KR101165745B1 - High-temperature power generation fuel cell system using catalytically-assisted combustor - Google Patents

Abstract

The present invention reduces the costs that can be incurred by using a large amount of noble metal catalyst by completely burning the exhaust gas of the fuel cell stack through the primary combustion in the catalytic auxiliary combustor and the secondary combustion which is the flame combustion and improves the durability of the system, The present invention relates to a fuel cell system for high temperature power generation having a catalytic auxiliary combustor capable of reusing heat generated in a combustion process to increase combustion efficiency and overall power generation efficiency of a system. A fuel cell stack having an anode and a cathode and producing electrical energy by chemical reaction using outside air and hydrogen supplied from the reformer; and a combustion catalyst, wherein the exhaust gas of the fuel cell stack A first combustion chamber injected and catalytically burned, and a second combustion chamber supplied with external air, And a second combustion chamber in which the gas injected from the gas injection nozzle is flame burned; and a catalyst-assisted combustor including a catalyst-assisted combustor which is heated by using heat generated and mixed with an exhaust gas of the first combustion chamber, A first heat exchanger for heating the fuel and water supplied to the reformer by using heat generated from the combustor, and a second heat exchanger for heating external air supplied to the fuel cell stack using heat generated in the catalytic auxiliary combustor And a group.

Description

TECHNICAL FIELD [0001] The present invention relates to a high-temperature power generation fuel cell system having a catalytic auxiliary combustor,

The present invention relates to a high-temperature power generation fuel cell system having a catalyst-assisted combustor, and more particularly, to a fuel cell system for a high-temperature power generation system in which exhaust gas from a fuel cell stack is completely burned through primary combustion and secondary combustion, There is provided a catalyst-assisted combustor capable of reducing the costs that can be incurred by using a large amount of noble metal catalyst, improving the durability of the system, reusing heat generated in the combustion process, To a fuel cell system.

A fuel cell is a power generation system that converts hydrogen from fuel such as natural gas or methanol into oxygen by reacting with oxygen in the atmosphere to convert the chemical energy of the fuel directly into electric energy through chemical reaction. In the existing thermal power generation system, the thermal energy obtained by burning the fossil fuel is converted into mechanical energy and then converted into electrical energy. However, the efficiency is very high in theory by eliminating the intermediate process, and the pollutant caused by the combustion of fossil fuel Can be reduced.

Fuel cells can be classified into low temperature fuel cells such as Phosphoric Acid Fuel Cell (PAFC), Polymer Electrolyte Fuel Cell (PEFC), and Molten Carbonate Fuel Cell (MCFC) temperature fuel cell such as a solid oxide fuel cell (SOFC) or a high-temperature fuel cell. Among them, particularly, the fuel cell for high temperature is economical because it does not require a noble metal electrode due to its high reaction speed at a high temperature, provides various fuel selectivity, and has an advantage of increasing power generation efficiency. have.

1 is a schematic diagram of a conventionally proposed high temperature power generation fuel cell system. The fuel cell system for high temperature power generation consists of a reformer, a stack, a combustor, and other peripherals.

The anode of the stack is fed with fuel containing hydrogen through a reformer. The anode exhaust gas contains unreacted fuel components such as H ₂ , CO, and CH _{4 that} are generated during the reforming process because 50 to 70% of the reformed fuel is reacted at the anode. However, the presence of a large amount of CO ₂ , H ₂ O, etc. generated during the reaction leads to a very low concentration of combustible components in the fuel.

Since the ratio of the reaction components in the exhaust gas is low, there are a method of supplying fuel additionally and a method of using a catalytic combustor as a method for completely burning it. However, the use of additional fuels may lead to a decrease in system efficiency, so catalytic combustors with excellent reactivity under lean conditions are widely used.

However, since the catalytic combustor uses a noble metal catalyst such as platinum (Pt) and palladium (Pd) in order to increase the reactivity, it is disadvantageous in that it is expensive.

Also, when the temperature of the catalyst layer rises above the endurance temperature of the catalyst due to the characteristics of the combustion catalyst, there is a problem that the catalyst is damaged and the service life is shortened.

SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems and it is an object of the present invention to provide a fuel cell system for high temperature power generation having a catalyst-assisted combustor capable of reducing the cost incurred in completely burning exhaust gas of a fuel cell stack only by catalytic combustion It has its purpose.

