KR101074486B1 - Cement binder composition, super ultra high strength precast concrete composition and method for producing super ultra high strength precast concrete goods using the same - Google Patents

Abstract

The present invention relates to a cement binder composition that can exhibit a compressive strength of 250 ~ 350MPa and a method for producing a concrete composition and precast concrete products using the same.

Cement binder composition according to the present invention, 45 to 55% by weight of ordinary portland cement containing coarse cement; Silica fume 15-25% by weight; Blast furnace slag fine powder 15-25 wt%; And, 2-8 wt% of anhydrous gypsum; wherein the cement binder composition is composed of 3-8 wt% of SO ₃ in the cement binder composition. Precast concrete product manufacturing method according to the present invention using the cement binder composition described above to perform the process of compaction molding, atmospheric steam curing, heating curing in order to concrete mixed with a water binder ratio of 11 to 15% by weight It is characterized by.

Ultra high strength, Atmospheric steam curing, Heating curing, Coarse cement

Description

     Cement binder composition, super ultra high strength precast concrete composition and method for producing super ultra high strength precast concrete goods using the same }

The present invention relates to a cement binder composition for ultra high strength concrete having a compressive strength of 250 to 350 MPa, and to a method for manufacturing an ultra high strength precast concrete product using the same. More specifically, ordinary portland cement, silica fume, containing coarse cement, Cement binder composition in which blast furnace slag fine powder and anhydrous gypsum are mixed in an appropriate ratio, a concrete composition in which the binder composition is mixed at a low water binder ratio, and the concrete composition are produced through a process of compaction molding, atmospheric steam curing, and heating curing. The present invention relates to a method for producing ultra-high strength precast concrete products.

Recently, the demand for large-scale and high-rise buildings is increasing rapidly due to the overpopulation of the city. As a key element technology for this purpose, the concrete field is required to significantly increase the strength of concrete. However, the current technology is in the level of ultra high strength of 120MPa or more in terms of concrete strength, the situation is showing the limitation of the technology for the development of ultra high strength concrete of more than 250MPa. In addition, although the prior art mainly focuses on the development of concrete for site casting, research on the development of ultra-high strength concrete for precast members is very insufficient. However, high-rise buildings that require the use of ultra-high-strength concrete require rapid construction to shorten the air, and for this, manufacturing technology of ultra-high-strength precast members is required rather than site casting.

In manufacturing ultra-high strength concrete, it is essential to minimize the voids of concrete which greatly affect the compressive strength.To do this, it is necessary to minimize the water binder ratio by using a super high performance water reducing agent, and also use the material having high pozzolanic reactivity. The water tightness of the concrete should be enhanced by producing low crystalline hydrates and having a continuous particle size distribution of the materials making up the entire concrete. In addition, it is essential to use high-strength aggregates, to prevent deformation of the molded body during concrete molding, to prevent cracking due to rapid temperature change during curing, and to prevent abnormal crystal growth of hydrate.

As the current technology regarding ultra-high strength concrete, appropriate ratios of silica fume, blast furnace slag powder, and anhydrous gypsum are applied to cement through Korean Patent Nos. 10-0878551, 10-0874584, 10-0867250, and 10-0686350. The binder composition for ultra-high-strength concrete, in which a binder mixed with a low water binder is mixed, has been disclosed, and Korean Patent No. 10-0622048 discloses a high-strength cement composition using metakaolin instead of silica fume. Patent No. 10-0873514 discloses a binder for ultra high strength concrete using silica sand as a filler. The conventional ultra high strength concrete-related technology is a method of increasing the expression level of the compressive strength mainly by using an excellent pozzolanic reaction material such as silica fume. However, the pozzolanic reaction material such as silica fume is a factor that lowers the fluidity of concrete, so there is a limit to increasing the amount of material used such as silica fume. Accordingly, the expression level of compressive strength does not reach the ultra high strength exceeding 250 MPa. to be.

