KR101134551B1 - Jelly carbonated beverage and the manufacturing method thereof - Google Patents

Jelly carbonated beverage and the manufacturing method thereof Download PDF

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KR101134551B1
KR101134551B1 KR1020090116636A KR20090116636A KR101134551B1 KR 101134551 B1 KR101134551 B1 KR 101134551B1 KR 1020090116636 A KR1020090116636 A KR 1020090116636A KR 20090116636 A KR20090116636 A KR 20090116636A KR 101134551 B1 KR101134551 B1 KR 101134551B1
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weight
jelly
gelling agent
gel
syrup
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KR20110060138A (en
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홍권표
성기준
이종수
허철성
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주식회사 팔도
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/40Effervescence-generating compositions
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/54Mixing with gases
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2200/00Function of food ingredients
    • A23V2200/20Ingredients acting on or related to the structure
    • A23V2200/228Gelling agent

Abstract

본 발명은 기존의 젤리음료 보다 강도가 단단하고 겔 복원력이 좋은 젤리탄산음료 및 그의 제조방법에 관한 것으로서, 젤란검, 구아검 및 LM-펙틴로 이루어진 겔화제 0.155~0.42중량%, 백설탕 6~8중량%, 아스파탐 0.01~0.02중량%, 아세설팜칼륨 0.005~0.008중량%, 젖산칼슘 0.1~0.2중량%, 무수구연산 0.3~0.35중량%, 사과농축액 0.8~1중량%, 착향료 0.08~0.12중량%, 자몽종자추출물 0.001~0.003중량% 및 잔량의 정제수를 혼합하여 제조된 액상의 젤리시럽을 포함하는 것을 특징으로 하는 젤리탄산음료 및 그의 제조방법을 제공함으로써 겔 강도와 겔 복원력이 좋아 보다 안정성있는 젤리탄산음료를 제조하고, 기존의 탄산음료 제조방법인 3~5배 시럽배합을 통한 정제수와의 2중 배합과정을 거친 후 탄산을 투입하는 방법에서 벗어나 한번의 배합을 통한 탄산투입으로 제조공정을 간소화함으로서 생산비용을 줄이는 효과를 기대할 수 있다. The present invention relates to a jelly drink having a stronger strength and better gel resilience than a conventional jelly drink, and a method for producing the same, comprising a gelling agent of 0.155 to 0.42% by weight of gellan gum, guar gum and LM-pectin, and white sugar 6 to 8 Weight%, Aspartame 0.01-0.02 weight%, Acesulfame potassium 0.005-0.008 weight%, Calcium lactate 0.1-0.2 weight%, Citric anhydride 0.3-0.35 weight%, Apple concentrate 0.8-1 weight%, Flavoring agent 0.08-0.12 weight% , Jelly jelly seed extract 0.001 ~ 0.003% by weight and the remaining amount of purified water prepared by mixing the jelly syrup, characterized in that it comprises a liquid jelly syrup, gel strength and gel resilience is good and more stable jelly After the carbonated beverage is prepared, and after the double mixing process with purified water through 3 ~ 5 times syrup blending, which is a conventional carbonated beverage manufacturing method, the carbonic acid is introduced through a single blending process. By reducing the cost of production.

젤란검, 구아검, LM-펙틴, 겔화제, 젤리탄산음료 Gellan gum, guar gum, LM-pectin, gelling agent, jelly drink

Description

젤리탄산음료 및 그의 제조방법{Jelly carbonated beverage and the manufacturing method thereof}Jelly carbonated beverage and the manufacturing method

본 발명은 젤리탄산음료 및 그의 제조방법에 관한 것으로, 보다 상세하게는 기존의 젤리음료 보다 강도가 단단하고 겔 복원력이 좋은 젤리탄산음료 및 그의 제조방법에 관한 것이다.TECHNICAL FIELD The present invention relates to a jelly beverage and a method for producing the same. More particularly, the present invention relates to a jelly and a method for preparing a jelly beverage having a stronger strength and better gel resilience than conventional jelly beverages.

기존의 젤리음료 및 젤리탄산음료는 겔형성을 위한 잔탄검(xanthan gum), 펙틴(pectin), 카라기난(carrageenan) 등을 사용하여 젤리음료를 만든 후 봉입하는 방법으로 하여 젤리탄산음료를 제조하고 있다. 주로 사용되는 겔화제인 카라기난은 홍조류를 뜨거운 물 또는 뜨거운 알칼리 수용액으로 추출한 후 정제하여 얻어지는 것으로 보수력이 우수하며 시간이 지남에 따른 점도 변화가 없는 것이 특징이나 온도의 상승과 교반에 의한 점성의 감소현상이 나타난다. 특히 여름철 온도 상승에 따른 점성의 약화로 인해 제품의 클레임 발생이 우려되는 실정으로서, 카라기난의 점성이 약화되어 네트워크 형성이 깨어지게 되어 겔 형성이 깨어지면 흔들어 먹는 탄산음료의 경우에 흔들어 캔을 따는 순간 탄산의 분출 등이 발생하는 문제점이 있다.Existing jelly beverages and jelly beverages are prepared using a xanthan gum, pectin, carrageenan, etc. to form a jelly beverage and then encapsulated the jelly beverage. . Carrageenan, a commonly used gelling agent, is obtained by extracting red algae with hot water or a hot alkaline aqueous solution and purifying it. It has excellent water retention and no viscosity change over time. However, viscosity decreases due to temperature rise and agitation. appear. Particularly, there is a concern that product claims may occur due to the weakening of viscosity due to the increase in temperature in the summer.As a carbonated beverage is shaken when a carbonated beverage is shaken when the gel formation is broken due to weakening of carrageenan viscosity There is a problem that the ejection of carbonic acid or the like occurs.