Another object of the present invention is to provide a high-efficiency fuel cell system for high-temperature power generation, which is equipped with a catalyst-assisted combustor capable of improving the durability by preventing the temperature of the catalyst layer from exceeding the durability temperature of the catalyst.

In order to accomplish the above object, the present invention provides a high-temperature power generation fuel cell system including a catalytic auxiliary combustor according to the present invention, comprising: a reformer for generating hydrogen by supplying fuel and water by a reforming reaction; A first combustion chamber in which a combustion catalyst is accommodated and external air and an exhaust gas of the anode are injected to be catalytically burned; And a second combustion chamber in which the gas injected from the gas injection nozzle is flame-burned, the catalyst-assisted combustor comprising: a gas-injection nozzle for heating by using heat generated from the first combustion chamber and mixing with the exhaust gas of the first combustion chamber, And a control unit.

Here, in order to promote the reforming reaction in the reformer and improve the reactivity of the stack, a first heat exchanger that heats the fuel and water supplied to the reformer using heat generated in the catalyst auxiliary combustor, or a first heat exchanger And a second heat exchanger for heating external air supplied to the fuel cell stack using heat generated by the second heat exchanger.

In addition, it is desirable to install a gas turbine in the system in order to increase the power generation efficiency of the fuel cell system. At this time, the gas turbine is composed of a compressor which pressurizes the outside air supplied to the fuel cell stack, a turbine which is driven by the exhaust gas of the catalytic auxiliary combustor, and a generator which can generate electricity from the turbine.

In order to promote the mixing of the exhaust gas exiting through the exhaust hole and the external air supplied from the air supply pipe after completing the primary combustion in the first combustion chamber of the catalytic combustion combustor, It is preferable that the swirl unit further includes a swirl unit for generating a turbulent flow.

According to the present invention, since the air supplied through the air supply pipe is heated by using the heat generated by the primary combustion of the catalytic auxiliary combustor, and the preheated air and the primary effluent gas are mixed to perform the secondary combustion, .

In addition, by using the combustion process of the first stage and the second stage, the amount of excess air can be reduced more than when the catalytic combustor is used alone, so that the capacity of the equipment or the compressor to inject air can be reduced, The efficiency is improved.

Further, the heat generated by the primary combustion is heat-exchanged with the air supplied through the air supply pipe, and the heat generated in the catalytic auxiliary combustor by the primary and secondary combustion causes the fuel, water and air supplied to the fuel cell stack The thermal efficiency of the system is improved by allowing heat exchange. Further, by controlling the amount of air for the primary combustion, the catalyst can be kept from rising above the durability temperature, thereby preventing thermal damage, thereby improving the durability of the system.

In addition, since the amount of catalyst used to burn out the exhaust gas of the fuel cell stack can be reduced, the cost that can be incurred by using a large amount of the noble metal catalyst can be reduced.

Here, there is an advantage that power generation efficiency can be increased without additional power supply by driving the compressor which generates electricity by the gas turbine driven by the exhaust gas of the catalytic auxiliary combustor and pressurizes and supplies the external air to the fuel cell stack.

In addition, in the catalytic-assisted combustor, the unburned fuel and air are mixed easily by mixing the exhaust gas that has passed through the primary combustion and the turbulent air passing through the swirl part, thereby assisting secondary combustion.

1 is a schematic diagram of a conventional high temperature power generation fuel cell system.
2 is a schematic view of a fuel cell system for high temperature power generation including a catalytic auxiliary combustor according to a first embodiment of the present invention.
3 is a cross-sectional view of a catalytic auxiliary combustor of a high temperature power generation fuel cell system having a catalytic auxiliary combustor according to a first embodiment of the present invention.
FIG. 4 is a cross-sectional view of the catalyst-assisted combustor of FIG. 3 taken along line A-A '.
FIG. 5 is a cross-sectional view of the catalyst-assisted combustor of FIG. 3 taken along line B-B '.
6 is a schematic view of a fuel cell system for high temperature power generation including a catalytic auxiliary combustor according to a second embodiment of the present invention.

