KR101582774B1 - Method of preparing incombustible binder - Google Patents
Method of preparing incombustible binder Download PDFInfo
- Publication number
- KR101582774B1 KR101582774B1 KR1020150085973A KR20150085973A KR101582774B1 KR 101582774 B1 KR101582774 B1 KR 101582774B1 KR 1020150085973 A KR1020150085973 A KR 1020150085973A KR 20150085973 A KR20150085973 A KR 20150085973A KR 101582774 B1 KR101582774 B1 KR 101582774B1
- Authority
- KR
- South Korea
- Prior art keywords
- solution
- water
- mixed
- mixing
- pva
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
-
- C08K3/0058—
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paper (AREA)
Abstract
Description
본 발명은 불연 바인더의 제조방법에 관한 것으로, 화재시 기초재료가 인화되지 않으며 유독가스를 발생시키지 않은 불연 바인더의 제조방법에 대한 것이다.The present invention relates to a method for producing a fire-retardant binder, and more particularly, to a method for producing a fire-retardant binder which does not cause a fire of a base material in a fire and does not generate toxic gas.
일반적으로 건축물에는 내장재가 설치되는데, 목재 등의 원재료를 분말하여 압착하여 제작하거나, 두 개의 판체 사이에 스치로품이나 폴리우레탄 스폰지, 석고 등을 개재하여 제작된다.In general, the interior material is installed in a building. The building material is produced by powdering and pressing the raw material such as wood, or by sandwiching a cloth, polyurethane sponge, gypsum, etc. between the two plates.
그러나 이러한 재료들은 단열성, 견고성을 확보하기 위해 분쇄된 목재, 스치로폼과 같은 기초재료를 바인더에 혼합하여 판재 형태로 성형된다. 그런데 바인더는 에폭시, 폴리이미드과 같은 경화제를 주성분으로 이루어져 있어, 화재시 쉽게 인화될 뿐만 아니라 심지어는 유독가스를 발생시킬 수 있다.
However, these materials are molded into a sheet form by mixing basic materials such as crushed wood and styrofoam into a binder in order to ensure insulation and rigidity. However, since the binder is composed mainly of a hardening agent such as epoxy or polyimide, it is not only easily burned in a fire but also can generate toxic gas.
본 발명은 상기한 문제점을 해결하기 위한 안출한 것으로서, 화재시 기초재료가 인화되지 않으며 유독가스를 발생시키지 않은 불연 바인더 및 이의 제조방법을 제공하려는 데 그 목적이 있다.SUMMARY OF THE INVENTION The present invention has been made to solve the above problems, and it is an object of the present invention to provide a fire-retardant binder which does not generate a toxic gas because the base material is not fired during a fire and a method of manufacturing the same.
본 발명의 해결하고자 하는 과제는 이상에서 언급한 과제로 제한되지 않으며, 언급하지 않은 다른 기술적 과제들은 이하의 기재로부터 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자에게 명확하게 이해될 수 있을 것이다.
The problems to be solved by the present invention are not limited to the above-mentioned problems, and other technical problems which are not mentioned can be clearly understood by those skilled in the art from the following description .
본 발명에 따른 불연 바인더는 이소프로필 알콜에 송진을 교반하고, 교반 중에 계면활성제를 첨가하여 졸 상태의 송진을 준비한 후, 물과 가성가리를 혼합한 가성가리 용액에 상기 졸 상태의 송진을 혼합한 다음, 물과 제2인산나트륨을 혼합한 제2인산나트륨 용액을 혼합하여 송진 혼합액을 준비하는 단계와, 아교를 물에 녹인 아교 용액과, PVA을 물에 녹인 PVA 용액을 준비하는 단계와, 교반기를 사용하여 상기 준비된 송진 혼합액과, 아교 용액과, PVA 용액을 혼합한 혼합 용액에 물과 염화마그네슘을 혼합하는 단계를 포함한다.The flame-retardant binder according to the present invention is produced by mixing the isopropyl alcohol with the pine resin and adding the surfactant to the resin in the sol state to prepare the pine resin, mixing the pine resin with the pseudo- Preparing a rosin mixture solution by mixing a sodium phosphate dibasic solution mixed with water and dibasic sodium phosphate; preparing a glue solution in which glue is dissolved in water and a PVA solution in which PVA is dissolved in water; And mixing water and magnesium chloride in a mixed solution obtained by mixing the prepared rosin mixture solution, glue solution and PVA solution.
