KR100880387B1 - Ion refining oil manufacturing system using an resonance device and refining method of waste oil using the system - Google Patents

Abstract

The present invention relates to an ion refined oil production system using a resonant resonance device and a waste oil purification method using the same. More particularly, the present invention relates to a filtration device for removing solids in a waste flow rate, and to store filtered waste oil and to activate water in the waste oil. A primary storage unit, a resonant resonance device for converting dissolved metal ions into crystalline minerals, lowering the tension and viscosity of the waste oil particles into active waste oil, and distributing the flow rate of the active waste oil and discharging it from the fractionation distillation unit. A flow rate distribution and preheating means for preheating the active waste oil using the waste gas to be used, a fractionation distillation apparatus for separating water and light oil contained in the active waste oil, a fine particle removing apparatus for removing solid particles from the active waste oil and separating residual moisture; Secondary storage for storing refined oil from which fine particles have been removed and shipping refined waste oil through a fine impurity removal module Ion with a resonant resonance apparatus is configured to include a functional biofilter apparatus for purifying a waste gas coming from the preheating means refined oil to the preparation system and waste oil refining method using the same.

Resonance / Resonance Device, Activated Waste Oil, Ion Refinery Oil

Description

ION REINING OIL MANUFACTURING SYSTEM USING AN RESONANCE DEVICE AND REFINING METHOD OF WASTE OIL USING THE SYSTEM}

1 is a schematic overall configuration diagram according to an embodiment of the ion refined oil production system according to the present invention,

Figure 2 illustrates in more detail a preferred configuration embodiment of a multi-stage filtration module device according to the present invention,

Figure 3 illustrates in more detail a side view of the multi-stage filtration module device according to the present invention,

Figure 4 illustrates in more detail the filtration process of the multi-stage filtration module device according to the present invention,

Figure 5 shows various forms of the filtering network used in the multi-stage filtration module device according to the present invention,

Figure 6 illustrates a preferred configuration embodiment of the primary storage unit according to the present invention in more detail,

Figure 7 illustrates in more detail a preferred configuration embodiment of a resonance resonance apparatus according to the present invention,

Figure 8 illustrates in more detail a preferred embodiment of the flow distribution means according to the invention,

Figure 9 illustrates in more detail a preferred configuration embodiment of the fractional distillation apparatus according to the present invention,

Figure 10 illustrates in more detail a preferred embodiment of the particulate removal device according to the present invention,

11 illustrates a preferred configuration embodiment of the secondary storage unit according to the present invention in more detail.

12 illustrates a preferred configuration embodiment of the functional biofilter according to the present invention in more detail.

13 is a block diagram of a method for purifying waste oil using an ion refined oil production system according to the present invention.

<Explanation of symbols for the main parts of the drawings>

100: waste oil 200: multi-stage filtration module device

300: primary storage unit 400: resonant resonance device

500: flow distribution device 600: fractional distillation device

700: particulate removal device 800: secondary storage

900: functional biofilter 1000: ion purification oil

The present invention relates to an ion refined oil production system using a resonant resonance device and a waste oil purification method using the same. More specifically, the present invention relates to a filtration device for removing solids in a waste stream, and to store filtered waste oil and activating water in the waste oil. A primary storage unit, a resonant resonance device for converting dissolved metal ions into crystalline minerals, lowering the tension and viscosity of the waste oil particles and converting them into active waste oil, and distributing the flow rate of the active waste oil and discharged from the fractionation distillation unit. A flow distribution device that preheats the active waste oil using waste gas, a fractionation distillation device that separates the water and light oil contained in the active waste oil, a particle removal device that removes the solid particles from the active waste oil and separates the remaining water, Secondary storage unit for storing the removed refined oil and discharge the purified waste oil through the fine impurity removal module, and preheated water Ion refined oil using a resonant resonance apparatus configured contain functional biofilter for purifying waste gases from the system relates to the production and waste oil refining method using the same.

Conventionally, as a method of preparing an ionic refined oil, a chemical treatment method, which is a general ionic refining method, is used. In this method, a chemical ion is reacted with a floating metal ion without precipitation in waste oil using a chemical agent to react the metal ion. By making the insoluble metal salts to have a large specific gravity to precipitate after separation. However, when the metal salt is removed by simple precipitation, as in the conventional method of preparing an ion refined oil, since a mixture layer of an aqueous solution of an anion and an oil (Oil) exists, productivity decreases significantly as the settling time increases, so that the temperature is increased. It is necessary to lower the tension and viscosity of the waste oil particles such as waste lubricating oil in order to distill water at 120 ° C. or higher and to facilitate metal salt formation and precipitation by centrifugal separator.

The ion purification method is simple and all processes are carried out at 120 ~ 150 ℃, so there is little risk of fire and explosion and low facility investment cost, but the stirring device and reaction for reacting ammonium phosphate, which is the most commonly used chemical, Reaction time is required. This is due to the difficulty of controlling the amount of chemicals and reaction time introduced every time due to the irregularities of the recovered waste oil, which is not perfect purification.Ion refined oil with unreacted chemicals and heavy metal ions produced after the process It is precipitated by the reaction at and may cause the production of low purity ion refined oil.

