KR101373299B1 - Nonflammable polyurethane foam and method of forming the same - Google Patents

Abstract

Flame retardant polyurethane foams and methods of making the same are disclosed. The polyurethane foam comprises a reactive phosphorus compound comprising at least two hydroxyl groups. At least one hydroxyl group of the reactive phosphorus compound is reacted with an isocyanate group to form a urethane bond. It is environmentally friendly because it does not contain halogen-based flame retardant materials, and contains phosphorus-reactive flame retardant materials that are integrally introduced into the interior.It has a very good flame retardant effect and does not extinguish even after a long time. The effect is not reduced.

Description

Flame retardant polyurethane foam and its manufacturing method {NONFLAMMABLE POLYURETHANE FOAM AND METHOD OF FORMING THE SAME}

The present invention relates to a flame retardant polyurethane foam and a method for producing the same, and more particularly, to a polyurethane foam having a uniform structure and excellent flame retardancy and a method for producing the same.

In general, polyurethane foams are widely used for electronic devices, sports, medical, automotive cushions and dustproof materials for computers, communications, etc. because they are easy to manufacture, excellent in shock absorption and resilience, and can be produced in various products. In particular, the polyurethane foam is usefully used as a sealing member suitable for placement between the edge of a liquid crystal display screen or the edge of a microphone or the like and the inner surface of a case in a display of a portable telecommunication equipment such as a portable telephone.

Polyurethane foams are generally prepared by reacting a mixture of polyether polyols, polyester polyols, foam stabilizers, fillers, curing catalysts, pigments and the like with aliphatic or aromatic isocyanate compounds in the presence of foams of water or gas components.

Flame retardation of the polyurethane foams thus produced has become very important in a situation where the use of the material is diversified. In addition, the spread of chemical products rapidly spreads, and in the event of a fire, enormous toxic gases and smoke are generated. In order to improve this problem, research is required to flame-retard the polyurethane foam to reduce the generation of toxic gas, low smoke and heat resistance. In particular, as environmental regulations become more stringent, the development of non-halogen flame retardants is being called for.

It is an object of the present invention to provide an integral polyurethane foam capable of maintaining excellent flame retardancy for a long time by introducing reactive flame retardant materials in the production of polyurethane foams.

Another object of the present invention is to provide a method for producing the above flame retardant polyurethane foam in a short time.

In order to achieve the above object, the present invention provides a polyurethane foam containing a reactive phosphorus compound including at least two hydroxyl groups.

In one embodiment, at least one hydroxyl group of the reactive phosphorus compound reacts with an isocyanate group to form a urethane bond.

In one embodiment, the reactive phosphorous compound is derived from at least one of Compound A and Compound B.

<Compound A>

In the compound A, R represents an alkyl group having 1 to 5 carbon atoms, and n has an average value of 4 to 5 range as an integer value. Preferably R represents CH ₂ CH ₃ when at the end, CH ₂ CH ₂ when in the middle and n is 4 or 5.

<Compound B>

In one embodiment, the polyurethane foam further comprises at least one inorganic flame retardant selected from the group consisting of ammonium phosphate, aluminum phosphate and melamine phosphate.

In one embodiment, the reactive phosphorus compound is included in the range of 5 to 20% by weight based on the total amount of polyol and polyisocyanate.

Another object of the present invention described above is achieved by a method for producing a polyurethane foam comprising reacting a polyol, a polyisocyanate, a reactive phosphorus compound comprising at least two hydroxyl groups and a blowing agent.

In one embodiment, the reactive phosphorus compound is at least one compound of Compound A and Compound B.

<Compound A>

In the compound A, R represents an alkyl group having 1 to 5 carbon atoms, and n has an average value of 4 to 5 range as an integer value. Preferably R represents CH ₂ CH ₃ when at the end, CH ₂ CH ₂ when in the middle and n is 4 or 5.

<Compound B>

In one embodiment, the reactive phosphorus compound is used in the range of 5 to 20% by weight based on the total amount of the polyol and polyisocyanate.

