KR101615515B1

KR101615515B1 - Complex deodorizer using catalytic oxidization

Info

Publication number: KR101615515B1
Application number: KR1020160013870A
Authority: KR
Inventors: 부진영
Original assignee: 주식회사 한하산업
Priority date: 2016-02-04
Filing date: 2016-02-04
Publication date: 2016-04-26

Abstract

A complex odor treatment system is disclosed. The disclosed complex odor treatment system includes a complex odor supply device and a catalytic oxidation water supply device, wherein the complex odor supplied by the complex odor supply device is contacted with the catalytic oxidation water supplied by the catalytic oxidation water supply device to remove the complex odor do.

Description

Complex deodorizer using catalytic oxidization < RTI ID = 0.0 >

A complex odor treatment system is disclosed. More particularly, a complex odor treatment system using catalytic oxidation water is disclosed.

In a place such as a sewage treatment plant, a sewage treatment plant, a food processing facility, an animal husbandry facility, etc., various organic or inorganic gases are generated and a complex odor is generally generated. Since the malodor is strong in complexity, There are difficult features.

In view of these characteristics, there are various methods for removing organic or inorganic odor gas. First, there are a plurality of nozzles in the deodorization tower, and water is sprayed from the odor-containing gas introduced into the deodorization tower to remove the offensive odor. Second, there is a method (an activated carbon adsorption method) in which an adsorbent layer such as activated carbon, silica gel and zeolite is disposed in a deodorization tower to adsorb odorous substances. Third, there is a method (microbial contact method) of disposing a specific microbial layer in the deodorization tower so that the microbes decompose the odor generating substances. Fourth, there is a washing and deodorizing tower, which is a general odor treatment facility that neutralizes odor components by bringing chemical liquid such as sulfuric acid or caustic soda into contact with odor components to cause a chemical reaction to remove odors.

However, in the case of the water washing method and the washing and deodorizing tower, there is an effect when the malodor component is well absorbed in water or a chemical solution, but a problem in that the treatment effect is unsatisfactory in the compound odor in which the malodor component is not easily absorbed in water or a chemical solution have.

The complex odor gas composed of an acid component, a basic component and a neutral component is usually cleaned by causing a neutralization reaction with "acid and alkali". Conventional deodorization towers using a neutralization reaction between the complex odor gas and " acid and alkali " as described above include two or more deodorization towers, that is, an acid washing tower and an alkali washing tower connected in series or in parallel.

On the other hand, basic odor components such as ammonia and amine are treated in an acid washing tower using sulfuric acid, and acidic odor components such as methyl mercaptan and hydrogen sulfide in residual odor are treated in an alkali washing tower using caustic soda, There have been attempts to treat neutral odor components such as malodorous acetaldehyde in biosystems such as biofilm tops using microorganisms. However, such attempts have shown that microbial growth deterioration occurs frequently in the biosystem due to caustic soda scattered in the alkali washing column, and the growth environment of specific microorganisms reacting only to specific odor components and the temperature, pH and humidity And the technical difficulties of system maintenance and the like. Therefore, there is a problem that the complex odor can not be satisfactorily treated.

On the other hand, the deodorization tower for removing the complex odor has been developed as the first generation deodorization tower and the second generation deodorization tower.

First, the first-generation deodorization tower is designed to contain acidic odor components such as hydrogen sulfide, methyl mercaptan, and sulfur dioxide contained in the exhaust gas, basic odor components such as ammonia and amine, and neutral odor components such as acetaldehyde A plurality of separate deodorization towers connected in series or in parallel to each other in which an acid washing liquid and an alkali washing liquid are respectively circulated in a sewage treatment plant, a manure treatment plant, a food processing facility, an animal husbandry facility, Can be independently removed by reacting with the respective cleaning liquids. However, the first-generation deodorization tower is complicated in structure, has a complicated construction, has a problem in that the deodorization speed of the complex odor gas is not quick, and the deodorization power is limited. Also, have.

The second generation deodorization tower may circulate separately the acid cleaning solution and the alkali cleaning solution in a single deodorization tower instead of two or more interconnected deodorization towers to separately chemically react with the individual components of the complex odor to remove the entire complex odor . However, the second-generation deodorization tower has not completely solved the problems of the first-generation deodorization tower, and has a complicated structure due to the structure installed for the purpose of preventing the generation of neutralized salt in the washing process.

One embodiment of the present invention provides a complex odor treatment system using catalytic oxidation water.

