KR101217450B1 - Optical sheet for light extracting for organic light emitting diodes - Google Patents

Abstract

The present invention includes an optical sheet for an organic light emitting display device in which unit lenses are uniformly disposed on one surface of a sheet, a glass substrate, a transparent electrode, a hole injection layer, a light emitting layer, an electron injection layer, and a metal electrode. An organic light emitting display device in which an optical sheet is disposed, and an optical sheet, a transparent electrode, a hole injection layer, a light emitting layer, an electron injection layer, and a metal electrode, wherein the optical sheet has a unit lens uniformly disposed on a light exit surface. An organic light emitting display device.

By forming a unit lens structure composed of curved surfaces such as a conical lens or a curved lens on one surface of the sheet, the interfacial angle condition between the glass substrate and the air layer in which total internal reflection occurs mainly is changed, so that the glass substrate of the organic light emitting display device The light extraction efficiency can be increased by extracting light of a specific angle having total internal reflection to the outside.

OLED display, light extraction, cone, curved surface, total reflection

Description

Optical sheet for light extracting for organic light emitting diodes

The present invention relates to an optical sheet for an organic light emitting display device and an organic light emitting display device including the same, and in particular, an optical sheet for improving light extraction efficiency by forming a unit lens structure such as a conical lens or a curved lens on one surface of the optical sheet; The present invention relates to an organic light emitting display device including the same.

Currently, a cathode ray tube (CRT) is used as a main device in a display device such as a television or a monitor, but this has a problem of high weight and volume and high driving voltage. Accordingly, there is a need for a flat panel display device having excellent characteristics such as thinness, light weight, and low power consumption. The liquid crystal display device, the plasma display device, the field emission display device, and the electroluminescence display device (LED) As described above, various flat panel display devices have been researched and developed.

Among them, an electroluminescent display device is a display device using an electroluminescence phenomenon that generates light when a certain electric field is applied to a phosphor. An organic light emitting display device and an organic light emitting display device (OLED or organic LED) according to the configuration of the light emitting layer. Can be divided into: Among them, the organic light emitting display device is attracting attention as a natural color display device because light of all regions of visible light including blue is emitted, and has been widely used because of its high luminance and low operating voltage characteristics. In addition, because of self-luminous, high contrast, ultra-thin display is possible, and the process is simple, so there is relatively little environmental pollution.

FIG. 1 illustrates a conventional organic light emitting display device. In the conventional organic light emitting display device, a transparent electrode anode 2 is formed on a glass substrate 1, as shown in FIG. The injection layer 3, the light emitting layer 4, and the electron injection layer 5 are laminated, and a cathode 6 composed of a metal electrode is formed on the electron injection layer.

The emission principle of the OLED is light emission by combining electrons and holes. When a driving voltage is applied to the anode 2 and the cathode 6, holes and electrons in the hole injection layer 3 are applied. The electrons in the injection layer 5 respectively propagate toward the light emitting layer 4 and combine in the light emitting layer 4 to emit visible light. Thus, an image or an image is displayed by the visible light generated from the light emitting layer 4.

FIG. 2 illustrates a path of light emitted from a general organic light emitting device. In the structure illustrated in FIG. 2, the light exit direction is indicated by an arrow. The light generated from the light emitting layer is an anode, which is a transparent electrode. IZO) and the transparent material of the glass substrate, which are emitted into the air, and the emitted light is partially emitted by the difference in refractive index of each layer constituting the light emitting device, in particular, the difference in refractive index between the glass substrate and the air. Is lost by internal reflection reflected inward. As such, the light extraction efficiency is substantially reduced by total internal reflection, so that the light finally emitted through the glass substrate is only about 28% of the first light emitted as shown in FIG. 2.

Accordingly, various light extraction films have been developed for more efficiently extracting light from an organic light emitting display device. As a conventional light extraction film, a film formed on one surface of a prism or hemispherical structure is generally used. However, the prism film has insufficient light extraction efficiency of light having a specific angle, and the hemispherical structure has excellent light extraction efficiency among the known shapes, but there is still a problem that many light is not extracted from the glass substrate into the air. .

Accordingly, there is a need for a new type of optical sheet capable of further improving the efficiency of light by preventing light loss due to total internal reflection.

Accordingly, one aspect of the present invention is to increase the light extraction efficiency by forming a curved unit lens on one surface of the sheet.

