KR101361756B1 - Method for extraction of chamaecyparis obutsa oil - Google Patents
Method for extraction of chamaecyparis obutsa oil Download PDFInfo
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- KR101361756B1 KR101361756B1 KR1020130060742A KR20130060742A KR101361756B1 KR 101361756 B1 KR101361756 B1 KR 101361756B1 KR 1020130060742 A KR1020130060742 A KR 1020130060742A KR 20130060742 A KR20130060742 A KR 20130060742A KR 101361756 B1 KR101361756 B1 KR 101361756B1
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/025—Recovery by solvent extraction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/02—Solvent extraction of solids
- B01D11/0203—Solvent extraction of solids with a supercritical fluid
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/02—Pretreatment
- C11B1/04—Pretreatment of vegetable raw material
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/10—Production of fats or fatty oils from raw materials by extracting
- C11B1/104—Production of fats or fatty oils from raw materials by extracting using super critical gases or vapours
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Abstract
Description
본 발명은 편백오일의 추출방법에 관한 것으로서, 구체적으로 편백나무 원료로부터 피톤치드 함량이 60% 이상 함유된 편백오일을 추출할 수 있는 편백오일의 추출방법에 관한 것이다.
The present invention relates to a method for extracting cypress oil, and more particularly, to a method for extracting cypress oil, capable of extracting cypress oil containing 60% or more of phytoncide content from a cypress raw material.
피톤치드(phytoncide)는 러시아어로 "식물의"란 뜻의 파이톤(phyton)과 "죽이다"라는 뜻의 사이드(cide)가 합쳐져 생성된 용어로, 모든 식물은 각각의 생육과정에서 세균 및 곤충 등의 공격이나 자극으로부터 방어용 물질을 발산하며, 이때 식물에서 발산되는 항균, 방충, 살균물질이 피톤치드이다.
Phytoncide is a Russian term that combines phyton, which means "plant," and cide, which means "kill." All plants are attacked by bacteria and insects in their respective growth processes. It emits a protective substance from irritation, and at this time, the antibacterial, insect repellent, and bactericidal substances emitted from plants are phytoncide.
피톤치드는 테르펜을 비롯한 페놀 화합물, 알칼로이드 성분, 글리코시드 성분으로 이루어져 인공합성이나 조합이 어려운 100% 천연물질로, 일반적으로 삼림욕을 통해 인간의 신체에 무리없이 빠르게 흡수되어, 인간에게 해로운 균들을 선택적으로 살균함으로써, 내성이 없는 강한 항균ㆍ항진균 작용, 스트레스 완화, 피부의 진정작용, 숙면 유도효과, 알레르기성 피부질환 개선 및 면역기능 증대 등의 다양한 효능을 갖는 순수한 자연치유 요법이다. 이에따라 삼림욕을 자주 할 수 없는 바쁜 현대인을 위해 방향제, 세안제, 화장품 및 의약품 등 일상생활에 접할 수 있는 여러 가지 제품에 피톤치드 성분을 첨가하여 간접적으로 삼림욕 효과를 기대하려는 제품 생산의 움직임이 활발하게 이루어 지고 있다.
Phytoncide is composed of terpene and other phenolic compounds, alkaloids, and glycosides. It is a 100% natural substance that is difficult to artificially synthesize or combine. It is generally absorbed quickly and easily by humans through a forest bath, and selectively removes harmful bacteria. By sterilization, it is a pure natural healing therapy with various effects such as strong antibacterial and antifungal action, stress relief, soothing effect of skin, sleep inducing effect, allergic skin disease improvement and immune function enhancement. Accordingly, for busy modern people who can't use forest bathing frequently, the movement of product production to actively expect the forest bathing effect by adding phytoncide ingredients to various products such as air fresheners, face washes, cosmetics, and medicines have.
피톤치드에 대한 연구 결과로는 식물에서 발산되는 피톤치드의 양은 물론이고 효능 또한 모두 다른 특징이 있는데, 소나무나 잣나무 등과 같은 침엽수에서 다량의 피톤치드가 발생하며, 특히, 편백나무(扁栢, Chamaecyparis obtusa (S. et Z.) ENDL)에서 가장 많은 성분 함량과 치유력이 강력한 피톤치드가 발생되는 것으로 알려져 있다.
