KR100954261B1 - Equipment and method for treating ballast water of ship using ionization and carbonate - Google Patents

Abstract

The present invention relates to a ballast water carbonate treatment apparatus and treatment method of a ship, the ballast tank; An acidic ionized water group for acidifying seawater filled in the ballast tank; A carbon dioxide bubble generator for generating carbon dioxide into fine bubbles in the ballast tank filled with sea water; Ballast water of a ship including a pressure maintaining valve for increasing the pressure in the ballast tank so that carbon dioxide supplied to the air bubbles in the ballast tank can be carbonized by reaction with seawater, and a catalyst adder for supplying a catalyst of carbonic anhydrase A technical configuration of a carbonate ion treatment device is disclosed.

In addition, the present invention by supplying carbon dioxide to the ballast water to be filled in the ballast tank to carbonize the ballast water and to distribute the carbon dioxide to the sea level in the ballast tank to sterilize and suffocate, carbonic anhydrase which is a catalyst in the ballast water The present invention discloses a technical configuration of a method for treating ballast water carbonate in a vessel which adds and forms a pressure higher than atmospheric pressure in a ballast tank to promote the reaction between carbon dioxide and ballast water, and lowers the acidity by acidifying the ballast water.

Vessel, ballast water, seawater, carbonation ionization, acidic ionization, carbonation

Description

Ballast water carbonate treatment system and treatment method for ships {EQUIPMENT AND METHOD FOR TREATING BALLAST WATER OF SHIP USING IONIZATION AND CARBONATE}

The present invention relates to a treatment apparatus and a treatment method for removing foreign species contained in ballast water of a ship, and more particularly, acidic ionization and carbonation of ballast water used in a ship, and thus acidity (pH). The present invention relates to a ballast water carbonate treatment apparatus and a treatment method of a ship which sterilizes foreign species by lowering and steals oxygen and removes oxygen from their respiratory organs.

In general, the ballast applied to the ship (ballast) is to play the role of weight of the ship for ship safety, means that the ballast tank is provided on the bottom and side sections of the ship and fill the fresh water or sea water, Water filled in the ballast tank is called ballast water.

Such ballast water is introduced into the ballast tank of the ship at the starting point and filled and discharged from the destination after the ship is operated.

However, the ballast water contains a variety of organisms, such as fish and plant planktonic bacteria, and because the ballast water moves more than 3000 species of marine organisms around the world during the day, the balance of food chains is balanced by these species. Breaking problems and a number of damages worldwide have been reported.

Vessel ballast water treatment apparatus has been proposed to reduce such damage, but the conventional technology for ballast water treatment apparatus removes foreign species and aquatic organisms existing in ballast water mainly using electric ozone, chemicals and ultraviolet rays. As a technique to use, there is a problem that all harmful effects exist, especially when using chemicals has a problem that causes another marine environment destruction.

In addition, since the vessel ballast water treatment apparatus according to the prior art requires many mechanical devices, it is not only structurally complicated but also expensive to install, and it is not easy to develop a technology capable of sterilizing and removing all kinds of marine organisms. Currently, the company is conducting R & D in Korea, Germany, Japan, the United Kingdom and Norway, as well as Korea, which leads the global shipbuilding market.

In particular, through the signing of an international agreement through the International Maritime Organization (IMO), the installation of ballast water treatment systems has been mandatory for all ships built since 2009. The shipbuilding industry is making a lot of efforts, and there is a demand for the development of a device that is simple and can increase the processing efficiency.

The present invention is to acidify the ionized and carbonated ballast water of the vessel to lower the acidity to sterilize the alien species and aquatic organisms present in the ballast water and take oxygen from their respiratory tract to suffocate and remove It is an object of the present invention to provide a ballast water carbonate treatment apparatus and treatment method for a vessel.

In addition, the present invention is not only harmful to treat foreign species and aquatic organisms present in the ballast water, but also to eliminate the risk of environmental pollution and destruction, and can increase the treatment efficiency even with a simple configuration, It is to provide a ballast water carbonate treatment apparatus and treatment method of a ship to pursue economics.

Ballast water carbonate treatment apparatus of the ship according to the present invention and the ballast tank; An acidic ionized water for acidifying the seawater filled in the ballast tank to supply acidic ionized water; A carbon dioxide bubble generator for generating carbon dioxide into fine bubbles in the ballast tank filled with sea water; And a pressure retaining valve for raising the pressure in the ballast tank so that carbon dioxide supplied to the ballast bubbles in the ballast tank can be carbonized by reaction with seawater, and a catalyst adder for supplying a catalyst of carbonic anhydrase. .