According to an aspect of the present invention,

Complex odor supply system; And

A catalytic oxidation water supply device,

A complex odor treatment system in which the complex odor supplied by the complex odor supply device is contacted with the catalytic oxidation water supplied by the catalytic oxidation water supply device to remove the complex odor.

The complex odor treatment system may further include a catalytic oxidation water producing device.

The catalytic oxidation water producing apparatus can produce a radical by contacting a radical initiator with a functional catalyst.

The radical initiator may include peroxide, hypochlorite, chlorine dioxide, chlorine gas, percarbonate, peroxide, or a combination thereof.

The functional catalyst may be a ferrite based compound (MFe _x O _y , M: Zn, Ni, Cu or Mg, 0 <x? 5, y = x + 2) (50-83.655 wt%), a magnetic substance (FeFe ₂ O ₄ ) (0.45-0.55 wt.%), Titanium (0.15-0.25 wt.%), Magnesium (1.45-1.50 wt.%), Iron (3.15-3.25 wt.%), Molybdenum %), Aluminum (4.75 to 4.85 wt.%), Potassium (0.75 to 0.85 wt.%), Zirconium (1.55 to 1.65 wt.%), Silicon (0.85 to 0.95 wt.%) And tungsten (0.045 to 0.055 wt. 2.55 to 2.65% by weight) of a metal oxide; (MFe _x O _y , M: Zn, Ni, Cu or Mg, 0 <x? 5, y = x + 2) (50 to 79.55 wt.%), A magnetic material (FeFe ₂ O ₄ (0.15-0.25 wt%), magnesium (1.35-1.45 wt%), aluminum (1.35-1.40 wt%), iron (3.15-3.25 wt%), manganese (2.55-2.65 wt%), cobalt (0.75-0.85 wt%), zirconium (1.55-1.65 wt%), silicon (0.85-0.95 wt%), calcium (0.35-0.45 wt%), and germanium (4.35-4.45 wt% %) Of a second particle of brown color sintered in combination with a metal oxide; And sintered in combination of metal oxides of aluminum oxide (37.5 to 41.5 wt.%), Zirconium oxide (16.25 to 19.35 wt.%), Diatomaceous earth (32.55 to 36.65 wt.%) And barium titanate (7.5 to 9.5 wt. wherein the first particle: the second particle: the third particle: 77.5-78.5 wt%: 18.5-19.5 wt%: 2.5-3.5 wt%.

The radical initiator is used in the form of an aqueous solution, and the concentration of the radical initiator in the aqueous solution may be 10 to 100 ppm by weight.

The complex odor treatment system may further include a deodorization tower coupled to the complex odor supply device and the catalytic oxidation water supply device, respectively.

The deodorization tower includes a body, a complex layer disposed in the body, the complex odor supplied by the complex odor supply device being contacted with the catalytic oxidation water supplied by the catalytic oxidation water supply device to convert into a process gas, A condenser for removing the liquid component in the discharged process gas, and a stack for discharging the process gas discharged from the demister to the atmosphere.

The complex odor supply device includes a blower and a complex odor supply line connected thereto, wherein the catalytic oxidation water supply device includes a catalytic oxidation water storage tank, a pump connected to the catalytic oxidation water storage tank, a catalytic oxidation water supply line connected to the pump, And a plurality of injection nozzles connected to the catalytic oxidation water distribution pipe and injecting the catalytic oxidation water into the filling layer.

The catalytic oxidation water supply device may include an air compressor that generates compressed air and an air flow nozzle that simultaneously supplies the catalytic oxidation water and the compressed air.

The complex odor treatment system using catalytic oxidation water according to an embodiment of the present invention is characterized in that the catalytic oxidation water containing radicals which react with both the acidic odor component, the basic odor component and the neutral odor component is used as a single cleaning liquid, And it is possible to prevent the malodor treatment efficiency from being deteriorated due to the generation of neutralized salt by preventing the neutralization salt which is inevitably generated due to the collision between the acid cleaning liquid and the alkali cleaning liquid, Rapid reaction of radicals within a given gas-liquid contact time allows rapid removal of complex odors.

In addition, the complex odor treatment system includes a structural device installed to prevent two cleaning liquids from being neutralized in a conventional deodorization tower, for example, two demisters, two chemical liquid pumps for transporting respective chemicals, A separate cleaning liquid reservoir, and the like, and it is possible to perform the original function for removing the complex odor even by a single cleaning liquid alone.