Accordingly, another aspect of the present invention is to improve the light extraction efficiency of the organic light emitting display device by arranging the sheet on top of the organic light emitting display device.

According to an aspect of the present invention, a plurality of unit lenses are uniformly disposed on one surface, and the unit lens is a conical lens having a triangular longitudinal cross section or a curved lens having a parabolic or hyperbolic curve in the central longitudinal cross section. Is provided.

Pitch of the unit lenses is preferably 20㎛ to 500㎛.

The diameter of the bottom surface of the unit lens is preferably 80% to 116% of the lens pitch.

The unit lens is preferably arranged in a honeycomb structure.

The height of the unit lens is preferably 20% to 95% of the diameter of the bottom surface of the lens.

It is preferable that the pitch, the diameter and the height of the bottom of the unit lenses are constant.

According to another aspect of the present invention, an organic light emitting display device is provided in which a glass substrate, a transparent electrode, a hole injection layer, a light emitting layer, an electron injection layer, and a metal electrode are sequentially stacked, and the optical sheet is disposed on the glass substrate. .

According to still another aspect of the present invention, an optical sheet having a light emitting surface and a light incident surface includes a transparent electrode, a hole injection layer, a light emitting layer, an electron injection layer, and a metal electrode sequentially disposed below the optical sheet, and the optical The sheet is provided with a plurality of unit lenses are uniformly arranged on the light emitting surface, the unit lens is provided with an organic light emitting display device which is a conical lens having a triangular longitudinal cross section or a curved lens having a parabolic or hyperbolic curve in the central longitudinal cross section.

A lens having a curved structure, such as a conical lens or a curved lens, is formed on one surface of the sheet, and the incident surface is formed into a curved surface to adjust the incident angle so that a specific angle having total internal reflection between the glass substrate and the air of the organic light emitting display device is achieved. By extracting the light to the outside it is possible to increase the light extraction efficiency by the optical sheet according to the present invention.

Hereinafter, the present invention will be described in detail with reference to the drawings.

In the present specification, the unit lens includes a conical lens and a curved lens, and the conical lens means that the longitudinal cross section of the lens center is triangular, and the curved lens particularly means that the longitudinal cross section of the lens center is parabolic or hyperbolic.

The optical sheet of the present invention for use in an organic light emitting display device (OLED) improves the light extraction efficiency of the organic light emitting display device by arranging a unit lens structure consisting of a curved surface on the light emitting surface of the sheet. Total reflection occurs when the angle of incidence is greater than or equal to the critical angle, and the optical sheet according to the present invention adjusts the angle of incidence by forming an incident surface of light into a curved surface. That is, as shown in FIG. 2, since light of a certain angle is mainly totally reflected between the glass substrate, which is the uppermost layer of the organic light emitting display device, and air, the light of a certain angle is totally reflected, thereby forming a curved unit lens on one surface of the sheet. The light extraction efficiency can be increased by effectively preventing the light of a certain angle from total internal reflection.

Preferably, the unit lens has a triangular, parabolic or hyperbolic vertical cross section at the center of the lens. As shown in FIG. 3A, the conical lens has a circular bottom surface and forms a triangular cross section. As shown in FIG. 3B, a conical lens has a circular bottom surface and a parabolic or hyperbolic cross section.

The unit lens may be disposed at a constant pitch (P, P) on one surface of the sheet, and in this case, the pitch between the lenses is preferably 20 μm to 500 μm. If it is smaller than 20㎛, it is difficult to manufacture lens mold. If it is larger than 500㎛, manufacturing cost increases due to the increase of lens volume, and the shape of the lens is easily recognized in appearance, and the uniformity of light distribution can be reduced, resulting in deterioration of appearance quality. have. The range of the pitch is mentioned in consideration of difficulties in the manufacturing process or various problems that may occur after manufacturing. In general, in the arrangement of micro lenses including tens to hundreds of lenses or more, the pitch may be easily manufactured and moiré. It is set in consideration of other matters of appearance quality and is not known to be a major factor in optical characteristics such as light extraction efficiency and luminance. For example, when changing the shape obtained at 50 micrometer pitch to 500 micrometer pitch, if the shape in 50 micrometer pitch is proportionally increased, this same optical characteristic can be obtained.

