KR101096989B1 - High strength and elongation adhesives for ceramic tiles - Google Patents
High strength and elongation adhesives for ceramic tiles Download PDFInfo
- Publication number
- KR101096989B1 KR101096989B1 KR1020090106776A KR20090106776A KR101096989B1 KR 101096989 B1 KR101096989 B1 KR 101096989B1 KR 1020090106776 A KR1020090106776 A KR 1020090106776A KR 20090106776 A KR20090106776 A KR 20090106776A KR 101096989 B1 KR101096989 B1 KR 101096989B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- adhesive
- tile
- resin
- dispersant
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/06—Homopolymers or copolymers of esters of polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
Abstract
본 발명은 2액형 에폭시 수지계 타일 접착제로서 조립식 건물의 재료인 샌드위치 판넬에 타일 시공시 적용하여, 접착강도와 연신율이 뛰어난 접착제로서 기존의 일반적인 타일접착제인 시멘트계 타일접착제, 아크릴에멀션계 타일접착제, 석재용 에폭시접착제 등으로 타일 시공이 불가능한 샌드위치판넬에 타일시공을 가능하게 할뿐만 아니라 타일시공이후 발생할 수 있는 샌드위치판넬의 변형이나 충격 등에도 우수한 내구성을 발휘할 수 있는 뛰어난 타일용 접착제에 대한 것이다.The present invention is applied as a two-component epoxy resin tile adhesive to a sandwich panel, which is a material of a prefabricated building, and has excellent adhesive strength and elongation, and is an existing general tile adhesive, cement-based tile adhesive, acrylic emulsion tile adhesive, and stone. The present invention relates to an excellent tile adhesive that can not only enable tile construction on a sandwich panel that cannot be tiled with epoxy adhesive, but also exhibit excellent durability against deformation or impact of sandwich panels that can occur after tile construction.
본 발명의 접착제는 에폭시 수지에 액상첨가제와 필러가 첨가된 주제부와 에폭시 수지 경화제에 액상첨가제와 필러를 혼입한 경화제부 2가지로 구성되며, 주제부 1 : 경화제부 1의 중량비로 혼합하여 사용한다. 주제부는 40～45중량％의 에폭시 수지, 0.3～0.5중량％의 분산제, 0.3～0.5중량％의 커플링제, 0.5～1.0중량％의 칙소성부여제, 0.3～0.5중량％의 침강방지제, 50～55중량％의 무기충전필러, 2～3중량％의 반응성희석제의 조성을 가지며, 경화제부는 30～34중량％의 탄성 경화수지, 10～14중량％의 폴리아마이드 경화수지, 0.3～0.5중량％의 분산제, 2～4중량％의 경화촉진제, 0.3～0.8중량％ 부착증진제, 0.5～1.0중량％의 칙소성부여제, 50～55중량％의 무기충전필러를 포함하는 조성을 가진다.The adhesive of the present invention is composed of two parts of the epoxy resin and a liquid additive and a filler added, and an epoxy resin curing agent mixed with a liquid additive and a filler. do. The main part consists of 40 to 45 weight percent epoxy resin, 0.3 to 0.5 weight percent dispersant, 0.3 to 0.5 weight percent coupling agent, 0.5 to 1.0 weight percent thixotropic agent, 0.3 to 0.5 weight percent sedimentation inhibitor, 50 to 55 wt% inorganic filler, 2 to 3 wt% reactive diluent, 30 to 34 wt% elastic curing resin, 10 to 14 wt% polyamide cured resin, 0.3 to 0.5 wt% dispersant , 2-4% by weight curing accelerator, 0.3-0.8% by weight adhesion promoter, 0.5-1.0% by weight thixotropic agent, 50-55% by weight inorganic filler filler.
샌드위치판넬, 타일접착제, 에폭시 Sandwich Panel, Tile Adhesive, Epoxy
Description
본 발명은 기존의 타일접착제와는 달리 샌드위치판넬 표면에 완벽한 접착성능을 발휘하고, 타일시공 이후에 발생할 수 있는 울림이나 변형에도 우수한 내구성을 발휘할 수 있는 타일용 접착제에 대한 것이다.The present invention, unlike the conventional tile adhesive, exhibits a perfect adhesive performance on the sandwich panel surface, and relates to a tile adhesive that can exhibit excellent durability against the ringing or deformation that may occur after the tile construction.
