KR101416095B1 - Paint composition for protecting transparent soundproof panel - Google Patents
Paint composition for protecting transparent soundproof panel Download PDFInfo
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
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- B05D3/065—After-treatment
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- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
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- C08K5/00—Use of organic ingredients
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- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
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- C08K5/07—Aldehydes; Ketones
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
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- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D7/63—Additives non-macromolecular organic
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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Abstract
본 발명은 우레탄 아크릴레이트 올리고머 15~25 중량%, 아크릴릭 단량체 5~10 중량%, 광개시제 1~5 중량%, 알콜 용매 20~30 중량%, 에테르 용매 10~20 중량%, 케톤 용매 10~20 중량% 및 첨가제 0.1~1.5 중량%를 포함하는 투명 방음판 보호용 도료 조성물에 관한 것이다. 본 발명에 따른 투명 방음판 보호용 도료 조성물은 PMMA, PC 등의 플라스틱 재질의 방음판에 플로우 코팅 방식으로 용이하게 적용하여 내후성, 내구성, 내마모성, 외관을 향상시킬 수 있다.The present invention relates to a process for the production of a copolymer comprising 15 to 25% by weight of a urethane acrylate oligomer, 5 to 10% by weight of an acrylic monomer, 1 to 5% by weight of a photoinitiator, 20 to 30% by weight of an alcohol solvent, 10 to 20% by weight of an ether solvent, % And 0.1 to 1.5% by weight of an additive. INDUSTRIAL APPLICABILITY The coating composition for protecting a transparent soundproof panel according to the present invention can be easily applied to a soundproof panel made of plastic such as PMMA or PC in a flow coating method to improve weatherability, durability, abrasion resistance and appearance.
Description
본 발명은 투명 방음판 보호용 도료 조성물에 관한 것으로, 보다 상세하게는 PMMA, PC 등의 플라스틱 재질 등의 방음판에 플로우 코팅 방식으로 용이하게 적용하여 내후성, 내구성, 내마모성, 외관을 향상시킬 수 있는 도료 조성물에 관한 것이다.
More particularly, the present invention relates to a coating composition capable of improving weatherability, durability, abrasion resistance and appearance by applying the coating composition to a soundproofing plate such as a plastic material such as PMMA or PC by a flow coating method. .
투명 방음벽은 일조·경관을 저해하는 방음벽 특유의 문제점을 해소할 수 있고, 나들목 또는 분기점 등에 설치되는 경우 시계 차단으로 발생될 수 있는 사고를 예방하는 장점이 있다. 또한, 방음벽으로 인해 그늘이 형성되면 동절기 노면 결빙이 지속되게 되는데 투명 방음벽을 사용하게 되면 이러한 영향을 현저하게 줄일 수 있다.The transparent sound barrier can solve the problem unique to the sound barrier which hinders the sunshine and the scenery, and has an advantage of preventing an accident that may be caused by a clock blockage when installed in a knuckle or a fork. Also, when the shade is formed due to the soundproof wall, the road surface freezing will be continued in the winter season. If the transparent soundproof wall is used, the influence can be remarkably reduced.
국내 고속도로 주변에 설치된 방음벽은 2008년을 기준으로 3,024개소에 총 설치연장 약 741 km에 이르고 있다. 투명 방음벽의 설치 비율은 전체 방음벽 연장의 2.2% 정도로서 매우 낮은 수준이나 다른 방음판과 혼합하여 사용되는 경우가 많다. 조망권에 대한 민원인들의 요구와 방음벽 디자인 평가 등으로 인하여 방음벽 전체 또는 일부에 투명 방음판을 적용하는 사례가 급격하게 증가하는 추세이다.As of 2008, the total installed length of the soundproof walls in the vicinity of the Korean highway is about 741 km, at 3,024 locations. The installation ratio of transparent sound barrier is about 2.2% of total sound barrier extension and is very low, but it is often used in combination with other sound insulation boards. The application of transparent soundproofing boards to all or part of the soundproof walls is increasing rapidly due to the requests of the complainants about the view rights and the evaluation of the soundproof wall design.