이에 본 발명자들은 보수력이 우수하고 시간이 지남에 따른 점도 변화가 없으면서 온도의 상승과 교반에 의한 점성이 감소되지 않는 다른 식품 재료를 연구하여 본 발명을 완성하게 되었다.Accordingly, the present inventors have completed the present invention by studying other food materials having excellent water retention and no viscosity change with time, and the viscosity is not reduced due to temperature rise and stirring.

상기와 같은 문제점을 해결하기 위하여, 본 발명은 겔 강도와 겔 복원력이 좋은 젤리탄산음료 및 그의 제조방법을 제공하는 것을 목적으로 한다.In order to solve the above problems, it is an object of the present invention to provide a jelly drink with good gel strength and gel restoring power and a method for producing the same.

또한, 본 발명은 기존의 탄산음료 제조방법인 3~5배 시럽배합을 통한 정제수와의 2중 배합과정을 거친 후 탄산을 투입하는 방법에서 벗어나 한번의 배합을 통한 탄산투입으로 제조공정을 간소화하는 젤리탄산음료의 제조방법을 제공하는 것을 또 다른 목적으로 한다.In addition, the present invention simplifies the manufacturing process by adding carbonic acid through a single blending method after entering the carbonic acid after a double blending process with purified water through the 3 ~ 5 times syrup blending method of the conventional carbonated beverage manufacturing method Another object of the present invention is to provide a method for preparing a jelly drink.

상기와 같은 목적을 달성하기 위하여, 본 발명은 젤란검, 구아검 및 LM-펙틴로 이루어진 겔화제 0.155~0.42중량%, 백설탕 6~8중량%, 아스파탐 0.01~0.02중량%, 아세설팜칼륨 0.005~0.008중량%, 젖산칼슘 0.1~0.2중량%, 무수구연산 0.3~0.35중량%, 사과농축액 0.8~1중량%, 착향료 0.08~0.12중량%, 자몽종자추출물 0.001~0.003중량% 및 잔량의 정제수를 혼합하여 제조된 액상의 젤리시럽을 포함하는 젤리탄산음료를 제공하는 것을 특징으로 한다.In order to achieve the above object, the present invention is a gelling agent composed of gellan gum, guar gum and LM-pectin 0.155 ~ 0.42% by weight, white sugar 6-8% by weight, aspartame 0.01 ~ 0.02% by weight, acesulfame potassium 0.005 ~ 0.008% by weight, calcium lactate 0.1-0.2% by weight, citric anhydride 0.3-0.35% by weight, apple concentrate 0.8-1% by weight, flavoring agent 0.08-0.12% by weight, grapefruit seed extract 0.001-0.003% by weight and the remaining amount of purified water It is characterized in that it provides a jelly drink containing a liquid jelly syrup prepared.

또한, 본 발명은 a)젤란검, 구아검 및 LM-펙틴로 이루어진 겔화제 0.155~0.42중량%와 백설탕 6~8중량%의 분체 혼합물을 정제수에 충분히 분산시켜 현탁액을 제조하는 공정; b)상기 a)공정의 현탁액에 아스파탐 0.01~0.02중량%와 아세설팜칼륨 0.005~0.008중량%를 투입하는 공정; c)상기 b)공정의 혼합물에 무수구연산 0.3~0.35중량%와 젖산칼슘 0.1~0.2중량%를 정제수에 용해시킨 혼합물을 혼합하는 공정; d)상기 c)공정의 혼합물에 사과농축액 0.8~1중량%, 자몽종자추출물 0.001~0.003중량% 및 착향료 0.08~0.12중량%를 혼합하여 액상의 젤리시럽을 제조하는 공정; 및 e)상기 d)공정의 액상의 젤리시럽에 탄산가스를 봉입한 것을 용기에 충전하여 밀폐한 후, 가열하여 졸화하고 냉각하여 겔화하는 공정을 포함하여 제조되는 젤리탄산음료의 제조방법을 제공하는 것을 특징으로 한다.In addition, the present invention is a) a process for preparing a suspension by sufficiently dispersing a powder mixture of a gelling agent of 0.155 ~ 0.42% by weight of gelling gum, guar gum and LM-pectin and 6 to 8% by weight of white sugar in purified water; b) adding 0.01% to 0.02% by weight of aspartame and 0.005% to 0.008% by weight of acesulfame potassium in the suspension of step a); c) mixing a mixture of 0.3 to 0.35% by weight of citric anhydride and 0.1 to 0.2% by weight of calcium lactate in purified water to the mixture of step b); d) preparing a liquid jelly syrup by mixing 0.8 ~ 1% by weight of apple concentrate, 0.001 ~ 0.003% by weight of grapefruit seed extract, and 0.08 ~ 0.12% by weight of flavoring agent, to the mixture of step c); And e) filling the container with the carbonic acid gas in the liquid jelly syrup of step d) to seal the container, and then heating and solving and cooling to gelate the method. It is characterized by.

이하, 본 발명을 상세하게 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated in detail.

