KR101585148B1 - Optical film for reducing color shift and organic light emitting display employing the same - Google Patents

Abstract

Wherein the optical film has a pattern in which a plurality of curved grooves are engraved, the grooves having a depth greater than the width, the high refractive index pattern layer being made of a material having a refractive index greater than 1; And a low refractive index pattern layer made of a material having a refractive index smaller than the refractive index of the high refractive index pattern layer and including a filling material filling the plurality of grooves.

Description

TECHNICAL FIELD [0001] The present invention relates to an optical film for reducing color change and an organic light emitting display employing the same,

This disclosure relates to an optical film for reducing color change and an organic light emitting display employing the same.

An organic light emitting diode (OLED) is formed by including an anode, an organic light emitting layer, and a cathode. Here, when a voltage is applied between the anode and the cathode, holes are injected from the anode into the organic light-emitting layer, and electrons are injected from the cathode into the organic light-emitting layer. At this time, the holes and electrons injected into the organic light emitting layer recombine in the organic light emitting layer to generate excitons, and the excitons emit light while transitioning from an excited state to a ground state.

In the case of such an organic light emitting device, the lifetime due to the deterioration of the organic light emitting material is a key part in the development of OLED technology, and many technologies are being developed to overcome this.

One of them is a technique using a micro cavity structure, which resonates light of a specific wavelength to emit light by increasing the intensity. That is, the distance between the anode and the cathode is designed to match the representative wavelength of each of red (R), green (G) and blue (B), and only light corresponding thereto is resonated out and the other light is weakened. As a result, the intensity of the outgoing light is sharp and sharp, thereby increasing the brightness and color purity. And this increase in brightness leads to lower power consumption, which leads to an increase in the life span.

On the other hand, in the micro cavity structure, the wavelength to be amplified is determined by the film thickness of the organic deposition material constituting the emission layer. The light path length is different from the front side, Resulting in different amplified wavelengths.

That is, as the viewing angle tilts from the front side to the side side, the maximum resonance wavelength appears at a short wavelength and a color shift appears at a short wavelength side. For example, white appears on the front side, and on the side of the road, a phenomenon of bluish white appears due to a blue shift phenomenon.

The present disclosure aims to provide an optical film for reducing color change and an organic light emitting display employing the same.

An optical film according to one type has a first side and a second side facing each other, the first side having a pattern engraved with a plurality of curved grooves, the groove having a depth greater than a width, A high refractive index pattern layer made of a material having a refractive index greater than 1;

And a low refractive index pattern layer made of a material having a refractive index smaller than the refractive index of the high refractive index pattern layer and including a filling material filling the plurality of grooves.

The filling material may be air or a resin material.

Alternatively, the filling material may be made of a transparent plastic material containing a light diffuser or a light absorber.

The low refractive index pattern layer may be in the form of a film having a protruding pattern corresponding to the plurality of grooves, and the low refractive index pattern layer may be made of a transparent plastic material containing a light diffuser or a light absorber.

The aspect ratio defined by the ratio of the depth to the width of the groove may be greater than 1 and less than 3.

The plurality of grooves may be in the form of an extended striped shape, or may be in the form of a dot.

The curved surface forming the plurality of grooves may be aspherical.

The ratio of the sum of the widths of the plurality of grooves to the width of the high refractive index pattern layer may be 25% to 50%.

The optical film may further include a first substrate disposed on the second surface of the high refractive index pattern layer.

The first substrate may be made of an optically isotropic material.

The first substrate may be made of TAC (triacetyl cellulose).

The optical film may further include a circular polarization layer disposed on the first base material, and the circular polarization layer may include a phase conversion layer, a linear polarization layer, and a second base material.

The second substrate may be made of an optically isotropic material, and the second substrate may be made of TAC (triacetyl cellulose).

The optical film may further include an adhesive layer formed between the first base material and the circularly polarizing layer.

The optical film may further include an adhesive layer formed on the back surface of the low refractive index pattern layer in contact with the high refractive index pattern layer.

The organic light emitting display according to one type includes a plurality of pixels each having an organic light emitting layer that emits light of different wavelengths and has a micro cavity structure that causes resonance with light of a corresponding wavelength, A luminescent panel; And one of the above-described optical films disposed on the organic luminescent panel.

The plurality of grooves may be extended in a stripe shape, and the optical film may be disposed on the organic luminescent panel such that the stripe shape extends vertically above and below the organic luminescent panel.

The plurality of pixels are two-dimensionally arranged in the upper, lower, left, and right directions of the organic light emitting panel, and the direction of the stripe shape and the direction in which the plurality of pixels are arranged upward and downward .

The distance from the organic light emitting layer to the optical film may be 1.5 mm or less.

The above-mentioned optical film refracts and emits light entering perpendicularly and diagonally at various angles including front and side.

Therefore, the organic light emitting display device employing the optical film described above can form an organic light emitting layer with a microcavity structure with improved color purity. At this time, the color change according to the viewing angle can be reduced, have.

1 is an exploded perspective view showing a schematic structure of an optical film according to an embodiment.
FIG. 2 is a cross-sectional view taken along line AA 'of FIG. 1, showing an optical path in which light perpendicular to the optical film is emitted.
FIG. 3 is a cross-sectional view taken along the line AA 'in FIG. 1, showing an optical path in which light incident obliquely onto the optical film is emitted.
4 is a computer simulation graph showing the color change according to? Change in the optical film of FIG.
5 is a computer simulation graph showing the transmittance and the color change according to the change of the pattern density in the optical film of FIG.
6 is an exploded perspective view showing a schematic structure of an optical film according to another embodiment.
7 is an exploded perspective view showing a schematic structure of an optical film according to another embodiment.
8 is an exploded perspective view showing a schematic structure of an optical film according to yet another embodiment.
9 is a cross-sectional view showing a schematic structure of an optical film according to another embodiment.
10 is a cross-sectional view showing a schematic structure of an optical film according to another embodiment.
11 to 17 are sectional views showing a schematic structure of an optical film according to various embodiments employing a circularly polarizing layer and an antireflection film.
18 to 21 are sectional views showing a schematic structure of an optical film according to various embodiments employing a transmittance controlling layer and an antireflection film.
22 is a cross-sectional view showing a schematic structure of an organic light emitting diode display according to an embodiment.
Fig. 23 schematically shows the arrangement relationship of the optical films with respect to the pixel arrangement in the organic light emitting diode display of Fig. 22. Fig.
FIG. 24 is a graph showing a comparison of the color change according to the viewing angle in the organic light emitting display device when the optical film according to the embodiment is employed and when it is not employed.
Fig. 25 is a graph comparing the luminance according to the viewing angle in the organic light emitting display device when the optical film according to the embodiment is employed and when it is not employed.
26 is a cross-sectional view illustrating a schematic structure of an organic light emitting display according to another embodiment.

