KR101121731B1 - Light emitting apparatus - Google Patents

Abstract

The present invention includes a first light emitting portion emitting a primary daylight color having a color temperature of 6000K or more and a second light emitting portion emitting a warm white color having a color temperature of 3000K or less, wherein the first light emitting portion and the second light emitting portion are driven independently. Provide a device. Accordingly, the present invention implements white light having various light spectrums and color temperatures, and thus has an advantage that it can be variously applied to a desired atmosphere and use. In particular, by appropriately adjusting the wavelength or color temperature of light according to the circadian rhythm of the human, there is an effect that can improve the health.

LED, Light Emitting Diode, Light Emitting Device, White Light, Color Temperature, Color Rendering, Fluorescent Material

Description

Light emitting apparatus

The present invention relates to a light emitting device, and more particularly, to a light emitting device capable of realizing light having various light spectra and color temperatures by forming a plurality of light emitting units in one package.

A light emitting diode (LED) refers to a device that generates a small number of carriers (electrons or holes) injected using a P-N junction structure of a compound semiconductor, and emits predetermined light by recombination thereof. Light emitting diodes consume less power and last several to several tens of times as compared to conventional light bulbs or fluorescent lamps, and are superior in terms of power consumption reduction and durability. In addition, it can be installed in a narrow space and provides a strong resistance to vibration. Light emitting devices using such light emitting diodes have been used as display elements and backlights, and active research is being conducted to apply them to general lighting applications. Recently, white light emitting diodes have been introduced in addition to single color components, for example, red, blue, or green light emitting diodes. As the light emitting device using the white light emitting diode is applied to automotive and lighting products, the demand is expected to increase rapidly.

Humans have a circadian rhythm that repeats their biorhythms every day or so. For example, cortisol, a stress hormone, and melatonin, a sleep hormone, have a significant effect on activity and sleep. Cortisol levels, the basis for daily activity, increase during the day, then decrease again at night Becomes On the other hand, sleep-causing melatonin levels decrease during the day, disappearing drowsiness and then increase at night, leading to healthy sleep.

In general, light has a lot of influence on human rhythms, especially sunlight, which plays a very big role in this effect. The color temperature of sunlight is higher than 6000K in the morning and then gradually decreases in the afternoon. Color temperature is a physical value for the color of the light source, expressed in Calvin K, and the higher the color temperature, the lighter the color of blue, and the lower the color temperature, the stronger red-yellow light is emitted. In addition, the higher the color temperature, the greater the activity and concentration of the brain, and the lower the color temperature, the emotional and active mind.

As described above, light gives a variety of feelings depending on the wavelength or color temperature, affects a lot of human rhythms, and when the rhythms do not adapt properly, it may cause various diseases such as impaired digestion and chronic fatigue. Therefore, the research on the lighting device considering the human circadian rhythm is in progress.

In a light emitting device using a conventional light emitting diode, a variety of white implementation methods have been proposed. Typically, a fluorescent material is disposed around the light emitting diode chip, thereby realizing white color by mixing a part of the first light emission of the light emitting diode chip and the secondary light emission wavelength-converted by the fluorescent material. Fluorescent materials for white implementations include garnet phosphors, thiogallates, sulfides, silicates or oxynitrides. However, a light emitting device using such a fluorescent material has a narrow color temperature range, a very low color rendering index, and unstable lamp stability. That is, it is difficult to manufacture a light emitting device that provides various light spectrums or color temperatures.

An object of the present invention is to provide a light emitting device capable of realizing light having various light spectrums or color temperatures by forming a plurality of light emitting units in one package.

Another object of the present invention is to provide a light emitting device capable of adjusting the light spectrum or the color temperature of light according to a human rhythm.

In order to achieve the above object, the present invention includes a first light emitting portion emitting a primary daylight color having a color temperature of 6000K or more and a second light emitting portion emitting a warm white color having a color temperature of 3000K or less, wherein the first light emitting portion and the second light emitting portion are independently It provides a light emitting device characterized in that the drive.

The light emitting device includes the first light emitting part and the second light emitting part including a light emitting diode chip and a fluorescent material, wherein the fluorescent material is represented by the following Chemical Formula 1,

<Formula 1>

a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? dAl ₂ O ₃ ? e (M ^III O)? f (M ^Ⅳ ₂ O ₃ )? g (M ^V _o O _p )? h ( ^MVI _x O _y )

M ^I is at least one element selected from the group containing Pb, Cu, and M ^II is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Ag, , M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, wherein M ^IV is at least in the group containing Sc, B, Ga, In One element is selected, and ^MV is at least one element selected from the group consisting of Si, Ge, Ti, Zr, Mn, V, Nb, Ta, W, Mo, and ^MVI is Bi, Sn At least one element is selected from the group comprising Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and X is at least one element selected from the group containing F, Cl, Br, I, wherein a, b, c, d, e, f, g, o, p, h, x, y is 0 <a ≤2, 0≤b≤2, 0≤c≤2, 0≤d≤8, 0≤e≤4, 0≤f≤3, 0≤g≤8, 1≤o≤2, 1≤p≤5 , 0≤h≤2, 1≤x≤2, 1 It can be set in the range of y≤5.

The fluorescent material is represented by the following formula (2),

<Formula 2>

a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? 4-abc (M ^III O)? 7 (Al ₂ O ₃ )? d (B ₂ O ₃ )? e (Ga ₂ O ₃ )? f (SiO ₂ )? g (GeO ₂ )? h (M ^IV _x O _y )

The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Au, M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and M ^IV is Bi, Sn, Sb, Sc, Y, La, In, At least one element is selected from the group comprising Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, wherein X is F, Cl, Br, I At least one element is selected from the group including a, b, c, d, e, f, g, h, x, and y are 0 <a≤4, 0≤b≤2, and 0≤c≤ 2, 0≤d≤1, 0≤e≤1, 0≤f≤1, 0≤g≤1, 0 <h≤0.5, 1≤x≤2, 1≤y≤5, 4-abc≥0 It can be set to a range.

The fluorescent material is represented by the following formula (3),

<Formula 3>

a (M ^I O)? b (M ^II O)? c (Al ₂ O ₃ )? d (M ^III ₂ O ₃ )? e (M ^Ⅳ O ₂ )? f (M ^V _x O _y )

The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn and, wherein M ^ⅲ is at least one element selected from the group consisting of B, Ga, in, the M ^ⅳ is at least one element selected from the group comprising Si, Ge, Ti, Zr, Hf, M ^V is at least one of a group containing Bi, Sn, Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu Is selected, and a, b, c, d, e, f, x, and y are 0 <a ≤ 1, 0 ≤ b ≤ 2, 0 <c ≤ 8, 0 ≤ d ≤ 1, 0 ≤ e It may be set in the range of ≤ 1, 0 <f ≤ 2, 1 ≤ x ≤ 2, 1 ≤ y ≤ 5.

