KR101336871B1 - Hair gel wax composition - Google Patents

Abstract

The present invention relates to a hair gel wax composition, wherein the hair gel wax composition comprises a polyoxyethylene (3) oleyl ether phosphate diethanolamine salt and a polyoxyethylene (7) lauryl ether. The hair gel wax composition according to the present invention is excellent in the effect of arranging and arranging the hair while giving gloss and softness to the hair, and can provide a fresh feeling without grease in the hands and hair, as well as being transparent and fingers. When tapping, it has a physical characteristic that makes it feel a vibration.

Hair gel wax, polyoxyethylene (3) oleyl ether phosphate diethanolamine salt, polyoxyethylene (7) lauryl ether

Description

Hair gel wax composition

The present invention relates to a hair gel wax composition, and more particularly, has an excellent effect of arranging and arranging hair while giving gloss and softness to the hair, and can provide a fresh feeling without hand and hair shine. Rather, it relates to a hair gel wax composition having a physical property that is transparent and feels a ringing feeling when tapping with a finger.

Humans feel satisfied by dyeing their hair, perm, and dryer to pursue beauty. However, hair is looking for a hair product that can provide a smooth luster of hair by dyeing, perm, dryer, etc., and can maintain a smooth and organized hair for a long time.

Treatment hair dressing products that give hair shine and softness include oil-based hair dressing agents such as emulsion type hair creams, hair lotions, and pomades (US Pat. Nos. 6,244,770, 4,938,954, and 5,993,832). have. The gloss and softening effects of these products vary depending on the formulation.

Emulsified hair styling creams or lotions are emulsified with water and oil components using surfactants, and the more oil components such as mineral oils, vegetable oils, silicone oils, etc., the hair is enhanced. However, the oil phase / water phase emulsifiers, which are generally used in a continuous phase, are water phases. Hair gel or hair glaze is a transparent phase product in which a small amount of oils, such as fragrance, are solubilized in a continuous phase by using a surfactant (emulsifier). The use of a small amount of oil or water soluble silicone has to be used to limit the gloss of the hair.

Hair product researchers have tried to give hair the ability to organize and trim the hair while making it soft and shiny.

Conventional continuous phase award-winning oil / water type hair wax hair dressing agents have generally used oily ingredients such as silicone gum or beeswax to have high viscosity and improve hair shine and softness. It did not satisfy enough. In addition, the water / oil phase hair wax hair dresser of the continuous phase is an oil phase hair wax hair dresser that can use much more oil than water due to the nature of the formulation. The use of oil-based ingredients in such hairstyling agents may result in the formation of an emulsified form, which may be glossy, but the hair looks greasy and oily, and hands and hair do not wash well with cleaning products such as shampoos and soaps. .

There is also a coating essence product as a hair treatment hair dresser in a tangible form rather than a conventional emulsified form. This product is usually made of silicone gum and silicone as a solvent, so the hair shine is very high.However, the hair looks greasy and oily, and hands and hair are not washed well by cleaning products such as shampoo or soap. Has

Therefore, the technical problem to be achieved by the present invention is excellent in the effect of arranging and arranging the hair while giving gloss and softness to the hair, and not only can provide a fresh feeling without hand and hair shine, but also transparent and fingers. It is to provide a hair gel wax composition having a physical property that feels a ringing feeling when tapping.

In order to achieve the above technical problem, the present invention is characterized in that the hair gel wax composition, comprising a polyoxyethylene (3) oleyl ether phosphate diethanolamine salt and polyoxyethylene (7) lauryl ether Provide a hair gel wax composition.

The composition is preferably included 2 to 15% by weight of polyoxyethylene (3) oleyl ether phosphate diethanolamine salt and 2 to 15% by weight of polyoxyethylene (7) lauryl ether relative to the total weight of the composition.

More preferably, the composition further includes a vinyl pyrrolidone / methacrylamide / vinyl imidazole copolymer, wherein the polyoxyethylene (3) oleyl ether phosphate diethanol is compared to the total weight of the composition. 6 to 10 weight percent amine salt, 5.5 to 10 weight percent polyoxyethylene (7) lauryl ether and 0.1 to 4 weight percent VPI / methacrylamide / vinylimidazole copolymer.