In addition, in order to solve this problem, the surfactant may be attached together with the chemical to form the micelle in the waste oil and to combine the chemical and the heavy metal ion in the micelle, but the role of the surfactant is not sufficient to obtain a great effect. It was.

Currently, the batch type of ion refined oil process has a low productivity, and thus, there is a limit in controlling the amount and reaction time of chemicals while preparing the ion refined oil using a continuous process. In addition, chemicals such as ammonium diphosphate to be used have a problem of corrosion of the rubber part forming the valve of the device because ammonium and the like other than phosphate to combine with metal ions have a strong alkalinity.

Meanwhile, looking at the most important water removal process in the production of ion refined oil, Korean Patent Publication No. 10-0255929 purifies the waste oil by vacuum vacuum distillation process 50 ~ 60 when removing water in the ion refined oil manufacturing process consisting of a pretreatment process It is disclosed to remove the precipitate and excess water by centrifugation after evaporating at 120 ° C. for about 2 hours by reducing the pressure of Torr. The total process time is about 4 hours. This is because the water in the waste oil is present in the oil in a cluster state where hundreds to thousands of water molecules are agglomerated and does not evaporate easily. Since the temperature rises through contact with the inner wall of the double wall reactor, a continuous transfer device is required through stirring. And, there is a problem in that the process time for water distillation is high because the tension and viscosity of the waste oil particles are high.

The present invention has been made to solve the above problems of the prior art, and an object of the present invention is to elute the metal ions suspended in the waste oil as crystalline metal molecules through a resonance and resonance apparatus, Ion refined oil production system that can be easily settled by lowering the viscosity, and can easily evaporate by converting the water on the cluster in the waste oil into active water releasing energy, thereby reducing the process time It is to provide a waste oil purification method using the same.

Ion refining oil production system according to the present invention for achieving the above object is a multi-stage filtration module device is installed in a plurality of layers forming a multi-layer layer structure to remove the solids, such as sludge in the waste oil to convert to filtered filtration oil; A primary storage unit for storing the filtered refined oil and converting the water molecules of the cluster contained in the filtered refined oil into activated water releasing energy by activating by radiation wavelength; Dissolved minerals or metal ions in the filtration refinery oil in which the water molecules are converted into active water are converted into crystalline minerals or metals by the movement of electrons by a voltage pulse electric field, and fine air is mixed with the filtration refinery oil to refine the refined oil particles. Resonance resonance device to convert the active waste oil by lowering the tension and viscosity of the; A flow rate distribution means for regulating the flow rate for circulating the active waste oil to the primary storage unit and the flow rate for supplying to the fractionation distillation apparatus at a predetermined ratio, and preheating the active waste oil with the heat of the waste gas generated in the fractionation distillation apparatus; A fractionation distillation apparatus for vaporizing and separating water and light oil in the active waste oil and discharging waste gas; A fine particle removing device for removing fine particles such as crystalline minerals or metals in the waste oil from which water is removed from the fractional distillation device and residual water; And a secondary storage unit for storing the refined oil from which the fine particles have been removed in the fine particle removing device and removing residual fine impurities at the final outflow.

Waste oil purification method using the ion refined oil production system according to the present invention, the multi-stage filtration step of removing solids such as sludge in the waste oil; Active water conversion step of converting the water contained in the waste oil into active water by releasing the radiation wavelength of 6 ~ 11㎛ wavelength that is the resonance absorption wavelength of water molecules through the far-infrared lamp while primaryly storing the filtered waste oil and stirring; An active waste oil conversion step of converting dissolved minerals or metal ions dispersed in the waste oil into crystalline minerals or metals through a resonance resonance device to lower the tension and viscosity of the waste oil particles; A flow rate distribution step of distributing and converting the converted active waste oil into a predetermined amount fractionation distillation apparatus, and preheating the active waste oil using waste gas; A fractionation distillation step of fractionally distilling the water and the light fraction contained in the active waste oil by a heat medium to produce a purified oil; A fine particle removing step of removing solid particles such as crystalline minerals or metal substances in the water refining oil; Oil and water separation step of separating and removing the residual water in the water refining oil; And an ion refining oil commercialization step of rectifying the separated oil and removing and commercializing impurities through a fine impurity removal module.

Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.

Figure 1 schematically shows the overall configuration according to an embodiment of the ion refined oil production system according to the present invention.

As shown, the ion-refining oil production system according to the present invention includes a multilayer filtration module device 200 for removing solids such as sludge in the collected waste oil, and the waste oil in which the solids are removed and contained in the waste oil. Primary storage unit 300 for activating molecules and converting them into active substance molecules, and converting dissolved minerals or metal ions in the waste oil into crystalline minerals or metals, and reducing the tension and viscosity of the waste oil particles into active waste oil. The resonance resonance apparatus 400 for converting, the flow distribution means 500 for distributing the flow rate of the active waste oil at a predetermined ratio and preheating the waste gas, and separating the water and light oil in the preheated waste oil from the oil component. A fractionation distillation apparatus 600 for storing the particulate matter, a particulate removal apparatus 700 for removing particulate minerals or metal substances in the oil and removing residual water, and a refined refined oil, and storing ion refined oil ( It is configured to include a secondary storage unit 800 to remove the residual fine impurities during the discharge of 1000. It further comprises a functional biofilter 900 for purifying the waste gas containing the water and light oil from the fractional distillation apparatus.