한편, 가성가리 용액은 물과 혼합되는 과정에서 뜨거워진 상태에 제2인산나트륨 용액을 혼합된다.On the other hand, the caustic soda solution is mixed with sodium bisphosphate solution in a state of being hot in the process of mixing with water.
또한, 상기 혼합 용액, 물, 염화마그네슘은 각각 중량비율로 2.5 : 60 : 37.5으로 혼합된다.The mixed solution, water, and magnesium chloride are mixed at a weight ratio of 2.5: 60: 37.5, respectively.
본 발명에 따라 제조된 불연 바인더는 재생 판지, 목재판 등에 도포하거나 분쇄된 목재, 스티로폼 등과 같은 기초재료에 혼합하여 판넬 형태로 성형될 수 있다.
The non-combustible binder produced according to the present invention can be molded into a panel form by being mixed with a base material such as wood, styrofoam, etc., which is applied to recycled paperboard, wood board, or the like.
본 발명에 따른 불연 바인더는 재생 판지, 목재판 등에 도포하거나 분쇄된 목재, 스티로폼 등과 같은 기초재료에 혼합 및 성형할 수 있으므로 쉽게 원하는 형태로 제작이 용이하다.The non-burnable binder according to the present invention can be easily mixed into a desired form and easily formed into a base material such as wood, styrofoam or the like, which is applied to a recycled paperboard, wood board, or the like.
또한, 성형된 판넬은 열적 성능이 우수하고, 화재 발생시 유해 가스 배출을 방지하여 인명피해를 줄일 수 있다.
In addition, the molded panel is excellent in thermal performance and can prevent harmful gas discharge when a fire occurs, thereby reducing personal injury.
도 1은 본 발명에 따른 불연 바인더의 제조 방법을 나타낸 것이다.
도 2는 불연 바인더가 처리된 판넬의 인화시험을 보여주는 이미지이다.1 shows a method for producing a fire retardant binder according to the present invention.
2 is an image showing a print test of a panel treated with a fire retardant binder.
이하, 본 발명의 바람직한 실시예를 상세히 설명한다.
Hereinafter, preferred embodiments of the present invention will be described in detail.
본 발명에 따른 불연 바인더는 재생 판지, 목재판 등에 도포하거나 분쇄된 목재, 스티로폼 등과 같은 재료와 혼합할 수 있는 조성물이며, 본 발명에 따른 불연 바인더가 도포되거나 불연 바인더가 혼합되는 재생 판지, 목재 판넬, 분쇄된 목재 등과 같은 재료를 기초재료라 칭한다.The non-burnable binder according to the present invention is a composition which can be mixed with a material such as wood, styrofoam, and the like which is coated on a recycled paperboard, a wood board, etc., and is used as a recycled paperboard to which a fire retardant binder according to the present invention is applied or a fire- , Crushed wood, and the like are referred to as base materials.
도 1은 본 발명에 따른 불연 바인더의 제조 방법을 나타낸 것이다.1 shows a method for producing a fire retardant binder according to the present invention.
본 발명에 따른 불연 바인더는 이소프로필 알콜에 송진을 교반하고, 교반 중에 계면활성제를 첨가하여 졸 상태의 송진을 준비한 후, 물과 가성가리를 혼합한 가성가리 용액에 상기 졸 상태의 송진을 혼합한 다음, 물과 제2인산나트륨을 혼합한 제2인산나트륨 용액을 혼합하여 송진 혼합액을 준비하는 단계와, 아교를 물에 녹인 아교 용액과, PVA을 물에 녹인 PVA 용액을 준비하는 단계와, 교반기를 사용하여 상기 준비된 송진 혼합액과, 아교 용액과, PVA 용액을 혼합한 혼합 용액에 물과 염화마그네슘을 혼합하는 단계를 포함하여 제조된다.