On the other hand, with regard to curing technology for the production of ultra-high strength concrete, Korean Air Patent No. 10-0717935 issued a cement containing 4CaO · 3Al ₂ O ₃ · SO ₃ as a main component to a cement mixture containing silica fume and anhydrous gypsum at atmospheric pressure. It has been disclosed a method for producing ultra-high strength concrete by curing, and also through the Republic of Korea Patent Publication No. 1999-016686 discloses a method for producing ultra-high strength concrete by autoclave curing (180 ℃ -10 atm). However, the curing technology according to No. 10-0717935 does not consider the fluidity of concrete as concrete exhibiting a compressive strength of about 100 MPa, the curing technology according to Patent Publication No. 1999-016686 is the autoclave curing method of the concrete product Depending on the size, the production of large diameters or long piles is not only limited, but also entails enormous capital investment and considerable maintenance costs. There is this.

The present invention has been developed to further develop the above-mentioned conventional ultra high strength concrete-related technology, there is a technical problem to provide a cement binder composition for ultra high strength concrete exhibiting a compressive strength of 250 ~ 350MPa while ensuring the fluidity of the concrete.

In addition, the present invention has a technical problem to provide a manufacturing method that can maximize the strength of the concrete when producing a precast concrete product using the cement binder composition described above.

The present invention to solve the above technical problem, 45 to 55% by weight of ordinary portland cement containing coarse cement; Silica fume 15-25% by weight; Blast furnace slag fine powder 15-25 wt%; And, 2-8 wt% of anhydrous gypsum; as a cement binder composition, it provides a cement binder composition characterized in that it is configured to contain 3 to 8% by weight of SO ₃ in the cement binder composition.

In addition, the present invention is a precast concrete characterized in that the step of compaction molding, atmospheric steam curing, heating curing of the concrete blended with the water binder ratio of 11 to 15% by weight using the above cement binder composition sequentially It provides a method of manufacturing a product.

According to the present invention, the following effects can be expected.

First, it can provide a cement binder composition for ultra-high strength concrete exhibiting a compressive strength of 250 ~ 350MPa.

Second, it is possible to provide an ultra-high strength precast concrete product that can be advantageously applied to the construction of ultra-high-rise buildings requiring ultra-high strength to rapid construction in the range of 250 ~ 350MPa.

Cement binder composition according to the present invention, 45 to 55% by weight of ordinary portland cement containing coarse cement; Silica fume 15-25% by weight; Blast furnace slag fine powder 15-25 wt%; And, anhydrous gypsum 2 to 8% by weight; characterized in that the composition.

The cement binder composition according to the present invention uses a common portland cement containing coarse cement as a base material. Coarse particle cement refers to the collection of cement generated at the cement mill exit during the cement manufacturing process before the cement classifier. The powder density of coarse cement is 1,500-2,500 cm 2 / g, which is smaller than that of ordinary portland cement, while the powder of ordinary portland cement is 3,000-3,800 cm 2 / g. Coarse cement not only lowers the heat of hydration in the high-strength concrete formulation with high unit cement content, but also physically contributes to the continuous particle size distribution of the entire binder, and chemically reduces the interstitial phase and calcium sulfate content such as calcium sulfoaluminate. Reduction of the contributes to the reduction of adsorption amount and flowability of the high performance water reducing agent added.

In the cement binder composition according to the present invention, the ordinary portland cement is preferably in the range of 45 to 55% by weight, and this content range is considering the content of other materials. In addition, the coarse cement in the ordinary Portland cement is preferably 30 to 70% by weight, which is according to the results confirmed in the following [Example 1].

The cement binder composition according to the present invention uses silica fume, blast furnace slag fine powder, and anhydrous gypsum as admixtures.

Silica fume acts as a micro filler to fill the pozzolanic reactivity and hydrate pores, improving compressive strength and durability. However, excessive use of silica fume is difficult to secure fluidity due to the increase of ultra-fine particles, and for this purpose, the unit yield increases, leading to a decrease in compressive strength. The range is a preferred range for fluidity and strength expression. Furthermore, the present invention proposes to use silica fume having a specific surface area of 5-15 m 2 / g while having 95% or more of amorphous silica (SiO ₂ ) content to maximize strength expression by silica fume.

