KR101169551B1 - A Composition for preparing The Hybrid Composite Board using Acryl Polymer and Geopolymer and The Hybrid Composite Board - Google Patents

A Composition for preparing The Hybrid Composite Board using Acryl Polymer and Geopolymer and The Hybrid Composite Board Download PDF

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KR101169551B1
KR101169551B1 KR1020090114403A KR20090114403A KR101169551B1 KR 101169551 B1 KR101169551 B1 KR 101169551B1 KR 1020090114403 A KR1020090114403 A KR 1020090114403A KR 20090114403 A KR20090114403 A KR 20090114403A KR 101169551 B1 KR101169551 B1 KR 101169551B1
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geopolymer
composite board
organic
acrylic polymer
inorganic composite
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KR20110057833A (en
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정재열
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(주)엘지하우시스
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/006—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26—Silicates of the alkali metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04—Waste materials; Refuse
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding

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  • Ceramic Engineering (AREA)
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  • Polymers & Plastics (AREA)
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  • Curing Cements, Concrete, And Artificial Stone (AREA)
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Abstract

본 발명은 아크릴계 폴리머와 지오폴리머를 적용한 복합보드 제조 관련 내용이다. 현재 다양한 종류의 보드가 국내에 생산, 유통되고 있으나, 아크릴계 폴리머와 지오폴리머를 주 원료로 가공된 하이브리드 Type의 유/무기 복합 보드에 대해서는 적어도 국내에서는 현재까지 전무하다고 할 수 있다.The present invention relates to the production of a composite board applying the acrylic polymer and geopolymer. Currently, various types of boards are produced and distributed in Korea, but there are no hybrid type organic / inorganic composite boards processed with acrylic polymer and geopolymer as the main raw materials, at least in Korea.

이러한 관점에서 아크릴계 폴리머와 지오폴리머를 적용한 복합 보드는 신소재 친환경 개념에서 해석될 수 있는 신개념 복합 보드이며, 현재까지 주로 사용된In this regard, the composite board using acrylic polymer and geopolymer is a new concept composite board that can be interpreted in the concept of eco-friendly materials.

석고보드와 무기소재 보드와는 차별화가 가능하다고 할 수 있다.It can be distinguished from gypsum board and inorganic board.

본 발명에 따르면, 아크릴계 폴리머와 지오폴리머를 적용하여, 기존 석고 보드 제조시 수반되는 소성 공정을 필요로 하지 않으면서, 제조가 가능한 친환경적 제조 방법이며, 동시에 치수안정성과 경도, 경량성, 등의 물성을 개선시킬 수 있는According to the present invention, by applying an acrylic polymer and a geopolymer, it is an eco-friendly manufacturing method that can be manufactured without the need for the firing process involved in manufacturing a conventional gypsum board, and at the same time, such as dimensional stability, hardness, light weight, and physical properties Can improve

유/무기 복합보드 제조용 조성물 및 이로부터 제조된 친환경 유/무기 복합 보드에관한 것이다.The present invention relates to an organic / inorganic composite board manufacturing composition and an environment-friendly organic / inorganic composite board manufactured therefrom.

하이브리드 타입, 유/무기 복합 보드, 지오폴리머, 아크릴계 폴리머 Hybrid type, organic / inorganic composite board, geopolymer, acrylic polymer

Description

아크릴계 폴리머와 지오폴리머를 이용한 유／무기 복합 보드 제조용 조성물 및 유／무기 복합 보드 {A Composition for preparing The Hybrid Composite Board using Acryl Polymer and Geopolymer and The Hybrid Composite Board}Composition for preparing organic / inorganic composite board using acrylic polymer and geopolymer and organic / inorganic composite board {A Composition for preparing The Hybrid Composite Board using Acryl Polymer and Geopolymer and The Hybrid Composite Board}

본 발명은 아크릴계 폴리머와 지오폴리머를 적용한 복합보드 제조 관련 내용이다. 현재 다양한 종류의 보드가 국내에 생산, 유통되고 있으나, 아크릴계 폴리머와 지오폴리머를 주 원료로 가공된 하이브리드 Type의 유/무기 복합 보드에 대해서는 적어도 국내에서는 현재까지 전무하다고 할 수 있다.The present invention relates to the production of a composite board applying the acrylic polymer and geopolymer. Currently, various types of boards are produced and distributed in Korea, but there are no hybrid type organic / inorganic composite boards processed with acrylic polymer and geopolymer as the main raw materials, at least in Korea.