먼저, 총 조성물 100중량%를 기준으로 젤란검, 구아검 및 LM-펙틴로 이루어진 겔화제 0.155~0.42중량%와 백설탕 6~8중량%의 분체 혼합물을 정제수에 충분히 분산시켜 현탁액을 제조한다.First, a suspension is prepared by sufficiently dispersing a mixture of 0.155 to 0.42 wt% of a gelling agent consisting of gellan gum, guar gum and LM-pectin and 6 to 8 wt% of white sugar in purified water, based on 100 wt% of the total composition.

상기 겔화제는 겔화제 100중량%를 기준으로 젤란검 64.5~71.4중량%, 구아검 3.2~4.8중량% 및 LM-펙틴 23.8~32.3중량%로 이루어진 것이 바람직하다. The gelling agent is preferably composed of 64.5 to 71.4% by weight of gellan gum, 3.2 to 4.8% by weight of guar gum and 23.8 to 33.3% by weight of LM-pectin based on 100% by weight of the gelling agent.

여기서, 젤란검은 포도당(glucose), 글루콘산(gluconic acid), 람노스(rhamnose)가 규칙적으로 반복된 곧은 사슬 모양의 다당류로 식품의 점도를 증가시키기 위하여 사용하는 것으로서 겔 강도를 단단히 하고 겔 복원력을 좋게 하기 위하여 겔화제 100중량%를 기준으로 64.5~71.4중량%로 하는 것이 바람직하다.Here, gellan gum is a straight-chain polysaccharide in which glucose, gluconic acid, and rhamnose are regularly repeated to increase the viscosity of food. In order to make it good, it is preferable to set it as 64.5-71.4 weight% with respect to 100 weight% of gelling agents.

여기서, 구아검은 식품의 점도를 증가시키고 식품의 물성과 촉감을 향상 시키기 위해 사용하는 것으로서 겔 강도와 겔 복원력이 우수하나 이미(異味)? 이취(異臭 )에 대한 문제가 있기 때문에 겔화제 100중량%를 기준으로 3.2~4.8중량%로 하는 것이 바람직하다.Here, guar gum is used to increase the viscosity of foods and to improve the physical properties and feel of foods. Since there is a problem about odor, it is preferable to set it as 3.2 to 4.8 weight% based on 100 weight% of gelling agents.

여기서, LM-펙틴은 식품의 점도를 높이는 역할을 하는 것으로서 특히 칼슘이온과의 반응성이 강하여 겔 네트워크 형성이 방해되는 것을 방지하기 위하여 겔화제 100중량%를 기준으로 23.8~32.3중량%로 하는 것이 바람직하다.Here, LM-pectin plays a role of increasing the viscosity of food, and in particular, it is preferable to set it as 23.8 to 33.3% by weight based on 100% by weight of the gelling agent in order to prevent the gel network formation due to its high reactivity with calcium ions. Do.

또한, 겔화제는 0.155중량% 미만의 경우에는 겔의 네트워크 형성이 약해 충분한 겔의 형성을 보이지 않을 수가 있고, 0.42중량% 초과의 경우에는 겔의 형성이 너무 강해 너무 단단한 겔을 형성할 수가 있기 때문에 총 조성물 100중량%를 기준으로 0.155~0.42중량% 범위인 것이 바람직하다.In addition, since the gelling agent is less than 0.155% by weight of the gel network formation is weak, it may not show the formation of a sufficient gel, when the gelling agent is more than 0.42% by weight the gel formation is too strong to form a too hard gel It is preferably in the range of 0.155 to 0.42% by weight based on 100% by weight of the total composition.

겔화제의 용해방법은 일반적인 방법에 따르며, 예를 들어, 적정량의 물에 겔화제와 설탕 등을 분체혼합한 것을 충분히 분산시킨 후, 겔화제가 충분히 용해하는 온도까지 자켓식탱크 및 플레이트식 열교환기 등을 이용하여 가열하여도 좋고, 65~95℃ 정도의 열수에 직접 겔화제와 설탕 등의 분체혼합물을 투입하여 교반하여 완전용해시켜도 좋다. 이때, 파워블랜더 등의 용해기를 사용할 수도 있다. 또한 가열조건의 설정에 따라 액상 겔의 살균에 이용할 수 있다. 또한 이 조건은 겔화제의 용해성 및 최종상품의 형태 및 품질, 생산공정의 설비 등에 의해 적절하게 결정된다.The method of dissolving the gelling agent follows a general method, for example, after sufficiently dispersing the powdered mixture of the gelling agent and sugar in an appropriate amount of water, and then jacketing tank and plate heat exchanger to a temperature where the gelling agent is sufficiently dissolved. It may be heated by using a mixture, or a powder mixture such as a gelling agent and sugar may be directly added to hot water at about 65 to 95 ° C, stirred, and completely dissolved. At this time, a dissolver such as a power blender may be used. Moreover, it can use for sterilization of a liquid gel according to setting of heating conditions. In addition, this condition is appropriately determined by the solubility of the gelling agent, the form and quality of the final product, the equipment of the production process, and the like.

또한, 백설탕은 수크로오스(sucrose)를 주성분으로 하는 감미료로서 적절한 단맛을 위하여 총 조성물 100중량%를 기준으로 6~8중량%로 하는 것이 바람직하다.In addition, white sugar is a sweetener based on sucrose (sucrose) is preferably from 6 to 8% by weight based on 100% by weight of the total composition for proper sweetness.