Blast furnace slag powder is generally excellent in long-term strength and when used in combination with cement has been used as a cement binder because of the cost reduction effect as well as excellent reactivity, the present invention utilizes the same characteristics as it is. The blast furnace slag powder is preferably used in an amount of 15 to 25% by weight, and the blast furnace slag powder having a characteristic of 5,000 to 8,500 cm 2 / g is preferable, in order to maximize the strength improvement effect by the blast furnace slag powder. to be.

Anhydrous gypsum (CaSO ₄ ) acts as an alkali stimulant for substances that react with pozzolanic reactions. That is, by reacting with alumina (Al ₂ O ₃ ) in the calcium sulfo aluminate or blast furnace slag fine powder in cement to produce ethrinzite to compensate the shrinkage of the hardened body and form a dense structure to increase the expression of compressive strength. Anhydrite is because usage is large, the main component of the content of SO ₃ of the anhydrite can lead to reduced durability by inducing over-expansion in concrete according to many, in the present invention uses in an amount of from 2 to 8% by weight and as well as SO ₃ It is proposed to use anhydrous gypsum having a content of 50 to 60% by weight and a powder level of 4,000 to 6,000 cm 2 / g.

On the other hand, and in relation to which the anhydrite part added as an alkaline stimulant during the blast furnace slag produced blast furnace slag is slightly occurs in the SO ₃ content in accordance with the manufacturer, but also because of anhydrite also to the SO ₃ content differences by Origin In the present invention, it is proposed that the composition of the total cement binder composition so that the content of SO ₃ is 3 to 8%. The content of SO ₃ in the total cement binder composition can be easily adjusted by adjusting the amount of anhydrous gypsum used.

The cement binder composition as described above may be blended into ultrahigh strength to ultrahigh strength concrete at a water binder ratio of 11 to 15% by weight. The cement binder composition is preferably pre-mixed using a zero gravity mixer. Of course, the concrete mixture is added with a PC (Polycarboxylate) -based high performance water reducing agent as a admixture, and coarse aggregates and fine aggregates having a maximum aggregate size of 10 mm or less, but when the PC-based high performance water reducing agent is added, the water binder ratio of 11 to 15% by weight is high performance Consider the amount of water excluding the solids in the water reducing agent.

Concrete composition blended from ultra high strength to ultra high strength can be commercialized in precast concrete (PC), the present invention proposes a method as shown in Figure 1 as a method for maximizing the expression of compressive strength in the process of productization to PC do. In other words, in the preparation of precast concrete products, it is suggested to mix the concrete composition blended with ultra high strength to ultra high strength for a certain period of time, and then carry out the processes of compaction molding, atmospheric steam curing, and heating curing. The procedure is according to the result confirmed in [Example 3] below.

The compaction forming process in the manufacturing process of the precast concrete product according to the present invention is to suppress the material separation.

The atmospheric steam curing process in the manufacturing process of the precast concrete product according to the present invention is to express the strength early through the accelerated curing. In the present invention, as a preferred atmospheric steam curing process, it is proposed to sequentially follow the pre-process-> temperature raising process-> constant temperature process-> cooling process as shown in FIG. The pretreatment process is to cure steam while maintaining at 24 ~ 48 hours at 15 ~ 25 ℃, and the temperature increase process is to cure steam while raising the temperature to 70 ~ 90 ℃ at a temperature increase rate of 5 ~ 10 ℃ / hour. Steam curing while maintaining for 72 to 120 hours, the cooling process is preferably steam curing while cooling to room temperature at a cooling rate of 2 ~ 10 ℃ / hour. In particular, the pretreatment process is performed prior to the temperature raising process, which is intended to induce initial strength expression. In other words, when the temperature of the concrete starts to rise in the temperature raising process, air and water in the concrete expand, and this expansion pressure may cause defects in the concrete. By going through the process, it is able to withstand the expansion pressures of air and water. In addition, the use of high-density water-reducing agents increased due to the combination of ultra high strength and ultra high strength concrete, and the amount of material that reacts with pozzolanics in addition to cement was increased. Accordingly, the end point of concrete may be delayed. Proceed.