The results of the phytoncide study show that not only the amount of phytoncide emitted from the plant but also its efficacy is different. A large amount of phytoncide occurs in conifers such as pine or pine, and in particular, Chamaecyparis obtusa (S) et Z.) ENDL) is known to produce phytoncide with strongest content and strong healing power.
현재 피톤치드 성분이 포함된 제품은 편백나무로부터 추출한 정유(精油, essential oil)를 주로 이용하고 있으며, 여기서 정유라 함은, 식물의 꽃ㆍ꽃봉오리ㆍ잎ㆍ줄기ㆍ뿌리ㆍ천연수지(天然樹脂) 등에서 얻는 향기가 강한 휘발성 물질로 피톤치드 성분을 포함하고 있다.
Currently, phytoncide-containing products mainly use essential oils extracted from cypress, where essential oils are plant flowers, buds, leaves, stems, roots, and natural resins. It contains a phytoncide component as a strong volatile substance obtained from the back.
편백나무 등의 수목에서 정유를 추출하는 방법으로는 수증기 증류법이 주로 사용되고 있는데, 정유의 대부분은 물에 녹지 않으므로 수증기의 열에 의해 향기성분이 변화되지 않는 방법으로 널리 사용되고 있는 방법이다.
Steam distillation is mainly used as a method of extracting essential oils from trees such as cypress, and since most of essential oils are insoluble in water, the fragrance component is not changed by the heat of steam.
서로 불용인 혼합물 증기의 전 압력은 순성분 각각의 증기압의 합과 같아지므로 정유의 증기압과 물의 증기압의 합이 증류탱크 내의 압력과 같아지면, 정유는 수증기와 함께 비등하여 유출하게 되고, 정유 성분의 비점(150~350℃)보다 훨씬 낮은 온도에서 유출시킬 수 있으므로 성분의 분해나 변질의 염려가 거의 없다.
Since the total pressures of the insoluble mixture vapors are equal to the sum of the respective vapor pressures of the pure components, when the sum of the vapor pressure of the refinery oil and the steam pressure of the water is equal to the pressure in the distillation tank, the essential oil is boiled out with water vapor and discharged. Since it can flow out at a temperature much lower than the boiling point (150 ~ 350 ℃), there is little concern about decomposition or deterioration of the components.
한편, 편백나무의 편백오일의 추출방법과 관련하여 공개특허 제2012-0050318호(저압 수증기 증류법에 의한 편백나무의 피톤치드 정유 추출 장치), 공개특허 제2012-0047039호(편백나무 잎의 정유 추출장치), 공개특허 제2011-0133961호(피톤치드 추출장치), 공개특허 제2011-0000285호(초임계유체를 이용한 잣나무로부터 피톤치드의 추출방법), 공개특허 제2004-0026152호(혈압완화 효능을 갖는 편백 정유의 가열촉진 시스템에 의한 추출법), 공개특허 제1999-0083666호(편백으로부터 추출된 항균, 항진균효과를 갖는 정유의 추출 방법), 등록특허 제0828927호(편백나무의 정유 추출 방법) 등의 다수의 선행특허가 제안된 바 있다.
On the other hand, in connection with the method of extracting the cypress oil of the cypress, Patent Publication No. 2012-0050318 (phytoncide essential oil extracting device of cypress by low pressure steam distillation method), Patent Publication No. 2012-0047039 (essential oil extracting device of cypress leaf ), Patent Publication No. 2011-0133961 (phytoncide extracting device), Patent Publication No. 2011-0000285 (method of extracting phytoncide from pine trees using supercritical fluid), Patent Publication No. 2004-0026152 (baekbaek with blood pressure relief effect Extraction method by heating promotion system of essential oil), Published Patent No. 1999-0083666 (Extract method of essential oil extracted from cypress, antifungal effect), Patent No. 0828927 (Essential oil extraction method of cypress) Prior patents have been proposed.
종래의 수증기증류법 및 선행특허들에 의한 편백오일 추출방법의 경우 피톤치드성분이 45% 미만으로 함유된 편백오일을 얻을 수 있을 뿐 피톤치드성분이 더욱 많이 함유된 고품질의 편백오일을 얻을 수 없는 문제가 있다.
