KR101116129B1 - The composition and manufacturing method of water permeable concrete - Google Patents

The composition and manufacturing method of water permeable concrete Download PDF

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KR101116129B1
KR101116129B1 KR20090063791A KR20090063791A KR101116129B1 KR 101116129 B1 KR101116129 B1 KR 101116129B1 KR 20090063791 A KR20090063791 A KR 20090063791A KR 20090063791 A KR20090063791 A KR 20090063791A KR 101116129 B1 KR101116129 B1 KR 101116129B1
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permeable concrete
concrete composition
aggregate
water
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KR20110006242A (en
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윤용선
최용민
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한일시멘트 (주)
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/145Calcium sulfate hemi-hydrate with a specific crystal form
    • C04B28/146Calcium sulfate hemi-hydrate with a specific crystal form alpha-hemihydrate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/16Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing anhydrite, e.g. Keene's cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
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    • C04B24/34Natural resins, e.g. rosin
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • C04B28/12Hydraulic lime
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Ceramic Engineering (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
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Abstract

본 발명은 포틀랜드시멘트 20~40kg에 α-반수석고를 2~15kg, CSA(Calcium sulfo aluminate)2~10 kg와 생석회(CaO) 0.5~5kg 타타르산 Tartaric acide( C4H6O6) 0.05~1.0 kg 고성능 감수제를 시멘트의 0.5~1.0kg, 스테아린산염(Ca(C18H35O2)2) 0.1~0.5kg, 10~20㎜의 천연야자섬유 1~3kg, 송이석을 미분쇄한 분말도(2,000~5,000cm2/g) 3~20kg, 재활용 황토벽돌을 분쇄한 골재와 모르타르 생산 공장에서 모래선별 후 부산물로 발생하는 콩자갈(5mm~ 10mm)을 80~85kg를 혼합한 신개념의 기능성 투수콘크리트용 모르타르조성물로써 초속경, 고강도, 무수축, 친환경, 고내구성의 기능을 갖는 다기능성 투수콘크리트 조성물 및 그 제조방법에 관한 것이다.The present invention is 20 ~ 40kg Portland cement 2 ~ 15kg α- hemihydrate gypsum, 2 ~ 10 kg of CSA (Calcium sulfo aluminate) and 0.5 ~ 5kg of quicklime (CaO) Tartaric acide tartaric acide (C 4 H 6 O 6 ) 0.05 ~ 0.5 kg to 1.0 kg of cement with 1.0 kg high performance water reducing agent, 0.1 to 0.5 kg of stearate (Ca (C 18 H 35 O 2 ) 2 ), 1 to 3 kg of natural palm fiber of 10 to 20 mm 3 ~ 20kg of island (2,000 ~ 5,000cm 2 / g), new concept of mixed aggregates crushed ocher brick and 80 ~ 85kg of soybean (5mm ~ 10mm) generated as a by-product after sand selection in the mortar production plant As a mortar composition for water-permeable concrete, it relates to a multifunctional water-permeable concrete composition having a function of ultrafast mirror, high strength, non-shrinkage, environment-friendly, high durability, and a manufacturing method thereof.

Description

투수콘크리트 조성물 및 그 제조방법 {The composition and manufacturing method of water permeable concrete} Water-permeable concrete composition and method for manufacturing the same {The composition and manufacturing method of water permeable concrete}

본 발명은 자건거도로, 생태공원내 산책로, 탐방로, 체험마을내 도로, 주차장등 의 투수성이 요하는 도로 및 하천등의 투수콘크리트 조성물 및 그 제조방법에 관한 것이다.The present invention relates to a water-permeable concrete composition such as roads and rivers, such as roads and rivers that require permeability, such as bicycle paths, trails in ecological parks, trails, experience village roads, and parking lots.

기존 투수콘크리트의 경우에는 인근의 레미콘 batcher에서 보통포틀랜트 시멘트와 천연골재, 부순골재 및 순환골재와 착색재로 무기계안료를 첨가하고 최소한의 물을 사용하여 노슬럼프 상태로 혼합하여 덤프트럭으로 운반 포설하는 습식방식으로 시공되고 있고, 운반과정상에 수분증발을 막기 위해서 별도의 양생포 및 차단장치를 덤프트럭에 설치하여 운행하고 있으며 현장여건상의 공사 지연시 제품의 겉마름으로 현장에서 살수하는 등 시공상의 문제점과 레미콘 batcher에서 현장시공까지의 90분 이내에서만 작업이 가능하여 작업의 한계성이 있으며 천연골재사용으로 골재원의 고갈에도 영향이 있다.In the case of conventional pitched concrete, inorganic pigments are added to ordinary portland cement, natural aggregates, crushed aggregates, circulating aggregates, and coloring materials in a nearby ready-mixed concrete batcher. In order to prevent water evaporation during the transport process, separate curing guns and blocking devices are installed in the dump truck, and when the construction conditions are delayed, water is sprayed on the site by the dryness of the product. There is a limitation of the work because it can be worked only within 90 minutes from the ready-mixed concrete batcher to the site construction.

또한 기존의 투수콘크리트의 경우에는 시멘트의 건조수축으로 인한 건조수축 균열과 시멘트 및 골재외의 가용성 염류등에 의한 원인으로 발생되는 백화현상으로 인한 문제가 야기되기도 하며 동결융해로 인한 팽창압으로 인하여 균열 및 표면박리현상도 발생하고 있는게 현실이며, 시멘트의 특성상 압축강도는 우수하나 휨강도에는 취약한 부분이 있어 지반침하 및 하중에 의한 균열발생도 나타나는게 현실이다.In addition, conventional permeable concrete may cause problems due to dry shrinkage cracking caused by dry shrinkage of cement and whitening phenomena caused by soluble salts other than cement and aggregates, and cracks and surfaces due to expansion pressure due to freezing thawing. The peeling phenomenon is also occurring, and because of the characteristics of cement, the compressive strength is excellent, but there is a weak part in the flexural strength.

종래의 경우 습식생산방식의 작업시간(운반거리)이 90분 이내로 한정되어 있어 작업현장의 한계성을 해결하고자 모르타르화 하는 건식방식으로 생산하여 현장에서 물만 부어 작업이 가능하도록 하여 작업성 및 시공의 용이성을 향상하고자 하며, 천연골재의 고갈 문제를 황토벽돌 공정에서 발생되는 황토벽돌과 모르타르 생산 공장에서 모래선별 후 부산물로 발생하는 콩자갈(5mm~10mm)를 재활용하고, 시공후 시멘트의 건조수축으로 인한 균열, 표면박리, 백화발생을 방지하고 내구성 및 긴급공사가 가능하도록 초속경, 고강도성과 원적외선 및 탈취기능을 가지며, 천연야자섬유를 사용하여 휨강도를 향상시키고 송이석을 미분쇄하여 천연안료로 사용하여 투수콘크리트 조성물을 개발하자 한다.In the conventional case, the working time (transportation distance) of the wet production method is limited to within 90 minutes, and it is produced in a dry method that mortars to solve the limitation of the work site, so that only water can be poured in the field so that workability and ease of construction are possible. The problem of depletion of natural aggregate is recycled soybean gravel (5mm ~ 10mm) generated as a by-product after sand selection in ocher brick and mortar production plant in ocher brick process, and the dry shrinkage of cement after construction It prevents cracking, surface peeling and whitening, and has super speed mirror, high strength, far infrared rays and deodorizing function to enable durability and emergency construction. It improves bending strength by using natural palm fiber and finely grinds pine stone to use as natural pigment. Let's develop a permeable concrete composition.