국내에서 투명 방음판으로 사용되는 소재는 폴리메틸메타크릴레이트(polymethylmethacrylate, PMMA), 폴리카보네이트(polycarbonate, PC) 등의 투명 플라스틱 계열이 가장 많이 사용되며 최근 접합 유리 제품도 사용되기 시작하였다. PMMA 는 투명성, 내광성, 표면 광택 등의 특성으로 지금까지 조명, 광학 부품, 차량 부품, 건재, 잡화 등 수많은 용도로 사용되고 있다. PMMA 시트는 투명성과 표면 질감이 우수하며 가공성이 좋을 뿐만 아니라 사용 중 유지 및 보수성이 뛰어나 건축 내·외장재로 다양하게 사용되고 있다. PC는 투명 또는 약한 갈색을 띠는 비정질의 플라스틱으로서 내충격성, 내열성, 상용성 등이 우수하여 전기·전자 기기, 자동차 부품, 의료기기 등 광범위한 분야에 사용되고 있다.Transparent plastics such as polymethylmethacrylate (PMMA) and polycarbonate (PC) are the most commonly used materials for transparent soundproofing panels in Korea, and recently laminated glass products have also started to be used. PMMA has been used for many applications such as lighting, optical parts, vehicle parts, construction materials, and miscellaneous goods due to its transparency, light resistance and surface gloss. PMMA sheet is excellent in transparency and surface texture, and is not only good in workability, but also excellent in maintenance and maintenance during use, and is widely used as interior and exterior materials for construction. PC is transparent or weakly brown amorphous plastic and has excellent impact resistance, heat resistance and compatibility, and is used in a wide range of fields such as electric and electronic devices, automobile parts, and medical devices.
이러한 플라스틱 소재는 시간이 경과됨에 따라 황변 현상과 재질 변경 등으로 인해 투명도가 떨어지고 오염된 상태로 남아 오히려 도시 미관을 손상시키는 경우를 흔히 볼 수 있다. 또한, 강성이 충분하지 않은 프레임을 사용하여 강풍에 의해 프레임이 휜 경우도 발생하며, 도로 상의 화물차에서 적재된 화물이 떨어지면서 방음판에 부딪치거나 노면으로부터 튄 돌이나 사람의 투석에 의해 파손된 방음판도 종종 발견된다.Such plastic materials tend to be deteriorated in transparency due to yellowing and material change as time passes, and it is often seen that they remain contaminated, but rather damage the cityscape. In addition, the frame may be bent by strong wind using a frame having insufficient rigidity, and the frame may be bent due to collision with the soundproof plate when the cargo loaded on the road is dropped, Are often found.
따라서, 고속도로 등의 도로에 설치되는 플라스틱 재질의 방음판은 투명성을 유지될 수 있도록 내후성을 가져야 하고, 내구성, 내마모성이 우수할 것이 요구된다.Therefore, a soundproofing plate made of a plastic material installed on a road such as a highway is required to have weather resistance so as to maintain transparency, and to have excellent durability and abrasion resistance.
한국등록특허 제1039306호에서는 접착성, 내약품성, 내후성, 내열성, 방음, 방수 등의 물성을 유지할 수 있는 외벽 마감용 도료 조성물을 개시하고 있으며, 상기 외벽 마감용 도료 조성물은 a) 상온 경화형 유기 액상 수지 100 중량부; b) 유리 비드(glass bead) 10 내지 200 중량부; 및 c) 칼슘실리케이트 수화물 또는 비정질 실리카 1 내지 40 중량부를 포함하여 구성된다.Korean Patent No. 1039306 discloses a coating composition for external wall finishing which can maintain physical properties such as adhesiveness, chemical resistance, weather resistance, heat resistance, soundproofing and waterproofing. The coating composition for external wall finishing comprises: a) 100 parts by weight of a resin; b) 10 to 200 parts by weight of glass beads; And c) 1 to 40 parts by weight of calcium silicate hydrate or amorphous silica.