The shape of the unit lens may be specified by diameter and height, and the shape of the curved lens may be specified from the following equation. The curved lens may include an elliptical lens, a parabolic lens, or a hyperbolic lens, but in the present invention, the curved lens particularly means a parabolic or hyperbolic lens. In general, the shape of a curved lens is expressed as a function of the radius of curvature r and the conic constant k at the vertices of the lens as variables. In this case, the koenic constant k determines the shape of the lens. If k = 0, a circular, k = -1, a parabolic lens, -1 <k <0, an elliptical lens, and k <-1, Hyperbolic lens appears. In the formula, r represents the radius of curvature and k represents the conic constant:

It is preferable that the diameter of the bottom surface of the curved lens is 80% to 116% of each lens pitch (P, P). If the diameter is less than 80%, the area of planar voids between the lenses increases, which reduces light extraction efficiency due to total internal reflection. There is a problem, because if it exceeds 116%, the maximum diameter that can be produced through the mold in an array of regular hexagons (honey comb) for placing the lenses does not exceed 116%. That is, when the pitch between the center and the center of the regular hexagon of the honeycomb structure is constant, if the diameter is 116% of the pitch, the voids are lost, the values of the above diameters are buried in the plate and there is no shape information. The present invention has the most preferable effect in the case of arranging the unit lens shape in the honeycomb structure as described above, the honeycomb arrangement structure referred to in the present specification is to make the center of the lens coincides with the center of the regular hexagon in the arrangement of the lens it means.

The unit lenses uniformly arranged on the optical sheet may each have a diameter of various sizes within the range of the diameter, but it is easy to arrange lenses having the same size diameter in terms of process convenience and uniformity of light emission. It is more preferable from a viewpoint.

The height of the unit lens is preferably 20% to 95% of the diameter of the bottom surface of the lens, there is a problem that the light extraction efficiency improvement is less than 20% or more than 95%. The unit lenses uniformly arranged on the optical sheet may each have various heights within the height range, but it is more convenient to arrange lenses having the same height and diameter in terms of process convenience and uniformity of light emission. desirable.

Preferably, the unit lens may be disposed such that there is no gap between the lenses within the above-described pitch and the diameter of the bottom surface of the lens, or may be disposed such that the gap is below a predetermined level. On the other hand, the unit lens may be arranged in a non-uniform lens so that the length of the pitch (P) shown in Figure 4 is different, but as shown in Figure 4 so that the bottom surface of the unit lens arranged as shown in Figure 4 to form a regular hexagon It is preferable that the length of the pitch P is constant. For example, when lenses of a certain size are arranged so that there are no gaps between the lenses, the bottom surface is most efficiently uniform when the bottom surface forms a regular hexagonal structure (honeycomb structure) as shown in FIG. Lenses can be arranged in a compact manner without voids. Even in the case of the regular hexagonal dense structure as described above, a difference in the actual light extraction efficiency may occur depending on the height and the diameter of the bottom surface of each lens, and the preferred height and the diameter of the bottom surface are as described above.

As shown in FIG. 4, even though the bottom surface of the unit lens has a polygonal structure, the upper protrusion is formed in the shape of a conical or curved lens, so the emitted light is refracted at various angles and the average angle of incidence is reduced, thereby reducing the total internal reflection to the front region. It is possible to increase the amount of light emitted.

FIG. 5 shows an exemplary optical sheet according to the present invention, and FIG. 5A shows an optical sheet arranged in a hexagonal dense structure with overlapping conical lenses of constant size, and FIG. 5B shows a curved lens of constant size overlapping. It shows an optical sheet arranged in a hexagonal dense structure.

The optical sheet of the present invention is not particularly limited as long as it is a transparent material capable of transmitting light with a visible light transmittance of about 85% or more. The refractive index of the optical sheet of the present invention is preferably similar to the refractive index of the glass substrate of the organic light emitting device, that is, the difference from the refractive index of the glass substrate of the organic light emitting device is less than 0.2, more preferably the same as the refractive index of the glass substrate. .

