into the wastewater treatment plant.

In addition, hypochlorous acid water (oxygen-rich water, oxidized acid water) is a generic chlorine-based disinfectant from the viewpoint of generation of disinfection by-products (disinfection by-products), and very little toxic substances such as chloroform, When hypochlorous acid water was used as a disinfectant, the amount of hypochlorous acid (oxygen-rich water, oxidized acid water, pH 2.7 effective chlorine concentration: 31 ppm, pH 5 .5, effective chlorine concentration: 25 ppm). When 50 g of cabbage and chicken 50 cm in 2 cm squares were immersed for 20 minutes, chloroform was not detected.

200 g of each of cucumber, cabbage, beef, and pork cut into 2 L of strongly acidic hypochlorous acid water (strong acidic volcanic acid, pH 2.5 to 2.6, effective chlorine concentration 27 to 40 ppm) was stirred for 10 minutes and the effective chlorine concentration As a result, no effective chlorine was detected in each sample. It was confirmed that hypochlorous acid water (oxygen - rich water, oxidized acid water) was very unlikely to remain in the food.

The effect of ascorbic acid, which is the main nutrient component, on the spinach was investigated by comparing the amount of ascorbic acid with the amount of acidic ascorbic acid In the case of the test.

It was confirmed that hypochlorous acid water (oxygen-rich water, oxidized acid water) acts on multifaceted growth factors such as cell wall DNA and enzymes of microorganisms.

The brain is a organ that strictly restricts the movement of substances using the blood brain gates and is very vulnerable to free radicals. Alzheimer's disease or Parkinson's disease became a social problem as society became more aging. Alzheimer's disease is a disease in which neurons, such as the hippocampus and tonsillitis, that play a very important role as memory entrances, die and die from dementia. Parkinson's disease is caused by neuronal cells that release neurotransmitter dopamine, It is a disease that occurs. Alzheimer's disease and Parkinson's disease are both called neurodegenerative diseases, which develop mainly after middle age. It is well known that active oxygen is involved in the death of these neurons. As arterial sclerosis progresses, blood vessels are temporarily blocked and then reperfusion of ischemia occurs, resulting in a large amount of reactive oxygen, resulting in the death of nerve cells. When hydrogen peroxide is applied to nerve cells, nerve cells are killed by self-destructive apotosis, but electrolytic reduced water (hydrogen-rich water) has been shown to inhibit neuronal cell death by removing active oxygen, The results of inhibition of cell death by glutamate toxicity were also reported. The electrolytic reduced water (hydrogen-rich water) removed intracellular peroxidation active oxygen but did not affect nitrogen monoxide. However, since cell death caused by the generation of nitrogen monoxide is suppressed, the cytotoxicity of peroxynitrite or hydroxy radical produced by the reaction of nitrogen monoxide and superoxide radical is reduced. Electrolytic reduced water (hydrogen - rich water) with active oxygen scavenging function can be expected to improve various diseases of the brain.

The reason why electrolyzed water (hydrogen-rich water, hydrogen-containing water) is helpful in improving Alzheimer's disease or Parkinson's disease is that this brain disease is caused by active oxygen, Because. Water is rapidly absorbed and rapidly transmitted to the brain. Through this, hydrogen, the most powerful antioxidant, is expected to be effective in improving brain diseases such as Parkinson's disease by removing active oxygen causing brain diseases and restoring oxidized cells . Similarly, it is expected to help improve brain diseases such as cerebral infarction and cerebral hemorrhage.

In 2009, it was discovered that the secrets of infinite proliferation of cancer cells are located at the end of the DNA of a cell called telomere, and as a result, the normal cells become shorter and the telomere shortens and the telomere disappears. Azera restores telomere through enzymes and grows infinitely without dying. It has been reported that "hydrogen interferes with the binding of telomerase and telomeres, causing cancer cells to turn into cells that can die normally" (telomere: attached to the end of the chromosome, A gene that indicates the state of telomerase, which keeps the telomeres from growing and helps keep the telomeres to some length even if cell division progresses. Hydrogen helps prevent cancer growth by eliminating toxic free radicals. In addition, attention has been paid to the fact that active oxygen in the body affects the onset of various diseases through experiments in culturing human cancer cells, and hydrogen in the electrolytic reduced water (hydrogen-rich water, hydrogen-containing water) "Human lung cancer cells and uterine cancer cells were treated with electrolytic reduced water (hydrogen-rich water, hydrogen-containing water) for one year. As a result, active oxygen in the cells was decreased and proliferation of cancer cells was delayed." The results have been published.

Cancer cells cause proliferation of trace amounts of free radicals. Hydrogen - rich cells act to remove these free radicals. Cancer cells lose their ability to proliferate due to the removal of free radicals. Once the proliferation is stopped, it is easy to die, which is characteristic of cancer cells, which can prevent the cancer from multiplying. According to this announcement, when human melanoma cells contacted with hydrogen-containing water, cell proliferation was suppressed to around 6%. In this case, the size of the cancer cell proliferation mass was reduced to about two-thirds, and the formation rate of the proliferation mass 54 to 72%. However, normal tongue cells have almost no change in cell proliferation even when they are exposed to hydrogen-containing water, so they are found to be almost harmless to normal cells. In other words, hydrogen is almost harmless to normal cells, but seems to have a preventive effect of oral cancer, oral salt, and sulphate.

In Japan, various functional products are released by using hydrogen-rich water. In connection with this, they are used for cosmetics, anti-aging, skin regenerating agent, skin moisturizer, skin whitening agent, skin softener and stress remedy. New products are being actively developed. It is applied to the treatment of various skin irritations such as hot springs, atopy treatment, omum and itch, and tan skin treatment due to overexposure to sunlight. The greatest feature and advantage of the hydrogen rich part is that hydrogen freely travels through the human body and safely removes the active oxygen generated in the human body. The fact that many diseases are caused by active oxygen has proved that the removal of active oxygen can prolong life, rejuvenate skin and prevent aging as well as various health promotion and beauty enhancement effects such as oral odor elimination . In particular, the hydrogen-rich water has excellent cleaning power, and it has been confirmed by experiments that the fruit is washed with tap water or the like and the hydrogen-rich water is washed with hydrogen-rich water for a much longer period of time. It has been confirmed that it has an effect on improvement.

Electrolytic reduction water (hydrogen-rich water, hydrogen-containing water) refers to water generated on the cathode side of an electrode when water is electrolyzed. At this time, acidic oxidation water (oxygen-rich water) is generated on the anode side of the electrode.

The electrolytic reduced water and the acidic oxidized water generating device are electrolytic water generator (Korean Food and Drug Administration) and the electrolytic reduced water is misplaced as alkaline ion water because it is alkaline.

Electrolytic reduction water is a functional water having an active hydrogen content abundantly and having a reducing action. Although the electrolytic reduced water is generally known as an alkaline ionized water, the alkaline ionized water and electrolytic reduced water are completely different concepts.

In particular, the electrolytic reduced water should be used separately from alkaline ionized water in the meaning of functional water (hydrogen-rich water, hydrogen-containing water) that has a function of removing various active oxygen as a result of containing water enriched with active hydrogen having a reducing power.