건축물 소재의 종류가 다양해지고, 빠르게 변화해가고 있는 최근에 조립식건물의 재료로 사용하는 샌드위치판넬의 적용 빈도가 날로 증가하고 있다. 조립식 건물의 장점은 일반 시멘트골조 건물에 비해 시공기간이 짧고, 보수, 구조변경 등이 용이하고, 시공비용도 절감됨으로 공장, 상가, 창고, 주차타워, 전시장, 일반주택 등에 널리 사용되고 있다. 또한 샌드위치판넬의 수요가 증가함에 따라 보수, 디자인변경 등의 이유로 샌드위치판넬 건물의 내외부에 페인트, 벽지, 타일부착 등 다양한 마감처리가 시도되고 있다.The variety of building materials has been diversified, and the rapidly changing frequency of sandwich panels used as prefabricated building materials is increasing day by day. The advantages of prefabricated buildings are that they are widely used in factories, malls, warehouses, parking towers, exhibition halls, and general houses, as they have shorter construction periods, easier maintenance and structural changes, and reduced construction costs compared to general cement framed buildings. In addition, as the demand for sandwich panels increases, various finishing treatments such as paint, wallpaper, and tile attachment to inside and outside of sandwich panel buildings have been attempted for reasons of repair and design change.
샌드위치판넬의 표면은 일반강판에 내식성, 내후성, 내습성, 내열성 등의 성능을 발휘할 수 있는 코팅처리가 되어있어 흡수성이 떨어짐으로 내외장 마감재료인 타일의 시공이 불가능 하였다. 또한 샌드위치판넬의 표면소재인 강판은 외부충격이 나 계절변화에 따라 울림이나 변형이 나타나기 때문에 양생이 끝나면 딱딱한 상태로 고화되는 기존의 시멘트계, 아크릴에멀션계 타일 접착제, 석재용 에폭시 접착제로 타일 시공 하였을때 많은 시공불량 사례가 발생하였다.The surface of the sandwich panel has a coating treatment that can show the performance of corrosion resistance, weather resistance, moisture resistance, heat resistance, etc. on the general steel sheet, so it is impossible to install tiles, an interior and exterior finishing material, due to its poor absorption. In addition, when the steel plate, which is the surface material of the sandwich panel, rings or deforms due to external impact or seasonal changes, when it is tiled with existing cement-based, acrylic emulsion-based tile adhesives and stone epoxy adhesives, which solidify in a hard state after curing. Many poor construction cases have occurred.
일반적인 타일용 접착제는 흡수성이 있는 표면에 접착제가 흡수되어 접착성능을 발휘는 방식으로 시멘트골조, 석고보드 등 흡수성이 있는 표면에는 타일시공시 양호한 성능을 나타내지만 비흡수면에는 성능이 저하되는 것이 사실이다. 그러므로 흡수성이 없는 소재인 샌드위치판넬에 타일 시공시 타일 접착제보다는 상대적으로 접착력이 우수한 석재용 에폭시 접착제를 사용하여 타일을 시공하고 있다. 그러나, 석재용 에폭시 접착제로 샌드위치판넬에 타일 시공시 안정적인 접착력이 발휘되지 않을 뿐만 아니라, 딱딱하게 경화되기 때문에 시공후 발생하는 샌드위치판넬에 울림, 변형에 대하여 근본적인 대응능력이 없어 현재의 기존 제품과 기술로는 샌드위치판넬에 타일시공은 불가능한 실정이다. 따라서 샌드위치판넬용 타일접착제에 대한 연구가 절실하다고 할 수 있다.In general, the tile adhesive shows good performance when tile is applied to absorbent surfaces such as cement frame and gypsum board, and the adhesive is absorbed on the absorbent surface, but the performance decreases on the non-absorbed surface. to be. Therefore, when constructing a tile on a sandwich panel, which is a non-absorbent material, the tile is constructed by using an epoxy adhesive for stone, which is relatively superior to tile adhesive. However, with the epoxy adhesive for stone, not only does not show stable adhesive strength when constructing a tile on the sandwich panel, but also hardens and hardens the sandwich panel that occurs after the construction. As for the tile construction in the sandwich panel is impossible. Therefore, it can be said that research on tile adhesives for sandwich panels is urgently needed.
건축물의 소재가 다양해짐에 따라 타일접착제의 대해서 다양한 요구가 발생하고 있다. 타일시공용 타일접착제는 내외부에 다양하게 적용되어 안정적인 접착력을 발휘하여 타일시공 후 발생할 수 있는 시공불량 사고를 방지할 수 있어야 한다. 따라서, 본 발명에서는 샌드위치판넬용 타일접착제에 에폭시수지를 적용하여, 에폭시수지 자체의 특징인 빠른 경화 및 높은 접착강도가 발휘될 뿐만 아니라 타일시공 후 발생 가능한 샌드위치판넬의 울림이나 변형에도 안정적인 물성을 발휘할수 있는 연신율이 뛰어난 타일접착제를 개발하고자 하는데 그 목적이 있다.As the construction materials are diversified, various demands are made on tile adhesives. The tile adhesive for tile construction should be applied in various ways inside and outside to show stable adhesive force and to prevent construction defects that can occur after tile construction. Therefore, in the present invention, by applying an epoxy resin to the tile adhesive for sandwich panels, not only exhibits rapid curing and high adhesive strength, which are the characteristics of the epoxy resin itself, but also exhibits stable physical properties against the ringing or deformation of the sandwich panel after tile construction. The purpose is to develop a tile adhesive with excellent elongation.