In the manufacturing process of the precast concrete product according to the invention the heating curing process is to maximize the strength expression. In the present invention, as a preferred heating curing process, it is proposed to follow the temperature raising step-> constant temperature step-> cooling step sequentially as in FIG. The temperature raising process proceeds while increasing the temperature to 180 ~ 220 ℃ at a temperature rising rate of 10 ~ 50 ℃ / hour, the constant temperature process to proceed while maintaining the maximum temperature 20 to 30 hours, the cooling process of 10 ~ 50 ℃ / hour It is preferable to proceed while cooling to room temperature at a cooling rate.

Hereinafter, look at the present invention based on the embodiment. However, the following examples are only for illustrating the present invention, and the scope of the present invention is not limited thereto.

Example 1 Mortar Experiment According to Coarse Cement Substitution Rate Change

(1) Experimental method

Using a material exhibiting physical and chemical properties as shown in Table 1 below, after forming the binder as shown in Table 2, mortar was mixed, and fluidity and compressive strength of the mortar were measured.

In the binder composition shown in [Table 2], cement was prepared by varying the substitution amount of coarse cement from 0% to 100% by weight based on ordinary portland cement, and the binder was a zero gravity mixer (twin shaft structure, upper and lower respectively, effective capacity). 25 L) for 5 minutes.

In addition, the mortar mixing of the formulation according to the following [Table 2], the binder, water, admixture and fine aggregates were first weighed, and then the binder, water, and admixture were put into a mortar mixer in which both the revolution and the rotating motion were carried out. The fine aggregate was slowly added while mixing at 120 rpm, and when the mortar began to loosen after about 1 minute while the fine aggregate was added, the mortar mixer was adjusted to 2 speeds (90 rpm, 225 rpm) and mixed for 4 minutes. 3 rpm (rotation 160 rpm, rotation 400 rpm) was carried out by mixing for 1 minute. Flow was measured for the mortar thus mixed. Mortar flow measurement was performed using a mold having an upper inner diameter of 60 mm, a lower inner diameter of 70 mm, and a height of 50 mm. The mortar flow was measured in two orthogonal diameters at a point when the spreading of the mortar stopped. 180 mm was set.

In addition, the compressive strength of mortar was measured about the molded object produced using 50x50mm, 100x100mm cubic mold, and Ø100xH200mm cylinder mold. The molded body was produced by a mold demoulding by performing tab filling 10 times at a height of about 1 cm from the bottom surface, followed by curing as shown in Table 3 below. However, in order to prevent the release of moisture in the molded body, the pupil and shrinkage of the molded body, the glass plate was covered on the upper surface of the molded mold during the curing process.

Physical and Chemical Properties of Materials Used in Cement Binder Compositions division density
(g / cm3) Specific surface area
(Cm 2 / g) Particle size distribution (㎛) Chemical composition (% by weight) middle
Particle diameter 10%
Pass 90%
Pass SiO ₂ Al ₂ O ₃ Fe ₂ O ₃ CaO MgO SO ₃ L.O.I. Common Portland Cement 3.15 3,276 16.9 2.63 44.4 22.09 4.76 3.12 63.15 2.40 2.23 1.10 Coarse Cement 3.15 2,268 27.9 3.89 75.8 22.39 4.69 3.40 61.50 2.76 1.59 0.54 Blast furnace slag
Fine powder 2.91 6,771 4.81 0.8 13.2 32.54 14.89 0.52 42.04 3.41 - +0.12 Anhydrous gypsum 2.89 4,583 13.1 2.1 47.8 2.14 0.02 0.02 38.22 1.48 58.1 3.62 Silica fume 2.20 90,000 1.3 - - 97.0 0.1 - 10 ^-4 3 * 10 ^-4 - 0.3

Binder Composition and Mortar Formulation Binder Composition SO _{3 in} binder
(weight%) Mortar cement
(weight%) Silica fume
(weight%) Blast furnace slag
Fine powder (% by weight) Anhydrous gypsum
(weight%) W / B
(weight%) Admixture
(weight%) Binder /
Fine aggregate rain Binder volume
(g / ℓ) 48 22 25 5 3.67-3.98 11.0 2.5 2.35 500

