KR100841103B1 - Use method and manufacturing method and muti functional liquefy color toner composition - Google Patents

Use method and manufacturing method and muti functional liquefy color toner composition Download PDF

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Publication number
KR100841103B1
KR100841103B1 KR1020070035719A KR20070035719A KR100841103B1 KR 100841103 B1 KR100841103 B1 KR 100841103B1 KR 1020070035719 A KR1020070035719 A KR 1020070035719A KR 20070035719 A KR20070035719 A KR 20070035719A KR 100841103 B1 KR100841103 B1 KR 100841103B1
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South Korea
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weight
color toner
toner composition
liquid color
functional
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KR1020070035719A
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Korean (ko)
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임선환
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임선환
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Priority to KR1020070035719A priority Critical patent/KR100841103B1/en
Priority to PCT/KR2007/002870 priority patent/WO2008126960A1/en
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Publication of KR100841103B1 publication Critical patent/KR100841103B1/en

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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/0802—Preparation methods
    • G03G9/0804—Preparation methods whereby the components are brought together in a liquid dispersing medium
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/0802—Preparation methods
    • G03G9/0804—Preparation methods whereby the components are brought together in a liquid dispersing medium
    • G03G9/0806—Preparation methods whereby the components are brought together in a liquid dispersing medium whereby chemical synthesis of at least one of the toner components takes place
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/083—Magnetic toner particles
    • G03G9/0831—Chemical composition of the magnetic components
    • G03G9/0832—Metals
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/093—Encapsulated toner particles
    • G03G9/09392—Preparation thereof
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/097—Plasticisers; Charge controlling agents
    • G03G9/09708—Inorganic compounds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/12—Developers with toner particles in liquid developer mixtures

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A multifunctional liquid color toner composition, a method for preparing the composition, and a method for using the composition in the preparation of artificial leather are provided to impart antibacterial effect, sterilizing effect, deodorizing effect and anion emitting effect to artificial leather. A multifunctional liquid color toner composition comprises 30-50 wt% of a colorant comprising a dye or a pigment; 35-40 wt% of a resin for foaming or leather; 8-18 wt% of a functional material; 6-8 wt% of a diluting solvent; and 1-4 wt% of a dispersant. Preferably the functional material comprises 10-30 wt% of silver nanoparticles, 8-10 wt% of germanium, 12-15 wt% of bioceramics, 3-5 wt% of titanium, 13-15 wt% of zirconium, 13-15 wt% of zeolite, 3-5 wt% of charcoal, 13-15 wt% of tourmaline, 3-5 wt% of yellow soil and 2-5 wt% of cinnamon.

Description

다기능성 액상 컬러 토너 조성물과 그 제조방법 및 이의 사용방법{Use method and Manufacturing method and muti functional liquefy color toner composition}Multifunctional liquid color toner composition and its preparation method and use method thereof {Use method and Manufacturing method and muti functional liquefy color toner composition}

본 발명은 다기능성 액상 컬러 토너 조성물과 그 제조방법 및 이의 사용방법에 관한 것으로서, 보다 상세하게는 항균, 살균, 탈취는 물론 원적외선과 음이온이 방사되는 액상 컬러 토너 조성물을 제공하는 것이고 또한 별도의 추가공정 없이 기존의 생산공정, 생산라인에서 기능성 피혁용 수지와 발포 폼을 얻을 수 있도록 한 것이며 아울러 불필요한 공정을 제거함으로 생산성 향상과 원가절감 및 특히 인체에 유해한 접착제와 코팅제를 사용하지 않게 되는 장점이 있고, 이로 인해 제품의 품질과 신뢰성을 대폭 향상시켜 소비자로 하여금 좋은 이미지를 심어줄 수 있도록 한 것이다.The present invention relates to a multifunctional liquid color toner composition, a method of manufacturing the same, and a method of using the same, and more particularly, to provide a liquid color toner composition in which far infrared rays and anions are radiated as well as antibacterial, sterilization, and deodorization. It is possible to obtain functional leather resin and foam foam in existing production process and production line without process, and it also has the advantage of eliminating unnecessary process to improve productivity, cost reduction, and not to use adhesives and coatings that are particularly harmful to human body. As a result, the quality and reliability of products have been greatly improved, enabling consumers to plant good images.

주지하다시피 합성피혁 [合成皮革, artificial leather] 또는 인조피혁은 합성 고분자 화합물을 주원료로 하여 무명, 화학 섬유(일명: 부직포) 따위의 기본이 되는 천 위에 플라스틱 층을 겹쳐 천연 피혁과 비슷하게 만든 피혁으로 질기며 손 질하기가 간단하여서 구두, 가방, 의자 따위를 만드는 데 쓴다.As is well known, artificial leather or artificial leather is a leather made of synthetic polymer compound as the main raw material, similar to natural leather, with a plastic layer overlaid on a cloth that is the basis of cotton or chemical fiber (aka nonwoven fabric). It's tough and easy to clean, so it's used to make shoes, bags and chairs.

또한 착색제 [着色劑, stain]는 염료 또는 안료(顔料) 등을 사용하여 착색할 때의 염색제로 스테인이라고도 한다.In addition, the coloring agent [wear coloration, stain] is a stain | dye at the time of coloring using dye, a pigment, etc., and is also called stain.

상기와 같은 착색제를 이용하여 종래에는 피혁제품에 색상을 내거나 또는 피혁제품에 기능성 물질을 도포하여 원적외선이 방출되도록 한 것이 있다.Conventionally, by using a colorant as described above, the color of leather products or a functional material is coated on leather products to allow far infrared rays to be emitted.