다음으로, 상기 현탁액에 아스파탐 0.01~0.02중량%와 아세설팜칼륨 0.005~0.008중량%를 투입한다.Next, 0.01 to 0.02% by weight of aspartame and 0.005 to 0.008% by weight of acesulfame potassium are added to the suspension.

이때, 상기 아스파탐(aspartame)은 페닐알라닌과 아스파르트산을 합성해 만든 아미노산계 저칼로리 감미료로서 총 조성물 100중량%를 기준으로 0.01~0.02중량%로 하는 것이 바람직하다.At this time, the aspartame (aspartame) is an amino acid-based low-calorie sweetener made by synthesizing phenylalanine and aspartic acid, preferably 0.01 to 0.02% by weight based on 100% by weight of the total composition.

상기 아세설팜칼륨(acesulfame potassium)은 설탕의 200배의 감미도를 지닌 무열량 감미료로 낮은 농도에서 특히 높은 감미를 나타내기 때문에 총 조성물 100중량%를 기준으로 0.005~0.008중량%로 하는 것이 바람직하다.Acesulfame potassium is a calorie-free sweetener having a sweetness of 200 times that of sugar, and since it shows particularly high sweetness at a low concentration, it is preferable to set it as 0.005 to 0.008% by weight based on 100% by weight of the total composition. .

다음으로, 무수구연산 0.3~0.35중량%와 젖산칼슘 0.1~0.2중량%를 정제수에 용해시킨 별개의 혼합물을 제조한 후 상기 아스파탐과 아세설팜칼륨이 혼합된 현탁액에 혼합한다.Next, after preparing a separate mixture in which 0.3 to 0.35% by weight of citric anhydride and 0.1 to 0.2% by weight of calcium lactate are prepared in purified water, the mixture is mixed with the suspension in which the aspartame and acesulfame potassium are mixed.

이때, 상기 무수구연산은 천연의 감귤 과즙에 많이 함유되어 있고, 설탕, 당질, 녹말, 포도당의 발효에 의해 얻어지는 물질로 강한 신맛을 내는 무색투명의 입자로서 일반적으로 음료수나 과일 관련 가공식품을 만드는 데 쓰이는 첨가물로 총 조성물 100중량%를 기준으로 0.3~0.35중량%로 하는 것이 바람직하다.At this time, the citric anhydride is contained in a lot of natural citrus juice, sugar, sugar, starch, glucose is a substance obtained by fermentation of strong acidic colorless transparent particles in general to make beverages or fruit-related processed foods The additive is preferably 0.3 to 0.35% by weight based on 100% by weight of the total composition.

상기 젖산칼슘은 2가 양이온을 공급함으로서 겔 네트워크 형성에 도움을 주고자 사용하는 것으로서 0.1중량% 미만의 경우에는 겔 네트워크 형성이 약해 겔이 약하게 형성될 수가 있고, 0.2중량% 초과의 경우에는 너무 강도가 강한 겔을 형성할 수 있기 때문에 총 조성물 100중량%를 기준으로 0.1~0.2중량%로 하는 것이 바람직하다.The calcium lactate is used to assist in the formation of a gel network by supplying a divalent cation. When less than 0.1% by weight, the gel network is weakly formed, so that the gel may be weakly formed. Since it is possible to form a strong gel is preferably from 0.1 to 0.2% by weight based on 100% by weight of the total composition.

다음으로, 상기의 무수구연산과 젖산칼슘를 정제수에 용해시킨 별개의 혼합물과 상기 아스파탐과 아세설팜칼륨이 혼합된 현탁액의 혼합물에 사과농축액 0.8~1중량%, 자몽종자추출물 0.001~0.003중량% 및 착향료 0.08~0.12중량%를 혼합하여 액상의 젤리시럽을 제조한다.Next, 0.8-1% by weight of apple concentrate, 0.001-0.003% by weight of grapefruit seed extract, and flavoring agent in a mixture of a separate mixture of citric anhydride and calcium lactate dissolved in purified water and a suspension of aspartame and acesulfame potassium. To prepare a liquid jelly syrup by mixing 0.08 ~ 0.12% by weight.

상기 사과농축액은 제품에 과즙의 풍미를 제공하기 위하여 사용하는 것으로서 총 조성물 100중량%를 기준으로 0.8~1중량%로 하는 것이 바람직하다.The apple concentrate is used to provide a flavor of the juice to the product, it is preferable to make 0.8 to 1% by weight based on 100% by weight of the total composition.

상기 자몽종자추출물은 쓴맛을 가지나 미생물의 생육을 억제하는 효과가 있어 사용하는 것으로서 0.001중량% 미만의 경우에는 미생물 생육억제에 대한 문제가 있고, 0.003중량% 초과의 경우에는 제품에서 쓴맛을 내기 때문에 총 조성물 100중량%를 기준으로 0.001~0.003중량%로 하는 것이 바람직하다.The grapefruit seed extract has a bitter taste, but is used to inhibit the growth of microorganisms, when less than 0.001% by weight of the problem of inhibiting the growth of microorganisms, if more than 0.003% by weight because the product gives a bitter taste It is preferable to set it as 0.001-0.003 weight% based on 100 weight% of compositions.