본 발명은 2액형 에폭시 수지계 타일 접착제로서 조립식 건물의 재료인 샌드위치 판넬에 타일 시공시 적용하여, 접착강도와 연신율이 뛰어난 접착제로서 기존의 일반적인 타일접착제인 시멘트계 타일접착제, 아크릴에멀션계 타일접착제, 석재용 에폭시접착제 등으로 타일 시공이 불가능한 샌드위치판넬에 타일시공을 가능하게 할뿐만 아니라 타일시공이후 발생할 수 있는 샌드위치판넬의 변형이나 충격 등에도 우수한 내구성을 발휘할 수 있는 것이 특징인 타일용 접착제이다.The present invention is applied as a two-component epoxy resin tile adhesive to a sandwich panel, which is a material of a prefabricated building, and has excellent adhesive strength and elongation, and is an existing general tile adhesive, cement-based tile adhesive, acrylic emulsion tile adhesive, and stone. It is a tile adhesive that is characterized by not only enabling tile construction in sandwich panels that cannot be tiled with epoxy adhesives, but also exhibiting excellent durability against deformation or impact of sandwich panels that may occur after tile construction.
본 발명품은 기존 타일 접착제로는 시공이 불가능한 샌드위치판넬에 우수한 접착강도를 나타낼뿐만 아니라 타일시공이후 발생할 수 있는 샌드위치판넬의 울림, 변형에도 대응할 수 있는 연실율이 우수한 제품으로서 샌드위치판넬에 안전한 타일 시공이 가능하도록 설계되었다.The present invention not only shows excellent adhesive strength on sandwich panels that are not applicable with existing tile adhesives, but also has excellent firing rate to cope with ringing and deformation of sandwich panels that can occur after tile construction. It is designed to be possible.
접착강도와 연신율이 뛰어난 샌드위치판넬용 타일접착제를 제조하기 위하여 본 발명은 에폭시수지에 각종 첨가제 및 무기충전필러를 첨가한 주제부와 탄성 경화수지와 폴리아마이드 경화수지에 각종 첨가제 및 무기충전필러를 혼합한 경화제부로 나뉘며, 주제부와 경화제부를 주제부 1 : 경화제부 1의 중량비로 혼합하여 적용하는 특징을 가지며, 주제부와 경화제부를 자세히 설명하면 다음과 같다.In order to manufacture the tile adhesive for sandwich panel with excellent adhesive strength and elongation, the present invention is a mixture of various additives and inorganic fillers in the main portion of the epoxy resin added various additives and inorganic filler filler, elastic curable resin and polyamide cured resin It is divided into one curing agent part, and the main part and the curing agent part has a characteristic of applying by mixing in a weight ratio of the main part 1: the curing agent part 1, the main part and the curing agent part will be described in detail as follows.
(1) 주제부(1) subject
40～45중량％의 에폭시 수지, 0.3～0.5중량％의 분산제, 0.3～0.5중량％의 커플링제, 0.5～1.0중량％의 칙소부여제, 0.3～0.5중량％의 침강방지제, 50～55중량％의 무기충전필러, 2～3중량％의 반응성희석제40 to 45 weight percent epoxy resin, 0.3 to 0.5 weight percent dispersant, 0.3 to 0.5 weight percent coupling agent, 0.5 to 1.0 weight percent thixotropic agent, 0.3 to 0.5 weight percent sedimentation inhibitor, 50 to 55 weight percent Inorganic filler, reactive diluent of 2-3% by weight
(2) 경화제부(2) hardener
30～34중량％의 탄성경화수지, 10～14중량％의 폴리아마이드경화수지, 0.3～0.5중량％의 분산제, 2～4중량％의 경화촉진제, 0.3～0.8중량％ 부착증진제, 0.5～1.0중량％의 칙소부여제, 50～55중량％의 무기충전필러30 to 34% by weight elastic curable resin, 10 to 14% by weight polyamide cured resin, 0.3 to 0.5% by weight dispersant, 2 to 4% by weight curing accelerator, 0.3 to 0.8% by weight adhesion promoter, 0.5 to 1.0 weight % Thixotropic agent, 50-55 wt% inorganic filler
에폭시 수지는 Bis-Phenol A형 에폭시 수지로 당량 160～280g/eq의 무용제형 에폭시 수지를 사용한다.Epoxy resin is Bis-Phenol type A epoxy resin, and solvent-free epoxy resin of equivalent weight 160 ~ 280g / eq is used.