즉, 상기한 종래의 기술 내용을 살펴보면 다음과 같다.That is, the above description of the related art is as follows.

종래에는 선 출원된 특허출원 제 1991-0020833호(공개번호 1993-0010307호)(명칭: 합성피혁의 제조방법)가 있다.Conventionally, there is a patent application No. 1991-0020833 (Publication No. 1993-0010307) (name: manufacturing method of synthetic leather).

상기한 종래의 기술적 구성은 섬유기재상에 공지의 폴리우레탄 수지, 희석용제, 계면활성제, 착색제 및 충전제로 구성된 수지용액으로 코팅하여 제조된 필름상 시이트를 희석용액에 침적한 기포지와 합포시켜 응고, 수세 건조후 필름상 시이트를 박리시킨 다음 엠보싱 표면처리하여 제조함을 특징으로 하고 있다. 이때의 폴리우레탄 조성비는 폴리우레탄 수지 30∼40%, 희석용제인 DMF 40∼50%, 음이온계면활성제1∼3% 비이온계면활성제1∼3%, 수지착색용 안료 2∼15%와 셀룰로우즈계 충전제 4∼5%로 하였다.The conventional technical configuration described above is solidified by combining a film-like sheet prepared by coating a resin solution composed of a known polyurethane resin, a diluent solvent, a surfactant, a colorant, and a filler on a fiber substrate with bubble paper deposited on the dilution solution. After peeling and drying, the film-like sheet is peeled off and then embossed. Polyurethane composition ratio at this time is 30-40% of polyurethane resin, DMF 40-50% of diluent solvent, 1-3% of anionic surfactant, 1-3% of nonionic surfactant, 2-15% of pigment for coloring resin and cellulose The wood filler was 4-5%.

그러나 상기한 종래의 기술은 일반 중량 배합비 방식으로만 배합하여 기능성을 부여함으로써 제품에 여러 가지 문제점이 발견되었다.However, the above-described prior art has been found to have various problems in the product by combining only in the general weight ratio ratio method to impart functionality.

이를 보다 상세히 설명하면, 일반적인 투입 방식인 기능성 물질을 프리믹서 하여 넣음으로 인조합성피혁과 발포 폼이 셀의 조밀도를 약화시키거나 또는 깨짐, 일부 한쪽 몰림 현상 발생으로 인한 기능성 발생이 고루지 못한 점 그리고 별도의 기능성 처리된 제품을 접착제를 사용하여 붙이는 또 다른 인체 유해물 첨가와 별도의 기능성 코팅제를 제조하여 코팅 처리하는 이중의 공정 등 많은 문제점이 발생 되었다.In more detail, the pre-mixing of functional materials, which is a general input method, prevents the occurrence of uneven generation of functional leather and foams due to the weakening of cell density or cracking, and the occurrence of one side crushing. In addition, a number of problems have arisen, such as the addition of another human harmful substance attached to a separate functionalized product using an adhesive and a double process of manufacturing and coating a separate functional coating agent.

본 발명은 상기와 같은 종래 기술의 제반 문제점을 해소하기 위하여 안출한 것으로, 항균, 살균, 탈취는 물론 원적외선과 음이온이 방사되는 액상 컬러 토너 조성물을 제공함을 제1목적으로 한 것이고, 제2목적은 별도의 추가공정 없이 기존의 생산공정, 생산라인에서 기능성 피혁용 수지와 발포 폼을 얻을 수 있도록 한 것이며, 제3목적은 불필요한 공정을 제거함으로 생산성 향상과 원가절감 및 특히 인체에 유해한 접착와 코팅제를 사용하지 않게 되는 장점이 있고, 제4목적은 기능성 물질과 착색제가 피혁용 수지 내에서 각자의 별도 독립 상태로 내재되어 있던 혼합 상태를 벗어나 수지 접착력의 효과로 안료 혹은 염료가 비중이 높은 기능성 물질들에 대해 전체 코팅화가 이루어져 소량 투입으로도 기능성 물질이 더 효과가 높은 기능을 발휘하도록 한 것이며, 제5목적은 이로 인해 제품의 품질과 신뢰성을 대폭 향상시켜 소비자로 하여금 좋은 이미지를 심어줄 수 있도록 한 다기능성 액상 컬러 토너 조성물과 그 제조방법 및 이의 사용방법을 제공한다.The present invention has been made to solve the above problems of the prior art, and the first object of the present invention is to provide a liquid color toner composition in which far infrared rays and anions are radiated, as well as antibacterial, sterilizing, and deodorizing. It is possible to obtain functional leather resin and foam foam in existing production process and production line without any additional process, and the third purpose is to improve productivity, reduce cost and especially use harmful adhesive and coating agent by eliminating unnecessary process The fourth purpose is to overcome the mixed state in which the functional material and the colorant are inherently separated from each other in the resin for leather, and to effect functional materials with high pigment or dye due to the effect of resin adhesion. The entire coating is made so that the functional material can be more effective even with a small amount of input. The fifth object of the present invention is to provide a multifunctional liquid color toner composition, a method of manufacturing the same, and a method of using the same, which greatly improves the quality and reliability of a product, thereby allowing a consumer to plant a good image.

