KR101008346B1 - Resolving equipment of a protective clothing and resolving method thereof - Google Patents

Abstract

PURPOSE: A resolving equipment and a method thereof are provided to easily dissolute the waste of a protection product by automatically supplying cooling water to a volume reducing furnace when temperature increases. CONSTITUTION: A volume reducing furnace(110) comprises an opening and closing hole, a first discharge pipe, and a heater. A first circulating pump(120) is arranged between the first discharge pipe and the first circulation pipe of the volume reducing furnace in order to circulate the waste of a protection product. An ozone generator(130) is connected to the first circulation pipe in order to supply ozone gas to the volume reducing furnace. A hydrogen peroxide tank(140) supplies hydrogen peroxide to the volume reducing furnace. A furnace(170) eliminates radioactive substances from the waste that is discharged from the volume reducing furnace. A cooling water tank supplies cooling water to the volume reducing furnace.

Description

Disassembling facility for high-performance functional protective article and its disassembly method

The present invention relates to a high-performance functional protective article decomposition equipment and its disassembling method, and more specifically, to the protective equipment such as protective clothing, protective work shoes, gloves, etc. made of polyvinyl alcohol resin materials recently used in nuclear power plants. The present invention relates to a high-performance functional protective article decomposition equipment and its decomposition method, which are finally discharged and treated with carbon dioxide gas and water.

In general, nuclear power plants periodically perform safety checks and maintenance on the facility for safety. During such inspection and maintenance work, in the high polluted area of radioactivity, the worker is protected from contaminants such as radiation and caused to workers. Protective equipment such as protective clothing, protective work shoes, and gloves are used to block dust and static electricity.

Such radiation protection articles are usually made of disposable to prevent the spread of radioactivity, and configured to be discarded after wearing once. For this purpose, the protection articles are made of polyvinyl alcohol (PVA) resin. That is, since the polyvinyl alcohol resin is water soluble at a predetermined temperature or more, a method of dissolving it in water and treating the solution (protective product waste solution) is used. As a part of the present invention, as of November 18, 2009, Patent Application No. 10-2009-0111303, "High Sensitive Protective Clothing Disassembly Device" has been filed.

As described above, the high-definition protective clothing decomposing device, as described above, has a discharge pipe 111 for discharging waste liquid from which polyvinyl alcohol is decomposed at the lower end and a cover 112 for injecting protective clothing at the upper end. A heating furnace 110 formed on the outer circumferential surface thereof; A pump 120 connected to a transfer pipe 115 formed at the bottom of the heating furnace 110 to supply protective clothing waste liquid to the reactor; An ozone gas generator (130) having an oxygen generator (131); A heater 140 for heating ozone gas generated from the ozone gas generator 130; A reactor 150 for supplying the heated ozone gas between the pump 120 and the transfer pipe 125 connecting the reactor 150 to decompose the ozone gas and the polyvinyl alcohol by reaction; And a hydrogen peroxide gas injector (160) connected to the transfer pipe (125) located between the reactor (150) and the venturi tube (125a).

As described above, the highly-reduced protective clothing decomposing device dissolves the protective clothing contaminated with radiation in water and then decomposes by ozone gas and hydrogen peroxide gas, thereby easily removing and releasing the radioactive material contained in the protective clothing waste liquid, and removing the radioactive material. To have the effect of improving the treatment efficiency of the treatment process. In other words, the protective clothing waste liquid from which the radioactive material has been removed can be discharged in the same manner as the general household waste water if the chemical oxygen demand (COD) is 40 ppm or less.

However, as described above, the highly-decreased protective clothing decomposing device is a pretreatment process in which a protective clothing made of polyvinyl alcohol resin is dissolved in water and then decomposed by ozone gas and hydrogen peroxide, in order to discharge the protective clothing waste liquid into the stream. There is a need for a post-treatment process to remove residual contaminants, that is, radioactive material, the high filing protective clothing decomposing device has a problem that the continuity to the post-treatment process is inferior.