The fluorescent material is represented by the following formula (4),

<Formula 4>

a (M ^I O)? b (M ^II O)? c (M ^III X)? d (M ^III ₂ O)? e (M ^Ⅳ ₂ O ₃ )? f (M ^V _o O _p ) _? g (SiO ₂ )? h ( ^MVI _x O _y )

The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn M ^III is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Ag, and M ^IV is at least one from the group containing Al, Ga, In, B Is selected from ^MV is Ge, V, Nb, Ta, W, Mo, Ti, Zr, Hf, P at least one element is selected, ^MVI is Bi, Sn, At least one element is selected from the group comprising Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and X Is at least one element selected from the group containing F, Cl, Br, I, wherein a, b, c, d, e, f, g, h, o, p, x, y is 0 <a 2, 0 <b≤8, 0≤c≤4, 0≤d≤2, 0≤e≤2, 0≤f≤2, 0≤g≤10, 0≤h≤5, 1≤o≤2, 1≤p≤5, 1≤x≤2, 1≤y It may be set in the range of?

The fluorescent material is represented by the following formula (5),

<Formula 5>

a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? d (Sb ₂ O ₅ )? e (M ^III O)? f (M ^IV _x O _y )

The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Ag, M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and M ^IV is Bi, Sn, Sc, Y, La, Pr, Sm, At least one element is selected from the group containing Eu, Tb, Dy, and Gd, and X is at least one element selected from the group containing F, Cl, Br, I, and the a, b, c, d, e, f, x, y are 0 <a≤2, 0≤b≤2, 0≤c≤4, 0 <d≤8, 0≤e≤8, 0≤f≤2, 1≤x≤ 2, 1≤y≤5 can be set.

The fluorescent material is represented by the following formula (6),

(6)

a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? dGeO ₂ ? e (M ^III O)? f (M ^Ⅳ ₂ O ₃ )? g (M ^V _o O _p ) _? h ( ^MVI _x O _y )

M ^I is at least one element selected from the group containing Pb, Cu, and M ^II is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Ag, , M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, the M ^IV comprises Sc, Y, B, Al, Ga, In, La At least one element is selected from the group, ^MV is at least one element selected from the group containing Si, Ti, Zr, Mn, V, Nb, Ta, W, Mo, and ^MVI is Bi At least one element is selected from the group containing Sn, Pr, Sm, Eu, Gd, and Dy, X is at least one element selected from the group containing F, Cl, Br, I, and a, b, c, d, e, f, g, h, o, p, x, y are 0 <a≤2, 0≤b≤2, 0≤c≤10, 0 <d≤10, 0≤e≤ 14, 0≤f≤14, 0≤g≤10, 0≤h≤2, 1≤o≤2, 1≤p≤5, 1≤x≤2, and 1≤y≤5. .

The fluorescent material is represented by the following formula (7),

<Formula 7>

a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? dP ₂ O ₅ ? e (M ^III O)? f (M ^Ⅳ ₂ O ₃ )? g (M ^V O ₂ ) _? h ( ^MVI _x O _y )

The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Ag, M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and M ^IV is Sc, Y, B, Al, La, Ga, In At least one element is selected from the group including ^MV , and at least one element is selected from the group including Si, Ge, Ti, Zr, Hf, V, Nb, Ta, W, and Mo, and M ^VI is at least one element selected from the group containing Bi, Sn, Pr, Sm, Eu, Gd, Dy, Ce, Tb, and X is at least one element from the group containing F, Cl, Br, I And a, b, c, d, e, f, g, h, x, and y are 0 <a ≤ 2, 0 ≤ b ≤ 12, 0 ≤ c ≤ 16, 0 <d ≤ 3, 0 ≤ e ≤ 5, 0 ≤ f ≤ 3, 0 ≤ g ≤ 2, 1 ≤ x ≤ 2, 1 ≤ y ≤ 5 can be set.

The fluorescent material may include a single or a plurality, and the light emitting diode chip may emit blue or UV light.

The light emitting device of the present invention may further include a controller for controlling a voltage applied to the first light emitting part and / or the second light emitting part from the outside. The control unit may adjust the voltage received from the outside according to time and apply the first light emitting unit and / or the second light emitting unit, and the control unit increases and decreases the voltage received from the outside every 24 hours. It may be applied to the first light emitting portion and / or the second light emitting portion.

The first light emitting part and the second light emitting part may be formed in one package. In the package, a light emitting diode chip of the first and second light emitting units may be mounted on a substrate, and a fluorescent material of the first light emitting unit and the second light emitting unit may be disposed on the light emitting diode chip. In addition, the package includes a heat sink for dissipating heat generated from the light emitting diode chip, the light emitting diode chip of the first and second light emitting unit is mounted on the heat sink, the top of the light emitting diode chip Fluorescent materials of the first and second light emitting units may be disposed, respectively.

The present invention has the advantage that by forming a plurality of light emitting portion in one package, by implementing a white light having a variety of light spectrum and color temperature can be variously applied to a desired atmosphere and applications. In particular, by appropriately adjusting the wavelength or color temperature of light according to the circadian rhythm of the human, there is an effect that can improve the health.

In addition, by forming what was previously configured as a separate package in one package, there is an effect that can reduce the cumbersome process, increase the space efficiency and reduce the cost.

Hereinafter, with reference to the accompanying drawings will be described an embodiment of the present invention in more detail. It will be apparent to those skilled in the art that the present invention may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, It is provided to let you know. Like numbers refer to like elements in the figures.

The light emitting device according to the present invention includes a first light emitting part for emitting white light having a relatively high color temperature and a second light emitting part for emitting white light having a relatively low color temperature in one package, and the first light emitting part and the second light emitting part. The light emitting units may be driven independently of each other.

The first light emitting part emits white light having a color temperature of 6000K or more, that is, white light known as daylight. The second light emitting part emits white light having a color temperature of 3000K or less, that is, white light known as warm white.

The first light emitting unit and the second light emitting unit include a light emitting diode chip and a fluorescent material. That is, the white light having the desired light spectrum and color temperature characteristics may be realized by mixing blue light or UV light emitted from the light emitting diode chip with light converted by the fluorescent material.