Atmospheric Steam Curing division Curing Process Condition (relative humidity 95%) Temperature range Retention time Temperature rise rate Cooling rate (end) Preprocess 23 ℃ 48 hours - - (I) Temperature raising process 23 ℃-> Maximum temperature 80 ℃ - 6 ℃ / hour - (All) Constant temperature process 80 ℃ 110 hours - - (la) Cooling process 80 ℃-> room temperature - - 6 ℃ / hour

(2) Experimental results

The results of measuring the fluidity and the compressive strength of the mortar are shown in FIG. 4. As shown in FIG. 4, the flowability of mortar tended to increase as the cement cement replacement rate increased, and the compressive strength of mortar was remarkably decreased when the cement cement replacement rate was 80% by weight or more. According to such a result, it is preferable to make the substitution rate of a coarse cement into 30 to 70 weight%.

[Example 2] Concrete test according to the composition change of the binder

(1) Experimental method

After the concrete was mixed as shown in the following [Table 4] using a binder having a different composition ratio, the fluidity and compressive strength of the concrete were measured. Concrete mixing was carried out in the same manner as the mortar mixing in Example 1 described above. The production of the concrete molded body was carried out in the same manner as the mortar molded body produced in [Example 1] described above, except that after the atmospheric steam curing according to the above [Table 3] demoulding and then demolded molded body in a dry oven The heating curing according to the following [Table 5] was further performed.

Concrete mix Water / binder
(weight%) Aggregate aggregate rate
(weight%) Admixture
(B x weight%) Unit material amount (㎏ / ㎥) water Binders Fine aggregate Coarse aggregate 11.0% 32.0 2.0 to 2.6 121 1100 468 992

Heating curing division Curing Process Condition Temperature range Retention time Temperature rise rate Cooling rate (end) Temperature raising process Room temperature-> Maximum temperature 200 ℃ - 40 ℃ / hour - (I) Constant temperature process 200 ℃ 24 hours - - (All) Cooling process 200 ℃-> room temperature - - 30 ℃ / hour

(2) Experimental results

The results of measuring the fluidity and the compressive strength of the concrete according to the binder composition are shown in the following [Table 6]. [Table 6] 250 ~ while satisfying the fluidity when forming a binder in the range of 45 ~ 55% by weight cement, 15 ~ 25% by weight silica fume, 15-25% by weight fine blast furnace slag and 2 ~ 8% by weight gypsum It can be seen that the compressive strength in the 350MPa range is expressed.

Flowability and Compressive Strength of Concrete According to Binder Composition No. Binder (% by weight) Premise
SO ₃ content in the binder
(weight%) Admixture
(B x weight%) slump
Flow
(Mm) Compressive strength
(MPa) cement
Of all cement
Coarse cement 40% by weight) Silica fume Slag
Fine powder Anhydrous gypsum One 45.0 25.0 25.0 5.0 5.3 2.6 670 310.1 2 47.5 24.5 23.0 5.0 5.2 2.4 660 328.7 3 50.0 20.0 25.0 5.0 5.4 2.2 650 317.6 4 52.5 17.5 25.0 5.0 5.4 2.2 700 292.2 5 55.0 15.0 25.0 5.0 5.5 2.2 690 262.8

Example 3 Concrete Experiment According to Curing Method

(1) Experimental method

The compressive strength of the concrete was measured after mixing the concrete in the formulation of [Table 4] using the binder having the composition of No. 2 in the [Table 6]. The compressive strength of concrete was measured in the same manner as in [Example 2] as a whole, but the curing method was measured by manufacturing a concrete molded body differently as shown in [Table 7].

(2) Experimental results

The result of measuring the compressive strength of concrete according to the curing method is shown in the following [Table 7]. As shown in [Table 7], the heating curing after the atmospheric steam curing showed a significantly higher compressive strength than the other curing methods. Accordingly, heating curing after atmospheric steam curing is a curing method that can maximize the compressive strength.