In addition, the complex odor treatment system can be used in deodorizing equipment such as a simple or continuous type washing tower or a biofilm tower installed in the room. That is, an air flow nozzle or an air flow nozzle of the deodorizing equipment installed in the apparatus is installed, the catalytic oxidation water is mixed with the compressed air through the air flow nozzle and sprayed in an aerosol state to remove untreated residual odor from the catalytic oxidation water It can be removed by further oxidative decomposition.

In addition, the complex odor treatment system can improve the treatment efficiency by about 12% as compared with the simultaneous washing and deodorizing tower by replacing the entire washing liquid of the single or continuous washing / deodorizing tower of the general system with catalytic oxidation water.

In addition, the complex odor treatment system has a problem in that the odor not treated in the existing biofilm tower is treated with the conventional odor treatment due to the treatment efficiency varying according to the change of unprocessed complex odor and microorganism state due to the treatment efficiency limit of the tower, The catalytic oxidation water containing OH radicals capable of chemical reaction with basic odor components, acidic odor components and neutral odor components from the complex odor components is connected to the connection duct or final exhaust stack of the system in series, It is possible to further treat 50% or more of the untreated odor by spraying in a mist form.

In addition, the complex odor treatment system is limited in terms of the processing efficiency (about 85%) of existing deodorization towers in the conventional single-stage washing deodorization tower, double-bed washing deodorization tower, , Or at least 15% of the residual odor discharged into the atmosphere due to untreated processing, or a workplace that has to compensate for the existing malodor due to strengthened legal regulations other than that at the time of installation, It can be used in workplaces where there is a lack of installation site of the supplementary facilities that can be treated, and therefore, it is impossible to install a supplementary facility due to site problems or other reasons.

In addition, the complex odor treatment system may spray catalytic oxidation water in a mist state through a nozzle in a downstream end of an influent blower of a conventional deodorization tower, a connecting duct of a multi-stage deodorization tower, or a final exhaust stack of a deodorization tower, The odor component can be chemically reacted with radicals such as oxygen radicals and hydroxyl radicals to remove more than 98% of all the odor of acidic, basic and neutral components through liquid-liquid contact.

Therefore, the complex odor treatment system can significantly improve the installation cost of a new or existing deodorizing tower and the collection efficiency of the complex odor gas.

FIG. 1 is a view showing an apparatus for producing catalytic oxidation water used in a complex odor treatment system according to an embodiment of the present invention.
2 is a schematic view of a complex odor treatment system according to an embodiment of the present invention.
3 is a schematic diagram of a complex odor treatment system according to another embodiment of the present invention.
4 is a schematic view of a complex odor treatment system according to another embodiment of the present invention.
5 is a schematic view of a complex odor treatment system according to another embodiment of the present invention.

Hereinafter, the complex odor treatment system according to one embodiment of the present invention will be described in detail.

The complex odor treatment system according to an embodiment of the present invention includes a complex odor supply device and a catalytic oxidation water supply device.

The complex odor treatment system removes the complex odor by contacting the complex odor supplied by the complex odor supply device with the catalytic oxidation water supplied by the catalytic oxidation water supply device.

The peroxide may include hydrogen peroxide, sodium peroxide, potassium peroxide, carbamide peroxide, sodium perborate, sodium percarbonate, or a combination thereof.

The hypochlorite may include sodium hypochlorite, potassium hypochlorite, calcium hypochlorite, barium hypochlorite, or combinations thereof.

The percarbonate may include sodium percarbonate, potassium percarbonate, or a combination thereof.

The peroxide may include peroxyacetic acid, peroxyphosphoric acid, peroxodisophosphoric acid, peroxic sulfuric acid, peroxic di-sulfuric acid, peroxic acid, or a combination thereof.

