KR101675233B1 - Method to manufacture cloth preventing from Atomic, Biological, Chemical and that preventing clothes - Google Patents
Method to manufacture cloth preventing from Atomic, Biological, Chemical and that preventing clothes Download PDFInfo
- Publication number
- KR101675233B1 KR101675233B1 KR1020150125883A KR20150125883A KR101675233B1 KR 101675233 B1 KR101675233 B1 KR 101675233B1 KR 1020150125883 A KR1020150125883 A KR 1020150125883A KR 20150125883 A KR20150125883 A KR 20150125883A KR 101675233 B1 KR101675233 B1 KR 101675233B1
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- KR
- South Korea
- Prior art keywords
- activated carbon
- air catalyst
- air
- carbon fiber
- fabric
- Prior art date
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/0035—Protective fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
Abstract
Description
More particularly, the present invention relates to a method of manufacturing a fabric for protecting a CBC, and more particularly, to a method of fabricating a fabric for protecting a CBC by using an air-catalyzing function, Adsorption of substances - Decomposition of harmful substances by air catalyst and decomposition of harmful substances adsorbed on activated carbon, which are manifested even in the absence of light - Method of fabricating protective clothing for CBC with repetitive function of recovery of activated carbon and protective clothing for CBC .
The development and complexity of the industry and the danger of war by international disputes are increasing day by day.
Particularly, some terrorist groups are in semi-national form, so they are not only threats to society as a whole but also attacks of terrorist groups by chemical and biology, outbreak of war, The need for protective coatings is increasing.
Until now, the protective clothing of CBR has been generally active in its performance, so it plays a role of simply adsorbing chemical substances coming into the inside of clothes from outside when wearing clothes.
As a method of this adsorption, products using porous activated carbon (spherical granule type) or porous activated carbon fiber (ACF: Activated Carbon Fabric) have been applied as disclosed in Korean Patent Application Nos. 1020140037934, 1020140122656 and 1020097022491.
However, since this product exerts its performance by adsorption using the fine surface area of activated carbon, even if it is not actually worn, the porous surface adsorbs organic dust or chemicals generated in the air or clothes itself It has a fatal disadvantage that its function is degraded.
On the other hand, such a product is disadvantageous in that when it is used in a place where a pollutant is present, the performance of the adsorption is saturated, or its function is rapidly deteriorated, so that it can not be used almost once if it is used once. In addition, even after one use, the wear time is prolonged, and after the performance of the adsorption is saturated, the wearer is at risk of continuing wearing even though the function is lost.
As a method of solving such a problem, there is a patent application No. 10-2009-07022491 using inorganic matter, but the adsorption of harmful substances by inorganic substances is weaker than the existing methods and is not used at present.
Particularly, when a group or gel method is used, due to the nature of the inorganic substance, the adhesive force on the surface of the clothes is weak, and it is difficult to exhibit the actual function for a long time.
Techniques for improving the function by forming five or more complex layers including a carbon layer as a more complicated technique have been proposed in Patent Application No. 10-2010-0084940 and the like. This technology is a technique in which a detoxifying catalyst containing a photocatalyst is used as a nano- A catalyst for detoxification comprising a photocatalyst is coated on a nano-sterilized fiber layer, and a nano-sterilized fiber layer is coated with a detoxifying catalyst containing a nanoparticle-containing photocatalyst And the mixture is applied to the NBC protective fabric.
This technology claims that it decomposes harmful substances by the ionization of metal oxide by light using photocatalyst, and this catalyst proposes a catalyst that acts under ultraviolet rays. However, there is no ultraviolet ray or general light in the inside of clothes Therefore, there is a problem that the function can not be exerted.
The present invention has been proposed in view of this, and it is an object of the present invention to provide a fabric for protecting a CBC, which is a semi-permanent decomposition function of harmful substances, in a darkroom, that is, inside a garment, using a new air ion catalytic technique that does not use photocatalyst technology And to provide a clothes for CBR use.
Disclosure of the Invention In order to solve the above problems, the present invention provides a method for producing a titanium oxide catalyst, comprising: dispersing an air catalyst comprising potassium oxide and titanium dioxide in water; Immersing the activated carbon fiber in the water in which the air catalyst is dispersed to coat the surface of the activated carbon fiber with the air catalyst component; And dehydrating the activated carbon fiber coated with the air catalyst component and drying the activated carbon fiber at a high temperature to fix the air catalyst component to the activated carbon fiber.
