KR101365929B1 - A paint composition of two liquid type having high flame-resistance property containing aluminium hydroxide - Google Patents
A paint composition of two liquid type having high flame-resistance property containing aluminium hydroxide Download PDFInfo
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- KR101365929B1 KR101365929B1 KR1020120112239A KR20120112239A KR101365929B1 KR 101365929 B1 KR101365929 B1 KR 101365929B1 KR 1020120112239 A KR1020120112239 A KR 1020120112239A KR 20120112239 A KR20120112239 A KR 20120112239A KR 101365929 B1 KR101365929 B1 KR 101365929B1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
Abstract
Description
본 발명은 철도 차량 및 각종 차량 내부에 적합한 난연도료에 관한 것으로, 더욱 상세하게는 난연성이 우수하고 메탈릭을 포함한 다양한 색상을 구현할 수 있는 2액형 자연건조형 난연도료 조성물에 관한 것이다.
The present invention relates to a flame retardant paint suitable for the interior of a railway vehicle and various vehicles, and more particularly, to a two-component natural dry flame retardant paint composition that can realize various colors including flame retardancy and metallic.
2003년 대구지하철 방화사건 이후 지하철을 비롯한 각종 차량의 내부에 적용되는 도료에 난연성이 요구되고 있다.After the Daegu subway fire accident in 2003, flame retardancy has been required for paints applied to the interior of various vehicles including subways.
기존의 난연도료는 브롬계 난연제 또는 인계 난연제를 사용하는 것이 대부분이였으나, 브롬계 난연제는 유독가스가 발생하고 인계 난연제는 인산 자체의 산성적인 특징 때문에 다양한 적용에 어려운 점이 있다.
Conventional flame retardant paints were mostly bromine-based flame retardant or phosphorus-based flame retardant, bromine-based flame retardant is toxic gas generated and phosphorus-based flame retardant has a difficult point in a variety of applications because of the acidic properties of phosphoric acid itself.
상기와 같은 본 발명은 종래기술의 문제점을 해결하기 위해 창안된 것으로서, 종래의 난연도료의 문제점인 유독가스 발생, 다양한 적용의 어려움, 한정된 솔리드 칼라 구현 등을 개선하여 난연성이 우수하고 다양한 칼라를 구현할 수 있는 난연도료 조성물을 제공하는 것을 해결하고자 하는 기술적 과제로 한다.
The present invention as described above has been invented to solve the problems of the prior art, by improving the generation of toxic gas, the difficulty of various applications, the implementation of a limited solid color, such as problems of the conventional flame retardant paint to implement a variety of colors excellent flame retardancy The technical problem to be solved to provide a flame retardant coating composition that can be.
상기와 같은 본 발명은 주제와 경화제를 혼합하여 사용하는 2액형 난연도료 조성물로서,The present invention as described above is a two-component flame retardant paint composition using a mixture of the main agent and a curing agent,
상기 주제는 아크릴 폴리올 30~55중량%(주제 내에서의 함량임, 이하 같음), 셀룰로즈 아세테이트 부틸레이트(CAB) 변성 아크릴 폴리올 1~10중량%, 수산화알루미늄 5~25중량%, 실리카 5~25중량%, 안료 3~20중량%, 분산제 0.1~2중량%, 레벨링제 0.1~1중량%, 경화 촉진제 0.001~0.1중량%, 침강방지제 0.1~2중량%, 용제 5~15중량%를 함유하고,The subject matter is 30 to 55% by weight of acrylic polyol (content in the topic, the same as below), 1 to 10% by weight of cellulose acetate butyrate (CAB) modified acrylic polyol, 5 to 25% by weight of aluminum hydroxide, 5 to 25 of silica Wt%, pigment 3-20 wt%, dispersant 0.1-2 wt%, leveling agent 0.1-1 wt%, curing accelerator 0.001-0.1 wt%, sedimentation inhibitor 0.1-2 wt%, solvent 5-15 wt% ,
상기 경화제는 폴리이소시아네이트 70~90중량%(경화제 내에서의 함량임, 이하 같음), 용제 10~30중량%를 함유하는 것을 특징으로 한다.
The curing agent is characterized in that it contains 70 to 90% by weight of polyisocyanate (content in the curing agent, the same as below), 10 to 30% by weight of the solvent.
이때 상기 주제의 용제는 초산부틸, 크실렌, 톨루엔 및 프로필렌 글리콜 모노메틸 에테르 아세트산 중의 적어도 어느 하나인 것을 특징으로 한다.
The solvent of the subject is characterized in that at least one of butyl acetate, xylene, toluene and propylene glycol monomethyl ether acetic acid.