In the conventional steam distillation method and the method of extracting cypress oil according to the prior patents, it is possible to obtain a cypress oil containing less than 45% of the phytoncide component, and there is a problem in that a high quality cypress oil containing more phytoncide component can not be obtained. .
본 발명은 편백나무 원료로부터 피톤치드 성분이 60% 이상 함유된 편백오일을 추출할 수 있는 편백오일의 추출방법을 제공하는 것을 목적으로 한다.
An object of the present invention is to provide a method for extracting cypress oil, which can extract cypress oil containing 60% or more of phytoncide components from a cypress raw material.
상기와 같은 목적을 달성하기 위한 본 발명은, According to an aspect of the present invention,
a) 편백나무 잎을 포함하는 편백나무 원료를 압력탱크 내에 투입하는 단계와;a) injecting a cypress raw material including a cypress leaf into a pressure tank;
b) 상기 압력탱크에 고압스팀과 함께 고압공기를 공급하는 단계와;b) supplying high pressure air together with high pressure steam to the pressure tank;
c) 상기 압력탱크로부터 배출되는 수증기를 냉각시켜 응축수로 변환시키는 단계와;c) cooling the water vapor discharged from the pressure tank and converting the water vapor into condensed water;
d) 상기 응축수로부터 편백오일과 편백수를 분리하는 단계;를 포함하여 이루어지는 것을 특징으로 하는 편백오일의 추출방법을 제공한다.d) separating the cypress oil from the condensed water and the cypress water; provides a method of extracting cyanoyl oil, comprising the.
특히, 상기 압력탱크 내에 상기 고압스팀을 2.5~3.0 kgf/cm2의 압력으로 공급하고, 상기 고압공기를 1.1~2.5 kgf/cm2의 압력으로 공급하는 것이 바람직하다. 더욱 바람직하게는 상기 고압공기는 히터에 의해 가열된 고압공기인 것이 좋다.In particular, the high pressure steam is supplied to the pressure tank at a pressure of 2.5 to 3.0 kgf / cm 2 , and the high pressure air is preferably supplied at a pressure of 1.1 to 2.5 kgf / cm 2 . More preferably, the high pressure air is high pressure air heated by a heater.
그리고 상기 압력탱크의 내부압력이 1.1~1.5 kgf/cm2이고 내부온도가 110~130℃일 때 상기 압력탱크 내부의 수증기를 배출시키는 것이 바람직하다.
And when the internal pressure of the pressure tank is 1.1 ~ 1.5 kgf / cm 2 and the internal temperature is 110 ~ 130 ℃ it is preferable to discharge the water vapor in the pressure tank.
본 발명은 압력탱크에 고압스팀과 고압 공기를 공급하여 편백나무 원료로부터 피톤치드 성분이 함유된 증기를 추출함으로서, 피톤치드 성분이 60% 이상 함유된 편백오일을 추출할 수 있는 효과가 있다.
The present invention is to supply a high pressure steam and high pressure air to the pressure tank to extract the steam containing the phytoncide component from the raw cypress wood, there is an effect that can extract the cypress oil containing more than 60% phytoncide component.
도 1은 본 발명의 편백오일의 추출방법의 순서를 개략적으로 나타내는 흐름도이고,
도 2는 본 발명을 위한 편백오일 추출장치를 개략적으로 나타내는 도면이다.1 is a flowchart schematically showing a procedure of a method for extracting cypress oil of the present invention;
2 is a view schematically showing an apparatus for extracting cypress oil for the present invention.
본 발명의 편백오일의 추출방법을 상세히 설명하면 다음과 같다.Hereinafter, a method of extracting cypress oil of the present invention will be described in detail.
도 1은 본 발명의 편백오일의 추출방법의 순서를 개략적으로 나타내는 흐름도이고, 도 2는 본 발명을 위한 편백오일 추출장치를 개략적으로 나타내는 도면이다.1 is a flow chart schematically showing the procedure of the method of extracting cypress oil of the present invention, Figure 2 is a diagram schematically showing the apparatus for extracting cypress oil for the present invention.