분산제는 무기충전필러들을 수지에 미립화 시키는 기능을 하는 것으로 수지와의 상용성이 좋은 불포화 지방산 폴리아민계 분산제와 금속 소지와 부착성을 향상시키는 폴리카르복실릭 산 폴리머계 제품을 반드시 1:1의 비율로 혼합하여 사용한다.The dispersant functions to atomize the inorganic fillers into the resin, and the ratio of the unsaturated fatty acid polyamine-based dispersant having good compatibility with the resin and the polycarboxylic acid polymer-based product which improves adhesion to the metal body must be 1: 1. Mix with and use.
커플링제는 조성물이 무기질 피착제에 대한 기계적 강도를 상승시키고 에폭시 수지의 경화를 촉진하는 첨가제로서 수지와의 상용성을 고려하여 3-Glycidoxypropyltrimethoxysilane계 제품을 사용한다.The coupling agent is a 3-Glycidoxypropyltrimethoxysilane-based product in consideration of compatibility with the resin as an additive to increase the mechanical strength to the inorganic adherend and promote the curing of the epoxy resin.
칙소부여제는 조성물의 작업성을 개선하는 첨가제로서 조성물의 점도와 Thixotropy를 증가시키서 타일접착 시공시 Sagging을 방지하는 역할을 하는 이산화규소계 첨가제를 사용한다. 첨가량에 따라 접착제의 레벨링성, 작업성에 영향이 크 므로 사용량에 주의를 하여야 한다.The thixotropic agent uses a silicon dioxide-based additive that serves to prevent sagging during tile adhesion by increasing the viscosity and thixotropy of the composition as an additive to improve the workability of the composition. The amount of additives affects the leveling and workability of the adhesive.
침강방지제는 수지에 분산된 무기충전필러들의 재응집을 방지하여 조성물의 저장안정성을 유지하는 역할을 한다. 변성우레아계 중극성 침강방지제인 BYK사의 제품을 적용한다.The antisettling agent serves to prevent reaggregation of the inorganic fillers dispersed in the resin to maintain the storage stability of the composition. BYK Co., Ltd., a modified urea-based bipolar sedimentation inhibitor, is applied.
무기충전필러는 탄산칼슘을 사용하는데 탄산칼슘의 종류는 평균입도 0.8～3.0㎛인 경질탄산칼슘, 평균입도 0.1～1.0㎛인 중질탄산칼슘, 평균입도 0.03～0.08㎛인 교질탄산칼슘으로 이루어지는데, 시공작업성 및 저장안정성 확보를 위해 경질탄산칼슘:중질탄산칼슘:교질탄산칼슘의 비율이 4.5 : 3 : 2.5의 비율이 가장 우수하였다. 비율이 달라지면 Sagging이 발생하여 작업성이 떨어지거나, 주제부:경화제부 혼합작업성이 떨어지므로 반드시 조성비를 지켜야 한다. 중질탄산칼슘과 교질탄산칼슘은 입자표면이 코팅된 합성탄산칼슘을 사용해야 한다.The inorganic filler uses calcium carbonate, which is composed of hard calcium carbonate with an average particle size of 0.8 to 3.0 μm, heavy calcium carbonate with an average particle size of 0.1 to 1.0 μm, and calcium carbonate with an average particle size of 0.03 to 0.08 μm. In order to secure construction workability and storage stability, the ratio of hard calcium carbonate: heavy calcium carbonate: colloidal calcium carbonate was 4.5: 3: 2.5. If the ratio is different, sagging occurs and the workability is reduced or the main part: hardening part mixing workability is low, so the composition ratio must be observed. Heavy calcium carbonate and calcium carbonate should be made of synthetic calcium carbonate coated with a particle surface.
희석용제로는 에폭시 수지와 상용성이 높은 알콜계의 반응성 희석제 중 벤질알콜을 적용하였다. 희석용제 적용시 저비점 희석용제를 사용하면 비점이 낮아 휘발성이 크기에 시공 시 냄새가 많이 나고, 시간이 지남에 따라 작업성이 크게 달라져 하자 발생의 가능성 있다.As the dilution solvent, benzyl alcohol was applied in an alcohol-based reactive diluent having high compatibility with an epoxy resin. When the dilution solvent is applied, a low boiling point dilution solvent has a low boiling point and thus has a high volatility, resulting in a lot of odors in construction, and a workability is greatly changed over time.
