KR101212323B1

KR101212323B1 - Method for metallic coating on glass processed using pvd and glass processed using thereof

Info

Publication number: KR101212323B1
Application number: KR1020100089150A
Authority: KR
Inventors: 성석원; 강진형
Original assignee: (주)보림시스템
Priority date: 2010-09-10
Filing date: 2010-09-10
Publication date: 2012-12-13
Also published as: KR20120026936A

Abstract

The present invention relates to a method of forming a metallic coating layer on a glass workpiece by the PVD vacuum coating method and to a glass workpiece manufactured using the same. The method includes disposing a glass workpiece and a coated specimen in a PVD chamber, and the PVD Vacuuming the inside of the surface treatment chamber to 1 to 50 mtorr and applying a bias voltage of 20 to 600 V to the PVD surface treatment chamber for 1 to 99 minutes to vacuum sputter the particles of the specimen onto the surface of the glass workpiece. The coating specimen may be uniform, translucent or opaque by using one or more of Ti, TiSi, Zr, Cr, TiAl, AlTi and TiAlSi or by using one or more of oxides, nitrides and carbides in the respective materials. It is characterized in that to obtain a glass product formed with a metallic coating layer of 0.1 ~ 10㎛ thickness.

Description

METHOD FOR METALLIC COATING ON GLASS PROCESSED USING PVD AND GLASS PROCESSED USING THEREOF}

The present invention relates to a technique for forming a metallic coating layer on a glass workpiece, and more particularly, a PVD (Physical Vapor Deposition) vacuum coating method on a surface of a glass workpiece such as glass bottles, wine glasses, glasses and ceramics. By forming a metallic coating layer using the present invention, while implementing a variety of colors and metal textures, the present invention relates to a technology that can implement a translucent shiny decoration effect.

In order to form a metal or a metallic coating layer containing metal on the surface of a product such as cement, glass, plastic, paper, or the like, coating or plating is generally used.

First, as a coating method, a method of coating and curing a metal powder mixed with an inorganic coating is used.

For this purpose, colored functional paints are used, and in particular, inorganic paints of metallic type have been applied to various fields.

However, at this time, the metallic type coating composition for imparting a metallic color has a problem in that it is impossible to express the texture and pattern of the surface of the metal as it is.

On the other hand, in the case of the plating method, the above-described metal surface texture can be saved, but it is not easy to improve the plating equipment, and there is a problem that plating is difficult on non-conductors such as glass or plastic.

SUMMARY OF THE INVENTION An object of the present invention is to provide a method for forming a metallic coating layer of a glass workpiece, which is capable of forming a metallic coating layer having a uniform and beautiful effect in forming the metal itself or the metallic coating layer containing the metal in the glass workpiece.

In addition, another object of the present invention is to provide a glass processed article formed with a metallic coating layer having a unique texture of the metal, but having a translucent or opaque property through the control of the coating conditions.

The method of forming a metallic coating layer of a glass workpiece using the PVD vacuum coating method according to an embodiment of the present invention comprises the steps of (a) disposing the glass workpiece and the coating specimen in a PVD surface treatment chamber, and (b) Vacuuming the inside of the PVD surface treatment chamber to 1 to 50 mtorr; and (c) sputtering the particles of the specimen onto the surface of the glass workpiece by applying a bias voltage of 20 to 600 V to the PVD surface treatment chamber for 1 to 99 minutes. Characterized in that it comprises a step.

Wherein the coated specimen is one or more of Ti, TiSi, Zr, Cr, TiAl, AlTi, and TiAlSi, or one or more of oxides, nitrides, and carbides in each of the materials, and the PVD surface The temperature inside the processing chamber is characterized in that ~ 500 ℃ at room temperature.

The method may further include performing masking or laser marking to expose the coated portion of the glass workpiece before or immediately after the step (a).

Next, the glass product is characterized in that at least one of glass bottles, glasses, wine glasses and porcelain, the step (c) is characterized in that the coating to a thickness of about 0.1 ~ 10㎛, the (c) After the step is characterized in that it may further form a UV coating layer.