In addition, the pre-applied high-performance protective clothing decomposition device is supplied with ozone gas to the reactor for the decomposition of the protective clothing waste liquid (polyvinyl alcohol) discharged through the discharge pipe of the heating furnace, hydrogen peroxide to promote the reaction of the ozone gas and the protective clothing waste liquid The gas is supplied. At this time, the protective clothing waste liquid is gradually boiled by the catalytic reaction of the hydrogen peroxide gas, causing a rise in the temperature of the heater and the reactor, and thus, the process for decomposing the protective garment waste liquid has been difficult.

Therefore, the present invention was devised to solve the above problems, the present invention is the opening and closing port for injecting the protective article on one side, and the first discharge pipe for discharging the protective fluid waste at the bottom is formed, the heater is on the lower outer peripheral surface A cooking furnace provided; A first circulation pump which is formed between the first discharge pipe and the first circulation pipe of the reduction furnace to circulate the waste protection waste product in the reduction furnace; An ozone generator connected to the first circulation pipe and provided with an oxygen generator for supplying ozone gas to the cooking path; A hydrogen peroxide tank to which a hydrogen peroxide supply pump and a hydrogen peroxide supply pipe are connected to supply hydrogen peroxide to the reducing furnace; A protective article disassembling device configured to include a reaction furnace for removing radioactive material by supplying waste liquid discharged from the cooking furnace, wherein a steam cooling coil is formed therein to supply cooling water to the cooking furnace, and A cooling water tank having a cooling water discharge pipe formed therein and having a cooling device for controlling the temperature of the cooling water; And a cooling water supply pump formed between the cooling water discharge pipe and the cooling water supply pipe connected to the cooling furnace. The steam cooling coil is configured to be connected to a steam discharge pipe for discharging the steam of the cooling furnace. The purpose of the present invention is to provide a highly functional protective article disassembly facility.

In addition, an aeration mechanism is formed inside the reactor for aeration of air supplied through an ozone lamp and an air supply pipe, and a second circulation pump is disposed between the second discharge pipe and the second circulation pipe formed at the lower end of the reactor. And a second ozone generator connected to the second circulation pipe, and configured to form an outlet for volatilizing volatile gas at an upper end of the reactor. There is a purpose.

In addition, a reverse osmosis pump is formed in the second discharge pipe of the reactor, and a reverse osmosis filter is provided between the reverse osmosis pump and the third circulation pipe connected to the reactor to remove acid from the wastewater of the protective article, and the reverse osmosis pressure. A mesh filter is further provided between the filter and the reverse osmosis pump to remove foreign substances from the waste of the protective article, and a third discharge pipe is formed at the lower end of the reverse osmosis filter to finally discharge the waste of the protective article. The purpose of the present invention is to provide a highly functional protective article disassembly facility.

In addition, it is an object of the present invention to provide a high-performance functional protective article decomposition equipment characterized in that it is configured to further include a manganese dioxide catalyst inside the reactor.

In addition, the present invention comprises the steps of maintaining the water level of the cooling water tank, the cooking furnace, the reactor at 85%, 25%, 25%, respectively; Inserting a contaminated protective article into the cooking furnace; Heating through a heater until the temperature of the cooking furnace becomes 100 ° C; When the heating is completed, hydrogen peroxide is injected into the cooking furnace, and when the water level of the cooking furnace reaches 50% while cooling water is supplied to control the temperature rise according to the hydrogen peroxide reaction, an ozone generator is operated to generate ozone in the cooking furnace. Causing an oxidation reaction; Cooling the protective article waste liquid to 65 ° C. or lower by a cooling water tank when the ozone oxidation reaction is completed; The cooled protective article waste solution is supplied to the reactor to remove the hydrogen peroxide water and contaminants, volatile gas remaining in the protective article waste solution; providing a highly sensitive functional protective article decomposition method comprising the Its purpose is to.

In addition, the inside of the reactor is provided with an aeration mechanism and a manganese dioxide catalyst for aeration of the air supplied through the ozone lamp and the air supply pipe, a part of the protective equipment waste liquid discharged through the second discharge pipe formed at the bottom of the reactor Is circulated by the second circulation pump and the second circulation pipe and the rest is circulated by the reverse osmosis pump and the third circulation pipe, the second circulation pipe is connected to the ozone generator and the third circulation pipe reverse osmosis filter Is provided with a step of removing contaminants, volatile gases of the hydrogen peroxide and the protective waste products; The contaminant and the volatile gas of the hydrogen peroxide and the protective article waste liquid is removed, the protective article is finally discharged through the third discharge pipe of the reverse osmosis filter in a state cooled to 20 ~ 50 ℃; An object of the present invention is to provide a method for disassembling a highly protective functional article.