경화수지로는 경화 후 높은 접착강도와 연신율을 동시에 발휘할 수 있도록 탄성경화수지와 폴리아마이드 경화수지의 비율을 7 : 3 ～ 7.5 : 2.5 의 비율로 반드시 혼합하여 적용해야 한다. 접착강도와 연신율은 반비례하기 때문에 상기의 비율에 벗어나게 혼합하여 사용하면 연신율이 너무 높아져 접착강도가 떨어질 수 있고, 연신율이 떨어지면 브리틀해져서 접착제가 깨지기 쉬우므로 타일시공시 문제가 생길 수 있다.As the cured resin, the ratio of elastic curable resin and polyamide cured resin must be mixed and applied in a ratio of 7: 3 to 7.5: 2.5 to simultaneously exhibit high adhesive strength and elongation after curing. Since the adhesive strength and the elongation are inversely proportioned, when the mixture is used out of the above ratio, the elongation may be too high and the adhesive strength may drop, and the elongation may be brittle and the adhesive may be easily broken, thereby causing problems in tile construction.
분산제, 침강방지제, 칙소부여제는 주제부에 적용된 분산제, 침강방지제, 칙소부여제와 동일한 제품을 경화제부에도 사용한다.Dispersants, antisettling agents and thixotropic agents use the same products for hardeners as dispersants, antisettling agents and thixotropic agents applied to the main body.
경화촉진제는 주제부:경화제부를 혼합한 조성물의 경화속도를 조정하는 역할을 하며 3급아민류의 경화촉진제를 온도변화와 계절에 맞게 2～5중량％로 적용하여야 한다.The curing accelerator plays a role in adjusting the curing rate of the composition mixed with the main part and the curing agent part. The curing accelerator of tertiary amines should be applied at 2 to 5% by weight according to the temperature change and the season.
부착증진제는 금속 소재 및 비철금속 소재와의 부착력을 향상 시키는 역할을 하고 산성그룹을 가진 공중합체 첨가제 제품을 사용한다.Adhesion enhancers improve the adhesion to metallic and non-ferrous metals and use copolymer additives with acidic groups.
경화제부의 무기충전필러는 주제부와 동일한 경질탄산칼슘, 중질탄산칼슘, 교질탄산칼슘을 사용하는데 주제부와 수지의 점도 및 유동성이 다르므로 시공작업성 및 저장안정성 확보를 위해 경질탄산칼슘:중질탄산칼슘:교질탄산칼슘의 비율이 3.5 : 3 : 3.5의 비율로 반드시 조성비를 지켜야 한다.The inorganic filler of the hardener part uses the same hard calcium carbonate, heavy calcium carbonate, and calcium carbonate as the main part, but since the viscosity and fluidity of the main part and the resin are different, the hard calcium carbonate: heavy carbonate for securing workability and storage stability The ratio of calcium to colloidal calcium carbonate is 3.5: 3: 3.5.
이하 실시 예를 비교예와 실험을 통하여 본 발명의 구성 및 발명 효과를 보다 상세하게 설명하고자 한다. 본 실시예는 본 발명을 예시하기 위한 것으로 본 발명의 내용이 이에 한정되는 것은 아니다.Hereinafter, the configuration and the effects of the present invention will be described in more detail with reference to comparative examples and experiments. This embodiment is for illustrating the present invention, but the content of the present invention is not limited thereto.
비교예1은 가장 일반적인 아크릴에멀션계 제품인 S사의 타일접착제, 비교예2는 재분산형 수지가 혼합된 S사의 시멘트계 타일접착제, 비교예3은 S사의 석재용 에폭시 접착제로 하고, 실시예는 본 발명의 범위 내에서 주제는 에폭시 수지 44중량％, 분산제 0.3중량％, 커플링제 0.4중량％, 칙소부여제 0.5중량％, 침강방지제 0.3중량％, 반응성희석용제 2.0중량％, 무기충전필러 53중량％, 경화제는 탄성경화수지 32중량％, 폴리아마이드경화수지 12중량％, 분산제 0.3중량％, 경화촉진제 3.0중량％, 칙소부여제 0.5중량％, 부착증강제 0.5중량％ 무기충전필러 51중량％의 조성으로 정한 후 시험을 실시하였다.Comparative Example 1 is a tile adhesive of the company S of the most common acrylic emulsion-based products, Comparative Example 2 is a cement-based tile adhesive of the company S mixed with a redispersible resin, Comparative Example 3 is an epoxy adhesive for stone of the company S, Example is Within the range, the main material is 44% by weight of epoxy resin, 0.3% by weight of dispersant, 0.4% by weight of coupling agent, 0.5% by weight of thixotropic agent, 0.3% by weight of antisettling agent, 2.0% by weight of reactive diluent solvent, 53% by weight of inorganic filler, and curing agent. After determining the composition of 32% by weight of the elastomeric resin, 12% by weight of polyamide cured resin, 0.3% by weight of dispersant, 3.0% by weight of curing accelerator, 0.5% by weight of thixotropic agent, 0.5% by weight of adhesion enhancer, 51% by weight of inorganic filler The test was conducted.