이러한 관점에서 아크릴계 폴리머와 지오폴리머를 적용한 복합 보드는 신소재 친환경 개념에서 해석될 수 있는 신개념 복합 보드이며, 현재까지 주로 사용된In this regard, the composite board using acrylic polymer and geopolymer is a new concept composite board that can be interpreted in the concept of eco-friendly materials.

석고보드와 무기소재 보드와는 차별화가 가능하다고 할 수 있다.It can be distinguished from gypsum board and inorganic board.

보다 자세하게는 아크릴계 폴리머와 지오폴리머를 적용하여, 기존 석고 보드More specifically, the acrylic gypsum board by applying acrylic polymer and geopolymer

제조시 수반되는 소성 공정을 필요로 하지 않으면서, 제조가 가능한 친환경적 제조Eco-friendly manufacturing that can be manufactured without requiring the firing process involved in manufacturing

방법이며, 동시에 치수안정성과 경도, 경량성, 등의 물성을 개선시킬 수 있는 유/무기 복합보드 제조용 조성물 및 이로부터 제조된 친환경 유/무기 복합 보드에 관한 것이다.The present invention relates to a composition for manufacturing an organic / inorganic composite board capable of improving dimensional stability, hardness, light weight, and the like, and an environment-friendly organic / inorganic composite board manufactured therefrom.

국내에서의 무기 보드 시장은 다양한 종류의 보드가 유통되고 있으나, 석고보드가 가격 대비 우수한 제품 경쟁력을 확보하고 있는 장점으로 석고 보드 중심으로 시장이 형성되어 있다.In the domestic inorganic board market, various types of boards are in circulation, but gypsum boards have an excellent product competitiveness compared to price.

기존의 석고 보드가 생산되기 위해서는 고온에서 소성이라는 공정을 거쳐야 하며, 석고 원지를 제외하면 깨지기 쉬운 결점을 지니고 있다. 이러한 석고 보드의Existing gypsum board has to go through the process of firing at high temperature and has a flaw that is fragile except for gypsum paper. Of these gypsum boards

문제점을 개선하기 위하여, 소성 공정이 불필요하며, 원지를 사용하지 않아도 잘In order to improve the problem, the firing process is unnecessary, and even without the original paper

깨지지 않는 경도를 지닌 아크릴계 폴리머와 지오폴리머를 적용한 하이브리드 타입의 유/무기 복합 보드를 발명하게 되었다.The inventors have invented a hybrid type organic / inorganic composite board using acrylic polymer and geopolymer having unbreakable hardness.

특히, 현재 국내시장에서 유통되고 있는 석고보드의 경우, 라돈 가스의 방출을 통한 암 유발 소재라는 논란이 끊임없이 제기되고 있으므로, 이러한 문제를In particular, in the case of gypsum boards currently distributed in the domestic market, controversy over cancer-causing materials through the release of radon gas has been raised.

불식시킬 수 있는 친환경 소재의 출현과 인체 유해성에 영향이 없는 제품을 제시할 수 있다면 더욱 더 바람직하다 할 것이다.It would be even more desirable if a product could be presented that would not affect the appearance of environmentally friendly materials that could be quenched and harm to humans.

이에, 유기물인 아크릴계 폴리머와 무기물인 지오폴리머의 적정 배합을 통하여, 석고 보드의 장점인 치수안정성, 난연성, 경량성 등의 물성을 동등 수준으로 확보 가능하도록 최적의 배합 처방을 설계하는 것이 최우선 해결 과제라 할 수 있다.Therefore, it is a top priority to design the optimal formulation formulation so that the physical properties such as dimensional stability, flame retardancy, light weight, etc., which are advantages of gypsum board, can be secured through proper mixing of organic acrylic polymer and inorganic geopolymer. It can be said.

즉, 본 발명의 목적은 석고 보드의 대체물로서 우수한 물성을 보유할 뿐 아니라 친환경적인 유/무기 복합 보드용 조성물 및 이로부터 제조된 유/무기 복합 보드와 그 제조방법을 제공하려는 것이다.That is, an object of the present invention is to provide an environment-friendly composition for organic / inorganic composite boards and organic / inorganic composite boards manufactured therefrom as well as having excellent physical properties as a substitute for gypsum board.

