KR101304188B1

KR101304188B1 - Carbon-ceramic brake disc and method for manufacturing the same

Info

Publication number: KR101304188B1
Application number: KR1020100119415A
Authority: KR
Inventors: 강정석; 신현규; 최연호; 이준상; 조채욱; 임동원; 채병근; 최문수
Original assignee: 주식회사 데크
Priority date: 2010-11-29
Filing date: 2010-11-29
Publication date: 2013-09-05
Also published as: WO2012074260A2; WO2012074260A3; KR20120057879A

Abstract

The method of making the carbon-ceramic brake disc of the present invention comprises: a first step of mixing a carbon fiber and a phenol resin to form a mixture; Inserting the mixture into a mold and pressing to form a first molded body, and putting the mixture into a mold and pressing to form a second molded body; A third step of carbonizing the first molded body and carbonizing the second molded body; A fourth step of machining the carbonized first molded body and machining the carbonized second molded body; A fifth step of adhering the machined first molded body and the machined second molded body to each other; A sixth step of dissolving silicon in the first molded body and the second molded body bonded to each other; And a seventh step of grinding the first molded body and the second molded body in which the silicon has penetrated.
With the present invention, the bonding force between the friction layer and the support layer is increased, so that the friction layer does not fall off from the support layer during brake operation. Thus, the braking performance of the carbon-ceramic brake disc is maintained continuously. In addition, since the friction layer is separated from the support layer, vibration and noise caused by irregular contact between the pad and the friction layer can be prevented. In addition, the support layer is prevented from being exposed to the outside and oxidized.

Description

CARBON-CERAMIC BRAKE DISC AND METHOD FOR MANUFACTURING THE SAME}

The present invention relates to a carbon-ceramic brake disc.

Automobile brakes are divided into drum brakes and disc brakes.

Disc brakes slow or stop the rotation of the disc by the frictional force generated by the friction between the surface of the disc and the pad, thereby slowing down or stopping the vehicle.

Discs with good braking force should be light in weight, have high thermal shock resistance, high oxidation resistance, high wear resistance, high strength, and high coefficient of friction. To this end, in recent years, discs are made of carbon fiber reinforced ceramic composites.

Carbon fiber reinforced ceramic composites are materials in which the matrix is ceramic and reinforced with carbon fibers.

Hereinafter, a brake disc made of a carbon fiber reinforced ceramic composite will be referred to as a carbon-ceramic brake disc.

In general, a carbon-ceramic brake disc is composed of a support layer and a friction layer bonded to the upper and lower surfaces of the support layer.

During brake operation, the friction layer is in frictional contact with the pad, and the support layer supports the friction layer to absorb shocks.

In general, the friction layer has a component composition of at least 75 wt% of SiC, at most 25 wt% of Si, and at most 0.5 wt% of C, in order to have excellent friction performance and oxidation resistance.

The support layer has a component composition of SiC 30-50 wt%, Si 25 wt% or less, and C 30-50 wt% in order to have ductility.

Since the difference in the composition of the friction layer and the composition of the support layer is large, the difference in the coefficient of thermal expansion of the friction layer and that of the support layer becomes large. This causes cracks in the friction layer in the process of making the carbon-ceramic brake discs (especially in the cooling stage).

If a crack occurs in the friction layer, the bonding force between the friction layer and the support layer is weakened, so that the friction layer may fall out of the support layer during brake operation. When the friction layer is separated from the support layer, the pads are in irregular friction contact with the friction layer.

As a result, the braking performance of the carbon-ceramic brake disc is reduced, and vibration and noise are generated. In addition, the support layer is oxidized by being exposed to the outside.

SUMMARY OF THE INVENTION An object of the present invention is to provide a carbon-ceramic brake disc having a high bonding force between a friction layer and a support layer and a method of making the same.

A method of making a carbon-ceramic brake disc for achieving the above object comprises: a first step of mixing a carbon fiber and a phenol resin to form a mixture; Inserting the mixture into a mold and pressing to form a first molded body, and putting the mixture into a mold and pressing to form a second molded body; A third step of carbonizing the first molded body and carbonizing the second molded body; A fourth step of machining the carbonized first molded body and machining the carbonized second molded body; A fifth step of adhering the machined first molded body and the machined second molded body to each other; A sixth step of dissolving silicon in the first molded body and the second molded body bonded to each other; And a seventh step of grinding the first molded body and the second molded body in which the silicon has penetrated.

