KR101317565B1 - Method for saving energy in aromatic compounds separation from naphtha - Google Patents

Abstract

The present invention is to process and remove the desorbent material from the raffinate after carrying out the adsorptive separation of the para-xylene from the xylene mixture in the aromatic compound treatment process of treating the raw material naphtha to para-xylene and benzene as the main final product Waste heat is recovered from the raffinate column top condenser to recover the energy by supplying it to the preheating butane separation column raw material of the platform forming process and / or the reboiler heat source of the NHT process stripper.

Description

Energy saving method in the separation process of aromatic compounds using waste heat {METHOD FOR SAVING ENERGY IN AROMATIC COMPOUNDS SEPARATION FROM NAPHTHA}

The present invention treats naphtha, a raw material, to produce para-xylene (PX) and benzene (benzene: BZ) in an aromatic compound treatment process. After the adsorptive separation, the waste heat is recovered from the upper condenser of the raffinate column for separating and recovering the desorbent material from the raffinate, which is then pre-heated and / or NHT debutanizer raw material in the forming process. (Naphtha Hydrotreating) Process of energy saving by supplying to the reboiler heat source of process stripper.

In the petrochemical industry, commercial use of distillation columns is well known, and the operating principles and operating examples of commonly used distillation columns are well described by way of example in the following literature: H.Z. Kister, "Distllation-Operation," McGraw Hill, Nt, 1990; H.Z. Kister, "Distllation-Design," McGraw Hill, NY, 1992; And J.D. Seader and E. J. Henley, "Separation Process Principles," 2nd ed., Wiley, NY, 2006.

Aromatic compound treatment process (hereinafter also referred to as "aromatic process") is a process in which petrochemical plants process naphtha, a raw material, using para-xylene and benzene as main end products. In the conventional aromatic process, the main process in which the mixed xylene is produced containing para-xylene (PX), which is one of the main products, is a reformer, xylene isomerization process and 7 carbon atoms and carbon atoms Three processes of transalkylation and disproportionation of nine aromatic compounds.

Commercially used para-xylene separation processes include a simulated moving bed (SMB) process and a crystallization method, and the PMB separation process using the SMB method is performed at each stage of a multistage adsorption tower. By periodically controlling the opening and closing of the valve to be positioned, the effect is as if the adsorbent and the fluid is in countercurrent contact, effectively separating the xylene isomer, a representative example is UOP's Parex process have.

Description of this conventional Parex process is well described in Korean Patent Registration No. 10-0741752. In the Parex process, a distillation column such as an extraction column and a raffinate column is used to separate and recover the desorbent material from the xylene column which performs the adsorptive separation of PX and then the extract and raffinate streams.

A typical conventional aromatic compound treatment process is shown in FIGS. 1, 2 and 3.

According to FIG. 1, the mixture (reformer) of the raw aromatic compound injected from the reformer 1 into the splitter 2 is a mixture containing 6 aromatic compounds and 7 carbon atoms, that is, a mixture containing benzene and toluene, and heavier. Separated into aromatic mixtures (such as xylene having 8 carbon atoms), the former is introduced via line 21 into the SULFOLANE process (3), which is a benzene-toluene fractionation process and a non-aromatic removal process. It is fed to xylene column 5 via line 22. In the sulfolane process, a mixture of benzene and toluene is separated into benzene and toluene, respectively, where benzene is discharged via line 33, and toluene (TOL) is aromatic via toluene and carbon 9 aromatics via line 31. It is fed to TATORAY process (4) which is a compound disproportionation and transalkylation process. In the xylene column 5, aromatic compounds having 9 or more carbon atoms are discharged through the line 52 to the heavy aromatic column 6, and the xylene mixture having 8 carbon atoms is discharged through the line 51 to form para-xyl. It is injected into the PAREX process (8) which is a lene separation process. The xylene mixture introduced into the PAREX process 8 via line 51 is separated into para-xylene and the remaining xylene mixture, the former being discharged through line 81, the latter through line 82 It is injected into the ISOMAR process (9) which is a xylene isomerization process. The output of the ISOMAR process 9 is withdrawn via line 91 and re-introduced to the xylene column 5. The mixture of aromatic compounds having at least 9 carbon atoms fed to the heavy aromatic column (6) via line (52) is composed of aromatic compounds (A9) having at least 9 carbon atoms containing trimethylbenzene and aromatic compounds having at least 10 carbon atoms (A10 +) in the heavy aromatic column (6). ), The former is introduced via line 61 into the TATORAY process 4, which is a disproportionation and transalkylation process of toluene and an aromatic compound having 9 carbon atoms, and the latter is discharged through line 62. The aromatic compound having 9 carbon atoms introduced into the TATORAY process (4) contains para-xylene by transalkylation reaction with toluene introduced through the line 31 from the sulfolane process (3) in the TATORAY process (4). The resulting mixture is produced, and the resulting mixture is reintroduced into xylene column 5 via line 71.