본 발명의 편백오일의 추출방법은 도 1 및 도 2와 같이 편백나무 잎을 포함하는 편백나무 원료를 압력탱크 내에 투입하고, 압력탱크에 고압스팀 및 고압공기를 공급하고, 증발된 수증기를 냉각시켜 저장탱크에 저정한 후 편백오일 및 편백수를 층분리시켜 각각 추출한다.
In the method of extracting cypress oil of the present invention, as shown in Figs. 1 and 2, a cypress raw material including a cypress leaf is introduced into a pressure tank, a high pressure steam and high pressure air are supplied to the pressure tank, and the vaporized water vapor is cooled. After storage in a storage tank, the cypress oil and the cypress water are separated and separated.
먼저, 상기 편백나무 원료를 압력탱크 내에 투입한다(S1). 상기 편백나무 원료로서 편백나무 잎 및 가지를 사용할 수 있으나, 고순도의 편백오일을 추출하고 작업성을 향상시키기 위해 편백나무 잎을 일정 길이로 절단하여 사용하는 것이 좋다.
First, the cypress raw material is injected into the pressure tank (S1). Although the cypress leaves and branches may be used as the cypress raw material, it is preferable to cut the cypress leaves to a certain length in order to extract high purity cypress oil and improve workability.
다음으로, 상기 압력탱크 내에 고압스팀과 고압공기를 공급한다(S2). 상기 고압스팀은 고압스팀보일러에 의해 발생된 고압의 스팀을 스팀 압력조절밸브를 통해 조절한 후 상기 압력탱크 내에 공급한다.Next, high pressure steam and high pressure air are supplied into the pressure tank (S2). The high pressure steam is supplied to the pressure tank after the high pressure steam generated by the high pressure steam boiler is regulated through the steam pressure control valve.
이때 편백오일에 피톤치드 성분이 높게 함유되도록 하기 위해 고압의 스팀을 상기 스팀 압력조절밸브를 통해 2.5~3.0 kgf/cm2으로 조절하여 상기 압력탱크 내에 공급하는 것이 좋다.In this case, in order to ensure that the phytoncide component is contained in the cypress oil, it is preferable to adjust the high-pressure steam to 2.5 to 3.0 kgf / cm 2 through the steam pressure regulating valve and supply it to the pressure tank.
그리고 상기 고압공기는 컴프레셔 등의 고압공기 공급장치를 통해 발생된 고압공기를 상기 압력탱크 내에 공급한다. 상기 고압공기를 상기 압력탱크 내에 상기 고압스팀과 함께 공급함으로써, 추출시간을 단축할 수 있고 반복적인 실험결과 피 60% 이상의 피톤치드 성분을 추출할 수 있는 이점이 있었다. 특히, 피톤치드 성분을 효과적으로 추출하기 위해 상기 고압공기를 공기 압력조절밸브를 통해 1.1~2.5 atm으로 조절하여 상기 압력탱크 내에 공급하는 것이 좋다.
The high pressure air supplies high pressure air generated through a high pressure air supply device such as a compressor into the pressure tank. By supplying the high pressure air together with the high pressure steam in the pressure tank, it is possible to shorten the extraction time and to extract more than 60% of the phytoncide component by repeated experiments. In particular, in order to effectively extract the phytoncide component, it is preferable to adjust the high pressure air to 1.1 to 2.5 atm through an air pressure control valve and to supply the pressure tank.
다음으로, 상기 압력탱크로부터 배출되는 수증기를 냉각시켜 응축수로 변환시킨다(S3). 특히, 피톤치드의 추출율을 향상시키기 위해 상기 압력탱크가 내부 압력이 1.1~1.5 kgf/cm2, 온도가 110~130℃일 때, 수증기가 열교환기로 배출되도록 제어하는 것이 좋다.Next, the water vapor discharged from the pressure tank is cooled and converted into condensate (S3). In particular, in order to improve the extraction rate of the phytoncide, the pressure tank may be controlled to discharge steam to the heat exchanger when the internal pressure is 1.1 to 1.5 kgf / cm 2 and the temperature is 110 to 130 ° C.
