KR100989348B1 - Composition of portable welding gas and manufacturing process of reservoir - Google Patents
Composition of portable welding gas and manufacturing process of reservoir Download PDFInfo
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- KR100989348B1 KR100989348B1 KR1020080087307A KR20080087307A KR100989348B1 KR 100989348 B1 KR100989348 B1 KR 100989348B1 KR 1020080087307 A KR1020080087307 A KR 1020080087307A KR 20080087307 A KR20080087307 A KR 20080087307A KR 100989348 B1 KR100989348 B1 KR 100989348B1
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- butane
- propane
- acetone
- pentane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K5/00—Gas flame welding
- B23K5/006—Gas flame welding specially adapted for particular articles or work
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/3612—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with organic compounds as principal constituents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/362—Selection of compositions of fluxes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C1/00—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
- F17C1/005—Storage of gas or gaseous mixture at high pressure and at high density condition, e.g. in the single state phase
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/12—Arrangements or mounting of devices for preventing or minimising the effect of explosion ; Other safety measures
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/28—Propane and butane
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
본 발명은 촉매를 혼합하여 가열온도를 상승시킴으로써 용접을 할 때 화력을 증대시킬 수 있는 휴대용 용접가스 조성물에 관한 것이다.The present invention relates to a portable welding gas composition that can increase the thermal power when welding by mixing the catalyst to increase the heating temperature.
종래의 부탄가스는 연소시 가열온도가 낮아(800℃ 이하) 다양한 재질의 금속을 용접할 수 없는 문제점이 있는데, 이를 해결하기 위하여 본 발명은 부탄(Propane-isbutane-nbutane) 45~60 중량%, 프로판(Propane) 15~30 중량%, 아세톤(Acetone) 14~29 중량%, 펜탄(Pentane) 1~10 중량%, 1,2-디클로로프로판(1,2-Dichloropropane) 0.1~0.9 중량%, 메틸 카보네이트(Methyl carbonate) 0.1~0.5 중량% 가 용기의 내측에서 액상인 상태로 혼합된 것을 특징으로 하는 휴대용 용접가스 조성물을 제공한다.Conventional butane gas has a problem in that the heating temperature is low during combustion (800 ° C. or less), so that metals of various materials cannot be welded. To solve this problem, the present invention provides 45 to 60 wt% of butane (Propane-isbutane-nbutane), Propane 15-30 wt%, Acetone 14-29 wt%, Pentane 1-10 wt%, 1,2-Dichloropropane 0.1-0.9 wt%, Methyl It provides a portable welding gas composition, characterized in that 0.1 to 0.5% by weight of carbonate is mixed in a liquid state inside the container.
따라서 본 발명에 의하면, 프로판과 부탄의 혼합물에 촉매인 아세톤과 펜탄을 혼합함으로써 용접을 할 때 가열온도가 상승하여 다양한 재질의 금속을 신속하게 용접할 수 있는 효과가 있다.Therefore, according to the present invention, by mixing acetone and pentane as a catalyst in a mixture of propane and butane, the heating temperature is increased when welding, thereby rapidly welding metals of various materials.
용접, 가스, 프로판, 부탄, 아세톤, 펜탄 Welding, gas, propane, butane, acetone, pentane
Description
본 발명은 용접용 토치를 장착하여 사용할 수 있는 휴대용 부탄가스에 관한 것으로, 더욱 상세하게는 촉매를 혼합하여 가열온도를 상승시킴으로써 용접을 할 때 화력을 증대시킬 수 있는 휴대용 용접가스 조성물 및 용접가스가 주입된 용접용기의 제조방법에 관한 것이다.The present invention relates to a portable butane gas that can be used by mounting a welding torch, and more particularly, a portable welding gas composition and a welding gas which can increase the thermal power when welding by mixing a catalyst and raising a heating temperature. It relates to a method for manufacturing the injected welding vessel.