The functional catalyst may be a ferrite based compound (MFe _x O _y , M: Zn, Ni, Cu or Mg, 0 <x? 5, y = x + 2) (50-83.655 wt%), a magnetic substance (FeFe ₂ O ₄ ) (0.45-0.55 wt.%), Titanium (0.15-0.25 wt.%), Magnesium (1.45-1.50 wt.%), Iron (3.15-3.25 wt.%), Molybdenum %), Aluminum (4.75 to 4.85 wt.%), Potassium (0.75 to 0.85 wt.%), Zirconium (1.55 to 1.65 wt.%), Silicon (0.85 to 0.95 wt.%) And tungsten (0.045 to 0.055 wt. 2.55 to 2.65% by weight) of a metal oxide; (MFe _x O _y , M: Zn, Ni, Cu or Mg, 0 <x? 5, y = x + 2) (50 to 79.55 wt.%), A magnetic material (FeFe ₂ O ₄ (0.15-0.25 wt%), magnesium (1.35-1.45 wt%), aluminum (1.35-1.40 wt%), iron (3.15-3.25 wt%), manganese (2.55-2.65 wt%), cobalt (0.75-0.85 wt%), zirconium (1.55-1.65 wt%), silicon (0.85-0.95 wt%), calcium (0.35-0.45 wt%), and germanium (4.35-4.45 wt% %) Of a second particle of brown color sintered in combination with a metal oxide; And sintered in combination of metal oxides of aluminum oxide (37.5 to 41.5 wt.%), Zirconium oxide (16.25 to 19.35 wt.%), Diatomaceous earth (32.55 to 36.65 wt.%) And barium titanate (7.5 to 9.5 wt. color) of the third particle.

The first particle: the second particle: the third particle may be 77.5-78.5 wt%: 18.5-19.5 wt%: 2.5-3.5 wt%.

The catalytic oxidation water may contain a radical. The radicals may include oxygen radicals, hydroxyl radicals (i.e., OH radicals), or combinations thereof.

The catalytic oxidation water may be a radical-containing solution. For example, the catalytic oxidation water may be a radical containing aqueous solution.

The radical initiator may be used in the form of an aqueous solution.

The concentration of the radical initiator in the aqueous solution may be 10 to 100 ppm by weight.

In the catalytic oxidation water production apparatus, the radical initiator (for example, NaOCl) may contact with the functional catalyst to generate radicals through the following reaction.

&Lt; Before contacting with functional catalyst >

Before NaOCl comes into contact with the functional catalyst, the following reaction takes place in an aqueous solution state.

NaOCl + H ₂ O → NaOH + HOCl (1)

NaOCl ^- > Na ⁺ + OCl ^- (2)

Since NaOCl itself is alkaline, OCl ^- is stable, but NaOCl is diluted by mixing with water before contact with the functional catalyst, so that it has a neutral pH and is converted to more stable HOCl. Specifically, when sodium hypochlorite (NaOCl) is dissolved in water, the sodium hypochlorite is decomposed into sodium hydroxide (NaOH) and hypochlorous acid (HOCl) to become alkaline.

&Lt; After contacting with the functional catalyst &

The above reaction (1) is extremely slow and does not easily proceed with a forward reaction in a normal state, but the functional catalyst remarkably promotes the reaction of the reaction (1).

When HOCl is contacted with the functional catalyst, the following reaction occurs.

HOCl → HCl + [O] (3), where [O] represents an oxygen radical.

That is, hypochlorous acid (HOCl) is decomposed to generate oxygen radicals, which exhibit a strong oxidizing action. The catalytic oxidation water thus produced has a strong oxidizing power of up to 300 times that of general chlorinated compounds. Therefore, the oxygen radicals and the hydroxyl radicals contained in the catalytic oxidation water chemically react with the complex odor, and the oxidation reactivity of the radicals is extremely excellent.

When the radical initiator is chlorine, the chlorine reacts with the functional catalyst as described below.

Cl ₂ + H ₂ O → HOCl + HCl (4)

HOCl? HCl + [O] (5)

HOCl ↔ H ⁺ + OCl ^- or Cl ^- + [OH] (6), where [OH] represents the hydroxyl radical.

1 is a view showing an apparatus 10 for producing catalytic oxidation water used in a complex odor treatment system according to an embodiment of the present invention.

Referring to FIG. 1, the catalytic oxidation water production apparatus 10 includes a functional catalyst C filled therein. First, a radical initiator (RI) is injected into one end of the catalyzed oxidation water producing apparatus 10. The injected radical initiator (RI) is contacted with the functional catalyst (C) to produce the radicals described above. As a result, the catalytic oxidation water (COW) containing radicals is discharged from the other end of the catalytic oxidation water production apparatus 10. [

The complex odor treatment system can remove or reduce the complex odor complexed with an acidic odor component, a basic odor component and / or a neutral odor component by chemically reacting with a radical (oxygen radical, hydroxyl radical, etc.) in the catalytic oxidation water .