본 발명자들은 상기 종래기술과 달리 도로 등에 설치된 투명 방음판의 내후성, 내구성, 내마모성, 외관을 향상시킬 수 있는 도료 조성물을 개발하기 위해 연구를 거듭하였고, 그 결과 PMMA, PC 등에 용이하게 적용하여 내후성, 내구성, 내마모성, 외관을 향상시킬 수 있는 도료 조성물을 개발하여 본 발명을 완성하기에 이르렀다.
The inventors of the present invention have conducted studies to develop a coating composition which can improve the weather resistance, durability, abrasion resistance, and appearance of a transparent soundproof panel installed on the road unlike the above-mentioned prior art. As a result, , Abrasion resistance, and appearance, thereby completing the present invention.
본 발명의 목적은 고속도로 등의 도로에 설치되는 플라스틱 재질 등의 방음판에 플로우 코팅 방식으로 용이하게 적용하여 내후성, 내구성, 내마모성, 외관을 향상시킬 수 있는 도료 조성물을 제공하는 데 있다.
An object of the present invention is to provide a coating composition which can be easily applied to a soundproof plate such as a plastic material installed on a road such as an expressway in a flow coating system to improve weatherability, durability, abrasion resistance and appearance.
상기 목적을 달성하기 위하여, 본 발명은 우레탄 아크릴레이트 올리고머 15~25 중량%, 아크릴릭 단량체 5~10 중량%, 광개시제 1~5 중량%, 알콜 용매 20~30 중량%, 에테르 용매 10~20 중량%, 케톤 용매 10~20 중량% 및 첨가제 0.1~1.5 중량%를 포함하는 투명 방음판 보호용 도료 조성물을 제공한다.In order to accomplish the above object, the present invention provides a process for producing an acrylic resin composition, which comprises 15 to 25 wt% of a urethane acrylate oligomer, 5 to 10 wt% of an acrylic monomer, 1 to 5 wt% of a photoinitiator, 20 to 30 wt% of an alcohol solvent, 10 to 20% by weight of a ketone solvent, and 0.1 to 1.5% by weight of an additive.
본 발명에서 상기 광개시제는 메틸 벤조일 포르메이트를 사용할 수 있다.In the present invention, the photoinitiator may be methylbenzoylformate.
본 발명에 따른 투명 방음판 보호용 도료 조성물은 첨가제로서 폴리에테르 개질된 트리실록산 등을 사용할 수 있다.The coating composition for protecting a transparent soundproof panel according to the present invention may use polyether-modified trisiloxane or the like as an additive.
본 발명에서 투명 방음판 보호용 도료 조성물의 용매로는 알콜 용매, 에테르 용매 및 케톤 용매의 혼합 용매를 사용할 수 있다.In the present invention, as the solvent of the coating composition for protecting a transparent soundproof panel, a mixed solvent of an alcohol solvent, an ether solvent and a ketone solvent may be used.
본 발명의 투명 방음판 보호용 도료 조성물은 PMMA, PC 등에 적용될 수 있으며, 4~6 ㎛의 두께로 도포되는 것이 바람직하다.The transparent anticorrosion paint coating composition of the present invention can be applied to PMMA, PC, etc., and is preferably coated to a thickness of 4 to 6 탆.
투명 방음판 보호용 도료 조성물은 PMMA, PC 등에 도포된 후 60~70℃에서 2~3 분 동안 UV 조사하여 경화됨으로써 내후성, 내구성, 내마모성을 향상시킬 수 있다.
The transparent paint panel protective coating composition is applied to PMMA, PC, and then cured by UV irradiation at 60 to 70 ° C for 2 to 3 minutes, thereby improving weather resistance, durability and abrasion resistance.
