KR101629440B1 - Cleaning composition for dentistry - Google Patents

Abstract

The present invention relates to a cleaning composition used in cleaning dentures and, more specifically, to a cleaning composition for dentures, comprising a cleaning agent of a powder type and a catalase agent of a powder type, wherein the cleaning agent comprises: a hydrogen peroxide addition compound layer consisting of hydrogen peroxide addition compound powders capable of generating hydrogen peroxide; a surfactant layer formed by coating a liquid surfactant on an outer surface of the hydrogen peroxide addition compound layer; and a saponin layer formed by coating saponin powder on the outer surface of the surfactant layer. Therefore, the cleaning composition for dentures is environment-friendly and harmless to a human body, and has improved cleansing and sterilizing effects.

Description

[0001] Cleaning composition for dentistry [

The present invention relates to a cleaning composition used for cleaning dentures, and more particularly, to a cleaning composition comprising a cleaning agent in the form of powder and a catalase preparation in powder form, wherein the cleaning agent comprises a hydrogen peroxide adduct of a powder capable of producing hydrogen peroxide A surface active agent layer formed by coating a liquid surface surfactant on the outer surface of the hydrogen peroxide addition compound layer and a saponin layer formed by coating the outer surface of the surface active agent layer with saponin powder, And has an improved cleaning and disinfecting effect.

If several teeth are missing, it is difficult to restore the teeth by attaching them to the teeth. In this case, use a denture (denture) in which the parts without teeth are connected together and can be inserted or removed in the mouth. When the denture is continuously used, contaminants are stuck, so that the denture is periodically cleaned using a detergent such as the following Patent Document.

(Patent Literature)

Published Japanese Patent Application No. 2002-0027509 (published on Apr. 13, 2002) "Composition for preventing deodorization and contamination of dental products"

However, a denture cleaning composition using an abrasive such as titanium dioxide or apatite has a problem of damaging the denture, and there is a problem that the denture can not be sufficiently cleaned with the oxygen-based cleaning composition using sodium percarbonate or the like.

SUMMARY OF THE INVENTION The present invention has been made to solve the above problems,

An object of the present invention is to provide a denture cleaning composition which can be used for cleaning and sterilizing dentures.

It is another object of the present invention to provide a denture cleaning composition which is made of a material extracted from a natural substance and is environmentally friendly and harmless to the human body.

The present invention also provides a dentifrice cleaning composition for forming a surfactant layer, a saponin layer and a sodium hydrogencarbonate layer on the outer surface of a hydrogen peroxide adduct in order to generate a large number of bubbles, increase oxygen generation time, The purpose is to provide.

It is another object of the present invention to provide a dentifrice cleaning composition capable of easily forming a multilayered cleaning agent by binding another solid powder (hydrogen peroxide adduct, saponin, sodium hydrogencarbonate) with a liquid surfactant. have.

In addition, the present invention is characterized in that the outermost layer of the cleaning agent is coated with sodium hydrogencarbonate to improve the cleaning effect and foaming effect while preventing the outer surface from being wetted, thereby preventing the cleaning agent from sticking, The present invention provides a cleaning composition for dentures that can be applied to a toothbrush.

In order to achieve the above object, the present invention is implemented by the following embodiments.

According to one embodiment of the present invention, the denture cleansing composition according to the present invention comprises a cleaning agent in powder form and a catalase agent in powder form, wherein the cleaning agent is a hydrogen peroxide A surfactant layer formed by coating a liquid surfactant on the outer surface of the hydrogen peroxide addition compound layer; and a saponin layer formed by coating the outer surface of the surfactant layer with saponin powder.

According to another embodiment of the present invention, in the cleaning composition for dentures according to the present invention, the detergent further comprises a sodium hydrogencarbonate layer formed by coating powdered sodium hydrogencarbonate on the outer surface of the saponin layer .

According to another embodiment of the present invention, in the cleaning composition for denture according to the present invention, the detergent may include a binder layer coated on the outer surface of the sodium hydrogencarbonate layer, and a yeast layer coated on the outer surface of the binder layer As shown in FIG.

According to another embodiment of the present invention, in the denture cleaning composition according to the present invention, the catalase preparation comprises a seed material; A catalase which is applied and dried on the seed material; And a gating layer formed by coating trehalose on the outer surface of the catalase.