As described above, the present invention applies and decomposes protective products such as protective clothing, protective work shoes, and gloves made of polyvinyl alcohol resin used in nuclear power plants by a continuous process, and finally discharges and processes them into volatile gas (carbonate gas) and water. Therefore, direct stream discharge is possible.

In addition, the present invention, when the temperature of the cooking furnace rises above a certain temperature in order to prevent the waste of the protective article is gradually boiled by the catalytic reaction of hydrogen peroxide in the cooking furnace to cause the temperature rise of the cooking furnace to increase the cooling water in the cooking furnace. It is a very useful invention to facilitate the dissolution of the protective article waste liquid and the reaction by ozone and hydrogen peroxide by being automatically supplied.

1 is a structural diagram showing a conventional protective equipment disassembly equipment.
2 is a structural diagram showing a disassembly facility for the protection of the present invention.

Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

High-performance functional protective article disassembly facility 100 according to the present invention, as shown in [2], the opening and closing port 111 for inputting the protective article on one side, and the first discharge pipe for discharging the waste of the protective article at the bottom 112 is formed, the cooking path 110 is provided with a heater 113 on the lower outer peripheral surface; A first circulation pump (120) formed between the first discharge pipe (112) and the first circulation pipe (121) of the reduction furnace (110) to circulate the waste protection fluid to the reduction furnace (110); An ozone generator 130 connected to the first circulation pipe 121 and provided with an oxygen generator 131 for supplying ozone gas to the reducing path 110; A hydrogen peroxide tank 140 to which a hydrogen peroxide supply pump 141 and a hydrogen peroxide supply pipe 142 are connected to supply hydrogen peroxide to the reduction furnace 110; A protective article disassembly facility configured to include a reactor 170 for removing radioactive material by supplying waste liquid discharged from the cooking furnace 110 to remove the radioactive material, and to supply cooling water to the cooking furnace 110. A cooling water tank 150 having a steam cooling coil 151 formed therein, a cooling water discharge pipe 152 formed at a lower end thereof, and having a cooling device 155 for controlling the temperature of the cooling water; It is configured to further include a cooling water supply pump 160 formed between the cooling water discharge pipe 152 and the cooling water supply pipe 161 connected to the reduction path 110, the steam cooling coil 151 is a reduction path 110 Steam discharge pipe 153 for discharging the steam of the) is configured to be connected.

The reduction path 110 is configured to dissolve and disassemble the protective article, the opening and closing port 111 for inputting the protective article is formed at one side, the first discharge pipe 112 is formed at the bottom of the waste discharged protective equipment One side of the lower outer circumferential surface is provided with a heater 113 for heating the reduction path 110 and a level sensor 114 for adjusting the water level on the other side, and a temperature sensor 116 for adjusting the temperature on the outside. Of course, the cooling water tank 150 and the reaction furnace 170 together with the reduction furnace 110 are provided with a level sensor and a temperature sensor, and the controller 115 is further provided on the upper portion of the reduction furnace 110 for the reduction furnace ( Of course, it is possible to drive 110 automatically.

The circulation pump 120 is configured to circulate the protective equipment waste liquid discharged from the reduction path 110, the venturi in the first circulation pipe 121 connected between the circulation pump 120 and the reduction path 110. The tube 121a is formed, and ozone generated by the oxygen generator 131 and the ozone generator 130 is supplied to the reduction path 110 together with the waste protection fluid on one side of the venturi tube 121a.

The hydrogen peroxide tank 140 is configured to supply hydrogen peroxide to the reduction furnace 110, and is composed of a hydrogen peroxide supply pump 141 and a hydrogen peroxide supply pipe 142 for supplying hydrogen peroxide to the reduction furnace 110.