In one embodiment, at least one inorganic flame retardant selected from the group consisting of ammonium phosphate, aluminum phosphate and melamine phosphate in the preparation of the polyurethane foam is further added in the range of 0.1 to 50% by weight relative to the total amount of the polyol and polyisocyanate. can do.

In one embodiment, a metal catalyst may be further added to the reacting step. The metal catalyst is selected from the group consisting of dioctyltin dilaurate, 1,8-diaza bicyclo (5,4,0) deck-7-ene (DBU) and salts of 2-ethyl hexanoic acid of DBU. It may be at least one.

In one embodiment, after performing the step of the reaction may be further performed a step of heating to a temperature range of 120 ~ 150 ℃.

In one embodiment, the surface of the polyurethane foam may be further carried out surface treatment with at least one resin of the ultraviolet curable resin and thermosetting resin.

Polyurethane foam according to an embodiment of the present invention configured as described above is environmentally friendly because it does not contain a halogen-based flame retardant material, and includes a phosphorus-based reactive flame retardant material introduced integrally therein and has a very excellent flame retardant effect and a long time Even after this, the flame retardant is not extinguished, so the flame retardant effect is not reduced over time.

1 is a chemical reaction diagram illustrating a method for preparing a reactive phosphorous flame retardant compound applied to prepare a polyurethane foam according to one embodiment of the present invention.
FIG. 2 shows an IR spectrum of a reactive phosphorous flame retardant compound prepared according to the preparation method shown in FIG. 1.

Hereinafter, a polyurethane foam according to an embodiment of the present invention and a manufacturing method thereof will be described in detail.

The present invention is capable of various modifications and various forms, and specific embodiments are illustrated in the drawings and described in detail in the text. It should be understood, however, that the invention is not intended to be limited to the particular forms disclosed, but includes all modifications, equivalents, and alternatives falling within the spirit and scope of the invention. The terms first, second, etc. may be used to describe various components, but the components should not be limited by the terms. The terms are used only for the purpose of distinguishing one component from another. For example, without departing from the scope of the present invention, the first component may be referred to as a second component, and similarly, the second component may also be referred to as a first component.

The terminology used in this application is used only to describe a specific embodiment and is not intended to limit the invention. Singular expressions include plural expressions unless the context clearly indicates otherwise. In this application, the terms "comprises", "having", and the like are used to specify that a feature, a number, a step, an operation, an element, a part or a combination thereof is described in the specification, But do not preclude the presence or addition of one or more other features, integers, steps, operations, components, parts, or combinations thereof.

On the other hand, unless otherwise defined, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art. Terms such as those defined in commonly used dictionaries are to be interpreted as having a meaning consistent with the contextual meaning of the related art and are to be interpreted as either ideal or overly formal in the sense of the present application Do not.

Hereinafter, the polyurethane foam and the manufacturing method thereof according to the present invention will be described in detail.

Polyurethane foam is widely used as a packing material to be sandwiched between the two sides of the hard plastic and the liquid crystal, or hard plastic when manufacturing electronic devices such as mobile phones and televisions. Polyurethane foam has elasticity while preventing the inflow of dust, light, etc., and thus has an effect of absorbing shock, thereby reducing the impact of electronic devices.

Low density polyurethane foams are a mixture of polyether polyols, polyester polyols, foam stabilizers to stabilize foams, fillers to maintain proper elasticity, curing catalysts to induce polymerization reactions, pigments to express colors, etc. And aliphatic or aromatic polyisocyanates are prepared by reacting in the presence of a blowing catalyst comprising water, a gas such as nitrogen, and the like. As a manufacturing method, first, the raw materials are mixed to form a uniform low density polyurethane foam and coated on a substrate such as a polyester film in a constant thickness. It is then cured to produce a low density polyurethane foam, for example in sheet form.