The LED chip and the fluorescent material constituting the first light emitting part or the second light emitting part may be variously configured. For example, the first light emitting part or the second light emitting part may include one blue light emitting diode chip and one yellow color. It may include a luminescent fluorescent material. That is, white is realized by mixing blue light emitted from the light emitting diode chip and yellow light wavelength-converted by the fluorescent material. The first light emitting unit or the second light emitting unit may include one blue light emitting diode chip, a green light emitting fluorescent material, and an orange light emitting fluorescent material. The white color is realized by mixing blue light emitted from the light emitting diode chip and green light and orange light wavelength-converted by the fluorescent material. In this case, there is an advantage that the improved color rendering can be obtained compared to the example consisting of the blue light emitting diode chip and the yellow light emitting fluorescent material. That is, the color rendering property can be improved by using a light emitting diode chip and a plurality of fluorescent materials having various emission peaks. When a plurality of fluorescent materials are used, white light having various color temperatures and color rendering properties may be realized according to the composition ratio of the plurality of fluorescent materials as well as the composition of the fluorescent materials.

It is preferable that the light emitting diode chip uses a blue or UV light emitting diode chip.

The fluorescent material is characterized by using a series of materials having various emission peak ranges, for example, a silicate-based fluorescent material having an emission peak range of green to red. That is, various colors can be realized by using light emitted from the light emitting diode chip as an excitation source, thereby realizing white light having various light spectrum and color temperature characteristics. In addition, by using the same series of materials when including a plurality of fluorescent materials, it is possible to minimize the influence of the fluorescent materials with each other.

The fluorescent material includes an aluminate-based, silicate-based, oxynitite-based, antimonate-based, germanate-based or phosphate-based. In particular, by using a fluorescent material containing lead or copper, high stability and excellent photoexcitation characteristics can be obtained.

The aluminate-based fluorescent material includes a fluorescent material represented by the following Chemical Formula 1, Chemical Formula 2, Chemical Formula 3.

a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? dAl ₂ O ₃ ? e (M ^III O)? f (M ^Ⅳ ₂ O ₃ )? g (M ^V _o O _p )? h ( ^MVI _x O _y )

In Formula 1, M ^I is selected from at least one element from the group containing Pb, Cu, M ^II is selected from at least one element from the group containing Li, Na, K, Rb, Cs, Au, Ag M ^III is at least one element selected from the group containing Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and M ^IV is at least one from the group containing Sc, B, Ga, I Is selected, ^MV is at least one selected from the group containing Si, Ge, Ti, Zr, Mn, V, Nb, Ta, W, Mo, ^MVI is Bi, Sn, Sb, At least one element is selected from the group comprising Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and X is F, At least one element is selected from the group comprising Cl, Br, I.

In addition, in Formula 1, a, b, c, d, e, f, g, o, p, h, x, y are 0 <a≤2, 0≤b≤2, 0≤c≤2, 0≤d ≤8, 0≤e≤4, 0≤f≤3, 0≤g≤8, 1≤o≤2, 1≤p≤5, 0≤h≤2, 1≤x≤2, 1≤y≤5 It is set in the range of.

a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? 4-abc (M ^III O)? 7 (Al ₂ O ₃ )? d (B ₂ O ₃ )? e (Ga ₂ O ₃ )? f (SiO ₂ )? g (GeO ₂ )? h (M ^IV _x O _y )

In Formula 2, M ^I is selected from at least one element from the group containing Pb, Cu, M ^II is selected from at least one element from the group containing Li, Na, K, Rb, Cs, Au, Ag M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, M ^IV is Bi, Sn, Sb, Sc, Y, La, In, At least one element is selected from the group comprising Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and X represents F, Cl, Br, I At least one element is selected from the containing group.

In addition, in Formula 2, a, b, c, d, e, f, g, h, x, y are 0 <a≤4, 0≤b≤2, 0≤c≤2, 0≤d≤1, 0 ≤ e ≤ 1, 0 ≤ f ≤ 1, 0 ≤ g ≤ 1, 0 <h ≤ 0.5, 1 ≤ x ≤ 2, 1 ≤ y ≤ 5, and 4-abc ≥ 0.

a (M ^I O)? b (M ^II O)? c (Al ₂ O ₃ )? d (M ^III ₂ O ₃ )? e (M ^Ⅳ O ₂ )? f (M ^V _x O _y )

In Formula 3, M ^I is at least one element selected from the group containing Pb and Cu, and M ^II is at least one element from the group containing Be, Mg, Ca, Sr, Ba, Zn, Cd, and Mn. is selected, M ^ⅲ is at least one element from the group consisting of B, Ga, in is selected, M ^ⅳ is at least one element from the group comprising Si, Ge, Ti, Zr, Hf and select , M ^V is at least one in the group containing Bi, Sn, Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu The element of is selected.

In Formula 3, a, b, c, d, e, f, x, y are 0 <a≤1, 0≤b≤2, 0 <c≤8, 0≤d≤1, 0≤e≤1 , 0 <f ≦ 2, 1 ≦ x ≦ 2, and 1 ≦ y ≦ 5.

The silicate-based fluorescent material includes a fluorescent material represented by the following formula (4).

a (M ^I O)? b (M ^II O)? c (M ^III X)? d (M ^III ₂ O)? e (M ^Ⅳ ₂ O ₃ )? f (M ^V _o O _p ) _? g (SiO ₂ )? h ( ^MVI _x O _y )

In Formula 4, M ^I is at least one element selected from the group containing Pb and Cu, and M ^II is at least one element from the group containing Be, Mg, Ca, Sr, Ba, Zn, Cd, and Mn. Is selected, ^MIII is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Ag, and ^MIV is at least one from the group containing Al, Ga, In, B Is selected, ^MV is at least one selected from the group consisting of Ge, V, Nb, Ta, W, Mo, Ti, Zr, Hf, P, ^MVI is Bi, Sn, Sb, At least one element is selected from the group comprising Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and X is F, At least one element is selected from the group comprising Cl, Br, I.

In addition, in Formula 4, a, b, c, d, e, f, g, h, o, p, x, y are 0 <a≤2, 0 <b≤8, 0≤c≤4, 0≤d ≤2, 0≤e≤2, 0≤f≤2, 0≤g≤10, 0≤h≤5, 1≤o≤2, 1≤p≤5, 1≤x≤2, 1≤y≤5 It is set in the range of.