또한 상기 경화제의 용제는 초산부틸 및 초산에틸 중 적어도 어느 하나인 것을 특징으로 한다.
In addition, the solvent of the curing agent is characterized in that at least one of butyl acetate and ethyl acetate.
또한 상기 침강방지제는 폴리아마이드계 왁스인 것을 특징으로 한다.
In addition, the anti-settling agent is characterized in that the polyamide wax.
또한 본 발명에 따른 난연도료 조성물은 여러 분야에 적용될 수 있으나, 특히 철도 차량 및 각종 차량 내부용에 적합하다.
In addition, the flame retardant coating composition according to the present invention may be applied to various fields, but is particularly suitable for railway vehicles and various vehicle interiors.
본 발명에서 활용한 수산화알루미늄은 무독성, 저발연성 특성을 가지며 다른 난연재에 비하여 상대적으로 저렴한 가격이 장점이다. 또한 흡열에 의한 탈수 반응으로 연소를 지연시키는 효과가 있다.Aluminum hydroxide utilized in the present invention has a non-toxic, low smoke characteristics and has a relatively low price compared to other flame retardants. In addition, there is an effect of delaying combustion by the dehydration reaction by endotherm.
2Al(OH)3 -> Al2O3 + 3H2O - 298cal/mol
2Al (OH) 3- > Al 2 O 3 + 3H 2 O-298 cal / mol
다음으로, 각 성분을 상기와 같이 제한한 이유를 구체적으로 설명한다.Next, the reason why each component was restrict | limited as mentioned above is demonstrated concretely.
상기 아크릴 폴리올은 주제 성분의 주성분 수지로서 메틸메탈아크릴레이트와 노르말부틸메타아크릴레이트를 주성분으로 하는 아크릴 폴리올을 사용할 수 있으며, 30중량% 미만으로 첨가하면 내충격성, 굴곡성 및 도막 외관 등이 저하되고 55중량% 초과하여 첨가하면 유동성이 심해서 흐름저항성이 저하되기 때문에 상기 범위로 함유되는 것이 바람직하다. The acrylic polyol may be an acrylic polyol containing methyl metal acrylate and normal butyl meth acrylate as a main component resin as a main component resin. When the acrylic polyol is added in an amount less than 30% by weight, impact resistance, flexibility, and coating appearance are reduced. If it is added in an amount exceeding% by weight, the fluidity is severe and the flow resistance is lowered.
상기 셀룰로즈 아세테이트 부틸레이트(CAB) 변성 아크릴 폴리올은 주제 성분의 보조 수지로서 메틸메탈아크릴레이트를 주성분으로 하고 셀룰로즈 아세테이트 부틸레이트를 부가한 아크릴 폴리올을 사용할 수 있으며, 1중량% 미만으로 첨가되면 건조속도가 저하되고 10중량% 초과하여 첨가하면 도막외관이 저하되기 때문에 상기 범위로 함유되는 것이 바람직하다.The cellulose acetate butyrate (CAB) modified acrylic polyol may be an acryl polyol containing methyl metal acrylate as a main component and cellulose acetate butyrate added as an auxiliary resin of a main component. It is preferable to be contained in the said range because it will reduce a coating film external appearance, when it adds in more than 10 weight%.
상기 수산화알루미늄은 난연성의 주된 원료로서 5중량% 미만이면 난연성이 저하되고 25중량%를 초과하면 난연도료의 물성이 저하되기 때문에 상기 범위로 첨가하는 것이 바람직하다.When the aluminum hydroxide is a flame retardant main raw material, the flame retardancy is lowered if it is less than 5% by weight and the physical properties of the flame retardant paint are lowered when it exceeds 25% by weight.
상기 실리카는 결정질 실리카로서 기계적 물성 향상의 주된 원료이다. 5중량% 미만으로 첨가하면 상기 효과를 얻기 어렵고 25중량%를 초과하여 첨가할 경우 도막 외관 등이 저하되기 때문에, 상기 범위로 첨가하는 것이 바람직하다.The silica is crystalline silica and is a major raw material for improving mechanical properties. If it is added less than 5% by weight, it is difficult to obtain the above effects, and when it is added in excess of 25% by weight, the appearance of the coating film and the like decreases.
상기 안료는 색상을 구현하는 주된 원료로서, 적용되는 안료 종류에 따라 3~20중량%로 첨가하는 것이 바람직하다. 적용할 수 있는 안료는 솔리드, 메탈릭 및 펄 등으로 다양하다.The pigment is the main raw material for implementing the color, it is preferably added in 3 to 20% by weight depending on the type of pigment applied. Pigments that can be applied vary in solids, metallics and pearls.