That is, the alkaline ionized water is simply an alkaline water containing ions, and the conventional alkaline ion water purifier is a water purifying apparatus that produces an alkaline water containing a hydroxide ion in which hydrogen is not dissolved.

As can be seen from the name, the water purifier has only a function of removing impurities in water and purifying it. In other words, it is the role of the water purifier to remove the mold odor of tap water, or to remove the carcinogenic substance trihalomethane and harmful substances to make safe and drinkable water. The simplest water purifier uses activated carbon to remove chlorine and impurities.

Considering the theory of electrolysis of water which has been continuously studied, and the effects of hydrogen-rich water and oxygen-rich water, the ORP-Oxidation Reduction Potential is minus, and the hydrogen- There is still a need for a portable device capable of generating abundant water, electrolytic reduced water (hydrogen-rich water, hydrogen-containing water).

The ballast water treatment system treats foreign aquatic organisms contained in ballast water (water placed on a ship to balance the ship) loaded in a foreign port with electricity and chemicals, It means a device that does not cause harm to the ecosystem even if it is discharged. When an oil tanker or a large cargo ship is not loaded with oil or cargo, the hull is not immersed in the water, making it difficult to maintain balance. In order to solve this problem, the water to be filled in the hull is the equilibrium of the ship, and when the ship is light and the ship is not immersed in more than a certain portion of the hull, the balance is difficult to maintain and the propeller is out of the water, Can be used to weight and balance the hull.

However, if the ship carrying the ballast water arrives at the destination and cargo is loaded, the ballast water is discharged again. In this way, 10 billion tons of water are being transported as ship equilibrium in the world every year, and more than 7,000 species are moving along the ship equilibrium. Most of them die in a new environment, but surviving species have a problem of disturbing and destroying ecosystems with strong survival and fertility.

For this reason, the International Maritime Organization (IMO) has mandated vessels delivered in 2012 to be equipped with a treatment system to remove microorganisms and pollutants contained in ship ballast water, and from 2017 it will be extended to all existing maritime vessels It is a plan. However, it does not solve the problem of completely killing marine life in the ballast water, and it should prevent secondary pollution from killing marine life. This is because the fungicide sprayed to kill the alien species can also kill the native species. In other words, the technology to sterilize the microorganisms in the seawater and discharge it to the sea without secondary pollution is necessary. In order to prevent the inflow of various aquatic organisms, microorganisms, and pathogens contained in the ballast water to other regions, Ultraviolet and ozone-based sterilization methods, electrolysis, deoxidation, drug injection, etc. are considered.

However, there is a problem in that the ultraviolet method has a simple apparatus and operation, but has a large energy consumption, and ozone has a disinfecting effect, but has a problem that an additional facility such as a neutralization facility becomes large.

The conventional electrolysis method has a problem that the sterilization duration is strong, but additional space is required for installation because additional equipment must be installed for corrosion of peripheral devices and electrolysis. In the case of electrolysis of cold seawater in polar regions (Antarctic and Arctic regions) and cold countries in accordance with the temperature change of seawater due to temperature drop and latitude difference of surface (mixed layer) of winter seawater in winter, electricity There is a problem that the efficiency of the decomposition is extremely lowered.

Hydrophilic ions (OH-) ionized by water molecules have a strong oxidizing power and the electrolytic hydrogen cation (H +) has strong reducing power .

The hydroxide ion (OH-) has a sterilization rate that is about 2000 times faster than ozone (O3) and about 180 times faster than UVC ultraviolet light. It is about twice as much as chlorine (Cl2), a sterilization disinfectant commonly used in tap water, Which is about 1.57 times more powerful than hydrogen peroxide (H2O2). In addition, the hydroxide ion is a harmless natural substance in our human body, so there are many great advantages and the removal performance is very good.

In addition, the deoxidation system has a problem that the installation cost is low but the removal performance is low.

That is, there is still a need for a ballast water electrolysis apparatus that is easier to implement and has superior performance.

In addition, conventional electric boilers (electric hot water heaters) use electric heaters such as nichrome wire and have a problem of low electric energy efficiency (1 Kwh = 860 kcal), and can provide only hot water, Can not provide.

An object of the present invention is to provide an electrolytic reduced water producing device capable of high concentration of functional water through specific configuration and arrangement of electrodes in electrolytic reduced water production using electrolysis, The purpose is to do.

An apparatus for generating electrolytic reduced water (neutral sterilization water) capable of concentrating and separating and collecting hydrogen-rich water and oxygen-rich water easily, which has a negative ORP-oxidation reduction potential and an active hydrogen- Hydrogen-rich water, and hydrogen-containing water) and an oxygen-rich water-soluble polymer.

It is an object of the present invention to provide an apparatus capable of mass production of sterilized hot water and disinfected hot water by means of a micro-electrolytic water producing device that combines an electrode structure with an electrode ion boiler capable of selecting cold or hot water depending on the operation of a boiler.

In addition, in order to solve the problem of extremely low efficiency of electrolysis when cold seawater in polar or cold countries is electrolyzed in accordance with the temperature change due to the falling temperature of the seawater surface (mixed layer) in winter and the difference in latitude, Efficiency electric ion boiler (electric hot water heater) device which uses the seawater itself as a heating element without needing a large extra installation space and is installed in the ballast water tank through the ballast water pump By raising the cold seawater entering the tank to the optimal temperature for electrolysis and secondly electrolyzing the seawater whose temperature has risen, even if the seawater is lowered in temperature by season or latitude difference, And a function of performing decomposition is added.

An electrolytic reduced water (neutral sterilized water) generating device for easily separating and collecting hydrogen-rich water and oxygen-rich water through electrode arrangement in the production of electrolytic reduced water using electrolysis is provided, and a device for generating acidic electrolytic water It is an object of the present invention to provide a device capable of sterilizing ship ballast water by installing the device inside the piping of a ship without requiring a separate additional installation space.

It is another object of the present invention to provide an electrode ion boiler of a new structure which does not require any additional installation space by disposing an electrode structure in a pipe by using water as a heat conductor without using a heat conductor such as a nichrome wire.

An electrolytic reduced water producing apparatus according to an aspect of the present invention includes a pipe-like structure having both ends penetrated and an anode disposed on the inside and outside of the pipe-like structure, having a polarity by being supplied with electric power, and partially or entirely immersed in the pipe And a plurality of pipe-shaped electrodes for electrolyzing the liquid.

The electrolytic apparatus for marine vessels according to another aspect of the present invention is disposed inside a pipe-like structure through which both ends of a pipe connected to a marine ballast water tank, a marine ballast water tank inflow pump and a ballast water tank are passed, Polarity and penetrates at both ends and seawater flowing into the ballast water tank is first heated to make hot water and secondarily becomes hot water to electrolyze the hot water with ion activation to obtain a constant electrolysis efficiency And a plurality of pipe-shaped electrode structures for holding the pipe-shaped electrode structures.

According to another aspect of the present invention, there is provided an electrode ion warm water heater apparatus comprising: a plurality of electrodes for electrolyzing a fluid flowing in a pipe; a plurality of electrodes provided inside the pipe to occupy no additional space; And is an electrode ion boiler (hot water heater) device used as a sieve.

The electrolytic water producing apparatus according to the present invention is powered by a dry cell (including a rechargeable battery, a solar charger) and other direct current adapters, is free from power supply, and can be miniaturized to be portable.