In addition, the above object, a support layer; A friction layer bonded to upper and lower surfaces of the support layer, respectively; And an adhesive layer formed between the support layer and the friction layer, wherein the support layer and the friction layer are achieved by a carbon-ceramic brake disc having the same composition.

In the present invention, since the composition of the friction layer and the composition of the support layer are the same, no cracking occurs in the friction layer during the process of making the carbon-ceramic brake disc. This increases the bonding force between the friction layer and the support layer, so that the friction layer does not fall off from the support layer during brake operation. Thus, the braking performance of the carbon-ceramic brake disc is maintained continuously. In addition, since the friction layer is separated from the support layer, vibration and noise caused by irregular contact between the pad and the friction layer can be prevented. In addition, the support layer is prevented from being exposed to the outside and oxidized.

In addition, the present invention can make the composition of the adhesive layer the same as the composition of the friction layer and the support layer. As a result, in the process of making the carbon-ceramic brake disc, fine cracks do not occur in the adhesive layer, and thus the bonding force between the friction layer and the support layer can be further increased.

1 is a flow chart illustrating a method of making a carbon-ceramic brake disc according to an embodiment of the present invention.
FIG.2 (a), (b), (c) is a figure which shows the procedure which makes a 1st molded object.
Fig.3 (a), (b), (c) is a figure which shows the procedure which makes a 2nd molded object.
FIG. 4 is a view showing a state in which the first molded body and the second molded body are adhered to a phenol resin mixed with graphite powder.
FIG. 5 is an enlarged view of a portion A of FIG. 4.
FIG. 6 is a view showing a state in which the first molded body and the second molded body are bonded with a phenol resin mixed with graphite powder and short carbon fiber, and the bonded portion is enlarged as shown in FIG. 5.
FIG. 7 is a view showing a state in which the first molded body and the second molded body are bonded to a phenol resin in which graphite powder and pulverized carbon fibers are mixed, and the bonded part is enlarged as shown in FIG. 5.
8 is a view showing a carbon-ceramic brake disc made by a method of making a carbon-ceramic brake disc according to an embodiment of the present invention.

Hereinafter, a method of making a carbon-ceramic brake disc according to an embodiment of the present invention will be described.

1 is a flow chart illustrating a method of making a carbon-ceramic brake disc according to an embodiment of the present invention. FIG.2 (a), (b), (c) is a figure which shows the procedure which makes a 1st molded object. Fig.3 (a), (b), (c) is a figure which shows the procedure which makes a 2nd molded object. The solid arrow shown in FIG. 2 or FIG. 3 shows the moving direction of the press, and the dotted arrow shows the direction in which the first molded body or the second molded body is taken out of the mold.

As shown in Figures 1, 2 (a), (b), (c), 3 (a), (b) and (c), a carbon-ceramic brake disc according to an embodiment of the present invention is How to make,

First step (S11) of mixing the carbon fiber and phenol resin to make a mixture (X); The mixture (X) is placed in a mold (M) and pressed with a press (P) to make a first molded body (Y1), and the mixture (X) is put into a mold (M) and pressed with a press (P) to a second molded body. A second step S12 of making Y2; A third step (S13) of carbonizing the first molded body (Y1) and carbonizing the second molded body (Y2); A fourth step (S14) of machining the carbonized first molded body (Y1) and machining the carbonized second molded body (Y2); A fifth step (S15) of adhering the machined first molded body (Y1) and the machined second molded body (Y2) to each other; A sixth step (S16) of dissolving silicon in the first molded body (Y1) and the second molded body (Y2) adhered to each other; And a seventh step (S17) of grinding the first molded body (Y1) and the second molded body (Y2) in which the silicon has penetrated.

The first step S11 will be described below.

30 to 70 vol% of carbon fiber and 70 to 30 vol% of phenol resin are mixed to form a mixture (X). The mixture (X) forms a support layer and a friction layer which will be described later. Since the support layer and the friction layer are made of the mixture X having the same composition, the composition of the support layer and the composition of the friction layer are the same.