The flame-retardant binder according to the present invention is produced by mixing the isopropyl alcohol with the pine resin and adding the surfactant to the resin in the sol state to prepare the pine resin, mixing the pine resin with the pseudo- Preparing a rosin mixture solution by mixing a sodium phosphate dibasic solution mixed with water and dibasic sodium phosphate; preparing a glue solution in which glue is dissolved in water and a PVA solution in which PVA is dissolved in water; And mixing water and magnesium chloride in a mixed solution obtained by mixing the prepared rosin mixture solution, glue solution and PVA solution.
<실시예><Examples>
설명에 앞서, 본 실시예에서는 송진 혼합액, 아교 용액, 및 PVA 용액을 제조한 후, 이들과 염화마그네슘을 물에 혼합하여 불연 바인더를 제조한다.Prior to the explanation, in this embodiment, after producing the rosin mixture solution, the glue solution and the PVA solution, they are mixed with the magnesium chloride to prepare the fire retardant binder.
1. 졸 상태의 송진을 준비하는 단계;1. preparing a rosin in a sol state;
이소프로필 알콜(IPA) 20g에 송진 15g을 넣고 약 6시간 동안 교반한다. 한편, 송진의 분산력을 높이고 이후 공정의 균일한 혼합을 위하여 교반 중에 계면활성제가 첨가된다. 실시예로서 분말 형태의 계면활성제 50g을 넣고 교반을 계속하면 끈적끈적한 상태(졸 상태)의 송진이 준비된다. 이때, 이소프로필 알콜은 이 과정에서 휘발된다. 송진은 분쇄된 스티로폴, 목재 등과 같은 기초재료를 강하게 응집시키고 방수성을 갖게 한다.15 g of pine rosin is added to 20 g of isopropyl alcohol (IPA) and the mixture is stirred for about 6 hours. On the other hand, a surfactant is added during agitation in order to increase the dispersibility of the resin and to homogeneously mix the following processes. As an example, when 50 g of a surfactant in the form of a powder is added and stirring is continued, the rosin in a sticky state (sol state) is prepared. At this time, isopropyl alcohol is volatilized in this process. Rinsing strongly coheses base materials such as crushed styropoles, wood, etc., and makes them waterproof.
2. 가성가리 용액에 졸 상태의 송진을 첨가하는 단계;2. adding solvated rhizome to the caustic solution;
우선, 물 60g에 가성가리(KOH) 15g을 넣어 녹여, 가성가리 용액을 준비한다. 이때 가성가리와 물을 혼합할 때 고열이 발생하므로 주의를 요한다. 가성가리는 강염기로서 이후에 첨가되는 조성물을 쉽게 용해시킨다.First, add 60 g of water and 15 g of caustic soda (KOH) to dissolve and prepare a caustic solution. Caution should be exercised in this case that high temperature is generated when mixing the caustic soda with water. The parasitic base is a strong base and easily dissolves the composition to be added later.
이와 같이 준비된 가성가리 용액에 졸 상태의 송진을 넣고 충분히 교반한다. 가성가리 용액은 물과 혼합되는 과정에서 뜨거워진 상태(약 65~85℃)가 되므로, 이후에 첨가되는 제2인산나트륨 용액이 쉽게 혼합될 수 있다. In the prepared caustic solution, the sol state pine rosin is added and stirred sufficiently. Since the fermentation solution becomes hot (about 65 ~ 85 ℃) in the process of mixing with water, the later added sodium phosphate solution can be easily mixed.