상기 목적을 달성하기 위한 본 발명의 유/무기 복합 보드 제조용 조성물은,Composition for producing an organic / inorganic composite board of the present invention for achieving the above object,

건축내장용 보드 제조용 조성물에 있어서, 지오폴리머 100 중량부에 대하여 아크릴계 폴리머 5 내지 50 중량부를 배합하는 것을 특징으로 한다.In the composition for building interior board production, it is characterized in that 5 to 50 parts by weight of the acrylic polymer with respect to 100 parts by weight of the geopolymer.

또한, 본 발명의 유/무기 복합 보드의 제조방법은,In addition, the manufacturing method of the organic / inorganic composite board of the present invention,

상술한 조성물을 배합하고 교반하는 단계; 및 상기 교반물을 상온 내지 최대 80도 범위 내로 경화하는 단계를 포함하여 이루어지는 것을 특징으로 한다.Blending and stirring the above-mentioned composition; And it characterized in that it comprises a step of curing the stirring in the range of room temperature to a maximum of 80 degrees.

또한, 본 발명의 친환경 유/무기 복합 보드는,In addition, the environment-friendly organic / inorganic composite board of the present invention,

상술한 방법으로 제조되며, 친환경일 뿐 아니라 치수안정성, 경도, 경량성을Manufactured by the above-mentioned method, not only eco-friendly, but also dimensional stability, hardness, light weight

만족하는 것을 특징으로 한다.It is characterized by being satisfied.

이하, 본 발명에 대하여 상세하게 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated in detail.

이 같은 석고 보드 대체용 유/무기 복합 보드를 제조하기 위한 조성물은The composition for manufacturing an organic / inorganic composite board for replacing such a gypsum board

지오폴리머 100 중량부에 대하여 아크릴계 폴리머 5 내지 50 중량부를 배합하는5 to 50 parts by weight of the acrylic polymer based on 100 parts by weight of the geopolymer

것이 바람직하다. 이때 상기 지오폴리머는 Al 과 Si 를 주성분으로 하는 알루미노It is preferable. At this time, the geopolymer is alumino having Al and Si as main components

규산염을 특징으로 한다. 이같은 지오폴리머는 이에 한정하는 것은 아니나, 슬래그It is characterized by silicates. Such geopolymers are not limited to this, but slag

미분, 플라이애쉬, 제지애쉬, 실라카흄, 카올린계 광물, 칼슘 실리케이트계 광물,Fine powder, fly ash, paper ash, silica gel fume, kaolin mineral, calcium silicate mineral,

칼슘 알루미네이트계 광물, 소성 분쇄 점토(분쇄 벽돌), 유혈암 애쉬(oil shaleCalcium aluminate minerals, calcined clay (crushed bricks), oil shale ash (oil shale)

ash, 유혈암: 역청질 석회 함유 혈암)로 이루어진 군으로부터 선택되는 1종 이상을 사용할 수 있다.ash, shale: one or more selected from the group consisting of bitumen lime-containing shale) can be used.

또한, 상기 아크릴계 폴리머는 PMMA (Poly methyl methacrylate)와 MMA (Methyl Methacrylate)를 주성분으로 가교제, 소포제, 안정제, 충진제 등이 첨가된 형태일 수 있다.In addition, the acrylic polymer may be a form in which a crosslinking agent, an antifoaming agent, a stabilizer, a filler, and the like are added based on polymethyl methacrylate (PMMA) and methyl methacrylate (MMA).

이같이 하여 조성되는 조성물에는 알칼리 활성화제가 바인더 역할을 하게 되며, 그 종류로는 이에 한정하는 것은 아니나, NaOH, NaAl2O3, Na2CO3, Na2SO4?2H2O, Na2SO4, KOH, KAl2(OH)3, Ca(OH)2, Sodium Silicate Solution로 이루어진 군으로부터Alkali activator acts as a binder in the composition thus formed, but is not limited thereto, but NaOH, NaAl 2 O 3 , Na 2 CO 3 , Na 2 SO 4 ˜2H 2 O, Na 2 SO 4 , KOH, KAl 2 (OH) 3 , Ca (OH) 2 , Sodium Silicate Solution

선택되는 1종 이상을 사용할 수 있다. 대표적인 알칼리 활성화제로는 NaOH, KOH,One or more kinds selected may be used. Representative alkali activators include NaOH, KOH,

Sodium Silicate Solution 등이 사용될 수 있으며, 지오폴리머 100 중량부에 대하 여 1~50 중량부를 배합하는 것을 특징으로 한다.Sodium Silicate Solution and the like can be used, characterized in that 1 to 50 parts by weight based on 100 parts by weight of the geopolymer.