It is possible to concentrate by electrolyzing a small amount of water contained in a personal cup or bottle regardless of time and place, thereby shortening the collection and separation time, reducing the ORP-oxidation reduction potential, (Hydrogen-dissolved water, hydrogen-containing water) and has an effect of easy drinking.

The user is able to electrolyze the small amount of water while observing the bubbles through the eyes, so that the ORP-Oxidation Reduction Potential (minus) and the hydrogen-rich active hydrogen-rich water are high in the skin penetration ability, It can be used for water, face pack, wrinkle improvement, and is easy to use.

It can be used as a portable sanitary water purification device that removes various viruses, bacteria, waterborne diseases, etc. that are inhabited by water. It contributes to the health of users by inhibiting the generation of carcinogenic substances due to organic substances and disinfectants contained in wells and tap water. .

The electrolytic solution can be made into a beneficial functional water in which the water cluster is decomposed to a small extent and absorbed in the human body, thereby contributing to health.

Reducing the active oxygen in the body is capable of reducing the number of antioxidant-reducing water (functional water) that can be easily made anywhere and at any time, and it can be applied to the skin, thereby improving the health and beauty of each person, It is effective to improve the performance, to remove the active oxygen of the patient, to help improve immunity and to recover, and to provide an easy means of survival that can prevent the waterborne disease in an individual disaster.

Military personnel, police officers, firefighters, etc., can be used in various ways such as personal recuperation, disaster response, various rescue operations, military operations, and military exercises, thereby enhancing combat power and operational capability and preventing waterborne infectious diseases. The present invention can be applied to disaster prevention and defense personal portable products that greatly improve crisis coping ability.

 Oxygen-rich water (acid oxidized water) generated from the positive electrode has high sterilizing power and can be used for a variety of purposes such as travel, vacation, mountain climbing, camping, outback exploration and shooting, overseas missions, Terrorism, typhoons, floods, earthquakes, droughts, tsunamis, volcanic eruptions, hurricanes, tornadoes, and other accidents and distress. Disinfection and deodorization of baby bottles, and disinfection and sterilization of food such as vegetables and fruits, it is possible to prevent the water-borne infectious diseases without drinking water and boil water for emergency, It has the effect of acting as a device.

There is no need to boil or live to disinfect utensils, utensils, baby bottles, toys, etc., because it has the effect of maintaining the lives of emergency patients through the removal of active oxygen and wound disinfection, which are more common in the injured body.

Hydrogenated hydrogen-rich water (electrolytic reduced water) which is dissolved in hydrogen richly by electrolysis of natural water (tap water), cold coffee, various tea, and drinking water according to use, hot coffee which is rich in hydrogen, hot various tea, cold It can be easily made directly by individual drinkers, regardless of the time and place, and can be made to drink and make it drinkable (body) (bath), and it has an effect of contributing to health promotion and beauty enhancement of individual and multiple.

In addition, the electrolytic reduced water (hydrogen-containing water, dissolved hydrogen water) generating device is disposed inside a cross, a statue formed in churches, cathedrals, immortals and the like, thereby providing an additional function to the drinking water tank.

Future food technology trend is to eliminate consumers' growing concern about residual pesticide and food pollution, so choose oxygen-rich water (micro-acidic electrolytic water, hypochlorous hypochlorous acid water or strong acid hypochlorous acid water) It is easy to collect and separate by cold and cold water, and it can be used directly. It can be applied to food sterilizer, food processing, disinfection of agricultural and livelihood facility, sterilization device, Sanitary disinfection can be maintained at all times by cleaning and disinfecting indoor and outdoor water using sterilized water regardless of temperature.

According to the Korea Technology Promotion Agency's (KIEP) Technology and Prediction Center, the infectious disease is reported to increase by 4% every time the air temperature increases by 1 ℃. It is anticipated that in case of unforeseen disasters, .

As the elderly society accelerates, it is effective to provide a healthier aging society as well as health and convenience by preventing the deterioration of antioxidant function, brain function and chewing function.

The hydrogen-rich water (hydrogen-dissolved water, hydrogen-containing water) can be consumed by using the electrolytic reduced water producing apparatus of the present invention, and the hydrogen-rich water can be sprayed Through bathing, it can be expected to improve immunity and prevent disease, promote growth of various crops, and prevent pests and diseases.

Optionally, it can be applied to food processing and farming and fishing village production facilities in the winter by providing versatile sanitizing hot water and disinfected hot water mass production device through the acidic electrolytic water producing device combining electrode ion heater and electrode arrangement, , Mad cow disease, foot-and-mouth disease, etc., can be sprayed directly to house and livestock, so that hygienic condition can be maintained at all times. Also, heat conservation through house heating and high-efficiency electrode ion boiler It is possible to increase the competitiveness of rural areas.

In addition, it does not require a separate installation space inside the narrow space vessel, and it is installed in the existing ship equilibrium water pipe, does not affect the flow of the fluid, occupies the minimum space, The efficiency of installation and maintenance can be greatly reduced.

In addition, it is possible to maintain high electrolysis efficiency even when electrolyzing cold seawater due to changes in surface temperature (mixed layer) and latitude difference of cold seawater in winter, thereby saving energy and preventing marine pollution , And the sanitary condition can be maintained by cleaning and disinfecting on board the sterilized water.

It is possible to provide a high-efficiency electrode ion boiler (hot water heater) device which does not require any additional space through the specific electrode arrangement structure but occupies an additional space by installing it in the middle of the pipe And the cost of installation and maintenance is reduced, so that the application range is wide.

Vortex derivatives can be used to increase the contact time between the electrodes and the fluid by inducing the vortex phenomenon by rotating the fluid in and out of the fluid in two directions to activate the electrolysis and to expect the energy saving effect, It is possible to prevent the phenomenon that the sand or foreign matter is settled in the piping and the piping is piled up, thereby preventing scale from being generated.