이러한 목적 달성을 위하여 본 발명은 염료 또는 안료로 이루어진 착색제, 발포 또는 피혁용 수지, 기능성 물질, 희석용제 및 분산제가 상호 혼합되어 얻어지는 다기능성 액상 컬러 토너 조성물을 제공한다.In order to achieve the above object, the present invention provides a multifunctional liquid color toner composition obtained by mixing a colorant, a foaming or leather resin, a functional material, a diluent, and a dispersant, each of which is a dye or a pigment.

또한 본 발명은 착색제 30∼50중량%, 발포 또는 피혁용 수지 35∼40중량%, 기능성물질(은나노, 게르마늄, 바이오세라믹, 티타늄, 지르코늄, 제올라이트, 숯, 토르말린, 황토 및 계피) 8∼18중량%, 희석용제 6∼8중량%, 분산제 1∼4중량%를 상온에서 1∼2시간 상호 혼합하는 공정; 상기 혼합공정 이후 상기 혼합물을 저속, 중속, 고속의 롤밀(roll mill)을 통과시켜 곱게 분쇄하는 1차 분산공정; 상기 분산공정 이후 상기 혼합물을 볼밀을 통해 곱게 분쇄하는 2차 분산공정; 및 상기 2차 분산공정에 의해 페이스트(paste) 형태의 용액을 얻는 다기능성 액상 컬러 토너 조성물의 제조방법을 제공한다.In addition, the present invention is 30 to 50% by weight colorant, 35 to 40% by weight resin for foaming or leather, functional materials (silver nano, germanium, bioceramic, titanium, zirconium, zeolite, charcoal, tourmaline, ocher and cinnamon) 8-18 weight %, 6-8 weight% of diluent solvents, and 1-4 weight% of dispersing agents mutually mixing at room temperature for 1 to 2 hours; A first dispersion step of grinding the mixture finely by passing the mixture through a low, medium, and high speed roll mill; A second dispersion step of grinding the mixture finely through the ball mill after the dispersion step; And it provides a method for producing a multi-functional liquid color toner composition to obtain a solution in the form of a paste (paste) by the secondary dispersion process.

더하여 본 발명은 다기능성 액상 컬러 토너 조성물을 의류, 신발, 자동차 시트, 쇼파, 의자, 사무용가구, 스포츠용품, 유아용완구, 건축용시트, PVC장판, 의료기구, 가구에 사용되는 인조합성피혁 제조시에 혼합하여 인조합성피혁이 항균, 살균, 탈취는 물론 원적외선과 음이온이 방사되도록 함을 특징으로 하는 다기능성 액상 컬러 토너 조성물의 사용방법을 제공하고, 아울러 다기능성 액상 컬러 토너 조성물을 실리콘 폼, 고무 폼, 우레탄 폼 제조시에 혼합하여 상기 폼이 항균, 살균, 탈취는 물론 원적외선과 음이온이 방사되도록 함을 특징으로 하는 다기능성 액상 컬러 토너 조성물의 사용방법을 제공한다.In addition, the present invention provides a multi-functional liquid color toner composition in the manufacture of synthetic leather used in clothing, shoes, car seats, sofas, chairs, office furniture, sporting goods, baby toys, building sheets, PVC flooring, medical equipment, and furniture. The method provides a method of using a multifunctional liquid color toner composition characterized in that the synthetic leather blends antimicrobial, sterilization, and deodorization as well as radiation of far infrared rays and anions. In the preparation of the urethane foam, the foam provides a method of using the multifunctional liquid color toner composition, characterized in that the antibacterial, sterilization, deodorization, as well as far infrared rays and anions are emitted.

이하에서는 이러한 목적 달성을 위한 본 발명의 바람직한 실시예를 첨부된 도면에 따라 상세히 설명하면 다음과 같다.Hereinafter, described in detail with reference to the accompanying drawings a preferred embodiment of the present invention for achieving this purpose are as follows.

본 발명에 적용된 다기능성 액상 컬러 토너 조성물과 그 제조방법 및 이의 사용방법은 다음과 같이 구성되는 것이다.The multifunctional liquid color toner composition applied to the present invention, a manufacturing method thereof, and a method of using the same are configured as follows.

하기에서 본 발명을 설명함에 있어, 관련된 공지 기능 또는 구성에 대한 구체적인 설명이 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우에는 그 상세한 설명은 생략할 것이다.In the following description of the present invention, if it is determined that a detailed description of a related known function or configuration may unnecessarily obscure the subject matter of the present invention, the detailed description thereof will be omitted.

그리고 후술되는 용어들은 본 발명에서의 기능을 고려하여 설정된 용어들로서 이는 생산자의 의도 또는 관례에 따라 달라질 수 있으므로 그 정의는 본 명세서 전반에 걸친 내용을 토대로 내려져야 할 것이다.The following terms are terms set in consideration of functions in the present invention, which may vary depending on the intention or custom of the producer, and their definitions should be made based on the contents throughout the specification.

먼저, 본 발명은 염료(천연포함) 또는 안료로 이루어진 착색제, 발포 또는 피혁용 수지, 기능성 물질, 희석용제 및 분산제가 상호 혼합되어 얻어지는 다기능성 액상 컬러 토너(또는 일명 "바인더"라고도 칭한다) 조성물을 제공하게 된다.First, the present invention relates to a multifunctional liquid color toner (or also referred to as a "binder") composition obtained by mixing a colorant, a foaming or leather resin, a functional material, a diluent, and a dispersing agent made of a dye (including natural) or a pigment. Will be provided.