이와 같이 제조된 조성물로부터 상온 또는 중온 (40～80도)에서 경화 과정을 거치면 친환경 하이브리드 타입의 복합 보드 제조가 가능하게 된다.When the curing process is performed at room temperature or medium temperature (40 to 80 degrees) from the composition thus prepared, it becomes possible to manufacture an eco-friendly hybrid type composite board.

상기와 같이 구성되는 본 발명의 하이브리드 타입 유/무기 보드용 조성물 및 이를 이용하여 제조된 유/무기 복합 보드는 기존 석고 보드 제조시 수반되는 소성The hybrid type organic / inorganic board composition and the organic / inorganic composite board manufactured using the composition of the present invention is configured as described above is plasticity accompanying the manufacture of conventional gypsum board

공정을 필요로 하지 않으면서, 제조가 가능한 친환경적 제조 방법으로 치수안정성과 경도, 경량성 등의 물성 확보가 가능하다.It is possible to secure physical properties such as dimensional stability, hardness and light weight as an eco-friendly manufacturing method that can be manufactured without requiring a process.

이하, 본 발명을 실시예에 의해 보다 자세히 설명하지만, 본 발명이 이에 의해 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited thereto.

실시예Example

주요 성분이 알루미노규산염으로 구성되어진 지오폴리머로서 슬래그, 플라이애쉬, 카올린을 각각 수집한 다음 각 100 중량부에 대하여 아크릴계 폴리머로서 PMMA (Poly methyl methacrylate) 와 MMA (Methyl Methacrylate)를 주성분으로 가교제, 소포제, 안정제, 충진제 등이 첨가된 아크릴계 폴리머와 알칼리성 활성화제를 사용하였으며, 하기 표 1에 기재한 중량부의 범위 내로 배합하여 교반한 다음 하기 표에 기재된 조건 하에 경화하여 조성물을 제조하였다.It is a geopolymer composed of aluminosilicate whose main component is slag, fly ash, and kaolin, respectively, and then each 100 parts by weight of acrylic polymer is PMMA (Poly methyl methacrylate) and MMA (Methyl Methacrylate) as cross-linking agent and defoamer. The acrylic polymer and the alkaline activator to which the stabilizer, the filler, etc. were added were used, and the composition was prepared by mixing and stirring in the range of the weight part shown in Table 1 below and curing under the conditions shown in the following table.

지오폴리머 종류Geopolymer Type 아크릴계 폴리머 함량
(중량부)Acrylic polymer content
(Parts by weight) 알칼리성 활성화제 함량
(중량부)Alkaline activator content
(Parts by weight) 경화 조건Curing conditions 고로슬래그Blast furnace slag 25 (5～50)25 (5-50) 25 (1～50)25 (1-50) 상온～80도Room temperature ～ 80 degrees 플라이애쉬Fly ash 25 (5～50)25 (5-50) 25 (1～50)25 (1-50) 상온～80도Room temperature ～ 80 degrees 카올린kaoline 25 (5～50)25 (5-50) 25 (1～50)25 (1-50) 상온～80도Room temperature ～ 80 degrees

비교예Comparative example

통상 건축자재로 사용하는 석고보드를 준비하였다.Gypsum board, which is usually used as a building material, was prepared.

시험예Test Example 1 One

상기 실시예에서 제조된 3종류의 유/무기 복합 보드와 비교예의 석고보드간 경도 차이를 확인하기 위하여 석고보드의 석고 원지를 제거한 후, 석고보드 Core 부분과의 비교 경도 비교 테스트를 수행하였다.In order to confirm the hardness difference between the three types of organic / inorganic composite board prepared in the above example and the gypsum board of the comparative example, after removing the gypsum base paper of the gypsum board, a comparative hardness comparison test with the gypsum board core part was performed.