이에 본 발명은 상기와 같은 문제점을 해결하기 위해서 재활용 황토벽돌과 모르타르 생산공장에서 발생하는 콩자갈을 80~85kg, 포틀랜드시멘트 20~40 kg에 초속경 및 고강도재료로 α-반수석고를 2~15kg, CSA(Calcium sulfo aluminate)2~10 kg와 시멘트건조수축 방지제로 생석회(CaO) 0.5~5kg를 사용하며, 현장 작업시간 조절을 위해 지연제로 타타르산 Tartaric acide( C4H6O6) 0.05~1.0 kg 고성능 감수제를 시멘트의 0.5~1.0kg, 백화방지를 위해 스테아린산염계(Ca(C18H35O2)2)를 0.1~0.5kg, 투수콘크리트의 휨강도 향상을 위해 10~20㎜크기의 천연 야자섬유를 1~3kg, 원적외선 및 탈취효과의 기능을 부여하기 위해 송이석을 미분쇄한 분말도(2,000~5,000cm2/g) 3~20kg를 혼합한 신개념의 기능성 투수콘크리트용 모르타르조성물로써 초속경, 초고강도, 무수축, 친환경, 고내구성의 기능을 갖는 다기능성 투수콘크리트 조성물 및 그 제조방법에 관한 것이다.In order to solve the problems described above, the present invention provides 80 to 85 kg of soybean gravel generated from recycled ocher bricks and mortar production plants, and 2 to 15 kg of α-half gypsum as a super hard and high strength material in 20 to 40 kg of Portland cement. , 2 ~ 10 kg of CSA (Calcium sulfo aluminate) and 0.5 ~ 5kg of quicklime (CaO) as cement dry shrinkage inhibitor, Tartaric acide (C 4 H 6 O 6 ) 0.5 kg to 1.0 kg of 1.0 kg high-performance water reducing agent, 0.1 to 0.5 kg of stearate (Ca (C 18 H 35 O 2 ) 2 ) to prevent bleaching, and 10 to 20 mm natural to improve the bending strength of permeable concrete This is a new concept functional mortar composition for water permeable concrete mixed with 1 ~ 3kg of palm fiber, 3 ~ 20kg of finely ground powder (2,000 ~ 5,000cm 2 / g) to give the function of far infrared rays and deodorizing effect. Light, ultra high strength, no shrinkage, eco-friendly, high durability Relates to a multifunctional water-permeable concrete composition and a method of manufacturing the same.

본 발명은 종래의 투수콘크리트제품에 비해 현장에서 물만 부어 시공하므로써 작업시간 및 운반시간의 제한이 없어 시공성 및 작업성이 유리하며 건조수축으로 인한 균열발생이 없어 균열유발발생줄눈 공정을 생략할 수 있다. 또한 시멘트 백화현상을 방지할 수 있으며, 동결융해저항성이 우수하며 약2~4배의 우수한 투수성 가지며, 초기강도(재령1일)에서 약 8~10배의압축강도를 향상되었고, 천연야자섬유를 사용하여 휨강도에도 2.3~3.3배 향상되었으며, 인공섬유에 비해 가격이 저렴하여 경제성 및 친환경성에 유리하다The present invention is advantageous in terms of workability and workability because there is no limitation of working time and transport time by pouring only water in the field compared to conventional water-permeable concrete products, and there can be no crack generation caused by dry shrinkage, so that the crack inducing joint process can be omitted. . In addition, it prevents cement whitening, has excellent freeze-thawing resistance, has excellent water permeability of about 2 ~ 4 times, and improves compressive strength of about 8 ~ 10 times at initial strength (1 day of age). The flexural strength has been improved by 2.3 ~ 3.3 times by using, and the price is cheaper than that of artificial fibers, which is advantageous for economic and eco-friendliness.

또한, 기존 제품에 비해 응결시간이 약 2~20배 빠르므로 공기단축효과와 긴급공사에 적합하고 α-반수석고와, 송이석분말을 친환경성과 기능성의 투수콘크리트 제조가 가능하며 황토골재와 콩자갈를 재활용하므로서 환경친화적인 장점이다.In addition, the condensation time is about 2 ~ 20 times faster than the existing products, so it is suitable for the air shortening effect and urgent construction, and it is possible to manufacture permeable concrete with eco-friendly and functional properties of α-half gypsum and pine stone, Recycling is an environmentally friendly advantage.

상기와 같은 문제점을 해결하기 위하여 본 발명은 투수콘크리트용 드라이모르타르의 조성물에 관한 것으로서 포틀랜드시멘트 20~40 kg에 초속경, 고강도, 팽창제어 재료로 α-반수석고를 2~15kg, CSA(Calcium sulfo aluminate)2~10 kg와 생석회(CaO) 0.5~5kg를 사용하며, 현장 작업시간 조절을 위해 지연제로 타타르산 Tartaric acide( C4H6O6)In order to solve the problems described above, the present invention relates to a composition of dry mortar for permeable concrete, and has a port speed of 20 to 40 kg, a high speed, high strength, expansion control material, α-15 hemihydrate gypsum, 2-15 kg, CSA (Calcium sulfo). Aluminate) 2-10 kg and 0.5-5 kg of quicklime (CaO). Tartaric acide (C 4 H 6 O 6 )

0.05~1.0 kg 지연제로 타타르산( C4H6O6), 구연산(C6H8O7) 중에서 선택된 어느 하나의 화합물 이거나 둘이상의 화합물을 사용할 수도 있다.As a 0.05 to 1.0 kg retardant, any one compound selected from tartaric acid (C 4 H 6 O 6 ), citric acid (C 6 H 8 O 7 ), or two or more compounds may be used.

분말형 나프탈렌계 고성능 감수제를 시멘트의 0.5~1.0kg, 백화방지를 위해 스테아린산염계(Ca(C18H35O2)2)를 0.1~0.5kg, 0.5 ~ 1.0kg of cement for powdered naphthalene-based high performance water reducing agent, 0.1 ~ 0.5kg for stearic acid salt (Ca (C 18 H 35 O 2 ) 2 ),

감수제로 나프탈렌계화합물, 리그린계화합물, 폴리카르본산계화합물 중에서 선택된 어느 하나의 화합물 이거나 둘이상의 화합물을 사용할 수도 있다.As the water reducing agent, any one compound selected from naphthalene compounds, ligline compounds, and polycarboxylic acid compounds may be used, or two or more compounds may be used.

투수콘크리트의 휨강도 향상을 위해 10~20㎜크기의 야자섬유 1~3kg을 첨가하였으 며,In order to improve the bending strength of the permeable concrete, 1 ~ 3kg of palm fiber of 10 ~ 20㎜ size is added.

천연섬유로 사탕수수섬유, 황마섬유 중에서 선택된 어느 하나의 화합물 이거나 둘이상의 화합물을 사용할 수도 있다.As natural fibers, any one compound selected from sugarcane fibers and jute fibers, or two or more compounds may be used.

원적외선 및 탈취효과의 기능을 부여하기 위해 다기성(원적외선, 음이온등) 송이석을 볼밀로 미분쇄한 분말도(2,000~5,000cm2/g) 3~20kg와 재활용 황토벽돌을 1~10mm로 분쇄한 골재와 레미탈공장에서 모래 선별후 부산물로 발생되는 콩자갈을 80~85kg를 고밀도 믹서(드럼타입)에서 120~200초 혼합한 신개념의 기능성 투수콘크리트용 모르타르조성물로써 초속경, 고강도, 무수축, 친환경, 고내구성의 기능을 갖는 다기능성 투수콘크리트 조성물 및 그 제조방법에 관한 것이다.To give the function of far-infrared and deodorant effect, 3 ~ 20kg of powder diagram (2,000 ~ 5,000cm 2 / g) and reclaimed ocher bricks are pulverized by ball milling multi-magnetic (far-infrared, anion, etc.) pine stone A new concept of functional mortar for permeable concrete mixed with 80 ~ 85kg of soybean gravel generated by sand after sorting sand at an aggregate and remittal plant in a high density mixer (drum type). It relates to a multifunctional water-permeable concrete composition having a function of eco-friendly, high durability, and a method of manufacturing the same.