The second step S12 will be described below.

As shown in Fig. 2 (a), the mixture (X) is put into the mold (M).

The core (V) is placed on the mixture (X). The core body V has the shape of a cooling channel. The mixture (X) is put on the core body (V).

As shown in FIG. 2 (b), the first molded body Y1 is formed by pressing the press P. FIG. At this time, the pressure to pressurize is 3-5 MPa. Here, the mixture X can also be heated by the heater provided in the press P. The temperature to heat is 120-180 degreeC.

As shown in FIG. 2 (c), the first molded object Y1 is taken out of the mold M. As shown in FIG.

The first molded product Y1 is composed of carbon fibers randomly distributed in the cured phenolic resin.

As shown in FIG. 3 (a), the mixture X is placed in the mold M.

As shown in FIG. 3 (b), the mixture X is pressurized with a press P to form a second molded body Y2. At this time, the pressure to pressurize is 3-5 MPa. Here, the mixture X can also be heated by the heater provided in the press P. The temperature to heat is 120-180 degreeC.

As shown in FIG. 3 (c), the second molded body Y2 is taken out of the mold M.

The second molded body (Y2) is composed of carbon fibers randomly distributed in the cured phenolic resin.

The third step S13 will be described below.

The first molded body Y1 is placed in a crucible. Put the crucible into the vacuum resistance furnace. It is either a vacuum atmosphere or an inert atmosphere in a vacuum resistance heating furnace.

In vacuum resistance heating, the temperature of the 1st molded object Y1 is heated up to 1550 degreeC for 13 hours. In vacuum resistance heating, the temperature of the 1st molded object Y1 is maintained at 1550 degreeC for 1-2 hours. While the temperature of the first molded product Y1 is elevated and maintained at 1550 ° C., the organic compound contained in the first molded product Y1 is thermally decomposed to become carbon. The organic compound is thermally decomposed and porosity is formed in the remaining position.

When carbonizing the first molded body Y1, the core body V is pyrolyzed. The amount of residual carbon upon thermal decomposition of the core body (V) is preferably less than 10 wt%. To this end, the core body (V) is made of a thermoplastic resin such as polycarbonate, ABS resin (Acrylonitrile Butadiene Styrene copolymer), styrene resin, polyethylene, acrylic resin and the like. When the core body V is thermally decomposed, the core body V is pyrolyzed and cooling channels are formed in the remaining empty space.

Put the second molding (Y2) in the crucible. Put the crucible into the vacuum resistance furnace. It is either a vacuum atmosphere or an inert atmosphere in a vacuum resistance heating furnace.

In vacuum resistance heating, the temperature of the 2nd molded object Y2 is heated up to 1550 degreeC for 13 hours. In the vacuum resistance heating furnace, the temperature of the second molded body Y2 is maintained at 1550 ° C. for 1 to 2 hours. While the temperature of the second molded body Y2 is maintained at 1550 ° C., the organic compound contained in the second molded body Y2 is thermally decomposed to become carbon. The organic compound is thermally decomposed and porosity is formed in the remaining position.

The fourth step S14 will be described below.

The axle passes through the shaft hole in the center of the first molded body (Y1) and the second molded body (Y2).

The through-holes through which bolts coupled to the hat parts pass through the axial holes of the first molded body Y1 and the second molded body Y2 are drilled at the same interval on the same circle. The hat part is combined with the wheels.

Hereinafter, a fifth step S15 will be described.

FIG. 4 is a view showing a state in which the first molded body and the second molded body are adhered to a phenol resin mixed with graphite powder. FIG. 5 is an enlarged view of a portion A of FIG. 4.

The first molded product Y1 and the second molded product Y2 are bonded to the phenol resin Pn mixed with the graphite powder Gp.

As shown in FIGS. 4 and 5, when the first molded object Y1 and the second molded object Y2 are adhered to each other, an adhesive layer to be described later is formed between the first molded object Y1 and the second molded object Y2.

The vol% of the phenol resin and the vol% of the graphite powder are adjusted to make the composition of the adhesive layer the same as that of the support layer and the friction layer. To this end, 70 to 30 vol% of the phenol resin and 30 to 70 vol% of the graphite powder are mixed. Then, the component composition of the adhesive layer becomes SiC 65-25 wt%, Si 15-25 wt%, C 20-50 wt%, which is the same as the component composition of the support layer and the friction layer.