Hereinafter, an optical film and an organic light emitting device employing the same according to an embodiment of the present invention will be described in detail with reference to the accompanying drawings. In the following drawings, like reference numerals refer to like elements, and the size of each element in the drawings may be exaggerated for clarity and convenience of explanation. On the other hand, the embodiments described below are merely illustrative, and various modifications are possible from these embodiments. In the following, what is referred to as "upper" or "upper"

1 is an exploded perspective view showing a schematic structure of an optical film 100 according to an embodiment.

The optical film 100 is formed on the high refractive index pattern layer 110 and the high refractive index pattern layer 110 having a pattern in which a plurality of curved grooves GR are engraved with the refractive index of the high refractive index pattern layer 110 And a low refractive index material layer 120 made of a material having a smaller refractive index and including a filling material filling the plurality of grooves GR.

The high refractive index pattern layer 110 may be made of a material having a refractive index greater than 1, for example, a transparent plastic material. Also, the high refractive index pattern layer 110 may be made of a transparent plastic material containing a light diffuser or a light absorbing material. As the light diffusing member, a diffusion bead may be used, and as the light absorbing member, a black dye such as carbon black may be used. In the case of the optical diffuser, it plays a role of improving the visual acuity characteristics by flattening the peaks that can appear in the luminance profile and the color change by the specific groove by the angle. In the case of a light absorber, it can contribute to enhancement of characteristics such as contrast ratio or color purity by using a dye selectively absorbing a specific wavelength or a carbon black absorbing over a visible light wavelength .

The groove GR is formed with an aspect ratio larger than one. That is, the depth d of the groove GR is formed to be larger than the width w, the aspect ratio d / w can be in a range of greater than about 1 and less than 3, have.

In the illustrated configuration, the apex of the groove GR can define the inclination angle [theta] with respect to the starting point of the adjacent groove GR. The inclination angle? Represents the angle formed by the apex of the groove GR and the straight line connecting the point where the adjacent groove starts on the upper surface of the high refractive index pattern layer 110, with the upper surface.

The inclination angle? Can be expressed as follows using the depth d, the width A, and the period C of the groove GR.

? = tan ^-1 (d / (CA / 2))

The inclination angle? Defined in this manner can be a factor that greatly affects the performance of the optical film 1, in particular, the ability to reduce the degree of color change depending on the viewing angle, and the following condition can be satisfied.

15 ° ≤ θ ≤ 75˚

In addition to the inclination angle, the width A and the period C of the groove GR also have a great influence on the performance of the optical film 1, in particular, the color change reduction and the transmittance characteristics, .

A / C < 0.5

The surface on which the groove GR is formed is formed of a curved surface and may also be an aspherical surface. For example, the curved surface forming the groove GR may be an elliptical surface, a parabolic surface or a hyperboloid surface. Further, the groove GR may have a shape elongated in a stripe shape as shown.

The ratio of the sum of the widths of the plurality of grooves GR to the width of the high refractive index pattern layer 110 may be about 25% to 50%.

The low refractive index pattern layer 120 may be in the form of a film having a protruding pattern P corresponding to a plurality of grooves GR as shown in the figure. That is, it is a form that not only fills a plurality of grooves GR but also includes a flat coating film having a thickness exceeding a certain thickness. Depending on the fill material filling the groove (GR) or the filling process, the thickness and leveling of the flat part may vary. The low refractive index pattern layer 120 may be made of a transparent plastic material having a refractive index smaller than the refractive index of the high refractive index pattern layer 110 and may be made of a transparent plastic material containing a light diffusing material or a light absorbing material have. As the light diffusing member, a diffusion bead may be used, and as the light absorbing member, a black dye such as carbon black may be used.

The optical film 100 refracts the light incident from one direction in various directions according to the incident position and emits the light. The optical film 100 serves to mix light and will be described with reference to FIGS. 2 and 3. FIG.

FIG. 2 is a cross-sectional view taken along the line AA 'of FIG. 1, showing an optical path through which light incident perpendicular to the optical film 100 is emitted. FIG. 3 is a cross- And a light path through which a light is emitted.

2 and 3, the interface between the high refractive index pattern layer 110 and the low refractive index pattern layer 120 includes a curved surface 110a and a flat surface 110b forming a groove GR, The curved surface 110a serves as a lens surface.

Referring to FIG. 2, the light perpendicular to the optical film 100 is refracted in different directions depending on the position where the optical film 100 meets the curved surface 110a, and is emitted from the optical film 100. That is, since the light beams having the same incident angle are refracted in various directions according to different positions on the curved surface 110a, the light is diffused.