일반적으로 산소용접기를 사용하기에 적당하지 않은 환경에서 긴급하게 용접을 해야 할 경우에는 부피가 작은 휴대용 부탄가스 주입구에 용접용 토치를 연결하여 용이하게 사용하고 있다.In general, when an urgent welding is required in an environment that is not suitable for using an oxygen welding machine, a welding torch is easily connected to a small butane gas inlet port.
그러나, 이러한 종래의 부탄가스는 연소시 가열온도가 낮아(800℃ 이하) 다양한 재질의 금속을 용접하는데 있어서 한계가 있다.However, such a conventional butane gas has a limitation in welding metals of various materials due to low heating temperature (800 ° C. or less) during combustion.
본 발명은 상기와 같은 문제점을 해결하기 위한 것으로, 본 발명은 상호 작용을 일으키는 복수의 가스를 혼합하여 빠른 시간 내에 가열온도를 상승시킬 수 있는 휴대용 용접가스 조성물을 제공함에 그 목적이 있다.The present invention is to solve the above problems, the present invention is to provide a portable welding gas composition that can increase the heating temperature in a short time by mixing a plurality of gas causing interaction.
본 발명에 의한 휴대용 용접가스 조성물은 부탄(Propane-isbutane-nbutane) 45~60 중량%, 프로판(Propane) 15~30 중량%, 아세톤(Acetone) 14~29 중량%, 펜탄(Pentane) 1~10 중량%, 1,2-디클로로프로판(1,2-Dichloropropane) 0.1~0.9 중량%, 메틸 카보네이트(Methyl carbonate) 0.1~0.5 중량% 가 용기의 내측에서 액상인 상태로 혼합된 것을 특징으로 한다.Portable welding gas composition according to the present invention is 45 to 60% by weight of butane (Propane-isbutane-nbutane), 15 to 30% by weight of propane (Acetone), 14 to 29% by weight of acetone (Pentane) 1 to 10 Weight%, 1,2-dichloropropane (1,2-Dichloropropane) 0.1 to 0.9% by weight, methyl carbonate (Methyl carbonate) is characterized in that mixed in a liquid state inside the container.
본 발명에 따른 휴대용 용접가스 조성물에 의하면, 프로판과 부탄의 혼합물에 촉매인 아세톤과 펜탄을 혼합함으로써 용접을 할 때 가열온도가 상승하여 다양한 재질의 금속을 신속하게 용접할 수 있는 효과가 있다.According to the portable welding gas composition according to the present invention, by mixing acetone and pentane as a catalyst in a mixture of propane and butane, the heating temperature is increased to perform welding of metals of various materials quickly.
상기 본 발명에 의해 제공되는 휴대용 용접가스 조성물은 다음의 성분을 포 함하는 것을 특징으로 한다. The portable welding gas composition provided by the present invention is characterized by including the following components.
1. 부탄(Propane-isbutane-nbutane) --------------------- 45~60 중량%Butane (Propane-isbutane-nbutane) --------------------- 45 ~ 60 wt%
2. 프로판(Propane) ------------------------------------ 15~30 중량%2. Propane ------------------------------------ 15 ~ 30 wt%
3. 아세톤(Acetone) ------------------------------------ 14~29 중량%3. Acetone ------------------------------------ 14 ~ 29 wt%
4. 펜탄(Pentane) --------------------------------------- 1~10 중량%4.Pentane --------------------------------------- 1 ~ 10 wt%
5. 1,2-디클로로프로판(1,2-Dichloropropane) ------------- 0.1~0.9 중량%5. 1,2-Dichloropropane ------------- 0.1 ~ 0.9 wt%
6. 메틸 카보네이트(Methyl carbonate) ------------------- 0.1~0.5 중량%6.Methyl carbonate ------------------- 0.1 ~ 0.5 wt%
본 발명에 의한 조성물에 혼합되는 프로판(Propane)과 부탄(Butane)은 가압과 냉각에 의한 액상의 상태로 휴대할 수 있는 금속의 용기에 주입되는데, 상기 프로판(Propane)과 부탄(Butane)은 휴대용 가스용기에 사용되는 부탄가스의 일반적인 혼합물로서, 이미 공지된 기술임으로 자세한 설명은 생략한다.Propane (butane) and butane (Butane) mixed in the composition according to the present invention is injected into a metal container that can be carried in a liquid state by pressing and cooling, the propane and butane (Butane) is portable As a general mixture of butane gas used in the gas container, detailed description is omitted because it is a known technique.