상기 착향료는 일반적으로 식품에 사용하는 것이면 제한이 없는 것으로서 총 조성물 100중량%를 기준으로 0.08~0.12중량%로 하는 것이 적당한 향을 내는데 바람직하다.If the flavoring is generally used in food, there is no limitation, it is preferable to make an appropriate flavor to 0.08 ~ 0.12% by weight based on 100% by weight of the total composition.

다음으로, 상기 액상의 젤리시럽에 탄산가스를 봉입한 것을 용기에 충전하여 밀폐 한 후, 가열하여 졸화하고 냉각하여 겔화하여 최종적으로 본 발명의 젤리탄산음료를 제조한다.Next, the liquid jelly syrup is filled with carbonic acid gas in a container and sealed, and then heated, solvated, cooled, and gelled to finally prepare a jelly beverage of the present invention.

액상의 젤리시럽에 대한 탄산가스의 봉입방법은 통상, 탄산가스를 봉입하는 방법으로 가능하다. 예를 들어, 액상의 젤리시럽에 직접 탄산가스를 봉입하는 방법, 액상의 젤리시럽을 1/2~1/5정도의 농축상태로 조합하고, 탄산가스를 봉입하기 직전에 희석하여 탄산가스를 봉입하는 방법, 농축 조합한 액상의 젤리시럽에 탄산수를 블렌드하는 방법 등 임의적으로 설정할 수 있다. 제품 가스 볼륨은 1.5이상이며 무게는 0.2~0.5중량%로 하는 것이 바람직하다.The method of encapsulating carbon dioxide gas in a liquid jelly syrup is usually possible by the method of encapsulating carbon dioxide gas. For example, a method of directly encapsulating carbon dioxide into a liquid jelly syrup, combining the liquid jelly syrup in a concentrated state of about 1/2 to 1/5, diluting immediately before encapsulating carbon dioxide, and encapsulating carbon dioxide gas. It can be arbitrarily set, such as a method of blending, a method of blending the carbonated water to the concentrated liquid jelly syrup. The product gas volume is 1.5 or more and the weight is preferably 0.2 to 0.5% by weight.

액상의 젤리시럽에 탄산가스를 봉입한 후에는 일반적인 방법에 따라 임의의 용기에 충진하고 밀봉한다. 용기는 젤리의 식감을 고려하여 탄산음료용 PET 병이 바람직하나, 그 외 음식용에 적합한 용기라면 특별히 제한을 두지는 않는다.After the carbon dioxide is filled into the liquid jelly syrup, it is filled and sealed in any container according to a general method. The container is preferably a PET bottle for carbonated beverages in consideration of the texture of the jelly, but is not particularly limited as long as the container is suitable for food.

밀봉한 후, 다시 내용물을 겔화온도 이상으로 온도를 높여 액상화(졸화)한다. 이 공정에서 온도조건을 제품의 살균에 맞춰서 실시할 수도 있다. 예를 들어, 온도는 60~75℃로, 시간은 15~45분 등으로 하며, 이 조건은 원료의 배합, 제품의 pH 등에 따라 적절하게 설정할 수 있다.After sealing, the contents are further liquefied (solvated) by raising the temperature above the gelation temperature. In this process, the temperature conditions can be adapted to the sterilization of the product. For example, the temperature is 60 to 75 ° C., the time is 15 to 45 minutes, or the like, and this condition can be appropriately set according to the formulation of the raw materials, the pH of the product, and the like.

액상화(졸화)한 내용물을 겔화 온도 이하, 바람직하게는 20℃ 이하로 냉각하므로써, 탄산가스가 균일하게 봉입되게 할 수 있다.By cooling the contents liquefied (solvated) to a gelling temperature or lower, preferably 20 ° C or lower, carbon dioxide gas can be uniformly enclosed.

본 발명은 겔 강도와 겔 복원력이 좋은 겔화제 선별 및 겔 형성시점에 대한 조사를 통한 젤리탄산음료를 제조함으로서 보다 안정성있는 젤리탄산음료를 제조하고 기존의 탄산음료 제조방법인 3~5배 시럽배합을 통한 정제수와의 2중 배합과정을 거친 후 탄산을 투입하는 방법에서 벗어나 한번의 배합을 통한 탄산투입으로 제조 공정을 간소화함으로서 생산비용을 줄이는 효과를 기대할 수 있다.The present invention is to prepare a more stable jelly carbonate drink by preparing the gel carbonate beverage through the selection of gelling agent having good gel strength and gel restoring power and investigation of the time of gel formation and 3 to 5 times syrup blending of the conventional carbonated drink manufacturing method The process of reducing the production cost by simplifying the manufacturing process by adding carbonic acid through a single blending process after passing through a double compounding process with purified water through a single blending can be expected.

이하 실시예를 통하여 본 발명을 보다 상세하게 설명한다. 그러나 다음의 실시예는 본 발명의 범위를 한정하는 것은 아니며, 본 발명의 기술적 사상의 범위 내에서 당업자에 의한 통상적인 변화가 가능하다.Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the following examples are not intended to limit the scope of the present invention, and ordinary changes by those skilled in the art are possible within the scope of the technical idea of the present invention.

<실시예><Examples>

젤리탄산음료의 제조Preparation of Jelly Carbonate Drink

1-1. 겔화제의 제조1-1. Preparation of Gelling Agent

젤란검 65중량%, 구아검 3.5중량% 및 LM-펙틴 31.5중량%를 혼합하여 겔화제 100중량%를 제조하였다.65% by weight of gelling agent was prepared by mixing 65% by weight of gellan gum, 3.5% by weight of guar gum and 31.5% by weight of LM-pectin.