The effects of the present invention are not limited to those mentioned above, and other effects not mentioned can be clearly understood by those skilled in the art from the following description.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a top view and side cross-sectional view of an apparatus for generating pipe-type electrolytic reduced water (functional water) according to an embodiment of the present invention. Fig.
2 is a side sectional view and a structural example of a pipe-type electrolytic reduced water (functional water) generating apparatus according to another embodiment of the present invention.
3 is a cross-sectional view showing an electrode arrangement of an apparatus for producing pipe-type electrolytic reduced water (functional water) according to an embodiment of the present invention.
FIG. 4 is a configuration diagram showing a power supply unit for supplying power to an electrode of a pipe-type electrolytic reduced water (functional water) generating apparatus according to an embodiment of the present invention and a pole changeover switch for switching an electrode.
5 is a view showing the configuration of an electrode connector of a pipe-type electrolytic reduced water (functional water) generating apparatus according to an embodiment of the present invention.
6 is a conceptual view illustrating a connection structure of a power source unit and an electrode according to an embodiment of the present invention.
7 is a conceptual diagram showing a connection structure of a power supply unit, a switch, a pole changeover switch and an electrode according to an embodiment of the present invention.
FIG. 8 and FIG. 9 are views showing an example of a coupling relationship with a power supply unit of a pipe-type electrolytic reduced water (functional water) generating apparatus according to an embodiment of the present invention; FIG.
10 is a configuration diagram showing the arrangement of an electrode connector and electrodes according to an embodiment of the present invention;
Figs. 11 and 12 are illustrations showing a spring-type or pipe-type electrode according to an embodiment of the present invention; Fig.
13A and 13B are views showing a filter disposed at one end of an electrolytic reduced water (functional water) generating device according to an embodiment of the present invention.
13C and 13D are diagrams showing a configuration in which a barrel is additionally disposed at one end of an electrolytic reduced water (functional water) generating device according to an embodiment of the present invention to supply a hydrogen-rich water and an oxygen-rich water to a user.
14 is an exemplary view showing a configuration in which a tube is disposed at one end of an electrolytic reduced water (functional water) generating device according to an embodiment of the present invention to supply hydrogen gas to a user (patient).
15 is an exemplary view showing an example in which an electrolytic reduced water (functional water) generating device according to an embodiment of the present invention is applied to a large structure (crossed shape).
16 is a view showing a spray head attached to an electrolytic reduced water (functional water) generating apparatus according to an embodiment of the present invention.
17 is a view illustrating a process of mixing hydrogen-rich water and oxygen-rich water collected and separated by using an electrolytic reduced water (functional water) generating device according to an embodiment of the present invention.
18 is an exemplary view showing a pipe-type electrode arrangement for mass production of hydrogen-rich water and oxygen-rich water according to an embodiment of the present invention.
19A is a conceptual diagram illustrating a process of separating hydrogen-rich water and oxygen-rich water using two pipe-shaped electrodes according to an embodiment of the present invention.
19B is an exemplary view showing a process of concentration of hydrogen-rich water and oxygen-rich water according to an embodiment of the present invention.
Fig. 20 is an exemplary view showing an embodiment in which pipe-shaped electrodes are arranged so that mass production can be achieved in the hydrogen-rich water and the oxygen-rich water mixture shown in Fig.
FIG. 21 is a conceptual diagram illustrating a process of a ship equilibrium water treatment of an electrolytic reduced water (functional water) generating apparatus applied to a ship according to another aspect of the present invention. FIG.
22 is a side sectional view showing an arrangement of electrodes constituting an electrolytic reduced water (functional water) generating apparatus applied to a ship according to another aspect of the present invention;
23 is a view illustrating an electrolytic reduced water (functional water) separation process according to an embodiment of the present invention.
24 is an electrode configuration diagram of an electrolytic reduced water (functional water) generating device attached to a piping line of a ship according to an embodiment of the present invention;
25 is a conceptual diagram showing a flow direction of an electrode, a double vortex induction unit, and ship ballast water of an electrolytic reduced water (functional water) generating apparatus applied to a ship according to an embodiment of the present invention.
26 is a view showing an example of a vortex phenomenon of a fluid by a double vortex induction unit and a vortex derivative in a marine electrolytic apparatus according to an embodiment of the present invention.
FIG. 27 is an exemplary view showing an embodiment in which a double vortex induction portion of a marine electrolytic apparatus according to an embodiment of the present invention is coupled to both ends of a pipe-like structure; FIG.
28 is an exploded perspective view of the pipe structure and the double vortex guide shown in Fig. 27;
29 is a view showing an example of coupling of a double vortex induction unit and a pipe-like structure of a marine electrolytic apparatus according to an embodiment of the present invention.
FIG. 30 is an exemplary view showing an embodiment in which a water tank containing a fluid according to an embodiment of the present invention induces a phenomenon of vortex, and an embodiment in which a plurality of pipe electrodes are combined and arranged so as to be mass-produced in a Vortex water tank.
31 is a view for explaining an embodiment in which a water tank containing the fluid shown in Fig. 30 induces a phenomenon of vortexing in a cyclone manner; Fig.
32 is a schematic view of an apparatus in which an electrode ion boiler (hot water heater) and a pipe strainer are combined according to another aspect of the present invention.
33 is a conceptual view showing a phenomenon in which a fluid swirls due to a double vortex phenomenon due to a double vortex derivative according to an embodiment of the present invention;
34 is a side sectional view showing a single-phase pipe-type electrode rod disposed in a pipe of an electrode ion boiler apparatus according to an embodiment of the present invention;
35 is a side sectional view showing a pipe-type three-phase electrode rod disposed in a pipe of the electrode ion boiler apparatus according to the embodiment of the present invention;
36 is a side sectional view showing a structure in which a through hole for ion passage is formed in a pipe type three-phase electrode rod disposed in a pipe of an electrode ion boiler apparatus according to an embodiment of the present invention;
37 is a view showing a pipe-type electrode rod arranged in a three-phase four-wire type or a three-phase three-wire type according to the embodiment of the present invention.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the drawings.

FIG. 1 and FIG. 2 are views showing the electrode arrangement of a pipe-type electrolytic reduced water (functional water) generating apparatus according to an embodiment of the present invention.

An electrolytic reduced water producing apparatus according to an embodiment of the present invention is disposed inside a pipe-like structure 10 and a pipe-like structure 10, both ends of which pass through, and is polarized by a power source, And includes a plurality of electrodes (100, 200) for electrolysis. The plurality of electrodes 100 and 200 include a first electrode 100 and a second electrode 200. The first electrode 100 and the second electrode 200 are formed in a virtual shape in the pipe- Are disposed inside and outside the zone based on a predetermined zone, or are disposed apart from each other in the inside of the pipe-like structure.

Figure 1 shows a configuration in which the first electrode 100 and the second electrode 200 are arranged inside and outside the zone with reference to a virtual predetermined zone inside the pipe-like structure 10, The first electrode 100 and the second electrode 200 are disposed to be spaced apart from each other in the inner structure 10 of the first embodiment.

As shown in FIG. 1, a diaphragm 400 for passing only insulation or ions is formed between the first electrode 100 and the second electrode 200, and a diaphragm 400 for passing only ions or ions is formed between the first electrode 100 and the second electrode 200, A diaphragm 400 is formed on an outer circumferential surface of the electrode 100 and the second electrode 200 to allow only insulation or ions to pass therethrough.

The first electrode 100 and the second electrode 200 are pipe type electrodes having bipolar and negative polarities and including an inner space surrounded by the first electrode 100 and the second electrode 200, respectively.

In the case where water is electrolyzed in the first electrode 100 and the second electrode 200 in the electrolysis, water is electrolyzed to form 2H ₂ O → 4 H ⁺ + 2 in the first electrode 100, The increase of O + 4eH ⁺ and the decrease of OH - result in the generation of many oxidizing ions, and the water electrolyzed in the first electrode 100 becomes oxygen rich. 2O is ultimately O ₂ , and a part thereof is dissolved in water. Oxygen-enriched oxygen is collected in the first electrode 100, so that oxygen becomes a large amount of water. Anions are collected in the first electrode 100, A reaction occurs in which the first electrode 100 is deprived. Therefore, chlorine gas (Cl 2) and hypochlorous acid (HClO) are generated according to the reaction formula 2 Cl ^- + 2 e → Cl ₂ , Cl ₂ + 2 H ₂ O → 2 HClO + 2 H ⁺ + 2 e.