The optical sheet that can be used in the present invention may be composed of, for example, resin, plastic and glass. That is, light emitted from the light emitting layer of the organic light emitting device is emitted to the outside through the transparent electrode and the transparent substrate, wherein a part of the light emitted between the transparent substrate and the air is a flat transparent substrate due to the difference in refractive index between the air and the transparent substrate Will not escape. That is, the light component that emits light above the critical angle between two media having a large refractive index difference is not emitted to the outside and is lost due to total internal reflection, thereby reducing light extraction efficiency. On the other hand, when the optical sheet of the present invention is used, the internal reflection is reduced by the sheet having a refractive index similar to that of the glass substrate and the curved structure formed on the sheet, thereby improving the light extraction effect of the emitted light.

In the manufacture of the optical sheet according to the present invention, the manufacturing method of the optical sheet may be used any manufacturing method well known in the art, for example, by placing a cured resin solution on the substrate with a die in the unit lens shape is engraved It can be formed by pouring and curing it. At this time, the curable resin that can be used in the present invention may include a urethane acrylate, epoxy acrylate, ester acrylate or a radical-generating monomer, and these may be used alone or in combination. Using a mold in which various shapes are engraved, lenses having various shapes, heights, and pitches can be formed. In addition, various manufacturing methods are known in the art, and the optical sheet of the present invention may be manufactured by other conventional manufacturing methods in addition to the above-described methods.

According to another aspect of the present invention, there is provided an organic light emitting display device including a glass substrate, a transparent electrode, a hole injection layer, a light emitting layer, an electron injection layer, and a metal electrode, and the optical sheet according to the present invention disposed on the glass substrate. The optical sheet according to the present invention obtained above may be disposed on the glass substrate of the organic light emitting display device to increase the light utilization efficiency of the light emitted from the glass substrate.

That is, when the optical sheet of the present invention is disposed on the light emitting surface of the organic light emitting device, the angle of the interface is changed by the curved unit lens so that the light emitted from the organic light emitting layer enters the optical sheet at a critical angle or less, and thus is totally internally reflected. The amount of light can be reduced, resulting in improved light extraction efficiency.

According to another aspect of the present invention includes an optical sheet having a light emitting surface and a light incident surface, a transparent electrode, a hole injection layer, a light emitting layer, an electron injection layer and a metal electrode sequentially disposed below the optical sheet, the optical sheet A plurality of unit lenses are uniformly disposed on a light emitting surface, and the unit lens is a conical lens having a triangular vertical cross section or a curved lens having a parabolic or hyperbolic cross section.

The unit lens is preferably a conical lens having a triangular cross section or a curved lens having a parabolic or hyperbolic curve in the central longitudinal section. The shape of the conical lens can be specified by the diameter and height of the circle forming the base, it can be specified from the following equation of the shape of the curved lens, in which r represents the radius of curvature, k is conic Represents a constant:

The unit lens may be disposed at a constant pitch (P, P) on one surface of the sheet, and in this case, the pitch between the lenses is preferably 20 μm to 500 μm.

The diameter of the circle constituting the bottom of the unit lens is preferably 80% to 116% of each lens pitch, if less than 80% is a problem that the light extraction efficiency due to total internal reflection decreases due to the large void area between the lenses If it exceeds 116%, the maximum diameter that can be produced through the mold in the array of regular hexagons (honey comb) for placing the lenses does not exceed 116%. The height of the unit lens is preferably 20% to 95% of the diameter of the bottom surface of the lens, there is a problem that the light extraction efficiency improvement is less than 20% or more than 95%.

The unit lens may be disposed to be greatly spaced apart from one surface of the sheet, but when there are many voids between the unit lenses, the total internally reflected light increases, so that the voids become less than a predetermined level or the lenses overlap the voids between the unit lenses. It is more preferable to arrange so that there is no.

When the unit lenses are arranged without voids, the unit lenses may be arranged unevenly so that the lengths of the pitches P shown in FIG. 4 are different from each other. However, as shown in FIG. It is preferable to form.

The optical sheet of the present invention is not particularly limited as long as it is a transparent material capable of transmitting light with a visible light transmittance of about 85% or more. The refractive index of the optical sheet of the present invention preferably has a difference of less than 0.2 from the refractive index of the glass substrate of the organic light emitting device, and more preferably the same as the refractive index of the glass substrate. The sheet of the present invention may be composed of, for example, resin, plastic, glass, and the like.