Hereinafter, a high temperature power generation fuel cell system 100 having a catalyst auxiliary combustor according to a first embodiment of the present invention will be described with reference to the accompanying drawings.

2 is a schematic view of a high-temperature power generation fuel cell system including a catalytic auxiliary combustor according to a first embodiment of the present invention. FIG. 3 is a schematic view of a high- FIG. 4 is a cross-sectional view of the catalyst-assisted combustor of FIG. 3 taken along line A-A ', and FIG. 5 is a cross-sectional view of the catalyst-assisted combustor of FIG. 1 is a cross-sectional view showing a cut section. This will be described below with reference to Figs. 2 to 5. Fig.

The high temperature power generation fuel cell system 100 including the catalytic auxiliary combustor according to the present embodiment includes a reformer 200, a fuel cell stack 300, a catalytic auxiliary combustor 400, a first heat exchanger 500, And a heat exchanger (600).

The reformer 200 supplies fuel and water and generates hydrogen by a reforming reaction.

The fuel cell stack 300 has an anode 310 and a cathode 320 and generates electrical energy by chemical reaction using external air and hydrogen supplied from the reformer 200.

The catalytic auxiliary combustor 400 includes a first combustion chamber 410 in which the combustion catalyst 411 is accommodated and external air and the exhaust gas of the fuel cell stack 300 are injected and catalytically burned, And a second combustion chamber 430 in which the gas injected from the gas injection nozzle 420 is flame burned. The gas injection nozzle 420 injects the mixed gas and the heated external air.

The first combustion chamber 410 includes a pipe portion 413 for receiving the combustion catalyst 411 and one end to which the exhaust gas of the fuel cell stack 300 is injected, And a discharge hole 412 formed in the outer circumferential surface of the pipe portion 413 to discharge the combustion exhaust gas from the combustion catalyst 411.

The pipe 413 is formed in a cylindrical shape so that the combustion catalyst 411 is provided therein and the discharge hole 412 is formed in the pipe 413 between the region where the combustion catalyst 411 is accommodated and the stopper 414 A plurality is formed on the outer circumferential surface. The combustion catalyst 411 is filled in the inside of the pipe portion 413 and the endurance temperature is about 800 to 900 DEG C, so that damage may occur when more heat is generated.

The gas injection nozzle 420 surrounds an area where the combustion catalyst 411 of the first combustion chamber 410 is accommodated and generates heat by the heat generated in the first combustion chamber 410, A heating unit 422 for heating the outside air supplied from the air supply pipe 421 and a heating unit 422 for heating the outside air passing through the heating unit 422 and the exhaust gas passing through the exhaust hole 412, A mixing hole 423 in which the gas passing through the mixing portion 423 is injected into the second combustion chamber 430 and a discharge hole 424 in which the outside air is discharged from the discharge hole 412 And a swirl portion 425 for forming a turbulent flow before mixing.

The heating portion 422 is formed in a ring shape so as to surround the cylindrical pipe portion 413. The heating section 422 is configured to double the pipe section 413 so that the heat generated in the first combustion chamber 410 sufficiently heats the external air passing through the heating section 422 through the wall surface of the pipe section 413 .

In the present embodiment, the swage portion 425 is formed so that the external air, which has passed through the swirl portion 425 and is turbulent, is mixed with the exhaust gas exiting the discharge hole 412 in a state where the irregular flow is maximized 422 to the discharge hole 412 in the region immediately preceding the discharge hole 412. Although the swage portion 425 takes the shape of the swirl portion formed along the ring-shaped heating portion 422, it can be any shape as long as it can generate turbulence in the outside air.

The first heat exchanger 500 and the second heat exchanger 600 are connected to the fuel and water supplied to the reformer 200 using the heat generated in the catalyst auxiliary combustor 400, And heats the external air supplied to the combustor 400.

Hereinafter, the operation of the high temperature power generation fuel cell system 100 having the catalyst auxiliary combustor according to the first embodiment of the present invention will be described.

The reformer 200, which has been supplied with the fuel and the water, converts CH ₄ + H ₂ O - > CO + 3H ₂ To produce hydrogen.

Generally, in the anode 310 of the fuel cell stack 300, hydrogen is oxidized and electrons are generated. By using the reformer 200, a fuel gas containing a hydrogen component such as methane or propane is reformed to obtain hydrogen Therefore, various kinds of gas can be used as fuel.

