KR101098850B1 - Integrated CO shift reactor with steam generating part and control method of outlet temperature using thereof - Google Patents

Abstract

The present invention relates to a carbon monoxide transition reactor including a steam generator and a method for controlling the outlet temperature of a carbon monoxide transition reactor using the same, and an object thereof is a carbon monoxide transition that can stably control the outlet temperature without using a separate complicated cooling pipe and a hot water pump. It is to provide an outlet temperature control method of a reactor and a carbon monoxide transition reactor using the same.

The configuration of the present invention comprises a steam generator (1) for generating steam as a heat source by combustion exhaust gas or reformed gas heat exchange; The carbon monoxide transition reaction unit (2) which is installed inside the steam generator and heat exchanged with the hot water stored in the steam generator at a lower temperature than that is stable to control the outlet temperature stably; comprises a steam generator A method for controlling the outlet temperature of a carbon monoxide transition reactor and a carbon monoxide transition reactor using the same.

Carbon monoxide transfer reactor, steam generator, heat pipe, catalyst bed, cooling pipe

Description

Integrated carbon shift reactor with steam generating part and control method of outlet temperature using

The present invention relates to a carbon monoxide transition reactor including a steam generator and a method for controlling the outlet temperature of a carbon monoxide transition reactor using the same. Specifically, a cooling medium is provided on the outer wall of the carbon monoxide transition reactor without a heat pipe installed thereon. A carbon monoxide transfer reactor providing a simple structure by integrating a steam generator and a carbon monoxide transition reactor so that the outlet temperature of the carbon monoxide transition reactor can be stably controlled so as to be in contact with each other, and a method for controlling the outlet temperature of a carbon monoxide transition reactor using such a structure will be.

The fossil fuel steam reforming process consists of a steam reforming reactor process in which the reaction proceeds above 700 ° C and a carbon monoxide transition reactor (or water gas shit reactor) process operating in the temperature range of 200 to 450 ° C.

In the above reaction, the steam reforming reaction is a strong endothermic reaction, in which a catalyst layer is usually heated by a combustion device such as a burner or a catalytic burner to maintain an appropriate operating temperature. At this time, the waste heat of the combustion flue-gas which is heated after the catalyst layer is discharged from the steam generator is configured to provide steam as a reaction raw material. The steam generator converts water into steam to generate steam. The heat source of the steam generator included in the steam reforming process mainly uses waste heat of combustion flue gas or reformed gas.

The carbon monoxide transfer reactor is a reaction that generates carbon dioxide and hydrogen by reacting carbon monoxide and water vapor, and is a weak exothermic reaction, and increases the yield of hydrogen. In the existing process, two adiabatic reactors for fast reaction speed and equilibrium carbon monoxide emission concentration are reduced. Mainly used. That is, the high temperature operating carbon monoxide transfer reactor operates in the temperature range of 300 to 450 ° C., and uses a fast reaction rate to reduce the outlet carbon monoxide by 2 to 3% and the outlet at the low temperature operating carbon monoxide transfer reactor operated at about 200 to 250 ° C. The carbon monoxide concentration is reduced to 1% or less. For controlling the temperature of the low temperature carbon monoxide transfer reactor, a heat exchanger for controlling the temperature of the reformed gas is installed at the rear end of the high temperature carbon monoxide transfer reactor and at the front end of the low temperature carbon monoxide transfer reactor.

In addition, the small- and medium-sized distributed production system for fuel cell hydrogen supply uses one reactor for simplicity and miniaturization.

However, when one reactor is used, if the inlet temperature is high, the reaction rate is increased to decrease the amount of catalyst used, but it is difficult to reduce the carbon monoxide concentration in the produced gas to 2% or less due to the high outlet temperature due to equilibrium conditions.

On the contrary, if the inlet temperature is low, the outlet temperature is also reduced to reduce the carbon monoxide concentration to 1% or less, but there is a problem that the reaction rate decreases, thus increasing the amount of catalyst used and increasing the total volume of the reactor.

Accordingly, the carbon monoxide transfer reactor of the forced cooling method is mainly adopted by installing a cooling device in the rear end portion of the reactor catalyst layer at around the inlet temperature of 180 ~ 220 ℃.

However, the existing cooling device is installed inside the catalyst bed and is cooled by steam, water, raw fossil fuel, air, etc., and thus, a liquid refrigerant requires a rotating device such as a hot water pump, thereby increasing the complexity of the system.