상기 분산제는 조성물의 중의 고형분들을 고르게 분산시키는 기능을 하는 것으로서 구체적으로 불포화 폴리카르복실릭산의 폴리아민 아마이드 용액 등이 사용되며, 0.1중량% 미만으로 첨가되면 분산 효과가 저하되고 2중량% 초과하여 첨가되면 난연도료의 물성이 저하되기 때문에 상기 범위로 첨가하는 것이 바람직하다.The dispersant is a function of uniformly dispersing solids in the composition, and specifically, polyamine amide solution of unsaturated polycarboxylic acid is used, and when added in less than 0.1% by weight, the dispersing effect is lowered and when added in excess of 2% by weight. Since the physical property of a flame retardant paint falls, it is preferable to add in the said range.
상기 침강방지제는 수산화알루미늄, 실리카 및 안료의 침강을 방지하는 기능을 하는 것으로서 구체적으로 폴리아마이드계 왁스가 사용되며, 0.1중량% 미만으로 첨가되면 침강방지 효과가 저하되고 2중량% 초과하여 첨가되면 난연도료의 물성이 저하되기 때문에 상기 범위로 첨가하는 것이 바람직하다.The anti-settling agent has a function of preventing the sedimentation of aluminum hydroxide, silica, and pigments, and specifically, polyamide wax is used. When the amount is less than 0.1 wt%, the anti-settling effect is lowered and the flame retardant is added when it is added in excess of 2 wt%. Since the physical property of a coating falls, it is preferable to add in the said range.
상기 경화촉진제는 구체적으로 디부틸 틴 디아우레이트 계통의 주석화합물 등이 사용되며, 0.001중량% 미만으로 첨가되면 건조시간이 늘어나고 0.1중량% 초과하여 첨가하면 도료 사용시간이 짧아지기 때문에 상기 범위로 첨가되는 것이 바람직하다.Specifically, the curing accelerator is a dibutyl tin diurate-based tin compound, etc. are used, and when added in less than 0.001% by weight, the drying time increases, and when added in excess of 0.1% by weight, the paint use time is shortened, so that it is added in the above range. It is preferable.
상기 폴리이소시아네이트는 구체적으로 헥사메틸렌 디이소이아네이트 등이 사용되며, 70중량% 미만으로 첨가되면 도막 물성이 저하되고 90중량% 초과하여 첨가되면 건조성이 저하되기 때문에 상기 범위로 첨가되는 것이 바람직하다.
Specifically, the polyisocyanate is preferably hexamethylene diisoyanate, and the like, and is preferably added in the above range because the physical properties of the polyisocyanate are lowered when added to less than 70% by weight, and the dryness is lowered when the amount exceeds 90% by weight. .
본 발명에 따른 난연도료 조성물은 후술하는 바와 같이 공인기관 기준치를 충분히 만족시키고 있어 종래의 난연도료에 비하여 난연성이 우수하다.The flame retardant coating composition according to the present invention satisfies the official engine standard value as described below, and is excellent in flame retardancy as compared with the conventional flame retardant paint.
또한 기계적 물성 역시 우수하여 유지 보수 기간을 연장할 수 있다.In addition, the mechanical properties are also excellent to extend the maintenance period.
또한 본 발명에 따른 난연도료 조성물은 종래의 난연도료에 비하여 메탈릭, 펄등 다양한 칼라를 구현할 수 있다.
In addition, the flame retardant paint composition according to the present invention can implement a variety of colors, such as metallic, pearl compared to the conventional flame retardant paint.
이하에서는 본 발명의 바람직한 실시예를 기초로 본 발명을 구체적으로 설명한다. 그러나 본 발명의 기술적 사항은 이에 한정되거나 제한되지 않고 당업자에 의해 변형되어 다양하게 실시될 수 있음은 물론이다.Hereinafter, the present invention will be described in detail based on the preferred embodiments of the present invention. However, the technical matters of the present invention are not limited thereto, but may be variously modified and modified by those skilled in the art.
본 발명의 실시예에 따른 난연도료 조성물은 하기 표 1과 같은 조성을 갖는다. 본 예시는 백색 난연도료 조성물에 관한 것이지만 안료 변경으로 솔리드, 메탈릭 및 펄 색상까지 구현할 수 있다.
Flame retardant paint composition according to an embodiment of the present invention has a composition as shown in Table 1. Although this example relates to a white flame retardant paint composition, it is possible to realize solid, metallic and pearl colors by changing the pigment.