이때 본 발명에 적용된 상기 착색제는 30∼50중량%, 발포 또는 피혁용 수지는 35∼40중량%, 기능성물질은 8∼18중량%, 희석용제는 6∼8중량%, 분산제는 1∼4중량%가 포함됨을 특징으로 구성된다.At this time, the colorant applied in the present invention is 30 to 50% by weight, 35 to 40% by weight of the foam or leather resin, 8 to 18% by weight of the functional material, 6 to 8% by weight of the diluent, 1 to 4% by weight of the dispersant % Is included.

그리고 상기 본 발명에 적용된 착색제가 30중량% 이하가 되면 분산 작업시 분산 수율이 낮아지는 문제점이 있고, 50중량% 이상이 되면 동일한 배합통에 여러 물질을 투입했을 때 착색제의 기본 액상 흡유율이 너무 커서 젖은 고상 상태로 있어 믹싱 작업이 불가하므로 상기 착색제는 30∼50중량%가 포함됨이 바람직하다.And when the colorant applied to the present invention is less than 30% by weight, there is a problem that the dispersion yield is lowered during the dispersing operation, when more than 50% by weight, the basic liquid oil absorption rate of the colorant is too much when a plurality of substances are added to the same mixing container It is preferable that the colorant contain 30 to 50% by weight since the mixing operation is impossible due to the large wet state.

또한 상기 발포 또는 피혁용 수지는 35중량% 이하가 되면 착색제의 액체 흡유성 특징을 고려할 때 너무 되게 되는 문제점이 있고, 40중량% 이상이 되면 너무 묽게 되는 미분산의 문제점이 있어 상기 발포 또는 피혁용 수지는 35∼40중량%가 포함됨이 바람직하다.In addition, when the foam or leather resin is less than 35% by weight, there is a problem that becomes too much when considering the liquid oil absorption characteristics of the colorant, when more than 40% by weight there is a problem of undispersed that is too thin for the foam or leather It is preferable that resin contains 35 to 40 weight%.

또한 상기 기능성물질이 8중량% 이하가 되면 원적외선과 음이온의 효과가 약하다는 문제점이 있고, 18중량% 이상이 되면 비용이 너무 비싸다는 문제점이 있어 상기 기능성물질은 8∼18중량%가 포함됨이 바람직하다.In addition, when the functional material is less than 8% by weight, there is a problem that the effect of far infrared rays and anions is weak, and when the weight is more than 18% by weight, there is a problem that the cost is too expensive, and the functional material preferably contains 8 to 18% by weight. Do.

또한 상기 희석용제가 6중량% 이하가 되면 점성도(粘性度)가 너무 높아지는 문제점이 있고, 8중량% 이상이 되면 점성도가 너무 낮아지는 문제점이 있어 상기 희석용제는 6∼8중량%가 바람직하다.In addition, when the dilution solvent is 6% by weight or less, there is a problem that the viscosity becomes too high, and when the dilution solvent is 8% by weight or more, the viscosity becomes too low, and the dilution solvent is preferably 6 to 8% by weight.

또한 상기 분산제가 1중량% 이하가 되면 분산력이 약화되는 문제점이 있고, 4중량% 이상이 되면 다른 물질과의 혼합력이 약화되어 상기 분산제는 1∼4중량%가 바람직하다.In addition, when the dispersant is less than 1% by weight, there is a problem in that the dispersing power is weakened. When the dispersant is more than 4% by weight, the mixing power with other substances is weakened, so that the dispersant is preferably 1 to 4% by weight.

한편, 상기 본 발명에 적용된 상기 기능성물질은 은나노, 게르마늄, 바이오세라믹, 티타늄, 지르코늄, 제올라이트, 숯, 토르말린, 황토 및 계피가 포함되어 구성된다.On the other hand, the functional material applied to the present invention is composed of silver nano, germanium, bioceramic, titanium, zirconium, zeolite, charcoal, tourmaline, ocher and cinnamon.

이때 본 발명에 적용된 상기 은나노는 10∼30중량%, 게르마늄은 8∼10중량%, 바이오세라믹은 12∼15중량%, 티타늄은 3∼5중량%, 지르코늄은 13∼15중량%, 제올라이트는 13∼15중량%, 숯은 3∼5중량%, 토르말린은 13∼15중량%, 황토는 3∼5중량%, 계피는 2∼5중량%로 포함되어 구성된다.At this time, the silver nano 10 to 30% by weight, germanium is 8 to 10% by weight, bioceramic 12 to 15% by weight, titanium 3 to 5% by weight, zirconium 13 to 15% by weight, zeolite 13 15 wt%, charcoal 3-5 wt%, tourmaline 13-15 wt%, ocher 3-5 wt%, cinnamon 2-5 wt%.

그리고 상기 본 발명에 적용된 은나노가 10중량% 이하가 되면 항균성이 떨어지기게 되고, 30중량% 이상이 되면 경제성이 떨어지게 되어 상기 은나노는 10∼30 중량%가 바람직하다.When the silver nanoscale applied to the present invention is 10 wt% or less, the antimicrobial activity is lowered. When the silver nanoscale is 30 wt% or more, economical efficiency is lowered, and the silver nanoparticles are preferably 10-30 wt%.

또한 본 발명에 적용된 상기 게르마늄이 8중량% 이하가 되면 원적외선 방출량이 약화되고, 10중량% 이상이 되면 제품 표면이 매끄럽지 못해 상기 게르마늄은 8∼10중량%가 최적의 경제성을 갖게 된다.In addition, when the germanium applied to the present invention is 8% by weight or less, the far-infrared emission is weakened. When the germanium is 10% by weight or more, the surface of the product is not smooth, and the germanium has 8 to 10% by weight of optimum economical efficiency.