상기 열교환기는 상기 압력탱크로부터 배출되는 수증기를 냉각시킬 수 있는 구조이면 족하고, 크게 한정되는 것은 아니나, 냉각수 저장탱크에 저장된 냉각수를 이용하여 수증기를 냉각 및 응축시키는 것이 좋다. 상기 열교환기는 응축수의 배출방향으로 하향경사지도록 형성되어 상기 열교환기에 의해 응축된 응축수가 자중에 의해 저장탱크로 공급된다.The heat exchanger may be sufficient as long as it is capable of cooling the steam discharged from the pressure tank, and the heat exchanger is not limited thereto. However, the heat exchanger may cool and condense the water vapor using the cooling water stored in the cooling water storage tank. The heat exchanger is formed to be inclined downward in the discharge direction of the condensate so that the condensed water condensed by the heat exchanger is supplied to the storage tank by its own weight.
그리고 상기 열교환기에 의해 상기 수증기와 열교환된 냉각수는 상기 냉각수 저장탱크로 회수된다.
The coolant heat exchanged with the water vapor by the heat exchanger is recovered to the coolant storage tank.
상기 저장탱크에 저장된 응축수를 편백오일과 편백수로 분리시켜 저장한다.(S4). 상기 응축수를 편백오일과 편백수로 분리하는 방법은 크게 한정되는 것은 아니고, 비중차이, 원심분리 등의 방법으로 상기 응축수를 편백오일과 편백수로 분리할 수 있다.
The condensate stored in the storage tank is separated and stored as cypress oil and cypress water (S4). The method of separating the condensate into cypress oil and cypress water is not particularly limited, and the condensate may be separated into cypress oil and cypress by means of specific gravity difference and centrifugation.
이와 같이 본 발명에서 압력탱크에 고압스팀과 고압 공기를 공급하여 편백나무 원료로부터 피톤치드 성분이 함유된 증기를 추출함으로서, 피톤치드 성분이 60% 이상 함유된 편백오일을 추출할 수 있다.
Thus, by supplying high pressure steam and high pressure air to the pressure tank in the present invention to extract the steam containing the phytoncide component from the cypress raw material, it is possible to extract the cypress oil containing more than 60% phytoncide component.
이하, 본 발명의 편백오일의 추출방법을 실시예를 들어 상세히 설명하면 다음과 같고, 본 발명의 권리범위는 하기의 실시예에 한정되는 것은 아니다.
Hereinafter, a method of extracting cypress oil of the present invention will be described in detail with reference to Examples. The scope of the present invention is not limited to the following Examples.
[실시예][Example]
편백나무 잎을 세척한 후 냉풍건조시켰다. 그리고 편백나무 잎을 압력탱크 내에 용이하게 투입할 수 있을 정도의 크기로 절단한 후 압력탱크에 투입하였다.The cypress leaves were washed and then air dried. And the cypress leaves were cut into a size that can be easily put into the pressure tank and then put into the pressure tank.
그리고 상기 압력탱크 내에 표 1과 같은 압력으로 고압스팀과 고압공기를 공급하고, 압력탱크의 온도가 표 1과 같은 조건일 때 수증기를 배출하였고, 수증기를 냉각시킨 응축수를 비중차이에 의해 편백오일과 편백수를 분리하여 편백수가 분리된 편백오일을 얻었다.
Then, the high pressure steam and the high pressure air were supplied to the pressure tank at the pressure as shown in Table 1, the steam was discharged when the temperature of the pressure tank was as shown in Table 1, and the condensed water cooled by the specific gravity was different from the one-pack oil. Cyanomegaly was separated to obtain cyanomegaly oil.
압력(kgf/cm2)High pressure steam
Pressure (kgf / cm 2 )
압력(kgf/cm2)High pressure air
Pressure (kgf / cm 2 )
실시예 1
Example 1
2.5
2.5
1.1
1.1
110
110
1.1
1.1
실시예 2
Example 2
2.5
2.5
2.0
2.0
120
120
1.1
1.1
실시예 3
Example 3
3.0
3.0
2.5
2.5
130
130
1.5
1.5
[비교예 1]Comparative Example 1
편백나무 잎을 세척한 후 냉풍건조시켰다. 그리고 편백나무 잎을 압력탱크 내에 용이하게 투입할 수 있을 정도의 크기로 절단한 후 압력탱크에 투입하였다.The cypress leaves were washed and then air dried. And the cypress leaves were cut into a size that can be easily put into the pressure tank and then put into the pressure tank.