- 아크릴 폴리올 : 메틸메탈아크릴레이트와 노르말부틸메타아크릴레이트를 주성분으로 하는 아크릴 폴리올(건설화학공업(주), A-829-JT)-Acrylic polyol: Acryl polyol whose main component is methyl methacrylate and normal butyl methacrylate (Construction Chemical Industries, Ltd., A-829-JT)
- CAB 아크릴 폴리올 : 메틸메탈아크릴레이트를 주성분으로 하고 셀룰로즈아세테이트 부틸레이트(CAB)를 부가한 아크릴 폴리올(건설화학공업(주), A-201-ET)-CAB acryl polyol: Acryl polyol with methyl methacrylate as main ingredient and cellulose acetate butyrate (CAB) added (Construction Chemical Industries, Ltd., A-201-ET)
- 침강방지제 : 폴리아마이드 왁스(흥산화성, HPA-803KS)-Sedimentation inhibitor: polyamide wax (hexoxidative, HPA-803KS)
- 분산제 : 불포화 폴리카르복실릭산의 폴리아민 아마이드Dispersant: polyamine amide of unsaturated polycarboxylic acid
(BYK, Disperbyk 130) (BYK, Disperbyk 130)
- 레벨링제 : 아크릴릭 코폴리머 (청우씨에프씨, Letch CFC-96S)-Leveling agent: acrylic copolymer (Cheongwoo CFC, Letch CFC-96S)
- 경화촉진제 : 디부틸 틴 디아우레이트(우창실업, DBTDL)-Curing accelerator: Dibutyl tin diaurate (Woochang Industry, DBTDL)
- 백색안료 : 루틸 타입 이산화티타늄(Dupont, TiO2 R-706)-White pigment: Rutile type titanium dioxide (Dupont, TiO2 R-706)
- 실리카 : 결정질 실리카(시벨코코리아, Silverbond CA-0030)-Silica: Crystalline silica (Sibelco Korea, Silverbond CA-0030)
- 수산화알루미늄 : (Showa Denko, HIGHLITE H-32)Aluminum hydroxide: (Showa Denko, HIGHLITE H-32)
- 폴리이소시아네이트 : 헥사메틸렌 디이소시아네이트(Perstop, Tolonate HDT)
Polyisocyanate: Hexamethylene diisocyanate (Perstop, Tolonate HDT)
이상과 같은 성분으로 분산기를 사용하여 안료를 분산하고, 최종적으로 용제를 투입하여 점도를 80~90KU로 조정하여 제조하였다.Pigments were dispersed using a disperser as described above, and finally a solvent was added to adjust the viscosity to 80 to 90 KU.
이와 같이 제조된 주제와 경화제를 혼합하여 도막을 형성한 후 물성을 평가한 결과를 하기 표 2에 나타내었다. 측정방법은 한국 산업 규격(KS), 미국재료시험규격(ASTM), 국제표준화규격(ISO), 영국 공업 규격(BS)을 인용하였다.
The results of evaluating the physical properties after mixing the main material and the curing agent thus prepared to form a coating film are shown in Table 2 below. The measurement method was quoted by Korean Industrial Standard (KS), American Material Testing Standard (ASTM), International Standardization Standard (ISO), and British Industrial Standard (BS).
상기 표 2에 나타나 있는 바와 같이 본 별명의 실시예에 따른 난연 도료의 경우 난연성을 결정하는 연기밀도, 가스유독성, 산소지수, 화염전파 실험에서 기준치보다 매우 우수한 결과를 나타내므로, 본 발명에 따른 난연 도료를 적용 시 난연성을 크게 개선 할 수 있다.As shown in Table 2, in the case of the flame retardant paint according to an embodiment of the present nickname, the flame retardancy according to the present invention shows a result superior to the reference value in the smoke density, gas toxicity, oxygen index, and flame propagation experiments to determine flame retardancy. When paint is applied, the flame retardancy can be greatly improved.
또한, 기계적 물성이 우수하여 유지 보수 기간을 연장할 수 있다.In addition, excellent mechanical properties can extend the maintenance period.
또한, 외관 평가에 있어서도, 기존 난연 도료와 대비할 때 차이가 없이 양호하였다.In addition, also in appearance evaluation, compared with the existing flame-retardant paint was good without any difference.