그리고 상기 본 발명에 적용된 바이오세라믹이 12중량% 이하가 될 경우에는 음이온과 원적외선의 방출량이 적다는 문제점이 있고, 15중량% 이상이 되면 혼합력이 약화되는 문제점이 있어 상기 바이오세라믹은 12∼15중량%가 적용됨이 바람직하다.In addition, when the bioceramic applied to the present invention is 12 wt% or less, there is a problem in that the amount of anion and far infrared rays are released, and when the bioceramic is 15 wt% or more, the mixing power is weakened. Preferably weight percent is applied.

또한 본 발명에 적용된 상기 티타늄이 3중량% 이하가 되면 원적외선 방출량이 떨어지는 문제점이 있고, 5중량% 이상이면 접착력이 떨어져 상기 티타늄은 3∼5중량%가 적용됨이 바람직하다.In addition, when the titanium applied to the present invention is less than 3% by weight, there is a problem that the far-infrared ray emission amount is lowered, and when the titanium is 5% by weight or more, the adhesive force is reduced, and the titanium is preferably 3 to 5% by weight.

또한 본 발명에 적용된 상기 지르코늄이 13중량% 이하가 되면 음이온과 원적외선의 방출량이 적어지게 되고, 15중량% 이상이면 경제성이 떨어지고 분산력이 약화되는 문제점이 있어 상기 지르코늄은 13∼15중량%가 포함됨이 바람직하다.In addition, when the zirconium applied to the present invention is less than 13% by weight, the emission amount of anion and far infrared rays is reduced, and if the weight is more than 15% by weight, the economical efficiency is lowered and the dispersing power is weakened, so that the zirconium contains 13-15% by weight. desirable.

본 발명은 또한 상기 제올라이트가 13중량% 이하가 되면 음이온과 원적외선의 방출량이 떨어지고, 15중량% 이상이면 경제성 및 접착력이 저하되는 문제점이 있어 상기 제올라이트는 13∼15중량%가 적용됨이 바람직하다.In the present invention, when the zeolite is 13% by weight or less, the amount of release of anions and far infrared rays is decreased, and when the zeolite is 15% by weight or more, economical efficiency and adhesive strength are deteriorated, so that the zeolite is preferably 13-15% by weight.

또한 본 발명에 적용된 상기 숯이 3중량% 이하가 되면 항균 및 살균 기능이 저하되고, 5중량% 이상이 되면 색상이 너무 검게 되어 상품가치가 떨어져 상기 숯은 3∼5중량%가 적용됨이 바람직하다.In addition, when the charcoal applied to the present invention is less than 3% by weight, antimicrobial and sterilization function is lowered, when the color is more than 5% by weight, the color is too dark, the product value is lowered, the charcoal is preferably applied 3 to 5% by weight. .

그리고 상기 본 발명에 적용된 토르말린이 13중량% 이하가 될 경우에는 인체의 신진대사를 촉진하는 원적외선과 음이온의 방출량이 떨어지게 되고, 15중량% 이상이 되면 경제성이 떨어지게 되어 상기 토르말린은 13∼15중량%가 포함됨이 바람직하다.When the tourmaline applied to the present invention is 13 wt% or less, the amount of far-infrared rays and anions that promote metabolism of the human body is reduced, and when the weight is 15 wt% or more, the economical efficiency is lowered, and the tourmaline is 13-15 wt%. It is preferred to include.

또한 상기 본 발명에 적용된 황토가 3중량% 이하가 될 경우에는 항균, 살균, 원적외선 기능이 저하되는 문제점이 있고, 5중량% 이상이 되면 혼합력이 저하되는 문제점이 있어 상기 황토는 3∼5중량%가 포함됨이 바람직하다.In addition, when the ocher applied to the present invention is 3% by weight or less, there is a problem that the antibacterial, sterilization, far-infrared function is lowered, when 5% by weight or more has a problem that the mixing power is lowered, the ocher is 3 to 5% by weight % Is preferably included.

더하여 본 발명에 적용된 상기 계피가 2중량% 이하가 될 경우에는 인체에 영향을 주는 항균성 최대효과 발휘가 약화 되는 문제점이 있고, 5중량% 이상이 되면 접착력이 약화되는 문제점이 있어 상기 계피는 2∼5중량%가 포함됨이 바람직하다.In addition, when the cinnamon applied to the present invention is 2% by weight or less, there is a problem in that the antibacterial maximum effect on the human body is weakened, and when 5% by weight or more, the adhesive strength is weakened. It is preferred to include 5% by weight.

상기와 같이 구성된 본 발명 조성물의 제조방법을 설명하면 다음과 같다.Referring to the manufacturing method of the composition of the present invention configured as described above are as follows.

<실시예 1><Example 1>

먼저, 본 발명은 착색제 30∼50중량%, 발포 또는 피혁용 수지 35∼40중량%, 기능성물질(은나노, 게르마늄, 바이오세라믹, 티타늄, 지르코늄, 제올라이트, 숯, 토르말린, 황토 및 계피) 8∼18중량%, 희석용제 6∼8중량%, 분산제 1∼4중량%를 상온에서 1∼2시간 상호 혼합하는 공정을 거치게 된다.First, the present invention is 30 to 50% by weight colorant, 35 to 40% by weight foam or leather resin, functional materials (silver nano, germanium, bioceramic, titanium, zirconium, zeolite, charcoal, tourmaline, ocher and cinnamon) 8-18 The mixture is subjected to a step of mixing 1% to 4% by weight of the diluent solvent and 1 to 4% by weight of the dispersant at room temperature.