1-2. 젤리탄산음료의 제조1-2. Preparation of Jelly Carbonate Drink

용해 탱크에 20℃, 62.710중량%의 정제수와 사전에 백설탕 7중량%와 상기 1-1의 겔화제 0.23중량%를 분체 혼합해 둔 것을 믹싱호퍼를 사용하여 투입하고 충분히 분산시켜 현탁액을 얻었다.Into the dissolution tank, 62.710% by weight of purified water, 7% by weight of white sugar and 0.23% by weight of the gelling agent of 1-1 were mixed and mixed with a mixing hopper, and sufficiently dispersed to obtain a suspension.

상기 현탁액에 아스파탐 0.016중량%와 아세설팜칼륨 0.007중량%를 투입하고 이를 40메쉬(mesh) 망을 통과시켜 배합 탱크로 이송하였다.0.016% by weight of aspartame and 0.007% by weight of acesulfame potassium were added to the suspension, which was then passed through a 40 mesh network to a blending tank.

한편, 무수구연산 0.35중량%와 젖산칼슘 0.15중량%를 50℃, 28.635중량%의 정제수에 용해시킨 후 이를 200메쉬 망을 통과시켜 상기 현탁액이 이송된 배합탱크로 이송하였다.Meanwhile, 0.35% by weight of citric anhydride and 0.15% by weight of calcium lactate were dissolved in purified water at 50 ° C. and 28.635% by weight, and then passed through a 200 mesh network to the mixing tank to which the suspension was transferred.

그런 다음, 사과농축액 0.8중량%, 자몽종자추출물 0.002중량% 및 착향료 0.1중량%를 상기 현탁액이 이송된 배합탱크에 투입하여 충분히 교반하여 액상의 젤리시럽을 얻었다.Then, 0.8% by weight of apple concentrate, 0.002% by weight of grapefruit seed extract, and 0.1% by weight of flavoring agent were added to the mixing tank to which the suspension was transferred, followed by sufficiently stirring to obtain a liquid jelly syrup.

상기 액상의 젤리시럽을 60메쉬 여과망을 통과시켜 여과한 후 blending을 충분히 한 후, 카보네이트를 사용하여 가스볼륨이 2.0이 되도록 탄산가스를 봉입하였다. After the liquid jelly syrup was filtered through a 60 mesh filter network, sufficient blending was performed, and carbon dioxide gas was encapsulated so that the gas volume was 2.0 using carbonate.

탄산가스를 봉입한 액상의 젤리시럽을 내열내압성의 탄산용 PET병 또는 캔에 충진하고 밀봉한 후, 파스터라이저를 사용하여 75℃에서 10분 동안 후살균하고, 180°반전을 2번 거친 후 다시 계속하여 45℃까지 냉각하고, 저온고에서 10℃ 이하로 냉각하여 겔화시킴으로서 본 발명의 젤리탄산음료를 제조하였다.After filling and sealing a liquid jelly syrup filled with carbon dioxide in a heat-resistant pressure-resistant PET bottle or can, and then pasteurizing at 75 ° C. for 10 minutes using a pasteurizer, and then going through 180 ° inversion twice. The gel jelly drink of the present invention was prepared by further cooling to 45 DEG C, cooling to 10 DEG C or lower at low temperature, and gelling.

<시험예><Test Example>

1-1. 겔의 강도 측정1-1. Gel strength measurement

진동(oscillation) 하에서 온도 10℃, 진동수 1Hz로 하여 구아검 1%, 잔탄검 1%, 젤란검 1%, 카라기난 1%, LM펙틴 1%, 로커스트 빈 검(locust bean gum) 1% 각각에 대하여 변형율(strain)을 0.01~200%까지 증가시킬 때, 선형 점탄성 구간을 특정하 고, 이러한 선형 점탄성 구간 내에서의 저장탄성율(storage modulus; G') 및 손실탄성율(loss modulus; G'')의 평균값을 구하였다.Guar gum 1%, xanthan gum 1%, gellan gum 1%, carrageenan 1%, LM pectin 1%, and locust bean gum 1%, respectively, at a temperature of 10 ° C. and a frequency of 1 Hz under oscillation. When increasing the strain by 0.01-200%, the linear viscoelastic zone is specified and the storage modulus (G ') and loss modulus (G' ') within this linear viscoelastic zone The average value was calculated | required.

그 결과를 하기의 표 1 및 도 1에 나타내었다.The results are shown in Table 1 below and FIG. 1.

1-2. 겔의 복원력 측정1-2. Measurement of the restorative force of the gel

구아검 1%, 잔탄검 1%, 젤란검 1%, 카라기난 1%, LM펙틴 1%, 로커스트 빈 검 (locust bean gum) 1% 각각에 대하여 진동(oscillation) 하에서 변형율을 1%, 진동수를 1Hz로 하여 저장탄성율 및 손실탄성율을 측정하여, 이를 평형 상태의 겔 특성값으로 하였다. 100초간 상기 평형상태의 겔 특성값을 측정한 후, 5초간 전단율을 3,000(1/초)로 하여 겔의 구조를 변형 시킨 후, 다시 진동(oscillation) 하에서 변형율을 1%, 진동수를 1Hz로 하여 평형 상태의 조건을 1,000초간 주어 복원 개시 후 60초 경과하였을 때의 복원된 정도를 %로 측정하여 겔의 복원 특성을 관찰하였다.Guar gum 1%, xanthan gum 1%, gellan gum 1%, carrageenan 1%, LM pectin 1%, locust bean gum 1%, respectively, strain 1% under oscillation and frequency 1Hz The storage modulus and loss modulus were measured to obtain the gel characteristic values in the equilibrium state. After measuring the equilibrium gel characteristic value for 100 seconds, the structure of the gel was deformed with a shear rate of 3,000 (1 / sec) for 5 seconds, and again 1% strain and 1Hz frequency under oscillation. Given the condition of equilibrium for 1,000 seconds, the degree of restoration at 60 seconds after the start of restoration was measured in% to observe the restoring characteristics of the gel.