The antimonynate fluorescent material includes a fluorescent material represented by the following Formula 5.

a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? d (Sb ₂ O ₅ )? e (M ^III O)? f (M ^IV _x O _y )

In Formula 5, M ^I is selected from at least one element from the group containing Pb, Cu, M ^II is selected from at least one element from the group containing Li, Na, K, Rb, Cs, Au, Ag M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, M ^IV is Bi, Sn, Sc, Y, La, Pr, Sm, At least one element is selected from the group containing Eu, Tb, Dy, and Gd, and X is at least one element selected from the group containing F, Cl, Br, I.

In Formula 5, a, b, c, d, e, f, x, y are 0 <a≤2, 0≤b≤2, 0≤c≤4, 0 <d≤8, 0≤e≤8 , 0 ≦ f ≦ 2, 1 ≦ x ≦ 2, and 1 ≦ y ≦ 5.

The germanate-based fluorescent material includes a fluorescent material represented by the following Chemical Formula 6.

a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? dGeO ₂ ? e (M ^III O)? f (M ^Ⅳ ₂ O ₃ )? g (M ^V _o O _p ) _? h ( ^MVI _x O _y )

In Formula 6, M ^I is selected from at least one element from the group containing Pb, Cu, M ^II is selected from at least one element from the group containing Li, Na, K, Rb, Cs, Au, Ag M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, M ^IV comprises Sc, Y, B, Al, Ga, In, La is at least one element is selected from the group, M ^ⅴ is Si, Ti, Zr, Mn, V, Nb, Ta, W, is at least one element from the group consisting of Mo is chosen, M ^ⅵ is Bi, Sn, At least one element is selected from the group containing Pr, Sm, Eu, Gd, and Dy, and X is selected from at least one element from the group containing F, Cl, Br, I.

In addition, in Formula 6, a, b, c, d, e, f, g, h, o, p, x, y are 0 <a≤2, 0≤b≤2, 0≤c≤10, 0 <d ≤10, 0≤e≤14, 0≤f≤14, 0≤g≤10, 0≤h≤2, 1≤o≤2, 1≤p≤5, 1≤x≤2, 1≤y≤5 It is set in the range of.

The phosphate-based fluorescent material includes a fluorescent material represented by the following Chemical Formula 7.

a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? dP ₂ O ₅ ? e (M ^III O)? f (M ^Ⅳ ₂ O ₃ )? g (M ^V O ₂ ) _? h ( ^MVI _x O _y )

In Formula 7, M ^I is selected from at least one element from the group containing Pb, Cu, M ^II is selected from at least one element from the group containing Li, Na, K, Rb, Cs, Au, Ag M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, M ^IV is Sc, Y, B, Al, La, Ga, In is at least one element selected from the group comprising, M ^ⅴ is at least one element from the group comprising Si, Ge, Ti, Zr, Hf, V, Nb, Ta, W, Mo is selected, M ^ⅵ is At least one element is selected from the group containing Bi, Sn, Pr, Sm, Eu, Gd, Dy, Ce, and Tb, and X is selected from at least one element from the group containing F, Cl, Br, I do.

In addition, in Formula 7, a, b, c, d, e, f, g, h, x, y are 0 <a ≤ 2, 0 ≤ b ≤ 12, 0 ≤ c ≤ 16, 0 <d ≤ 3, 0 ≤e≤5, 0≤f≤3, 0≤g≤2, 1≤x≤2, 1≤y≤5 It is set in the range of.

1 is a conceptual block diagram illustrating a light emitting device according to an embodiment of the present invention.

Referring to FIG. 1, the light emitting device includes a first light emitting part emitting a daylight color having a color temperature of 6000K or more, and a second light emitting part emitting a warm white color of 3000K or less. The light emitting unit and the second light emitting unit may be driven independently of each other.

Since the light emitting device can be electrically connected to a plurality of light emitting units in one package A, the first light emitting unit and the second light emitting unit can be driven independently. For example, when power is applied only to the first light emitting unit, daylight white light having a color temperature of 6000K or more may be realized, and when power is applied only to the second light emitting unit, the warm white color having a color temperature of 3000K or less ( Warm white light can be achieved. In addition, when power is simultaneously applied to the first light emitting part and the second light emitting part, the white light having a color temperature in the range of 3000 to 6000K may be realized due to the mixing of the white light of the first light emitting part and the white light of the second light emitting part. Accordingly, the light emitting device may implement white light having various light spectra and color temperatures and excellent color rendering property by selective driving of the first light emitting part and the second light emitting part.

Since the light emitting device of the present invention can realize white light having various light spectrums and color temperatures, the light emitting device of the present invention can be variously applied to a desired atmosphere and use in one package (A). For example, during the day, only the first light emitter is driven to improve brain activity and concentration due to daylight white light having a color temperature of 6000K or more, and at night, only the second light emitter is driven to have a color temperature of 3000K or less. Warm white light gives you a comfortable and relaxing stay. In particular, by appropriately adjusting the wavelength or color temperature of light according to the circadian rhythm of the human, there is an effect that can improve the health.

2 is a conceptual block diagram illustrating a light emitting device according to another embodiment of the present invention.

Referring to FIG. 2, the light emitting device includes a first light emitting part emitting daylight of 6000 K or more color temperature, a second light emitting part emitting warm white of 3000 K or less color temperature, and the first light emitting part And a second controller connected to the second light emitter, wherein the first and second controllers control a voltage applied to the first and second light emitters from the outside. It is done.

The first and second controllers are for controlling voltages applied to the first and second light emitting units, respectively. For example, the first and second controllers adjust the voltages received from an external power source according to time. do. To this end, the first and second controllers may include a timer and a voltage controller circuit. That is, after the voltage input to the controller from the external power source is adjusted over time through a timer and a voltage controller circuit, the voltage is transferred to the first and second light emitting units.

3A and 3B illustrate an example of the first and second control units. In the case of the first control unit ①, as shown in FIG. 3A, a voltage from an external power source is transmitted for 12 hours as it is. Do not apply voltage for 12 hours. On the contrary, in the case of the second control unit ②, as shown in FIG. 3B, the voltage is not applied from the external power source for 12 hours, and the voltage from the external power source is transferred as it is for 12 hours. That is, 12 hours of the day may transfer the external power to the first light emitting unit as it is to drive only the first light emitting unit, and after 12 hours to transmit the external power to the second light emitting unit as it is to drive only the second light emitting unit. .

The operation of such a light emitting device is as follows. External power is applied to the first and second control units, and the first and second control units apply voltage to the first and second light emitting units by adjusting the voltage according to time. As mentioned above, 12 hours of the day delivers the voltage applied from the outside to the first light emitting unit as it is, and 12 hours later transfers the external voltage to the second light emitting unit. That is, 12 hours of the day, for example, only the first light emitting unit may be driven during the day, thereby implementing daylight white light having a color temperature of 6000K or higher, and then driving only the second light emitting unit for 12 hours, for example, at night. Warm white light with a color temperature of 3000K or less can be realized.