3. 송진이 혼합된 가성가리 용액에 제2인산나트륨을 첨가하는 단계;3. adding a second sodium phosphate to the caustic solution mixed with the rosin;
제2인산나트륨(Na2HPO4) 20g을 물 60g에 녹인 후, 송진이 첨가된 가성가리 용액과 혼합한다. 제2인산나트륨은 정인산염으로서 냄새가 없고 백색의 분말 또는 결정형 과립체이다. 제2인산나트륨은 물에는 쉽게 용해되며 알코올이나 에탄올에는 녹지 않는다. 제2인산나트륨은 기초재료의 결착력을 증대시킨다.20 g of dibasic sodium phosphate (Na2HPO4) is dissolved in 60 g of water, and then mixed with the sparingly added caustic solution. Sodium phosphate dibasic phosphate is odorless and white powder or crystalline granules. Dibasic sodium phosphate is readily soluble in water and does not dissolve in alcohol or ethanol. The dibasic sodium phosphate increases the binding force of the base material.
한편, 가성가리 용액에 송진과 제2인산나트륨을 동시에 첨가하여도 되지만, 졸 상태의 송진에는 계면활성제가 혼합되어 있어, 동시에 첨가하는 것보다 계면활성제가 포함된 용액에 제2인산나트륨을 첨가하면 상기 제2인산나트륨은 충분히 분산시킬 수 있다.On the other hand, when the sodium phosphate is added to the solution containing the surfactant rather than adding the surfactant to the polysaccharide solution in the sol state, The dibasic sodium phosphate can be sufficiently dispersed.
이와 같이 송진, 가성가리, 제2인산나트륨, 계면활성제가 물에 용해된 송진 혼합액이 준비된다. 이어서, 아교 용액과 PVA 용액을 준비한다.Thus, a rosin mixture solution in which the rosin, the pharyngeal, the dibasic sodium phosphate, and the surfactant are dissolved in water is prepared. Next, a glue solution and a PVA solution are prepared.
4. 아교 용액과 PVA 용액을 준비하는 단계;4. preparing a glue solution and a PVA solution;
약 70~80℃의 물 100g에 아교 15g을 넣고 약 30~40분 동안 흐물거릴 때까지 녹여 준비한다. 아교는 기초재료의 내진동, 내충격, 압축강도, 인장강도를 높인다. 또한 약 80~90℃의 물 100g에 PVA(polyvinyl alcohol) 7g을 넣고 약 20~30분 동안 완전히 분해될 때까지 녹여 PVA 용액을 준비한다. PVA는 물에는 쉽게 녹고 유기용매에는 잘 녹지 않는 백색의 분말이다. 기초재료의 점착력을 높인다.Add 15 g of glue to 100 g of water at about 70 to 80 ° C and dissolve for about 30 to 40 minutes until dissolved. Glue increases the vibration resistance, impact resistance, compressive strength and tensile strength of the base material. In addition, 7 g of PVA (polyvinyl alcohol) is added to 100 g of water at about 80 to 90 ° C., and the PVA solution is prepared by dissolving it for 20 to 30 minutes until it is completely decomposed. PVA is a white powder which is readily soluble in water and not soluble in organic solvents. Increases adhesion of base material.
5. 송진 용액, 아교 용액, 및 PVA 용액을 혼합하는 단계;5. mixing the rosin solution, glue solution, and PVA solution;
약 55~65℃의 물 538g에 앞서 준비한 송진 혼합액과, 아교 용액, 및 PVA 용액을 넣고 교반하여 혼합한다. 상기 혼합된 용액에는 물 87.55중량%, 송진 1.53중량%, 계면활성제 5.1중량%, 가성가리 1.53중량%, 제2인산나트륨 2.04중량%, 아교 1.53중량%, PVA 0.72중량%로 이루어져 있다.To the 538 g of water at about 55 to 65 ° C, the previously prepared pine rosin mixture, the glue solution and the PVA solution are added and mixed by stirring. The mixed solution is composed of 87.55% by weight of water, 1.53% by weight of rosin, 5.1% by weight of surfactant, 1.53% by weight of caustic soda, 2.04% by weight of sodium phosphate dibasic, 1.53% by weight of glue and 0.72% by weight of PVA.