상기 아세톤(Acetone)은 향기가 있는 무색의 액체로서 가열온도를 상승시키는 촉매의 역할을 수행하고, 가장 간단한 케톤(ketone)의 일종이므로 2차알코올인 이소프로판올을 산화시켜 생성하며, 유기용매로서 다른 유기물질과 잘 섞인다.Acetone (Acetone) is a colorless liquid with a scent, serves as a catalyst to increase the heating temperature, and is produced by oxidizing isopropanol, a secondary alcohol, because it is one of the simplest ketones, and other organic as an organic solvent Mix well with the material.
이때, 상기 케톤(ketone)은 탄소가 산소와 이중결합을 하고 있고, 그 탄소가 또 다른 두 개의 결합자리를 가지고 있어 두 알킬기(alkyl group)들과 결합하고 있는 특징이 있으며, 아세톤의 화학식은 CH3COCH3이다. In this case, the ketone is characterized in that the carbon has a double bond with oxygen, the carbon has another two bonding sites and is bonded to two alkyl groups, and the chemical formula of acetone is CH 3 is COCH 3 .
아세톤은 양쪽에 하나씩 총 두(di) 개의 메틸기(metyl)와 결합하고 있기 때문에 디메틸케톤(dimethylketone)이라고 부르기도 한다. 또 탄소가 총 세 개인 프로판(propane)에서 변형된 케톤(ketone)이라는 의미에서 프로판온(propanone)이라고 부르기도 한다.Acetone is sometimes called dimethylketone because it binds to a total of two methyl groups, one on each side. It is also called propanone in the sense of a ketone modified from a total of three carbon propanes.
아세톤의 분자량은 58.08으로, 향기가 있는 무색의 액체이다. 물에 잘 녹으며, 유기용매로서 다른 유기물질과도 잘 섞인다. 그래서 물로 세척이 되지 않는 물질을 아세톤으로 처리하면 쉽게 세척할 수 있어 일상 생활에 많이 사용된다. 예를 들어, 페인트를 지우는 데 쓰이기도 하며, 손톱에 바른 에나멜을 지우는 데에도 많이 쓰인다. 그리고 인화성이 강해 불이 잘 붙는다.Acetone has a molecular weight of 58.08, which is a colorless liquid with a scent. Soluble in water and mix well with other organic materials as organic solvent. So, if you can not wash the material with acetone, it can be easily washed and used a lot in daily life. For example, it can be used to remove paint, and it can also be used to remove enamel applied to nails. And it is flammable and catches fire well.
한편, 펜탄(Pentane)은 용접가스의 냉각제어를 하는 것으로서, 메탄계탄화수소에 속하는 n-펜탄 및 그 이성질체인 이소펜탄과 네오펜탄의 총칭으로, 상쾌한 냄새가 나는 무색의 액체인데, 석유에 함유되어 있다. 추출용제나 마취제 등으로 사용된다.Pentane, which controls cooling of welding gas, is a generic term for n-pentane belonging to methane-based hydrocarbons and isomers such as isopentane and neopentane. have. Used as an extraction solvent or anesthetic.