At this time, the hydrogen peroxide supply pump 141 is a quantitative pump for supplying a fixed amount of hydrogen peroxide to the reduction furnace 110, the hydrogen peroxide supply pump 141 is operated by adjusting the flow rate adjusting dial adjuster (not shown) to 20% or less The operating conditions are up to 2 hours in 1 minute increments. The supply of hydrogen peroxide to the quenching furnace 110 in a quantitative manner is to prevent the temperature of the warehousing furnace 110 from rising as the waste of the protective article gradually boils due to the catalytic reaction of hydrogen peroxide in the quenching furnace 110. to be.

The cooling water tank 150 replenishes water in the cooling furnace 110 and cools the steam generated in the cooling furnace 110 when the protective clothing waste liquid of the cooling furnace 110 is heated by the heater 113. Supplying to the reactor 170 by the 125, when the temperature of the cooking furnace 110 exceeds 110 ℃ by the catalytic reaction of the hydrogen peroxide when supplying hydrogen peroxide to the cooking furnace 110, the cooking furnace 110 It is used to control the temperature by supplying cooling water.

To this end, the cooling water tank 150 has a steam cooling coil 151 formed therein, a cooling water discharge pipe 152 is formed at the bottom, and one end of the steam cooling coil 151 is applied by the steam discharge pipe 153. It is connected to the furnace 110 and the lower end is connected to the reactor 170 by the transfer pipe (125). Of course, the water supply pipe 150a for supplying water to the cooling water tank 150 is formed on the upper side of the cooling water tank 150.

At this time, the cooling water tank 150 is further provided with a cooling device 155, the cooling device 155 is configured to control the temperature of the cooling water tank 150, the temperature of the cooling water tank 150 is 25 ℃ When the temperature exceeds 22 ° C., the cooling device 155 is driven until the cooling water is supplied to the cooling water tank 150 by the cooling water supply pipe 155a and the cooling water supply pump 160. At this time, the temperature of the cooling water should be kept lower than the cooling water of the cooling water tank 150.

As described above, the cooling water supply pump 160 supplies the cooling water cooled by the cooling device 155 to the cooling water tank 150 or controls the temperature rise due to the catalytic reaction of hydrogen peroxide in the cooling path 110. It is used to supply the cooling water to the reducing path 110 through the cooling water supply pipe 161.

The reactor 170 is configured to remove contaminants such as hydrogen peroxide dissolved in the protective fluid waste liquid, radioactive substances remaining in the protective fluid waste liquid, and volatile gases, which will be described in detail below.

An aeration mechanism 173 is formed in the reactor 170 to aeration the air supplied through the ozone lamp 171 and the air supply pipe 172, and a second formed at the bottom of the reactor 170. The second circulation pump 176 is formed between the discharge pipe 174 and the second circulation pipe 175, the ozone generator 177 is connected to the second circulation pipe 175, the reaction furnace 170 At the top of the top) an outlet 178 is formed for volatilizing the volatile gas. At this time, the ozone lamp (AOP) generates CO ₃ to react with the contaminants remaining in the waste of the protective article.

In addition, a reverse osmosis pump 181 is formed in the second discharge pipe 174 of the reactor 170, and between the reverse osmosis pump 181 and the third circulation pipe 182 connected to the reactor 170. Reverse osmosis filter 180 is provided to remove the acid from the waste of the protective article, the mesh filter 185 is further provided between the reverse osmosis filter 180 and the reverse osmosis pump 181 to remove foreign substances of the waste of the protective article Although removed, a third discharge pipe 183 is formed at the lower end of the reverse osmosis filter 180 to finally discharge the waste protection product.

In this case, the mesh filter 185 may be formed of an activated carbon filter. The activated carbon filter is highly adsorptive, and most of the constituents are carbonaceous materials. It is useful for removing contaminants, etc., and also for removing foreign matter from the waste of protective products.

The reaction furnace 170 may further include a manganese dioxide catalyst 179. The manganese dioxide catalyst 179 accelerates the decomposition reaction of hydrogen peroxide, that is, decomposition of water and oxygen into the reaction furnace ( Volatilize through outlet 178 of 170;

At this time, it is obvious that the enzyme can be used as a substitute for the manganese dioxide catalyst 179, and the protective clothing waste solution is in a state of atmospheric pressure in order to remove hydrogen peroxide, volatilization of volatile gas, and contaminants of the protective waste product. Is cooled.