Figure 2 shows a preferred configuration embodiment of a multi-stage filtration module device according to the present invention. The multi-stage filtration module device 200, as shown, a plurality of connecting grooves formed on the inner surface of the exterior 210 and the oblique line of about 20 to 40 ° and one side wall is made of an open polygonal tube ( 220) and a plurality of filter nets 230 which are inserted into the connecting grooves and have a planar or embossing (_∩_∩_) shape having voids of 2 to 20 mm or less, and are installed at the lower part of the filter net and move back and forth. Solids desorption means (240) having a spray nozzle for injecting air, and the separation wall 250 to fill the open surface after the filter network is inserted into the connecting groove, and to connect the pipe of the other device It is configured to include a connecting means 260 coupled to the upper and lower of the appearance.

At this time, the appearance 210 is preferably formed wider than the inlet pipe through which waste oil is introduced to remove solids in more waste oil in a short time, the filter net 230 is shown in Figure 5, It may be configured in various forms such as flat, lower embossing (230a, 230f), upper embossing (230b, 230e), upper and lower embossing mixing (230c, 230d), egg plate (230g). In addition, the plurality of the filtering network is installed in a multi-layer structure inside the outer appearance, it is preferable that the multi-layered filtering network is configured to have a smaller pores as installed in the lower portion so that sequential filtration can occur. .

In addition, the multi-stage filtration module device 200, as shown in Figure 3, the separation wall 250 is hinged to the upper end of the exterior 210, the filter net 230 is oblique so as to tilt at an angle. Is connected to, the solids desorption means 240 is preferably configured to be connected to the external high pressure compressor 270. At this time, the solids desorption means 240 is moved to move back and forth after a predetermined time and is configured to clean the filter net by detaching the solid attached to the filter net 230 by spraying air.

Figure 4 shows the filtration process of the multi-stage filtration module device 200 according to the present invention, as shown in the waste oil 100 is oil 110, solids 120, water 130, dissolved minerals Alternatively, the metal ions 140 may be mixed and the like. When the waste oil 100 passes through the filter net 230, the bulky solid does not pass through the filter net but is attached to an embossed portion and the like. Accordingly, the waste oil 100 passes through the multi-stage filtration module device 200 in which the pores of the filtering network are reduced, and solids such as sludge are removed to generate the filtered oil 280.

After filtering for a predetermined time, the solids desorption means 240 installed in the lower portion of the filter net 230 moves forward and backward to spray the air of the high pressure compressor 270 through the injection nozzle to desorb and wash the solids. At this time, the detached solids 120 are gathered to the lower side by riding the filter net 230 inclined at a predetermined slope, and the solids 120 are removed after the separation wall 250 is opened.

In addition, the multi-stage filtration module device is preferably configured to prevent the operation of the system at the time of washing the filter network by installing two sets alternately every predetermined time.

6 illustrates a preferred embodiment of the primary storage unit according to the present invention, wherein the primary storage unit 300 is a storage tank in which the filtered refined oil 280 filtered by the multi-stage filtration module device 200 is stored ( 310, a waste oil inlet 330 into which the filtered refined oil flows, and a far-infrared ray emitter 320 formed of a plurality of far-infrared lamps disposed at an upper portion of the reservoir and radiating a wavelength of 6-11 μm, which is a response wavelength of water molecules. ), A stirring device 340 installed under the reservoir to contact the water 130 contained in the filtered refined oil 280 to the radiation wavelength, and stirring the filtered refined oil, and the resonant resonance device 400 for the filtered refined oil. The circulation outlet 350 and the circulation inlet 360 to circulate is configured to include. In addition, the primary storage unit 300 is preferably configured to further include a safety valve for discharging the air in the reservoir to the outside at 2 atm or more.

FIG. 7 illustrates a preferred embodiment of the resonance resonance apparatus 400 according to the present invention. The resonance resonance apparatus 400 includes an oil pump 410 for sucking filtered filtration oil transmitted from a primary storage part. Fine air injection means 420 for injecting fine air into the filtered refined oil 280 sucked from the oil pump through micropores, a compressor 430 for supplying air to the fine air injection means, and fine air and filtration Gas-liquid mixing means for mixing the refined oil 440, a flow controller 450 for adjusting the flow rate discharged from the gas-liquid mixing means, a lower inlet through which the mixed liquid supplied through the flow regulator is introduced and the upper outlet for discharging it The voltage pulse reduction resonance resonance means 460 provided with a voltage pulse acid having an upper inlet through which the mixed liquid discharged from the voltage pulse reduction resonance resonance means is introduced and a lower outlet outlet through which the mixed solution discharged from the voltage pulse reduction resonance resonance means is provided. Resonance is 0 people means 470, and this resonance resonance imaging configuration includes a control panel 480 for controlling.

At this time, the pressure of the compressor connected to the micro-air injection means 420 is preferably configured to have a range of 2.5 ~ 3.0 horsepower.