본 발명에서 사용된 각 조성물의 작용기구를 설명하며,Describe the mechanism of action of each composition used in the present invention,

스테아린산계 화합물은 화학적 반응하지 않고, 물리적으로 충전되어 친수되어 친수기는 모세관 공극에서 시멘트 및 골재로 배향하고, 소수기에는 모세관 공극의 내부로 배향함으로써 모세관공극에서의 수분 이동을 막아 백화성분이 콘크리트 및 모르타르의 표면으로 이동하는 것을 방지하여 백화를 저감시키게 된다. 백화방지제는 스테아린산계화합물, 실란계화합물 중에서 선택된 어느 하나의 화합물 이거나 둘이상의 화합물을 사용할 수도 있다.Stearic acid-based compounds do not chemically react, but are physically filled and hydrophilic, so that the hydrophilic groups are oriented in the capillary pores to cement and aggregates, and the hydrophobic groups are oriented in the capillary pores to prevent water migration from the capillary pores, thereby making the whitening component concrete and The whitening is reduced by preventing migration to the surface of the mortar. The anti-whitening agent may be any one compound selected from stearic acid compounds and silane compounds, or two or more compounds may be used.

α-반수석고, CSA, CaO 는 α-Half Gypsum, CSA, CaO

속경성 및 무수축성을 확보하기 위해 조강바인더(CSA, α-반수석고)를 사용하였다.A crude steel binder (CSA, α-half gypsum) was used to secure fast hardening and shrinkage.

조강바인더의 수화반응을 살펴보면,Looking at the hydration reaction of the crude steel binder,

① 3CaO.3Al2O3.CaSO4+18H2O① 3CaO.3Al2O3.CaSO4 + 18H2O

→3CaO.Al2O3.3CaSO4.12H2O+2Al(OH)3                         → 3CaO.Al2O3.3CaSO4.12H2O + 2Al (OH) 3

② 3CaO.3Al2O3.CaSO4+2CaSO4+32H2O② 3CaO.3Al2O3.CaSO4 + 2CaSO4 + 32H2O

→3CaO.Al2O3.3CaSO4.32H2O+2Al(OH)3                         → 3 CaO.Al 2 O 3.3 Ca aSO4.32 H 2 O + 2 Al (OH) 3

③ 3CaO.3Al2O3.CaSO4+6Ca(OH)2+2CaSO4+26H2O③ 3CaO.3Al2O3.CaSO4 + 6Ca (OH) 2 + 2CaSO4 + 26H2O

→3(3CaO.Al2O3.3CaSO4.12H2O)                         → 3 (3CaO.Al2O3.3CaSO4.12H2O)

④ 3CaO.3Al2O3.CaSO4+6Ca(OH)2+8CaSO4+74H2O④ 3CaO.3Al2O3.CaSO4 + 6Ca (OH) 2 + 8CaSO4 + 74H2O

→3(3CaO.Al2O3.3CaSO4.32H2O)                        → 3 (3CaO.Al2O3.3CaSO4.32H2O)

조강바인더에(CSA:3CaO.3Al2O3.CaSO4)에 α-반수석고를 공급하여 팽창물질인 Ettringite를 생성시켜 무수축성을 확보하였고 OPC내부의 C3A와 반응하여 C3A 활성을 촉진시켜 속경성을 부여하였음.The steel binder: supplying an α- half of the plaster (CSA 3CaO.3Al2O3.CaSO4) to generate the expansion material of Ettringite was secured non-shrinkable grant in hard to promote C3A active to react with the OPC internal C 3 A Yes.

α반수석고(α?CaSO4?1/2H2O)는 [도1]에서 보는바와 같이 이수석고(CaSO4?2H2O)로부터 상압수용액법, 가압수열법, 마이크로웨이브법 및 수열반응법 등에 의해 습식가압 탈수화하여 건조 제조되어진다. α half gypsum (α? CaSO 4? 1 / 2H 2 O) is high yisuseok As shown in Fig. 1] (CaSO 4? 2H 2 O) from the normal pressure solution method, a pressure hydrothermal method, a microwave method and a hydrothermal reaction method It is manufactured by drying by wet pressure dehydration by, for example.

이러한 과정으로부터 제조되는 α반수석고는 시멘트와 동등한 기계적 강도를 가지며, 속경성을 지니고 있어 주로, 의료용 및 공업용 형재등에 사용되어지고 있다.The α hemihydrate gypsum produced from such a process has the same mechanical strength as that of cement and has a fast hardness, and is mainly used for medical and industrial shapes.

천연야자섬유의 균열구속효과 및 역학적 거동으로 나타내어, 취성 매트릭스 내에 섬유를 분산시킴에 의해. 인장.휨강도 및 충격강도 등에 역학적으로 성질이 개선되며 인공섬유에 비해 가격이 저렴하고 성능도 우수한 특성을 보이고 있다.The crack-binding effect and the mechanical behavior of natural palm fibers are shown by dispersing the fibers in a brittle matrix. Its mechanical properties are improved mechanically for tensile, flexural and impact strength, and it is cheaper than artificial fiber and shows excellent performance.

또한 α-반수석고와 송이석을 사용하여 인체의 신진대사기능의 활성화를 돕는 원적외선 방사골재를 사용하였다.In addition, far-infrared radiation aggregate was used to help activate the metabolic function of the human body using α-half gypsum and Song-seok.

송이석을 미분쇄하여 천연안료로 사용하므로써 친환경성과 경제성을 확보하였다.By crushing Songseok Stone to use it as a natural pigment, eco-friendliness and economics were secured.

[표1] 사용재료별 물리.화학적 특성[Table 1] Physical and chemical properties by materials used

재료명Name of material 화학성분Chemical composition 물리적특성Physical properties SiO2 SiO 2 Al2O3 Al 2 O 3 Fe2O3 Fe 2 O 3 CaOCaO MgOMgO SO3SO3 K2OK2O ig.lossig.loss 분말도
(cm2/g)
Powder
(cm 2 / g)
진비중Heavy weight
시멘트cement 21.2121.21 5.175.17 3.343.34 62.7262.72 2.412.41 2.342.34 1.201.20 32503250 3.153.15 CSACSA 10.9410.94 35.9635.96 2.162.16 41.7541.75 0.200.20 8.558.55 0.280.28 0.460.46 42304230 2.832.83 황토골재Ocher aggregate 51.9651.96 26.4626.46 5.365.36 1.801.80 1.131.13 0.050.05 9.519.51 -- -- 생석회quicklime 2.962.96 1.131.13 1.881.88 74.9674.96 3.273.27 -- 14.7714.77 송이석분말Songseok Stone Powder 40.4240.42 18.1018.10 10.8710.87 2.752.75 1.781.78 2.942.94 0.930.93 1.371.37 46284628 1.181.18

재료명Name of material 화학성분Chemical composition 물리적특성Physical properties 이수
석고
complete
gypsum
반수
석고
Half
gypsum
CaCO3CaCO3 SO3SO3 MgOMgO 분말도
(cm2/g)
Powder
(cm 2 / g)
진비중Heavy weight
α-반수석고α-Half Gypsum 4.434.43 90.0890.08 1.271.27 1.321.32 2.412.41 16581658 2.62.6

이하 본 발명을 실시예를 통하여 상세히 설명하기로 한다.Hereinafter, the present invention will be described in detail through examples.