According to another embodiment of the present invention, in the denture cleansing composition, 0.5 to 4 parts by weight of the catalase preparation is used in an amount of 0.5 to 4 parts by weight based on 100 parts by weight of the cleansing agent, and the cleansing agent comprises 100 parts by weight of the hydrogen peroxide addition compound , 8 to 13 parts by weight of a surfactant, 0.5 to 2 parts by weight of saponin and 4 to 8 parts by weight of sodium hydrogencarbonate are used.

According to still another embodiment of the present invention, in the denture cleaning composition according to the present invention, the saponin is saponin extracted from an alder tree.

According to another embodiment of the present invention, in the denture cleaning composition according to the present invention, the seed material may be at least one selected from the group consisting of sugar, sodium sulfate, salt, sodium citrate, and phosphate.

According to another embodiment of the present invention, there is provided a method of manufacturing a denture cleaning composition according to the present invention, which comprises mixing a hydrogen peroxide addition compound of a powder with a liquid surfactant and stirring the mixture, thereby forming a hydrogen peroxide addition compound layer, A hydrogen peroxide addition compound layer and a surfactant layer forming a layer; A step of forming a saponin layer on the outer surface of the surfactant layer by further mixing and stirring the saponin powder after the step of forming the hydrogen peroxide addition compound layer and the surfactant layer; And forming a sodium bicarbonate layer on the outer surface of the saponin layer by further mixing and stirring the powdered sodium bicarbonate after the step of forming the saponin layer.

According to the present invention, the following effects can be obtained by this embodiment.

The present invention has an effect that can be used for cleaning and sterilizing dentures.

In addition, the present invention is made of a material extracted from a natural substance, and is eco-friendly and harmless to human body.

Further, the present invention has the effect of forming a surfactant layer, a saponin layer and a sodium hydrogencarbonate layer on the outer surface of the hydrogen peroxide adduct in order to generate a large number of bubbles, to increase the oxygen generation time, and to improve the cleaning and disinfecting effect .

Further, the present invention has an effect of easily producing a cleaning agent of a multilayer structure by bonding another solid powder (hydrogen peroxide addition compound, saponin, sodium hydrogencarbonate) with a liquid surfactant.

In addition, the present invention is characterized in that the outermost layer of the cleaning agent is coated with sodium hydrogencarbonate to improve the cleaning effect and foaming effect while preventing the outer surface from being wetted, thereby preventing the cleaning agent from sticking, There is an effect that can be made.

BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a cross-sectional view of a cleaning agent used in a denture cleansing composition according to an embodiment of the present invention.
2 is a cross-sectional view of a cleaning agent used in a denture cleansing composition according to another embodiment of the present invention.
3 is a cross-sectional view of a catalase formulation used in a denture cleansing composition according to one embodiment of the present invention.
Fig. 4 is a reference diagram for explaining an induction bed dryer used in the production of the catalase preparation of Fig. 3; Fig.

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, a denture cleansing composition and a method of manufacturing the same according to the present invention will be described in detail with reference to the accompanying drawings. Unless defined otherwise, all terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs and, if conflict with the meaning of the terms used herein, It follows the definition used in the specification. Throughout the specification, when an element is referred to as "including " an element, it is understood that the element may include other elements as well, without departing from the other elements unless specifically stated otherwise.

1, 3 and 4, the cleaning composition for dentures according to an embodiment of the present invention comprises a cleaning agent (1) for a powder having a hydrogen peroxide addition compound and a cleaning agent (2) of a powder for promoting dissolution, wherein the catalase preparation is used in an amount of 0.5 to 4 parts by weight based on 100 parts by weight of the detergent.

The cleaning agent (1) is in the form of a powder and comprises a hydrogen peroxide addition compound layer (11), a surfactant layer (12) coated on the outer side of the hydrogen peroxide addition compound layer (11) A sodium carbonate layer 14 coated on the outer side of the saponin layer 13, and the like. It is preferable that 8 to 13 parts by weight of the surfactant, 0.5 to 2 parts by weight of saponin and 4 to 8 parts by weight of sodium hydrogencarbonate are used as the cleaning agent in 100 parts by weight of the hydrogen peroxide addition compound.

The hydrogen peroxide adduct compound layer 11 is preferably made of powdery hydrogen peroxide adduct compound capable of generating hydrogen peroxide. The hydrogen peroxide adduct compound is preferably sodium percarbonate, sodium perborate or the like, and sodium percarbonate having high solubility at low temperature More preferably, it is used.