7 is a schematic diagram of a steam reforming system according to an exemplary embodiment of the present invention. As illustrated, a fossil fuel steam reforming system is typically a steam reforming reactor 51; Burner 52 and combustion space 53; Raw hydrocarbon desulfurizer 54; Raw material preheater 55; Steam generator 512; And a carbon monoxide transfer reactor 57.

In the steam reforming reactor 51, the steam reforming reaction proceeds at a temperature of about 600 ° C. to 800 ° C., and the temperature of the steam reforming reactor maintains the catalyst bed temperature using the combustion heat generated in the burner 52. Since the temperature of the combustion exhaust gas is supplied to the steam reforming catalyst layer adjacent to the combustion space and discharged, the temperature of the combustion exhaust gas is 500 ° C. or more, so that the heat exchange between the combustion exhaust gas heat recovery cooling pipe 59 of the steam generator 512 and the steam generator hot water storage unit 510 is performed. By supplying the amount of heat required to generate steam, it is cooled to a temperature below 200 ℃ and discharged. The raw hydrocarbon and steam are converted into hydrogen-rich reforming gas in the steam reforming reactor 51 and discharged to 500 ° C. or more, which is exchanged with the raw material hydrocarbon and steam mixture mixture to heat the carbon monoxide transition reactor 57. Supplied.

Since the carbon monoxide transition reactor 57 is usually configured in the form of an adiabatic reactor, the outlet of the carbon monoxide transition reactor in which the exothermic reaction proceeds is discharged from the reformed gas treated at a temperature higher than the inlet temperature. In this case, since the temperature of the reformed gas discharged from the carbon monoxide transition reactor is about 200 to 300 ° C., the steam generator 512 is equipped with a reforming gas heat recovery cooling pipe 58 to recover waste heat in the reformed gas, thereby providing additional steam generation heat supply. It is configured to be possible. Since the steam generator 512 is configured to control pressure to operate at a constant pressure, the boiling temperature of the hot water is maintained at a constant temperature and is operated at about 145 to 200 ° C. according to the set pressure.

In the drawing, reference numeral 56 denotes a raw material hydrocarbon and a steam mixer, and 511 denotes a steam generator steam storage.

[references]

1. "Fuel cell power generation system" (JP1994-140068, filed date: October 26, 1992)

2. "Carbon monoxide modifier for fuel cells" (JP1997-268001, filing date: 1996.04.01)

3. "CO transformer in reforming system for fuel cell" (JP2002-216827, filed date: Jan. 12, 2001)

4. "CO modification method in reformed gas" (JP2003-34505, filing date: July 19, 2001)

An object of the present invention for solving the above problems is to integrate the carbon monoxide transition reaction unit and heat recovery type steam generator having a similar operating temperature to miniaturize the device and to heat the heat generated by contacting the heat generated by the carbon monoxide transition reaction unit with the hot water storage zone of the steam generator. By providing a carbon monoxide transition reactor that can control the outlet temperature in a stable manner.

It is another object of the present invention to provide a method for controlling the outlet temperature of a carbon monoxide transition reactor that can stably control the outlet temperature without using a separate complicated cooling pipe and a hot water pump.

The present invention to achieve the object as described above and to solve the conventional drawbacks, the present invention comprises: a steam generator for generating steam by heat exchange between combustion exhaust gas waste heat and supply water as a raw material of steam;

Carbon monoxide transition unit comprising a steam generator, characterized in that the steam generator is characterized in that the unit is installed inside the steam generator is heat exchanged with the hot water stored in the steam generator at a lower temperature than the heat generation is stable control the outlet temperature; By providing a reactor.

The temperature control of the transition reaction outlet of the carbon monoxide transition reaction part controls the temperature of the gas introduced into the transition reaction inlet, the pressure inside the case of the steam generation part, and the transition of the hot water temperature in the boiling state and the rear end of the carbon oxide transition catalyst. The reaction unit case is characterized in that the temperature is controlled by adjusting any one or more of the areas in contact with the hot water portion.

The carbon monoxide transition reaction unit is operated in a temperature range of 180 ~ 300 ℃ by heat exchange with the steam generator to control the carbon monoxide transition reaction catalyst outlet temperature to 200 ℃ or less,

The hot water stored in the steam generating unit is characterized in that configured to operate in a temperature range of 145 ~ 180 ℃ by heat exchange with the carbon monoxide transition reaction unit.