Polyurethane resins generally have a density of about 1, but when they are manufactured in a foam state by injecting air or gas, the density can not be greater than 1, which is expressed as low density.

Examples of the polyol component used in the production of the polyurethane foam according to the embodiment of the present invention include polyester-based polyols and polyether-based polyols. Specifically, polyester-based polyols are obtained by reacting dicarboxylic acids with diols. As dicarboxylic acid, succinic acid, glutaric acid, adipic acid, pimeline acid, subberic acid, azelaic acid, sebacic acid, phthalic acid, terephthalic acid, isophthalic acid, maleic acid, fumaric acid, itaconic acid, tetrabromophthalic acid, tri Meritic acid, ester derivatives thereof, acid anhydrides thereof, and the like. These may be used alone or in combination of two or more. Examples of the diol constituting the polyester-based polyol include ethylene glycol, propylene glycol, butanediol, pentanediol, 1,6-hexanediol, 1,8-octanediol, neopentyl glycol, trimethylolpropane, glycerin, pentaerythritol, Quinitol, diethylene glycol, triethylene glycol, tetraethylene glycol, polyethylene glycol, polypropylene glycol, diglycerin, textrose, sorbitol and the like. These may be used alone or in combination of two or more.

Examples of the polyether polyols include block or random alkylene oxide adducts such as alcohols and amines. In other words, diols of polyoxyethylene and polyoxypropylene, triols and polyols, polyoxytetramethylene glycols, mixtures thereof, and the like can be given.

Examples of the compound having two or more active hydrogens among the compounds used for preparing the polyether polyol include ethylene glycol, diethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, butylene glycol, and neopentyl glycol. , 1,4-butanediol, 1,6-hexanediol, cyclohexanedimethanol, glycerin, trimethylolpropane, pentaerythritol, 1,2,6-hexanetriol, 1,2,4-butanetriol, tri Examples thereof include ethylol ethyne, diglycerin, dextrose, sucrose, bisphenol A, ethylenediamine, and modified substances thereof. These can be used individually or in mixture, respectively. In addition, the alkylene oxide may include ethylene oxide, propylene oxide, 1,2-butylene oxide, 2,3-butylene oxide, styrene oxide and the like.

The polyol component usable in the present invention preferably has an average molecular weight in the range of 200 to 8,000, preferably in the range of 1,000 to 5,000, in view of maintaining a moderate viscosity and improving workability and maintaining the strength of the polyurethane foam.

In addition, the polyol component includes 40 to 80% by weight of a polyester-based polyol having 2 functional groups, an average molecular weight of 1,000 to 5,000, and 20 to 60% by weight of a polyester polyol having a functional group of 3 and an average molecular weight of 1,000 to 5,000. It is preferable to mix and use a polyol component, in terms of viscosity control during operation and the desired foam molding to have good physical properties.

As isocyanate compounds used in the production of the polyurethane foam of the present invention, aromatic, alicyclic, aliphatic polyisocyanates having two or more isocyanate groups (NCO), mixtures thereof, modified polyisocyanates obtained by modifying them, etc. Can be used. Specific examples include ethylene diisocyanate, toluene diisocyanate, tolylene diisocyanate, methylene diphenyl diisocyanate, tetramethyl xylene diisocyanate, naphthalene diisocyanate, xylene diisocyanate, polymethylene polyphenyl isocyanate, hydrogenated methylene diphenyl diisocyanate, hydrogenated tolyl Examples thereof include rendiisocyanate, isophorone diisocyanate, hexamethylene diisocyanate, trimethylhexamethylene diisocyanate, lysine diisocyanate and mixtures thereof and modified substances thereof.

Examples of the modified product include prepolymer-type modified products, reaction product modified from a polyisocyanate and a polyol, nurate modified products, urea modified products, carbodiimide modified products, arophanate modified products, and biuret modified products.