이어서, 이와 같이 혼합된 용액에 물과 염화마그네슘을 첨가하여 혼합하면 불연 바인더가 완성된다. 본 실시예에 따른 불연 바인더는 혼합 용액(송진 혼합액, 아교 용액, PVA 용액이 혼합된 용액) 2.5중량%, 물 60중량%, 염화마그네슘 37.5중량%로 혼합된다. 이와 같은 물의 혼합비율은 기초재료에 바인더 처리시 적당한 끈적임을 제공할 수 있다.Subsequently, water and magnesium chloride are added to the mixed solution and mixed to complete the fire-retardant binder. The incombustible binder according to the present embodiment is mixed with 2.5 wt% of a mixed solution (a mixture of a rosin mixture solution, a glue solution and a PVA solution), 60 wt% of water and 37.5 wt% of magnesium chloride. Such a water mixing ratio can provide adequate tackiness to the base material during binder processing.
염화마그네슘은 염소와 마그네슘의 화합물로서 대기중에서 습기를 빨아들이는 성질이 있는 무색결정으로 보통 육수화염으로 존재한다. 염화마그네슘은 방염 특성을 향상시킨다.
Magnesium chloride is a compound of chlorine and magnesium, a colorless crystal that absorbs moisture in the atmosphere and is usually present as a gas water flame. Magnesium chloride improves flame resistance.
이와 같이 제조된 불연 바인더는 재생 판지, 목재판 등에 도포하거나 분쇄된 목재, 스티로폼 등과 같은 기초재료에 혼합 및 성형하여 판넬 형태로 성형될 수 있다.
The fire retardant binder thus produced can be molded into a panel form by being applied to a recycled paperboard, a wood board, etc., or mixed with a base material such as pulverized wood, styrofoam, and the like.
아래 표들은 불연 바인더를 사용하여 분쇄된 목재를 판넬 형태로 제작하여 시험한 것을 나타낸 것이다.The following tables show that the milled wood is produced in panel form using a fireproof binder.
[표 1][Table 1]
상기 표 1은 열방출 시험의 시험조건을 나타낸 것이다.
Table 1 shows the test conditions of the heat release test.
[표 2][Table 2]
상기 표 2는 마우스를 이용한 가스유해성 시험 조건을 나타낸 것이다.
Table 2 shows the conditions of the gas toxicity test using a mouse.
[표 3][Table 3]
상기 표 3은 열방출 시험과 가스 유해성 시험 결과를 나타낸 것이다.
Table 3 shows the results of the heat release test and the gas toxicity test.
도 2는 불연 바인더가 처리된 판넬의 인화시험을 보여주는 이미지이다. 도면에서 보듯, 판넬은 철제 플레이트를 사이에 두고 가운데에 스치로폼이 개재되어 있다. 하측 이미지는 일반적인 판넬에 가스 토치(gas torch)로 20초간 가열한 것이고, 상측 이미지는 본 발명에 따른 불연 바인더를 혼합한 스치로폼을 사용한 판넬을 사용한 것으로 5분간 가스 토치로 가열한 것이다.2 is an image showing a print test of a panel treated with a fire retardant binder. As shown in the drawing, the panel is provided with a steel foam in the center with a steel plate interposed therebetween. The lower image was obtained by heating for 20 seconds on a general panel with a gas torch and the image on the upper side was heated with a gas torch for 5 minutes using a panel using a styrofoam mixed with a fire retardant binder according to the present invention.
불연 바인더 처리가 이루어지지 않은 판넬은 짧은 가열에도 스치로폼이 열에 의해 쉽게 변형되나, 불연 바인더 처리가 이루어진 판넬은 상당한 시간을 가열하여도 그 형태를 유지하며, 열적 변형 및 인화가 이루어지지 않음을 보여준다. 따라서 인화에 따른 유해가스의 배출이 거의 이루어지지 않고 있음을 볼 수 있다.
In the panel in which the fire retardant binder treatment is not performed, the foam foam is easily deformed by heat even in a short heating, but the panel subjected to the fire retardant binder treatment maintains its shape even after heating for a considerable period of time and shows no thermal deformation and no printing. Therefore, it can be seen that the discharge of harmful gas due to the printing is hardly achieved.