In addition, the voltage-pulse reduction resonance resonance means 460 is configured to change electrons into crystalline minerals or metals by emitting electrons through an electron rod provided therein and reacting with dissolved minerals or metal cations. The voltage pulse oxidized resonance resonance means 470 is configured to change electrons into crystalline minerals or metals by attracting electrons through an electron rod provided therein and reacting with dissolved minerals or metal anions. This oxidation and reduction process is repeated to produce the ion-refining mixed oil 490 in the resonance resonance apparatus.

8 shows a preferred configuration of the flow distribution device 500 according to the present invention, as shown in the flow distribution device 500, the T-shaped form (510a) or the Y (Y) Piping made of a child shape (510b), and flow rate meter 520 installed at the upper end portion to the fractional distillation apparatus 500 from the primary storage unit 300 to check the flow rate supplied to the fractional distillation apparatus, and is supplied Preheating the active waste oil to 70 ° C. or more using waste gas from the fractionation distillation apparatus, which is installed at a position connected to the flow rate control valve 530 installed at the rear end of the flow meter, and the fractionation distillation apparatus 600 to adjust the flow rate. It is configured to include a preheat mixing means.

At this time, the preheating and mixing means is a preheating and mixing means for preheating the ion-refining mixed oil (490) to 70 ℃ or more is composed of a double tube consisting of an outer tube formed in the inlet and outlet to the waste gas in and out, the mixing plate is installed therein ( 540a) or a preheating and mixing means formed in a form of a single tube provided with a mixing plate in the center of the inlet and outlet of the waste gas inlet and outlet formed in a diagonal direction from the inlet to the outlet. 540b).

That is, the preheating mixing means has a waste heat mixing plate in the center and the preheating mixing means 540a of the double pipe structure configured so that the waste gas discharged from the fractional distillation device between the inner tube and the outside flows into the heat medium, or the waste heat mixing plate in the center. The preheating and mixing means 540b of the single-pipe structure, which is configured so that the waste gas discharged from the fractionation distillation apparatus flows into the heat medium, is installed in a spring form and is used as a spring.

In addition, the pipe is a tee (T) -shaped (510a) or Y (Y) -shaped (510b) to be provided with one inlet and two outlets connected to the primary reservoir and the fractionation device as described above. Consists of a flow meter and a flow control valve is connected in series to the outlet of the pipe.

At this time, the flow rate distribution in the flow rate distribution means 500 is preferably configured such that the flow rate of the active waste oil supplied to the primary storage unit 300 and the fractionation distillation apparatus 600 is 1: 9 ~ 9: 1. Do.

9 illustrates a preferred configuration embodiment of the fractional distillation apparatus 600 according to the present invention in more detail.

The fractional distillation apparatus 600 is formed of a double wall structure consisting of an outer wall 610 and an inner wall 630 and a reaction tank in which a heat medium 620 of 120 to 140 ° C. flows between the double walls, and formed at an upper portion of the double wall to 70 ° C. An inlet 640 through which the ion-prepared mixed oil 490 preheated above is introduced, an outlet 650 formed at a position spaced apart from the lower portion of the double wall by a predetermined distance, and an outlet 650 through which the water-refining oil 690 flows out; Stirring means 660 for even heat transfer to the center in the reaction tank, waste gas outlet 670 formed on the reaction tank is discharged to the waste gas generated during stirring, and installed in the bottom of the reactor consisting of a funnel shape It is configured to include a sediment collecting means 680 to collect the sediment.

At this time, the outer wall 610 of the reaction tank is formed with a heat medium inlet through which the heat medium 620 flows between the double walls of the reactor, and a heat medium outlet through which the cooled heat medium is discharged is formed at the upper portion in the opposite direction.

Accordingly, the ion-refining mixed oil 490 is introduced into the fractional distillation apparatus 600 and is agitated by the stirring means to rise to 120-130 ° C. by the heat medium 620 between the outer wall and the inner wall. The light oil is vaporized and discharged, and the material having a higher specific gravity among crystalline minerals or metal particles is precipitated and discharged to the bottom to be converted into a water refining oil 690.

At this time, the waste gas of 120 ~ 130 ℃ discharged from the fractionation distillation apparatus 600 is supplied to the preheat mixing means to preheat the active waste oil to 70 ℃ or more. In addition, since there are crystalline mineral or metal particles in the ionic mixed oil 490, it is preferable to collect precipitates of large particles using the precipitate collection means 680 every predetermined time.

Figure 10 illustrates in more detail a preferred embodiment of the particulate removal device 700 according to the present invention.

The fine particle removing device 700 is a net of a predetermined pore having an inlet 720 and a screw 730 in the center of the water refining oil 690 containing the solid particles 710 is purified after the fractionation distillation apparatus A hole network tube 740 having a shape and narrowing in diameter toward the distal end, a power unit 750 for rotating the screw 730 and the hole network tube, and a particulate collector 760 for collecting particulates of filtered minerals and metals; , The outlet portion 770 has an asymmetric funnel shape, and the oil and water separation tank 780 for separating the oil and water, characterized in that it is configured to include.