In the second electrode 200, that is, the (-) cathode electrode, OH- increases by the reaction formula 4 H ₂ O + 4 e → 4 OH ^- + 2 H ₂ , and hydrogen abundance is obtained by decreasing H +. At this time, hydrogen (H 2) gas is generated, and hydrogen ions, which are dissolved in water and positively charged, collect in the second electrode 200 to become hydrogen rich antioxidant rich in hydrogen. Cations are gathered in the second electrode 200, and a reaction occurs in which electrons e are received from the second electrode 200. At this time, some of the minerals such as calcium, magnesium, sodium, potassium in the water are ionized together, and reductive ions are generated as the electrons e increase and the redox potentials (ORP) decrease to minus

The electrolytic reduced water producing apparatus according to an embodiment of the present invention can drink cold water, coffee, various tea, various beverages, etc. as hydrogen rich water (electrolytic reduced water) By applying the electrolytic reduced water generating device according to the invention to a personal portable electrolytic reduced water generator, the user can carry it with him or herself regardless of the place and time, and can easily use it, so that the health promotion and beauty enhancement effect can be expected.

(Hydrogenated water), which is widely known, can be easily obtained. Therefore, it is possible to produce multipurpose electrolytic reduced water (functional water) which insects, sterilize and purify unsafe polluted water in the event of natural disasters and various accidents Small number, disinfection sterilized water production) is possible.

Since the anode water and the cathode water can be separated through the construction and arrangement of the pipe-type electrode according to the embodiment of the present invention, it is easy to concentrate electrolytic reduced water (functional water) and oxidized water (oxygen-rich water).

The size of the electrolytic reduced water (functional water) generating device that can be enriched is small, medium and large, and it can be manufactured in accordance with the application. It is possible to produce electrolytic reduced water (containing electrolytically reduced active hydrogen, (The number of dissolved hydrogen atoms present therein) can be easily produced.

Alkaline ion water purifiers approved by the KFDA are alkaline ionized water (ionic alkaline water) containing no dissolved hydrogen, which has a partial effect on the treatment of gastric hyperplasia and gastritis.

According to the present invention, the number of functional groups such as the active hydrogen-rich water in which hydrogen is dissolved and the number of oxygen-rich water in which a large number of oxidizing ions capable of sterilization and disinfection are present are minus in the ORP-oxidation reduction potential And it is possible to concentrate such functional water.

In addition, since the electrolytic reduced water (functional water) producing apparatus according to one aspect of the present invention contains hypochlorous acid in the acidic oxidized water (oxygen rich water) generated on the first electrode 100 side, it has germicidal power and is present in the wild and accident environment It is possible to remove various viruses, bacteria, microorganisms, various parasites and waterborne pathogens in the water, and thus the electrolytic reduced water producing device according to one aspect of the present invention disinfects medical instruments, various tools necessary for survival, It is applicable to disinfection and sterilizer for various kinds of food such as fruit and fruit. In addition, disinfecting and disinfection of wounds caused by a situation in which no emergency medicine is prepared can be substituted for the disinfectant. The electrolytic reduced water (functional water) obtained through the second electrode 200 even in an emergency situation and an accident environment has the effect of removing active oxygen which causes aging and various diseases.

The miniature electrolytic reduced water generator according to one aspect of the present invention can be easily carried by anyone and can be used for electrolysis of various kinds of water, food water, hot coffee, tea, and drinking water to remove active oxygen generated in the body And can collect and separate electrolytic reduced water (hydrogen-rich water) to be able to drink or inhale and be applied to the body (wound).

The first grade of nature is livestock or the side shrimp, and it can be eaten through simple water purification. From the second grade, where the larvae live, they can be used as drinking water for sedimentation and filtration. However, it is possible to survive by preventing various diseases by removing various viruses, bacteria, unidentified microorganisms, various parasites, and waterborne pathogens in the first and second water. In addition, the third grade in which the dragonfly, leech, and water snails live, the dragonfly moth, the fourth grade of the fly larva, the insect worm, and the earthworm's 5th grade are suitable water for chemical ingestion . During electrolysis of water, hydrogen (H +) and hydroxyl (OH-) are produced, and the hydroxyl group (OH-) binds to hydrogen (H +), which is a cell membrane component of bacteria. Usually, the oxidation-reduction reaction accompanies the exchange of electrons. Since the electron exchange function takes electrons from the cell membrane necessary for the metabolism and survival of Salmonella and Listeria including E. coli, hydrogen (H +) and hydroxyl (OH- ) Are combined and reduced to water. Various viruses, bacteria, etc. living in water in nature are deprived of hydrogen (H +) and cell membrane and cell nucleus are destroyed and sterilized and killed within a short time.

3, 4 and 7, an apparatus for generating electrolytic reduced water (functional water) according to an embodiment of the present invention includes a first electrode 100 and a power source 600 for applying power to the second electrode 200 The power source 600 includes a power source 610 for applying power to the first electrode 100 and the second electrode 200 and a power source 610 for applying power to the first electrode 100 and the second electrode 200. [ And a pole changeover switch 620 for switching polarity. The polarity of the first electrode 100 and the polarity of the second electrode 200 can be changed by using the pole changeover switch 620, thereby suppressing scale generation. The power unit 600 is a power source 10 that provides power to the first electrode 100 and the second electrode 200 for electrolysis and may be applied to general electricity, solar light, a rechargeable battery, a battery, have.

8 and 9, the power supply unit 600 of the present invention may be integrally formed with the pipe-like structure 10 including the first electrode 100 and the second electrode 200, It is possible to connect with the pipe-like structure 10.

The electrode connector 700 shown in FIGS. 5 and 10 is preferably a connector that surrounds the outer peripheral surfaces of the first and second electrodes 100 and 200 formed of the pipe-like structure 10.

11 and 12 are diagrams showing an example of a pipe-type electrode. In order to increase the contact area with a liquid (for example, water) to be electrolyzed as much as possible, a spring-shaped electrode or a triangular cone And it is a basic structure that a flat plate is formed in a pipe shape as shown in Fig.

The first electrode 100 is formed in a pipe shape in which a flat plate is rolled in order to enlarge the area of the electrode. The second electrode 200 is formed in a predetermined area by calculating the length and the width in proportion to the area of the first electrode 100 So that the area of the first electrode 100 and the area of the second electrode 200 can be adjusted.

As shown in FIG. 13A, the first electrode 100 and the second electrode 200 are connected to the filter unit 900 disposed at the other end, which is formed on the opposite side of one end of the liquid immersion unit. The filter unit 900 includes at least a reductive block filter 910 or positive charge magnetic field filter 920 that filters impurities including residual chlorine in the liquid electrolyzed by the first electrode 100 and the second electrode 200 Quot; In addition, the produced acidic oxidation water (oxygen-rich water) can be sprayed through the spray head 140.

As shown in FIG. 13B, the reducing block filter 910 is composed of a sediment layer such as gravel, sand, activated carbon, cotton and the like to filter impurities such as residual chlorine. The positively charged magnetic field filter 920 is constructed so that the magnetic fields of the magnets face each other and the electrolytic reduced water (functional water) is passed through the central portion of the magnetic force lines to attach the magnetic field filter to the barrel portion immediately before drinking, can do. The remaining filter elements 900 for removing impurities such as residual chlorine and hypochlorous acid ions in the hydrogen-rich water and the total trihalomethane and the like may be formed of metals (stainless steel, cast iron, aluminum, Titanium, and alloys), plastics (PE, PP, Teflon, etc.), and rubber. By using the adsorption properties of charcoal made by treating oak, coconut, etc. with high heat, chlorine, bad smell, chemical Or the like can be connected or selectively connected, so that the small filter and the magnetic processor by the magnet can be freely detached and attached depending on the use.