Ballast water carbonate treatment method of the vessel according to the present invention by supplying carbon dioxide to the ballast water to be filled in the ballast tank to carbonate the ballast water and distribute the carbon dioxide to the sea level in the ballast tank to sterilize and suffocate, the ballast Carbonate anhydrase, which is a catalyst, is added to the water and a pressure higher than atmospheric pressure is formed in the ballast tank to promote the reaction between carbon dioxide and the ballast water, and the acidification of the ballast water lowers acidity.

The present invention has sterilizing power by acidification of seawater and removes oxygen by carbonation of seawater, so it is possible to suffocate and remove foreign species or aquatic organisms contained in seawater (ballast water). In the treatment of paper and aquatic organisms, carbon can be disposed of in the air and can be treated without any hazards. Since no chemicals are added, it can eliminate the risk of environmental pollution and destruction, and it is a foreign species contained in ballast water. However, the treatment efficiency of aquatic organisms can be greatly increased, thereby preventing the destruction of food chains and ecosystems.

In addition, the carbonated seawater oxidizes the debris in the ballast tank, thereby maintaining cleanliness, and eliminating the need for complicated mechanical devices, thereby reducing the installation and facility costs for the treatment device. It can also be installed on ships, and economics can be pursued.

Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

1 is an exemplary view showing a vessel ballast water carbonate treatment device according to an embodiment of the present invention, Figure 2 is shown to explain a vessel ballast water carbonate treatment device according to another embodiment of the present invention It is an illustration.

As shown in FIG. 1, the vessel ballast water carbonate ion treatment apparatus according to the present invention acidifies the ballast tank 110 and seawater (ballast water) filled in the ballast tank 110 to supply acidic ionized water. Ionizer 120, the carbon dioxide bubble generator 130 for generating carbon dioxide into the micro-bubbles in the ballast tank 110 filled with sea water, and carbon dioxide supplied to the air bubbles in the ballast tank 110 reacts with the sea water to carbonize It consists of a configuration including a pressure maintaining valve 140 for increasing the pressure in the ballast tank 110 and a catalyst adder 150 for supplying a catalyst of carbonic anhydrase.

The acidic ionizer 120 is built in the ballast water supply pipe 160 connected to the ballast tank 110 to supply seawater with salt to the ballast tank 110, and acidified by making the seawater supplied as ballast water into acidic ionized water. The ballast tank 110 is filled with the ballast water (sea water).

The carbon dioxide bubble generator 130 is installed on the lower side of the ballast tank 110, and receives carbon dioxide from the carbon dioxide filled carbon dioxide tank 170 to generate a bubble, bubbles of carbon dioxide in the ballast tank 110 filled with sea water By supplying the furnace, the reaction area with seawater can be increased.

The pressure maintaining valve 140 is disposed at the upper end of the ballast tank 110 so as to form and maintain a pressure higher than atmospheric pressure in the ballast tank 110, and the ballast tank through the catalyst adder 150. Along with the carbonic anhydrase added in the 110, the carbon dioxide supplied to the bubbles reacts well with the seawater to be carbonated.

As shown in FIG. 2, the catalyst coating plate 180 coated with the carbonic anhydrase in place of the catalyst adder 150 may be installed in the ballast tank 110 to promote the reaction of carbon dioxide and seawater. It can also be configured to do so. In this case, it is preferable to increase the treatment efficiency by allowing the reaction between the carbon dioxide and the seawater to be made in the ballast tank 110 as a whole by installing on the passage and the sea surface through which the carbon dioxide bubbles are generated and the seawater surface.

Referring to the operation of the vessel ballast water carbonate treatment apparatus according to the present invention with such a configuration as follows.

The seawater (ballast water) is supplied into the ballast tank 110 through the ballast water supply pipe 160. At this time, the seawater supplied to the ballast tank 110 is acidified by passing through the acidic ionizer 120 to be filled in the ballast tank 110 and the acidified seawater disinfects and sterilizes microorganisms present in the ballast tank 110. Done.

Here, since the seawater is rich in salt, there is no electrolyte required for ionization, and it is easily acidified and ionized while passing through the acidic ionizer 120.

When seawater is filled in the ballast tank 110, the pressure maintaining valve 140 is adjusted to form a pressure higher than atmospheric pressure in the ballast tank 110, and carbonic anhydride, which is a catalyst in seawater, is added to the catalyst adder 150. Add enzyme This is to ensure that the carbon dioxide generated in the micro-bubbles in the ballast tank 110 after the reaction with the sea water to be dissolved so that the environmental conditions that can be carbonated.

Subsequently, while supplying carbon dioxide into the ballast tank 110 through the carbon dioxide bubble generator 130, the carbon dioxide is generated as micro bubbles so that carbon dioxide is dissolved in seawater (S4).