At this time, the water refining oil 690 is a solid particle 710 remains in the hole network pipe 740 by the centrifugal force by the rotation of the hole network pipe 740, oil and residual water through the air hole network pipe 740 The oil and water of the oil refining oil are separated from the oil and water separation tank 780 by flowing out, and the solid particles 710 are pushed out by a screw rotating inside the hollow tube 740. Gather in the collection box.

11 illustrates a preferred configuration embodiment of the secondary storage unit 800 according to the present invention in more detail.

The secondary storage unit 800 is a storage tank 810 in which the ion refining oil 790 from which fine particles and water are removed from the particulate removal device is introduced through the inlet 820 and stored therein, and the ion refining oil stored in the storage tank. The outflow part 830 and the outflow part are connected to one end of the outflow part and include a fine impurity removal module 840 for removing the fine impurity that may remain in the ion refining oil 790.

At this time, the fine impurity removal module 840 is provided with a flange at both ends, there is a filter medium such as a mesh, filter paper, etc. having a pore of 0.5 mm or less inside the tube, the fine impurity remaining while the ionic refined oil passes through the filter medium It is configured to remove.

12 illustrates in more detail a preferred embodiment of the functional biofilter 900 according to the present invention.

The functional biofilter 900 is an inlet 910 through which the waste gas 690 is introduced, a perforated jet plate 920 for evenly dispersing the introduced waste gas 690, and removes volatile organic compounds or odors. The functional microbial carrier module 930 and the upper and lower sides of the microbial carrier module 930 is open alternately between the module partition wall 920 to increase the treatment efficiency by increasing the residence time, and the purge gas outlet for discharging the purified gas 940, a gas collecting means 960 consisting of a pipe for collecting a sample of the exhaust gas, a drainage device 950 for removing water collected in the lower part of the reaction tank, and a top of the inside of the reaction tank to control the humidity in the reaction tank. A spray nozzle 970 for maintaining and injecting microbial nutrients when the activity of microorganisms is reduced, and a maintenance tube installed at an outer top of the functional biofilter 900 to replace the microorganism carrier module 930. A manhole 980 is constructed contains a.

At this time, the microbial carrier module 930 is made of cork material with a particle diameter of 8 ~ 16㎜ or the surface of the cork burned, the upper and lower portion is made of a mesh, a perforated plate having a predetermined pore and the side wall has no pores Form. In particular, if the surface is composed of a cork burned can be increased the removal efficiency by the initial adsorption.

Next, a method of purifying waste oil using an ion refined oil production system using the resonance resonance apparatus configured as described above will be described.

Waste oil purification method according to the present invention, as shown in Figure 13, the multi-stage filtration step (S10) for removing the solids, such as sludge in the waste oil, and the resonance of the water molecules through the far-infrared lamp while storing and stirring the filtered waste oil first Active water conversion step (S20) that converts the water contained in the waste oil into active water by emitting a radiation wavelength in the wavelength range of absorption wavelength of 6 ~ 11㎛, and dissolved minerals or metal ions dispersed in the waste flow rate through a resonance resonance device And converting the activated waste oil into crystalline minerals or metals and lowering the tension and viscosity of the waste oil particles (S30), and the flow distribution step (S40) of distributing and supplying and preheating the converted active waste oil to the fractional distillation apparatus. Fractional distillation step (S50) of producing a purified oil by fractional distillation of water and light oil contained in the active waste oil using a heat medium, and crystallinity of the active waste oil Particle removal step (S60) for removing solid particles, such as water or metal materials, oil-water separation step (S70) for removing residual moisture by layer separation, and after the separated oil is rectified to remove impurities through a fine impurity removal module Ion refined oil commercialization step (S80) to remove and commercialize is configured to include.

The multi-stage filtration step (S10) is a plurality of filter nets 230 made of various embossed forms in order to increase the surface area installed in the multi-stage filtration module device 100, such as sludge contained in the collected waste oil (100) To be removed while passing through, the filter net 230 is preferably installed in a multi-stage layer structure in which the pores are gradually reduced so that the solids are sequentially filtered through several layers. In addition, by installing two or more multi-stage filtration module devices provided with valves at the front end and operating them alternately, when a certain amount of solids is attached to the filtering network, air is injected from the injection nozzle in the solids detaching means 240 moving back and forth under the filtering network. It is preferable that the filtration is carried out after the solids are separated using.

The active water conversion step (S20) is a 6 ~ 11 ㎛ wavelength radiation of the water absorption resonance wavelength of the water molecules using a far-infrared lamp in the upper portion of the storage tank 310 while stirring the filtered waste oil flowing into the primary storage unit 300 By emitting wavelengths, the water contained in the waste oil is reacted with the radiation wave, thereby causing the active movement of water molecules on the cluster, causing energy to be released while colliding violently and converting it into active water.

The active waste oil conversion step (S30) is a constant suction of the waste oil of the primary storage unit 300 through the flow regulator 450 to inject finely divided air through the fine air injection means 420, gas-liquid mixture After mixing with the means 440, dissolved minerals or metal ions dispersed in the waste oil by passing through the voltage reduction resonance resonance device 460 and the voltage oxidation resonance resonance device 470 are positive (+) and negative in the barrier discharge part. The process of oxidizing and reducing ions to crystalline minerals or metals by repetitive oxidation and reduction processes in accordance with the transfer of charges generated by strong electric fields due to negative voltage pulses and reducing tension and viscosity of waste oil particles. It is configured to convert into active waste oil by continuing to circulate for a period of time.