In the above, the on / off of the power applied to the first and second light emitting units has been exemplified, but the present invention is not limited thereto. For example, as illustrated in FIGS. 4A and 4B, the voltage may be increased or decreased with time so that the light emission intensity of the first and second light emitting units may be increased or decreased. Accordingly, the color temperature of the white light emitted from the light emitting device may be gradually increased or decreased.

Since the light emitting device can control the driving of the first and second light emitting units through the first and second controllers, the light emitting device can be applied in various ways as desired. That is, it is possible to manufacture a light emitting device in which the color temperature is automatically adjusted with time without the need for a separate input. For example, as described above, it is possible to form white light having a relatively high color temperature during the day and white light having a relatively low color temperature at night. In particular, by applying so that the wavelength or color temperature of the light is properly adjusted according to the circadian rhythm of the human, there is an effect that can improve the health.

Although the above-described example has been described with respect to a control unit for adjusting the voltage according to time, the present invention is not limited thereto, and the control unit may further include a separate input unit so that the color temperature may be adjusted as desired by the user. In addition, although an example in which an external power source is simultaneously applied to the first and second control units has been described, the present invention is not limited thereto, and the first and second control units may be independently connected to separate external power sources. In addition, the first light emitting unit and the second light emitting unit may be formed to include only one controllable at the same time.

Since the light emitting device of the present invention can realize white light having various light spectrums and color temperatures, the light emitting device of the present invention can be variously applied to a desired atmosphere and use in one package (A). For example, during the day, only the first light emitter is driven to improve brain activity and concentration due to daylight white light having a color temperature of 6000K or more, and at night, only the second light emitter is driven to have a color temperature of 3000K or less. Warm white light gives you a comfortable and comfortable rest. In particular, by appropriately adjusting the wavelength or color temperature of light according to the circadian rhythm of the human, there is an effect that can improve the health.

In addition, by forming a separate package in a single package to implement a white light having a variety of light spectrum and color temperature in the conventional, there is an effect that can reduce the process hassle, increase the space efficiency and reduce the cost.

Hereinafter, the present invention will be described in detail through the following examples.

[Example 1]

A light emitting diode chip emitting blue light at 456 nm, a Cu _0,15 Ba _1,82 Sr _0,03 Si _0,99 Ge _0,01 O ₄ : eu fluorescent substance having an emission peak at _{515 nm} , and 593 nm The first light emitting part is formed by using a fluorescent material of Cu _0,05 Sr _1,72 Ca _0,23 Si _0,99 Ge _0,01 O ₄ : Eu having an emission peak of.

A light emitting diode chip emitting blue light at 452 nm, a Cu _0,15 Ba _1,84 Sr _0,01 Si _0,99 Zr _0,01 O ₄ : eu fluorescent substance having an emission peak of ₅₀₈ nm, and a 605 nm A second light emitting part is formed by using a fluorescent material of Cu _0,05 Sr _1,85 Ca _0,10 SiO ₄ : Eu having an emission peak of.

FIG. 5 shows the emission spectrum of the first light emitting part, and FIG. 6 shows the emission spectrum of the second light emitting part. As can be seen in the figure, the first light emitting part has a relatively high light emission intensity in the blue light emitting area, and the second light emitting part has a relatively high light emission intensity in the yellow to red light emitting area. That is, it can be seen that the first light emitting part has a relatively high color temperature, and the second light emitting part has a relatively low color temperature.

The first light emitting part of the present embodiment implements white light having a color temperature of 9500K and excellent color rendering property of the color rendering index 88. In addition, the second light emitting part has a color temperature of 2640K and realizes white light having excellent color rendering property of the color rendering index 83.

By selectively driving the first light emitting unit and the second light emitting unit, white light having excellent color rendering properties and various light spectra and color temperatures can be realized. For example, white light having a relatively high color temperature of 9500K is realized by driving only the first light emitting unit during the day, and white light having a relatively low color temperature of 2640K is achieved by driving only the second light emitting unit at night.

[Example 2]

A light emitting diode chip emitting blue light of 456 nm, a Cu _0,15 Ba _1,82 Sr _0,03 Si _0,99 Ge _0,01 O ₄ : Eu fluorescent material having an emission peak of ₅₁₅ nm, and 600 nm A first light emitting part is constructed by using a fluorescent material of Cu _0,05 Sr _1,8 Ca _0,15 SiO ₄ : Eu having an emission peak of.

A light emitting diode chip emitting blue light of 456 nm, a Cu _0,15 Ba _1,82 Sr _0,03 Si _0,99 Ge _0,01 O ₄ : Eu fluorescent material having an emission peak of ₅₁₅ nm, and 600 nm A second light emitting part is constructed using a fluorescent material of Cu _0,05 Sr _1,8 Ca _0,15 SiO ₄ : Eu having an emission peak of.

The first and second light emitting units of the present exemplary embodiment may realize white light having different color temperatures and color rendering properties by adjusting the compositions of the two fluorescent materials.

7 illustrates the emission spectrum of the first emission unit, and FIG. 8 illustrates the emission spectrum of the second emission unit. As can be seen in the figure, it can be seen that the first light emitting part has a relatively high color temperature, and the second light emitting part has a relatively low color temperature.

The first light emitting unit of the present embodiment implements white light having a color temperature of 8800K and excellent color rendering property of the color rendering index 92. In addition, the second light emitting unit has a color temperature of 2550K and a color rendering index of 80 to realize white light having excellent color rendering properties.

By selectively driving the first light emitting unit and the second light emitting unit, white light having excellent color rendering properties and various light spectra and color temperatures can be realized. For example, the white light having a relatively high color temperature of 8800K is realized by driving only the first light emitting unit during the day, and the white light having a relatively low color temperature of 2550K is realized by driving only the second light emitting unit at night.

[Example 3]

A light emitting diode chip that emits 405 nm UV light, a Cu _0,02 Ba _2,8 Sr _0,2 Mg _0,98 Si ₂ O ₈ : Eu fluorescent material having an emission peak of 440 nm, and a 508 nm Cu _0,15 Ba _1,84 Sr _0,01 Si _0,99 Zr _0,01 O ₄ with emission peak: Cu _0,02 Ba _0,98 Sr ₀ with fluorescent material of Eu and 565 nm _{, 98} Ca _0,02 A first light emitting part is constituted by using a fluorescent material of SiO ₄ : Eu and a fluorescent material of Cu _0,15 Mg _0,85 BaP ₂ O ₇ : Eu, Mn having an emission peak of ₆₃₀ nm. .