Referring to FIG. 2, which is a schematic diagram of another embodiment of the aromatic compound treatment process, the process shown in FIG. 2 is a case where the TATORAY process in the process of FIG. 1 is replaced by a PX-Plus process and a TAC9 process. Same as the process, but different from FIG. 1 in the following matters. Toluene (TOL) separated in the sulfolane process is introduced into the PX-Plus process (4), which is a selective disproportionation process of toluene, and the TAC9 process (7), which is a transalkylation process, through the line 31, and the PX- Mixtures resulting from the selective disproportionation in Plus process (4) include aromatic compounds (A9) having 9 carbon atoms, such as benzene (A6), toluene (A7), xylene (A8) and trimethylbenzene, Among them, para-xylene is included in the xylene mixture in an amount of about 85 to 95% by weight. The resulting mixture of this PX-Plus process (4) is reintroduced to the SULFOLANE process (3) via line 41, where x8 carbon atoms and heavier trimethylbenzene are lighter components. After being separated from, it is discharged via line 32 and fed to xylene column 5 via line 22. Aromatic compound (A9) having 9 carbon atoms including trimethylbenzene separated in heavy aromatic column (6) is fed via line (61) to TAC9 process (7) which is a transalkylation process. The aromatic compound having 9 carbon atoms introduced into the TAC9 process (7) contains para-xylene by transalkylation reaction with toluene introduced through the line (31) from the sulfolane process (3) in the TAC9 process (7). The resulting mixture is produced, and the resulting mixture is reintroduced into xylene column 5 via line 71.

Referring to FIG. 3, which is a schematic diagram of another embodiment of the aromatic compound treatment process, the process shown in FIG. 3 is a case where the crystallization process is installed in the process of FIG. 2, and is basically the same as the process of FIG. 2. Xylene and heavier trimethylbenzene, etc. having 8 carbon atoms discharged from the process (3) are introduced into the crystallization process (10) via the line 32, and in this crystallization process (10), the input mixture is para-xylene and para. The process of FIG. 2 only after being separated into a xylene mixture other than xylene, the former is discharged through line 101 and the latter is discharged through line 102 and introduced into xylene column 5 There is a difference.

In the existing process as described above, there is a platform forming process, which is a reaction process (corresponding to the reformer of FIGS. 1 and 2) for converting raw naphtha into an aromatic component as a shearing process, and a component causing corrosion and catalyst deactivation in a post-stage process (Sulfur, Nitrogen, etc.) is a process for removing hydrogen through hydrogenation, which is a preheating butane separation column raw material of the existing platform forming process and a reboiler heat source of the NHT process stripper. However, in terms of energy savings, there is room for improvement that can further enhance energy savings.

It is an object of the present invention to recover waste heat from a raffinate column top condenser for separating and recovering desorbent material from raffinate during the aromatics separation process, thereby preheating the butane separation column raw material and / or retreat of NHT process stripper. By supplying the boiler heat source, it is intended to significantly reduce energy by reducing the amount of use of middle pressure steam (MS) and C4LPG, which are used as heat sources in the conventional aromatic compound separation process.

According to the present invention, in the process for treating an aromatic compound including para-xylene and benzene as main end products by treating naphtha as a raw material, which includes the use of xylene column, extraction column and raffinate column, After the para-xylene adsorption separation, waste heat is recovered from the upper condenser of the raffinate column for separating and recovering the desorbent material from the raffinate. Supplying a heat source provides an energy saving method in the aromatic compound separation process.