Concrete compressive strength by curing method No. Curing method Compressive strength
(MPa) Remarks One  Heating curing after atmospheric steam curing 320.5 Atmospheric vapor curing: according to Table 3 above
Heating curing: according to Table 5 above 2  Atmospheric Steam Curing 252.2  Atmospheric vapor curing: according to Table 3 above 3  Natural Curing (14 days) 162.4 -

Example 4 Concrete Experiment with Water Binder Ratio

(1) Experimental method

Using the binder having a composition ratio of No. 2 in Table 6, the concrete was mixed with varying the water binder ratio, and then the fluidity and compressive strength of the concrete were measured. The fluidity and compressive strength of the concrete were measured in the same manner as in [Example 2].

(2) Experimental results

The results of measuring the flowability and compressive strength of concrete according to the water / binder ratio are shown in the following [Table 8]. As shown in [Table 8], when the water / binder ratio is 11 to 15% by weight, the compressive strength is generally expressed in the range of 250 to 350 MPa. It can be seen that higher compressive strength is expressed.

Flowability and Compressive Strength of Concrete According to Water / Binder Ratio No. Concrete mix slump
Flow
(Mm) Compressive strength
(MPa) Full water / binder
(weight%) Water / binder
(weight%) Admixture
(B x weight%) One 11.82 10.0 2.60 640 280.7 2 12.32 10.5 2.60 670 310.1 3 12.75 11.0 2.50 690 327.2 4 13.18 11.5 2.40 720 296.4 5 13.54 12.0 2.20 720 278.5

1 shows a schematic process of a method for producing a precast concrete product according to the present invention.

Figure 2 shows the temperature history of the atmospheric steam curing process in the method of manufacturing a precast concrete product according to the present invention.

Figure 3 shows the temperature history of the heating curing process in the method of manufacturing a precast concrete product according to the present invention.

4 shows the compressive strength and fluidity of mortar according to the substitution rate of coarse cement as cement binder.

Claims (8)

45 to 55% by weight of ordinary portland cement, containing 30 to 70% by weight coarse cement; Silica fume 15-25% by weight; Blast furnace slag fine powder 15-25 wt%; Anhydrous gypsum 2-8% by weight; As a cement binder composition, Cement binder composition characterized in that the composition containing 3 to 8% by weight of SO ₃ in the cement binder composition. In claim 1, Coarse cement included in the ordinary portland cement has a powder degree of 1,500 ~ 2,500 ㎠ / g, The silica fume is one having a silica content of at least 95% by weight and a powder degree of 5-15 m 2 / g, The blast furnace slag fine powder has a powder degree of 5,000 ~ 8,500 cm 2 / g, The anhydrous gypsum is a cement binder composition, characterized in that the SO ₃ content of 50 to 60% by weight and having a powder degree of 4,000 ~ 6,000 cm 2 / g. delete A concrete composition, wherein the concrete composition is blended at a water binder ratio of 11 to 15% by weight using the cement binder composition according to any one of claims 1 to 4. Method for producing a precast concrete product, characterized in that the step of compaction molding, atmospheric steam curing, heating curing the concrete composition according to claim 4. The method of claim 5, The concrete composition is a method of producing a precast concrete product, characterized in that by mixing the cement binder composition in advance and prepared by mixing water, admixture, aggregate. The method of claim 5, The atmospheric steam curing, Pretreatment step of steam curing while maintaining at 15 ~ 25 ℃ 24 ~ 48 hours; A temperature raising step of steam curing while raising the temperature to 70 to 90 ° C. at a temperature rising rate of 5 to 10 ° C./hour; Constant temperature process of steam curing while maintaining the maximum temperature 72 ~ 120 hours; A cooling step of steam curing while cooling to room temperature at a cooling rate of 2 to 10 ° C./hour; Method for producing a precast concrete product, characterized in that comprises a. The method of claim 5, The heating curing is, A temperature raising step of raising the temperature to 180 to 220 ° C at a temperature rising rate of 10 to 50 ° C / hour; Constant temperature process to maintain the maximum temperature for 20 to 30 hours; A cooling step of cooling to room temperature at a cooling rate of 10 to 50 ° C./hour; Method of manufacturing a precast concrete product, characterized in that consisting of.

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