테스트 방법으로는 간이 시험 방식을 취했으며, 시험 방식은 보드 시편을 한The test method was a simple test method.

손으로 잡고 다른 한 손으로 힘을 주어 시편을 부러뜨려 보았으며, 결과는 동일 두께에서 석고보드와 동등 수준 이상의 경도 물성을 확인할 수 있었다.The specimens were gripped with force by the other hand while holding them by hand, and the results were confirmed to be equal to or greater than those of the gypsum board at the same thickness.

도 1은 본 발명의 실시예에 의해 제조된 유/무기 복합 하이브리드 보드 제조1 is an organic / inorganic hybrid hybrid board manufactured by the embodiment of the present invention

과정을 보이는 사진이다.It is a photograph showing the process.

도 2는 도 1에 의해 보드를 제조한 다음 실온 경화(양생) 과정을 보이는 사진이다.FIG. 2 is a photograph showing a process of manufacturing a board according to FIG. 1 and then curing at room temperature (curing).

Claims (5)

건축내장용 보드 제조용 조성물에 있어서,In the composition for manufacturing the board for building interior, 지오폴리머 100 중량부에 대하여 아크릴계 폴리머 5 내지 50 중량부를 배합하는 것을 특징으로 하는 아크릴계 폴리머와 지오폴리머를 이용한 유/무기 복합 보드 제조용 조성물.5 to 50 parts by weight of the acrylic polymer with respect to 100 parts by weight of the geopolymer, the composition for producing an organic / inorganic composite board using the acrylic polymer and the geopolymer. 제 1 항에 있어서,The method of claim 1, 상기 지오폴리머는 슬래그 미분, 플라이애쉬, 제지애쉬, 실라카흄, 카올린계 광물, 칼슘 실리케이트계 광물, 칼슘 알루미네이트계 광물, 소성 분쇄 점토(분쇄 벽돌), 유혈암 애쉬(oil shale ash)로 이루어진 군으로부터 선택되는 1종 이상인 것을 특징으로 하는 아크릴계 폴리머와 지오폴리머를 이용한 유/무기 복합 보드 제조용 조성물.The geopolymer is composed of slag fine powder, fly ash, paper ash, silakafume, kaolin mineral, calcium silicate mineral, calcium aluminate mineral, calcined clay (crushed brick), shale ash (oil shale ash) Composition for producing an organic / inorganic composite board using an acrylic polymer and a geopolymer, characterized in that at least one selected from. 제 1 항에 있어서,The method of claim 1, 상기 유/무기 복합 보드는 나아가 알칼리 활성화제를 바인더로 사용하며, 상기 알칼리 활성화제는 NaOH, NaAl2O3, Na2CO3, Na2SO4?2H2O, Na2SO4, KOH, KAl2(OH)3, Ca(OH)2, Sodium Silicate Solution로 이루어진 군으로부터 선택되는 1종 이상을The organic / inorganic composite board further uses an alkali activator as a binder, and the alkali activator is NaOH, NaAl 2 O 3 , Na 2 CO 3 , Na 2 SO 4 ˜2H 2 O, Na 2 SO 4 , KOH, At least one selected from the group consisting of KAl 2 (OH) 3 , Ca (OH) 2 , Sodium Silicate Solution 지오폴리머 100 중량부에 대하여 1~50 중량부를 적용하는 것을 특징으로 하는 아크릴계 폴리머와 지오폴리머를 이용한 유/무기 복합 보드 제조용 조성물.1 to 50 parts by weight based on 100 parts by weight of the geopolymer, the composition for producing an organic / inorganic composite board using the acrylic polymer and the geopolymer. 제1항 내지 제3항 중 어느 한 항의 조성물을 배합하고 교반하는 단계; 및Compounding and stirring the composition of any one of claims 1 to 3; And 상기 교반물을 상온 내지 최대 80도 범위 내로 경화하는 단계를 포함하여 이루어지는 유/무기 복합 보드의 제조방법.Method for producing an organic / inorganic composite board comprising the step of curing the stirring in a range of room temperature to a maximum of 80 degrees. 제4항의 방법에 의해 제조되는 친환경 유/무기 복합 보드.Eco-friendly organic / inorganic composite board manufactured by the method of claim 4.
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