본 발명은 PMMA, PC 등의 플라스틱 재질 등의 방음판에 플로우 코팅 방식으로 용이하게 적용할 수 있는 투명 방음판 보호용 도료 조성물을 제공함으로써 고속도로 등의 도로 등에 설치된 방음판의 내후성, 내구성, 내마모성을 향상시킬 수 있다.
The present invention can improve the weatherability, durability and abrasion resistance of a soundproofing plate installed on a road such as a highway by providing a coating composition for protecting a transparent soundproofing plate which can be easily applied to a soundproofing plate such as a plastic material such as PMMA and PC by a flow coating method .
이하, 본 발명을 상세히 설명한다.
Hereinafter, the present invention will be described in detail.
본 발명에 따른 투명 방음판 보호용 도료 조성물은 우레탄 아크릴레이트 올리고머 15~25 중량%, 아크릴릭 단량체 5~10 중량%, 광개시제 1~5 중량%, 알콜 용매 20~30 중량%, 에테르 용매 10~20 중량%, 케톤 용매 10~20 중량% 및 첨가제 0.1~1.5 중량%를 포함하여 구성된다.The coating composition for protecting a transparent soundproof panel according to the present invention comprises 15 to 25% by weight of a urethane acrylate oligomer, 5 to 10% by weight of an acrylic monomer, 1 to 5% by weight of a photoinitiator, 20 to 30% by weight of an alcohol solvent, 10 to 20% by weight of a ketone solvent, and 0.1 to 1.5% by weight of an additive.
본 발명에서 사용되는 우레탄 아크릴레이트 올리고머로는 다기능성 지방족 우레탄아크릴레이트를 사용할 수 있다.As the urethane acrylate oligomer used in the present invention, a multifunctional aliphatic urethane acrylate may be used.
본 발명에서 사용되는 우레탄 아크릴레이트는 하기 화학식 1 에 따라 이소시아네이트와 히드록시 아크릴레이트를 반응시켜 제조된 것을 사용할 수 있다.The urethane acrylate used in the present invention can be prepared by reacting isocyanate with hydroxyacrylate according to the following formula (1).
[화학식 1][Chemical Formula 1]
상기 우레탄 아크릴레이트 올리고머 15~25 중량%로 본 발명의 도료 조성물에 포함되는 것이 바람직하다.The urethane acrylate oligomer is preferably contained in the coating composition of the present invention in an amount of 15 to 25% by weight.
상기 우레탄 아크릴레이트 올리고머 15 중량% 미만으로 포함되는 경우 작업성, 외관, 내구성, 내마모성 등이 불량해지는 문제가 발생될 수 있으며, 상기 우레탄 아크릴레이트 올리고머가 25 중량%를 초과하여 포함되는 경우 작업성, 외관, 부착성이 불량해지는 문제가 발생될 수 있다.When the urethane acrylate oligomer is contained in an amount of less than 15% by weight, problems such as workability, appearance, durability and abrasion resistance may be poor. When the urethane acrylate oligomer is contained in an amount exceeding 25% by weight, A problem that appearance and adhesion may become poor may occur.
본 발명에서 아크릴릭 단량체는 본 발명이 속하는 기술분야에서 통상적으로 알려진 아크릴릭 단량체를 사용할 수 있다.The acrylic monomer used in the present invention may be an acrylic monomer commonly known in the art.
본 발명에서 아크릴릭 단량체는 UV 조사하여 경화시키는 경우 우레탄 아크릴레이트 올리고머와 가교되어 내구성, 내마모성을 향상시킬 수 있다.In the present invention, when the acrylic monomer is cured by UV irradiation, the acrylic monomer can be crosslinked with the urethane acrylate oligomer to improve durability and abrasion resistance.