The steam generator includes a steam generator case for storing hot water; A heat exchanger immersed in hot water stored in the steam generator case; An auxiliary electric heater installed on the inner wall of the steam generating unit case; characterized in that consisting of.

The steam generating unit case is horizontally isolated from the high-temperature water stored in the upper part is isolated and horizontally separated through a plurality of pipes constituting a heat exchanger; A vertical separator separating the horizontal separator into two space parts; A burner exhaust gas inlet formed at a lower portion of one side space divided by a vertical separation plate and a burner exhaust gas outlet formed at a lower portion of the other space; An upper opening which protrudes and is opened to a size into which the transition reaction part case of the carbon monoxide transition reaction part is inserted; A water vapor outlet formed at one side of the upper opening; It is characterized in that it comprises a; supplementary water supply port formed on one side higher than the lower horizontal isolation plate.

The heat exchanger is characterized in that a plurality of pipes having a different radius is installed in a coil shape having a separate circulation path.

The heat exchanger is characterized in that a plurality of tubes having a different radius is installed in a 'U' shape having a separate circulation path.

The carbon monoxide transition reaction unit is inserted into the upper open portion protruding from the upper portion of the steam generating unit case, the transition reaction portion case formed on the upper portion of the transition reaction inlet;

An inner riser pipe installed inside the transition reaction part case and having a transition reaction outlet at the upper end thereof bent to protrude through the transition reaction part case;

Characterized in that consisting of; carbon monoxide transfer reaction catalyst filled in the space between the transition reaction part case and the inner riser.

The carbon monoxide transition reaction unit is inserted into the upper open portion protruding from the upper portion of the steam generating unit case, the transition reaction portion case formed with a transition reaction inlet on the upper portion;

A lower end pipe connected to a lower portion of the transition reaction part case and an outer side, and penetrating the upper opening portion, the end section in which the transition reaction outlet is formed is bent;

Characterized in that consisting of; carbon monoxide transfer reaction catalyst charged in the transfer reaction case.

In another embodiment, the present invention includes a carbon monoxide transfer reactor including the steam generator, and heats the carbon monoxide transition reaction unit by contacting the heat generated by the carbon monoxide transfer unit with the hot water storage zone of the steam generation unit to heat exchange the carbon monoxide transition unit. To recover from

Transition reaction outlet temperature control of the carbon monoxide transition reaction part controls the temperature of the gas introduced into the transition reaction inlet, the pressure inside the case of the steam generating part, the temperature of the hot water in the boiling state and the transition reaction at the rear end of the carbon oxide transfer catalyst. It is achieved by providing a method for controlling the outlet temperature of a carbon monoxide transition reactor comprising a steam generator, characterized in that the temperature is controlled by controlling any one or more of the areas in which the subcase is in contact with the hot water portion.

The carbon monoxide transition reaction part is operated in a temperature range of 180 ~ 300 ℃ by heat exchange with the steam generator, so that the carbon monoxide transition reaction catalyst outlet temperature is adjusted to 200 ℃ or less,

The steam generator is characterized in that configured to operate in a temperature range of 145 ~ 180 ℃ by heat exchange with the carbon monoxide transition reaction unit.

The present invention has the advantage of simplifying the reactor structure by contacting the cooling medium on the outer boundary of the outer wall without installing a heat pipe inside the catalyst layer of the carbon monoxide transfer reactor,

In addition, there is an advantage of cooling the reactor with a simple structure without an external rotating device such as a high temperature water pump by allowing the hot water portion of the steam generating unit and the outer wall of the carbon monoxide transfer reaction unit to contact each other without installing a heat pipe inside the catalyst layer of the carbon monoxide transfer reactor.

In addition, unlike the existing patent to control the temperature distribution by adjusting the pitch of the cooling pipe inside the CO transformer catalyst layer, the present invention provides an advantage that the temperature distribution is controlled by adjusting the length of the carbon monoxide transfer reactor exposed to the vapor phase liquid phase and the gas phase portion,

In addition, the existing patent is filled with a different catalyst in the front end and the rear end of the carbon monoxide transition reactor, and the cooling tube is installed to control the temperature of the lower end of the carbon monoxide transition, but the present invention does not install a cooling tube to contact the refrigerant outside the carbon monoxide transition reactor carbon monoxide It is a useful invention having the advantage of controlling the temperature at the rear end of the transition reaction part, and is an invention that is expected to be greatly used in industry.