In addition, the glass processed article according to an embodiment of the present invention is characterized by having a coating layer of about 0.1 ~ 10㎛ prepared by the method described above.

Metallic coating layer forming method of the glass workpiece using the PVD vacuum coating method according to the present invention by using a PVD (Physical Vapor Deposition) vacuum coating method, it is easy to form a metallic coating layer of a translucent or opaque material that was difficult to implement in plating or painting There are advantages to it.

In addition, by using one or more of Ti, TiSi, Zr, Cr, TiAl, AlTi and TiAlSi or one or more of oxides, nitrides and carbides in the above materials, a metallic coating layer of various colors can be obtained.

In addition, the present invention provides a processing method of adjusting the vacuum degree in the PVD surface treatment chamber to 1 to 50 mtorr and applying a bias voltage of 20 to 600 V for 1 to 99 minutes, thereby forming a glass with a coating layer having a uniform and metallic surface material. It provides the effect that the workpiece can be easily obtained.

1 is a flow chart showing a glass workpiece coating method according to an embodiment of the present invention.
Figure 2 is a photograph of the product photographed coating the metallic coating layer on the glass bottle according to an embodiment of the present invention.
3 is a product photograph taken of the coating of the metallic coating layer on the glass according to another embodiment of the present invention.
4 is a product photograph taken of the coating of the metallic coating layer on the glass according to another embodiment of the present invention.

Hereinafter, a method of forming a metallic coating layer of a glass processed product using the PVD vacuum coating method according to the present invention and a glass processed product manufactured using the same will be described in detail.

Advantages and features of the present invention, and methods of accomplishing the same will become apparent with reference to the embodiments described below and the accompanying drawings. However, the present invention is not limited to the embodiments disclosed below, but can be implemented in various different forms, only the embodiments are to make the disclosure of the present invention complete, it is common in the art It is provided to fully inform those skilled in the art of the scope of the invention, which is to be defined only by the scope of the claims.

By using the PVD coating method according to the present invention, it is possible to secure the translucency or opacity that was difficult to implement in the conventional method using an organic paint.

In addition, the PVD coating method according to the present invention can solve the problems of thermal discoloration, low hardness and low weather resistance characteristics of the organic coating, and can solve the problem of dissolving the glass workpieces by the organic solvent and the emission of toxic gases in the event of fire.

In the present invention, 'metallic' may be used to mean 'metal itself' or 'containing metal'. Accordingly, the metallic coating layer may be a coating layer using one or more materials of Ti, TiSi, Zr, Cr, TiAl, AlTi, and TiAlSi, or one or more of oxides, nitrides, and carbides.

1 is a flow chart showing a glass workpiece coating method according to an embodiment of the present invention.

Referring to Figure 1, the glass workpiece coating method according to the present invention is the step of charging and placing the glass workpiece and the coating specimen inside the PVD surface treatment chamber (S110), and heating and vacuuming the PVD surface treatment chamber (S120) And applying a bias voltage to the PVD surface treatment chamber, performing a sputtering deposition coating (S130), and performing other surface treatment such as UV coating and laser marking (S140).

Here, first, the glass processed product may use products such as glass bottles, glasses, wine glasses, and ceramics. In this case, the glass processed product in the present invention includes a common glass bottle, glass and wine glasses, but by further expanding the scope to be defined as a concept that also includes processed products of ceramics.

In the present invention, since a vacuum chamber is used, a product having a relatively small size of a product to be coated is advantageous, but is not limited thereto.

Next, the coated specimen is a metallic coated specimen composed of the metal itself or a metal compound, and one or more materials of Ti, TiSi, Zr, Cr, TiAl, AlTi and TiAlSi or one of oxides, nitrides and carbides in the above materials. The above materials can be used.

In this case, when Ti alone was used, a cloudy silvery coating layer was obtained, and in the case of TiN, yellow was obtained, and even gold color was possible.