On the other hand, the phenol resin mixed with the graphite powder may be in a liquid state or a solid state.

First, a method of adhering the first molded object Y1 and the second molded object Y2 with a liquid phenol resin in which graphite powder is mixed will be described.

A phenolic resin in a liquid state in which graphite powder is mixed is applied to the upper and lower surfaces of the first molded body Y1. Coating thickness is 0.1 ~ 2mm. The second molded object Y2 is adhered to the upper and lower surfaces of the first molded object Y1. The phenolic resin in the liquid state in which the graphite powder exited between the first molded object Y1 and the second molded object Y2 is mixed is removed.

Next, a method of adhering the first molded object Y1 and the second molded object Y2 with a phenolic resin in a solid state in which graphite powder is mixed will be described.

The phenolic resin of the solid state which mixed graphite powder is sprayed on the upper surface and lower surface of the 1st molded object Y1. The second molded body Y2 is placed on the upper and lower surfaces of the first molded body Y1, respectively, and is pressed by a press and heated by a heater installed in the press. As the phenolic resin in the solid state mixed with the graphite powder is melted, the second molded body Y2 is adhered to the upper and lower surfaces of the first molded object Y1. The phenol resin in the liquid state (the state in which the phenol resin is dissolved in the solid state) in which the graphite powder exited between the first molded body Y1 and the second molded object Y2 is mixed is removed.

FIG. 6 is a view showing a state in which the first molded body and the second molded body are bonded with a phenol resin mixed with graphite powder and short carbon fiber, and the bonded portion is enlarged as shown in FIG. 5.

As shown in FIG. 6, the first molded product Y1 and the second molded product Y2 may be bonded with a phenol resin (Pn) mixed with graphite powder (Gp) and short carbon fiber (Cf-s). have. In this case, not only the vol% of the phenol resin and the vol% of the graphite powder, but also the vol% of the short carbon fiber can be adjusted to make the composition of the adhesive layer more easily identical to that of the support layer and the friction layer. Short carbon fiber length is 1 ~ 3mm.

70-30 vol% of phenol resin, 15-35 vol% of graphite powder, and 15-35 vol% of short carbon fiber are mixed. Then, the component composition of the adhesive layer becomes SiC 65-25 wt%, Si 15-25 wt%, C 20-50 wt%, which is the same as the component composition of the support layer and the friction layer.

When the phenolic resin mixed with graphite powder and short carbon fiber is in liquid or solid state, the first molding (Y1) and the second molding (Y2) are bonded to each other. Since it is the same as the method of adhering the 1st molded object Y1 and the 2nd molded object Y2 in a state, the description is abbreviate | omitted.

FIG. 7 is a view showing a state in which the first molded body and the second molded body are bonded to a phenol resin in which graphite powder and pulverized carbon fibers are mixed, and the bonded part is enlarged as shown in FIG. 5. As shown in FIG. 7, the first molded product Y1 and the second molded product Y2 may be bonded with a phenol resin (Pn) mixed with graphite powder (Gp) and pulverized carbon fibers (Cf-m). .

In this case, not only the vol% of the phenol resin and the vol% of the graphite powder, but also the vol% of the pulverized carbon fibers can be adjusted to make the composition of the support layer and the friction layer and the composition of the adhesive layer the same. The diameter of the pulverized carbon fiber is 0.01 ~ 0.1mm.

70-30 vol% phenol resin, 15-35 vol% graphite powder, and 15-35 vol% pulverized carbon fiber are mixed. Then, the component composition of the adhesive layer becomes SiC 65-25 wt%, Si 15-25 wt%, C 20-50 wt%, which is the same as the component composition of the support layer and the friction layer.

When the phenolic resin mixed with graphite powder and pulverized carbon fiber is in a liquid or solid state, the first molding (Y1) and the second molding (Y2) are bonded to each other in a liquid or solid state. In this case, since it is the same as the method of adhering the first molded body Y1 and the second molded body Y2, the description thereof is omitted.

The sixth step S16 will be described below.

Put the silicon in the crucible.