실시예 1Example 1

제1공정(재활용 골재 제조)First Process (Manufacturing Recycled Aggregate)

황토벽돌 공장에서 부산물로 발생하는 황토벽돌 1000 kgOcher brick 1000 kg as a by-product from ocher brick factory

을 크러셔를 이용하여 분쇄 및 골재크기 5~10mm로 선별하고,Using a crusher to sort and crush the aggregate size 5 ~ 10mm,

레미탈 공장에서 모르타르의 잔골재로 활용하기 위해 건조 및 선별하고 부산물로 발생한 콩자갈 크기 5~10mm를 황토골재와 50:50의 비율로 혼합하여 제조한 후에In order to use as fine aggregate of mortar in Remithal factory, it is dried and screened and manufactured by mixing soybean gravel size 5 ~ 10mm generated by by-product with ocher aggregate in 50:50 ratio.

제2공정(송이석 분말 제조)2nd process (Song-seok powder manufacture)

송이석 100 kg,100 kg of pine nuts,

분쇄조제로 디에칠글리콜(DEG Diethylene glycol) 0.1 kg을 혼합하여 분말도 2,000~5,000cm2/g으로 미분쇄하여 제조한 후에After mixing 0.1 kg of diesel glycol (DEG Diethylene glycol) as a grinding aid to prepare a fine powder to 2,000 ~ 5,000cm 2 / g

제3공정(다기능성 투수콘크리트용 드라이모르타르 제조)3rd process (manufacturing dry mortar for multifunctional permeable concrete)

보통포트랜트 시멘트 13kg,Ordinary port cement 13kg,

α-반수석고 1.3kg,α-half gypsum 1.3 kg,

알루미나설포계 광물 CSA(Calcium sulfo aluminate) 1.3kg, 1.3 kg of alumina sulfo mineral CSA (Calcium sulfo aluminate),

생석회 0.5kg, 0.5 kg of quicklime,

타타르산 Tartaric acide( C4H6O6) 0.05kg,Tartaric acide (C 4 H 6 O 6 ) 0.05 kg,

스테아린산염(Ca(C18H35O2)2) 0.065kg,Stearate (Ca (C 18 H 35 O 2 ) 2 ) 0.065 kg,

천연야자섬유 2㎏, 2kg natural coconut fiber,

나프탈렌계 분말형 고성능감수제 0.5kg, Naphthalene powder type high performance reducer 0.5kg,

제2공정에서 제조된 조성물 3kg와 3 kg of the composition prepared in the second step and

제1공정에서 제조된 조성물 78.29kg을  78.29 kg of the composition prepared in the first step

고밀도 드럼믹서에서 혼합하여 투수콘크리트 조성물을 제조하였다. A water-permeable concrete composition was prepared by mixing in a high density drum mixer.

실시예2Example 2

제1공정(재활용 골재 제조)First Process (Manufacturing Recycled Aggregate)

황토벽돌 공장에서 부산물로 발생하는 황토벽돌 1000 kgOcher brick 1000 kg as a by-product from ocher brick factory

을 크러셔를 이용하여 분쇄 및 골재크기 5~10mm로 선별하고,Using a crusher to sort and crush the aggregate size 5 ~ 10mm,

레미탈 공장에서 모르타르의 잔골재로 활용하기 위해 건조 및 선별하고 부산물로 발생한 콩자갈 크기 5~10mm를 황토골재와 50:50의 비율로 혼합하여 제조한 후에In order to use as fine aggregate of mortar in Remithal factory, it is dried and screened and manufactured by mixing soybean gravel size 5 ~ 10mm generated by by-product with ocher aggregate in 50:50 ratio.

제2공정(송이석 분말 제조)2nd process (Song-seok powder manufacture)

송이석 100 kg,100 kg of pine nuts,

분쇄조제로 디에칠글리콜(DEG Diethylene glycol) 0.1 kg을 혼합하여 분말도 2,000~5,000cm2/g으로 미분쇄하여 제조한 후에,After mixing 0.1 kg of dimethyl glycol (DEG Diethylene glycol) as a grinding aid to prepare a fine powder to 2,000 ~ 5,000cm 2 / g,

제3공정(다기능성 투수콘크리트용 드라이모르타르 제조)3rd process (manufacturing dry mortar for multifunctional permeable concrete)

보통포트랜트 시멘트 13kg, Ordinary port cement 13kg,

α-반수석고 1.3kg,α-half gypsum 1.3 kg,

알루미나설포계 광물 CSA(Calcium sulfo aluminate) 1.3kg, 1.3 kg of alumina sulfo mineral CSA (Calcium sulfo aluminate),

생석회 0.5kg, 0.5 kg of quicklime,

스테아린산염(Ca(C18H35O2)2) 0.065kg,Stearate (Ca (C 18 H 35 O 2 ) 2 ) 0.065 kg,

천연야자섬유 2㎏, 2kg natural coconut fiber,

나프탈렌계 분말형 고성능감수제 0.5kg, Naphthalene powder type high performance reducer 0.5kg,

타타르산 Tartaric acide( C4H6O6) 0.05kg,Tartaric acide (C 4 H 6 O 6 ) 0.05 kg,

제2공정에서 제조된 조성물 3kg와 3 kg of the composition prepared in the second step and

제1공정에서 제조된 조성물 78.29kg을  78.29 kg of the composition prepared in the first step

고밀도 드럼믹서에서 혼합하여 투수콘크리트 조성물을 제조하였다.  A water-permeable concrete composition was prepared by mixing in a high density drum mixer.

실시예3Example 3

제1공정(재활용 골재 제조)First Process (Manufacturing Recycled Aggregate)

황토벽돌 공장에서 부산물로 발생하는 황토벽돌 1000 kg Ocher brick 1000 kg as a by-product from ocher brick factory

을 크러셔를 이용하여 분쇄 및 골재크기 5~10mm로 선별하고,Using a crusher to sort and crush the aggregate size 5 ~ 10mm,

레미탈 공장에서 모르타르의 잔골재로 활용하기 위해 건조 및 선별하고 부산물로 발생한 콩자갈 크기 5~10mm를 황토골재와 50:50의 비율로 혼합하여 제조한 후에, In order to use as a fine aggregate of mortar in the remithal factory, after drying and screening, after mixing soybean gravel size 5 ~ 10mm generated as a by-product in the ratio of 50:50 with ocher aggregate,

제2공정(송이석 분말 제조)2nd process (Song-seok powder manufacture)

송이석 100 kg,100 kg of pine nuts,

분쇄조제로 디에칠글리콜(DEG Diethylene glycol) 0.1 kg을 혼합하여 분말도 2,000~5,000cm2/g으로 미분쇄하여 제조한 후에,After mixing 0.1 kg of dimethyl glycol (DEG Diethylene glycol) as a grinding aid to prepare a fine powder to 2,000 ~ 5,000cm 2 / g,

제3공정(다기능성 투수콘크리트용 드라이모르타르 제조)3rd process (manufacturing dry mortar for multifunctional permeable concrete)

보통포트랜트 시멘트 12kg, Ordinary port cement 12kg,

α-반수석고 1.2kg, α-half gypsum 1.2 kg,

알루미나설포계 광물 CSA(Calcium sulfo aluminate) 1.2kg, 1.2kg of alumina sulfo mineral CSA (Calcium sulfo aluminate),

생석회 0.5kg, 0.5 kg of quicklime,

스테아린산염(Ca(C18H35O2)2) 0.060kg,Stearate (Ca (C 18 H 35 O 2 ) 2 ) 0.060 kg,

천연야자섬유 2㎏,  2kg natural coconut fiber,

나프탈렌계 분말형 고성능감수제 0.5kg, Naphthalene powder type high performance reducer 0.5kg,

타타르산 Tartaric acide( C4H6O6) 0.10kg,Tartaric acide (C 4 H 6 O 6 ) 0.10 kg,

제2공정에서 제조된 조성물 3kg와 3 kg of the composition prepared in the second step and

제1공정에서 제조된 조성물 79.44kg을  79.44 kg of the composition prepared in the first step

고밀도 드럼믹서에서 혼합하여 투수콘크리트 조성물을 제조하였다.  A water-permeable concrete composition was prepared by mixing in a high density drum mixer.