화학식은 CH3(CH2)3CH3. 상쾌한 냄새가 나는 무색 액체이며 녹는점 -129.723 ℃, 끓는점 36.074 ℃이다. 많은 용매에 녹는다. n-펜탄은 펜탄이라고도 하며 석유에 많이 함유되어 있다. 천연가스 ·천연가솔린 ·직류(直溜)가솔린 등으로부터 분류하거나, 2-브롬펜탄에 부틸에테르 중의 마그네슘으로 분해시켜 얻는 그리냐르시약(試藥)을 황산으로 분해한다. 추출용제로 사용되는 외에, 저온온도계나 마취제에 도 사용된다. 또 이소펜탄 (CH3)2CHCH2CH3은 끓는점이 30 ℃이며, 네오펜탄 (CH3)4C은 끓는점이 9 ℃인데, 이소펜탄은 증기압(蒸氣壓)이 높고 앤티노크성(性)도 높으므로 고옥탄가(價) 가솔린의 성분으로 중요시된다.Chemical formula is CH 3 (CH 2 ) 3 CH 3 . It is a colorless liquid with a pleasant smell. It has a melting point of -129.723 ℃ and a boiling point of 36.074 ℃. Soluble in many solvents. N-pentane is also known as pentane and is found in petroleum. The Grignard reagent obtained by classifying from natural gas, natural gasoline, direct gasoline, or the like or by decomposing 2-brompentane with magnesium in butyl ether is decomposed with sulfuric acid. In addition to being used as an extraction solvent, it is also used in cryogenic thermometers and anesthetics. In addition, isopentane (CH 3 ) 2 CHCH 2 CH 3 has a boiling point of 30 ° C., and neopentane (CH 3 ) 4 C has a boiling point of 9 ° C. It is also high and is considered important as a component of high octane gasoline.
또한, 1,2-디클로로프로판(1,2-Dichloropropane)은 세척용재로 많이 사용되는데, 지방족 염소계 탄화수소 중에서 디클로로프로판은 대체로 오존파괴성이 거의 없으며, 저독성이고 세정력도 우수한 것으로 평가되고 있으며, 그 중에서도 1,2-디클로로프로판이 가장 우수한 것으로 평가되고 있다. 화학식은 CH3CCl2NO2 ; C3H7Cl2 로서, 본 발명에서는 각각의 혼합물이 서로 잘 섞일 수 있도록 용매의 역활을 수행한다. In addition, 1,2-dichloropropane (1,2-Dichloropropane) is widely used as a cleaning material, among the aliphatic chlorine-based hydrocarbons, dichloropropane is generally low in ozone degradability, low toxicity and excellent cleaning power, among which 1 , 2-dichloropropane is said to be the best. Formula is CH 3 CC l2 NO 2 ; A C 3 H 7 C l2, the present invention performs the role of the solvent to each of the mixtures can be mixed well with each other.
또한, 메틸 카보네이트(Methyl carbonate)는 대기압에서 인화점이 낮은 저점도 용매로서, 복수의 액상이 혼합된 상태에서 전기 화학적으로 용접가스를 안정화시킨다. 화학식이 CO(OCH3)2 ; C3H6O3 이며 인화점은 19℃ 이고, 비중(물=1)은 1.1 이다. 증기밀도(공기=1)는 3.1 이며, 끓는점은 88.9℃ 이다.In addition, methyl carbonate (Methyl carbonate) is a low viscosity solvent having a low flash point at atmospheric pressure, electrochemically stabilizes the welding gas in the state of mixing a plurality of liquid phases. The formula is CO (OCH 3 ) 2 ; C 3 H 6 O 3 Flash point is 19 ℃, specific gravity (water = 1) is 1.1. The vapor density (air = 1) is 3.1 and the boiling point is 88.9 ° C.
이와 같이 구성된 휴대용 용접가스 조성물은 다음의 순차적인 공정을 통해 용접용기에 주입된다. The portable welding gas composition thus constructed is injected into the welding vessel through the following sequential process.
먼저, 액상의 14~30 중량% 아세톤과 1~10 중량% 펜탄의 혼합물을 용접용기의 내측에 주입하는 제1공정이 진행된다. First, a first process of injecting a mixture of liquid 14-30 wt% acetone and 1-10 wt% pentane into the welding vessel is performed.
상기 아세톤과 펜탄은 촉매 및 냉각제어를 위해 사용되는 것이므로, 연료 가스 성분과의 충분한 혼합을 위해 용접용기의 내측에 먼저 주입되는 것이 바람직하다. Since acetone and pentane are used for catalyst and cooling control, it is preferable to first inject the inside of the welding vessel for sufficient mixing with the fuel gas components.