상기 아크릴릭 단량체가 5 중량% 미만으로 포함되는 경우 외관, 부착성 등이 불량해지는 문제가 발생될 수 있으며, 상기 아크릴릭 단량체가 10 중량%를 초과하여 포함되는 경우 건조, 내마모성이 불량해지는 문제가 발생될 수 있다.If the amount of the acrylic monomer is less than 5% by weight, problems such as appearance and adhesion may be poor. If the acrylic monomer is contained in an amount exceeding 10% by weight, drying and abrasion resistance may be poor .
본 발명의 투명 방음판 보호용 도료 조성물에 포함되는 광개시제는 메틸 벤조일 포르메이트 등을 사용할 수 있으나, 반드시 이에 제한되는 것은 아니다.The photoinitiator included in the transparent anticorrosion paint coating composition of the present invention may be, but not limited to, methylbenzoylformate.
본 발명에서 광개시제로서 메틸 벤조일 포르메이트를 사용하는 경우 내후성(황변성)이 향상될 수 있다.In the present invention, when methyl benzoyl formate is used as a photoinitiator, the weather resistance (sulfur change) can be improved.
본 발명에서 케톤 용매로서 메틸 이소부틸 케톤을 사용하고, 알콜 용매로서 이소프로필 알콜을 사용하고, 에테르 용매로서 프로필렌글리콜 모노메틸에테르를 사용할 수 있으나 이에 반드시 제한되는 것은 아니다.In the present invention, methyl isobutyl ketone may be used as the ketone solvent, isopropyl alcohol may be used as the alcohol solvent, and propylene glycol monomethyl ether may be used as the ether solvent. However, the present invention is not limited thereto.
본 발명의 투명 방음판 보호용 도료 조성물에는 폴리에테르 개질된 트리실록산 등의 첨가제가 포함됨으로써, 흐름성, 레벨링 등이 향상될 수 있다.The coating composition for protecting a transparent soundproof panel of the present invention may contain additives such as polyether-modified trisiloxane to improve flowability, leveling, and the like.
상기 투명 방음판 보호용 도료 조성물은 PMMA 또는 PC에 4~6 ㎛의 두께로 도포한 후 60~70℃에서 2~3 분 동안 UV 조사하여 경화시킴으로써 적용될 수 있다.
The transparent anticorrosive coating composition may be applied to PMMA or PC to a thickness of 4 to 6 탆 and cured by UV irradiation at 60 to 70 캜 for 2 to 3 minutes.
이하, 본 발명의 이해를 돕기 위하여 바람직한 실시예를 설명한다. 하지만 하기 실시예는 본 발명을 예시하는 것일 뿐 본 발명의 범주 및 기술사상 범위 내에서 다양한 변경 및 수정이 가능함은 당업자에게 명백한 것이며, 이러한 변형 및 수정이 첨부된 특허 청구 범위에 속하는 것도 당연한 것이다.
Hereinafter, a preferred embodiment will be described in order to facilitate understanding of the present invention. It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit and scope of the invention as defined by the appended claims.
[실시예][Example]
(유레카 U.V #64002 유광)Product Name
(Eureka UV # 64002 polished)
표 1 에 나타난 조성 및 공정 조건으로 U.V 경화형 플로우 코팅(flow coating) 도막층을 형성하여 도막을 제조하였다. 도료 유레카 U.V #64002유광(유림특수화학(주))을 사용하였으며 이를 플로우 코팅하여 상단:4㎛/중앙:6㎛하단:8㎛ 도막층을 형성한 후 IR 60℃/3분 건조 후 상단:400mJ/cm2/중앙:800mJ/cm2/하단:800mJ/cm2로 U.V. 조사하였다 (온도/습도는 각각 25℃/55% 임).