실시예4Example 4

제1공정(재활용 골재 제조)First Process (Manufacturing Recycled Aggregate)

황토벽돌 공장에서 부산물로 발생하는 황토벽돌 1000 kgOcher brick 1000 kg as a by-product from ocher brick factory

을 크러셔를 이용하여 분쇄 및 골재크기 5~10mm로 선별하고,Using a crusher to sort and crush the aggregate size 5 ~ 10mm,

레미탈 공장에서 모르타르의 잔골재로 활용하기 위해 건조 및 선별하고 부산물로 발생한 콩자갈 크기 5~10mm를 황토골재와 50:50의 비율로 혼합하여 제조한 후에,In order to use as a fine aggregate of mortar in the remithal factory, after drying and screening, after mixing soybean gravel size 5 ~ 10mm generated as a by-product in the ratio of 50:50 with ocher aggregate,

제2공정(송이석 분말 제조)2nd process (Song-seok powder manufacture)

송이석 100 kg,100 kg of pine nuts,

분쇄조제로 디에칠글리콜(DEG Diethylene glycol) 0.1 kg을 혼합하여 분말도 2,000~5,000cm2/g으로 미분쇄하여 제조한 후에,After mixing 0.1 kg of dimethyl glycol (DEG Diethylene glycol) as a grinding aid to prepare a fine powder to 2,000 ~ 5,000cm 2 / g,

제3공정(다기능성 투수콘크리트용 드라이모르타르 제조)3rd process (manufacturing dry mortar for multifunctional permeable concrete)

보통포트랜트 시멘트 11kg, Ordinary port cement 11kg,

α-반수석고 1.1kg, α-half gypsum 1.1 kg,

알루미나설포계 광물 CSA(Calcium sulfo aluminate) 1.1kg, 1.1 kg of alumina sulfo mineral CSA (Calcium sulfo aluminate),

생석회 0.5kg, 0.5 kg of quicklime,

스테아린산염(Ca(C18H35O2)2) 0.055kg,Stearate (Ca (C 18 H 35 O 2 ) 2 ) 0.055 kg,

천연야자섬유 2㎏, 2kg natural coconut fiber,

나프탈렌계 분말형 고성능감수제 0.5kg, Naphthalene powder type high performance reducer 0.5kg,

타타르산 Tartaric acide( C4H6O6) 0.20kg,0.20 kg Tartaric acide (C 4 H 6 O 6 ),

제2공정에서 제조된 조성물 3kg와 3 kg of the composition prepared in the second step and

제1공정에서 제조된 조성물 80.55kg을  80.55 kg of the composition prepared in the first step

고밀도 드럼믹서에서 혼합하여 투수콘크리트 조성물을 제조하였다.  A water-permeable concrete composition was prepared by mixing in a high density drum mixer.

실시예5Example 5

제1공정(재활용 골재 제조)First Process (Manufacturing Recycled Aggregate)

황토벽돌 공장에서 부산물로 발생하는 황토벽돌 1000 kgOcher brick 1000 kg as a by-product from ocher brick factory

을 크러셔를 이용하여 분쇄 및 골재크기 5~10mm로 선별하고,Using a crusher to sort and crush the aggregate size 5 ~ 10mm,

레미탈 공장에서 모르타르의 잔골재로 활용하기 위해 건조 및 선별하고 부산물로 발생한 콩자갈 크기 5~10mm를 황토골재와 50:50의 비율로 혼합하여 제조한 후에,In order to use as a fine aggregate of mortar in the remithal factory, after drying and screening, after mixing soybean gravel size 5 ~ 10mm generated as a by-product in the ratio of 50:50 with ocher aggregate,

제2공정(송이석 분말 제조)2nd process (Song-seok powder manufacture)

송이석 100 kg,100 kg of pine nuts,

분쇄조제로 디에칠글리콜(DEG Diethylene glycol) 0.1 kg을 혼합하여 분말도 2,000~5,000cm2/g으로 미분쇄하여 제조한 후에,After mixing 0.1 kg of dimethyl glycol (DEG Diethylene glycol) as a grinding aid to prepare a fine powder to 2,000 ~ 5,000cm 2 / g,

제3공정(다기능성 투수콘크리트용 드라이모르타르 제조)3rd process (manufacturing dry mortar for multifunctional permeable concrete)

보통포트랜트 시멘트 10kg,Ordinary port cement 10kg,

α-반수석고 1.0kg,α-half gypsum 1.0 kg,

알루미나설포계 광물 CSA(Calcium sulfo aluminate) 1.0kg,1.0 kg of alumina sulfo mineral CSA (Calcium sulfo aluminate),

생석회 0.5kg, 0.5 kg of quicklime,

스테아린산염(Ca(C18H35O2)2) 0.05kg,Stearate (Ca (C 18 H 35 O 2 ) 2 ) 0.05 kg,

천연야자섬유 2㎏, 2kg natural coconut fiber,

나프탈렌계 분말형 고성능감수제 0.5kg, Naphthalene powder type high performance reducer 0.5kg,

타타르산 Tartaric acide( C4H6O6) 0.30kg,Tartaric acide (C 4 H 6 O 6 ) 0.30 kg,

제2공정에서 제조된 조성물 3kg와 3 kg of the composition prepared in the second step and

제1공정에서 제조된 조성물 81.65kg을  81.65 kg of the composition prepared in the first step

고밀도 드럼믹서에서 혼합하여 투수콘크리트 조성물을 제조하였다.  A water-permeable concrete composition was prepared by mixing in a high density drum mixer.

실시예 6Example 6

실시예1~실시예4에서 제조한 조성물 100kg100 kg of the composition prepared in Examples 1-4

물 17kg을 강제식 콘크리트 믹서기에서 90초가 혼합후에 시공하였다.17 kg of water was constructed after 90 seconds of mixing in a forced concrete mixer.

비교실시예1Comparative Example 1

보통포트랜트 시멘트 17kg, 10mm강골재 80kg, 무기질 안료 3kg 및 Ordinary port cement 17kg, 10mm steel aggregate 80kg, mineral pigment 3kg and

물 17kg을 강제식 콘크리트 믹서기에서 90초가 혼합후에 시공하였다. 17 kg of water was constructed after 90 seconds of mixing in a forced concrete mixer.

실험 예Experimental Example

다기능성 투수콘크리트용 모르타르 조성물과 기존의 일반투수콘크리트와 비 교하여 투수성능, 압축강도, 길이변화, 동결융해, 백화억제능력을 기존제품과 비교 실시하였다.Permeability performance, compressive strength, length change, freeze thawing, and anti-whitening ability were compared with those of conventional products in comparison with the mortar composition for multifunctional permeable concrete and conventional permeable concrete.