As shown in Figs. 13C, 13D, and 19, the pipe-type barrel 120 can be used as a water line for drinking water when drinking water (hydrogen-rich water) The first and second electrodes 100 and 200 spaced apart from each other and the oxygen-rich water and the hydrogen-rich water separated and collected from the second electrode 200 may be divided into separate barrels 110 and 120. The oxygen-rich water that can be obtained through the barrel 110 can be used as sterilizing water, and the hydrogen-rich water that can be obtained through the barrel 120 can be consumed for the removal of active oxygen.

14, the other end of the filter unit 900, one end of which is connected to the barrel 120, is connected to a tube 130 that carries hydrogen gas, , The user can insert the tube into the nose and suck the hydrogen gas to remove the active oxygen. In the case of emergency patients who can not drink hydrogen-rich water by themselves, it is possible to induce the hydrogen gas to be inhaled by using the tube 130 to remove the active oxygen in the body. Also, the oxygen-rich water collected through the barrel 110 can be sprayed through the spray head 140 and used as sterilizing water.

As shown in FIG. 15, an electrolytic reduced water (functional water) generating device according to an aspect of the present invention is disposed inside a statue of a cross, a temple of a church, a church for sanitizing drinking water of a multi- It is possible to provide abundant water. The so-called "miracle water" in the same places as Lourdes's mothers was also analyzed to be high in hydrogen content, so that the electrolytic reduced water producing device according to one aspect of the present invention was applied to such a common facility, Effect can be expected. In addition, a plurality of electrolytic reduced water (functional water) generating devices according to one aspect of the present invention can be configured to easily separate and collect the oxygen and hydrogen gas generated according to the application, and a large number of pipe- As it is possible to selectively produce rich water and oxygen rich water, it can be used for hydroponic and various crop cultivation, various kinds of aquarium, aquaculture farm, cattle, pig farm, livestock farming industry.

As shown in FIG. 16, an electrolytic reduced water (functional water) generating device according to an aspect of the present invention includes a spray head 140 disposed at the opposite end of one end of a first electrode 100, ). That is, the oxygen-rich water generated in the pipe of the first electrode 100 may be sprayed directly through the spray head 140, or may be sterilized by disposing of the other end, use. It is also possible to use sterilized water for various utensils, foods such as vegetables and fruits.

17, an apparatus for generating electrolytic reduced water (functional water) according to an embodiment of the present invention includes a first electrode 100 and a second electrode 200, And mixing unit 850 for mixing according to the set ratio. At this time, it is possible to selectively concentrate the oxygen-rich portion and the hydrogen-rich portion by disposing a valve in the flow path through which the oxygen rich portion and the hydrogen rich portion are discharged. By using the mixing part 850, the hydrogen-rich water and the oxygen-rich water can be appropriately mixed with the hydrogen-rich water and the Ph-neutral water depending on the case, so that hydrogen-rich water and oxygen-rich water can be selectively produced according to the application.

As shown in FIGS. 18 and 20, a plurality of electrolytic reduced water (functional water) generating devices according to one aspect of the present invention may be provided for mass production, or a plurality of electrolytic reduced water A plurality of electrodes 200 can be arranged.

FIG. 19A is a conceptual view illustrating a process of separating hydrogen-rich water and oxygen-rich water using two pipe-shaped electrodes according to an embodiment of the present invention. FIG. Water concentration process.

As shown in Figs. 19A and 19B, a valve is disposed in a flow passage through which hydrogen-rich water and oxygen-rich water generated by electrolysis are discharged. 19B, when the valve disposed on the first electrode 100 side is in the ON state and the valve disposed on the second electrode 200 side is in the OFF state, the hydrogen rich portion can be concentrated. On the other hand, when the valve disposed on the first electrode 100 side is in the OFF state and the valve disposed on the second electrode 200 side is in the ON state, the oxygen rich portion can be concentrated.

As shown in Figs. 21 and 22, the electrolytic apparatus for marine vessels according to another aspect of the present invention includes a ballast water tank 12 and a pipe-like structure 10 having both end portions penetrated therethrough, And a plurality of electrodes (100, 200) having a polarity and for electrolyzing seawater flowing into the ballast water tank (12). The plurality of electrodes 100 and 200 include a first electrode 100 and a second electrode 200. The first electrode 100 and the second electrode 200 are formed in a virtual shape in the pipe- Are arranged on the inside and outside of the zone on the basis of a predetermined zone or are disposed apart from each other inside the pipe-like structure 10. The first electrode 100 and the second electrode 200 are installed horizontally in the middle of the piping, so that they do not require a separate installation space and are easy to maintain.

As shown in Fig. 21, when the seawater is introduced into the pipe-like structure 10 of the electrolytic apparatus for marine use, the electrode ion heater unit 30 is disposed at the front end.

In the case of a cold season or a cold country such as polar regions due to latitude, the temperature of the seawater will be relatively low compared to other provinces. If such cold seawater is used as a ballast water, There is a problem that it is extremely deteriorated.

Therefore, the electrode ion heater unit 30 electrolyzes the cold seawater to sufficiently raise the temperature of the seawater. When the salt (NaCl) is dissolved in water, it dissociates into a sodium cation (Na +) and a chlorine anion (Cl-) and becomes an electrolyte solution. Since seawater is a substance divided into (+) charged particles and (-) charged particles as an electrolyte, when electricity flows in seawater, the positive ions move to the negative electrode and the negative ions move to the positive electrode. And the molecules are subjected to friction due to vibration to generate heat (convert heat).

The electrode ion heater unit 30 applied to the present invention uses a plurality of electrodes so that electricity is applied to the seawater having a high electrical resistance so that the positive ions move to the negative electrode and the negative ions move to the positive electrode every 60 seconds, And the plurality of electrodes are provided with a pipe-type electrode structure inside the pipe to occupy no additional space, and is an energy saving type high-efficiency hot water heater that uses seawater itself as a heating element.

When the seawater whose temperature is raised by the electrode ion heater unit 30 flows into the inside of the pipe-like structure 10, the first electrode 100 and the second electrode 200 inside the pipe- There is an effect that the electrolysis efficiency is higher.

As shown in FIG. 22, the ballast water electrolyzed by the electrolysis of the first electrode 100 and the second electrode 200 is provided with a valve in each discharge flow path, It is possible.

23, the ballast water electrolyzed by the electrolytic action of the first electrode 100 and the second electrode 200 can be separated or mixed after being separated from each other. That is, it is possible to separate the hydrogen-rich water and the oxygen-rich water separately according to the application, or to separate the raw water into the hydrogen-rich water and the oxygen-rich water and mix them. It is possible to increase the neutralization efficiency of the residual chlorine produced excessively by passing the ballast water of the ship through the mixing device before discharging it to the ocean. It is also possible to increase the neutralization efficiency of the electrolytic water (acidic hypochlorous acid water: Ph 5 ~ ~ 60 ppm), it has a strong sterilizing power in a short time at a relatively low effective chlorine concentration and protects the environment and prevents marine pollution because chloroform is not produced even if it comes in contact with organic matter in an environmentally friendly manner.