Hereinafter, the hair gel wax composition of the present invention will be described in more detail.

In the present invention, as a result of using polyoxyethylene (3) oleyl ether phosphate diethanolamine salt and polyoxyethylene (7) lauryl ether in the microemulsion type hair gel wax composition, it has excellent shine and softness effect. Not only good feeling, but also polyoxyethylene (3) oleyl ether phosphate diethanolamine salt, polyoxyethylene (7) lauryl ether and V / methacrylamide / vinylimidazole copolymer The result is a high-viscosity ring-type solids of approximately 1,500 ps or more, which provides a visually transparent and formulationally differentiated effect, and provides excellent gloss and softness when applied to the hair, and provides the ability to clean and trim the hair. In addition, hair gel wax composition with excellent effect of fresh feeling and washability without hand and hair shine It was confirmed that it can provide, and completed the present invention.

The polyoxyethylene (3) oleyl ether phosphate diethanolamine salt has a pH of 5.5 to 7.5 as measured by a 2% aqueous solution at 25 ℃, it is preferable to use a melting point of 10 to 30 ℃ at 760 mmHg.

The polyoxyethylene (7) lauryl ether is a compound represented by the following formula (1), pH of 5.0 to 7.0, specific gravity of 0.85 to 0.99, molecular weight (Mw) is measured from 1% aqueous solution at 25 ℃ It is better to use 600.

[Formula 1]

CH ₃ (CH ₂ ) ₁₁ CH ₂ (OCH ₂ CH ₂ ) ₇ OH

The VP / methacrylamide / vinylimidazole copolymer (vinyl pyrrolidone / methacrylamide / vinyl imidazole copolymer) is a compound represented by the following Chemical Formula 2, and has a pH of 6 to 8 when measured at 25 ° C. with a 10% aqueous solution. (Mw) is 200,000 to 350,000, the melting point at 760 mmHg is -5 to 10 ° C, it is preferable to use a viscosity (at 23 ° C Brookfield, RVT # 4 to 20 rpm measurement) 700 to 2,000 mPa.s.

(2)

In Formula 2, x, y and z can be inferred through the molecular weight (Mw).

Hair gel wax composition of the present invention consisting of the above components is 2 to 15% by weight of polyoxyethylene (3) oleyl ether phosphate diethanolamine salt and 2 to 15 polyoxyethylene (7) lauryl ether relative to the total weight of the composition It is preferable to include the weight percent.

When the hair gel wax composition of the present invention contains the polyoxyethylene (3) oleyl ether phosphate diethanolamine salt and the polyoxyethylene (7) lauryl ether in the same content as above, it is solidified at 65 ° C. or lower. It is possible. However, when the components are included below the content range, production is possible because they solidify even at a temperature below 60 ° C., but the emulsion form breaks down with time at room temperature, and the viscosity gradually drops and flows like water without ringing. Problems may occur, and when the content exceeds the content range, there is a problem that the production is very difficult because it exists in a solidified state even at a high temperature of 80 ℃ or more.

In addition, even when used in excess of 15% by weight of each of the polyoxyethylene (3) oleyl ether phosphate diethanolamine salt and polyoxyethylene (7) lauryl ether alone, ringing There is a problem that the type of emulsified form is not well formed, and the change of properties occurs after one month passes at a high temperature of 50 ° C., and the feeling of use is very stiff.

More preferably, the hair gel wax composition comprises 6 to 10% by weight of polyoxyethylene (3) oleyl ether phosphate diethanolamine salt, 5.5 to 10% by weight of polyoxyethylene (7) lauryl ether and VP based on the total weight of the composition. / Methaacrylamide / vinylimidazole copolymer containing 0.1 to 4% by weight of a desirable ring (ringing) while giving the hair shine and softness while giving the function to clean and trim the hair and give a fresh feeling have.