Referring to FIG. 3, the light incident on the optical film 100 is deflected in different directions depending on the incident position. Specifically, the light L1 passing through the flat surface 110b and meeting the curved surface 110a in the high refractive index pattern layer 110 is totally reflected on the curved surface 110a, and the optical film 100 is emitted. In this path, the angle at which the upper surface of the high refractive index pattern layer 110 is emitted is smaller than that at the time when it is incident on the optical film 100. On the other hand, the light L2 passing through the flat surface 110b by the path not passing through the curved surface 110a is refracted in such a form that the refraction angle becomes larger than the incident angle at the boundary between the high refractive index pattern layer 110 and the outside, The optical film 100 is emitted at a larger angle than the angle incident on the film 100. [ In addition, since the light that meets the curved surface 110a in the low refractive index pattern layer 120 is refracted in the curved surface 110a and refracted again in the upper surface of the high refractive index pattern layer 110, the light passing through the flat surface 110b The optical film 100 is emitted at a larger refraction angle than the light L2 emitted without encountering the curved surface 110a. As described above, the light beams L1, L2, and L3 incident obliquely at the same angle on the optical film 100 emit the optical film 100 at different refraction angles depending on the incident positions.

As described above, the light having passed through the optical film 100 is mixed with the angles incident on the optical film 100 at various angles.

In the above description, a specific optical path through which incident light is diffused is an example, and the refractive index difference between the high refractive index pattern layer 110 and the low refractive index pattern layer 120, the refractive index difference between the high refractive index pattern layer 110 and the groove GR The shape of the groove GR, and the ratio of the grooves GR, the light path is slightly different, and accordingly, the degree of light mixing and the brightness of the emitted light are different.

When the light incident on the optical film 100 has different optical characteristics according to the incident angle, the above-described optical mixing effect brings about an effect of evenly mixing such optical characteristics and emitting the same. For example, when a light is emitted from an organic light emitting device, a color change phenomenon appears somewhat different depending on an emission angle of the light. After the light passes through the optical film 100 of the above structure, The color change due to the viewing angle is reduced.

4 is a computer simulation graph showing the color change (? U'v ') according to? Change in the optical film 100 of FIG.

Computer simulations were performed using an illumination optics simulation program and how the color change (△ u'v ') per viewing angle appears in OLED (organic light emitting device) panel simulations involving a micro cavity structure (x, y) = (0.28, 0.29).

The specific data shown in the graph are shown in Table 1 below.

case # θ (°) Width (A) (um) Depth (d) (um) Period (C) (um) △ u'v ' One 3.95 10 2 34 0.0384 2 9.78 10 5 34 0.031 3 17.24 10 9 34 0.02 4 46.22 10 24 28 0.0125 5 55.3 10 26 23 0.0098 6 63.43 10 36 23 0.0156 7 69.4 10 12 9.5 0.019 8 74.5 10 36 15 0.023

Referring to the graph, it can be seen that as the θ increases, the color change (Δu'v ') decreases and then increases again. That is, until the angle reaches a certain angle, the color change (u u 'v') decreases, and when this angle becomes larger than about 60 °, the color change (u u 'v') increases again.

This is presumed to be due to the fact that the function of diffusivity becomes insignificant when? Becomes larger than a certain value. That is, as described with reference to FIG. 3, light such as L1, L2, and L3 must be properly mixed, because the ratio of light of the same type as L3 is reduced.

As a whole, the color change graph shows a V-shape from a certain angle. It is generally known that when the color change in the front contrast side is less than about 0.02, the color change in the human eye is not well recognized. Therefore, a range such as 15 ° <θ <75 ° can be considered as an improvement in color change. Also, the larger the?, The more difficult it is in the manufacturing process. Considering this, the range of 15? <? <65? May be set.

FIG. 5 is a computer simulation graph showing the transmittance and the color change (? U'v ') according to the change of the pattern density in the optical film 100 of FIG.

The specific data shown in the graph are shown in Table 2 below.

case # A / C θ (°) Width (A) (um) Depth (d) (um) Period (C) (um) △ u'v ' Transmittance One 0.18 55.4 9 66 50 0.0227 97.50% 2 0.2 55.7 10 66 50 0.0213 97% 3 0.22 55.6 11 65 50 0.02 96.40% 4 0.435 55.3 10 26 23 0.0098 87.60% 5 0.5 55.7 10 22 20 0.087 84.30% 6 0.55 55.4 11 21 20 0.093 81.30%

The graph shows the change in color and transmittance by changing the value of A / C while fixing the inclination angle (θ) in the vicinity of about 55 °.

As shown in the graph, the color change decreases as the A / C value increases, and then increases again from about 0.5 as shown in the graph. In addition, in the case of the front transmittance, the transmittance decreases linearly with the increase of A / C. However, a transmittance of a certain level or lower is insignificant as a film disposed on the front surface of the display panel. Therefore, when the A / C value at which the color change improvement is slowed or reversed is 0.5 or less, the color change improvement becomes more significant.

Hereinafter, the structure of the optical film of various embodiments will be described.

6 is a perspective view showing a schematic structure of an optical film 101 according to another embodiment.

The optical film 101 has a pattern in which a plurality of curved grooves GR are engraved, a groove GR is formed to have a depth greater than the width, and a high refractive index pattern layer 110 made of a material having a refractive index greater than 1, And a low refractive index pattern layer 121 made of a material having a refractive index smaller than the refractive index of the high refractive index pattern layer 110.

The optical film 101 of the present embodiment differs from the optical film 100 of Fig. 1 in the form of the low refractive index pattern layer 121, that is, the refractive index of the low refractive index pattern layer 120 The groove GR is filled with a low refractive index material. The low refractive index material may be a resin material or air.

7 is an exploded perspective view showing a schematic structure of an optical film 200 according to another embodiment.

The optical film 200 is formed on the high refractive index pattern layer 210 and the high refractive index pattern layer 210 having a pattern in which a plurality of curved grooves GR are engraved with the refractive index of the high refractive index pattern layer 210, And a low refractive index pattern layer 220 made of a material having a smaller refractive index and having a protruding pattern P corresponding to a plurality of grooves GR.

The optical film 200 of this embodiment is different from the optical film 100 of FIG. 1 in that the groove GR is in the form of a dot.

8 is a perspective view showing a schematic structure of an optical film 201 according to another embodiment.