A coating film was formed by forming a UV curable flow coating film layer according to the composition and processing conditions shown in Table 1. Coating with Eureka UV # 64002 (Yurim Specialty Chemical Co., Ltd.) was used and flow coating was performed to form a coating layer having a top: 4 탆 / center: 6 탆 bottom: 8 탆, followed by IR 60 캜 / UV was irradiated with 800mJ / cm 2 (temperature / humidity being 25 ℃ / 55%, respectively): 400mJ / cm 2 / center: 800mJ / cm 2 / the bottom.
성능 평가Performance evaluation
상기 실시예에 따라 제조된 본 발명의 도막의 성능을 다음과 같은 항목에 대해 평가하였고, 그 결과를 하기 표 2에 나타내었다.The performance of the coating of the present invention prepared according to the above examples was evaluated for the following items, and the results are shown in Table 2 below.
(1,500시간, 자외선형광 램프, 폭로방식:1)Accelerated weathering test (1)
(1,500 hours, ultraviolet fluorescent lamp, exposure method: 1)
황변도(ΔYI) 3 이하,
흐림도 변화(ΔH) 10% 이하
Yellowing degree (DELTA YI ) 3 or less,
Haze change (Δ H) 10% or less
KS M 3026
KS M ISO 14782KS M ISO 4892-3
KS M 3026
KS M ISO 14782
(무색 투광부재 기준)Visible light transmittance
(Based on a colorless light-transmitting member)
(마모륜: CS-10F,
하중: 4.9N, 100회전)Taber abrasion test (2)
(Wear wheel: CS-10F,
Load: 4.9 N, 100 revolutions)
흐림도 변화(ΔH) 15% 이하
Haze change (Δ H) than 15%
KS M ISO 9352KS M ISO 5470-1
KS M ISO 9352
충격 후 파편의 결락에 따른 노출 부분이 없을 것At a height of 48 cm, the steel ball (45 kg)
There should be no exposed parts due to missing pieces after impact.
시험Heat resistance
exam
PC : 방법 A
PMMA : 방법 BKS M ISO 75-2
PC: Method A
PMMA: Method B
(1) 현장에 반입되는 투명방음판 자재는 투광부재의 제조회사별, 재질별로 2,000㎡마다 촉진 내후성 시험을 실시하여 그 품질을 확인할 필요가 있음.(1) It is necessary to check the quality of the transparent soundproofing board material carried on site by carrying out the accelerated weathering test every 2,000㎡ for each manufacturer and material of the translucent member.
(2) 브러시를 강하게 누르는 기계청소 작업 등으로 고내마모성이 요구되는 경우 외에는 적용하지 않음(2) Not applicable except when high abrasion resistance is required due to machine cleaning work which strongly presses the brush.
-테이버 마모시험(하기 내용의 환경실험을 기기적/물리적 대체실험)- Taber abrasion test (Environmental / physical substitution experiment of the following contents)
모래/돌/바람 세척작업에 의한 마모현상 및 표면 긁힘을 방지Prevents abrasion and surface scratches by sand / stone / wind wash
-촉진내후성- accelerated weathering
(하기 내용의 환경실험을 기기적/물리적 대체실험)(Environmental / physical substitution experiment of the following environmental experiment)
산성비/자동차 매연 등에 의한 내화학적 변화 및 대기 중 먼지/유분에 의한 표면 오염, 자외선에 의한 변색 방지Chemical changes due to acid rain / automobile soot, surface contamination by dust / oil in the atmosphere, prevention of discoloration by ultraviolet rays
상기 표 2를 참조하면, 본 발명의 투명 방음판 보호용 도료 조성물을 사용하여 제조된 도막의 경우 테이버 마모시험, 촉진내후성, 충격시험 및 내열성 시험에 대한 결과로부터 내후성, 내구성, 내마모성이 우수함을 알 수 있다.Referring to Table 2, it can be seen from the results of Taber abrasion test, accelerated weathering resistance, impact test and heat resistance test that the coating film prepared using the coating composition for protecting a transparent soundproof panel of the present invention is excellent in weather resistance, durability and abrasion resistance have.