The surface active agent layer 12 is formed by coating a liquid surface surfactant on the outer surface of the hydrogen peroxide addition compound layer 11. The surface active agent is preferably a nonionic surface active agent obtained from a natural material, , Palm oil, and the like are preferably used. An edible emulsifier may be used as a surfactant instead of fatty acid sodium which is widely used in a detergent (detergent), thereby reducing the occurrence of turbidity during dissolution of the cleaning composition. The surfactant is preferably used in an amount of 8 to 13 parts by weight based on 100 parts by weight of the hydrogen peroxide addition compound. When the surfactant is used in an amount of less than 8 parts by weight, the formation of the saponin layer is not easy. When the surfactant is used in an amount of more than 13 parts by weight, a solid detergent is not easily produced.

The saponin layer 13 is formed by coating the outer surface of the surfactant layer 12 with saponin powder, and the saponin is preferably saponin extracted from soapberry. The saponin imparts an improved cleaning, antibacterial and bubble forming effect to the detergent. The saponin is preferably used in an amount of 0.5 to 2 parts by weight based on 100 parts by weight of the hydrogen peroxide addition compound. When the saponin is used in an amount less than 0.5, there is a problem that the cleaning, antibacterial and bubble-forming effect is poor. When the saponin is used in an amount exceeding 2 parts by weight, the saponin is economically undesirably deteriorated.

The sodium bicarbonate layer 14 is formed by coating powdered sodium hydrogencarbonate on the outer surface of the saponin layer 13, and the sodium hydrogencarbonate increases the cleaning and foaming power of the detergent. In addition, the sodium hydrogencarbonate can dry the detergent to increase storage and use period. The sodium hydrogen carbonate is preferably used in an amount of 4 to 8 parts by weight based on 100 parts by weight of the hydrogen peroxide addition compound. When the sodium hydrogencarbonate is used in an amount of less than 4 parts by weight, there is a problem that the cleaning agents stick to each other due to a surfactant in a liquid phase. If the sodium hydrogencarbonate is used in an amount of 8 parts by weight or more, there is a problem that detergency is deteriorated.

The preparation method of the cleaning agent includes the steps of forming a hydrogen peroxide addition compound layer and a surfactant layer, forming a saponin layer, forming a sodium bicarbonate layer, and the like. In the manufacturing method of the detergent agent, an industrial mixer (stirrer) which is conventionally used for mixing various materials is used.

The hydrogen peroxide addition compound layer and the surfactant layer are formed by mixing a hydrogen peroxide addition compound of a powder and a liquid surfactant in a mixer for industrial use and stirring to form a hydrogen peroxide addition compound layer 11 and a surface active agent layer 12 on the outer surface of the hydrogen peroxide addition compound layer, . The surfactant is used in an amount of 8 to 13 parts by weight based on 100 parts by weight of the hydrogen peroxide addition compound. Since the surfactant is in a liquid state, the surfactant is easily coated on the outer surface of the hydrogen peroxide addition compound.

In the step of forming the saponin layer, after the step of forming the hydrogen peroxide addition compound layer and the surfactant layer, the saponin powder is further added to the industrial mixer and stirred to form the saponin layer 13 on the outer surface of the surfactant layer. Saponin is used in an amount of 0.5 to 2 parts by weight based on 100 parts by weight of the hydrogen peroxide addition compound. Since the surfactant layer is in a sticky state in the liquid phase, the outer surface of the surfactant layer is easily coated with saponin.

In the step of forming the sodium hydrogencarbonate layer, the sodium bicarbonate powder is further added to the industrial mixer after the step of forming the saponin layer, followed by stirring to form the sodium hydrogencarbonate layer 14 on the outer surface of the saponin layer. The sodium hydrogencarbonate is used in an amount of 4 to 8 parts by weight based on 100 parts by weight of the hydrogen peroxide addition compound. Since a saponin layer is formed on the outer surface of the surfactant layer, a part of the saponin layer is wetted by the surfactant. Therefore, by mixing and stirring the sodium hydrogen carbonate, sodium hydrogen carbonate can easily be formed on the outer surface of the saponin layer Can be coated. The cleaning agent is not a single use of the hydrogen peroxide addition compound but forms a surfactant layer, a saponin layer and a sodium hydrogencarbonate layer on the outer side thereof to generate a large number of bubbles and forms a multilayer on the outer side of the hydrogen peroxide addition compound, And can be washed, sterilized, and sterilized. It is environmentally friendly, made of natural materials, easily binds other solid powders by a liquid surfactant, and is improved in cleaning by sodium hydrogencarbonate Effect and foaming effect while preventing the outer surface from being wetted, so that the cleaning agent can not stick to the cleaning agent, and storage and use period can be increased. In addition, since the detergent agent and the catalase agent are components dissolved in water, scratches do not occur on the outer surface of the dentures.