According to another aspect of the present invention, there is provided a method for producing an air filter, comprising: dispersing an air catalyst made of a mixture of potassium oxide and titanium dioxide in water; Immersing the nonwoven fabric in water in which the air catalyst is dispersed to coat the surface of the nonwoven fabric with the air catalyst component; Dewatering the nonwoven fabric coated with the air catalyst component, and drying the nonwoven fabric at a high temperature to fix the air catalyst component to the nonwoven fabric; And a step of laminating the nonwoven fabric to the activated carbon fiber.
Preferably, potassium oxide and titanium dioxide are mixed in an amount of 10 to 30 wt% and 70 to 90 wt%, respectively, in the air catalyst, and the particle size of the potassium oxide and the titanium dioxide may be 1 to 100 nm.
Preferably, the air catalyst is contained in an amount of 10 to 20 parts by weight with respect to 100 parts by weight of water, the water is dispersed at a temperature of 80 to 100 ° C, and the air catalyst- The drying temperature of the fabric may be 80 ° C to 100 ° C.
Also, the CBR protective clothing can be constructed using the fabric for protecting the CBR.
The protective clothing fabricated by the present invention manufactured by the present invention has the characteristics of its performance characteristics, so that even when there is no light, the harmful substances are always adsorbed by the catalytic action - adsorption of harmful substances by activated carbon - Decomposition of toxic substances by the catalyst and decomposition of the harmful substances adsorbed on the activated carbon - it is possible to perform repetitive functions of recovering the function of the activated carbon.
In addition, the protective clothing made from this fabric can be used repeatedly when used in some chemistry-related workplaces, or can be used repeatedly to increase the risk of chemical substances that can occur during prolonged use in one place It is also possible to prevent the growth of the mold by removing the odor by inhibiting the growth of the mold due to the antibacterial action by the radical anion.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a cross-sectional view of a NBC protective fabric according to the present invention. FIG.
2 is a sectional view of a NBC protective fabric according to another embodiment of the present invention.
Hereinafter, the present invention will be described in detail with reference to the embodiments shown in the attached drawings.
The present invention is to produce a fabric for protecting CBR by fusing the function of an
The
That is, it is a well-known fact that the elemental symbol K, potassium, contains a trace amount of the isotope Potassium-40, which is about 0.0117% of the natural potassium.
Potassium containing this isotope attacks the water in the air in the natural world, resulting in the formation of hydroxy radicals (OH - ) and hydrogen peroxide (H 2 O 2 ) in water molecules.
At this time, the generated hydrogen peroxide reacts repeatedly with the anion generation reaction that generates the hydroxyl radical again by the transition metal titanium dioxide.
In the present invention, an
The particle size of potassium oxide and titanium dioxide may be as small as possible to be coated on the inside of the activated carbon fiber which is the fabric for protecting CBR. If the particle size is too small, the coating will not be able to be coated and will escape from the fabric. It is preferable that the particle size of potassium oxide and titanium dioxide is 1 to 100 nm.
The
When the activated
In the meantime, the present invention can be configured such that the
Then, the CBR protective clothing is manufactured using the CBR protective fabric.
As described above, the fabric for protecting the CBR can generate water (H 2 O) in the air as hydroxy radical and hydrogen peroxide even in the absence of light, and the titanium dioxide component can convert hydrogen peroxide into hydrogen radical The anion generation reaction which generates repetitive generation is caused, and the bacterial or organic compound can be decomposed by the ionized anion.
Therefore, even if the chemical protective clothing according to the present invention is worn in a place without light, it is possible to prevent harmful substances from entering the
The following is a test result of the fabric for protecting CBR according to the present invention.
[Example 1]
Measuring time
ACF Fabric
ACF Fabric
Test method: Gastec detector tube method
① A fabric (size: 297 mm × 210 mm) consisting of an activated carbon fiber (10) fabric (SPUN type with a thickness of 1 mm) and a polyethylene [PE] nonwoven fabric (30) 5l Tedlar After injecting the test gas (Formaldehyde, Ammonia, Trimethylamine) into the bag and sealing it, the decomposition performance of the above three organic substances was tested in a dark room without light.