In the manufacture of the organic light emitting display device of the present invention, the organic light emitting display device is produced by attaching an optical sheet having the shape proposed in the present invention to the glass substrate of the OLED device manufactured by the process of the existing organic light emitting device (OLED) Alternatively, the glass substrate may be manufactured by using a glass substrate in which the shape proposed in the present invention is formed in advance on the glass substrate used for manufacturing the OLED device.

In this case, the optical sheet of the present invention is manufactured through a mold, an injection process or an etching process of the glass substrate by a method that can be cured by heat, cooling or light in a resin or other liquid state on a polymer substrate or a glass substrate. It can be produced to have a shape on the glass substrate itself.

The organic light emitting display device according to the present invention obtained as described above may increase the light utilization efficiency of the emitted light.

Hereinafter, the present invention will be described in more detail with reference to the following examples, which are intended to illustrate the present invention, but are not intended to limit the present invention.

Example 1 Light Extraction Effect of Optical Sheet According to the Present Invention

In order to confirm the light extraction effect of the optical sheet according to the present invention, the total light amount of the light emitted from the organic light emitting device was calculated using a geometric optical simulation tool (TracePro, Lambda Research Co.). The results are shown in Table 1 as the light extraction rate, where the light extraction rate is the ratio of the total light amount of light emitted into the air through the optical sheet of the present invention, assuming that the total light amount of light generated in the glass substrate is 100. .

Simulation of the light extraction characteristics of the organic light emitting device for the present invention was performed as follows. The OLED light source was set to have a distribution corresponding to Lambertian light distribution, and the absorption and reflection characteristics of the reflective layer used reflection and absorption characteristics of aluminum, and the absorption or scattering characteristics of the light emitting layers were determined by the light extraction member. It was defined as a method of correcting the measurement results and simulation results for the case where only the general glass substrate which was not applied was applied. In this simulation, the optical sheet of the present invention was used in which the bottom surface of the lens had a diameter of 57.7 μm, a height of 21.6 μm, a curved lens having r and k values of 6.7 μm and -2.155, respectively, having a pitch of 50 μm and arranged in a regular hexagonal structure. The refractive index of the material of the optical sheet was set to about 1.52 which is the same as that of the glass substrate.

Example 2: light extraction effect of the optical sheet according to the present invention

The light extraction efficiency was calculated under the same conditions as in Example 1 except that the diameter of the bottom surface of the lens was 53 μm and the height of the lens was 19.5 μm.

Example 3 Light Extraction Effect of Optical Sheet According to the Present Invention

The light extraction efficiency was calculated under the same conditions as in Example 1 except that the diameter of the underside of the lens was 44 μm and the height of the lens was 15.5 μm.

Example 4 Light Extraction Effect of Optical Sheet According to the Present Invention

The light extraction efficiency was calculated under the same conditions as in Example 1 except that k = -1.05 and the height of the lens was 52.0 μm.

Example 5 Light Extraction Effect of Optical Sheet According to the Present Invention

The light extraction efficiency was calculated under the same conditions as in Example 1 except that r = 30 μm and the height of the lens was 11.4 μm.

Example 6 Light Extraction Effect of Optical Sheet According to the Present Invention

The light extraction efficiency was calculated under the same conditions as in Example 1 except that r = 3.6 μm, k = -3.74, and the height of the lens was 16.2 μm.

Example 7 Light Extraction Effect of Optical Sheet According to the Present Invention

The light extraction efficiency was calculated under the same conditions as in Example 1 except that the shape of the unit lens was a cone having a diameter of 48 μm and a height of 17 μm.

Example 8 Light Extraction Effect of Optical Sheet According to the Present Invention

The light extraction efficiency was calculated under the same conditions as in Example 1 except that the shape of the unit lens was a cone having a diameter of 57.7 μm and a height of 17 μm.

Comparative Example 1: Light Extraction Effect When No Optical Sheet is Applied

For comparison, the light extraction rate was calculated under the same conditions as in Example 1 except that the optical sheet for light extraction proposed in the present invention was not applied.

Comparative Example 2: Light Extraction Effect When Applying Optical Sheet with Hemispherical Shape

Instead of the optical sheet having the shape of the present invention, the light extraction rate was calculated when the semi-spherical lenses having a radius of 25 μm were applied with an optical sheet arranged in a regular hexagonal structure with a pitch of 50 μm.