이상, 본 발명을 구체적인 실시예를 통하여 상세하게 설명하였으나, 본 발명은 상기 실시예에 한정되지 않고, 본 발명의 기술적 사상의 범위내에서 통상의 지식을 가진 자에 의하여 여러 가지 변형이 가능하다.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the present invention is not limited to the disclosed exemplary embodiments, but various changes and modifications may be made by those skilled in the art without departing from the scope of the present invention.
Claims (5)
물과 제2인산나트륨을 혼합한 제2인산나트륨 용액을 혼합하여 송진 혼합액을 준비하는 단계;
아교를 물에 녹인 아교 용액과, PVA을 물에 녹인 PVA 용액을 준비하는 단계;
교반기를 사용하여 상기 준비된 송진 혼합액과, 아교 용액과, PVA 용액을 혼합한 혼합 용액에 물과 염화마그네슘을 첨가하는 단계;
를 포함하는 것을 특징으로 하는 불연 바인더의 제조방법.
After stirring the pine rosin in isopropyl alcohol and adding a surfactant to the solution during the stirring to prepare a sol state rosin, the rosin in the sol state was mixed with a caustic solution mixed with water and a soda ash,
Mixing a dibasic sodium phosphate solution mixed with water and dibasic sodium phosphate to prepare a rosin mixture solution;
Preparing a glue solution in which glue is dissolved in water and a PVA solution in which PVA is dissolved in water;
Adding water and magnesium chloride to a mixed solution obtained by mixing the prepared rosin mixture solution, glue solution and PVA solution using an agitator;
Wherein the binder is a metal.
가성가리 용액은 물과 혼합되는 과정에서 제2인산나트륨 용액을 혼합하는 것을 특징으로 하는 불연 바인더의 제조방법.
The method according to claim 1,
Wherein the sphalerite solution is mixed with sodium bisphosphate solution during mixing with water.
상기 혼합 용액, 물, 염화마그네슘은 각각 중량비로 2.5 : 60 : 37.5로 혼합되는 것을 특징으로 하는 불연 바인더의 제조방법.
The method according to claim 1,
Wherein the mixed solution, water, and magnesium chloride are mixed at a weight ratio of 2.5: 60: 37.5, respectively.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020150085973A KR101582774B1 (en) | 2015-06-17 | 2015-06-17 | Method of preparing incombustible binder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020150085973A KR101582774B1 (en) | 2015-06-17 | 2015-06-17 | Method of preparing incombustible binder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR101582774B1 true KR101582774B1 (en) | 2016-01-07 |
Family
ID=55169043
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020150085973A KR101582774B1 (en) | 2015-06-17 | 2015-06-17 | Method of preparing incombustible binder |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR101582774B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101812203B1 (en) * | 2016-07-12 | 2017-12-26 | 주식회사 그린바이오 | The eco-friendly inorganic flame retardant adhesive composition |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR200280502Y1 (en) * | 2002-04-16 | 2002-07-02 | 이윤선 | native rock mat |
| KR20050033423A (en) | 2004-08-30 | 2005-04-12 | 오은영 | Incombustible building panel and manufacturing method |
| KR100556902B1 (en) | 2002-06-12 | 2006-03-03 | 주식회사영일화성 | A manufacturing method of inorganic binder for liquefied sodium-silicate |
| KR20070017777A (en) * | 2005-08-08 | 2007-02-13 | 김종호 | Process for Preparing Nonflammable Panel With Improved Waterproof, Flexural Strength, and Fine-finishing Properties |
| KR20090016809A (en) | 2007-08-13 | 2009-02-18 | (주)새론화인켐 | Process for preparing flame retardant one component inorganic adhesive and one component inorganic adhesive prepared thereby |
| KR20130104381A (en) * | 2012-03-14 | 2013-09-25 | 주식회사 지엔케이 | Nonflammables suspension |
| KR20130104382A (en) * | 2012-03-14 | 2013-09-25 | 주식회사 지엔케이 | Nonflammables sandwich panel used styrofoam |
-
2015
- 2015-06-17 KR KR1020150085973A patent/KR101582774B1/en active IP Right Grant
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR200280502Y1 (en) * | 2002-04-16 | 2002-07-02 | 이윤선 | native rock mat |