The flow distribution step (S40) is to distribute the active waste oil between the primary storage unit 300 and the fractional distillation unit 600 through the flow controller 1: 9 to 9: 1, and sent to the fractional evaporator 600 The activated waste oil is configured to preheat up to about 70 ° C. through preheating mixing means 540a, 540b using waste gas generated from the fractionation distillation apparatus.

The fractional distillation step (S50) by raising the temperature of the active waste oil ionized by the heat medium 620 between the outer wall 610 and the inner wall 620 to 120 ~ 130 ℃ while stirring in the reaction tank, Water and light oil are separated and discharged to the top, and the natural sedimented precipitate is discharged to the bottom.

The fine particle removing step (S60) is introduced into the hole network pipe 740, the oil containing fine particles of mineral or metal components and residual water, and the hole network pipe 740 is rotated by the power of the power unit 750 Particulates are configured to remain inside the perforated pipe and be discharged to the outside through a screw.

At this time, the fine particle removal step (S60) may be made in the fine particle removal device 700 after the fractional distillation step (S50), the fractionation distillation step (S50) that the fractional distillation of water and light oil in the fractionation distillation apparatus 600, in the flow rate distribution device By supplying activated waste oil to the fine particle removal device 700, the fine particles are first removed, and the active waste oil from which the fine particles have been removed is supplied to the fractionation distillation device 600, whereby the fine particle removal step S60 precedes the fractional distillation step S50. Of course, it may be configured to. As such, when the particulates in the active waste oil are removed first and then fractionally distilled, the efficiency of fractional distillation can be further improved.

In the oil and water separation step (S70), the oil and the water pass through the pores of the hole network pipe 740 and are discharged to the lower outlet 770 to be separated by the difference in specific gravity in the oil and water separation tank 780, so that the water is lowered. It is removed through the valve of the discharge pipe in the and is configured to move only the oil to the secondary reservoir.

The ion refining oil commercialization step (S80) is configured to generate the ion refining oil by removing impurities through the fine impurity removal module 840 after rectifying the oil separated from the residual moisture. In this case, the fine impurity removal module 840 is preferably configured to remove particulates that may be present in the oil by passing through a filter medium having a pore size of 0.5 mm or less.

On the other hand, the above-described embodiments and drawings are only for the purpose of describing the contents of the invention in detail, not intended to limit the scope of the technical idea of the invention, the present invention belongs to those skilled in the art Since various substitutions, modifications, and changes can be made without departing from the spirit and scope of the present invention, the present invention is not limited to the above embodiments and the accompanying drawings, as well as the following claims, as well as equivalent claims. It should be judged including the scope.

As described above, in the ion refining oil production system and waste oil refining method using the same, the dissolved minerals and metal ions in the waste oil can be converted into crystalline minerals and metals without chemicals. There is an effect that the time required for the reaction between the drug and the metal ion is unnecessary.

In addition, the present invention converts the waste oil particles into active waste oil by reducing the tension and viscosity, and preheating the active waste oil using the waste gas generated in the fractionation distillation unit to separate the water and light oil, significantly reducing the processing time than before In addition, it is possible to separate a larger amount of water and light oil than conventional methods, there is an effect that can produce a high-purity ion refined oil having a higher quality than conventional ion refined oil.

In addition, the resonance resonance apparatus of the ion refined oil production system according to the present invention can be used in various modifications depending on the situation has an excellent effect of coping with the situation change.

Claims (24)