2, the detergent agent (1 ') is a binder agent coated on the outer surface of the sodium hydrogencarbonate layer 14 in the detergent agent described with reference to FIG. 1, Layer 15 and an eutectic layer 16 coated on the outer surface of the binder layer 15. The binder layer 15 serves to attach yeast to the outer surface of the sodium hydrogencarbonate layer 14, for example, polyethylene glycol, fructose, sorbitol, and the like. The yeast layer 16 is formed by coating the outer surface of the binder layer 15 with yeast. The yeast reacts by the action of the catalase to have a cleaning effect.

The catalase preparation (2) is constituted to promote dissolution of the hydrogen peroxide addition compound, and the catalase preparation is used in an amount of 0.5 to 4 parts by weight based on 100 parts by weight of the cleaning agent. When the catalase is used as an enzyme in a cleaning composition, the catalase itself is in a liquid state and reacts with other substances (cleaning agent) in the cleaning composition to inhibit the stabilization of the cleaning composition. Thus, the catalase is powdered to form a phthalate preparation, Can be improved. The catalase preparation (2) comprises a seed material (21), a liquid catalase (22) applied to the seed material and dried, and a coating layer (23) surrounding and protecting the outer surface of the catalase (22).

The seed material 21 is a substance that supports the liquid catalase, and for example, at least one of sugar sphere, polyethylene glycol (PEG 4,000 to 6,000), sodium sulfate, salt, sodium citrate and phosphate is used .

The catalase 22 has a liquid phase and is applied and dried on the seed material 21. The catalase is an enzyme present in the peroxisome of almost all the aerobic cells and is distributed in some organs of the human body. It also exists in cells. The catalase consists of four polypeptide chains of four residues, and the chain consists of more than 500 amino acids. The catalase has four porphyrin heme groups and is known as a catalyst for decomposing hydrogen peroxide by reacting with hydrogen peroxide. The reaction rate of catalase is so fast that it is known that within one minute one mole of catalase degrades hydrogen peroxide of 500 million molecules. In the cleaning composition, the catalase promotes sodium percarbonate to be dissolved in water at 15 ° C to 25 ° C.

The coating layer 23 is formed by coating trehalose on the outer surface of the catalase 22 to prevent the outer surface of the catalase preparation from being wetted so as not to stick to the catalase and the detergent, Increase.

The method for preparing a catalase preparation including the above-described composition includes a quantification step, a coating step, a drying step, a coating layer forming step, and the like. The fluidized bed drier 100 forms an outer shape and includes an inlet port (not shown) for allowing the seed material to flow in and out, and an inlet port 111 for the heating air to flow in and out ) And an outlet (112); A perforated plate 120 positioned inside the housing 110 to support a seed material; A nozzle portion 130 for spraying liquid catalase or liquid trehalose toward the seed material, and the like.

The quantifying step is a step of locating a certain amount of seed material inside the fluidized bed dryer 100 through an entrance. In the coating and drying step, the seed material is sprayed on the seed material through the nozzle unit 130, and the heated air having a predetermined pressure and a predetermined temperature is injected through the inlet 111, To allow catalase to be coated on the outside of the fluidized seed material. In the coating and drying step, 250 to 350 ml of catalase is used per kg of the seed material, the heating air injection pressure is 1 to 2.5 kg / m ² , the heating air injection temperature is 55 to 69 degrees, ) Is less than 50 degrees, and the amount of catalase is set at 1.5 to 3 ml / min. In the coating step, after spraying and drying, the tracheal solution is sprayed on the seed material coated with the catalase through the nozzle unit 130, and heated air having a predetermined pressure and a predetermined temperature is injected through the inlet 111 And the outlet 112 is discharged, so that a solid coating layer is formed on the outside of the catalase. In the coating step, 150 to 250 ml of trehalose solution (10% concentration) is used per 1 kg of the seed material, the heating air injection pressure is 1 to ^2.5 kg / m ² , the heating air injection temperature is 55 to 69 degrees, The outlet temperature (the temperature in the housing) is less than 50 degrees, and the input amount of the trehalose solution is 1.5 to 3 ml / min. In the method for producing the catalase preparation, granulated catalase can be easily obtained without losing the activity of the catalase by having the injection pressure, the injection temperature, and the catalase injection rate of the heated air under the above-described conditions.

Hereinafter, the present invention will be described in more detail with reference to Examples. However, these are only for the purpose of illustrating the present invention in more detail, but the scope of the present invention is not limited thereto.