Hereinafter, the configuration and the operation of the embodiments of the present invention will be described in detail with reference to the accompanying drawings. In the following description of the present invention, a detailed description of known functions and configurations incorporated herein will be omitted when it may make the subject matter of the present invention rather unclear.

1 is an overall configuration diagram of a steam reforming system including the present invention, the reforming reactor 51 in the configuration of the steam reforming system according to the present invention as shown; Burner 52 and combustion space 53; Raw hydrocarbon desulfurizer 54; Raw material preheater 55; It is composed of a similar to the conventional system configuration, but features of the present invention is a steam generator (1) corresponding to the conventional steam generator; And directly recovering the heat of reaction generated by integrating the carbon monoxide transfer reaction unit 2 corresponding to the conventional carbon monoxide transfer reactor 2 by placing the carbon monoxide transition reaction unit 2 inside the steam generator 1. The representative difference is that the carbon monoxide transfer reactor including a steam generator integrated into the steam generator.

In other words, the outer surface of a portion of the carbon monoxide transition reaction unit 2 is in direct contact with the steam generator high temperature water storage unit 510 to cool the carbon monoxide transition reaction unit itself and discharge the treated reformed gas.

Hereinafter, the configuration of the present invention will be described in more detail.

2 is a front sectional view of an integrated carbon monoxide transfer reactor according to an embodiment of the present invention, integrating a carbon monoxide transfer reactor and a waste heat recovery type steam generator to increase hydrogen yield in a fossil fuel (natural gas, LPG, etc.) steam reforming process It can be seen that one form. To this end, the configuration of the carbon monoxide transfer reactor according to the present invention includes a steam generator (1) for generating steam by heat exchange between combustion exhaust gas waste heat and a supply water that is a raw material of steam; The carbon monoxide transition reaction unit (2), which is installed inside the steam generator and heat exchanges with the hot water stored in the steam generator at a lower temperature, to stably control the outlet temperature, is integrated. At this time, in order to control the carbon monoxide concentration of the outlet of the carbon monoxide transition unit 2 to 1% or less, the outlet temperature of the carbon monoxide transition unit is adjusted to about 180 to 220 ° C.

The steam generator 1 is provided with a steam generator case 11 in which hot water for steam generation is stored, and a heat exchanger 12 immersed in hot water stored in the steam generator case 11. It is immersed by water to exchange heat with water. The hot water storage zone refers to a space in which hot water heat-exchanged with the heat exchanger is stored in a boiling state.

The steam generator case 11 is provided with a horizontal separator 111 to be isolated from the water-storage space of the upper portion of the water vapor generating unit at the bottom and through a plurality of pipes of the heat exchanger, and the horizontal separator is a vertical separator 112 again. Are separated into two spaces.

In addition, a burner exhaust gas inlet 113 is formed at a lower portion of the one space portion divided by the vertical isolation plate 112, and a burner exhaust gas outlet 114 is formed at the lower portion of the other space portion.

In addition, the upper opening 115 is installed at the upper portion of the carbon monoxide transition reaction part 2 so as to be inserted into the transition reaction part case, and the protruding upper opening 115 is provided on the side of the upper opening 115. 116 is formed.

In addition, the supplementary water supply port 117 is formed at one side of the lower side of the horizontal isolation plate 111 so that a constant level is maintained by supplying the supplementary water even though the level of the hot water is lowered by the discharge of steam.

The heat exchanger 12 is a plurality of pipes having a different radius is installed in a coil shape having a separate circulation path, each tube passes through the horizontal isolation plate 111, one heat exchanger inlet does not contact with water The 121 is supplied with the exhaust gas through the burner exhaust gas inlet 113 formed at the lower part of the steam generator case 11, circulated through the internal path, and then discharged through the other heat exchanger outlet 122, and then the other burner exhaust gas outlet ( 114). The water is evaporated by heat exchange with the stored water while moving along the circulation path. What looks like a perforated plate in the figure shows the cross section of the individual coils, and the shape of the individual coils should be as long as the shape shown on the right, and only the radius of the configuration should be different. In addition, the shape of the coil is not limited to that shown in the rotation can also be configured to come down while rotating while moving up even when rising and falling directly when falling.