In addition to the above components, the hair gel wax composition of the present invention includes oil and vegetable fats and oils such as paraffin wax, squalane, mineral oil, and moisturizing agents, such as propylene glycol and glycerin, which are used in general hair creams in addition to the above components. It can be further used as long as it does not inhibit. In addition, the water phase portion includes a hair protectant such as hydrolyzed protein, animal and vegetable extracts; Metal ion blocking agents such as ethylene glycol tetrasodium acetate; PH adjusters such as citric acid; Preservatives such as para-benzoic acid esters; coloring agent; Flavoring agents may be further included.

As described above, the hair gel wax composition of the present invention provides the characteristics of a solidified formulation having a very high viscosity even when a small amount or no use of a thickener such as an acrylate copolymer, which is a component for increasing the viscosity, when carrying or using a product. There is also the convenience of controlling usage. In addition, the hair wax composition of the present invention is excellent in hair shine and softness even without using wax components such as paraffin wax and beeswax and silicone gum.

Hereinafter, embodiments of the present invention will be described in detail to facilitate understanding of the present invention. However, embodiments according to the present invention can be modified in many different forms, the scope of the invention should not be construed as limited to the following examples. Embodiments of the invention are provided to more fully describe the present invention to those skilled in the art.

Examples 1-6

To the hair gel wax composition of the emulsion form having the components and contents as shown in Table 1 was prepared by the following method.

First, raw materials 2 and 4 were added to a predetermined amount of purified water, dissolved to form an aqueous phase, and then heated to 90 ° C. Then, an oil phase prepared by heating the raw materials 3, 5 to 9 to 90 ° C. was added to the heated water phase and stirred, and then cooled to 80 ° C. Raw materials 10-12 were added thereto and stirred to prepare a final hair gel wax composition.

The unit in Table 1 below is weight percent.

ingredient Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 One Purified water Balance Balance Balance Balance Balance Balance 2 glycerin 2.0 2.0 2.0 2.0 2.0 2.0 3 Mineral oil 8.0 8.0 8.0 8.0 8.0 8.0 4 Propylene glycol 12.5 12.5 12.5 12.5 12.5 12.5 5 Squalane 3.0 3.0 3.0 3.0 3.0 3.0 6 Emulsifiers 1 2.0 2.0 2.0 2.0 2.0 2.0 7 Emulsifiers 2 8.0 8.0 8.0 8.0 8.0 8.0 8 Emulsifiers 3 10 9 9 8 5.5 13 9 Emulsifiers 4 8 5 7 8 8 12 10 Hair dresser 3 3 3 2 2 2 11 Spices 0.4 0.4 0.4 0.4 0.4 0.4 12 antiseptic 0.3 0.3 0.3 0.3 0.3 0.3 Emulsifier 1: ethoxylated / propoxylated cetyl alcohol (Croda)
Emulsifier 2: polyoxyethylene (4) lauryl ether (Dongnam Synthetic Co., Ltd.)
Emulsifier 3: polyoxyethylene (3) oleyl ether phosphate diethanolamine salt (ICID name: Dea Oleth03 phosphate, Croda)
Emulsifier 4: polyoxyethylene (7) lauryl ether of the general formula (1)
Hair dressing agent: VP / methacrylamide / vinylimidazole copolymer of the formula (2)
Preservative: Paraoxybenzoic acid ester

Comparative Examples 1 to 6

To the hair gel wax composition of the emulsion form having the components and contents as shown in Table 2 was prepared by the following method.

First, raw materials 3 and 5 were added to a predetermined amount of purified water, dissolved to form an aqueous phase, and then heated to 90 ° C. Then, an oil phase prepared by heating the raw materials 2, 4, 6 to 13 to 90 ° C. was added to the heated water phase and stirred, and then cooled to 80 ° C. Raw materials 14-16 were added thereto and stirred to prepare a final hair gel wax composition.