그리고 상기 압력탱크 내에 5.5 kgf/cm2의 고압스팀을 공급하고, 압력탱크의 온도가 105℃이고 압력이 1.5 kgf/cm2일 때 수증기를 배출하였고, 수증기를 냉각시킨 응축수를 비중차이에 의해 편백오일과 편백수를 분리하여 편백수가 분리된 편백오일을 얻었다.
Then, a high pressure steam of 5.5 kgf / cm 2 was supplied into the pressure tank, steam was discharged when the temperature of the pressure tank was 105 ° C. and the pressure was 1.5 kgf / cm 2 , and the condensed water that cooled the steam was concentrated by specific gravity. The oil and cypress water were separated to obtain the cypress oil from which the cypress water was separated.
[편백오일 성분분석][Cycle Oil Component Analysis]
실시예 1~3 및 비교예 1의 편백오일을 핵산(MERCK)에 충분히 교반하여 원심분리기를 이용하여 부유물을 제거하고 마이크로 필터(0.45 ㎛)를 사용하여 준비하였다. 시료 분석은 GC/MS 장비(240-MS, Varian)를 이용하여 다음과 같은 조건으로 진행하였다. 컬럼은 VF-5ms(30 mm×0.25 mm×0.25 mm), 이동 기체로는 He (1mL/min), 주입 온도는 250 ℃, 오븐 온도는 50 ~ 300 ℃/ 3 ℃ 승온, 주입 부피는 1 ㎕, 주입 모드는 스플릿 비율(Split ratio) 10:1 조건에서 성분분석을 하였으며 MDS(Mass Selective Detector)에서 질량 범위 28 ~ 550, 수집 모드(acqusition mode)는 스캔 모드(scan mode) 조건으로 성분들을 정량하였다. Cyclone oils of Examples 1 to 3 and Comparative Example 1 were sufficiently stirred in nucleic acid (MERCK) to remove suspended matter using a centrifuge, and prepared using a micro filter (0.45 μm). Sample analysis was performed using the GC / MS equipment (240-MS, Varian) under the following conditions. The column is VF-5 ms (30 mm × 0.25 mm × 0.25 mm), He (1 mL / min) as the moving gas, the injection temperature is 250 ° C., the oven temperature is 50 to 300 ° C./3° C., and the injection volume is 1 μl. In the injection mode, the component was analyzed under a split ratio of 10: 1. The mass range was 28 to 550 in a mass selective detector (MDS), and the acquisition mode was used to quantify the components under the scan mode. It was.
그리고 GC피크면적을 기준으로 각 성분의 백분율을 계산하였다. 각 성분의 백분율은 각 피크의 면적을 모든 피크의 총면적에 대한 백분율로 계산하였다. 그리고 모든 성분 중 각 피톤치드 성분이 차지하는 백분율의 합을 계산하여 표 2로 나타냈다. And the percentage of each component was calculated based on GC peak area. The percentage of each component calculated the area of each peak as a percentage of the total area of all peaks. And the sum of the percentage occupied by each phytoncide component of all components is shown in Table 2.
피톤치드 성분으로는 Tricyclene, α-Pinene, Camphene, β-Pinene, Sabinene, Myrcene, β-Phellandrene, α-Terpinene, Limonene, α-Thujene, γ-Terpinene, ρ-Cymene, Terpinolene, α-Cubebene, α--Copaene, Camphore, Linalool, Linalyl acetate, Bornyl acetate, Thymol methyl ether, β-Elemene, β-Caryophyllene, Terpinene, Widdrene, Humulene, β-Selinene, γ-Muurolene, α-Terpineol, Borneol, α-Terpinyl acetate, γ-Elemene, Bicyclosesquiphellandrene, phellandrene, phellandrene, α-Muurolene, α-Cadinene, δ-Cadinene γ-Cadinene ρ-Cymene-3-ol, Caryophyllene, oxide, Farnesol, Elemol, α-Selinene, Cedrol, Spathulene, β-Selinene, T-Muurolol, Stach-15-ene, α-Eudesmol, Globulol, α-Podocarprene을 들 수 있다.