본 발명의 효과를 확인하기 위하여 상기와 같이 제조된 샌드위치판넬용 타일접착제의 특성을 하기의 측정방법에 따라 측정하여 그 결과를 표에 나타내었다.In order to confirm the effect of the present invention, the properties of the tile adhesive for sandwich panels prepared as described above were measured according to the following measuring method and the results are shown in the table.
[측정방법][How to measure]
측정방법은 한국 산업 규격에서 KS L 1592, KS L 1593의 부분을 기준으로 인용하였으며, 한국 산업 규격에 측정 방법이 나와 있지 않는 시험방법은 통상의 이해할 수 있는 방법으로 실시하였다.The measurement method was cited based on the parts of KS L 1592 and KS L 1593 in the Korean Industrial Standards, and the test method whose measurement method is not listed in the Korean Industrial Standards was carried out by a general understandable method.
시험의 일반 조건은 다음과 같다.General conditions of the test are as follows.
- 시료 및 시험체의 제작 및 시험조건은 특별히 지정하지 않는 한 온도 20±2℃, 습도 60± 5％를 따른다.-Unless otherwise specified, the preparation and test conditions of specimens and test specimens shall be followed by temperature 20 ± 2 ℃ and humidity 60 ± 5%.
- 시험에 사용하는 재료는 시험조건에 제작 전 12시간 동안 방치해 두어야 한다.-The materials used for the test should be left under test conditions for 12 hours before manufacture.
- 주제와 경화제는 시험 전 균일한 상태로 교반해서 사용한다.-The main agent and the curing agent should be stirred in a uniform state before testing.
시험에 사용하는 재료 및 용구는 다음과 같다.Materials and tools used for the test are as follows.
- 시험에 사용하는 재료 및 용구는 아래 표1에 따른다.-Materials and tools used for the test are to be in accordance with Table 1 below.
[ 표 1 ]TABLE 1
- 시험체의 제작에 사용하는 철편의 접착면은 40×40mm로 한다.-The adhesive surface of the iron strip used for the manufacture of the test specimen shall be 40 × 40mm.
비교예와 실시예의 혼합은 다음과 같은 방법으로 실시한다.Mixing of a comparative example and an Example is performed by the following method.
- 비교예1은 1액형 제품이므로 혼합없이 사용한다.-Comparative Example 1 is a one-component product and should be used without mixing.
- 비교예2는 제품의 설명에 따라 필요량의 물을 첨가한 후 KS L 1592 7.3.4 모르타르 혼합 반죽 부분에 따라 혼합한다.In Comparative Example 2, the required amount of water was added according to the description of the product, followed by mixing according to KS L 1592 7.3.4 Mortar mixing dough portion.
- 비교예3, 실시예는 비율에 맞도록 주제와 경화제를 1:1의 혼합비로 계량후 교반기를 사용하여 충분히 혼합한다.-Comparative Example 3 and Example, the main body and the curing agent in a mixing ratio of 1: 1 to measure the ratio and then thoroughly mixed using a stirrer.
1) 접착강도1) Adhesive strength
접착강도 시험방법은 다음과 같다.Adhesive strength test method is as follows.
(1) 시험용 재료(1) Test materials
① 바탕재① Batangjae
바탕재는 샌드위치판넬로 하고 크기 70×70mm로 한다.The base material is sandwich panel and the size is 70 × 70mm.
표면은 먼지, 그 밖의 이물질이 부착되지 않도록 청소한다.Clean the surface to prevent dust and other foreign matter from adhering to it.
② 도자기질 타일② porcelain tiles
도자기질 타일은 미리 40×40mm의 크기로 절단한 것을 사용한다.Porcelain tiles are cut to 40 × 40 mm in advance.
(2) 시험체의 제작(2) Preparation of test body
① 접착제의 도포① Application of adhesive
바탕재에 접착제의 도포는 KS L 1593의 철재 도포용 보조틀에 평활면을 위로 하여 바탕판 5매를 틈이 없이 삽입 고정하고, 공시 접착제의 적당량을 취하고 표준 빗으로 도포한다. 접착제의 도포 조작을 할 때에는 바탕재에 KS A 1527에 규정하는 테이프를 나비7mm 덮이도록 부착하고 적당량의 접착제를 올려놓고, 주걱 등을 사용하여 두께 7mm로 도포한 후, 표준 빗을 각도 약 60°로 세워서 양손으로 단번에 자기 앞으로 당겨 접착제를 5매의 바탕재로 균일하게 도포한다. 테이프는 접착제 도포 후 즉시 서서히 벗겨낸다.To apply the adhesive to the base material, insert 5 pieces of base plate without gaps and fix it with a smooth surface on the steel frame of application of KS L 1593 without gaps, take the appropriate amount of adhesive and apply it with a standard comb. When applying the adhesive, attach the tape specified in KS A 1527 to the base material so that it covers the butterfly 7mm, put the appropriate amount of adhesive on it, apply a thickness of 7mm with a spatula, etc., and then use the standard comb at an angle of about 60 °. Stand up and pull in front of you with both hands at once and apply the adhesive evenly with 5 sheets of base material. The tape is peeled off slowly after applying the adhesive.