The unit in Table 2 below is weight percent.

ingredient Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 One Purified water Balance Balance Balance Balance Balance Balance 2 silicon Balance - - - - 10 3 glycerin - 2.0 2.0 2.0 2.0 2.0 4 Mineral oil 15 8.0 8.0 8.0 8.0 8.0 5 Propylene glycol - 12.5 12.5 12.5 12.5 12.5 6 Squalane 5 3.0 3.0 3.0 3.0 3.0 7 Silicone sword 25 - - - - - 8 Emulsifiers 1 - - - - - 6.0 9 Emulsifiers 2 - - - - - 2.0 10 Emulsifiers 3 - - - 5.0 - - 11 Emulsifiers 4 - 5.0 7.0 12.0 - - 12 Emulsifiers 5 - 7.0 9.0 - 12.0 - 13 Emulsifiers6 - - - - 8.0 - 14 Hair dresser - - - 3.0 - - 15 Spices 0.3 0.4 0.4 0.4 0.4 0.4 16 antiseptic - 0.3 0.3 0.3 0.3 0.3 Emulsifier 1: polyoxyethylene (3) oleyl ether phosphate diethanolamine salt (ICID name: Dea Oleth03 phosphate, Croda)
Emulsifier 2: ethoxylated / propoxylated cetyl alcohol (Croda)
Emulsifier 3: polyoxyethylene (4) lauryl ether (Dongnam Synthetic Co., Ltd.)
Emulsifier 4: Glyceryl Stearate and PEG-100 Stearate (Uniqema)
Emulsifier 5: Polysorbate 60 (Uniqema)
Emulsifier 6: polyoxyethylene (7) lauryl ether of the general formula (1)
Hair dressing agent: VP / methacrylamide / vinylimidazole copolymer of the formula (2)
Preservative: Paraoxybenzoic acid ester

It evaluated as follows using the hair gel wax composition prepared in Examples 1 to 6 and Comparative Examples 1 to 6.

end. Sensory Evaluation of Gloss

After the evaluator took 3 g of each of the hair gel wax compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 6 on the hand and applied it to the hair, the glossiness in the hair was 5 points according to the following evaluation criteria. It evaluated on the perfect scale. After adding each evaluator score, the average value is divided by the number of evaluators (n = 100) and is shown in Table 3 below. Test conditions were a constant temperature and humidity room, 25 ℃, 40% RH.

Evaluation standard 1 point Very poor gloss 2 points Gloss is bad (no gloss before use of test sample) 3 points Gloss is normal (gloss is same before and after using test sample) 4 points Gloss is good (there is gloss than before use of test sample) 5 points Gloss is very good (it is very shiny than before test sample use)

I. Sensory Evaluation of Softness

The evaluator was allowed to apply 3 g of each of the hair gel wax compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 6 to the hair, and then the softness was measured on a five-point scale according to the following evaluation criteria. Evaluated. After adding each evaluator score, the average value is divided by the number of evaluators (n = 100) and is shown in Table 3 below. Test conditions were a constant temperature and humidity room, 25 ℃, 40% RH.

Evaluation standard 1 point Very soft (not very soft than before using the test sample) 2 points Softness (no softness before using test sample) 3 points Softness is normal (smoothness before and after using test sample) 4 points Softness (smooth than before test sample use) 5 points Softness is very good (softer than before test sample)

All. Device evaluation for hairstyling power

The hairs evenly coated with the hair gel waxes prepared in Examples 1 to 6 and Comparative Examples 1 to 6 were wound around a spiral and dried. Curling hairs were placed in a constant temperature and humidity chamber with a temperature of 25 ° C. and a relative humidity of 40% to measure the retention over time (curl retention, CR (%)) as shown in Equation 1 below. It was. The results are shown in Table 3 below.

[Equation 1]

In Equation 1, L _o denotes a hair tress length, L _t denotes a hair tress length after t elapses, and L _s denotes an initial curled hair tress length (t = 0). Albert L. Micchelli, BA, and F. Theodore Koehler, BS "Polymer Properties Influencing Curl Retention at High Humidity" J. Soc. Cosmetic Chemists. 19, 863-880 (Dec 9, 1968).

la. Sensory Evaluation of Freshness

After the evaluator took 3 g of each of the hair gel wax compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 6 on the hand, applied it to the hair and styled it with the fingers, five points of freshness were obtained according to the following evaluation criteria. It evaluated on the perfect scale. After adding each evaluator score, the average value is divided by the number of evaluators (n = 100) and is shown in Table 3 below. Test conditions were a constant temperature and humidity room, 25 ℃, 40% RH.