The isocyanate component has a molecular weight in the range of 300 to 500, 30 to 70% by weight of a polymeric methylene diphenyl diisocyanate having an isocyanate content of 25 to 50% and a modified methylene diphenyl diisocyanate having an isocyanate content of 25 to 50% by 70 to It is preferable to mix and use the isocyanate containing 30 weight%.

In the present invention, when the low density polyurethane foam is produced, the following compound A and / or compound B are added as a phosphorus flame retardant to introduce a material having flame retardancy into the foam.

<Compound A>

In the compound A, R represents an alkyl group having 1 to 5 carbon atoms, and n has an average value of 4 to 5 range as an integer value. Preferably R represents CH ₂ CH ₃ when at the end, CH ₂ CH ₂ when in the middle and n is 4 or 5.

<Compound B>

The compound A is understood to provide a flame retardant effect of the P═O functional group of the phosphate contained in the molecule as a phosphorpolyol. Compound B also provides the flame retardant effect of the P═O functional groups of phosphates contained in the molecule. Both Compound A and Compound B contain hydroxyl groups at the terminal portions of the molecule, and these hydroxyl groups (-OH) react with the isocyanate groups (-NCO) of the polyisocyanate to form urethane bonds. That is, flame retardant phosphorus compounds are included via chemical bonds in the polyurethane foam from which they are made. Accordingly, the compound A and the compound B are referred to as reactive compounds.

Such phosphorus-based flame retardant compounds may exhibit flame retardancy if included in trace amounts. Preferably it is added in the range of about 5 to 20% by weight based on the total amount of polyol and polyisocyanate. If the flame retardant compound is added in an amount less than 5% by weight, the flame retardant effect is insignificant, and if it is added in excess of 20% by weight, it is not preferable because the curing time becomes long.

In particular, the compounds A and B has the advantage that the viscosity of the raw material is low and the reactivity is good, it is easy to induce a long pot-life while the reaction time is fast. And compound B is CAS NO. 2,2-dimethyl propane-1,3-di (phosphoryl-2-di (epoxy-1-pentanol)) as 227089-98-7 (2,2-dimethyl propane-1,3-diphosphoryl-2- di (2- epoxy-1-pentanol)), and contains an epoxy group in the molecule. The epoxy group does not have any particular advantage when the polyurethane foam itself is used, but when the polyurethane foam sheet is manufactured, the epoxy group functions as a secondary reaction functional group to provide an effect of increasing the adhesive strength when combined with the adherend. Can be.

Compound B may be synthesized by various methods, but the present inventors prepared and used the chemical reaction scheme shown in FIG. 1. The obtained compound B was found to have a yellowish brown liquid, poorly soluble in water and not complexed at room temperature. A flash point was 217 degreeC and specific gravity was 1.29 (20 degreeC). In compound B, P content was about 12.2%.

FIG. 2 shows an IR spectrum of a reactive phosphorous flame retardant compound prepared according to the preparation method shown in FIG. 1. 23 ~ 35 ~ 1500 cm ^-1 peak in the range from 600 IR spectrum shows a band of the CC alkane, 1000 ~ 26 ~ 28 times the peak of 1300cm ^-1 range represents an epoxy group, 18 2850 ~ 2960cm ^-1 range of time The peak represents the CH band of the alkanes, and the peaks 14-15 in the range of 3590-3650 cm ^-1 represent the OH bond of the alcohol.

In the case of the above-mentioned compounds A and B, both of them react within about 1 minute during the production of the polyurethane foam, and the pot life is about 9 minutes or more, and the production conditions are very satisfactory. On the other hand, phosphorus-based flame retardants that do not contain hydroxyl groups or phosphorus-based flame retardants with too high molecular weight have difficulty in producing on-site due to the slow curing reaction.

As a blowing agent used for manufacture of the polyurethane foam of this invention, water, the gas containing nitrogen, etc. are mentioned.