In addition, the TiCN series was able to obtain purple to indigo blue, and even darker gray.

Next, when using ZrN it was possible to implement from light yellow to ivory color, and in the case of Cr it was possible to implement from white to silver.

Next, in the case of CrN, a light gray color could be realized, and in the case of TiAlN, purple to dark purple, ultramarine, and blue colors could be implemented.

Next, in the case of TiAlCN, it was possible to implement from brown to light black series, and in the case of TiAlSiN, various colors from light blue to dark blue were possible.

Therefore, in the case of mixing the above-mentioned materials it is possible to obtain a coating layer of more various colors.

Here, the implementation of the color is possible by controlling the conditions of the PVD surface treatment chamber and other coating conditions, looking at the specific conditions are as follows.

First, the reaction temperature inside the PVD surface treatment chamber is preferably adjusted to ˜500 ° C. at room temperature. At this time, the room temperature used in the present invention may be 18 ~ 28 ℃ but is not limited thereto. However, when the reaction temperature is less than room temperature, the deposition temperature may be too low to coat the metal particles normally, and when the reaction temperature exceeds 500 ° C., the coating may be performed too well, but precise control may be performed. There may be problems that make it difficult.

Therefore, the temperature for heating to control the reaction temperature of the PVD surface treatment chamber according to the present invention is preferably from room temperature to 500 ℃, the coating is to be carried out at a processing temperature suitable for the product to be coated for the best coating conditions More preferably.

Next, evacuating the inside of the PVD surface treatment chamber is preferably to maintain a vacuum degree of 1 ~ 50mtorr. If the degree of vacuum is less than 1 mtorr, there may be a problem that a single color is not realized due to the influence of foreign matters. If the degree of vacuum exceeds 50 mtorr, the cost for maintaining the degree of vacuum may be increased, and the degree of vacuum control may not be easy. There may be.

Next, it is preferable to control the bias voltage for sputtering deposition in the PVD surface treatment chamber to be 20 to 600V. If the bias voltage is also less than 20V, sputtering deposition may not be performed normally, and if it exceeds 600V, sputtering control may not be easy and there may be a problem of low economic efficiency.

In this case, a source for sputter deposition may be ion-beam using Ar gas, various methods such as electron-beam, radio-frequency (RF) beam, or excimer laser beam. In the former to the latter, a finer metallic coating layer can be formed.

Next, it is preferable to control the coating time according to the product for 1 to 99 minutes according to the bias voltage applied.

If the vacuum PVD coating time is less than 1 minute, the coating layer may be insufficient. If the vacuum PVD coating time is less than 1 minute, the thickness of the coating layer may not be easily adjusted, resulting in a non-uniform coating layer or a complete decrease in transparency. There may be.

In addition, the thickness of the metallic coating layer according to the coating time as described above is preferably to be 0.1 ~ 10㎛.

When the thickness of the metallic coating layer is less than 0.1㎛ may be almost no coating effect, when the thickness of the metallic coating layer exceeds 10㎛ the semi-transparent glitter effect is reduced, the metallic coating layer is too thick to cause cracks There may be a problem such as.

At this time, in order to ensure excellent translucency according to the present invention, it is preferable to form the thickness of the metallic coating layer to 1.0 μm or less.

As described above, by using the PVD coating method according to the present invention, it is possible to implement a variety of colors on the glass workpiece, obtain a semi-transparent effect while obtaining a unique gloss of the metal, it is possible to use a variety of.

Examples of this are as follows.

2 is a photograph of a product taken to form a metallic coating layer on a glass bottle according to an embodiment of the present invention.

Referring to Figure 2, by implementing a metallic coating layer of various colors in the actual glass bottle, even the inlet portion of the glass bottle can be formed to a uniform thickness, even in general, the coating is not easy, the overall uniform coating state I can keep it.