The hydrogen generated in the reformer 200 moves to the anode 310 of the fuel cell stack 300 and is supplied to the anode 310 of the fuel cell stack 300 as H ₂ + CO ₃ ^{2 -} > H ₂ O + CO ₂ + 2e ^- In the case of a battery, electrons are generated through a chemical reaction of H ₂ + O ^{2 -} → H ₂ O + 2e ^- .

In the cathode 320 of the fuel cell stack 300, the oxygen contained in the supplied external air is used for the molten carbonate fuel cell to react again by the reaction of 1/2 O ₂ + CO ₂ + _{2 e} ^- → CO ₃ ^{2 -} In the case of a solid oxide fuel cell, oxygen ions are generated through a chemical reaction of ½ O ₂ + 2e ^- → O ^{2 -} and transferred through the electrolyte.

The catalyst auxiliary combustor 400 serves to completely burn off the exhaust gas of the anode 310 of the fuel cell stack. The exhaust gas of the stack anode 310 includes H ₂ , And unreacted fuel components such as CO and remaining CH _{4 that} have not participated in the reforming reaction. However, since CO ₂ and H ₂ O are generated in the reaction process, the concentration of combustible components in the total exhaust gas is very low.

Since the combustion catalyst 411 is excellent in reactivity, even if the concentration of the combustible component in the exhaust gas is low, it can be combusted. When the exhaust gas of the stack anode 310 is injected into the pipe section 413 of the first combustion chamber 410 together with the outside air, the exhaust gas passes through the region where the combustion catalyst 411 is filled in the pipe section 413, .

Since the one end of the pipe portion 413 is closed by the stopper portion 414, the gas that has passed through the region filled with the combustion catalyst 411 escapes to the gas injection nozzle 420 through the exhaust hole 412.

External air is injected into the gas injection nozzle 420 through the air supply pipe 421. The injected outside air passes through the channel of the heating unit 422 which doubly surrounds the region where the catalyst of the pipe unit 411 is accommodated. Heat generated in the combustion catalyst 412 in the primary combustion process is transferred to the pipe section 411, which in turn contacts the pipe section 411 and is transferred to the flowing external air. Heat exchange occurs between the pipe section 411 and the outside air, and the pipe section 411 having a high temperature is cooled again, and the temperature of the outside air having a relatively low temperature rises. As described above, the risk that the heat generated in the combustion catalyst 412 by the catalytic combustion is transferred to the outside air through the heating portion 422 and the combustion catalyst 412 is cooled, .

Also, since the temperature of the combustion catalyst 412 can be kept below the durability temperature by the heat exchange, the amount of excess air necessary for preventing the temperature of the combustion catalyst 412 from rising excessively can be reduced. When the general catalytic combustor is used, the excess air ratio is about 300 to 400%. However, when the catalytic combustor 400 according to the present invention is used, complete combustion can be performed even with an excess air amount of about 120%. This reduces the facilities required for air injection and the capacity of the compressor 700 to be described later, resulting in an improvement in efficiency of the entire system.

The exhaust gas that has exited through the exhaust hole 413 after the first combustion with the heated outside air is mixed in the mixing portion 423 and is sent to the second combustion chamber. Here, the outside air is converted into turbulent flow through the swirling section 425 before reaching the mixing section 423. By increasing the turbulence intensity of the outside air, mixing with the exhaust gas can be promoted, which facilitates secondary combustion in the second combustion chamber 430 by allowing the unreacted fuel component and the oxygen contained in the air to easily mix.

Secondary combustion is burning accompanied by flame. The mixed gas in the mixing portion 423 is injected into the second combustion chamber 430 through the injection hole 424 to perform secondary combustion. The combustion efficiency can be increased by preheating the outside air constituting the mixed gas, Thereby enabling complete combustion. As a result, the amount of the combustion catalyst 412 used for burning the exhaust gas of the fuel cell stack 300 in the primary combustion can be reduced, so that it is possible to reduce the cost that can be incurred by using a large amount of the noble metal catalyst.