≪ Example 1 >

1) Preparation of cleaning agent

8 g of sodium percarbonate and 70 g of a surfactant (edible emulsifier tween 20) were placed in an industrial mixer and stirred. 10 g of the saponin powder was further added to an industrial mixer and stirred. Then, 50 g of sodium hydrogen carbonate was further added to an industrial mixer, A cleaning agent is produced.

2) Preparation of catalase preparation

1 kg of Sugar Spear was injected into the fluidized bed dryer and the catalase was sprayed for 2 hours and 30 minutes at a rate of 2 ml / min through the nozzle portion. Heating air (injection pressure: ^2.0 Kg / m ² , injection temperature: (10% concentration) was sprayed through the nozzle at a rate of 2 ml / min for 1 hour and 40 minutes, and heated air (injection pressure: ^2.0 Kg / m ² , injection temperature: Temperature of 47 degrees) is supplied to the fluidized bed dryer to produce the catalase preparation.

3) Preparation of denture cleansing composition

The first kg of the detergent and 10 g of the catalase preparation are mixed to prepare a denture cleansing composition.

≪ Example 2 >

In the denture cleansing composition preparation method of Example 1, 700 g of sodium percarbonate and 60 g of a surfactant (edible emulsifier tween 20) were placed in an industrial mixer and stirred. Then, 10 g of saponin powder was further added to an industrial mixer and stirred, Except that 20 g of sorbitol was further added to an industrial mixer and stirred. After that, 160 g of yeast was placed in an industrial mixer and stirred to produce a cleaning agent. To produce a denture cleansing composition.

≪ Comparative Examples 1 to 3 >

1) In Comparative Example 1, the denture cleansing composition is produced in the same manner as in Example 1 except that 1000 g of sodium percarbonate is used as a cleansing agent in the denture cleansing composition preparation method.

2) In Comparative Example 2, 900 g of sodium percarbonate and 100 g of a surfactant (edible emulsifier tween 20) were placed in an industrial mixer and stirred to prepare a cleaning agent. In the same manner, a denture cleansing composition is produced.

3) In Comparative Example 3, 890 g of sodium percarbonate and 90 g of a surfactant (edible emulsifier tween 20) were put into an industrial mixer and stirred. Then, 20 g of saponin powder was further added to an industrial mixer and stirred , Thereby producing a denture cleansing composition with the same other conditions except that a cleansing agent is produced.

Experimental Example 1 Evaluation of Detergency of Denture

1) A 60 - year - old male dipped the dentures for 5 days in coffee for 10 minutes to contaminate the dentures. Thereafter, 5 g of the denture cleansing composition prepared in each of the above Examples and Comparative Examples was put into a beaker containing 500 ml of water, and the denture was placed in the beaker for 10 minutes. Thereafter, The degree of contaminant removal was visually evaluated and the results are shown in Table 1. The evaluation criteria are as follows. 5: very excellent, 4: excellent, 3: normal, 2: poor, 1: very poor

2) It can be seen that Examples 1 and 2 have excellent detergency (decontamination power) as compared with Comparative Examples 1 to 3. The cleaning power of Comparative Example 3 is superior to that of Comparative Example 1 and the cleaning power of Example 1 is superior to that of Comparative Example 3. This is because saponin and sodium hydrogencarbonate are coated on the outer side of sodium percarbonate rather than simply using sodium percarbonate, It can be seen that the bleaching power is excellent.

Before Using Cleaning Composition Example 1 Example 2 Comparative Example 1 Comparative Example 2 Comparative Example 3 denture
(Washing power) One 5 5 3 2 4

≪ Experimental Example 2 >

1) 5 g of denture cleansing composition prepared in each of the above Examples and Comparative Examples was put into a beaker containing 500 ml of water, and a denture for 60 days of age for 5 days was placed in a beaker for 10 minutes, The degree of removal of the plaque before and after the use of the cleaning composition for dentures was evaluated visually using reagents, and the results are shown in Table 2. The evaluation criteria are as follows. 5: very excellent, 4: excellent, 3: normal, 2: poor, 1: very poor

3) It can be seen that Examples 1 and 2 are superior to those of Comparative Examples 1 to 3 in removing plaque. The above results are generally in agreement with those of Experimental Example 1.