Comparative Example 3: Light extraction effect when the void has a certain level or more

The light extraction rate was calculated under the same conditions as in Example 1 except that the diameter of the underside of the lens was 39 μm and the height was 13.2 μm.

Comparative Example 4: Light extraction effect when the height of the lens has 95% or more of the diameter of the bottom surface

The light extraction rate was calculated under the same conditions as in Example 1 except that k = -1.03 and the lens height was 55.3 μm.

Comparative Example 5: Light extraction effect when the height of the lens has less than 20% of the diameter of the base

The light extraction rate was calculated under the same conditions as in Example 1 except that r = 33 μm and the height of the lens was 10.6 μm.

Light extraction rate (%) Comparative Example 1 52.0 (1.00) Comparative Example 2 79.3 (1.53) Comparative Example 3 79.0 (1.52) Comparative Example 4 79.2 (1.52) Comparative Example 5 79.2 (1.52) Example 1 81.4 (1.57) Example 2 81.5 (1.57) Example 3 80.6 (1.55) Example 4 79.7 (1.53) Example 5 79.7 (1.53) Example 6 80.7 (1.55) Example 7 80.8 (1.55) Example 8 80.8 (1.55)

According to the results of Table 1, the light extraction rate of the optical sheet according to the embodiment to which the light extraction film of the present invention is applied compared to Comparative Example 1 without the light extraction film has an effect of increasing to 53% to 57%. The light extraction rate of the optical sheet having the unit lens shape according to the present invention can be confirmed that the amount of light extraction is increased than the light extraction rate of the optical sheet having the hemispherical lens shape (Comparative Example 2). The numerical values in parentheses in the results of Table 1 indicate the amount of light extracted in each example when the light extraction amount of the light extraction film was not applied (ie, Comparative Example 1) as 1.

1 is a cross-sectional view of a general organic light emitting device (OLED).

FIG. 2 illustrates a path of light emitted from a general organic light emitting device, and shows light of a specific angle totally reflected inside.

3 illustrates the shape of the unit lens disposed on one surface of the optical sheet of the present invention, and shows the conical lens a and the curved lens b, respectively.

Figure 4 shows the shape of the bottom surface of the unit lens is disposed on one surface of the optical sheet according to the present invention, showing a dense hexagonal structure.

Figure 5 shows an exemplary optical sheet according to the present invention, Figure 5 (a) is arranged so that the bottom surface of the conical lens has a hexagonal dense structure, Figure (b) is the bottom surface of the curved lens hexagonal dense structure It shows the sheet arranged to have.

Claims (13)

A plurality of unit lenses are uniformly arranged on one surface, and the unit lenses are curved lenses whose parabolic or hyperbolic curves have a central longitudinal cross section. The height of the unit lens is 20% to 95% of the diameter of the lens bottom surface optical sheet for an organic light emitting display device. The optical sheet of claim 1, wherein the unit lenses have a pitch of 20 μm to 500 μm. The optical sheet of claim 1, wherein a diameter of a bottom surface of the unit lens is 80% to 116% of a lens pitch. The optical sheet of claim 1, wherein the unit lens has a honeycomb structure. delete The optical sheet of claim 1, wherein the unit lenses have a constant pitch, a bottom diameter, and a height. A glass substrate, a transparent electrode, a hole injection layer, a light emitting layer, an electron injection layer and a metal electrode are sequentially stacked, and the optical sheet according to any one of claims 1 to 4 and 6 is disposed on the glass substrate. Organic light emitting display device. An optical sheet having a light exit surface and a light incident surface, a transparent electrode sequentially disposed below the optical sheet, a hole injection layer, a light emitting layer, an electron injection layer, and a metal electrode, wherein the optical sheet includes a plurality of unit lenses on the light exit surface Are uniformly arranged, the unit lens is a curved lens having a parabolic or hyperbolic central longitudinal section, The height of the unit lens is 20% to 95% of the diameter of the bottom surface of the lens. The organic light emitting display device of claim 8, wherein the unit lenses have a pitch of about 20 μm to about 500 μm. The organic light emitting display device of claim 8, wherein a diameter of a bottom surface of the unit lens is 80% to 116% of a lens pitch. The organic light emitting display device of claim 8, wherein the unit lens has a honeycomb structure. delete The organic light emitting display device of claim 8, wherein the unit lenses have a constant pitch, a bottom diameter, and a height.

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