In seawater, sodium hypochlorite (NaOCl) is generated from sodium chloride, which is contained in about 3% of the seawater, and is utilized to prevent the attachment and propagation of fresh water and marine life by the strong sterilizing power of sodium hypochlorite.

There is a need for a method for improving the electrolytic efficiency by reducing the adherence of foreign substances in the operation of the electrolysis apparatus of seawater and a technique for minimizing the marine pollution due to excessively generated electrolytic water, , The electrolytic apparatus for marine vessels is primarily designed to remove the biological organisms from aquatic organisms having a diameter of 50 microns or more by modifying the flow pattern of the ballast water by installing a process tube made in the form of a filter, A high-efficiency electrolytic unit is installed to generate residual chlorine to completely remove remaining aquatic organisms and microorganisms. To completely remove marine life, the excess chlorine residue is treated to restore similar to natural sea water. A marine electricity using a high efficiency electrolysis apparatus including a neutralization treatment apparatus Decomposition device.

The ship's electrolytic apparatus physically removes more than 50 microorganisms by using a primary filter-type water treatment pipe in the ballast water electrolysis disinfection and disinfection treatment of ships. The structure of the electrolysis electrode, which is a secondary treatment device, is constructed as a pipe-dong type as shown in Figs. 21 to 25, so that electrolysis occurs in the flow of the fluid without disturbing the flow of the fluid, So that an improvement in efficiency can be expected. In addition, it is possible to arrange the electrodes composed of the first electrode 100, which is a positive electrode, and the second electrode 200, which is a negative electrode, in the direction of electrolytic water flow in the electrolysis tank, and the DC power can be supplied through the rectifier The pipe-type barrier of the second electrode 200 corresponding to the first electrode 100 may be disposed in a single or plural number. The flow of the fluid through the valve 150 is switched as shown in FIG. 24 so that the operation of any one of the electrolytic apparatuses can be continued and the other electrolytic apparatuses can remove the attached foreign substances . Therefore, it is possible to maximize the efficiency by maximizing the efficiency because it does not disturb the flow of the fluid, and it is possible to maximize the energy saving, and it is possible to install it in the inside according to the structure of the piping.

As shown in FIGS. 25 to 31, the electrolytic apparatus for marine vessels according to another aspect of the present invention includes a double vortex generating a vortex by inducing a vortex phenomenon in ship ballast water flowing into a plurality of electrodes 100 and 200, (20). The double vortex guiding portion 20 is a flanged double vortex guiding portion 20 coupled to both ends of the pipe-like structure 10 and the double vortex guiding portion 20 includes a vortex guiding portion 21 therein. The double-vortex induction portion 20 of the flange structure is mounted on the pipe-type electrode to induce a double vortex phenomenon in the fluid flowing into the first electrode 100 and the second electrode 200 inside. 26, the vortex phenomenon of the fluid passing through the space between the second electrode 200 and the first electrode 100 is induced by the fan-blade double-vortex derivative 22, The vortex phenomenon with respect to the fluid passing through the inside of the one electrode 100 is rotated by the double vortex derivative 21. It is preferable that the double vortex derivative 21 is a fluid rotating derivative of a folded shape based on a virtual point of one side of the triangle-shaped derivative. In other words, it includes a double vortex derivative 21 which is formed by folding an iron plate of a triangular shape on the basis of an imaginary point on one side of an iron plate of a triangular shape and rotating the fluid. The vortex phenomenon is induced to prevent foreign matter from adhering to the inside of the piping and the pipe dangling type electrode, the fluid swirls due to the vortex phenomenon and contacts the first and second electrodes 100 and 200 to increase the electrolysis efficiency, It is possible to increase the flow rate of the fluid by increasing the flow rate of the fluid by inducing a double vortex phenomenon in the internal and external fluids and by rotating the fluid. The effect of energy saving can be expected, and the sand or foreign matter is precipitated in the pipe, Thereby preventing the phenomenon of accumulation and preventing generation of scales.

The double vortex derivatives 21 and 22 shown in Fig. 26 are installed in the middle of a general pipeline to double-rotate the inside and the outside of the fluid due to the double vortex phenomenon, so that sand or foreign matter is deposited in the pipeline, It is possible to prevent the developing phenomenon and prevent scale generation.

The vortex 21 shown in Fig. 26 induces a vortex phenomenon such that the fluid rotates outward from the center of the pipe, and the vortex 22 of the fan-shaped vortex induces a fluid flow from the outer surface of the pipe to the center of the pipe It induces a vortex phenomenon so as to swirl and swirls, thereby accelerating the flow of the fluid, preventing foreign matter such as sand from being deposited inside the pipe, preventing the pipe from being accumulated, and preventing scale from being generated.

Fig. 27 shows a structure in which the double-vortex induction portion 20 is coupled to both ends of the pipe-like structure 10 to support the pipe-like structure, and Fig. 28 is an exploded perspective view showing the structure shown in Fig. 28, the vortex inducing portion 20 is formed in a flange shape and is fitted to both ends of the pipe-like structure 10, and the first electrode 100 is disposed on the inner surface of the pipe-like structure 10 When the second electrode 200 is disposed on the outer surface of the pipe-like structure, the double vortex 21 induces a phenomenon of vortex in the oxygen-rich water generated through the electrolysis of the first electrode 100, The fan-shaped double-vortex derivative 22 induces a vortex phenomenon in the hydrogen-rich portion generated through the electrolysis of the second electrode 200. A plurality of the first electrode 100 and the second electrode 200 may be selectively provided in the pipe. In order to achieve the purpose of generating more oxygen rich water, the second electrode 200 The number of the first electrodes 100 is larger than the number of the first electrodes.

29, the double-vortex induction portion 20 is formed in a flange shape, and the pipe-like structure 10 including the first electrode 100 and the second electrode 200 is formed between the flanges And the double vortex induction unit 20 is connected to the double vortex induction unit 20 and the double vortex induction unit 20 includes a vortex inducing unit 20 for inducing a vortex phenomenon in the oxygen rich water generated by the electrolysis action of the first electrode 100, And a plurality of the vortex derivatives 21 are arranged at the positions where the fluid flows into the first electrode 100 in a triangular folded shape.

30 and 31 illustrate an embodiment in which a water tank itself induces a vortex phenomenon. In the vortex phenomenon, the fluid swirls inside and outside the pipe-like structure 10. The fluid in the water tank swirls and flows toward the upper part of the water tank by the induction of the vortex of the water tank itself and the oxygen rich water in which the raw water is electrolyzed by the positive electrode disposed inside the pipe structure 10 is separated and collected, The hydrogen-rich water electrolyzed by the raw water is separated and collected by the negative electrode disposed outside the pipe-like structure 10 while swirling. Further, as shown in the lower part of Fig. 30, it is possible to mass-produce the oxygen-rich portion and the hydrogen-rich portion by arranging a plurality of the pipe-like structures 10 in a water tank.