A light emitting diode chip emitting UV light of 405 nm, a Cu _0,02 Ba _2,8 Sr _0,2 Mg _0,98 Si ₂ O ₈ : Eu fluorescent material having an emission peak of 440 nm, and a 515 nm Cu _0,15 Ba _1,82 Sr _0,03 Si _0,99 Ge _0,01 O ₄ with emission peak: Cu _0,05 Sr _1,72 Ca ₀ with emission peak at _{593 nm , 23} Si _0,99 Ge _0,01 O ₄ : A second material using a fluorescent material of Eu and a Cu _0,15 Mg _0,85 BaP ₂ O ₇ : Eu, Mn fluorescent material having an emission peak of ₆₃₀ nm; The light emitting portion is constituted.

9 shows the emission spectrum of the first light emitting part, and FIG. 10 shows the emission spectrum of the second light emitting part. As can be seen in the figure, it can be seen that the first light emitting part has a relatively high color temperature, and the second light emitting part has a relatively low color temperature.

The first light emitting part of the present embodiment implements white light having a color temperature of 8800K and excellent color rendering property of the color rendering index 88. In addition, the second light emitting unit has a color temperature of 2600K and a color rendering index of 95 to implement white light having excellent color rendering properties.

By selectively driving the first light emitting unit and the second light emitting unit, white light having excellent color rendering properties and various light spectra and color temperatures can be realized. For example, the white light having a relatively high color temperature of 8800K is realized by driving only the first light emitting unit during the day, and the white light having a relatively low color temperature of 2600K is realized by driving only the second light emitting unit at night.

11 to 15 illustrate examples in which the light emitting device according to the present invention is applied to various structures.

Referring to FIG. 11, the light emitting device includes a substrate 10, a first light emitting part 200, and a second light emitting part 300 formed on the substrate 10.

The first light emitting unit 200 includes a first light emitting diode chip 20 and a first fluorescent material 30, and the first fluorescent material 30 is mixed with a curable resin, for example, an epoxy resin or a silicone resin. It is formed by dotting on the first light emitting diode chip 20 in the form (50). The first light emitting unit 200 implements a white light of daylight color having a color temperature of 6000K or more by mixing light emitted from the first LED chip 20 with light that is wavelength-converted by the first fluorescent material 30.

Similarly, the second light emitting part 300 includes the second light emitting diode chip 60 and the second fluorescent material 70, and the second fluorescent material 70 is in the form 90 mixed with the curable resin. It is formed by dotting on the second LED chip 60. The second light emitting unit 300 realizes warm white white light having a color temperature of 3000K or less by mixing light emitted from the second LED chip 60 and light converted into wavelengths by the second fluorescent material 70.

The substrate 10 may form a predetermined groove in a region where the first and second light emitting parts 200 and 300 are formed to form a predetermined slope on the sidewall surface of the groove. Referring to FIG. 12, the substrate 10 includes a substrate 10 having a groove 100, a first light emitting part 200, and a second light emitting part 300 formed on a lower surface of the groove 100. The first light emitting unit 200 including the first light emitting diode chip 20 and the first fluorescent material 30, and the second light emission including the second light emitting diode chip 60 and the second fluorescent material 70. The unit 300 is formed on the lower surface of the groove 100, and the mixture 50 and 90 of the first and second fluorescent materials 30 and 70 and the curable resin is formed on the first and second light emitting diode chips ( 20 and 60, respectively, are formed by being doped. Due to the sidewall surface of the groove 100 having a predetermined slope, it is possible to maximize the reflection of the light emitted from the light emitting diode chips 20 and 60 and increase the luminous efficiency. Although not shown, a molding part filled with a transparent curable resin may be further formed inside the groove 100 to protect the first and second light emitting parts 200 and 300.

In addition, grooves corresponding to each light emitting part may be formed to separate the first light emitting part 200 and the second light emitting part 300. Referring to FIG. 13, a substrate 10 having a plurality of grooves formed to separate each of the light emitting units 200 and 300, and a first light emitting unit 200 and a second light emitting unit formed separately from the bottom surface of the groove, respectively. 300. That is, the first light emitting diode chip 20 is mounted on the lower surface of the groove 110, and the inside of the groove 110 is filled with the mixture 50 of the first fluorescent material 30 and the curable resin. The first light emitting unit 200 may be formed, and similarly, the second light emitting unit 300 may be formed. In this case, a predetermined slope may be formed on the sidewall surface of each of the grooves to maximize reflection of light emitted from the light emitting diode chips 20 and 60 and increase luminous efficiency.

The side wall surface of the groove may be formed as a curved surface rather than a straight surface. Referring to FIG. 14, the substrate 10 having the groove 120 having the curved sidewall surface, the first light emitting part 200 and the second light emitting part 300 formed on the lower surface of the groove 120 may be formed. Include. In addition, a predetermined partition wall 130 separating the first light emitting part 200 and the second light emitting part 300 may be included in a predetermined area under the groove 120. The partition 130 may be formed at the same height as the height of the substrate 10 as in the case of FIG. 13, but is formed at a height smaller than the height of the substrate 10 as shown in FIG. A molding unit 140 may be further formed to separate the 200 from the second light emitting unit 300 and to encapsulate the first light emitting unit 200 and the second light emitting unit 300 in common. This protects the first and second light emitting units 200 and 300, and at the same time, facilitates mixing of light emitted from the first and second light emitting units 200 and 300.

Referring to FIG. 15, there is shown an example applied to a structure for effectively dissipating heat from the light emitting diode chips 20 and 60. The light emitting device includes a heat sink 160 and formed on the heat sink 160. A first light emitting unit 200 and a second light emitting unit 300, the housing 150 surrounding the heat sink 160, and protruded to the outside of the housing 150 to supply external power. The lead frames 170 and 180 and the molding part 190 encapsulating the first and second light emitting parts 200 and 300 are included. In this case, the heat sink 160 may use a material having excellent thermal conductivity, for example, a material such as a metal, to more effectively release heat emitted from the light emitting diode chips 20 and 60.

The heat sink 160 corresponds to each of the light emitting parts 200 and 300 such that the mixtures 50 and 90 of the fluorescent materials 30 and 70 and the curable resin are easily doped on the light emitting diode chips 20 and 60. Thereby including a protrusion formed. Of course, the present invention is not limited thereto, and a light emitting part may be formed on a flat surface of the heat sink, and the heat sink may include a predetermined light emitting part on a lower surface of the groove.