In addition, the steam generator 1 is an auxiliary electric heater 13 for auxiliary water heating in case the heat source supplied from the flue gas or the carbon monoxide transfer reaction unit 2 is not sufficient to generate steam, such as when the device is initially started. ) Is installed on the inner wall of the steam generator case (11).

On the other hand, the carbon monoxide transfer reaction unit 2 is inserted into the upper opening portion 115 protruding from the upper portion of the steam generating unit case 11, the transition reaction unit case having a transition reaction inlet 211 formed thereon ( 21); An inner lift pipe 22 installed inside the transition reaction part case 21 and having a transition reaction outlet 221 formed at an upper end thereof bent to protrude through the transition reaction part case 21; It consists of; carbon monoxide transfer reaction catalyst (23) filled in the space between the transition reaction part case 21 and the inner riser (22).

The water vapor and carbon monoxide introduced through the transition reaction inlet 211 by the above-described configuration are converted into carbon dioxide and hydrogen while passing through the carbon monoxide transfer reaction catalyst 23, and then flowed into the lower portion of the internal rising pipe 22 inside to rise. After it is discharged through the transition reaction outlet (221).

The transition reaction part case 21 is installed so that a portion of the section is lowered to a certain point of the heat exchanger 12 having a coil shape immersed in high temperature water so that the reaction heat generated during the transition reaction is located in the high temperature water and the heat exchanger 12. While exchanging heat with hot water, the temperature at the outlet side of the transition reaction catalyst 23 is lowered, thereby controlling the temperature of the transition reaction outlet 221 in a predetermined range.

At this time, the temperature control of the transition reaction outlet 221 controls the temperature of the gas introduced into the transition reaction inlet 211, or adjusts the pressure inside the steam generator case 11 to adjust the temperature of the hot water in a boiling state. The temperature can be controlled by adjusting the area in which the transition reaction part case 21 at the rear end of the carbon oxide transfer reaction catalyst 23 is in contact with the hot water portion. Here, since the hot water contacting the transition reaction part case is in a boiling state in the steam generation part, steam of saturated steam pressure equal to the set pressure of the steam generator is generated, and the heat transferred from the transition reaction part is the latent heat of evaporation of the hot water. Since the temperature of the hot water is kept constant. Usually, the steam generator of the atmospheric steam reforming process is operated at a pressure of 3 to 10 atm. The boiling point of water in this pressure range corresponds to 145 to 180 ° C.

As described above, since the steam generator 1 and the carbon monoxide transfer unit 2 are integrally formed, the carbon monoxide transfer unit 2 is operated in an exothermic reaction in a temperature range of 180 to 300 ° C. and the outlet temperature is 200 ° C. or lower. Will be maintained. Steam generator 1 is maintained in a boiling state in the temperature range of 145 ~ 180 ℃.

When operating under such a temperature condition, as shown in FIG. 3, the carbon monoxide transition reaction occurs rapidly at the inlet portion of the catalyst layer at 200 to 270 ° C., and the outlet CO concentration can be lowered to 1% or less by the reaction equilibrium by the rear end cooling. Without cooling, the outlet CO concentration is above 1% because the outlet temperature is above 250 ° C.

In addition, the temperature of the gas introduced into the transition reaction inlet 211 may be configured by forming a bypass path in the raw material preheater 55 of FIG.

In addition, the internal pressure of the steam generator case 11 is controlled by using the auxiliary electric heater 13 shown in FIGS. 2, 4, and 5 to control the hot water temperature, and the saturated steam pressure of the hot water in the boiling state is constant. Maintained in the range, the internal pressure can be adjusted.

3 is a longitudinal temperature distribution diagram of a carbon monoxide transition reaction unit according to the present invention, where a carbon monoxide transition reactor is configured in the form of a conventional adiabatic reactor and in the case of the present invention, a portion of the carbon monoxide transition reaction unit is a hot water storage zone of a steam generation unit; The temperature change of the carbon monoxide reaction catalyst with respect to the longitudinal direction of the reaction part when the rear end portion of the carbon monoxide transfer reaction part is cooled by direct contact with is shown. As shown, according to the configuration of the present invention, when the rear end of the carbon monoxide transfer part is cooled to about 50% of the rear end, it is possible to cool the catalyst bed outlet temperature to 200 ° C or less, and reduce the CO concentration of the outlet reforming gas to 1% or less. Can be.