The first molded body (Y1) and the second molded body (Y2) bonded to each other in the crucible are put in silicon.

Put the crucible into the vacuum resistance furnace. It is either a vacuum atmosphere or an inert atmosphere in a vacuum resistance heating furnace.

In vacuum resistance heating, the temperature of the 1st molded object Y1 and the 2nd molded object Y2 is raised to 1550 degreeC for 13 hours. In vacuum resistance heating, the temperature of the 1st molded object Y1 and the 2nd molded object Y2 is kept at 1550 degreeC for 1-2 hours.

While the temperature of the first molded product Y1 and the second molded product Y2 is elevated and maintained at 1550 ° C., the silicon melts and penetrates into pores of the first molded product Y1 and the second molded product Y2.

Most of the silicon infiltrated into the pores reacts with the carbon contained in the first molded object Y1 and the second molded object Y2 to form silicon carbide (SiC). The remaining silicon that does not react with carbon fills the pores. In addition, the silicon penetrated into the pores reacts with the carbon in the bonding portion between the first molded body Y1 and the second molded body Y2 to become silicon carbide, and the remaining silicon not reacted with the carbon remains in the bonded part.
When the sixth step S17 is completed, the first molded body Y1 becomes the support layer 110 (see FIG. 8), the second molded body Y2 becomes the friction layer 120 (see FIG. 8), and the first molded body The adhesive part between Y1 and the second molded object Y2 becomes an adhesive layer 130 (see FIG. 8).

The seventh step S17 will be described below.

The first molded object Y1 and the second molded object Y2 are polished by a grinder.

8 is a view showing a carbon-ceramic brake disc made by a method of making a carbon-ceramic brake disc according to an embodiment of the present invention.

As shown in FIG. 8, the carbon-ceramic brake disc 100 produced by the method of manufacturing the carbon-ceramic brake disc according to the embodiment of the present invention may include a support layer 110, a friction layer 120, and an adhesive layer 130. It is composed of

The carbon-ceramic brake disc 100 has a shaft hole 101 through which the axle passes. Around the shaft hole 101, through-holes 102 through which bolts coupled with hat parts pass, are provided at the same interval on the same circle.

The support layer 110 has a cooling channel 111. The thickness of the support layer 110 is 20-50 mm. The composition of the support layer 110 is SiC 65-25 wt%, Si 15-25 wt%, C 20-50 wt%. In the support layer 110, carbon fibers are randomly distributed. The carbon fiber is composed of a bundle of filament 1K to 48K having a diameter of 7 µm. Carbon fiber is 25 ~ 30mm long.

The thickness of the friction layer 120 is 0.1 ~ 2mm. The composition of the friction layer 120 is the same as the composition of the support layer 110, SiC 65-25 wt%, Si 15-25 wt%, C 20-50 wt%. In the friction layer 120, carbon fibers are randomly distributed. The carbon fiber is composed of a bundle of filament 1K to 48K having a diameter of 7 µm. The length of carbon fiber is 1-3mm.

Since the composition of the support layer 110 and the composition of the friction layer 120 are the same, the coefficient of thermal expansion of the support layer 110 and the coefficient of thermal expansion of the friction layer 120 are the same. Therefore, in the process of making the carbon-ceramic brake disc 100, cracks do not occur in the friction layer 120 due to a difference between the thermal expansion coefficient of the support layer 110 and the thermal expansion coefficient of the friction layer 120.

On the other hand, even if the composition of the support layer 110 and the composition of the friction layer 120 is the same, as a result of the experiment, the friction performance and the oxidation resistance of the friction layer 120 was not significantly lower than the conventional. In addition, the ductility of the support layer 120 is also not significantly lowered than in the prior art.

The thickness of the adhesive layer 130 is 0.05-1 mm. The composition of the adhesive layer 130 is SiC 65-25 wt%, Si 15-25 wt%, C 20-50 wt% the same as the composition of the friction layer 120 and the support layer 110.

Since the composition of the adhesive layer 130 is the same as that of the support layer 110 and that of the friction layer 120, the coefficient of thermal expansion of the adhesive layer 130 may be determined by the coefficient of thermal expansion of the support layer 110 and the friction layer 120. It is the same as the coefficient of thermal expansion. Therefore, in the process of making the carbon-ceramic brake disc, minute cracks do not occur in the adhesive layer 130.