Phytoncide components include Tricyclene, α-Pinene, Camphene, β-Pinene, Sabinene, Myrcene, β-Phellandrene, α-Terpinene, Limonene, α-Thujene, γ-Terpinene, ρ-Cymene, Terpinolene, α-Cubebene, α- -Copaene, Camphore, Linalool, Linalyl acetate, Bornyl acetate, Thymol methyl ether, β-Elemene, β-Caryophyllene, Terpinene, Widdrene, Humulene, β-Selinene, γ-Muurolene, α-Terpineol, Borneol, α-Terpinyl acetate, γ-Elemene, Bicyclosesquiphellandrene, phellandrene, phellandrene, α-Muurolene, α-Cadinene, δ-Cadinene γ-Cadinene ρ-Cymene-3-ol, Caryophyllene, oxide, Farnesol, Elemol, α-Selinene, Cedrol, Spathulene, β-- Selinene, T-Muurolol, Stach-15-ene, α-Eudesmol, Globulol, α-Podocarprene.
(%)Phytoncite Ingredients
(%)
63.414
63.414
65.532
65.532
63.717
63.717
44.329
44.329
표 2와 같이 실시예 1 내지 3은 피톤치드 성분함량이 63% 이상으로, 비교예 1의 44%에 비하여 매우 높게 측정되었다.As shown in Table 2, Examples 1 to 3 had a phytoncide component content of 63% or more, which was very high compared to 44% of Comparative Example 1.
Claims (5)
b) 상기 압력탱크에 고압스팀과 함께 고압공기를 공급하는 단계와;
c) 상기 압력탱크로부터 배출되는 수증기를 냉각시켜 응축수로 변환시키는 단계와;
d) 상기 응축수로부터 편백오일과 편백수를 분리하는 단계;를 포함하여 이루어지며,
상기 압력탱크 내에 상기 고압스팀을 2.5~3.0 kgf/cm2의 압력 및 상기 고압공기를 1.1~2.5 kgf/cm2의 압력으로 공급하고, 상기 압력탱크의 내부압력이 1.1~1.5kgf/cm2이고 내부온도가 110~130℃일 때 상기 압력탱크 내부의 수증기를 배출시키는 것을 특징으로 하는 편백오일의 추출방법.
a) injecting a cypress raw material including a cypress leaf into a pressure tank;
b) supplying high pressure air together with high pressure steam to the pressure tank;
c) cooling the water vapor discharged from the pressure tank and converting the water vapor into condensed water;
d) separating the cypress oil and cypress water from the condensate;
In the pressure tank, the high pressure steam is supplied at a pressure of 2.5 to 3.0 kgf / cm 2 and the high pressure air at a pressure of 1.1 to 2.5 kgf / cm 2 , and the internal pressure of the pressure tank is 1.1 to 1.5 kgf / cm 2 . Method for extracting cypress oil, characterized in that to discharge the steam inside the pressure tank when the internal temperature is 110 ~ 130 ℃.
상기 고압공기는 히터에 의해 가열된 고압공기인 것을 특징으로 하는 편백오일의 추출방법.The method of claim 1,
The high-pressure air is a high-pressure air heated by a heater, characterized in that the extraction method of cypress oil.
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| KR20190074834A (en) * | 2017-12-20 | 2019-06-28 | 허진희 | Double microcapsule |
| KR102017156B1 (en) | 2018-07-02 | 2019-09-03 | 임회규 | Aromatic extraction method |
| KR102105797B1 (en) * | 2019-11-04 | 2020-04-28 | 박상호 | Extracting Apparatus and An Extracting Method using that A Chamaecyparis Obtusa Oil |
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| KR20220069230A (en) | 2020-11-20 | 2022-05-27 | 김성준 | Apparatus and Method of drying red fine matched red pine oil extraction |
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| KR20220069230A (en) | 2020-11-20 | 2022-05-27 | 김성준 | Apparatus and Method of drying red fine matched red pine oil extraction |
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