At this time, as the carbon dioxide is generated by bubbles, the reaction area with seawater can be increased, and since carbonic anhydrase is added to the seawater, the reaction rate for carbonation is accelerated.

In addition, when the catalyst coating plate 180 is installed in the ballast tank 110 instead of the catalyst adder 150, the carbonic anhydrase coated on the catalyst coating plate 180 acts as a catalyst, thereby reacting carbon dioxide with seawater. Make it well and let it react to the sea level.

Therefore, the seawater filled in the ballast tank 110 has a large amount of carbonic acid and carbon dioxide having a higher specific gravity than air remains distributed over the sea level of the ballast tank 110 and blocks oxygen from melting on the sea surface.

At this time, the carbonated sea water also serves to oxidize debris existing in the ballast tank 110, thereby exerting a purification function to clean the ballast tank 110.

On the other hand, when explaining the ballast water carbonate treatment method according to the present invention for removing foreign species and aquatic life contained in the ballast water as follows.

When carbon dioxide is supplied to the ballast water (sea water) filled in the ballast tank, the carbon dioxide reacts with the ballast water so that the ballast water is carbonated and the carbon dioxide stays distributed over the sea level in the ballast tank, thereby providing sterilization and asphyxiation. .

At this time, when the carbon dioxide supplied to the ballast water is generated as fine bubbles, the reaction area between the ballast water and the carbon dioxide can be further increased, and acidification is also partially progressed by supplying carbon dioxide.

In addition, when acidic ionization of the ballast water supplied with carbon dioxide using an acidic ionizer or the like, the acidity (pH) of the ballast water is further lowered to add sterilization.

Furthermore, when carbonic anhydrase, which is a catalyst, is added to the ballast water and a pressure higher than atmospheric pressure is formed in the ballast tank, the reaction rate between carbon dioxide and seawater can be increased to promote the reaction.

Therefore, according to the treatment apparatus and the treatment method of the present invention, since it has a sterilizing power by acidification of seawater and removes oxygen by carbonation of seawater, it is possible to sterilize foreign species or aquatic organisms existing in seawater (ballast water). Not only can it be removed by suffocation, but also it can be treated without any harm in treating foreign species or aquatic organisms, eliminating the concern of environmental pollution and destruction, and greatly improving the treatment efficiency of foreign species or aquatic organisms compared to the existing ones. It becomes possible.

1 is an exemplary view showing a ballast water carbonate treatment apparatus of a ship according to an embodiment of the present invention.

Figure 2 is an exemplary view showing a ballast water carbonate treatment apparatus of a ship according to another embodiment of the present invention.

Explanation of symbols on the main parts of the drawings

110: ballast tank 120: acidic ionizer

130: carbon dioxide bubble generator 140: pressure holding valve

150: catalyst addition 160: ballast water supply pipe

170: carbon dioxide tank 180: catalyst coating plate

Claims (7)

In the processing apparatus for processing the foreign species or aquatic organisms contained in the ballast water (sea water) of the ship, Ballast tanks; An acidic ionized water for acidifying the seawater filled in the ballast tank to supply acidic ionized water; A carbon dioxide bubble generator for generating carbon dioxide into fine bubbles in the ballast tank filled with the acidified seawater; A pressure holding valve for increasing pressure in the ballast tank so that carbon dioxide supplied to the ballast bubbles in the ballast tank can be carbonized by reacting with sea water; Ballast water carbonate treatment apparatus of the ship comprising a catalyst adder for supplying a catalyst of carbonic anhydrase. The method of claim 1, Ballast water carbonate treatment apparatus of the ship characterized in that the catalyst coating plate coated with carbonic anhydrase in place of the catalyst adder is installed in the ballast tank to promote the reaction of carbon dioxide and seawater. In the treatment method for treating the foreign species or aquatic organisms contained in the ballast water (sea water) of the ship, Supplying carbon dioxide to the ballast water filled in the ballast tank to carbonize the ballast water and distributing carbon dioxide over the sea level in the ballast tank to sterilize and suffocate, The carbon dioxide supplying step of the ballast water carbonate treatment method of the ship characterized in that to increase the reaction area between the ballast water and carbon dioxide by generating the carbon dioxide supplied to the ballast water as fine bubbles. The method of claim 3, wherein The carbon dioxide supplying step further includes a catalyst adding step of adding a carbonic anhydrase as a catalyst to the ballast water. The method of claim 3, wherein The carbon dioxide supplying step further comprises a pressurizing step to promote a reaction between the carbon dioxide and the ballast water by forming a pressure higher than atmospheric pressure in the ballast tank. delete The method of claim 3, wherein Ballast water carbonate treatment method of the ship further comprising an ionization step to lower the acidity (pH) by the acidification of the ballast water flowing into the ballast tank using an acidic ionizer to sterilize.

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