A multi-stage filtration module device having a plurality of filter networks formed in a multi-stage layer structure to remove solids such as sludge in the waste oil and converting them into filtered oil; A primary storage unit for storing the filtered refined oil and converting the water molecules of the cluster contained in the filtered refined oil into activated water releasing energy by activating by radiation wavelength; Dissolved minerals or metal ions in the filtration refinery oil in which the water molecules are converted into active water are converted into crystalline minerals or metals by the movement of electrons by a voltage pulse electric field, and fine air is mixed with the filtration refinery oil to refine the refined oil particles. Resonance resonance device to convert the active waste oil by lowering the tension and viscosity of the; A flow rate distribution means for regulating the flow rate for circulating the active waste oil to the primary storage unit and the flow rate for supplying to the fractionation distillation apparatus at a predetermined ratio, and preheating the active waste oil with the heat of the waste gas generated in the fractionation distillation apparatus; A fractionation distillation apparatus for vaporizing and separating water and light oil in the active waste oil and discharging waste gas; A fine particle removing device for removing fine particles such as crystalline minerals or metals in the waste oil from which water is removed from the fractional distillation device and residual water; And And a secondary storage unit for storing the refined oil from which the fine particles have been removed from the fine particle removing device and removing the remaining fine impurities in the final outflow. The method of claim 1, The multi-stage filtration module device, A plurality of filter nets having a variety of pores of 2 to 20 mm or less, formed in a planar or embossing (_∩_∩_) shape, and having a multi-stage layer structure in which pores become smaller toward the bottom; A plurality of connection grooves formed in a multi-level layer structure in the interior of the exterior of which one side wall is inclined at an angle of 20 to 40 °; And It is installed in the lower portion of each of the filter net ion refining oil production system characterized in that it comprises a solid desorption means having a spray nozzle for injecting air to move back and forth. The method of claim 2, The filter net, Ion refined oil production system, characterized in that it is configured in a variety of forms, such as flat, egg plate, upper embossing, lower embossing, or upper and lower embossing. The method of claim 1, The primary storage unit, A storage tank in which the filtered refined oil is stored; Waste oil inlet through which the filtered oil is introduced; A far-infrared light emitting unit which is installed on an upper portion of the reservoir and composed of a plurality of far-infrared lamps emitting a wavelength of 6 to 11 μm, which is a sensitive wavelength of water molecules; A stirring device installed under the reservoir to contact the water contained in the filtered refined oil with a radiation wavelength to stir the filtered refined oil; And And a circulation inlet and a circulation inlet for circulating the filtered refined oil to a resonance resonance apparatus. The method of claim 1, The resonance resonance apparatus, Micro-air injection means for injecting micro-air through the micro-pores to the filtered refined oil sucked through the oil pump; Gas-liquid admixing means for admixing the fine air with the filtered refined oil; A flow controller for controlling the flow rate discharged from the gas-liquid mixing means; A voltage pulse reduction resonant resonance means having a lower inlet through which the mixed liquid supplied through the flow controller is introduced, an upper outlet outlet for discharging it, and an electron bar that emits electrons and reacts with dissolved minerals or metal cations; And The voltage pulse oxidation resonance resonance means having an upper inlet through which the mixed liquid discharged from the voltage pulse reduction resonance resonance means flows in, a lower outlet outlet for discharging it, and an electron rod that pulls electrons and reacts with dissolved minerals or metal anions. Ion refining oil production system characterized in that it is configured to include. The method of claim 1, The flow distribution device, A pipe formed in the shape of a wire (Y) or tee (T) having one inlet and two outlets connected between the primary storage unit and the fractionation device; A flow control valve connected in series with the outlet for controlling the flow rate supplied to the fractionation distillation apparatus; And And a preheating and mixing means for preheating the active waste oil to 70 ° C by using the waste gas discharged from the fractional distillation apparatus. The method of claim 6, The flow distribution device, Ion refined oil production system, characterized in that controlled to send the flow rate of the active waste oil 1: 9 to 9: 1 to the primary storage unit and the fractionation distillation apparatus. The method of claim 6, The preheating mixing means, A waste heat mixing plate in the center, the pipe is installed in the form of a spring outside, the ion refined oil production system, characterized in that the waste gas discharged from the fractional distillation apparatus to the heat medium flows in the heat pipe structure. The method of claim 6, The preheating mixing means, In the center, there is a waste heat mixing plate, an inlet and an outlet through which the waste gas enters and an outer tube formed therein, and an inner tube installed inside the mixing plate. Ion refining oil production system, characterized in that consisting of a structure. The method of claim 1, The fractional distillation apparatus, A reaction tank in which a heat medium of 120 to 140 ° C. flows between a double wall formed of an outer wall and an inner wall; An inlet formed on an upper portion of the double wall and into which ion mixed oil preheated to 70 ° C. is introduced; An outlet portion formed at a position spaced a predetermined distance from the lower portion of the double wall to allow the water refining oil to flow out; Stirring means for heat transfer evenly to the center in the reactor; A waste gas outlet formed at an upper portion of the reactor to discharge waste gas generated during stirring; And Ion refined oil production system characterized in that it comprises a sediment collecting means for collecting the precipitate is installed in the lower portion of the reactor. The method of claim 1, The particulate removal device, An inlet part, after the water refining oil is purified in the fractionation distillation apparatus; A screw having a central portion, and having a net shape of a predetermined pore, and having a diameter narrowed toward the distal end; A power unit for rotating the screw and the hole network; A fine particle collecting means for collecting fine particles of a mineral or a metal component filtered from the porous network; An outlet portion of which a lower portion is formed in an asymmetrical funnel; And Ion refined oil manufacturing system, characterized in that comprises an oil-water separation tank for separating oil and water. The method of claim 1, The secondary storage unit, A storage tank in which the ion refining oil from which the fine particles and water are removed is stored in the fine particle removing device; And And a fine impurity removal module connected to one end of the outlet portion through which the ion refined oil is discharged. The method of claim 12, The fine impurity removal module, the ion refining oil production system, characterized in that is provided with a filter medium, such as a mesh tube, filter paper having a