When the complex odor treatment system treats neutral odor components and other odor components using the catalytic oxidation water, a reaction represented by the following reaction equations occurs in the complex odor treatment system.

1) Treatment of acetaldehyde (CH ₃ CHO)

CH ₃ CHO + [O] -> CH ₃ COOH, and acetic acid (CH ₃ COOH) are dissolved in water to eliminate odor.

2) Treatment of hydrogen sulfide (H ₂ S)

H ₂ S + 4 [O] -> H ₂ SO ₄ , and sulfuric acid (H ₂ SO ₄ ) are also dissolved in water and the odor disappears.

3) Treatment of methyl mercaptan (CH ₃ SH)

CH ₃ SH + 3 [O] -> CH ₃ SO ₃ H, and methylsulfonic acid (CH ₃ SO ₃ H) are also dissolved in water to eliminate the odor.

4) Treatment of methyl sulfide (CH ₃ SCH ₃ )

CH ₃ SCH ₃ + [O] → (CH ₃ ) ₂ SO, dimethylsulfoxide ((CH ₃ ) ₂ SO) reacts continuously with the oxygen radical as follows.

(CH ₃ ) ₂ SO + 2 [O] → (CH ₃ ) ₂ SO ₃ , and dimethylsulfonic acid (CH ₃ SO ₃ H) are also dissolved in water to eliminate the odor.

5) Treatment of methyl disulfide ((CH ₃ ) ₂ S ₂ )

(CH ₃ ) ₂ S ₂ + H ₂ O → CH ₃ SH + CH ₃ SOH and methanesulfinic acid (CH ₃ SOH) are also dissolved in water to eliminate the smell.

CH ₃ SH + 3 [O]? CH ₃ SO ₃ H, as described above, methylsulfonic acid (CH ₃ SO ₃ H) is also dissolved in water and the odor disappears.

When the catalytic oxidation water is used as a cleaning liquid for the complex odor treatment system, the radicals contained in the catalytic oxidation water chemically react with neutral odor components at an equivalent ratio, and basic odor components and acid malodor components are also mixed with the catalytic oxidation water It can be simply increased and treated at the equivalence ratio.

2 is a schematic diagram of a complex odor treatment system 100 in accordance with an embodiment of the present invention.

Referring to FIG. 2, the complex odor treatment system 100 may include a complex odor supply device, a catalytic oxidation water supply device, and a deodorization tower.

The deodorization tower is disposed in the main body 101 and the body 101. The deodorization tower is provided with a complex odor (not shown) supplied by the complex odor supply device in contact with the catalytic oxidation water COW supplied by the catalytic oxidation water supply device (Not shown) for removing the liquid component (mainly catalytic oxidation water) in the process gas discharged from the packed bed 107, and a condenser 108 for removing the liquid component And a stack 109 for discharging the process gas to the atmosphere.

The fill layer 107 may comprise a filler such as a pall ring, plastic, metal, wood, magnetic, or a mixture of two or more thereof.

The demister 108 may have a Z-shape. A plurality of such demisters 108 may be stacked vertically. Further, the demister 108 can prevent the catalytic oxidation water (COW) from being scattered to the outside of the stack 109 by wind pressure.

The complex odor supply device may include a blower F and a complex odor supply line 102 connected thereto.

The catalytic oxidation water supply device includes a catalytic oxidation water storage tank 103 filled with catalytic oxidation water (COW), a pump P connected to the catalytic oxidation water storage tank 103, a catalytic oxidation water supply line 104 connected to the pump P, A plurality of injection nozzles 106 connected to the catalytic oxidation water distribution pipe 105 connected to the line 104 and a plurality of injection nozzles 106 connected to the catalytic oxidation water distribution pipe 105 for injecting catalytic oxidation water COW onto the filling layer 107 inside the deodorization tower 105 ).