The optical film 201 of this embodiment differs from the optical film 200 of FIG. 5 in the form of the low refractive index pattern layer 221. That is, instead of providing a film-shaped low refractive index pattern layer 220 having a protruding pattern, the low refractive index material may be a resin material or air, instead of a dot-shaped groove GR filled with a low refractive index material.

The optical films 100, 101, 200, and 201 may further include an antireflection film, a circularly polarized light layer, or a transmittance control layer in addition to the adhesive layer required for application to an organic light emitting display device. The structure of the optical film of various embodiments will be described in detail.

9 is a cross-sectional view showing a schematic structure of an optical film 300 according to yet another embodiment.

The optical film 300 includes a high refractive index pattern layer 110 and a low refractive index pattern layer 120. The high refractive index pattern layer 110 includes a plurality of grooves and the low refractive index pattern layer 110 is made of a material having a refractive index lower than that of the high refractive index pattern layer 120, Filling material filling the grooves. In addition to the shapes shown, the shapes of the high refractive index pattern layer 210 and the low refractive index pattern layers 121, 220, and 221 described above may also be applied.

Further, the first base material 320 may be further formed on the high refractive index pattern layer 110. The first substrate 320 may be made of an optically isotropic material, for example, TAC (triacetyl cellulose).

The circular polarization layer 340 may further include a phase conversion layer 342, a linear polarization layer 344, and a second base material 346. The circular polarization layer 340 may be formed on the first base material 320, can do. The second substrate 346 may be made of an optically isotropic material, for example, TAC (triacetyl cellulose). However, it is not limited thereto. For example, when the film to be disposed on the first base material 320 is not a circularly polarizing layer, a film such as PET, PC or the like can be used.

Further, an adhesive layer 330 may be further formed between the first substrate 320 and the circular polarization layer 340. The adhesive layer may be made of PSA (Pressure Sensitive Adhesion), or may be made of PSA containing a light absorber or a light diffusing agent.

The adhesive layer 310 may further be formed on the lower surface of the low refractive index pattern layer 120, that is, on the back surface of the low refractive index pattern layer 120 in contact with the high refractive index pattern layer 120. The lower surface of the low refractive index pattern layer 120 becomes a surface bonded to the organic light emitting display panel when the optical film 300 is applied to the organic light emitting display. The adhesive layer 310 may be composed of a PSA including a light absorber and a light diffusing agent.

10 is a cross-sectional view showing a schematic structure of an optical film 905 according to yet another embodiment.

 The optical film 905 has a structure in which the antireflection film 190 is formed on the high refractive index pattern layer 110 and the first adhesive layer 131 is formed on the low refractive index pattern layer 120, The first base material 141 may be further formed between the pattern layer 110 and the antireflection film 190.

The antireflection film 190 may have a multilayer structure of inorganic materials having different refractive indices, and may have a two-layer structure of, for example, a high refractive index layer and a low refractive index layer.

The first adhesive layer 131 may be made of PSA (Pressure Sensitive Adhesion) or PSA including a light absorber or a light diffusing agent. In addition, the high refractive index pattern layer 110 and / or the low refractive index pattern layer 120 may be formed of a transparent material containing a light absorber. When a material containing a light absorber is applied to various layers constituting the optical film, the reflectance of external light can be lowered to improve the visibility.

The first base material 141 is used as a base material for forming the high refractive index pattern layer 110 and the low refractive index pattern layer 120 and may be made of an optically isotropic material and may be made of, for example, TAC (triacetyl cellulose) Lt; / RTI &gt;

11 to 17 are sectional views showing the schematic structure of optical films 906 to 912 according to various embodiments employing a circularly polarized light layer and an antireflection film.

The circular polarization layer may include a phase conversion layer 150 and a linear polarization layer 160.

The phase conversion layer 150 may be, for example, a quarter wave film.

The linear polarized light layer 160 may include a polyvinyl alcohol (PVA) film, a laminated structure with a TAC film (triacetyl cellulose film), or various other structures. The PVA film is a film that polarizes light and can be formed by adsorbing a dichroic dye to polyvinyl alcohol as a polymer material.

11 and 12, the optical films 906 and 907 are composed of an adhesive layer 131, a low refractive index pattern layer 120, a high refractive index pattern layer 110, a phase conversion layer 150, a linear polarization layer 160, a first base 141, and an anti-reflection film 190.

The circularly polarized light layer made of the phase conversion layer 150 and the linear polarized light layer 160 serves to lower the reflectance of the external light to improve the visibility. When the non-polarized external light is incident, the external light passes through the linear polarized light layer 160, changes into linear polarized light, and is converted into circular polarized light by the phase conversion layer 150. The circularly polarized light passes through the interface high refractive index pattern layer 110 between the phase conversion layer 150 and the high refractive index pattern layer 110, the low refractive index pattern layer 120 and the first adhesive layer 131, 1 adhesive layer 131, and is changed to a circularly polarized light having an opposite direction of rotation by being reflected at the interface of the organic luminescent panel (not shown) The circularly polarized light passes through the phase conversion layer 150 and becomes linearly polarized light perpendicular to the transmission axis of the linearly polarized light layer 160, so that it is not emitted to the outside.

As shown in the figure, the circular polarization layer is disposed on the high refractive index pattern layer 110. Therefore, when the high refractive index pattern layer 110 is formed of an anisotropic material having a different optical axis from the circular polarization layer, The external light can go out again, and the amount of reflection may increase sharply and the visibility may be lowered. Therefore, the high refractive index pattern layer 110 should be formed of the same isotropic material as the circular polarization layer and the optical axis, such as triacetyl cellulose (TAC) or solvent cast polycarbonate (PC).

The optical film 907 shown in Fig. 12 differs from the optical film 906 shown in Fig. 11 in that the optical film 907 is formed between the high refractive index pattern layer 110 and the phase conversion layer 150 and between the high refractive index pattern layer 110 and the phase conversion layer 150, the second base material 142 and the second adhesive layer 132 are formed in this order.