| KR100556902B1 (en) | 2002-06-12 | 2006-03-03 | 주식회사영일화성 | A manufacturing method of inorganic binder for liquefied sodium-silicate |
| KR20050033423A (en) | 2004-08-30 | 2005-04-12 | 오은영 | Incombustible building panel and manufacturing method |
| KR20070017777A (en) * | 2005-08-08 | 2007-02-13 | 김종호 | Process for Preparing Nonflammable Panel With Improved Waterproof, Flexural Strength, and Fine-finishing Properties |
| KR20090016809A (en) | 2007-08-13 | 2009-02-18 | (주)새론화인켐 | Process for preparing flame retardant one component inorganic adhesive and one component inorganic adhesive prepared thereby |
| KR20130104381A (en) * | 2012-03-14 | 2013-09-25 | 주식회사 지엔케이 | Nonflammables suspension |
| KR20130104382A (en) * | 2012-03-14 | 2013-09-25 | 주식회사 지엔케이 | Nonflammables sandwich panel used styrofoam |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101812203B1 (en) * | 2016-07-12 | 2017-12-26 | 주식회사 그린바이오 | The eco-friendly inorganic flame retardant adhesive composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105694648B (en) | The resistance to fire-proof and explosion-proof coating of hydro carbons | |
| KR101812203B1 (en) | The eco-friendly inorganic flame retardant adhesive composition | |
| KR101766316B1 (en) | Nonflammability corting mortar and method using them thereof | |
| HU206739B (en) | Latexbinded anti-burning materials and layered materials against burning | |
| KR20130104382A (en) | Nonflammables sandwich panel used styrofoam | |
| KR20160112399A (en) | A non-flammable coating composition | |
| KR101582774B1 (en) | Method of preparing incombustible binder | |
| US20210340384A1 (en) | Intumescent polyacrylic acid compositions | |
| KR20150142769A (en) | The Magnesia Cemnent Composte Containing Modified Sulfur And The Method For Preparing Thereof, Lightweight Panel Comprising The Magnesia Cement Composite and Method for preparing the Same | |
| KR101589060B1 (en) | Environment Friendly and None Toxic Intumescent Fire-Retardant Paint | |
| AT511015B1 (en) | COMPOSITION FOR PREPARING FLAME-REDUCING SURFACES OR OBJECTS | |
| KR20120075821A (en) | Anti-flammable composite | |
| KR20160050402A (en) | Non-flammable composition comprising SiO2 | |
| CN109553978B (en) | Formula of flame-retardant room-temperature vulcanized silicone rubber and flame-retardant room-temperature vulcanized silicone rubber | |
| KR20090073412A (en) | Water-based transparent fire-proofing paint, method of manufacturing a water-based fire-proofing paint and method of forming a fire-proofing layer | |
| KR20160142178A (en) | Noncombustible composition for construction material | |
| KR101512443B1 (en) | The manufacturing method of non-flammable board using expanded polystyrene particles | |
| KR101720780B1 (en) | Sandwich panel using noncombustible composition and manufacturing method there of | |
| CN107141712A (en) | A kind of power equipment environment-friendly fireproof material and preparation method thereof | |
| KR101108780B1 (en) | Incombustible ceramic panel and producing method of sandwich panel using thereof | |
| KR101019980B1 (en) | non-combustible styrofoam manufacture method | |
| KR20170060233A (en) | A Composite insulation board with water-resistance property and non-flammable property | |
| KR100865177B1 (en) | Incombustible coating material for styrofoam, method for preparing the same, and flameproof process using the same | |
| RU2026842C1 (en) | Polymer cement composition | |
| KR101900620B1 (en) | Flame-retardant insulation composition comprising corn cob and flame-retardant insulation material manufactured by same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20181210 Year of fee payment: 4 |