투수시험은 KS F 2322에 준하여 실시하였고, 염에 의한 백화 및 동결융해로 인한 박리 및 균열은 장기적으로 나타나기 때문에 KS F 2456규격에 따라 동결융해 촉진시험을 진행하였으며, 백화발생유도는 10%-NaCl2수용액에 침지하여 백화발생을 촉진하여 시험을 진행하였음Permeability test was carried out in accordance with KS F 2322, and peeling and cracking due to whitening and freeze-thawing by salt appeared in the long term, so the freeze-thawing acceleration test was carried out according to KS F 2456 standard, and the occurrence of bleaching was 10% -NaCl. 2 Test was conducted by immersing in aqueous solution to promote the occurrence of whitening

또한 시멘트의 건조수축으로 발생하는 균열추정시험은 0.1*0.1*1m 길이변화시험체를 이용하여 재령70일간 측정하였다.In addition, the crack estimation test caused by dry shrinkage of cement was measured for 70 days using a 0.1 * 0.1 * 1m length change specimen.

압축강도 시험은 KS F 2405에 의거하여 진행을 기존제품과 비교하여 실시하였다Compressive strength test was conducted in accordance with KS F 2405 and compared with existing products.

응결시험은 KS L5108에 준하여 실시하였다.The condensation test was conducted according to KS L5108.

시험항목Test Items

시험항목은 투수율시험, 길이변화, 압축강도, 휨강도, 동결융해, 백화발생시험, 응결시험을 현행 투수시멘트 콘크리트제품과 비교하여 실시하였다The test items were permeability test, length change, compressive strength, flexural strength, freeze-thawing, bleaching test, and condensation test compared to current permeable cement concrete products.

시험결과Test result

1. 투수율 1. Permeability

투수콘크리트용 모르타르의 투수율 시험결과는 다음과 같음.  Permeability test results of mortar for permeable concrete are as follows.

[도2] 투수율시험결과Fig. 2 Permeability Test Results

구분division 시멘트cement α반수
석고
α half
gypsum
CSACSA CaOCaO 스테아린산염Stearate 천연야
자섬유
Wild field
Magnetic fiber
강골재Steel aggregate 콩자갈Bean pebbles 황토
벽돌
ocher
brick
송이석분말Songseok Stone Powder 안료Pigment 지연제Retardant 고성능
감수제
High performance
Water reducing agent
투수율
(%)
Permeability
(%)
비교시험예1Comparative Test Example 1 2020 -- -- -- -- -- 7777 -- 33 -- -- 100
100
실시
예1
practice
Example 1
1313 1.31.3 1.31.3 0.50.5 0.0650.065 22 -- 39.1539.15 39.1539.15 33 -- 0.050.05 0.50.5 108108
실시
예2
practice
Example 2
1212 1.21.2 1.21.2 0.50.5 0.0600.060 22 -- 39.7239.72 39.7239.72 33 -- 0.100.10 0.50.5 115115
실시
예3
practice
Example 3
1111 1.11.1 1.11.1 0.50.5 0.0550.055 22 -- 40.2840.28 40.2840.28 33 -- 0.200.20 0.50.5 120120
실시
예4
practice
Example 4
1010 1.01.0 1.01.0 0.50.5 0.0500.050 22 -- 40.8340.83 40.8340.83 33 -- 0.300.30 0.50.5 150150

투수시험결과 비교실시예1과 실시예1~4에서 모두 현행 제품에 비해 우수한 투수율을 나타났으며, In the permeability test results, Comparative Example 1 and Examples 1 to 4 showed excellent permeability compared to the current product,

2. 길이변화 안전성2. Length change safety

길이변화 시험체는 0.1× 0.1 ×1m 크기로 제작된 몰드와 0.00mm범위 까지 측정이 가능한 다이얼게이지를 이용하여 타설 초기부터 1hr단위로 Data값을 측정하여 재령 70일 까지 수축팽창변화를 측정하였다.The length change specimen was measured by shrinkage expansion change up to 70 days by measuring data value in the 1hr unit from the beginning of casting by using a mold manufactured to 0.1 × 0.1 × 1m size and dial gauge that can measure up to 0.00mm range.

[도3] 투수콘크리트 길이변화율[Figure 3] Permeable Concrete Length Change Rate

구분division 길이변화율(%)Length change rate (%) 1hr1hr 2hr2hr 3hr3hr 1일1 day 3일3 days 7일7 days 14일14 days 21일21st 28일28 days 40일40 days 50일50 days 70일70 days 비교실시예1Comparative Example 1 0.000.00 0.000.00 0.000.00 -0.03-0.03 -0.02-0.02 -0.01-0.01 -0.02-0.02 -0.03-0.03 -0.04-0.04 -0.05-0.05 -0.06-0.06 -0.06
-0.06
실시예1Example 1 0.000.00 -0.009-0.009 -0.012-0.012 -0.012-0.012 -0.012-0.012 -0.012-0.012 -0.012-0.012 -0.012-0.012 -0.012-0.012 -0.012-0.012 -0.012-0.012 -0.012-0.012

표3에 나타난 바와 같이, 비교실시예1의 경우 재령1일부터 건조수축을 시작하여 재령 70일에는 수축율 -0.06으로 나타났으며, 반면 투수모르타르(실시예2)의 경우에는 2hr경과시 -0.009, 3hr경과시 -0.012의 수축율을 보이고 재령70일 까지 체적변화 없이 안정적으로 나타났다.As shown in Table 3, in case of Comparative Example 1, dry shrinkage was started from 1 day of age, and at 70 days of age, the shrinkage was -0.06. , 3hr elapsed to -0.012 and stable until 70 days of age without volume change.

이는 속경성 및 고강도, 무수축성을 확보하기 위해 조강바인더(α-반수석고, CSA, CaO)의 반응을 통하여 팽창을 이용한 무수축성을 확보하였다.In order to secure fast hardness, high strength and non-shrinkability, the non-shrinkability using expansion was secured through the reaction of a crude steel binder (α-semi-hydrated gypsum, CSA, CaO).

CSA, 생석회, α-반수석고의 경우 수축보상 및 고강도, 초속경을 부여하는 물질로써 일반적을 알려져 있다. In the case of CSA, quicklime and α-mimetic gypsum, it is generally known as a material that gives shrinkage compensation, high strength, and superfast diameter.

CSA의 경우 수화생성물은 에트링자이트를 생성하며 시험결과 시멘트대비 5~15%을 혼입시에 가장 안정적인 체적변화를 나타났으며, CaO의 경우 수화생성물은 Calcium Hydroxide(Ca(OH)2)로 인한 팽창효과이며, .In the case of CSA, the hydration product produced ettringite, and the test result showed the most stable volume change when incorporating 5 ~ 15% of the cement. In the case of CaO, the hydration product was Calcium Hydroxide (Ca (OH) 2 ). Due to the swelling effect.

3%이상 시에는 발열반응으로 응결시간이 빨라져 작업시간 확보에 문제가 있는 것으로 나타났다.시멘트 대비 0.2~3% 혼입시에 체적변화 및 응결시간이 가장 효과적으로 나타났다When 3% or more, the condensation time is accelerated due to the exothermic reaction, which indicates that there is a problem in securing working time.

또한 α-반수석고의 경우에도 고강도, 초속경 및 팽창재의 역할을 하는데Also in the case of α-half gypsum, it acts as a high strength, super-speed mirror and expander

수차례 시험을 진행한 결과 시멘트 대비 10% 혼입시에 강도, 체적변화에 안정적인 값을 나타났다. As a result of several tests, it showed stable values in strength and volume change when 10% mixed with cement.

3. 압축강도 및 휨강도3. Compressive strength and flexural strength

투수콘크리트의 압축강도시험은 Φ10×20 몰드로 제작하였고, 휨강도는 4×4×16㎝ 공시체를 사용하였으며 재령1일에 공시체를 분리하여 21±2℃의 수조에 넣어 양생을 실시한 후 재령별 압축강도를 측정하였다.Compressive strength test of permeable concrete was made by Φ10 × 20 mold, and flexural strength was used by 4 × 4 × 16㎝ specimens, and the specimens were separated on a day of age and placed in a 21 ± 2 ℃ water bath for curing. Intensity was measured.