Figure 4 is a front sectional view of an integrated carbon monoxide transfer reactor according to another embodiment of the present invention, the basic configuration is the same as the configuration of Figure 2, only the configuration of the carbon monoxide transfer unit 2, carbon monoxide transition as shown in some other The generator 2 is inserted into the upper opening portion 115 protruding from the upper portion of the steam generator case 11, the transition reaction portion case 21 and the transition reaction inlet 211 is formed on the upper portion and ;

A lower end pipe 22 'which is connected to the lower and outer portion of the transition reaction part case 21 and penetrates through the upper opening 115, and the end section in which the transition reaction outlet 221 is formed is bent;

It is composed of; carbon monoxide transfer reaction catalyst (23) filled in the transition reaction part case (21).

According to the above configuration, it is possible to control the heat exchange efficiency of the external rising pipe 22 'to a lower temperature. That is, by this structure, the amount of charge of the carbon monoxide transfer catalyst 23 can be increased, and the gas discharged from the carbon monoxide transfer reactor can be further heat exchanged with hot water adjacent to the external riser 22 '.

The water vapor and carbon monoxide introduced through the transition reaction inlet 211 by the above configuration are converted into carbon dioxide and hydrogen while passing through the carbon monoxide transfer reaction catalyst 23, and then flowed into the external riser 22 ′ and then transferred. It is discharged through the reaction outlet 221.

FIG. 5 is a sectional front view of an integrated carbon monoxide transfer reactor according to another embodiment of the present invention, and FIG. 6 is a cross-sectional view taken along line AA ′ of FIG. 5, and the basic configuration is the same as that of FIG. The shape of 12) is different from that of using a 'U' shaped heat exchanger, not a coil type as shown in FIG. The 'U' shaped heat exchanger is composed of straight tube heat exchange tubes consisting of bundles and inlet and outlet manifolds for connecting them, which is more advantageous in terms of fabrication convenience than a coil type heat exchanger for increasing steam generator capacity.

The present invention is not limited to the above-described specific preferred embodiments, and various modifications can be made by any person having ordinary skill in the art without departing from the gist of the present invention claimed in the claims. Of course, such changes will fall within the scope of the claims.

1 is an overall configuration diagram of a steam reforming system including the present invention,

2 is a front sectional view of an integrated carbon monoxide transfer reactor according to one embodiment of the present invention,

3 is a longitudinal temperature distribution diagram of the carbon monoxide transition reaction unit according to the present invention,

4 is a front sectional view of an integrated carbon monoxide transfer reactor according to another embodiment of the present invention,

5 is a front sectional view of an integrated carbon monoxide transfer reactor according to another embodiment of the present invention,

6 is a cross-sectional view taken along line AA ′ of FIG. 5;

7 is a schematic diagram of a steam reforming system according to a conventional embodiment.

<Description of the symbols for the main parts of the drawings>

(1): steam generating part (2): carbon monoxide transition reaction part

(11): steam generator case (12): heat exchanger

(13): auxiliary electric heater (21): transition reaction case

(22): Internal lift tube (22 '): External lift tube

(23): carbon monoxide transfer reaction catalyst (111): horizontal separator

(112): vertical separator (113): burner flue gas inlet

114: burner exhaust gas outlet 115: upper opening

116: water vapor outlet 117: supplemental water supply port

121: heat exchanger inlet 122: heat exchanger outlet

(211): transition reaction inlet (221): transition reaction inlet

Claims (11)