When explaining the decomposition method and the operating state of the present invention having the above configuration in more detail.

Highly functional protective article disassembly method according to the present invention comprises the steps of maintaining the water level of the cooling water tank 150, the reduction furnace 110, the reactor 170, respectively 85%, 25%, 25%; Contaminating the protective article contaminated with the reducing path 110; Heating through the heater 113 until the temperature of the cooking furnace 110 becomes 100 ° C; When the heating is completed, hydrogen peroxide is injected into the reduction furnace 110, when the cooling water is supplied to control the temperature rise according to the hydrogen peroxide reaction, when the water level of the reduction furnace 110 reaches a 50% level, the ozone generator 130 ) Is activated to cause an ozone oxidation reaction in the cooking path 110; When the ozone oxidation reaction is completed, cooling the protective equipment waste liquid to 65 ° C. or less by the cooling water tank 150; The cooled protective article waste liquid is supplied to the reactor 170 to remove the hydrogen peroxide water and contaminants, volatile gas remaining in the protective article waste liquid.

At this time, the reactor 170 is provided with an aeration mechanism 173 and a manganese dioxide catalyst 179 for aeration of the air supplied through the ozone lamp 171 and the air supply pipe 172, the reaction furnace ( A part of the protective equipment waste liquid discharged through the second discharge pipe 174 formed at the bottom of 170 is circulated by the second circulation pump 176 and the second circulation pipe 175, and the rest of the reverse osmosis pump 181 and It is circulated by the third circulation pipe 182, the second circulation pipe 175 is connected to the ozone generator 177 and the third circulation pipe 182 is provided with a reverse osmosis filter 180 is hydrogen peroxide and Removing contaminants and volatile gases in the protective waste products; The protective article in which the contaminants and volatile gases of the hydrogen peroxide and the protective article waste solution are removed are finally discharged through the third discharge pipe 183 of the reverse osmosis filter 180 while being cooled to 20 to 50 ° C .; It is configured to include.

The protective article is introduced through the opening and closing port 111 of the reducing furnace 110, and the water level of the cooling water tank 150 is always maintained at 85% or more before the start of operation of the protective equipment disassembly equipment, automatic when the water level is 65% or less Refill the water level.

After the protective article is put in, the water level of the cooling water tank 150 is 85%, the water level of the reduction furnace 110 is 25%, the water level of the reactor 170 is 25% to maintain the water level, this time required The turnaround time is maintained within about 10 minutes.

When replenishment of the water of the cooling water tank 150, the reduction furnace 110, and the reaction furnace 170 is completed, the heater 113 of the reduction furnace 110 may have a temperature of the reduction furnace 110 at 100 ° C. Until it works. In this case, when the water replenished in the reduction path 110 is heated by the heater 113 to generate steam, the steam is discharged from the steam discharge pipe 153, the discharged steam of the cooling water tank 150 It is supplied to the reactor 170 by the transfer pipe 125 in a state of being cooled by the steam cooling coil 151.

When the heating of the reduction furnace 110 is completed, the hydrogen peroxide supply pump 141 is driven to supply hydrogen peroxide of the hydrogen peroxide tank 140 to the reduction furnace 110 through the hydrogen peroxide supply pipe 142, the reaction of the hydrogen peroxide In order to control the temperature according to the intermittent cooling water supply pump 160 is supplied to the cooling water to the cooling path 110.

At this time, since the method of injecting hydrogen peroxide has a large influence on the measurement of chemical oxygen demand (COD) of the waste of protective products, the flow rate adjusting dial adjuster of the hydrogen peroxide supply pump 141 is adjusted to 20% or less so as to be injected at 560 ml or less per minute. The driving time is up to 2 hours in 1 minute increments.

In this case, the heater 113 is automatically controlled to maintain the temperature of the cooking furnace 110 between 88 and 105 ° C., and the pressure of the cooking furnace 110 is controlled within 0.2 kg / cm ² .