그 결과를 하기의 표 1 및 도 2에 나타내었다.The results are shown in Table 1 below and FIG. 2.

1-3. 겔의 형성 온도 측정1-3. Formation Temperature Measurement of Gel

구아검 1%, 잔탄검 1%, 젤란검 1%, 카라기난 1%, LM펙틴 1%, 로커스트 빈 검 (locust bean gum) 1% 각각에 대하여 진동(oscillation) 하에서 변형율을 1%, 진동수를 1Hz로 하여 온도 조건의 변화에 따른 겔의 형성 온도를 측정하였다. Guar gum 1%, xanthan gum 1%, gellan gum 1%, carrageenan 1%, LM pectin 1%, locust bean gum 1%, respectively, strain 1% under oscillation and frequency 1Hz The formation temperature of the gel according to the change of temperature conditions was measured.

즉, 30초 동안 온도를 20℃로 유지시키는 온도평형과정, 상기 온도평형과정의 20℃에서 80℃까지 분당 10℃씩 온도를 상승시키는 승온과정, 상기 승온과정의 온도 80 ℃를 5분 동안 정온시키는 정온과정, 상기 정온과정의 온도 80℃에서 4℃까지 분당 5℃씩 감온시키는 감온과정, 상기 감온과정의 4℃를 200초 동안 정온시키는 정온과정을 통해 저장탄성율(G')이 손실탄성율(G'')을 초과하기 시작하는 시점을 겔이 형성되는 시점으로 가정하고 시간 및 온도를 측정하였다.That is, a temperature equilibrium process for maintaining the temperature at 20 ° C. for 30 seconds, a temperature increase process for increasing the temperature by 10 ° C. per minute from 20 ° C. to 80 ° C. of the temperature equilibrium process, and constant temperature for 80 minutes at 80 ° C. for the temperature increase process. The storage modulus (G ′) is the loss modulus (G ′) through the temperature reduction process of deceleration by 5 ° C. per minute from 80 ° C. to 4 ° C., and the temperature reduction process of the temperature decrease 4 ° C. for 200 seconds. The time and temperature were measured assuming the time point at which G '') began to exceed was formed.

그 결과를 하기의 표 1 및 도 3에 나타내었다.The results are shown in Table 1 below and FIG. 3.

Figure 112009073591705-pat00001
Figure 112009073591705-pat00001

상기의 표 1 및 도 1 내지 도 3에서 확인할 수 있는 바와 같이, ⅰ)구아검의 경우에는 다른 안정제보다 높은 탄성을 가지며, 겔(gel)의 강도도 가장 높음을 알 수 있었다. 또한 겔의 복원 정도도 가장 높은데, 이는 구아검의 겔을 이루는 네트워크(network)의 구조가 비교적 균일하고, 네트워크의 유동성도 높기에 관찰할 수 있는 현상이라 판단된다. 또한, 겔의 형성 시점은 881.8초가 지난 후로써, 이는 공정 적용시 해당 정도 이상의 에너지 투입이 필요함을 의미한다.As can be seen in Table 1 and Figures 1 to 3, iii) guar gum has a higher elasticity than other stabilizers, it was found that the strength of the gel (gel) is also the highest. In addition, the degree of gel restoration is also the highest, which is considered to be a phenomenon that can be observed because the network structure of the guar gum gel is relatively uniform and the fluidity of the network is high. In addition, the formation time of the gel is after 881.8 seconds, which means that more than that energy input is required for the process application.

ⅱ)잔탄검의 경우에는 저장탄성율(G')이 손실탄성율(G'')에 비해 아주 높음을 알 수 있었는데, 이는 겔을 이루는 네트워크의 유동성이 작음을 간접적으로 시사하는 것이며, 이로 인해 다른 겔보다 복원력이 낮음을 알 수 있었다. 또한, 겔 형성시점은 약 764초로써, 이는 공정 적용시 해당 정도 이상의 에너지 투입이 이루어져야만 졸(sol)이 완전히 해리되어 겔(gel)을 이루는데 필요한 구조를 형성할 수 있다고 할 수 있다.Ii) In the case of xanthan gum, the storage modulus (G ') is very high compared to the loss modulus (G' '), which indirectly suggests that the fluidity of the gel-forming network is small. It was found that the resilience is lower. In addition, the gel formation time is about 764 seconds, which can be said that the sol (sol) completely dissociates to form the structure necessary to form a gel (gel) only when the energy input is applied to the degree or more during the process application.