The reason why the crack formed in the adhesive layer 130 is referred to as "fine crack" is that the thickness of the adhesive layer 130 (0.05 to 1 mm) is smaller than the thickness of the friction layer 120 (0.1 to 2 mm). This is because the cracks generated in the friction layer 120 are relatively smaller than the cracks generated in the friction layer 120.

Claims

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A first step of mixing a 30 to 70 vol% carbon fiber and 70 to 30 vol% phenol resin to form a mixture;
Inserting the mixture into a mold and pressing to form a first molded body, and putting the mixture into a mold and pressing to form a second molded body;
A third step of carbonizing the first molded body and carbonizing the second molded body;
A fourth step of machining the carbonized first molded body and machining the carbonized second molded body;
A fifth step of adhering the machined first molded body and the machined second molded body to each other;
Melting and infiltrating silicon into the first molded body and the second molded body bonded to each other to make the first molded body into a support layer, the second molded body into a friction layer, and the adhesive portion between the first molded body and the second molded body A sixth step of making an adhesive layer; And
And a seventh step of grinding the first molded body and the second molded body in which the silicon has penetrated.
In the fifth step, by bonding the machined first molded body and the machined second molded body in a mixture of 70 ~ 30 vol% phenol resin and 30 ~ 70 vol% graphite powder,
After the sixth step is completed, a carbon-ceramic brake disc is made to make the composition of the support layer, the friction layer and the adhesive layer equal to SiC 65-25 wt%, Si 15-25 wt%, C 20-50 wt%. Way.

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A first step of mixing a 30 to 70 vol% carbon fiber and 70 to 30 vol% phenol resin to form a mixture;
Inserting the mixture into a mold and pressing to form a first molded body, and putting the mixture into a mold and pressing to form a second molded body;
A third step of carbonizing the first molded body and carbonizing the second molded body;
A fourth step of machining the carbonized first molded body and machining the carbonized second molded body;
A fifth step of adhering the machined first molded body and the machined second molded body to each other;
Melting and infiltrating silicon into the first molded body and the second molded body bonded to each other to make the first molded body into a support layer, the second molded body into a friction layer, and the adhesive portion between the first molded body and the second molded body A sixth step of making an adhesive layer; And
And a seventh step of grinding the first molded body and the second molded body in which the silicon has penetrated.
In the fifth step, the machined first molded body and the machined second molded body are 70 to 30 vol% of phenol resin, 15 to 35 vol% of graphite powder, and 15 to 1 carbon fiber having a length of 1 to 3 mm. Adhering to a mixture of 35 vol%,
After the sixth step is completed, a carbon-ceramic brake disc is made to make the composition of the support layer, the friction layer and the adhesive layer equal to SiC 65-25 wt%, Si 15-25 wt%, C 20-50 wt%. Way.

A first step of mixing a 30 to 70 vol% carbon fiber and 70 to 30 vol% phenol resin to form a mixture;
Inserting the mixture into a mold and pressing to form a first molded body, and putting the mixture into a mold and pressing to form a second molded body;
A third step of carbonizing the first molded body and carbonizing the second molded body;
A fourth step of machining the carbonized first molded body and machining the carbonized second molded body;
A fifth step of adhering the machined first molded body and the machined second molded body to each other;
Melting and infiltrating silicon into the first molded body and the second molded body bonded to each other to make the first molded body into a support layer, the second molded body into a friction layer, and the adhesive portion between the first molded body and the second molded body A sixth step of making an adhesive layer; And
And a seventh step of grinding the first molded body and the second molded body in which the silicon has penetrated.
In the fifth step, the machined first molded body and the machined second molded body are pulverized 70 ~ 30 vol% phenol resin, 15 ~ 35 vol% graphite powder, 0.01 ~ 0.1mm diameter Bonded with a mixture of 15 to 35 vol% carbon fiber,
After the sixth step is completed, a carbon-ceramic brake disc is made to make the composition of the support layer, the friction layer and the adhesive layer equal to SiC 65-25 wt%, Si 15-25 wt%, C 20-50 wt%. Way.

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