32 is a flange-like configuration in which a pipe strainer 950 of an electrode ion boiler (hot water heater) apparatus according to another aspect of the present invention is combined. The electrode ion boiler apparatus includes a first electrode 100 inside a pipe, The first electrode 100 serving as a positive electrode is used to electrolyze water flowing into the boiler pipe to generate oxygen rich water and the second electrode 200 serving as a negative electrode is connected to the boiler pipe To generate hydrogen-rich water. The first electrode 100 and the second electrode 200 do not require a separate installation space and are disposed inside a conventional boiler pipe to electrolyze the water to generate hot water and a hot hydrogen rich water, It is possible not only to separate and collect the oxygen-rich water, but also to combine the produced hydrogen-rich water and oxygen-rich water in a desired ratio and provide it to the user. In other words, it is not necessary to install a separate additional space, and it is installed in the existing boiler pipe to electrolyze the water, so that the additional cost for the electrode placement is low and the maintenance cost of the boiler (hot water heater) . The strainer 950 filters foreign substances in the fluid to be electrolyzed by the first electrode 100 and the second electrode 200.

33 is a graph showing the relationship between the inner space of the first electrode 100 and the inner space of the first electrode 100 and the inner space of the first electrode 100 by inducing a vortex phenomenon in the fluid flowing into the first electrode 100 and the second electrode 200, A first electrode 100 is formed in a space between the outer side of the first electrode 100 and the inner side of the second electrode 200 in a process of sparing the space between the first electrode 100 and the second electrode 200. In a preferred embodiment of the present invention, (A double vortex derivative) as shown in Fig. 26 is applied to both the fluid flowing in the direction of the second electrode 200 and the fluid flowing in the direction of the second electrode 200 in order to generate hydrogen-rich water, It is preferable to induce the vortex phenomenon to rotate the fluid.

Figs. 34 to 36 are views showing an embodiment of the electrode configuration disposed inside the pipe of such an electrode ion boiler (hot water heater), wherein Fig. 34 shows a single- FIG. 36 shows a structure in which a through hole capable of flowing ions is formed in a three-phase pipe-shaped electrode.

That is, according to FIG. 34, a rod type electrode is disposed inside the boiler pipe, which is different from a pipe type having a space therein. Fig. 34 shows a configuration in which single-phase electrodes are disposed, and a single-phase electrode has polarities of positive and negative electrodes. Fig. 35 is a view showing a configuration in which three-electrode electrode type electrodes disposed inside the boiler pipe are arranged. When the electricity flows into the fluid flowing into the boiler pipe, the positive ions move to the negative electrode and the negative ions move to the positive electrode. The polar molecules oscillate according to the moving directions of the ions. : Convertive Heat) occurs. FIG. 36 is a view showing a structure in which a through hole is formed in the electrode of the three-phase electrode type shown in FIG. 35. This is an embodiment in which a through hole is formed in the three-phase electrode type electrode for easy understanding by those skilled in the art, Of course, can be formed. According to Fig. 36, the holes are formed in the electrodes of the electrode type, the ions are more freely moved during the electrolysis, and the more heat is generated due to the friction due to the vibration of the molecules, . The rod type electrode according to the embodiment shown in Figs. 34 to 36 can be applied to the electrode ion heater portion 30 shown in Fig. 21 in the embodiment of the present invention.

FIG. 37 is a view showing a three-phase four-wire type three-phase three-wire type pipe-type electrode according to an embodiment of the present invention.

As shown in FIG. 37, the three-phase electrode type electrode disposed inside the pipe causes a vortex phenomenon, and electrolyzes the fluid to be flowed, thereby allowing electricity to flow into the fluid flowing along the flow direction.

In this case, according to the embodiment of the present invention shown in FIG. 37, electricity flows according to a three-phase four-line system or a three-phase three-line system, and R , S, and T are the promised characters that indicate the phases in the alternating current. In a three-phase four-wire system, N means Neutral and Neutral. The voltage between the terminals is 380 V between R-S, S-T and T-R, and 220 V between R-N, S-N and T-N.

The three-phase, four-wire type is a star type, used for high-voltage low-current applications, and can ground N, facilitating the grounding of various devices. The three-phase three-wire type is a delta type and is used for low voltage and high current applications. There is a feature that does not adversely affect.

The embodiments of the present invention have been described above. It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. Therefore, the disclosed embodiments should be considered in an illustrative rather than a restrictive sense. The scope of the present invention is defined by the appended claims rather than by the foregoing description, and all differences within the scope of equivalents thereof should be construed as being included in the present invention.

10: pipe-shaped structure 12: ballast water tank
20: double vortex induction portion 21, 22: double vortex induction portion
30: electrode ion heater part 100: first electrode
110, 120: Daarong 130: Tube
140: Spray head 150: Valve
200: second electrode 300: insulator
400: diaphragm 500: electrode part
600: Power supply unit 620: Polarity changeover switch
700: electrode connector part 800: cap
850 mixing portion 860 induction furnace
900: Filter part 910: Reducing block filter
920: Positive charge magnetic field filter 950: Strainer

Claims (19)

A pipe-shaped structure having both ends penetrated; And
And a pair of electrodes disposed in the interior of the pipe-like structure, one end of the pipe is immersed in the liquid, and disposed inside and outside the zone based on a virtual predetermined space inside the pipe-like structure, And a first electrode and a second electrode arranged to electrolytically decompose the liquid,
Wherein the first electrode and the second electrode are a pipe-shaped electrode having positive and negative polarities, respectively,
The other end of the first electrode is connected to the first barrel to transmit oxygen-rich water,
The other end of the second electrode is connected to a second barrel, and the second bar is connected to a filter portion including at least one of a reductive block filter and a positive charge magnetic field filter for filtering impurities including residual chlorine, The other end of which is connected to a tube which is a passage for carrying hydrogen gas
Functional water capable of concentrating phosphorus, hydrogen-rich active hydrogen-rich water, personal portable sterilizing and disinfection water purification equipment using oxygen-rich water production and electrolysis.
delete delete The method according to claim 1,
And a power supply unit for applying power to the first electrode and the second electrode, wherein the power supply unit includes a pole changeover switch for switching polarities of the first electrode and the second electrode
Functional water capable of concentrating phosphorus, hydrogen-rich active hydrogen-rich water, personal portable sterilizing and disinfection water purification equipment using oxygen-rich water production and electrolysis.
The method of claim 1, wherein the first and second electrodes
A spring shape and a triangular cone shape passing through the center portion
Functional water capable of concentrating phosphorus, hydrogen-rich active hydrogen-rich water, personal portable sterilizing and disinfection water purification equipment using oxygen-rich water production and electrolysis.
delete delete delete The method according to claim 1,
And a spray head disposed at the other end of the first electrode, the part being immersed in the liquid
Functional water capable of concentrating phosphorus, hydrogen-rich active hydrogen-rich water, personal portable sterilizing and disinfection water purification equipment using oxygen-rich water production and electrolysis.
The method according to claim 1,
And a mixing unit for introducing the liquid electrolyzed by the first electrode and the second electrode respectively and mixing the introduced liquid according to a predetermined ratio
Functional water capable of concentrating phosphorus, hydrogen-rich active hydrogen-rich water, personal portable sterilizing and disinfection water purification equipment using oxygen-rich water production and electrolysis. delete delete delete delete delete delete delete delete delete

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