또한 본 발명은 상기 혼합공정 이후 상기 혼합물을 저속, 중속, 고속의 롤밀(roll mill)을 통과시켜 곱게 분쇄하는 1차 분산공정을 거치게 된다.In addition, the present invention is subjected to the first dispersion process of grinding the mixture finely by passing through the roll mill of a low speed, medium speed, high speed after the mixing process.

본 발명은 또한 상기 분산공정 이후 상기 혼합물을 볼밀을 통해 곱게 분쇄하는 2차 분산공정을 거치게 된다.The present invention also undergoes a second dispersion step of grinding the mixture finely through a ball mill after the dispersion step.

마지막으로 본원발명은 상기 2차 분산공정에 의해 페이스트(paste) 형태의 용액인 다기능성 액상 컬러 토너 조성물을 만들게 된다.Finally, the present invention is to make a multi-functional liquid color toner composition in the form of a paste (paste) by the secondary dispersion process.

본 발명은 상기 1, 2차 분산공정을 거치므로 기능성 물질과 착색제가 피혁용 수지 내에서 각자의 별도 독립 상태로 내재되어 있던 혼합 상태를 벗어나 수지 접착력의 효과로 안료 혹은 염료가 비중이 높은 기능성 물질들에 대해 전체 코팅화가 이루어져 소량 투입으로도 기능성 물질이 더 효과가 높은 기능을 발휘하게 된다.The present invention is a functional material having a high specific gravity pigment or dye due to the effect of the resin adhesive force out of the mixed state in which the functional material and the colorant are inherently separated from each other in the resin for the leather since the first and second dispersion process The entire coating is done on the field so that even a small amount of the functional material is more effective.

<실시예 2><Example 2>

본 발명은 상기 2차 분산공정에 의해 얻어진 페이스트(paste) 형태의 용액을 70∼90℃의 온도로 24∼48시간 건조시켜 고체상태로 만드는 공정을 거치게 된다.The present invention undergoes a step of drying the solution in the form of a paste obtained by the secondary dispersion process at a temperature of 70 to 90 ° C. for 24 to 48 hours to make it into a solid state.

이후 본 발명은 상기 고체상태로 굳어진 혼합물을 파쇄기로 곱게 분쇄하여 분말 형태의 파우더로 만드는 공정에 의해 다기능성 액상 컬러 토너 조성물을 만들게 된다.Then, the present invention is to make a multi-functional liquid color toner composition by a process of grinding the mixture solidified in the solid state finely with a crusher to form a powder in powder form.

따라서 본 발명은 다기능성 액상 컬러 토너 조성물을 액상 또는 분말 형태로 제조하게 됨은 물론이다.Therefore, the present invention is of course to prepare a multi-functional liquid color toner composition in the form of a liquid or powder.

상기한 본원발명은 일반적인 투입 방식인 기능성 물질을 프리믹서 하여 넣음으로 인조합성피혁과 발포 폼이 셀의 조밀도를 약화시키지 않게 되는 효과를 제공하게 된다.The invention of the present invention is to provide the effect that the synthetic leather and foam foam does not weaken the density of the cell by pre-mixing the functional material which is a common input method.

또한 상기한 본원발명은 깨짐, 일부 한쪽 몰림 현상 발생으로 인한 기능성 발생이 고루지 못한 점도 개선 시키게 된다.In addition, the present invention improves the uneven development of the functional due to the cracking, the occurrence of some one-sided phenomenon.

그리고 본원발명은 별도의 기능성 처리된 제품을 접착제를 사용하여 붙이는 또 다른 인체 유해물 첨가와 별도의 기능성 코팅제를 제조하여 코팅 처리하는 이중의 공정 등 많은 문제점을 일거에 해소하게 되는 효과를 제공하게 된다.And the present invention will provide the effect of eliminating a number of problems, such as the addition of another human pests attaching a separate functional treated product using an adhesive and a dual process of manufacturing and coating a separate functional coating agent at a glance.

한편 본 발명은 상기의 구성부를 적용함에 있어 다양하게 변형될 수 있고 여러 가지 형태를 취할 수 있다.On the other hand, the present invention may be variously modified and may take various forms in applying the above configuration.

그리고 본 발명은 상기의 상세한 설명에서 언급되는 특별한 형태로 한정되는 것이 아닌 것으로 이해되어야 하며, 오히려 첨부된 청구범위에 의해 정의되는 본 발명의 정신과 범위 내에 있는 모든 변형물과 균등물 및 대체물을 포함하는 것으로 이해되어야 한다.And it is to be understood that the invention is not limited to the specific forms referred to in the above description, but rather includes all modifications, equivalents and substitutions within the spirit and scope of the invention as defined by the appended claims. It should be understood that.

상기와 같이 구성된 본 발명 다기능성 액상 컬러 토너 조성물의 사용방법을 설명하면 다음과 같다.Referring to the method of using the multifunctional liquid color toner composition of the present invention configured as described above is as follows.

우선, 본 발명은 상기 본 발명으로 제조된 다기능성 컬러 토너 조성물을 이용하여 인조합성피혁을 제조하게 된다.First, the present invention is to produce a synthetic leather using the multi-functional color toner composition prepared by the present invention.