When the water level of the reducing path 110 reaches a level of 50%, the first circulation pump 120 is driven so that the ozone generated in the oxygen generator 131 and the ozone generator 130 is circulated in the second together with the protective equipment waste liquid. It is circulated in the reducing path 110 through the pipe. At this time, the pressure of the oxygen generator 131 is maintained at 0.6 ~ 1.2Psi, the water level of the coolant tank 150 is automatically maintained more than 85%. As described above, the protective article is decomposed by the ozone oxidation reaction in the reduction furnace 110 by the hydrogen peroxide and ozone supplied to the reduction furnace 110. In this case, the ozone oxidation reaction proceeds for 4 hours.

When the ozone oxidation reaction, that is, the circulation of the protective equipment waste liquid is completed, the heater 113 is stopped, the steam circulation of the first circulation pump 120 and the first circulation pump 120 and the cooling water tank 150 When the protective article waste fluid is circulated to the heating path 110 through the cooling circulation pipe 122 connected to one end of the coil 151 and the steam discharge pipe 153 connected to the other end of the steam cooling coil 151 to reach 65 ° C. Cools down.

When the cooling of the protective article waste liquid is completed, the protective article waste liquid is supplied to the reactor 170 through the first circulation pump 120 and the transfer pipe 125.

At this time, the protective equipment waste liquid supplied to the reactor 170, as described above, the impurities, contaminants, etc. of the hydrogen peroxide and the protective equipment waste liquid are removed by various other equipment, the volatile gas is the upper end of the reactor 170 Volatilized through the outlet 178 formed in the.

The protective equipment waste fluid in which the contaminants of the hydrogen peroxide and the protective equipment waste liquid and the volatilization of the volatile gas are circulated by various equipment provided in the reactor 170, wherein the circulating protective equipment waste liquid is ozone oxygen 177 and By the reverse osmosis filter 180, the mesh filter 185 to remove the contaminants remaining in the protective waste products again. At this time, when the chemical oxygen demand (COD) of the protective equipment waste liquid is less than the reference value is discharged to the river through the third discharge pipe 183 formed at the lower end of the reverse osmosis filter 180.

As described above, the present invention has been described by means of a limited embodiment, but the present invention is not limited thereto and is intended by the person skilled in the art to which the present invention pertains to the technical spirit of the present invention and the claims to be described below. Various modifications and variations are possible within the scope of equivalents.

* Description of the symbols for the main parts of the drawings *
100: the present invention protective equipment decomposition equipment
110: saengyongro 111: opening and closing
112: first discharge pipe 113: heater
114: level sensor 115: controller
116: temperature sensor 120: first circulation pump
121: first circulation pipe 122: cooling circulation pipe
125: transfer pipe 130: ozone generator
131: oxygen generator 140: hydrogen peroxide tank
141: hydrogen peroxide supply pump 142: hydrogen peroxide supply pipe
150: coolant tank 151: steam cooling coil
152: cooling water discharge pipe 153: steam discharge pipe
155: cooling device 160: cooling water supply pump
161: cooling water supply pipe 170: reactor
171: ozone lamp 172: oxygen supply pipe
173: aerator 174: second discharge pipe
175: second circulation pipe 176: second circulation pump
177: ozone generator 178: outlet
179: manganese dioxide catalyst 180: reverse osmosis filter
181: reverse osmosis pump 182: third circulation pipe
183: third discharge pipe 185: mesh filter
V1 ~ V13: Valve

Claims (7)