A distillation column (column) is generally a column for gas-liquid contact, a reboiler that boils a liquid flowing down the column, vaporizes a portion of it and returns it to the inside of the column, and condenses all or a part of the gas discharged from the column top again. It consists of a condenser that returns a portion back into the distillation column.

As a heat source for preheating the raw material for the butane separation column of the conventional platform, medium pressure steam, which is usually steam of about 17 kg / cm ² g, is mainly used. The present invention can reduce the use of the existing medium pressure steam and C4LPG by recovering the waste heat from the upper condenser in the raffinate column as a heat source as described above.

In general, the temperature / pressure conditions on the upper part of the raffinate column are difficult to use as a reboiler heat source in a general BTX process, but the high temperature bottom stream used in the raw material preheating of the butane separation column of the platform forming process is used. It has been achieved by the present invention to reduce the energy (medium pressure steam: MPS) usage of the reboiler by using it as a reboiler heat source of the NHT process stripper.

According to the present invention, the waste heat from the upper condenser of the raffinate column is recovered and supplied to the reboiler heat source of the butane separation column raw material of the platform forming process and the reboiler heat source of the NHT process stripper, thereby saving energy significantly compared to the conventional aromatic compound separation process. Can be improved.

1 is a schematic of a typical aromatics treatment process.
2 is a schematic diagram of another exemplary aromatic compound treatment process.
3 is a schematic diagram of another exemplary aromatic compound treatment process.
4 is a schematic diagram of one embodiment of an improved aromatics treatment process according to the present invention.
5 is a schematic diagram of an embodiment of a conventional aromatic compound treatment process.

Hereinafter, the present invention will be described in more detail with reference to Examples, but the scope of the present invention is not limited by these Examples.

Example

In this embodiment, the energy saving method in the aromatic compound separation process according to the present invention was realized through the heat exchanger three new heat exchangers (EA 137, EA 220, EA 221) with reference to FIG.

As shown in FIG. 4, the upper condenser of the raffinate column (DA-701) was operated at 157 ° C., and the upper waste heat was respectively preformed in the forming process butane separation column raw material preheating (EA-510 and EA-504) and the NHT process stripper. Boiler (EA-420) was supplied as a heat source.

By operating in this way, energy savings of 3.6MMKcal / hr can be saved annually compared to the use of C4LPG, which is used as a heat source for preheating debutulization of the platform forming process and C4LPG, which is used as a heat source for NHT process stripper reboilers. In this regard, energy savings of W8.9bn per year were achieved.

Comparative Example

In the existing method as shown in FIG. 5, MS is supplied to the preheating heat source of the butane separation column raw material of the platform forming process, and C4LPG is supplied to the NHT process stripper reboiler heat source, and energy saving is not achieved as in the example.

SULFOLANE: Benzene-toluene fractionation process and non-aromatic removal process
TATORAY: Disproportionation and transalkylation process of toluene and aromatic compound having 9 carbon atoms
PAREX: Para-Xylene Separation Process
ISOMAR: Xylene Isomerization Process
PX-Plus: Selective Disproportionation Process of Toluene
TAC9: transalkylation process of aromatic compound having 9 carbon atoms
A6: aromatic compound having 6 carbon atoms
A7: aromatic compound having 7 carbon atoms
A8: aromatic compound having 8 carbon atoms
A9: aromatic compound having 9 carbon atoms
A10 +: aromatic compound having 10 or more carbon atoms
BA 103: DA-103 Column Reboiler Heater
DA 103: Stripper of Naphtha Hydrotreating Process
DA 201: Butane Separation Column in Platform Forming Process
DA 601: column for separating aromatic hydrocarbons having 7 or more carbon atoms from the reactants of the platform (reformate splitter)
EA-137, EA-138, EA-204, EA-205, EA-220, and EA-221: Heat Exchanger
EC-601: Reformatted Splitter Column Condenser

Claims (3)

Aromatic compounds, including benzene, toluene and xylene (BTX) from naphtha, including the use of xylene columns, extraction columns, raffinate columns, butane separation columns, and naphtha hydrogenated (NHT) sulfolane process strippers. When the separation process is carried out, the waste heat is recovered from the upper condenser of the raffinate column, and the separation of the aromatic compound, which is supplied as a reboiler heat source of the raw material preheating heat source and naphtha hydrogenated sulfolane process stripper of the platform forming process butane separation column. How to save energy in the process. delete delete

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