ⅲ)젤란검의 경우에는 겔 형성 시점의 저장탄성율(G')이 0.22로 매우 낮은 값을 가지며, 그 때의 온도는 32.07.℃ 임을 알 수 있는데, 겔의 강도가 온도에 매우 민감함을 알 수 있었고, 겔 형성 능력이 제일 이상적인 상태임을 알 수 있었다.젤) In case of gellan gum, the storage elastic modulus (G ') at the time of gel formation is 0.22, which is very low, and the temperature at that time is 32.07. ℃, indicating that the strength of the gel is very sensitive to temperature. It was found that the gel formation ability was the most ideal state.

도 1은 젤란검 1%의 겔강도를 측정한 결과를 표시한 그래프이다.1 is a graph showing the results of measuring the gel strength of gellan gum 1%.

도 2는 젤란검 1%의 겔복원력을 측정한 결과를 표시한 그래프이다.Figure 2 is a graph showing the results of measuring the gel resilience of gellan gum 1%.

도 3은 젤란검 1%의 겔형성온도 및 시점을 측정한 결과를 표시한 그래프이다.3 is a graph showing the results of measuring gel formation temperature and time point of gellan gum 1%.

Claims (3)

젤란검, 구아검 및 LM-펙틴로 이루어진 겔화제 0.155~0.42중량%, 백설탕 6~8중량%, 아스파탐 0.01~0.02중량%, 아세설팜칼륨 0.005~0.008중량%, 젖산칼슘 0.1~0.2중량%, 무수구연산 0.3~0.35중량%, 사과농축액 0.8~1중량%, 착향료 0.08~0.12중량%, 자몽종자추출물 0.001~0.003중량% 및 잔량의 정제수를 혼합하여 제조된 액상의 젤리시럽에 탄산가스를 봉입한 것을 특징으로 하는 젤리탄산음료.Gelling agent consisting of gellan gum, guar gum and LM-pectin 0.155 to 0.42% by weight, 6-8% by weight of white sugar, 0.01 to 0.02% by weight of aspartame, 0.005 to 0.008% by weight of acesulfam potassium, 0.1-0.2% by weight of calcium lactate Encapsulated carbon dioxide in a liquid jelly syrup prepared by mixing 0.3 to 0.35 wt% anhydrous citric acid, 0.8 to 1 wt% apple concentrate, 0.08 to 0.12 wt% flavoring agent, 0.001 to 0.003 wt% grapefruit seed extract, and the remaining amount of purified water. Jelly carbonated drink characterized in that. 제1항에 있어서,The method of claim 1, 상기 젤란검은 겔화제 100중량%를 기준으로 64.5~71.4중량%, The gellan gum is 64.5 ~ 71.4% by weight, based on 100% by weight of the gelling agent, 상기 구아검은 겔화제 100중량%를 기준으로 3.2~4.8중량%,The guar gum is 3.2 to 4.8% by weight based on 100% by weight of the gelling agent, 상기 LM-펙틴은 겔화제 100중량%를 기준으로 23.8~32.3중량%로 이루어진 것을 특징으로 하는 젤리탄산음료.The LM-pectin is a jelly drink, characterized in that consisting of 23.8 ~ 3.33% by weight based on 100% by weight of the gelling agent. a)젤란검, 구아검 및 LM-펙틴로 이루어진 겔화제 0.155~0.42중량%와 백설탕 6~8중량%의 분체 혼합물을 정제수에 충분히 분산시켜 현탁액을 제조하는 공정;a) preparing a suspension by sufficiently dispersing a powder mixture of 0.155 to 0.42% by weight of a gelling agent consisting of gellan gum, guar gum and LM-pectin and 6 to 8% by weight of white sugar in purified water; b)상기 a)공정의 현탁액에 아스파탐 0.01~0.02중량%와 아세설팜칼륨 0.005~0.008중량%를 투입하는 공정;b) adding 0.01% to 0.02% by weight of aspartame and 0.005% to 0.008% by weight of acesulfame potassium in the suspension of step a); c)상기 b)공정의 혼합물에 무수구연산 0.3~0.35중량%와 젖산칼슘 0.1~0.2중량%를 정제수에 용해시킨 혼합물을 혼합하는 공정;c) mixing a mixture of 0.3 to 0.35% by weight of citric anhydride and 0.1 to 0.2% by weight of calcium lactate in purified water to the mixture of step b); d)상기 c)공정의 혼합물에 사과농축액 0.8~1중량%, 자몽종자추출물 0.001~0.003중량% 및 착향료 0.08~0.12중량%를 혼합하여 액상의 젤리시럽을 제조하는 공정; 및 d) preparing a liquid jelly syrup by mixing 0.8 ~ 1% by weight of apple concentrate, 0.001 ~ 0.003% by weight of grapefruit seed extract, and 0.08 ~ 0.12% by weight of flavoring agent, to the mixture of step c); And e)상기 d)공정의 액상의 젤리시럽에 탄산가스를 봉입한 것을 용기에 충전하여 밀폐한 후, 가열하여 졸화하고 냉각하여 겔화하는 공정을 포함하여 제조되는 것을 특징으로 하는 젤리탄산음료의 제조방법.e) a method of manufacturing a jelly beverage, characterized in that it comprises the step of filling the container with the carbonic acid gas in the liquid jelly syrup of step d) and sealing it, followed by heating, solving, cooling and gelling. .
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JP2006304655A (en) 2005-04-27 2006-11-09 I Ran Foods Industrial Co Ltd Method for producing jelly-containing carbonated beverage

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