On the other hand, catalysts used in the preparation of the polyurethane foam of the present invention include dioctyltin dilaurate, 1,8-diaza bicyclo (5,4,0) deck-7-ene (DBU) and DBU. At least one metal salt catalyst selected from the group consisting of salts of ethyl hexanoic acid is preferably used. In particular, when the content of the phosphorus compound is high, the polyurethane reaction may be delayed, but curing delay phenomenon may be prevented by using the metal salt catalyst.

Surfactants may be used as the foam stabilizer used in the production of the polyurethane foam of the present invention. This serves to maintain the molded state of the urethane foam well. Surfactants include silicone-based surfactants having polydimethylsiloxane and polyoxyalkylene chains, anionic surfactants such as fatty acid salts, sulfuric acid ester salts, phosphoric acid ester salts, sulfonate salts and the like. The surfactant is used 0.1 to 10 parts by weight based on 100 parts by weight of the polyol component.

Fillers used in the production of the polyurethane foams of the present invention include particulate fillers, layered fillers, fibrous fillers and the like. Specifically, particulate fillers such as calcium carbonate, barium sulfate, silica, clay, talc, aluminum hydroxide, melamine; Layered fillers such as mica, willlastonite and aluminum flakes; And fibrous fillers such as various glass fibers, carbon fibers, alumina fibers and potassium titanate. The filler increases the hardness of the foam, improves thermal stability, improves elastic modulus, and is effective for energy absorption.

According to one embodiment of the present invention, at least one inorganic flame retardant selected from the group consisting of ammonium phosphate, aluminum phosphate and melamine phosphate may be further added in a range of 0.1 to 50 wt% based on the total amount of the polyol and polyisocyanate. These inorganic flame retardants are used as a powder and may serve as a filler while providing a flame retardant effect. Accordingly, the addition of the inorganic flame retardant can obtain a further improved flame retardant effect apart from the flame retardant effect obtained by the addition of the reactive phosphorus compound. In addition, the inorganic flame retardant also acts as a filler, so adding it eliminates or eliminates the use of such fillers, such as calcium carbonate. The amount of the inorganic flame retardant can be adjusted according to the density, hardness, tensile strength, elongation, etc. of the polyurethane foam. Its preferred addition amount is in the range of 0.1 to 50% by weight, based on the total amount of polyol and polyisocyanate. If the inorganic flame retardant is added in less than 0.1% by weight, the flame retardant effect and the role as a filler is insignificant. If the inorganic flame retardant exceeds 50% by weight, the amount of the main polyurethane component is reduced so that it can not function properly as a foam, the amount of addition thereof is in the above range. To be

In order to impart color in the production of the polyurethane foam of the present invention, colored pigments or dyes such as titanium dioxide, iron oxide, and carbol black may be used.

In addition to these, additives such as antioxidants, ozone inhibitors, UV stabilizers, conductive polymers, and the like may also be used.

Hereinafter, a method of manufacturing a polyurethane foam according to an embodiment of the present invention will be described.

First, a polyol component, a reactive phosphorus compound, a catalyst, a blowing agent, a filler, an additive, and the like are mixed and stirred to prepare a polyol mixed solution. The isocyanate compound is mixed, stirred and foamed therein. More specifically, the polyol solution is mixed and stirred using a tank or the like and the temperature is adjusted to about 20 to 45 ° C. Thereafter, using a foaming machine such as an automatic mixing injection foaming machine or an automatic mixing injection foaming machine, an isocyanate compound, air, and an inert gas are forcibly injected to foam by a froth method.

Next, the obtained molded body is heat treated at a temperature of 60 ~ 200 ℃ to improve the tensile strength and tear strength of the molded body and to further improve the compression characteristics. And the middle addition effectively promotes the reaction and promotes the high molecular weight of the polyurethane foam. The heat treatment temperature is 60 to 200 占 폚, preferably 80 to 180 占 폚, more preferably 120 to 150 占 폚 from the viewpoint of preventing the molded body from thermal deformation.

According to one embodiment of the present invention, the surface of the foam sheet is coated with a urethane resin, an acrylic resin, an ultraviolet curable resin, etc. in order to control the surface properties such as softening the surface after the polyurethane foam is prepared and completely cured. can do.