[표 4]투수콘크리트 압축강도 및 휨강도 시험결과[Table 4] Test result of permeable concrete compressive strength and flexural strength

구분division 압축강도(MPa)Compressive strength (MPa) 휨강도(MPa)Flexural strength (MPa) 1일1 day 3일3 days 7일7 days 28일28 days 28일28 days 비교실시예1Comparative Example 1 1.51.5 4.24.2 15.215.2 22.922.9 0.380.38 실시예1Example 1 15.615.6 19.819.8 34.534.5 46.546.5 1.261.26 실시예2Example 2 13.813.8 17.617.6 28.228.2 38.038.0 0.970.97 실시예3Example 3 13.213.2 16.216.2 27.127.1 36.736.7 0.890.89 실시예4Example 4 11.411.4 12.612.6 25.725.7 31.531.5 0.860.86

4. 응결시험   4. Condensation test

응결시험측정결과 Condensation test measurement result

[표5] 타타르산 Tartaric acide( C4H6O6)를 첨가한 응결시험측정결과[Table 5] Condensation test measurement results with tartaric acide (C 4 H 6 O 6 ) added

구분division 시멘트cement α반수
석고
α half
gypsum
CSACSA CaOCaO 스테아린산염Stearate 천연야
자섬유
Wild field
Magnetic fiber
강골재Steel aggregate 콩자갈Bean pebbles 황토
벽돌
ocher
brick
송이석분말
Songseok Stone Powder
안료Pigment 지연제Retardant 고성능
감수제
High performance
Water reducing agent
응결시간Setting time
초결First 종결closing 비교시험예1Comparative Test Example 1 2020 -- -- -- -- -- 7777 -- -- 33 -- -- 6:206:20 11:2611:26 실시
예1
practice
Example 1
1313 1.31.3 1.31.3 0.50.5 0.0650.065 22 -- 39.1539.15 39.1539.15 33 -
-
0.050.05 0.50.5 0:400:40 0:550:55
실시
예2
practice
Example 2
1212 1.21.2 1.21.2 0.50.5 0.0600.060 22 -- 39.7239.72 39.7239.72 33 -- 0.100.10 0.50.5 1:201:20 1:351:35
실시
예3
practice
Example 3
1111 1.11.1 1.11.1 0.50.5 0.0550.055 22 -- 40.2840.28 40.2840.28 33 -- 0.0200.020 0.50.5 2:102:10 2:252:25
실시
예4
practice
Example 4
1010 1.01.0 1.01.0 0.50.5 0.0500.050 22 -- 40.8340.83 40.8340.83 33 -- 0.300.30 0.50.5 3:303:30 3:503:50

실시예1의 경우 너무 빠르게 경화되어 작업성확보에 어려움이 있어 시멘트 및 α-반수석고의 반응시간 조절을 위해 타타르산 Tartaric acide( C4H6O6)를 0.1~0.3까지 첨가하면서 작업성확보를 해결하였다.In the case of Example 1 hardening so fast that it is difficult to secure the workability to ensure the workability by adding tartaric acide (C 4 H 6 O 6 ) to 0.1 ~ 0.3 to control the reaction time of cement and α- hemihydrate gypsum Solved.

그 결과 초결 1:20분에서 최대 3시간 30분정도의 작업시간을 확보할 수 있었다.As a result, it was possible to secure a working time of up to 3 hours and 30 minutes from the first 1:20 minutes.

지연제(Retarder)란 일반적으로 시멘트의 수화반응을 억제하여 콘크리트의 응결 또는 경화를 지연시키는 물질을 말한다.Retarder generally refers to a material that inhibits the hydration of cement to retard condensation or hardening of concrete.

시멘트 수화반응은 시멘트가 물과 접촉하면서 수산화칼슘, 에트린자이트, 규산칼슘수화물 등을 생성하기 때문에 발생한다. 그러므로 액상 중 칼슘이온(Ca+2)이 증가하여 최고치에 이른 후 다시 감소하게 되고, 이 초고치에 도달할 때까지의 시간이 규산칼슘수화물의 생성 개시시기 또는 응결 개시시기이다.Cement hydration occurs because cement produces calcium hydroxide, ethrinite, calcium silicate hydrate, etc. when it comes in contact with water. Therefore, the calcium ion (Ca + 2 ) in the liquid phase increases and decreases again after reaching the highest value, and the time until reaching the ultrahigh value is the start time of production or the start of condensation of calcium silicate hydrate.

따라서, 액상의 Ca+2가 최고치에 도달하는 시간(과포하 최대시간)을 연장시키는 화학물이 지연제로서 기능을 하며 일반적으로, 액상의 Ca+2를 봉쇄하는 것(Ca를 착염화하는 것)이나, 시멘트 입자에 수화방지막을 만드는 것이 지연제가 된다.Therefore, chemicals that extend the time (maximum time under supersaturation) of the liquid Ca +2 to its maximum function as a retarder and generally block the liquid Ca +2 (complexing Ca). ), Or to make a hydration prevention film on cement particles becomes a retardant.

그러나 지연제의양이 일정량이상 사용시 과지연으로 작업성에 문제가 있으며, 초기강도발현이 저하되는 문제가 있다.However, when the amount of the retardant is used over a certain amount, there is a problem in workability due to overdelay, and there is a problem in that initial strength expression is lowered.

본 시험결과 지연제의량이 0.4%이상사용시에는 응결지연이 너무 되어 현장시공에 문제가 있는 것을 나타났으며, 투수콘크리트의 시공시간을 고려한 적정 사용량은 0.2~0.3%범위이가 가장 이상적으로 나타났다.As a result of this test, when the amount of retardant was used more than 0.4%, there was a problem in the field construction because the condensation delay was too high.

5. 백화발생시험5. Whitening outbreak test

백화시험은 실시예3으로 제조한 조성물과 비교실시예1과 비교하여 실시하였다.The whitening test was conducted by comparing the composition prepared in Example 3 with Comparative Example 1.

시험은 10% NaCl2수용액을 제조하여 백화발생을 촉진하여 육안으로 관찰하였으며 그 결과는 [표6]과 [도3]에 나타냈다.In the test, a 10% NaCl 2 aqueous solution was prepared to promote whitening and visually observed. The results are shown in [Table 6] and [FIG. 3].

[표6] 백화발생 촉진시험결과[Table 6] Results of whitening development test

구분division 백화발생 유무Whitening occurrence 비교실시예1Comparative Example 1 U 실시예3Example 3 radish

[도3]에서 보듯이 비교실시의 경우에는 침지 후 재령3일 이후부터 표면에 흰색의 백화현상이 발생한 반면, 실시예2의 경우에는 스테아린산염(Ca(C18H35O2)2)에 의해 백화억제효과로 백화발생이 없었다.As shown in FIG. 3, in the case of the comparative example, white phenomena occurred on the surface from 3 days after immersion, whereas in Example 2, stearic acid salt (Ca (C 18 H 35 O 2 ) 2 ) was used. There was no whitening due to the whitening inhibitory effect.

그러나 스테아린산계 사용량을 증가할 수록 백화억제효과는 증진되나, 시멘트 대비 1.0%이상 사용시에는 투수율이 저하되어, 적정사용량은 시멘트대비 약 0.3~0.6%범위가 적정한 것으로 나타났다.However, as the amount of stearic acid used increased, the effect of suppressing bleaching was enhanced. However, when using more than 1.0% of cement, the permeability decreased, and the proper amount of use was about 0.3 ~ 0.6%.