Before Using Cleaning Composition Example 1 Example 2 Comparative Example 1 Comparative Example 2 Comparative Example 3 denture
(PLAG) One 5 5 4 3 4

<Experimental Example 3> Evaluation of sterilization effect

1) In a beaker containing 500 ml of water, 5 g of denture cleansing composition prepared in each of the above Examples and Comparative Examples was put into a beaker. After a denture used by a 60-year-old male for 5 days was placed in a beaker for 10 minutes, The number of bacteria before and after the use of the cleaning composition was measured using a simple bacterial counting device (ATP TEST) and is shown in Table 3.

2) It can be seen that Examples 1 and 2 are excellent in sterilization effect as compared with Comparative Examples 1 to 3. In addition, the comparative example 2 shows that the sterilizing effect is relatively inferior, because the cleansing agent of the comparative example 2 did not sufficiently dissolve in the tongue.

Before use Example 1 Example 2 Comparative Example 1 Comparative Example 2 Comparative Example 3 denture 2569 11 13 38 78 26

&Lt; Example 4 > Bubbles and oxygen generation sustained effect

1) 5 g of denture cleaning composition prepared in each of the above Examples and Comparative Examples was put into a beaker containing 500 ml of water and visually evaluated for 30 minutes to determine the amount of bubbles and the degree of oxygen generation The results are shown in Table 4. The evaluation criteria are as follows. 5: very excellent, 4: excellent, 3: normal, 2: poor, 1: very poor

2) It can be seen that Examples 1 and 2 generate more bubbles and longer oxygen generation duration than Comparative Examples 1 to 3. It was found that the effect of Comparative Example 1 as well as Comparative Example 1 was inferior. In Comparative Example 1, only bubbles could not be formed by using only sodium carbonate, and bubbles could not be formed, so that the oxygen generated from the sodium tartrate rapidly flew .

Example 1 Example 2 Comparative Example 1 Comparative Example 2 Comparative Example 3 Bubble generation 5 5 3 2 4 Sustained oxygen evolution 5 5 3 2 4

While the present invention has been described in connection with what is presently considered to be practical exemplary embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, Should be interpreted as belonging to the scope.

1, 1 ': Cleaning agent 2: Catalase preparation 11: Hydrogen peroxide addition compound
12: Surfactant layer 13: Saponin layer 14: Sodium hydrogencarbonate layer
15: Binder layer 16: East layer 21: Seed material
22: Catalase 23: Coating layer

Claims (8)

A detergent powder form and a catalase formulation in powder form,
The cleaning agent includes a hydrogen peroxide addition compound layer formed of a hydrogen peroxide addition compound of a powder capable of generating hydrogen peroxide, a surfactant layer formed by coating a liquid surfactant on the outer surface of the hydrogen peroxide addition compound layer, and a surfactant layer formed on the outer surface of the surfactant layer And a saponin layer formed by coating the saponin of the powder. The cleaning composition according to claim 1,
And a sodium hydrogencarbonate layer formed by coating powdered sodium hydrogencarbonate on the outer surface of the saponin layer. The cleaning composition according to claim 2,
A binder layer coated on the outer surface of the sodium hydrogencarbonate layer, and an eutectic layer coated on the outer surface of the binder layer. 3. The method according to claim 2, wherein the catalase preparation comprises
A seed material; A catalase which is applied and dried on the seed material; And a gating layer formed by coating trehalose on the outer surface of the catalase. 5. The method of claim 4,
The catalase preparation is used in an amount of 0.5 to 4 parts by weight based on 100 parts by weight of the cleaning agent,
Wherein the detergent is used in an amount of 8 to 13 parts by weight of a surfactant, 0.5 to 2 parts by weight of saponin, and 4 to 8 parts by weight of sodium hydrogencarbonate per 100 parts by weight of the hydrogen peroxide addition compound. 6. The method of claim 5, wherein the saponin
Wherein the saponin extracted from the mushroom tree is used. 6. The method of claim 5, wherein the seed material
Wherein at least one of sugar, sugar, sodium sulfate, salt, sodium citrate, and phosphate is used. A hydrogen peroxide addition compound layer and a surfactant layer in which a hydrogen peroxide addition compound of a powder and a liquid surfactant are mixed and stirred to form a surfactant layer on the outer surface of the hydrogen peroxide addition compound layer; A step of forming a saponin layer on the outer surface of the surfactant layer by further mixing and stirring the saponin powder after the step of forming the hydrogen peroxide addition compound layer and the surfactant layer; And forming a sodium bicarbonate layer on the outer surface of the saponin layer by further mixing and stirring the powdered sodium bicarbonate after the step of forming the saponin layer to form a sodium bicarbonate layer. Gt;

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