Here, the UV coating layer may be further formed on the metallic coating layer according to various purposes such as preventing the internal material of the metallic coating layer from being changed by ultraviolet rays. The UV coating layer is preferably formed by mixing an acrylic copolymer, a siloxane compound and a conductive polymer compound. In this case, when the siloxane compound is not added, the UV blocking effect is remarkably lowered, and in the case of the conductive polymer compound, the phenomenon of gloss or texture inherent in the metallic coating layer may be prevented.

3 is a photograph of a product photographed by coating a translucent metallic coating layer on a glass according to another embodiment of the present invention.

Referring to Figure 3, by forming a gray-based coating layer on the wine glass can be seen that while exhibiting the unique texture of the metal, excellent translucency.

In this case, the coating layer having a thickness of 0.1 ~ 1.0㎛ according to the PVD coating conditions of the present invention, it can be seen that even in the handle portion of the wine glass can easily form a uniform and excellent coating layer. .

4 is a product photograph taken of the coating of the metallic coating layer on the glass according to another embodiment of the present invention.

Referring to FIG. 4, it can be seen that a thicker coating layer is implemented than in the embodiment of FIG. 3. In addition, it can be seen that various colors such as gold color are implemented using various coated specimens.

In this case, after the wine glass is disposed in the PVD surface treatment chamber or before the wine glass, a separate masking process may be performed on the wine glass so that the metallic coating layer is formed only on a desired portion.

Although the wine glasses shown in FIG. 4 appear to be opaque on the photo, the coating is not made on the inner surface of the wine glass by a separate masking process, and thus actually shows a translucent state.

As described above, the method of coating the metallic coating layer on the glass workpiece according to the present invention by using the PVD vacuum coating method, it is possible to easily obtain a metallic coating layer of a translucent or opaque material that was difficult to implement in plating or painting.

In addition, by using one or more materials of Ti, TiSi, Zr, Cr, TiAl, AlTi and TiAlSi or one or more of oxides, nitrides and carbides in the above materials, a metallic coating layer of various colors can be obtained. Since a partial coating layer can be realized by a masking process or laser marking, various coating effects can be obtained.

In addition, the present invention can form a coating layer having a unique surface material while maintaining a uniform coating state by controlling the temperature and the degree of vacuum in the PVD surface treatment chamber, and controlling the bias voltage, the coating time and the coating thickness. In addition, the present invention can be easily applied to various processes such as UV coating layer formation as a metallic coating subsequent process, it is possible to maximize the utilization.

While the present invention has been described in connection with what is presently considered to be practical exemplary embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, It will be understood by those skilled in the art that the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. It is therefore to be understood that the above-described embodiments are illustrative in all aspects and not restrictive.

S110: Glass workpiece and coated specimen placement
S120: PVD surface treatment chamber heating and vacuumization
S130: bias applied and sputtered deposition coating
S140: Finished Glass Workpiece

Claims

(a) placing the glass workpiece and metallic coated specimen in a Physical Vapor Deposition (PVD) surface treatment chamber;
(b) evacuating the interior of the PVD surface treatment chamber to 1-50 mtorr; And
(c) applying a bias voltage of 20 to 600 V to the PVD surface treatment chamber for 1 to 99 minutes, and adjusting the temperature inside the PVD surface treatment chamber to room temperature to 500 ° C. to obtain particles of the metallic coated specimen from the glass workpiece. Sputter deposition on the surface to form a metallic coating layer of 0.1 ~ 10㎛ thickness; And
(d) forming a UV coating layer on the metallic coating layer by using a mixture of an acrylic copolymer, a siloxane compound and a conductive polymer compound;
The metallic coating specimen may be any one selected from at least one material of Zr or Cr, one or more materials of oxides, nitrides and carbides of Zr or Cr, and titanium carbide. .

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The method of claim 1,
Before or immediately after step (a)
And performing a masking or laser marking for exposing the coated portion of the glass workpiece.

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The method of claim 1,
The glass workpiece is
A method of forming a metallic coating layer of a glass workpiece, characterized in that it is at least one of glass bottles, glasses, wine glasses, and ceramics.

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