6. 동결융해시험  6. Freeze thawing test

동결융해저항성시험은 KS F 2456 급속동결융해에 대한 콘크리트의 저항 시험방법에 준하여 시험을 실시하였으며 그 시험결과는 다음과 같다.The freeze-thaw resistance test was conducted in accordance with the test method for the resistance of concrete to rapid freezing and thawing. The test results are as follows.

[표7]동결융해저항성 측정시험[Table 7] Measurement of freezing resistance

사이클수Cycles 00 3030 6060 9090 120120 150150 180180 210210 240240 270270 300300 상태
동탕성계수(%)
condition
Dongtang coefficient (%)
실시예2Example 2 98.3598.35 97.7597.75 91.2491.24 86.9386.93 82.782.7 79.579.5 7272 68.2568.25 57.8957.89 -- --
비교
실시예1
compare
Example 1
92.2492.24 88.6388.63 79.5679.56 74.1674.16 65.2265.22 53.0553.05 -- -- -- -- --

실시예2로 제조한 투수콘크리트용 모르타르의 경우 210사이클에 탄성계수 68.25%를 유지하였으며, 비교실시예1의 경우에는 120사이클에서 65.22%의 상대동탄성계수를 나타냈다.In the case of the mortar for permeable concrete prepared in Example 2, the modulus of elasticity was maintained at 68.25% at 210 cycles, and in Comparative Example 1, the relative dynamic modulus was 65.22% at 120 cycles.

[표7]에서 보듯이 실시예2가 비교실시예1에 비해 동결융해저항성이 탁월한 것으로 나타났다.As shown in Table 7, Example 2 was found to have excellent freeze-thawing resistance compared to Comparative Example 1.

도1 각종 석고의 상변의 모식도1 Schematic diagram of the upper edge of various plaster

도2 본 발명의 길이변화측정결과 그래피Figure 2 is a graph of the result of measuring the change in length of the present invention

도3 본 발명의 백화시험 결과 사진Figure 3 photograph of the test results of the bleaching test of the present invention

Claims (5)

투수콘크리트 조성물에 있어서, In the pitcher concrete composition, 포틀랜드시멘트 20~40kg,Portland cement 20-40 kg, α-반수석고를 2~15kg,2-15 kg of α-half gypsum, CSA(Calcium sulfo aluminate)2~10kg,Calcium sulfo aluminate (CSA) 2-10 kg, 생석회(CaO) 0.5~5kg,Quicklime (CaO) 0.5-5 kg, 지연제 0.05~1.0kg,Retardant 0.05∼1.0kg, 천연야자섬유 1~3kg,1 to 3 kg of natural palm fiber, 고성능 감수제 0.5~1.0kg,High performance water reducing agent 0.5 ~ 1.0kg, 스테아린산염(Ca(C18H35O2)2) 0.1~0.5kg,Stearate (Ca (C 18 H 35 O 2 ) 2 ) 0.1-0.5 kg, 송이석을 미분쇄한 분말도(2,000~5,000cm2/g) 3~20kg,3 ~ 20kg fine powder (2,000 ~ 5,000cm 2 / g) 골재크기 5~10mm의 황토골재 35~45kg, 골재크기 5~10mm의 콩자갈 35~45kg로 혼합한 골재를 70~90kg로 조성되어 있음을 특징으로 하는 투수콘크리트 조성물.Permeable concrete composition characterized in that the aggregate is composed of 70 ~ 90kg aggregates mixed with 35 ~ 45kg of aggregate size 5 ~ 10mm ocher aggregate, 35 ~ 45kg aggregate size 5 ~ 10mm. 제 1항에 있어서, 상기 지연제는 타타르산( C4H6O6), 구연산(C6H8O7) 중에서 선택된 어느 하나의 화합물 이거나 둘이상의 화합물을 사용하고,The method of claim 1, wherein the retardant is any one compound selected from tartaric acid (C 4 H 6 O 6 ), citric acid (C 6 H 8 O 7 ) or two or more compounds, 상기 천연섬유는 야자섬유, 사탕수수섬유, 황마섬유 중에서 선택된 어느 하나의 화합물 이거나 둘이상의 화합물로 조성되어 있음을 특징으로 하는 투수콘크리트 조성물.The natural fiber is any one compound selected from palm fiber, sugarcane fiber, jute fiber, or a pitcher concrete composition, characterized in that it is composed of two or more compounds. 제 1항에 있어서, 상기 고성능 감수제는 나프탈렌계화합물, 리그린계화합물, 폴리카르본산계화합물 중에서 선택된 어느 하나의 화합물 이거나 둘이상의 화합물로 조성되어 있음을 특징으로 하는 투수콘크리트 조성물.The water-permeable concrete composition according to claim 1, wherein the high performance sensitizer is any one compound selected from naphthalene compounds, ligline compounds, and polycarboxylic acid compounds, or is composed of two or more compounds. 제 1항에 있어서, 상기 백화방지제는 스테아린산계화합물, 실란계화합물 중에서 선택된 어느 하나의 화합물 이거나 둘이상의 화합물로 조성되어 있음을 특징으로 하는 투수콘크리트 조성물. The water permeable concrete composition according to claim 1, wherein the anti-whitening agent is any one compound selected from stearic acid compounds and silane compounds or is composed of two or more compounds. 투수콘크리트 조성물의 제조방법에 있어서,In the method for producing a water-permeable concrete composition, 포틀랜드시멘트 20~40kg에 초속경, 고강도, 팽창제어 재료로 α-반수석고를 2~15kg, CSA(Calcium sulfo aluminate)2~10kg와 생석회(CaO) 0.5~5kg를 사용하며, 현장 작업시간 조절을 위해 지연제로 타타르산 Tartaric acide( C4H6O6) 0.05~1.0kg 분말형 나프탈렌계 고성능 감수제를 0.5~1.0kg 백화방지를 위해 스테아린산염(Ca(C18H35O2)2)를 휨강도 향상을 위해 천연야자섬유 1~3kg, 0.1~0.5kg, 원적외선 및 탈취효과의 기능을 부여하기 위해 송이석을 볼밀로 미분쇄한 분말도(2,000~5,000cm2/g) 3~20kg와 재활용 황토벽돌을 5~10mm로 분쇄한 골재와 레미탈공장에서 모래 선별후 부산물로 발생되는 콩자갈을 80~85kg를 고밀도 믹서(드럼타입)에서 120~200초 혼합하여 제조함을 특징으로 투수콘크리트 조성물의 제조방법.20 ~ 40kg Portland Cement, 2 ~ 15kg α-Half Gypsum, 2 ~ 10kg CSA (Calcium sulfo aluminate) and 0.5 ~ 5kg CaO, with super speed, high strength and expansion control material. Tartaric acide (C 4 H 6 O 6 ) 0.05∼1.0kg Powdered naphthalene-based high performance water reducing agent 0.5 ~ 1.0kg As a retardant, stearic acid salt (Ca (C 18 H 35 O 2 ) 2 ) was added to prevent bleaching. 1 ~ 3kg, 0.1 ~ 0.5kg of natural palm fiber for improvement, 3 ~ 20kg of fine powder (2,000 ~ 5,000cm 2 / g) and finely ground crushed pine granite with ball mill to give the function of far infrared rays and deodorizing effect Permeable concrete composition characterized in that it is prepared by mixing 80 ~ 85kg of soybean gravel generated as a by-product after sand sorting at 5-10 mm aggregate and crushed brick in 120 to 200 seconds in a high-density mixer (drum type) Manufacturing method.
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