In particular, in order to soften a polyurethane foam composed of a combination of polyol and isocyanate, a polyol having a relatively high molecular weight is used, or a mole ratio of polyol is designed slightly higher than isocyanate to slow the elastic recovery rate by controlling the molar ratio of polyol and isocyanate. There is a case. At this time, the characteristics of the foam is excellent, but the surface may be sticky. In order to improve this, the top of the polyurethane foam layer can be surface treated.

Coating the resin may be UV curing method, thermosetting method and the like depending on the curing method. The UV curing method includes a urethane-based acrylic resin such as phenylglycidyl ether acrylate, and the thermosetting method uses an aqueous or oily general urethane or acrylic resin.

Hereinafter, the present invention will be described in detail through specific examples.

&Lt; Example 1 >

The polyol was added to a 1000 L capacity mixing tank made of stainless steel equipped with a stirring device (dissol bar) capable of high speed stirring up to 2000 rpm, and stirred uniformly at room temperature. A reactive phosphorus compound and an inorganic flame retardant were added thereto to disperse well, and then a foam stabilizer, a pigment, a catalyst, a filler, and the like were added, followed by stirring at high speed for about 1 hour or more. A homogeneous liquid mixture A was prepared. At this time, the influx of water inhibited the urethane reaction, so that it was suppressed as much as possible.

Next, the polyisocyanate liquid was prepared separately and it was set as reaction liquid B. Mixing liquid A and reaction liquid B were supplied to a high speed mixing head, which is a device capable of uniformly mixing three components at high speed, at a constant rate using a metering pump, while simultaneously supplying nitrogen gas. Nitrogen gas was supplied while adjusting density and hardness. The three components were mixed uniformly and coated to a uniform thickness on the polyester film. After curing at a high temperature in the range of about 120 ~ 150 ℃ in the reaction curing machine to prepare a flame-retardant polyurethane foam sheet. Flame retardancy measurements were performed.

&Lt; Examples 2 to 3 >

Performed in the same manner as in Example 1, but changed the composition and content of the mixture A as shown in Table 1 to prepare a polyurethane foam sheet, it was measured for flame retardancy.

&Lt; Comparative Examples 1 to 4 >

Performed in the same manner as in Example 1, but changed the composition and content of the mixture A as shown in Table 1 to prepare a polyurethane foam sheet, it was measured for flame retardancy.

Raw materials used in the above Examples and Comparative Examples are summarized in Table 1 below.

<Table 1>

In Table 1, RCR-2080 represents Compound B, OP-550 is Compound A, and R at the end is CH ₂ CH ₃ , and R in the middle is CH ₂ CH ₂ And n represents a compound having an average value of 4.5. Table 2 below shows the types and amounts of raw materials used in each of Examples and Comparative Examples.

<Table 2>

Table 3 shows the data on the flame retardant effect of the polyurethane foam according to each Example and Comparative Example.

The polyester film used for coating a polyurethane foam is made into a general polyester film of 50-100 micrometers in the case of peeling type, and a flame-retardant flame-retardant polyester film may be used when manufacturing a film integral polyurethane foam sheet. In this embodiment, a peeling type general film was used to implement the characteristics of the polyurethane foam sheet and confirm the effect thereof, and then, after peeling off the film, the flame retardant properties of the polyurethane foam sheet were measured.

The thickness of the specimen used for measuring the flame retardant was 1.0mm, the density was 0.40 g / cm ³ , the hardness was 60, and the flame retardancy was measured according to the UL 94 foam material horizontal combustion test method.

First, thickness and weight were measured to obtain density. The thickness was measured using a Mitutoyo (Japan) measuring instrument with a minimum measurement unit of 0.01 mm, and the weight was measured using a shimadzu (Japan) microscopic precision balance with a minimum measurement unit of 0.01 g.