In the above description, the number of light emitting diode chips constituting the first and second light emitting parts is formed as one, but the present invention is not limited thereto, and the number of light emitting diode chips constituting the first and second light emitting parts may be plural. have.

As described above, the present invention can be applied to products having various structures, and can be applied to general lighting devices. In order to be applied to a general lighting device, as many as 50 to 80 light emitting diodes are required. To this end, a package made of various structures as described above may be mounted on the substrate, and a plurality of light emitting diode chips may be directly mounted on the substrate.

As shown in FIG. 16, in the substrate 400 including a plurality of dots 500, each dot 500 may include a first light emitting part and a second light emitting part. That is, in each dot 500, white light of daylight color and warm white color may be realized. Of course, the present invention is not limited thereto, and each dot 500 may include any one of the first light emitting part and the second light emitting part. That is, the dot including the first light emitting part and the dot including the second light emitting part may be repeatedly arranged adjacently, or the area including the dot including the first light emitting part and the area including the dot including the second light emitting part may be distinguished from each other. have. This can be variously formed according to the process convenience or the desired purpose.

It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the invention as defined in the appended claims. It will be understood that the invention may be varied and varied without departing from the scope of the invention.

1 is a conceptual block diagram illustrating a light emitting device according to an embodiment of the present invention.

2 is a conceptual block diagram illustrating a light emitting device according to another embodiment of the present invention.

3A and 3B are graphs for explaining examples of the first and second control units.

4A and 4B are graphs for explaining another example of the first and second control units.

5 and 6 are graphs showing emission spectra of the light emitting device according to Example 1;

7 and 8 are graphs showing emission spectra of the light emitting device according to Example 2;

9 and 10 are graphs showing emission spectra of the light emitting device according to Example 3;

11 to 16 are schematic cross-sectional views showing examples in which the light emitting device according to the present invention is applied to various structures.

<Explanation of symbols for the main parts of the drawings>

20, 60: light emitting diode chip 30, 70: fluorescent material

200: first light emitting part 300: second light emitting part

Claims (21)