Opening and closing port 111 for injecting the protective article on one side, and the first discharge pipe 112 for discharging the waste of the protective article at the bottom is formed, the heating path 110 is provided with a heater 113 on the lower outer peripheral surface; A first circulation pump (120) formed between the first discharge pipe (112) and the first circulation pipe (121) of the reduction furnace (110) to circulate the waste protection fluid to the reduction furnace (110); An ozone generator 130 connected to the first circulation pipe 121 and provided with an oxygen generator 131 for supplying ozone gas to the reducing path 110; A hydrogen peroxide tank 140 to which a hydrogen peroxide supply pump 141 and a hydrogen peroxide supply pipe 142 are connected to supply hydrogen peroxide to the reduction furnace 110; In the protective article disassembling facility configured to include a reactor 170 for removing radioactive material by supplying the protective article waste liquid discharged from the reduction furnace 110,
A steam cooling coil 151 is formed therein for supplying cooling water to the reduction furnace 110, and a cooling water discharge pipe 152 is formed at a lower end thereof, and a cooling device 155 is provided to adjust the temperature of the cooling water. Coolant tank 150; It is configured to further include a cooling water supply pump 160 formed between the cooling water discharge pipe 152 and the cooling water supply pipe 161 connected to the reduction path 110, the steam cooling coil 151 is a reduction path 110 High-performance functional protective equipment decomposition equipment, characterized in that the steam discharge pipe 153 for discharging the steam is configured to be connected.
The method of claim 1,
An aeration mechanism 173 is formed in the reactor 170 to aeration the air supplied through the ozone lamp 171 and the air supply pipe 172, and a second formed at the bottom of the reactor 170. The second circulation pump 176 is formed between the discharge pipe 174 and the second circulation pipe 175, the ozone generator 177 is connected to the second circulation pipe 175, the reaction furnace 170 The upper end of the high-functional functional protective equipment decomposition equipment, characterized in that the outlet 178 is formed to volatilize the volatile gas.
The method of claim 2,
The reverse osmosis pump 181 is formed in the second discharge pipe 174 of the reactor 170, and is reversed between the reverse osmosis pump 181 and the third circulation pipe 182 connected to the reactor 170. An osmotic filter 180 is provided to remove the acid from the waste of the protective article, and a mesh filter 185 is further provided between the reverse osmosis filter 180 and the reverse osmosis pump 181 to remove foreign substances in the waste of the protective article. However, at the bottom of the reverse osmosis filter 180, the third discharge pipe (183) is formed, the high sensitivity functional protective article decomposition equipment, characterized in that configured to finally discharge the protective fluid waste.
The method of claim 2,
Highly functional protective article decomposition equipment is characterized in that the reaction furnace 170 is configured to further include a manganese dioxide catalyst (179).
Maintaining the cooling water tank 150, the reduction furnace 110, and the water level of the reactor 170 at 85%, 25%, and 25%, respectively; Contaminating the protective article contaminated with the reducing path 110; Heating through the heater 113 until the temperature of the cooking furnace 110 becomes 100 ° C; When the heating is completed, hydrogen peroxide is injected into the reduction furnace 110, when the cooling water is supplied to control the temperature rise according to the hydrogen peroxide reaction, when the water level of the reduction furnace 110 reaches a 50% level, the ozone generator 130 ) Is activated to cause an ozone oxidation reaction in the cooking path 110; When the ozone oxidation reaction is completed, cooling the protective equipment waste liquid to 65 ° C. or less by the cooling water tank 150; The cooled protective article waste liquid is supplied to the reactor 170 to remove the hydrogen peroxide water and contaminants, volatile gas remaining in the protective article waste liquid; high sensitivity functional protective article decomposition comprising Way.
The method of claim 5, wherein if the temperature of the cooking furnace 110 exceeds 110 ℃, it is configured to further comprise the step of supplying and cooling the cooling water of the cooling water tank 150 to the cooling furnace 110 Disassembling method of functional protective article for. The aeration mechanism 173 and the manganese dioxide catalyst 179 for aeration of the air supplied through the ozone lamp 171 and the air supply pipe 172 are provided in the reactor 170. A part of the protective article waste liquid discharged through the second discharge pipe 174 formed at the bottom of the reactor 170 is circulated by the second circulation pump 176 and the second circulation pipe 175, and the rest is reverse osmosis pressure. It is circulated by the pump 181 and the third circulation pipe 182, the ozone generator 177 is connected to the second circulation pipe 175 and the reverse osmosis filter 180 to the third circulation pipe 182. Is provided with a step of removing contaminants, volatile gases of the hydrogen peroxide and the protective waste products; The protective article in which the contaminants and volatile gases of the hydrogen peroxide and the protective article waste solution are removed are finally discharged through the third discharge pipe 183 of the reverse osmosis filter 180 while being cooled to 20 to 50 ° C .; Method for disassembling high-functional functional protective article, characterized in that configured to include.

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