이어서, 상기 용접용기를 밀폐하기 위해 크램핑(clamping)하고 상측에 밸브를 결합시키는 제2공정이 진행된다. Subsequently, a second process of clamping to seal the welding vessel and coupling the valve to the upper side is performed.
이때, 상기 밸브는 종래의 휴대용 부탄가스 용기와 동일한 구조로서, 중앙부를 내측으로 밀어넣으면 내부의 용접가스가 외측으로 방출되고, 일정 압력 이상으로 가압하여 내부로 다른 가스를 유입할 수 있게 된다. In this case, the valve has the same structure as a conventional portable butane gas container, and when the center portion is pushed inward, the welding gas is discharged to the outside, and the valve is pressurized to a predetermined pressure or more to allow other gas to flow therein.
상기 크램핑은 종래의 휴대용 가스 장치에서 주입된 가스의 유출을 방지하기 위해 별도의 자동화 설비를 통해 이루어지는 공지의 기술이므로, 이하 추가 설명은 생략한다. Since the clamping is a known technique made through a separate automation facility to prevent the outflow of the gas injected from the conventional portable gas device, further description will be omitted below.
이어서, 상기 밸브를 통해 일정한 가압을 하면서 액상의 45~60 중량% 프로판과 15~30 중량% 부탄의 혼합물을 주입하는 제3공정이 진행된다. Subsequently, a third process of injecting a mixture of 45 to 60 wt% propane and 15 to 30 wt% butane in a liquid phase is performed while applying constant pressure through the valve.
또한, 제3공정이 완료된 후, 상기 밸브를 통해 액상의 0.1~0.9 중량% 1,2-디클로로프로판, 0.1~0.5 중량% 메틸 카보네이트의 혼합물을 추가적으로 주입한다. In addition, after the third process is completed, a mixture of 0.1 to 0.9 wt% 1,2-dichloropropane, 0.1 to 0.5 wt% methyl carbonate in the liquid phase is additionally injected through the valve.
이로써 용접을 할 때 가열온도가 약1,500℃까지 상승하여 화력이 증대됨으로써 다양한 재질의 금속을 신속하게 용접할 수 있다.Thus, when welding, the heating temperature rises to about 1,500 ° C., thereby increasing the thermal power, so that metals of various materials can be quickly welded.
한편, 본 발명에 의한 용접 가스는 용기 내부에서 액상으로 존재하며, 외부로 배출되면서 공기압에 의해 가스로 변환되는데, 액상의 용접 가스가 이동시의 흔들림 또는 외부 충격에 반응하는 것을 방지하기 위해 용기에는 위 제1공정 이전 단계에서 스폰지 등의 완충재를 삽입하여 제조할 수도 있다. On the other hand, the welding gas according to the present invention is present in the liquid phase inside the container, is converted to the gas by the air pressure while being discharged to the outside, in order to prevent the liquid welding gas from reacting to the shaking or external impact during movement, It may be prepared by inserting a cushioning material such as a sponge in the step before the first process.
상기와 같은 본 발명은 상술한 특정의 실시 예에 한정되지 아니하며, 청구범위에서 청구하는 본 발명의 요지를 벗어남이 없이 당해 발명이 속하는 분야에서 통상의 지식을 가진 자라면 누구든지 다양한 변경 실시가 가능할 것이다.The present invention as described above is not limited to the above-described specific embodiments, and any person having ordinary skill in the art to which the present invention pertains may make various changes without departing from the gist of the present invention as claimed in the claims. will be.
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JPH106009A (en) * | 1996-06-19 | 1998-01-13 | Komatsu Ltd | Shield gas welding apparatus used in common for heating device |
JP2007190586A (en) | 2006-01-18 | 2007-08-02 | Mitsubishi Heavy Ind Ltd | Welding method, and manufacturing method of liquefied gas tank |
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JPH106009A (en) * | 1996-06-19 | 1998-01-13 | Komatsu Ltd | Shield gas welding apparatus used in common for heating device |
JP2007190586A (en) | 2006-01-18 | 2007-08-02 | Mitsubishi Heavy Ind Ltd | Welding method, and manufacturing method of liquefied gas tank |
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