Evaluation standard 1 point Freshness is very bad (the bleeding is very severe) 2 points Freshness is bad (the bleeding is severe) 3 points Freshness is normal (no difference between before and after using test sample) 4 points Freshness is good (it is natural without bleeding) 5 points Freshness is very good (no flicker, very natural)

hemp. Evaluation of the Ringing Phenomenon

When the hair gel wax composition prepared in Examples 1 to 6 and Comparative Examples 1 to 6 was touched with a finger and a ringing was felt (○) and when there was no vibration (×), the results were evaluated. Table 3 shows.

As shown in Table 3 above, the polyoxyethylene (3) oleyl ether phosphate diethanolamine salt, the polyoxyethylene (7) lauryl ether and V / methacrylamide / vinylimidazole copolymer In the case of the hair gel wax compositions of Examples 1 to 6, which contained all, it was confirmed that the gloss, softness, hairstyling power, and freshness of the hair were excellent overall while having a ringing phenomenon.

On the other hand, Comparative Examples 1 to 6, which are conventional gel wax compositions, show not only ringing at all, but also a general drop in hair gloss, softness, hairstyling power, and freshness compared to Examples 1 to 6. And it was found.

The hair gel wax composition according to the present invention is excellent in the effect of arranging and arranging the hair while giving gloss and softness to the hair, and can provide a fresh feeling without grease in the hands and hair, as well as being transparent and fingers. When tapping, it has a physical characteristic that makes it feel a vibration.

Claims (8)

In the hair gel wax composition, Polyoxyethylene (3) oleyl ether phosphate diethanolamine salts; Polyoxyethylene (7) lauryl ether; And A hair gel wax composition comprising a VP / methacrylamide / vinylimidazole copolymer (VP / methacrylamide / vinyl imidazole copolymer). delete The method of claim 1, The composition may comprise at least one < RTI ID = 2 to 15 weight percent polyoxyethylene (3) oleyl ether phosphate diethanolamine salt; And 2 to 15% by weight of polyoxyethylene (7) lauryl ether; hair gel wax composition comprising a. The method of claim 1, The composition may comprise at least one < RTI ID = 6 to 10 weight percent polyoxyethylene (3) oleyl ether phosphate diethanolamine salt; 5.5 to 10 weight percent polyoxyethylene (7) lauryl ether; And 0.1 wt% to 4 wt% of VP / methacrylamide / vinylimidazole copolymer; hair gel wax composition comprising a. The method of claim 1, The polyoxyethylene (3) oleyl ether phosphate diethanolamine salt has a pH of 5.5 to 7.5 as measured by 2% aqueous solution at 25 ℃, hair gel wax, characterized in that the melting point of 10 to 30 ℃ at 760 mmHg Composition. The method of claim 1, The polyoxyethylene (7) lauryl ether has a pH of 5.0 to 7.0, a specific gravity of 0.85 to 0.99, and a molecular weight (Mw) of 400 to 600 as measured by a 1% aqueous solution at 25 ° C. Composition. The method of claim 1, The VP / methacrylamide / vinylimidazole copolymer has a pH of 6 to 8, a molecular weight (Mw) of 200,000 to 350,000, and a melting point of -5 to 10 at 760 mmHg as measured by a 10% aqueous solution at 25 ° C. And a viscosity (at 23 ° C. Brookfield, measured at RVT # 4 to 20 rpm) of 700 to 2,000 mPa · s. The method of claim 1, The composition is a hair gel wax composition, characterized in that it further comprises any one or more additives selected from the group consisting of mineral copper, vegetable oils, moisturizers, hair protectors, metal ion sequestrants, pH adjusting agents, preservatives, colorants and flavoring agents.