The complex odor treatment system 100 may include two or more structures in the form of a stacked structure that includes the filling layer 107, the injection nozzle 106, and the catalytic oxidation water distribution pipe 105 sequentially. The deodorization tower is not limited to the structure shown in FIG. 2, and may have the same or similar structure as the conventional deodorization tower, such as the first-generation deodorization tower or the second-generation deodorization tower. In this case, the catalytic oxidation water containing radicals can be used as a single cleaning liquid for the existing deodorization tower, and the deodorization tower can be supplemented by spraying the catalytic oxidation water in the form of mist from the front and rear ducts of the conventional deodorization tower, have. Specifically, the complex odor treatment system 100 can treat untreated residual odor (15%) due to the marginal efficiency (about 85%) in a conventional single or continuous type deodorization tower in operation, The residual odor untreated in the biofilm tower where the degradation occurs frequently and the specific dominant microorganism reacts only with specific odor components, the difficult cultivation of a severe microorganism such as maintaining the temperature, the pH and the humidity within a certain range, Lt; / RTI > That is, the complex odor treatment system 100 treats the complex odor through the chemical reaction with the residual odor component discharged upward by spraying down the COW to the exhaust stack of the existing odor facility, It can be supplemented economically and efficiently.

Figure 3 is a schematic diagram of a complex odor treatment system 200 according to another embodiment of the present invention.

3, the complex odor treatment system 200 includes a catalytic oxidation water storage tank 201 filled with catalytic oxidation water (COW), a metering pump 203 connected to the catalytic oxidation water storage tank 201, an air compressor 202, and an air stream nozzle 204 for supplying catalytic oxidation water (COW) and the compressed air at the same time.

A mixture of catalytic oxidation water (COW) and compressed air is injected into the complex odor source (MOS) through the air nozzle 204 to convert the complex odor into the process gas CG. Specifically, the catalytic oxidation water (COW) in the mixture chemically reacts with the complex odor to remove or reduce the complex odor to generate the process gas (CG).

4 is a schematic view of a complex odor treatment system 300 according to another embodiment of the present invention.

4, the complex odor treatment system 300 includes a catalytic oxidation water storage tank (not shown) filled with catalytic oxidation water (COW), a metering pump (not shown) connected to the catalytic oxidation water storage tank, An air compressor (not shown), and a plurality of air nozzles 301 that simultaneously supply catalytic oxidation water (COW) and compressed air (CA).

Catalytic oxidation water (COW) and compressed air (CA) are injected into the air nozzle 301 and then mixed to form a mixture. The mixture is injected into a complex odor source (MOS) through the air nozzle 301 to convert the complex odor into a process gas (not shown). Specifically, the catalytic oxidation water (COW) in the mixture chemically reacts with the complex odor to remove or reduce the complex odor to produce a process gas. Here, a mixed odor source (MOS) may be a waste water treatment plant, a sludge yard, a cake hopper, a compost, a cake exporting facility, a pig farm, a dirty soil treatment plant, or an organic solvent.

5 is a schematic diagram of a complex odor treatment system 400 according to another embodiment of the present invention.

5, the complex odor treatment system 400 includes a catalytic oxidation water storage tank (not shown) filled with catalytic oxidation water (COW), a metering pump (not shown) connected to the catalytic oxidation water storage tank, A blower 401 for supplying a complex odor derived from an air compressor (not shown) and a complex odor source (MOS) to a complex odor treatment system 400, a plurality of (403) for removing the liquid component from the mixed odor (i.e., process gas (CG)) treated with the catalytic oxidation water (COW)
5, a plurality of air nozzles for simultaneously supplying catalytic oxidation water and compressed air are provided on both sides of the supplied complex odor, and catalytic oxidation water is supplied on both sides of the complex odor, .

Catalytic oxidation water (COW) and compressed air (CA) are injected into the air nozzle 402 and then mixed to form a mixture. The mixture is injected into the complex odor through the air nozzle 402 to convert the complex odor into the process gas CG. Specifically, the catalytic oxidation water (COW) in the mixture chemically reacts with the complex odor to remove or reduce the complex odor to generate the process gas (CG). The process gas CG is injected into the demister 403 before being discharged from the complex odor processing system 400 to the atmosphere to remove the liquid component. Here, a complex odor source (MOS) may be an indoor odor.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, There will be. Accordingly, the scope of protection of the present invention should be determined by the appended claims.