② 타일부착② Tile
접착제 도포 후 원칙적으로 5분 후에 미리 40×40mm의 크기로 절단한 도자기질 타일을 접착제가 도포된 바탕재의 중앙에 가만히 올려놓고 다시 그 위에 무게 1kg의 추를 약 30초간 올려놓은 후 추를 제가하여 7일간 양생한다.In principle, after 5 minutes, apply the ceramic tile cut to 40 × 40mm size in the center of the base material on which the adhesive is applied, and then put the weight of 1kg on it for about 30 seconds and then remove the weight. Heal for 7 days.
③ 철편의 장치③ device of iron piece
양생 4일에서 6일 사이에 KS L 1593에서 규정하는 철편을 표준 상태 속에서 에폭시 수지계 접착제 등으로 타일에 접착한다.(시험체를 작성할 때 타일의 시유 면을 샌드페이퍼 등으로 거칠게 하여 두면 좋다.)Between 4 and 6 days of curing, the iron piece specified in KS L 1593 is adhered to the tile with epoxy resin adhesive or the like under the standard condition.
(3) 접착 강도(3) adhesive strength
① 시험기① testing machine
시험기는 파괴하중이 시험기 용량이 15～85％에 들 수 있는 인장 시험기로서, 인장속도를 3mm/min 조절할 수 있는 것으로 한다.The tester is a tensile tester whose breakdown load is 15 to 85% of the tester capacity. The tester shall control the tensile speed by 3 mm / min.
② 접착강도② adhesive strength
접착강도는 시험체를 양생한 후 지그를 사용하여 시험기에 장치하고, 인장속도 3mm/min로 인장시험을 하고 끊어질 때까지의 최대하중을 측정하고 끊어진 상태를 기록한다. 또한 인장시험은 양생종료 후 즉시 한다.After curing the test body, the adhesive strength is set in the tester using a jig, the tensile test is performed at a tensile speed of 3mm / min, and the maximum load until breaking is recorded and the broken state is recorded. Tensile tests are also done immediately after completion of curing.
③ 접착강도를 구하는 방법③ How to find the adhesive strength
접착강도는 다음 식에 따라 구한다.Adhesion strength is calculated by the following equation.
접착강도는 5시험체의 평균치로 표시한다.Adhesion strength is expressed by the average value of 5 specimens.
2) 연신율 측정2) elongation measurement
연신율은 인장강도 시험시 재료가 늘어나는 비율을 측정한다.Elongation is a measure of the rate at which the material stretches during tensile strength testing.
KS M3015에서 규정한 인장강도 시험편을 제작하여 측정하며, 길이 변화의 측정은 KS B5203에 규정한 버니어 캘리퍼스로 측정한다.Tensile strength test specimens specified in KS M3015 are prepared and measured, and the length change is measured by vernier calipers specified in KS B5203.
시험편을 인장강도 시험기에서 하중을 가하여 거의 중앙 부분에서 절단되거나 파괴가 일어날때까지의 길이변화를 측정한다.Load the specimen in a tensile strength tester and measure the change in length until it is cut or fractured almost at the center.
연신율은 다음 식에 따라 계산한다.Elongation is calculated by the following equation.
[ 표 2 ] 비교예, 실시예 제품 시험 결과Table 2 Comparative Example, Example Product Test Results
상기 결과에 나타난 바와 같이 실시예가 비교예 1, 비교예 2, 비교예 3과 비교하여 접착강도, 파단유형, 연신율 관련 시험항목에서 월등한 성능으로 측정되었다.As shown in the results, compared with Comparative Example 1, Comparative Example 2, and Comparative Example 3, the Example was measured with superior performance in the test items related to adhesive strength, breaking type, and elongation.