즉, 의류, 신발, 자동차 시트, 쇼파, 의자, 사무용가구, 스포츠용품, 유아용완구, 건축용시트, PVC장판, 의료기구, 가구에 사용되는 인조합성피혁 제조시에 다기능성 액상 컬러 토너 조성물을 함께 혼합하면 별도의 추가 공정 없이 기존의 생산공정, 생산라인에서 다기능성 인조합성피혁을 얻을 수 있게 됨과 아울러 상기와 같이 제조된 다기능성 인조합성피혁은 항균, 살균, 탈취는 물론 원적외선과 음이온이 방사되는 효과를 제공하게 된다.That is, a multifunctional liquid color toner composition is mixed together in the manufacture of synthetic leather used in clothing, shoes, car seats, sofas, chairs, office furniture, sporting goods, baby toys, building sheets, PVC flooring, medical equipment, and furniture. The multifunctional synthetic leather can be obtained from the existing production process and production line without any additional process, and the multifunctional synthetic leather manufactured as described above has the effect of radiation of far infrared rays and anions as well as antibacterial, sterilization and deodorization. Will be provided.

또한 본원발명은 상기 본 발명으로 제조된 다기능성 컬러 토너 조성물을 이 용하여 발포 폼을 제조하게 된다.In addition, the present invention is to prepare a foam using the multi-functional color toner composition prepared by the present invention.

즉, 실리콘 폼, 고무 폼, 우레탄 폼 제조시에 다기능성 액상 컬러 토너 조성물을 함께 혼합하면 별도의 추가 공정 없이 기존의 생산공정, 생산라인에서 다기능성 발포 폼을 얻을 수 있게 됨과 아울러 상기와 같이 제조된 다기능성 발포 폼은 항균, 살균, 탈취는 물론 원적외선과 음이온이 방사되는 효과를 제공하게 된다.That is, when the multi-functional liquid color toner composition is mixed together in the production of silicone foam, rubber foam, and urethane foam, the multifunctional foam can be obtained in the existing production process and production line without any additional process and is manufactured as described above. The multifunctional foams will provide the antibacterial, antiseptic, deodorizing effect as well as the radiation of far infrared rays and anions.

상기 본원발명에 적용된 인조합성피혁과 발포 폼은 용도별 반드시 착색제를 투여하여 색상을 내야 하는 것으로, 본원발명에 적용된 상기 다기능성 액상 컬러 토너 조성물을 함께 혼합하면 별도의 추가 공정 없이 기존의 생산공정, 생산라인에서 다기능성 인조합성피혁과 발포 폼을 얻을 수 있게 된다.The synthetic leather and the foam foam applied to the present invention must be colored by administering a colorant for each use, and when the multifunctional liquid color toner composition applied to the present invention is mixed together, the existing production process and production without additional processes Multifunctional phosphorus leather and foam foam are available on the line.

상기에서 상세히 살펴본 바와 같이 본 발명은 항균, 살균, 탈취는 물론 원적외선과 음이온이 방사되는 액상 컬러 토너 조성물을 제공하는 것이다.As described in detail above, the present invention provides a liquid color toner composition in which far infrared rays and anions are radiated, as well as antibacterial, sterilizing, and deodorizing.

또한 본 발명은 별도의 추가공정 없이 기존의 생산공정, 생산라인에서 기능성 피혁용 수지와 발포 폼을 얻을 수 있도록 한 것이다.In addition, the present invention is to obtain a functional leather resin and foam foam in the existing production process, production line without any additional process.

본 발명은 또한 불필요한 공정을 제거함으로 생산성 향상과 원가절감 및 특히 인체에 유해한 접착와 코팅제를 사용하지 않게 되는 장점이 있다.The present invention also has the advantage of eliminating unnecessary processes, improving productivity, reducing costs, and in particular not using harmful adhesives and coatings.

더하여 본 발명은 기능성 물질과 착색제가 피혁용 수지 내에서 각자의 별도 독립 상태로 내재되어 있던 혼합 상태를 벗어나 수지 접착력의 효과로 안료 혹은 염료가 비중이 높은 기능성 물질들에 대해 전체 코팅화가 이루어져 소량 투입으로 도 기능성 물질이 더 효과가 높은 기능을 발휘하도록 한 것이다.In addition, in the present invention, a small amount of the coating material is added to the functional materials having a high specific gravity by pigment or dye due to the effect of resin adhesion, out of the mixed state in which the functional material and the colorant are inherently separated from each other in the leather resin. In addition, the functional material is to have a more effective function.

본 발명은 상기한 효과로 인해 제품의 품질과 신뢰성을 대폭 향상시켜 소비자로 하여금 좋은 이미지를 심어줄 수 있도록 한 매우 유용한 발명인 것이다.The present invention is a very useful invention that can significantly improve the quality and reliability of the product due to the above-described effect so that consumers can plant a good image.

Claims (8)