10: Catalytic oxidation water production apparatus 11: Catalyst
00, 200, 300, 400: Complex odor treatment system
101: Main body 102: Complex odor supply line
103, 201: Catalytic oxidation water storage tank 104: Catalytic oxidation water supply line
105: catalytic oxidation water distribution pipe 106: catalytic oxidation water injection nozzle
107: filling layer 108, 403: demister
109: stacked stones 202: air compressor
203: metering pump 204, 301, 402: air flow nozzle
401: blower

Claims

A catalytic oxidation water producing device;
Complex odor supply system;
A catalytic oxidation water supply device; And
And a deodorization tower coupled to the complex odor supply device and the catalytic oxidation water supply device, respectively,
A complex odor treatment system in which the complex odor supplied by the complex odor supply device is contacted with the catalytic oxidation water supplied by the catalytic oxidation water supply device to remove the complex odor,
The apparatus for producing catalytic oxidation water is a device for producing a radical by contacting a radical initiator made of peroxide, percarbonate, peroxide or a combination thereof with a functional catalyst,
Wherein the peroxide is at least one selected from the group consisting of hydrogen peroxide, sodium peroxide, potassium peroxide, carbamide peroxide, sodium perborate and sodium percarbonate,
The percarbonate may be at least one selected from the group consisting of sodium percarbonate and potassium percarbonate,
Wherein the peroxide is at least one selected from the group consisting of peracetic acid, peroxylic acid, peroxodisulfuric acid, peroxydisulfuric acid, peroxydisulfuric acid and peroxic acid,
The functional catalyst may be a ferrite based compound (MFe _x O _y , M: Zn, Ni, Cu or Mg, 0 <x? 5, y = x + 2) (50-83.655 wt%), a magnetic substance (FeFe ₂ O ₄ ) (0.45-0.55 wt.%), Titanium (0.15-0.25 wt.%), Magnesium (1.45-1.50 wt.%), Iron (3.15-3.25 wt.%), Molybdenum %), Aluminum (4.75 to 4.85 wt.%), Potassium (0.75 to 0.85 wt.%), Zirconium (1.55 to 1.65 wt.%), Silicon (0.85 to 0.95 wt.%) And tungsten (0.045 to 0.055 wt. 2.55 to 2.65% by weight) of a metal oxide; (MFe _x O _y , M: Zn, Ni, Cu or Mg, 0 <x? 5, y = x + 2) (50 to 79.55 wt.%), A magnetic material (FeFe ₂ O ₄ (0.15-0.25 wt%), magnesium (1.35-1.45 wt%), aluminum (1.35-1.40 wt%), iron (3.15-3.25 wt%), manganese (2.55-2.65 wt%), cobalt (0.75-0.85 wt%), zirconium (1.55-1.65 wt%), silicon (0.85-0.95 wt%), calcium (0.35-0.45 wt%), and germanium (4.35-4.45 wt% %) Of a second particle of brown color sintered in combination with a metal oxide; And sintered in combination of metal oxides of aluminum oxide (37.5 to 41.5 wt.%), Zirconium oxide (16.25 to 19.35 wt.%), Diatomaceous earth (32.55 to 36.65 wt.%) And barium titanate (7.5 to 9.5 wt. wherein the first particles: the second particles: the third particles are mixed in an amount of 77.5 to 78.5% by weight: 18.5 to 19.5% by weight: 2.5 to 3.5% by weight,
The deodorization tower includes a body, a complex layer disposed in the body, the complex odor supplied by the complex odor supply device being contacted with the catalytic oxidation water supplied by the catalytic oxidation water supply device to convert into a process gas, A demister for removing the liquid component in the discharged process gas, and a stack for discharging the process gas discharged from the demister to the atmosphere,
The demister is formed in a Z shape, and a plurality of demisters are stacked vertically.
The complex odor supply device includes a blower and a complex odor supply line connected thereto, wherein the catalytic oxidation water supply device includes a catalytic oxidation water storage tank, a pump connected to the catalytic oxidation water storage tank, a catalytic oxidation water supply line connected to the pump, And a plurality of injection nozzles connected to the catalytic oxidation water distribution pipe and injecting the catalytic oxidation water into the filling layer,
Wherein the catalytic oxidation water supply device comprises an air compressor for generating compressed air and an air flow nozzle for simultaneously supplying the catalytic oxidation water and the compressed air,
Wherein the blower is provided with a plurality of air nozzles for supplying the mixed odor supplied through the mixed odor supply line to the reactor and supplying both the catalytic oxidation water and the compressed air to both sides of the supplied mixed odor, The mixed odor is converted into the process gas by supplying the catalytic oxidation water on both sides of the mixed odor,
Characterized in that the reactor is connected in series to a connecting duct or a final exhaust stack of a previously installed odor treatment system to treat the complex odor component
Complex odor treatment system.

delete

The method according to claim 1,
Wherein the radical initiator is used in the form of an aqueous solution, wherein the concentration of the radical initiator in the aqueous solution is from 10 to 100 ppm by weight.

delete