Claims (10)
상기 첨가제는 폴리에테르 개질된 트리실록산인 것을 특징으로 하는 투명 방음판 보호용 도료 조성물.
A photoinitiator, 1 to 5 wt% of an acrylic solvent, 20 to 30 wt% of an alcohol solvent, 10 to 20 wt% of an ether solvent, 10 to 20 wt% of a ketone solvent, and 15 to 25 wt% 0.1 to 1.5% by weight,
Wherein the additive is a polyether-modified trisiloxane.
상기 우레탄 아크릴레이트 올리고머는 다기능성 지방족 우레탄아크릴레이트인 것을 특징으로 하는 투명 방음판 보호용 도료 조성물.
The method according to claim 1,
Wherein the urethane acrylate oligomer is a multifunctional aliphatic urethane acrylate.
상기 광개시제는 메틸 벤조일 포르메이트인 것을 특징으로 하는 투명 방음판 보호용 도료 조성물.
The method according to claim 1,
Wherein the photoinitiator is methylbenzoylformate. ≪ RTI ID = 0.0 > 11. < / RTI >
상기 케톤 용매는 메틸 이소부틸 케톤인 것을 특징으로 하는 투명 방음판 보호용 도료 조성물.
The method according to claim 1,
Wherein the ketone solvent is methyl isobutyl ketone.
상기 알콜 용매는 이소프로필 알콜인 것을 특징으로 하는 투명 방음판 보호용 도료 조성물.
The method according to claim 1,
Wherein the alcohol solvent is isopropyl alcohol.
상기 에테르 용매는 프로필렌글리콜 모노메틸에테르인 것을 특징으로 하는 투명 방음판 보호용 도료 조성물.
The method according to claim 1,
Wherein the ether solvent is propylene glycol monomethyl ether.
상기 투명 방음판 보호용 도료 조성물은 PMMA 또는 PC에 적용되는 것을 특징으로 하는 투명 방음판 보호용 도료 조성물.
The method according to claim 1,
Wherein the transparent anticorrosion paint coating composition is applied to PMMA or PC.
상기 투명 방음판 보호용 도료 조성물은 PMMA 또는 PC에 4~6 ㎛의 두께로 도포되는 것을 특징으로 하는 투명 방음판 보호용 도료 조성물.
The method of claim 8,
Wherein the coating composition for protecting a transparent sound insulation panel is applied to PMMA or PC to a thickness of 4 to 6 占 퐉.
상기 투명 방음판 보호용 도료 조성물은 60~70℃에서 2~3 분 동안 UV 조사하여 경화되는 것을 특징으로 하는 투명 방음판 보호용 도료 조성물.The method according to claim 1,
Wherein the coating composition for protecting a transparent soundproof panel is cured by UV irradiation at 60 to 70 캜 for 2 to 3 minutes.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR100759101B1 (en) | 2007-05-10 | 2007-09-19 | 주식회사 에스폴리텍 | A coating composition and a transparent soundproof panel using the same |
| KR101025185B1 (en) | 2010-09-15 | 2011-03-31 | 주식회사 금화소재 | Uv-coated transparent resin soundproofing panel and fabrication method thereof |
| KR20110050952A (en) * | 2009-11-09 | 2011-05-17 | 주식회사 케이씨씨 | Resin and composition for ultraviolet curable coating and automobile head lamp lens comprising a coating layer thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR100759101B1 (en) | 2007-05-10 | 2007-09-19 | 주식회사 에스폴리텍 | A coating composition and a transparent soundproof panel using the same |
| KR20110050952A (en) * | 2009-11-09 | 2011-05-17 | 주식회사 케이씨씨 | Resin and composition for ultraviolet curable coating and automobile head lamp lens comprising a coating layer thereof |
| KR101025185B1 (en) | 2010-09-15 | 2011-03-31 | 주식회사 금화소재 | Uv-coated transparent resin soundproofing panel and fabrication method thereof |
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