염료 또는 안료로 이루어진 착색제, 발포 또는 피혁용 수지, 기능성 물질, 희석용제 및 분산제가 상호 혼합되어 얻어지는 다기능성 액상 컬러 토너 조성물.A multifunctional liquid color toner composition obtained by mixing a colorant consisting of a dye or a pigment, a resin for foaming or leather, a functional substance, a diluent solvent, and a dispersant. 제 1 청구항에 있어서,According to claim 1, 상기 착색제는 30∼50중량%, 발포 또는 피혁용 수지는 35∼40중량%, 기능성물질은 8∼18중량%, 희석용제는 6∼8중량%, 분산제는 1∼4중량%가 포함됨을 특징으로 하는 다기능성 액상 컬러 토너 조성물.30 to 50% by weight of the colorant, 35 to 40% by weight of foaming or leather resin, 8 to 18% by weight of functional material, 6 to 8% by weight of diluent, and 1 to 4% by weight of dispersant. Multifunctional liquid color toner composition. 제 1 또는 제 2 청구항에 있어서,The method according to claim 1 or 2, 상기 기능성물질은 은나노, 게르마늄, 바이오세라믹, 티타늄, 지르코늄, 제올라이트, 숯, 토르말린, 황토 및 계피가 포함됨을 특징으로 하는 다기능성 액상 컬러 토너 조성물.The functional material is a multifunctional liquid color toner composition comprising silver nano, germanium, bioceramic, titanium, zirconium, zeolite, charcoal, tourmaline, ocher and cinnamon. 제 3 청구항에 있어서,According to claim 3, 상기 은나노는 10∼30중량%, 게르마늄은 8∼10중량%, 바이오세라믹은 12∼15 중량%, 티타늄은 3∼5중량%, 지르코늄은 13∼15중량%, 제올라이트는 13∼15중량%, 숯은 3∼5중량%, 토르말린은 13∼15중량%, 황토는 3∼5중량%, 계피는 2∼5중량%임을 특징으로 하는 다기능성 액상 컬러 토너 조성물.10-30% by weight of silver nano, 8-10% by weight of germanium, 12-15% by weight of bioceramic, 3-5% by weight of titanium, 13-15% by weight of zirconium, 13-15% by weight of zeolite, 3 to 5% by weight of charcoal, 13 to 15% by weight tourmaline, 3 to 5% by weight ocher, 2 to 5% by weight cinnamon. 착색제 30∼50중량%, 발포 또는 피혁용 수지 35∼40중량%, 기능성물질(은나노, 게르마늄, 바이오세라믹, 티타늄, 지르코늄, 제올라이트, 숯, 토르말린, 황토 및 계피) 8∼18중량%, 희석용제 6∼8중량%, 분산제 1∼4중량%를 상온에서 1∼2시간 상호 혼합하는 공정;30 to 50% by weight of colorant, 35 to 40% by weight of foam or leather resin, 8 to 18% by weight of functional substance (silver nano, germanium, bioceramic, titanium, zirconium, zeolite, charcoal, tourmaline, ocher and cinnamon), diluent Mixing 6 to 8% by weight and 1 to 4% by weight of the dispersant at room temperature for 1 to 2 hours; 상기 혼합공정 이후 상기 혼합물을 저속, 중속, 고속의 롤밀(roll mill)을 통과시켜 곱게 분쇄하는 1차 분산공정;A first dispersion step of grinding the mixture finely by passing the mixture through a low, medium, and high speed roll mill; 상기 분산공정 이후 상기 혼합물을 볼밀을 통해 곱게 분쇄하는 2차 분산공정; 및 A second dispersion step of grinding the mixture finely through the ball mill after the dispersion step; And 상기 2차 분산공정에 의해 페이스트(paste) 형태의 용액을 얻는 다기능성 액상 컬러 토너 조성물의 제조방법.A method for producing a multifunctional liquid color toner composition which obtains a paste solution by the secondary dispersion process. 제 5 청구항에 있어서,The method of claim 5 wherein 상기 2차 분산공정에 의해 얻어진 페이스트(paste) 형태의 용액을 70∼90℃의 온도로 24∼48시간 건조시켜 고체상태로 만드는 공정; 및Drying the paste-shaped solution obtained by the second dispersion step at a temperature of 70 to 90 ° C. for 24 to 48 hours to make it into a solid state; And 이후 상기 고체상태로 굳어진 혼합물을 파쇄기로 곱게 분쇄하여 분말 형태의 파우더로 만드는 공정;이 포함됨을 특징으로 하는 다기능성 액상 컬러 토너 조성물의 제조방법.And then pulverizing the mixture solidified in the solid state finely with a crusher to form a powder in powder form. 제 5 청구항의 방법으로 제조된 다기능성 액상 컬러 토너 조성물을 의류, 신발, 자동차 시트, 쇼파, 의자, 사무용가구, 스포츠용품, 유아용완구, 건축용시트, PVC장판, 의료기구, 가구에 사용되는 인조합성피혁 제조시에 함께 혼합하여 인조합성피혁이 항균, 살균, 탈취는 물론 원적외선과 음이온이 방사되도록 함을 특징으로 하는 다기능성 액상 컬러 토너 조성물의 사용방법.The multifunctional liquid color toner composition prepared by the method of claim 5 is used in clothing, shoes, automobile seats, sofas, chairs, office furniture, sporting goods, baby toys, building sheets, PVC flooring, medical equipment, and furniture. Method of using a multi-functional liquid color toner composition characterized in that the synthetic leather is mixed together during manufacture of the leather so that the anti-infrared and anion are emitted as well as antibacterial, sterilizing, deodorizing. 제 5 청구항의 방법으로 제조된 다기능성 액상 컬러 토너 조성물을 실리콘 폼, 고무 폼, 우레탄 폼 제조시에 함께 혼합하여 상기 폼이 항균, 살균, 탈취는 물론 원적외선과 음이온이 방사되도록 함을 특징으로 하는 다기능성 액상 컬러 토너 조성물의 사용방법.The multi-functional liquid color toner composition prepared by the method of claim 5 is mixed together in the manufacture of silicone foam, rubber foam, and urethane foam, so that the foam is antibacterial, sterilized, deodorized, as well as far infrared rays and anions are emitted. Method of using the multifunctional liquid color toner composition.
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