The heat generated in the catalytic auxiliary combustor 400 through the primary combustion and the secondary combustion is used to heat the fuel and water supplied to the reformer 200 through the first heat exchanger 500. Since the reforming reaction is a high endothermic reaction, the reforming reaction in the reformer 200 can be promoted by using the preheated fuel and water.

 And is also used to heat the outside air supplied to the fuel cell stack 300 and the catalytic auxiliary combustor 400 through the second heat exchanger 600. [ The preheated external air improves the thermal efficiency of the entire system by improving the reactivity of the chemical reaction inside the fuel cell stack 300 and the primary and secondary combustion inside the catalytic auxiliary combustor 400.

Hereinafter, a high temperature power generation fuel cell system 100 having a catalyst auxiliary combustor according to a second embodiment of the present invention will be described with reference to the accompanying drawings. Members designated by the same reference numerals as those of the members shown in Figs. 2 to 5 have the same configuration and function, and therefore detailed description of the overlapping portions is omitted.

6 is a schematic view of a fuel cell system for high temperature power generation including a catalytic auxiliary combustor according to a second embodiment of the present invention. This will be described below with reference to FIG.

The high temperature power generation fuel cell system 100 having the catalyst auxiliary combustor according to the present embodiment includes a gas turbine system capable of generating electric power. The gas turbine is composed of an air supplyable compressor 700, a turbine 800 driven by an exhaust gas, and a generator 900 generating electricity by the rotational force of the turbine 800.

The turbine 800 is driven by the high temperature exhaust gas generated after the secondary combustion in the second combustion chamber 430 of the catalytic auxiliary combustor 400. The fuel cell stack 300 and the catalytic auxiliary combustor 400 are connected to each other through a compressor 700 driven by a part of the generated electric power through a generator 900 driven by the rotational force of the turbine 800, So that there is no need to use external electric power for supplying external air.

100: High-temperature power generation fuel cell system equipped with a catalyst auxiliary sequence
200: Reformer 300: Fuel cell stack
310: anode 320: cathode
400: catalytic auxiliary combustor 410: first combustion chamber
411: Combustion catalyst 412: Exhaust hole
413: pipe section 414:
420: gas injection nozzle 421: air supply pipe
422: heating section 423: mixing section
424: minute spray hole 425:
430: second combustion chamber 500: first heat exchanger
600: second heat exchanger 700: compressor
800: Turbine 900: Generator

Claims (6)

A reformer for generating hydrogen by a reforming reaction by supplying fuel and water;
A fuel cell stack having an anode and a cathode and producing electrical energy by chemical reaction using outside air and hydrogen supplied from the reformer;
A first combustion chamber in which the combustion catalyst is accommodated and the outside air and the exhaust gas of the anode are injected to be catalytically burned; heating using the heat generated in the first combustion chamber by receiving external air; And a second combustion chamber in which a gas injected from the gas injection nozzle is flame-ignited, wherein the catalyst-assisted combustor includes a catalyst-assisted combustor. The method according to claim 1,
Further comprising a first heat exchanger for heating the fuel and water supplied to the reformer using heat generated from the catalyst auxiliary combustor. The method according to claim 1,
Further comprising a second heat exchanger for heating external air supplied to the fuel cell stack and the catalytic auxiliary combustor by using heat generated from the catalytic auxiliary combustor. system. The method according to claim 1,
A compressor for pressurizing the outside air supplied to the fuel cell stack;
A turbine driven by the exhaust gas of the catalytic auxiliary combustor;
Further comprising a generator capable of generating electricity from the turbine. ≪ Desc / Clms Page number 24 > The method according to claim 1,
Wherein the gas injection nozzle includes a swirl portion for allowing the supplied external air to form a turbulent flow. The method according to claim 1,
Wherein the first combustion chamber includes a pipe portion in which the combustion catalyst is accommodated and the exhaust gas of the fuel cell stack is injected as one end, a plug portion that is coupled to the other end of the pipe portion, And a discharge hole through which the gas escapes,
Wherein the gas injection nozzle comprises an air supply pipe for supplying external air, a heating unit for double-wrapping the area of the first combustion chamber accommodating the combustion catalyst and heating the external air supplied from the air supply pipe, And a spray hole into which the gas having passed through the mixing section is injected into the second combustion chamber. The high-temperature power generation apparatus according to claim 1, Fuel cell system.

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