pore of 0.5 mm or less inside the tube. The method of claim 1, An inlet through which waste gas containing water and light oil discharged from the flow distribution means is introduced; A perforated spray plate to evenly distribute the introduced waste gas; Functional microbial carrier module to remove volatile organic compounds or odors; An upper and lower sides of the microbial carrier module are alternately opened to increase a treatment efficiency through an increase in residence time; A purge gas outlet for discharging the purified gas; A gas sampling pipe for collecting a sample of the exhaust gas; A plurality of drain pipes for removing water collected at the bottom of the reactor; A spray nozzle for maintaining humidity at the uppermost part of the reaction tank and injecting microbial nutrients when the activity of the microorganisms decreases; And Ion refining oil production system, characterized in that the maintenance manhole is included for replacing the microorganism carrier module, etc., further comprises a functional biofilter for purifying the waste gas. The method of claim 14, The microorganism carrier module, ion refined oil production system, characterized in that composed of a cork having a particle diameter of 8 ~ 16mm or a surface cork. A multistage filtration step of removing solids such as sludge in the waste oil; An active water conversion step of converting the water contained in the waste oil into active water by releasing the radiation wavelength of 6 ~ 11㎛ wavelength which is the resonance absorption wavelength of water molecules through the far infrared lamp while primaryly storing the filtered waste oil and stirring; An active waste oil conversion step of converting dissolved minerals or metal ions dispersed in the waste oil into crystalline minerals or metals through a resonance resonance device to lower the tension and viscosity of the waste oil particles; A flow rate distribution step of distributing and converting the converted active waste oil into a predetermined amount fractionation distillation apparatus, and preheating the active waste oil using waste gas; A fractionation distillation step of fractionally distilling the water and the light fraction contained in the active waste oil by a heat medium to produce a purified oil; A fine particle removing step of removing solid particles such as crystalline minerals or metal substances in the water refining oil; Oil and water separation step of separating and removing the residual water in the water refining oil; And Refining the separated oil, and after the fine impurity removal module to remove impurities and commercialize the refined waste oil comprising a commercialization step comprising the commercialized. A multistage filtration step of removing solids such as sludge in the waste oil; An active water conversion step of converting the water contained in the waste oil into active water by releasing the radiation wavelength of 6 ~ 11㎛ wavelength which is the resonance absorption wavelength of water molecules through the far infrared lamp while primaryly storing the filtered waste oil and stirring; An active waste oil conversion step of converting dissolved minerals or metal ions dispersed in the waste oil into crystalline minerals or metals through a resonance resonance device to lower the tension and viscosity of the waste oil particles; A flow rate distribution step of distributing the converted active waste oil to a predetermined amount of fine particle removing device and preheating the active waste oil using waste gas; A particulate removal step of removing solid particulates such as crystalline minerals or metal substances in the active waste oil; A fractionation distillation step of fractionating distillation of water and light oil contained in the active waste oil from which solid particulates have been removed by heat medium to produce a purified oil; Oil and water separation step of separating and removing the residual water in the water refining oil; And Refining the separated oil, and after the fine impurity removal module to remove impurities and commercialize the refined waste oil comprising a commercialization step comprising the commercialized. The method according to claim 16 or 17, The multi-stage filtration step, Forming a multi-stage layer structure so that the pores gradually become smaller, the solids such as sludge contained in the waste oil are filtered through a plurality of filtering networks installed inside the multi-stage filtration module device, and when a certain amount of solids is attached to the filtering network, the filter moves under the filtering network. Waste oil refining method, characterized in that configured to detach the solids by the air injected from the injection nozzle provided in the solids removal means. The method according to claim 16 or 17, The active water conversion step, While the filtered waste oil flowing into the primary storage part is stirred by the stirring means, the radiation wave of 6 ~ 11㎛ wavelength, which is the resonance absorption wavelength of water molecules, is emitted by the far-infrared lamp in the upper part of the storage tank to radiate the water contained in the waste oil. And sensitizing and causing active movement of water molecules on the cluster to release energy while colliding, thereby converting the waste oil into active water. The method according to claim 16 or 17, The active waste oil conversion step, By inhaling the waste oil of the primary storage part through the flow regulator, the finely divided air is injected through the fine air injection means, mixed with the gas-liquid mixing means, and then passed through the voltage reduction resonance resonance device and the voltage oxidation resonance resonance device. Dissolved minerals or metal ions dispersed in the waste oil are repeatedly oxidized and reduced as the charge transfers through the strong electric field caused by positive and negative voltage pulses at the barrier discharge. A method of purifying waste oil, characterized by converting into crystalline minerals or metals and converting them into active waste oil by continuously circulating a process of lowering the tension and viscosity of the waste oil particles for a predetermined time. The method according to claim 16 or 17, The flow rate distribution step, The active waste oil is distributed between the primary storage unit and the fractionation distillation unit at a flow rate controller between 1: 9 and 9: 1, and the active waste oil sent to the fractionation unit is preheated using a waste gas generated from the fractionation unit. Waste oil purification method characterized in that configured to preheat to 70 ℃. The method according to claim 16 or 17, The fractional distillation step, While stirring inside the reactor, the temperature of the activated waste oil purified by the heat medium between the outer wall and the inner wall is increased to 120-130 ° C. The water and light oil in the activated waste oil are separated and discharged to the upper part. Waste oil purification method characterized in that configured to discharge to the bottom. The method according to claim 16 or 17, The particulate removal step, Particles containing mineral or metal particles and residual water are introduced into the hole network tube, and the hole network tube is rotated by a power unit, so that the particles remain inside the hole network tube and are discharged to the outside through the screw. Waste oil purification method. The method according to claim 16 or 17, The oil and water separation step, The oil and water are discharged to the lower outlet through the air gap of the perforated pipe and separated by the specific gravity difference in the oil-water separation tank. Waste oil purification method characterized in that it is.

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