13 and 14, the optical films 908 and 909 include a first adhesive layer 131, a phase conversion layer 150, a linear polarization layer 160, a low refractive index pattern layer 120, Layer 110, a first substrate 141, and an anti-reflection film 190. [

The optical film 909 shown in Fig. 14 is disposed between the linear polarization layer 160 and the low refractive index pattern layer 120 in order from the linear polarization layer 160 toward the low refractive index pattern layer 120, A second adhesive layer 132 is further formed.

15 and 16, the optical films 910 and 911 include a first adhesive layer 131, a phase conversion layer 150, a low refractive index pattern layer 120, a high refractive index layer A patterned layer 110, a linear polarization layer 160, a first base 141, and an antireflection film 190.

In the optical film 911 of FIG. 16, a second base material 142 is further formed between the high refractive index pattern layer 110 and the linear polarization layer 160.

17 includes a first adhesive layer 131, a phase change layer 150, a linear polarization layer 160, a first base material 141, a low refractive index pattern layer 120 A high refractive index pattern layer 110, and an antireflection film 190.

18 to 20 are sectional views showing the schematic structure of optical films 913 to 916 according to various embodiments employing a transmittance controlling layer and an antireflection film.

The transmittance controlling layer 170 may be formed by dispersing a black dye, a pigment, a carbon black or a crosslinked particle coated with a black material, which is capable of absorbing light, into the polymer resin Shaped film. As the polymer resin, not only a binder such as PMMA but also a UV-curable resin such as an acrylic resin may be used. In addition, the thickness of the transmittance controlling layer 170 and the content of the black material contained in the polymer resin may be appropriately determined according to the optical properties of the black material. The transmittance of the transmittance controlling layer 170 may be 40% or more, which is somewhat higher than the transmittance of the circularly polarizing layer. The use of the transmittance controlling layer 170 is intended to compensate the disadvantage that the circular polarizing layer substantially completely shields the silver external light, but has a low transmittance.

18 and 19, the optical films 913 and 914 are composed of a first adhesive layer 131, a low refractive index pattern layer 120, a high refractive index pattern layer 110, 1 carrier film 181, and an anti-reflection film 190.

The optical film 914 of Figure 19 has a second adhesive layer 132 between the first carrier film 181 and the transmittance controlling layer 170 and a second adhesive layer 132 between the transmittance controlling layer 170 and the anti- A second carrier film 182 is further formed.

The optical films 915 and 916 in FIGS. 20 and 21 are composed of a first adhesive layer 131, a low refractive index pattern layer 120, a high refractive index pattern layer 110, a transmittance adjusting layer 170, a first carrier film 181, and an anti-reflection film 190.

The optical film 916 of Figure 21 has a second adhesive layer 132 formed between the high refractive index pattern layer 110 and the transmittance control layer and a second adhesive layer 132 between the first adhesive layer 131 and the low refractive index pattern layer 120 A second carrier film 182 is further formed.

The first and second carrier films 181 and 182 may be used for the high refractive index pattern layer 110 and the substrate for forming the low refractive index pattern layer 120 or for the antireflection film 190 or the transmittance control layer 170 Is used as a substrate. Since the optical films 913 to 916 of the embodiments of Figs. 16 to 19 do not include a linear polarization layer, the function of maintaining the polarization is not required, and various materials including PET, PC, Can be used.

1 are illustrated as the high refractive index pattern layer 110 and the low refractive index pattern layer 120 in the optical films 915 to 916 of FIGS. 11 to 21, the present invention is not limited thereto, and in FIGS. 6 to 8 And may be modified into the illustrated structure.

FIG. 22 is a cross-sectional view showing a schematic structure of an organic light emitting display 500 according to an embodiment. FIG. 23 is a cross-sectional view illustrating a pixel arrangement of the organic light emitting display panel 510 in the organic light emitting display 500 of FIG. And the arrangement of the optical film 520 is schematically shown.

The organic light emitting diode display 500 includes an organic light emitting layer including a plurality of pixels each having an organic light emitting layer that emits light having a different wavelength and generates a resonance phenomenon with respect to light having the corresponding wavelength, A panel 510, and an optical film 530 disposed on the organic luminescent panel 510. An adhesive layer 520 may be further formed between the organic luminescent panel 510 and the optical film 530. Further, a circularly polarizing layer 540 may be further disposed on the optical film 530.

The organic luminescent panel 510 is formed as a micro cavity structure for improving brightness and color purity. That is, the organic light emitting panel 500 includes a plurality of organic light emitting devices that emit red, green, blue, or white light. The organic light emitting device includes an anode 13, an organic light emitting layer 14, a cathode 15). 7, in the case of the organic luminescent panel 510 having the organic light emitting element configured to emit red (R), green (G), and blue (B) The microcavity structure is formed in a structure in which the distance between the anode 14 and the cathode 16 is the longest and the distance between the anode 14 and the cathode 16 of the blue organic light emitting element having a short wavelength is relatively shortest. That is, the organic luminescent panel 510 is formed so that the distance between the anode 13 and the cathode 15 is matched to the representative wavelength of each of red, green, and blue so that only the corresponding light is resonated and emitted outside, .

A more detailed structure of the organic luminescent panel 510 will be described below.

Each sub-pixel of the organic luminescent panel 510 is disposed between the first substrate 11 and the second substrate 19 facing each other and includes an anode 13, an organic emission layer 14, And a driving circuit unit 112 formed on the first substrate 11 and electrically connected to the anode 13 and the cathode 15. [

The anode 15 may be made of an opaque metal such as aluminum and the cathode 15 may be made of indium tin oxide (ITO) so that light emitted from the organic light- Or a semitransparent electrode of a nickel (Ni) thin film.

The driving circuit unit 12 may include at least two thin film transistors (not shown) and a capacitor (not shown), and may control the amount of current supplied to the organic light emitting element according to the data signal to control the brightness of the organic light emitting element .

The driving circuit unit 12 is a circuit for driving the unit pixels of the organic light emitting panel 510 and includes a gate line and a data line perpendicularly intersecting the gate line, A driving thin film transistor connected between the switching thin film transistor and the power supply line and a storage capacitor connected between the gate electrode of the driving thin film transistor and the power supply line, .