A sample of 100 mm (width) x 100 mm (length) size was prepared, and the thickness (cm) was measured and averaged at nine points from the left, middle, right and right centers of each of four sides of the sample using a thickness meter. . The weight in grams was then measured using a micro precision balance. The weight of the sample was divided by the volume of the sample to obtain a density value. At this time, the density for the pure polyurethane foam except for the polyester film was obtained.

Hardness was measured and averaged at nine points in total from the left, middle, right and right centers of four sides of a sample of 100 mm (width) x 100 mm (length) size using a Teclock (Japan) measuring instrument.

In order to evaluate the flame retardancy of the polymer materials used in the electrical equipment and electronic products, the flame retardancy was verified through the Horizontal Burning Foamed Material Test (HBF test) of the foamed products among the test methods and procedures described in UL94. HBF test method is to measure the combustion characteristics in the horizontal direction, and prepare the specimen (150 ± 5mm (length) x 50 ± 1mm (width)) according to the standard, pretreatment, and perform flame retardancy test. The same test was performed for. In Table 3, yes means that the combustion propagation velocity of all five specimens did not exceed 40 mm / min in the 25 mm to 125 mm section of the specimen, or that the combustion site would stop at 125 mm, and no would not satisfy this. .

<Table 3>

Through the results shown in Table 3 it can be seen that the polyurethane foam according to Examples 1 to 3 containing a reactive phosphorus compound exhibits excellent flame retardancy.

As a result of verifying the flame retardancy of the polymer resin as described above, it can be confirmed that the polyurethane foam including the phosphorus-based flame retardant compound according to the embodiment of the present invention exhibits excellent flame retardancy. Phosphorus-based flame retardant compounds provided by the present invention exhibit excellent performance because they are non-halogen-based flame retardant functionalizing agents and contain two or more reactive hydroxy functional groups and are integrated with a polymer.

Polyurethane foam according to an embodiment of the present invention can be used for electronic devices, such as computers, communications, sports, medical, automobile cushions, etc. and in particular can be usefully used as a shock absorbing sealing member of the electric appliances.

It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the present invention as defined by the following claims. It can be understood that it is possible.

Claims (13)

A polyurethane foam comprising a reactive phosphorus compound comprising at least two hydroxyl groups,
The reactive phosphorus compound is a polyurethane foam, wherein at least one hydroxyl group reacts with an isocyanate group to form a urethane bond.
<Compound B>

delete delete The polyurethane foam of claim 1 further comprising at least one inorganic flame retardant selected from the group consisting of ammonium phosphate, aluminum phosphate and melamine phosphate. The polyurethane foam according to claim 1, wherein the reactive phosphorus compound is included in an amount of 5 to 20% by weight based on the total amount of polyol and polyisocyanate. Reacting the polyol, polyisocyanate, reactive phosphorous compound B comprising at least two hydroxy groups and a blowing agent; And
To prepare a polyurethane foam by performing a step of heating to a temperature range of 120 ~ 150 ℃,
The reactive phosphorus compound B is a method for producing a polyurethane foam, characterized in that used in the range of 5 to 20% by weight based on the total amount of the polyol and polyisocyanate.
<Compound B>

delete delete The polyurethane according to claim 6, wherein at least one inorganic flame retardant selected from the group consisting of ammonium phosphate, aluminum phosphate and melamine phosphate is further added in the range of 0.1 to 50% by weight based on the total amount of the polyol and polyisocyanate. Method for producing a foam. The method of claim 6, wherein a metal catalyst is further added to the reacting step. The metal catalyst of claim 10, wherein the metal catalyst is a dimethyl dilaurate, 1,8-diaza bicyclo (5,4,0) deck-7-ene (DBU) and DBU of 2-ethyl hexanoic acid. Method for producing a polyurethane foam, characterized in that at least one selected from the group consisting of salts. delete The method of claim 6, further comprising surface treatment of the surface of the polyurethane foam with at least one of an ultraviolet curable resin and a thermosetting resin.

Images