Claims (5)
상기 주제는 아크릴 폴리올 30~55중량%(주제 내에서의 함량임, 이하 같음), 셀룰로즈 아세테이트 부틸레이트(CAB) 변성 아크릴 폴리올 1~10중량%, 수산화알루미늄 5~25중량%, 실리카 5~25중량%, 안료 3~20중량%, 분산제 0.1~2중량%, 레벨링제 0.1~1중량%, 경화 촉진제 0.001~0.1중량%, 침강방지제 0.1~2중량%, 용제 5~15중량%를 함유하고,
상기 경화제는 폴리이소시아네이트 70~90중량%(경화제 내에서의 함량임, 이하 같음), 용제 10~30중량%를 함유하는 것을 특징으로 하는 난연도료 조성물.As a two-component flame retardant paint composition using a mixture of a main body and a curing agent,
The subject matter is 30 to 55% by weight of acrylic polyol (content in the topic, the same as below), 1 to 10% by weight of cellulose acetate butyrate (CAB) modified acrylic polyol, 5 to 25% by weight of aluminum hydroxide, 5 to 25 of silica Wt%, pigment 3-20 wt%, dispersant 0.1-2 wt%, leveling agent 0.1-1 wt%, curing accelerator 0.001-0.1 wt%, sedimentation inhibitor 0.1-2 wt%, solvent 5-15 wt% ,
The curing agent is a flame retardant paint composition, characterized in that it contains 70 to 90% by weight of polyisocyanate (content in the curing agent, the same as below), 10 to 30% by weight of the solvent.
상기 주제의 용제는 초산부틸, 크실렌, 톨루엔 및 프로필렌 글리콜 모노메틸 에테르 아세트산 중의 적어도 어느 하나인 것을 특징으로 하는 난연도료 조성물.The method of claim 1,
The solvent of the subject is at least one of butyl acetate, xylene, toluene and propylene glycol monomethyl ether acetic acid.
상기 경화제의 용제는 초산부틸 및 초산에틸 중 적어도 어느 하나인 것을 특징으로 하는 난연도료 조성물.3. The method according to claim 1 or 2,
The solvent of the curing agent is a flame retardant coating composition, characterized in that at least one of butyl acetate and ethyl acetate.
상기 침강방지제는 폴리아마이드계 왁스인 것을 특징으로 하는 난연도료 조성물.The method of claim 3,
The anti-settling agent is a flame retardant coating composition, characterized in that the polyamide wax.
상기 난연도료 조성물은 철도차량 및 각종 차량 내부에 적용되는 것을 특징으로 하는 난연도료 조성물.The method of claim 3,
The flame retardant paint composition is a flame retardant paint composition, characterized in that applied to the inside of a railway vehicle and various vehicles.
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| KR1020120112239A KR101365929B1 (en) | 2012-10-10 | 2012-10-10 | A paint composition of two liquid type having high flame-resistance property containing aluminium hydroxide |
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| KR1020120112239A KR101365929B1 (en) | 2012-10-10 | 2012-10-10 | A paint composition of two liquid type having high flame-resistance property containing aluminium hydroxide |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103897573A (en) * | 2014-04-18 | 2014-07-02 | 昆山金有利新材料科技有限公司 | Fireproof polyurethane foam coating and preparation method thereof |
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|---|---|---|---|---|
| JP2000297247A (en) | 1999-04-15 | 2000-10-24 | Origin Electric Co Ltd | Flame-retardant coating composition |
| KR100406685B1 (en) | 2001-06-20 | 2003-11-21 | 에스에스씨피 주식회사 | Composition for the 1-coat surface treatment of acrylonitrile-butadiene-styrene mold products |
| JP2008222773A (en) | 2007-03-09 | 2008-09-25 | Auto Kagaku Kogyo Kk | Polyurethane-based curable resin composition and coating material comprising the same |
| KR20090114898A (en) * | 2008-04-30 | 2009-11-04 | 아이케이 주식회사 | Composite of anti-flammable adhesive and sandwich panel using the same |
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2012
- 2012-10-10 KR KR1020120112239A patent/KR101365929B1/en active IP Right Grant
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000297247A (en) | 1999-04-15 | 2000-10-24 | Origin Electric Co Ltd | Flame-retardant coating composition |
| KR100406685B1 (en) | 2001-06-20 | 2003-11-21 | 에스에스씨피 주식회사 | Composition for the 1-coat surface treatment of acrylonitrile-butadiene-styrene mold products |
| JP2008222773A (en) | 2007-03-09 | 2008-09-25 | Auto Kagaku Kogyo Kk | Polyurethane-based curable resin composition and coating material comprising the same |
| KR20090114898A (en) * | 2008-04-30 | 2009-11-04 | 아이케이 주식회사 | Composite of anti-flammable adhesive and sandwich panel using the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103897573A (en) * | 2014-04-18 | 2014-07-02 | 昆山金有利新材料科技有限公司 | Fireproof polyurethane foam coating and preparation method thereof |
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