At this time, the switching thin film transistor supplies the data signal of the data line to the gate electrode of the driving thin film transistor and the storage capacitor in response to the scan signal of the gate line. In addition, the driving thin film transistor controls the current supplied from the power supply line to the organic light emitting element in response to the data signal from the switching thin film transistor to control the brightness of the organic light emitting element. The storage capacitor charges the data signal from the switching thin film transistor and supplies the charged voltage to the driving thin film transistor so that the driving thin film transistor can supply a constant current even if the switching thin film transistor is off.

The organic light emitting layer 15 is formed to include a hole injecting layer, a hole transporting layer, a light emitting layer, an electron transporting layer, and an electron injecting layer which are sequentially stacked on the anode 13. According to this structure, when a forward voltage is applied between the anode 13 and the cathode 15, electrons are moved from the cathode 15 to the light emitting layer through the electron injection layer and the electron transporting layer, The hole injection layer and the hole transport layer to the light emitting layer. The electrons and holes injected into the light emitting layer are recombined in the light emitting layer to generate excitons. The excitons emit light while transitioning from an excited state to a ground state, The brightness of the light is proportional to the amount of current flowing between the anode 13 and the cathode 15.

Further, the organic luminescent panel 10 is provided with a color filter 17 for improving color efficiency. At this time, the color filter 17 is formed on the second substrate 12, and a red color filter is formed in the red sub pixel region, a green color filter is formed in the green sub pixel region, and a blue color filter is formed in the blue sub pixel region. If the unit pixel includes four colors (red, green, blue, and white), the color filter 17 may be omitted in the white sub pixel area.

Although not shown, a black matrix may be formed on the second substrate 12 at the boundaries of the sub-pixels to prevent light leakage and prevent color mixing. In addition, a spacer for electrical connection between the anode 13 and the cathode 15 and for electrical connection between the anode 13 and the driving circuit portion 12 may be formed, which is electrically connected to the first substrate 11 and the second And by face-to-face covalent bonding by the sealing material of the substrate 12.

On the other hand, as the viewing angle is tilted from the front side to the side side, the organic light emitting display 500 employing the micro cavity structure exhibits a maximum resonance wavelength at a short wavelength and a color shift toward a short wavelength side. For example, white appears on the front side, and on the side of the road, a phenomenon of bluish white appears due to a blue shift phenomenon.

The organic light emitting diode display 500 of this embodiment has the optical film 530 disposed on the organic light emitting display panel 510 to reduce the color change. The optical film 530 has a pattern in which a plurality of curved grooves GR are engraved, the groove GR has a high refractive index pattern layer 531 made of a material having a refractive index greater than 1, And a filling material made of a material having a refractive index smaller than the refractive index of the high refractive index pattern layer and filling the plurality of grooves GR. For example, a high refractive index pattern layer 531 and a low refractive index pattern layer 532 having a protruding pattern corresponding to a plurality of grooves GR.

As the optical film 530, the optical films 100, 101, 200, and 201 having various structures described with reference to FIGS. 1 to 6 may be employed.

The grooves GR of the optical film 530 may be elongated in the form of a stripe and the stripe shape may be a shape extending in the vertical direction of the organic light emitting panel 510. In this case, Gt; 510 &lt; / RTI &gt; The optical film 530 may be disposed on the organic light emitting panel 510 such that an integer number of grooves GR of the optical film 530 correspond to one pixel of the organic light emitting panel 510. [

As described in FIGS. 2 and 3, the optical film 530 serves to output light incident at a predetermined angle at various angles. On the other hand, the light emitted from the organic light emitting display panel 510 has a predetermined angular distribution and slightly different color changing properties depending on the angle. After this light passes through the optical film 530, the light incident on the optical film 53 at a large angle of color change and the light incident on the optical film 530 at a small angle of color change are mixed and emitted uniformly , The color change due to the viewing angle of the viewer is reduced.

23, the plurality of pixels R, G, and B of the organic light emitting panel 510 are arranged two-dimensionally in the upper, lower, left, and right directions of the organic light emitting panel, The direction of the stripe shape formed by the grooves GR of the pixels 530 and 530 and the direction in which the plurality of pixels are arranged upward and downward can be shifted without being aligned with each other. In the case where the groove GR is a stripe pattern, a moire pattern due to interference between the organic luminescent panel 510 and the optical film 530 may occur. As shown in the figure, a predetermined angle is formed between the stripe direction and the pixel array direction A moire pattern can be prevented from occurring.

 The adhesive layer 520 may be formed on the organic luminescent panel 510 and the optical film 530. The adhesive layer 520 may be formed of a pressure sensitive adhesive (PSA) material containing a light absorber and a light diffusing agent, &Lt; / RTI &gt;

The high refractive index pattern layer 531 and / or the low refractive index pattern layer 532 constituting the optical film 530 may be formed of a transparent material containing a light absorbing material.

When a substance containing a light absorber is applied to the adhesive layer 520 or the optical film 530 as described above, the reflectivity of external light can be lowered and the visibility can be increased.

 A circular polarization layer 540 may be further disposed on the optical film 530 and the circular polarization layer 540 may include a linear polarization layer 544 and a phase conversion layer 542.

The linear polarized light layer 544 may include a triacetyl cellulose film and a polyvinyl alcohol (PVA) film. For example, the linear polarizing layer 544 may be a laminated structure of a TAC film / PVA film / TAC film. The linear polarization layer 544 may have various other configurations. Here, the PVA film is a film that polarizes light, and can be formed by adsorbing a dichroic dye to polyvinyl alcohol, which is a high molecular substance. The TAC film disposed on both sides of the PVA film serves to support the PVA film.

The phase conversion layer 542 may be, for example, a quarter wave film.