또한 비교예3의 석재용 에폭시 제품의 경우에는 가사시간과 부착가능시간의 현저한 차이를 나타내었고, 비교예1, 비교예2에 비해서도 우수한 성능을 나타내었다.In addition, in the case of the stone epoxy product of Comparative Example 3 showed a significant difference between the pot life and the adhesion time, and showed excellent performance compared to Comparative Examples 1 and 2.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020090106776A KR101096989B1 (en) | 2009-11-06 | 2009-11-06 | High strength and elongation adhesives for ceramic tiles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020090106776A KR101096989B1 (en) | 2009-11-06 | 2009-11-06 | High strength and elongation adhesives for ceramic tiles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20110049982A KR20110049982A (en) | 2011-05-13 |
| KR101096989B1 true KR101096989B1 (en) | 2011-12-20 |
Family
ID=44360857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020090106776A KR101096989B1 (en) | 2009-11-06 | 2009-11-06 | High strength and elongation adhesives for ceramic tiles |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR101096989B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101731887B1 (en) | 2017-02-21 | 2017-05-02 | 임환명 | Tile adhesive and grout composition and tile constructing method therewith |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101497942B1 (en) * | 2014-10-08 | 2015-03-12 | 주식회사 유니온 | Mortar composition for binding the tile |
| KR102094921B1 (en) * | 2018-06-22 | 2020-03-30 | 주식회사 유니테크 | Low specific gravity adhesive composition for automobility |
| KR102256581B1 (en) * | 2019-08-09 | 2021-05-26 | 주식회사 케이씨씨 | Two-component type epoxy adhesive composition |
| KR102529515B1 (en) * | 2023-02-06 | 2023-05-08 | 동양에폭시 주식회사 | Method and material for preparing adhesive |
| KR102573844B1 (en) * | 2023-04-05 | 2023-09-01 | 주식회사 삼성에코텍 | Method and material for preparing adhesive |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100897417B1 (en) | 2008-07-15 | 2009-05-14 | 한서포리머주식회사 | Two liquids type composition of ceramic anticorrosive paint |
-
2009
- 2009-11-06 KR KR1020090106776A patent/KR101096989B1/en not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100897417B1 (en) | 2008-07-15 | 2009-05-14 | 한서포리머주식회사 | Two liquids type composition of ceramic anticorrosive paint |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101731887B1 (en) | 2017-02-21 | 2017-05-02 | 임환명 | Tile adhesive and grout composition and tile constructing method therewith |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20110049982A (en) | 2011-05-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101096989B1 (en) | High strength and elongation adhesives for ceramic tiles | |
| EP2277961A1 (en) | Acrylic-polyurethane polymer coating dispersions for roofing | |
| KR100789104B1 (en) | The mixing ratio and manufacturing method of a antifreezing and elastic 2 component adhesives for ceramic tiles | |
| KR101170307B1 (en) | Functional Tile Adhesive Using Elasticity Powder | |
| WO2004076573A1 (en) | Coating material, use thereof and method for applying said coating material | |
| KR101453244B1 (en) | 2-Component epoxy resin type adhesion reinforcing agent for ceramic tiles and method of tile adhesion to used that | |
| JP2008063189A (en) | Polymer cement mortar excellent in coating workability and adhesion property | |
| KR101791653B1 (en) | Epoxy Primer for Preventing Pin Hole | |
| KR101030375B1 (en) | 2-component epoxy resin type adhesives for ceramic tiles | |
| JP2015518515A (en) | Surface composition and coating method thereof | |
| KR102230767B1 (en) | Waterproofing coating composition having waterproof surface without long-term cracking | |
| KR100924675B1 (en) | Lightweight adhesive composition for ceramic tile | |
| CN111560215A (en) | Coating material for improving surface strength of stone and application thereof | |
| KR100910129B1 (en) | Inorganic polymer acid resistant mortar for concrete repair included liquid amorphous silicate hydrolysis agent and concrete repair method using the mortar | |
| JP4093179B2 (en) | Rooftop exterior insulation waterproofing method | |
| KR101713644B1 (en) | Organicinorganic hybrid putty composition | |
| KR20090092379A (en) | Fast hard tile adhesive | |
| JP2005220411A (en) | Composition of rust-preventive, and rust-preventing method | |
| JP3767873B2 (en) | Structure reinforcement method | |
| CN102888185A (en) | Stone-like paint and preparation method thereof | |
| KR101364323B1 (en) | The tile adhesive of fast dry and no vertical slip for polishing tile | |
| CN112852199A (en) | Preparation method of cement-based steel structure protective coating | |
| KR101044891B1 (en) | High performance polymer-type tile adhesive with no vertical slip and extended open time (dry fix eco) | |
| KR101045106B1 (en) | Ultra high speed hardening type complex waterproofing system | |
| JP4108264B2 (en) | Cement modifier and resin mortar composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20141208 Year of fee payment: 4 |
|
| FPAY | Annual fee payment |
Payment date: 20160104 Year of fee payment: 5 |
|
| FPAY | Annual fee payment |
Payment date: 20161213 Year of fee payment: 6 |
|
| LAPS | Lapse due to unpaid annual fee |