(2) The coating solution was dipped in a potassium compound (exhibiting a catalytic function in the air without light in the air) and an air catalyst 20 (20 wt% in solute) containing titanium dioxide, followed by roll quenching, After drying, it was used.
③ After standing for 60 to 180 minutes at room temperature, the gas was measured using a gas detector tube. The results are shown in Table 1 above. The temperature is 25 ° C and the humidity is 60%.
[Example 2]
The
[Example 3]
In Example 1, spraying the titanium dioxide as a photocatalyst onto the activated
As shown in the above Experimental Example, it can be seen that the carbon nanofiber protective fabric according to the present invention has the best ability to decompose noxious gas of the activated carbon fiber coated with the
In addition, the activated
In order to realize the effect of the
As a result of investigating the antimicrobial activity of the air catalyst (20), it was confirmed that there was no fungal growth due to the radical activity generated in a large amount in the dark room.
This results in the generation of hydroxy radicals and hydrogen peroxide in the air in the dark room by the potassium compound forming the
Therefore, in the conventional protective clothing, it is impossible to prevent the smell of the mold or the adsorption capacity of the activated
10: Activated carbon fiber 20: Air catalyst layer
30: Nonwoven fabric
Claims (5)
Immersing the activated carbon fiber in the water in which the air catalyst is dispersed to coat the surface of the activated carbon fiber with the air catalyst component; And
And dewatering the activated carbon fiber coated with the air catalyst component and drying the activated carbon fiber at a high temperature to fix the air catalyst component to the activated carbon fiber.
Immersing the nonwoven fabric in water in which the air catalyst is dispersed so that the air catalyst component is coated on the nonwoven fabric;
Dewatering the nonwoven fabric coated with the air catalyst component, and drying the nonwoven fabric at a high temperature to fix the air catalyst component to the nonwoven fabric; And
And a step of sandwiching the nonwoven fabric on the activated carbon fiber.
In the air catalyst, 10 to 30 wt% of potassium oxide and 70 to 90 wt% of titanium dioxide are mixed,
Wherein the particle size of the potassium oxide and the titanium dioxide is 1 to 100 nm.
Wherein the air catalyst is contained in an amount of 10 to 20 parts by weight based on 100 parts by weight of the water,
Wherein the water is dispersed at a temperature of 80 to 100 占 폚 and the drying temperature of the activated carbon coated with the air catalyst is 80 to 100 占 폚.
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KR1020150079485 | 2015-06-04 | ||
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101933340B1 (en) | 2018-01-23 | 2018-12-27 | 국방과학연구소 | A protective fabric comprising a reactive polymer and a method for preparing the same |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20030068174A (en) * | 2000-12-15 | 2003-08-19 | 킴벌리-클라크 월드와이드, 인크. | Coated Activated Carbon |
JP2005185915A (en) * | 2003-12-25 | 2005-07-14 | Toyobo Co Ltd | Fibrous photocatalyst and its production method |
JP2008184718A (en) * | 2007-01-31 | 2008-08-14 | Fuji Electric Holdings Co Ltd | Activated carbon sheet and method for producing the same |
KR101222694B1 (en) * | 2012-08-02 | 2013-01-16 | (주)성한코퍼레이션 | The fabric for cbr defense and the cbr defense clothes using the same |
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- 2015-09-05 KR KR1020150125883A patent/KR101675233B1/en active IP Right Grant
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20030068174A (en) * | 2000-12-15 | 2003-08-19 | 킴벌리-클라크 월드와이드, 인크. | Coated Activated Carbon |
JP2005185915A (en) * | 2003-12-25 | 2005-07-14 | Toyobo Co Ltd | Fibrous photocatalyst and its production method |
JP2008184718A (en) * | 2007-01-31 | 2008-08-14 | Fuji Electric Holdings Co Ltd | Activated carbon sheet and method for producing the same |
KR101222694B1 (en) * | 2012-08-02 | 2013-01-16 | (주)성한코퍼레이션 | The fabric for cbr defense and the cbr defense clothes using the same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101933340B1 (en) | 2018-01-23 | 2018-12-27 | 국방과학연구소 | A protective fabric comprising a reactive polymer and a method for preparing the same |
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