The circularly polarizing layer 540 serves to lower the reflectance of external light to improve visibility. When the non-polarized external light is incident, the external light passes through the linear polarized light layer 544, becomes linearly polarized light, and is converted into circularly polarized light by the phase conversion layer 542. The circularly polarized light is reflected at the interface between the phase conversion layer 542 and the optical film 530 or at the interface between the optical film 530 and the organic light emitting panel 510, . The circularly polarized light passes through the phase conversion layer 542, becomes linearly polarized light perpendicular to the transmission axis of the linearly polarized light layer 544, and eventually is not emitted to the outside.

Since the circularly polarized light layer 540 is disposed on the optical film 530, the high refractive index pattern layer 531 constituting the optical film 530 can be separated from the circularly polarized light layer 530 by a ratio The polarized light is broken, and the incident external light can be returned to the outside. As a result, the amount of reflection of the organic luminescent panel 510 is rapidly increased and the visibility may be lowered. The high refractive index pattern layer 531 is formed of the same isotropic material as the circular polarization layer 530 such as triacetyl cellulose (TAC) or solvent cast polycarbonate (PC) .

22 shows an example in which a phase conversion layer 542 and a linear polarization layer 544 are sequentially formed on the optical film 530. It is to be noted that the optical film 530 is formed between the phase conversion layer 542 and the linear polarization layer 544 530) may be disposed.

The optical film 530 is disposed to reduce the color change depending on the viewing angle, but there may be image distortion. Therefore, the distance from the organic light emitting layer 14 to the optical film 530 can be set to about 1.5 mm or less so as to minimize image distortion.

FIG. 24 is a graph showing a comparison of the color change depending on the viewing angle in the organic light emitting display device when the optical film according to the embodiment is employed, and when it is not employed.

The horizontal axis of the graph represents the viewing angle, and the vertical axis of the graph represents the color change, indicating the degree of deviation from the reference color coordinate. Referring to the graph, in the case of employing an optical film, the color change due to the viewing angle change is small. Further, when a light diffusing agent is used together, it becomes a smooth shape in which a peak appearing by a specific groove disappears in a color change graph corresponding to a change in viewing angle. It becomes.

Fig. 25 is a graph comparing the luminance according to the viewing angle in the organic light emitting display device when the optical film according to the embodiment is employed and when it is not employed.

Referring to the graph, when an optical film is used, the luminance distribution according to the viewing angle and the case where the optical film is not used are similar. In addition, when the light diffusing agent is used together, it becomes a smooth shape in which the peak appearing by the specific groove disappears in the luminance distribution graph according to the viewing angle.

24 and 25, it can be seen that the optical film employed in the organic light emitting display according to the embodiment hardly affects the shape of the luminance distribution according to the viewing angle, and reduces the color change according to the viewing angle.

FIG. 26 is a cross-sectional view showing a schematic structure of an organic light emitting diode display 600 according to another embodiment.

The OLED display 600 includes an OLED display panel 510 and an optical film 300. The optical film 300 may have the structure exemplified in Fig. 7, i.e., the adhesive layer 310, the low refractive index pattern layer 120, the high refractive index pattern layer 110, the first substrate 320, And the circular polarization layer 340 may include a linear polarization layer 342, a phase conversion layer 344, and a second base material 346. The circular polarization layer 340 may be a circular polarization layer.

The first substrate 320 and the second substrate 346 may be made of an optically isotropic material, for example, TAC (triacetyl cellulose). The adhesive layers 310 and 330 may be made of PSA (Pressure Sensitive Adhesion), or PSA containing a light absorber and an optical acid.

The low refractive index pattern layer 120 and the high refractive index pattern layer 110 may be changed to the shapes illustrated in Figs. 6 to 8, in addition to the shapes shown in Figs.

The optical film 300 employed in the organic light emitting display 600 is shown in the structure of FIG. 9, but this is merely an example, and the optical films 915 to 912 of FIGS. 10 to 21 may be employed.

Although the optical film and the organic light emitting device employing the optical film of the present invention have been described with reference to the embodiments shown in the drawings in order to facilitate understanding, it is to be understood that those skilled in the art will appreciate that various modifications, It will be appreciated that other equivalent embodiments are possible. Accordingly, the true scope of the present invention should be determined by the appended claims.

100, 101, 200, 201, 300, 530, 905 to 916 ... optical film
110, 210, 531 ... high refractive index pattern layers 141, 320 ... first substrate
120, 121, 220, 221, 532 ... low refractive index pattern layer
310, 330, 520 ... adhesive layer 142, 346 ... second substrate
510 ... organic luminescent panel 340, 540 ... circular polarizing layer
150, 342, 542 ... phase conversion layers 160, 344, 544 ... linear polarization layer
181, 182 ... First and second carrier films 170 ... Transmittance controlling layer
190 ... antireflection film 500, 600 ... organic light emitting display

Claims (45)