A steam generator case (11) for storing hot water so as to generate steam by heat exchange between the waste heat of combustion flue gas and the supply water serving as a raw material of steam; A heat exchanger 12 immersed in hot water stored in the steam generator case 11; A steam generator 1 composed of an auxiliary electric heater 13 installed on an inner wall of the steam generator case 11; The carbon monoxide transition reaction unit (2) is installed inside the steam generator to heat exchange with the hot water stored in the steam generator to a temperature lower than that, and the outlet temperature is stably adjusted. The steam generator case 11 includes a horizontal isolation plate 111 through which a plurality of pipes constituting a heat exchanger are isolated from the high temperature water stored therein and are isolated from the high temperature water; A vertical separator 112 for dividing the horizontal separator into two spaces; A burner exhaust gas inlet 113 formed at one lower space portion divided by the vertical isolation plate 112 and a burner exhaust gas outlet 114 formed at the lower portion of the other space; An upper opening 115 which protrudes and opens to a size into which the transition reaction part case of the carbon monoxide transfer reaction part 2 is inserted; A steam outlet 116 formed at one side of the upper opening 115; One side of the lower horizontal isolation plate 111, the carbon monoxide transition reactor comprising a steam generator, characterized in that comprises ;; supplemental water supply port (117) formed. The method according to claim 1, Temperature control of the transition reaction outlet 221 of the carbon monoxide transition reaction unit 2 controls the temperature of the gas introduced into the transition reaction inlet 211 and the pressure inside the steam generator case 11 to a boiling state. It includes a steam generator, characterized in that the temperature is controlled by controlling any one or more of the hot water temperature and the transition reaction part case 21 of the rear end portion of the carbon dioxide transfer reaction catalyst 23 in contact with the hot water portion Carbon monoxide transfer reactor. The method according to claim 1, The carbon monoxide transition reaction unit 2 is operated in a temperature range of 180 ~ 300 ℃ by heat exchange with the steam generator 1 so that the carbon monoxide transition reaction catalyst 23 outlet temperature is adjusted to 200 ℃ or less, The steam generator (1) is a carbon monoxide transition reactor comprising a steam generator, characterized in that configured to operate in a temperature range of 145 ~ 200 ℃ by heat exchange with the carbon monoxide transition reaction unit (2). delete delete The method according to claim 1, The heat exchanger 12 is a carbon monoxide transition reactor including a steam generator, characterized in that the plurality of pipes having a different radius is installed in a coil shape having a separate circulation path. The method according to claim 1, The heat exchanger 12 is a carbon monoxide transfer reactor comprising a steam generator, characterized in that the plurality of pipes having a different radius is installed in a 'U' shape having a separate circulation path. The method according to claim 1, The carbon monoxide transfer reaction unit 2 is inserted into the upper opening portion 115 protrudingly formed on the upper portion of the steam generating unit case 11, and the transition reaction unit case having the transition reaction inlet 211 formed thereon. 21; An internal elevating pipe 22 installed inside the transition reaction part case 21 and having a transition reaction outlet 221 formed at an upper end thereof bent to protrude through the transition reaction part case 21; And a carbon monoxide transfer reaction catalyst (23) filled in the space between the transition reaction part case (21) and the inner riser (22). The method according to claim 1, The carbon monoxide transition reaction unit 2 is inserted into the upper opening portion 115 protruding from the upper portion of the steam generating unit case 11, the transition reaction unit case formed with a transition reaction inlet 211 (top) 21); A lower end pipe 22 'which is connected to the lower and outer portion of the transition reaction part case 21 and penetrates through the upper opening 115, and the end section in which the transition reaction outlet 221 is formed is bent; Carbon monoxide transfer reaction catalyst (23) filled in the transfer reaction case (21); Carbon monoxide transfer reactor comprising a steam generating unit characterized in that consisting of. Claims 1, 2, 3, 6, 7, 8, 9 having a carbon monoxide transition reactor including a steam generating unit according to any one of the heat generation by contacting the heat generated in the carbon monoxide transfer unit with the hot water storage zone of the steam generating unit The heat required in the steam generator is recovered from the carbon monoxide transition reactor, The temperature control of the transition reaction outlet 221 of the carbon monoxide transition reaction part controls the temperature of the gas introduced into the transition reaction inlet 211, the pressure of the steam generator case 11, and the temperature of the hot water in the boiling state. Carbon monoxide transfer reactor comprising a steam generator, characterized in that the temperature is controlled by controlling any one or more of the area in which the transition reaction part case 21 at the rear end of the carbon oxide transfer catalyst 23 is in contact with the hot water portion. How to control the outlet temperature of The method according to claim 10, The carbon monoxide transfer reaction part is operated in a temperature range of 180 ~ 300 ℃ by heat exchange with the steam generator, so that the carbon monoxide transfer catalyst 23, the outlet temperature is adjusted to 200 ℃ or less, The steam generator is an outlet temperature control method of a carbon monoxide transition reactor comprising a steam generator, characterized in that configured to operate in a temperature range of 145 ~ 200 ℃ by heat exchange with the carbon monoxide transition reactor.

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