Board; And A first light emitting device and a second light emitting device disposed on the substrate; At least one of the first light emitting device and the second light emitting device includes a first light emitting part emitting a first white light and a second light emitting part emitting a second white light having a color temperature higher than that of the first white light, And the first light emitting part and the second light emitting part are driven independently. Board; And A first light emitting device and a second light emitting device disposed on the substrate; The first light emitting device includes a first light emitting part emitting a first white light, The second light emitting device includes a second light emitting part emitting a second white light having a color temperature higher than that of the first white light. And the first light emitting part and the second light emitting part are driven independently. The method according to claim 1 or 2, The first light emitting unit and the second light emitting unit includes a light emitting diode chip and a fluorescent material, The fluorescent material is represented by the following formula (1), <Formula 1> a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? dAl ₂ O ₃ ? e (M ^III O)? f (M ^Ⅳ ₂ O ₃ )? g (M ^V _o O _p )? h ( ^MVI _x O _y ) The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Ag, M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and M ^IV is at least one from the group containing Sc, B, Ga, In of the selected elements, the M ^ⅴ is Si, Ge, Ti, Zr, Mn, V, Nb, Ta, W, and at least one element selected from the group consisting of Mo, wherein M ^ⅵ is Bi, Sn, At least one element is selected from the group comprising Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and X Is at least one element selected from the group containing F, Cl, Br, I, wherein a, b, c, d, e, f, g, o, p, h, x, y is 0 <a 2, 0≤b≤2, 0≤c≤2, 0≤d≤8, 0≤e≤4, 0≤f≤3, 0≤g≤8, 1≤o≤2, 1≤p≤5, 0≤h≤2, 1≤x≤2, 1≤ Illumination apparatus characterized in that it is set in the range of y≤5 The method according to claim 1 or 2, The first light emitting unit and the second light emitting unit includes a light emitting diode chip and a fluorescent material, The fluorescent material is represented by the following formula (2), <Formula 2> a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? 4-abc (M ^III O)? 7 (Al ₂ O ₃ )? d (B ₂ O ₃ )? e (Ga ₂ O ₃ )? f (SiO ₂ )? g (GeO ₂ )? h (M ^IV _x O _y ) The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Au, M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and M ^IV is Bi, Sn, Sb, Sc, Y, La, In, At least one element is selected from the group comprising Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, wherein X is F, Cl, Br, I At least one element is selected from the group including a, b, c, d, e, f, g, h, x, and y are 0 <a≤4, 0≤b≤2, and 0≤c≤ 2, 0≤d≤1, 0≤e≤1, 0≤f≤1, 0≤g≤1, 0 <h≤0.5, 1≤x≤2, 1≤y≤5, 4-abc≥0 Lighting device, characterized in that set in the range. The method according to claim 1 or 2, The first light emitting unit and the second light emitting unit includes a light emitting diode chip and a fluorescent material, The fluorescent material is represented by the following formula (3), <Formula 3> a (M ^I O)? b (M ^II O)? c (Al ₂ O ₃ )? d (M ^III ₂ O ₃ )? e (M ^Ⅳ O ₂ )? f (M ^V _x O _y ) The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn and, wherein M ^ⅲ is at least one element selected from the group consisting of B, Ga, in, the M ^ⅳ is at least one element selected from the group comprising Si, Ge, Ti, Zr, Hf, M ^V is at least one of a group containing Bi, Sn, Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu Is selected, and a, b, c, d, e, f, x, and y are 0 <a ≤ 1, 0 ≤ b ≤ 2, 0 <c ≤ 8, 0 ≤ d ≤ 1, 0 ≤ e The lighting apparatus is set in the range of ≤ 1, 0 <f ≤ 2, 1 ≤ x ≤ 2, 1 ≤ y ≤ 5. The method according to claim 1 or 2, The first light emitting unit and the second light emitting unit includes a light emitting diode chip and a fluorescent material, The fluorescent material is represented by the following formula (4), <Formula 4> a (M ^I O)? b (M ^II O)? c (M ^III X)? d (M ^III ₂ O)? e (M ^Ⅳ ₂ O ₃ )? f (M ^V _o O _p ) _? g (SiO ₂ )? h ( ^MVI _x O _y ) The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn M ^III is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Ag, and M ^IV is at least one from the group containing Al, Ga, In, B Is selected from ^MV is Ge, V, Nb, Ta, W, Mo, Ti, Zr, Hf, P at least one element is selected, ^MVI is Bi, Sn, At least one element is selected from the group comprising Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and X Is at least one element selected from the group containing F, Cl, Br, I, wherein a, b, c, d, e, f, g, h, o, p, x, y is 0 <a 2, 0 <b≤8, 0≤c≤4, 0≤d≤2, 0≤e≤2, 0≤f≤2, 0≤g≤10, 0≤h≤5, 1≤o≤2, 1≤p≤5, 1≤x≤2, 1≤y Illumination apparatus, characterized in that set in the range of ≤5. The method according to claim 1 or 2, The first light emitting unit and the second light emitting unit includes a light emitting diode chip and a fluorescent material, The fluorescent material is represented by the following formula (5), <Formula 5> a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? d (Sb ₂ O ₅ )? e (M ^III O)? f (M ^IV _x O _y ) The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Ag, M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and M ^IV is Bi, Sn, Sc, Y, La, Pr, Sm, At least one element is selected from the group containing Eu, Tb, Dy, and Gd, and X is at least one element selected from the group containing F, Cl, Br, I, and the a, b, c, d, e, f, x, y are 0 <a≤2, 0≤b≤2, 0≤c≤4, 0 <d≤8, 0≤e≤8, 0≤f≤2, 1≤x≤ 2, 1 ≤ y ≤ 5 lighting device characterized in that it is set in the range. The method according to claim 1 or 2, The first light emitting unit and the second light emitting unit includes a light emitting diode chip and a fluorescent material, The fluorescent material is represented by the following formula (6), (6) a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? dGeO ₂ ? e (M ^III O)? f (M ^Ⅳ ₂ O ₃ )? g (M ^V _o O _p ) _? h ( ^MVI _x O _y ) The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Ag, M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, and M ^IV comprises Sc, Y, B, Al, Ga, In, La is at least one element selected from a group, the M ^ⅴ is at least one element in the group is selected to include Si, Ti, Zr, Mn, V, Nb, Ta, W, Mo, wherein M ^ⅵ is Bi, At least one element is selected from the group containing Sn, Pr, Sm, Eu, Gd, and Dy, X is at least one element selected from the group containing F, Cl, Br, I, and a, b , c, d, e, f, g, h, o, p, x, y are 0 <a≤2, 0≤b≤2, 0≤c≤10, 0 <d≤10, 0≤e≤14 0≤f≤14, 0≤g≤10, 0≤h≤2, 1≤o≤2, 1≤p≤5, 1≤x≤2, and 1≤y≤5 Lighting equipment. The method according to claim 1 or 2, The first light emitting unit and the second light emitting unit includes a light emitting diode chip and a fluorescent material, The fluorescent material is represented by the following formula (7), <Formula 7> a (M ^I O)? b (M ^II ₂ O)? c (M ^II X)? dP ₂ O ₅ ? e (M ^III O)? f (M ^Ⅳ ₂ O ₃ )? g (M ^V O ₂ ) _? h ( ^MVI _x O _y ) The M ^I is at least one element selected from the group containing Pb, Cu, the M ^II is at least one element selected from the group containing Li, Na, K, Rb, Cs, Au, Ag, M ^III is at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and M ^IV is Sc, Y, B, Al, La, Ga, In At least one element is selected from the group including ^MV , and at least one element is selected from the group including Si, Ge, Ti, Zr, Hf, V, Nb, Ta, W, and Mo, and M ^VI is at least one element selected from the group containing Bi, Sn, Pr, Sm, Eu, Gd, Dy, Ce, Tb, and X is at least one element from the group containing F, Cl, Br, I And a, b, c, d, e, f, g, h, x, and y are 0 <a ≤ 2, 0 ≤ b ≤ 12, 0 ≤ c ≤ 16, 0 <d ≤ 3, 0 The lighting apparatus is set in the range of ≤e≤5, 0≤f≤3, 0≤g≤2, 1≤x≤2, and 1≤y≤5. The method according to claim 1 or 2, The first light emitting unit and the second light emitting unit includes a light emitting diode chip and a fluorescent material, Illumination device characterized in that the fluorescent material comprises a single or a plurality. The method according to claim 1 or 2, The first light emitting unit and the second light emitting unit includes a light emitting diode chip and a fluorescent material, And the light emitting diode chip emits blue or UV light. The method according to claim 1 or 2, And a controller for controlling a voltage applied to any one of the first light emitting part, the second light emitting part, or a combination thereof from the outside. The method according to claim 12, And the control unit adjusts the voltage received from the outside according to time and applies it to any one of the first light emitting unit, the second light emitting unit, or a combination thereof. 14. The method of claim 13, The control unit increases and decreases the voltage received from the outside every 24 hours to apply to any one of the first light emitting unit, the second light emitting unit or a combination thereof. The method according to claim 2, And the first light emitting part and the second light emitting part are formed in one package. 16. The method of claim 15, The package includes light emitting diode chips mounted on the first light emitting part and the second light emitting part on a package substrate, and each of the first light emitting part and the second light emitting part is disposed on the LED chip. Illumination apparatus characterized in that the fluorescent material is disposed. 16. The method of claim 15, The package includes a heat sink for dissipating heat generated from the light emitting diode chip, wherein the light emitting diode chips of the first and second light emitting units are mounted on the heat sink, and the first light emitting diode chips are mounted on the light emitting diode chips. An illumination device, characterized in that the fluorescent material of the first and second light emitting portion is disposed respectively. The method according to claim 1 or 2, The first light emitting part includes a first light emitting diode chip and first fluorescent means composed of at least one fluorescent material, The second light emitting part includes a second light emitting diode chip and second fluorescent means composed of at least one fluorescent material, And said first fluorescent means and said second fluorescent means are different. 19. The lighting apparatus according to claim 18, wherein the first fluorescent means comprises at least one fluorescent material having a light emission peak wavelength different from that of the fluorescent material contained in the second fluorescent means. 19. The method of claim 18, wherein all the fluorescent materials included in the first fluorescent means and all the fluorescent materials included in the second fluorescent means are the same, wherein the first fluorescent means and the second fluorescent means have a component ratio of the fluorescent materials Lighting device characterized in that the other. The method according to claim 1 or 2, The first light emitting part includes a first light emitting diode chip and first fluorescent means composed of at least one fluorescent material, The second light emitting part includes a second light emitting diode chip and second fluorescent means composed of at least one fluorescent material, And the first light emitting diode chip and the second light emitting diode chip have different light emission wavelengths.

Images