And a first surface and a second surface facing each other, wherein the first surface has a pattern in which a plurality of grooves are engraved, a flat surface is provided between the plurality of grooves, and a material having a refractive index greater than 1 A refractive index pattern layer;
And a low refractive index pattern layer made of a material having a refractive index smaller than that of the high refractive index pattern layer and including a filling material filling the plurality of grooves,
The width (A) and the period (C) of the groove satisfy the following condition,
A / C ≤ 0.5
And the light incident through the low refractive index pattern layer is emitted through the high refractive index pattern layer. The method according to claim 1,
Wherein the filling material is air or a resin material. The method according to claim 1,
Wherein the filling material is made of a transparent plastic material containing a light diffuser or a light absorber. The method according to claim 1,
Wherein the low refractive index pattern layer is in the form of a film having a protruding pattern corresponding to the plurality of grooves. 5. The method of claim 4,
Wherein the low refractive index pattern layer is made of a transparent plastic material containing an optical diffuser or a light absorber. 6. The method according to any one of claims 1 to 5,
Wherein the aspect ratio defined by the ratio of the depth to the width of the groove is greater than 1 and less than 3. 6. The method according to any one of claims 1 to 5,
Wherein the plurality of grooves are in the form of stripes. 6. The method according to any one of claims 1 to 5,
Wherein the plurality of grooves are in the form of dots. 6. The method according to any one of claims 1 to 5,
Wherein the curved surface forming the plurality of grooves is an aspherical surface. 6. The method according to any one of claims 1 to 5,
Wherein the ratio of the sum of the widths of the plurality of grooves to the width of the high refractive index pattern layer is 25% to 50%. 6. The method according to any one of claims 1 to 5,
And a first adhesive layer is further formed under the low refractive index pattern layer. 12. The method of claim 11,
And a circular polarization layer is further formed on the high refractive index pattern layer. 13. The method of claim 12,
Between the high refractive index pattern layer and the circular polarization layer
Wherein the first substrate and the second adhesive layer are further formed in the order from the high refractive index pattern layer toward the circularly polarized layer. 14. The method of claim 13,
Wherein the circular polarizing layer comprises a phase conversion layer, a linear polarized light layer, and a second substrate sequentially disposed on the second adhesive layer. 12. The method of claim 11,
And an antireflection film is further formed on the high refractive index pattern layer. 16. The method of claim 15,
And the first substrate is formed between the high refractive index pattern layer and the antireflection film. 17. The method of claim 16,
And a circular polarization layer having a phase conversion layer and a linear polarization layer. 18. The method of claim 17,
Between the first adhesive layer and the anti-reflection film,
Antireflection film on the first adhesive layer,
The low refractive index pattern layer, the high refractive index pattern layer, the phase conversion layer, the linear polarization layer, and the first substrate. 19. The method of claim 18,
Between the high refractive index pattern layer and the phase conversion layer,
In order from the high refractive index pattern layer toward the phase conversion layer,
A second substrate, and a second adhesive layer. 20. The method of claim 19,
Wherein the first base material and the second base material are made of an optically isotropic material. 18. The method of claim 17,
Between the first adhesive layer and the anti-reflection film,
Antireflection film in order from the first adhesive layer to the antireflection film,
Wherein the phase conversion layer, the linearly polarized light layer, the low refractive index pattern layer, the high refractive index pattern layer, and the first substrate are arranged. 22. The method of claim 21,
Between the linearly polarized light layer and the low refractive index pattern layer,
The linearly polarized light layer and the low refractive index pattern layer,
A second substrate, and a second adhesive layer. 18. The method of claim 17,
Between the first adhesive layer and the anti-reflection film,
Antireflection film in order from the first adhesive layer to the antireflection film,
Wherein the phase conversion layer, the low refractive index pattern layer, the high refractive index pattern layer, the linear polarization layer, and the first substrate are arranged. 24. The method of claim 23,
And a second base material is further formed between the high refractive index pattern layer and the linearly polarized light layer. 16. The method of claim 15,
Between the first adhesive layer and the low refractive index pattern layer
Refractive index pattern layer in the order from the first adhesive layer to the low refractive index pattern layer,
A phase conversion layer, a linear polarization layer, and an optical film on which a first substrate is formed. 16. The method of claim 15,
And a transmittance adjusting layer is further formed between the high refractive index pattern layer and the antireflection film. 27. The method of claim 26,
And a first carrier film is further formed between the high refractive index pattern layer and the transmittance control layer. 28. The method of claim 27,
A second adhesive layer is further formed between the first carrier film and the transmittance controlling layer,
And a second carrier film is further formed between the transmittance controlling layer and the antireflection film. 27. The method of claim 26,
Wherein the first carrier film is formed between the transmittance controlling layer and the antireflection film. 30. The method of claim 29,
A second adhesive layer is further formed between the high refractive index pattern layer and the transmittance control layer,
And a second carrier film is further provided between the first adhesive layer and the low refractive index pattern layer. An organic light emitting panel including a plurality of pixels each having an organic light emitting layer composed of a micro cavity structure that emits light of different wavelengths and causes resonance to light of a corresponding wavelength; And
The optical film according to any one of claims 1 to 5, which is disposed on the organic luminescent panel,
Wherein the optical film is disposed on the organic luminescent panel such that light from the organic luminescent panel is incident on the optical film through the low refractive index pattern layer and emerges through the high refractive index pattern layer. 32. The method of claim 31,
Wherein the plurality of grooves extend in a stripe shape. 33. The method of claim 32,
Wherein the optical film is disposed on the organic luminescent panel such that the stripe shape extends vertically from the organic luminescent panel. 34. The method of claim 33,
The plurality of pixels are two-dimensionally arranged in the upper, lower, left, and right directions of the organic light emitting panel,
And the direction of the stripe shape and the direction in which the plurality of pixels are arranged upward and downward are shifted without being parallel to each other. 32. The method of claim 31,
Wherein the plurality of grooves are in the form of a dot. 32. The method of claim 31,
Wherein the optical film has an aspect ratio defined by a ratio of a depth to a width of the groove greater than 1 and less than 3. 32. The method of claim 31,
Wherein the curved surface forming the plurality of grooves of the optical film is an aspherical surface. 32. The method of claim 31,
Wherein the ratio of the sum of the widths of the plurality of grooves to the width of the high refractive index pattern layer is 25% to 50%. 32. The method of claim 31,
Wherein an adhesive layer is further formed between the organic light emitting display panel and the optical film. 40. The method of claim 39,
Wherein the adhesive layer comprises a pressure sensitive adhesive (PSA) material containing a light absorber and a light diffusing agent. 40. The method of claim 39,
And a circularly polarized light layer is further formed on the high refractive index pattern layer. 40. The method of claim 39,
And an anti-reflection film is further formed on the high refractive index pattern layer. 43. The method of claim 42,
And a circular polarization layer having a phase conversion layer and a linear polarization layer is further formed between the high refractive index pattern layer and the anti-reflection film. 43. The method of claim 42,
And a transmittance adjusting layer is further formed between the high refractive index pattern layer and the anti-reflection film. 32. The method of claim 31,
Wherein a distance from the organic light emitting layer to the optical film is 1.5 mm or less.

Images