KR100829023B1 - High-pressure liquid injection method for in-situ remediation of contaminated soil, and the apparatus of that - Google Patents
High-pressure liquid injection method for in-situ remediation of contaminated soil, and the apparatus of that Download PDFInfo
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- KR100829023B1 KR100829023B1 KR1020070017499A KR20070017499A KR100829023B1 KR 100829023 B1 KR100829023 B1 KR 100829023B1 KR 1020070017499 A KR1020070017499 A KR 1020070017499A KR 20070017499 A KR20070017499 A KR 20070017499A KR 100829023 B1 KR100829023 B1 KR 100829023B1
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Abstract
Description
도 1은 본 발명 방법의 공정 블록도.1 is a process block diagram of the method of the present invention.
도 2는 본 발명 장치의 일실시예 구성도.Figure 2 is an embodiment configuration of the device of the present invention.
도 3은 본 발명 장치를 구성하는 일실시예 주입정의 구조도.Figure 3 is a structural diagram of one embodiment injection tablet constituting the device of the present invention.
((도면의 주요 부분에 대한 부호의 설명)) ((Explanation of symbols for main part of drawing))
21. 미생물액 탱크 22. 고압공기주입기 21.
22A,23A. 대차 22B. 에어컴프레셔 22A, 23A.
23. 미생물액주입기 23B. 액주입펌프 23.
24. 주입정 24A. 몸체 24. Injection well 24A. Body
24B.연결부 H 주입공 24B.H Connection hole
h. 통공 S. 오염토양 h. Through S. Polluted Soil
본 발명은, 오염토양의 복원을 위하여 오염토양에 압축공기를 주입하여 지반의 균열을 증가시켜 오염토양 지반의 통기성을 높인 상태에서, 미생물액을 고압으로 주입하여 오염토양을 효율적으로 정화할 수 있도록 하는, 오염토양 정화를 위한 지중고압액상주입 방법과 장치에 관한 것이다.
참고로, 본 발명은 환경부에서 지원하는 차세대 핵심환경기술개발사업의 성과물로서, 연구개발과제의 고유번호는 041-061-039 이며, 연구개발과제명은 "유류오염 토양-지하수의 저온열처리 및 생물학적 정화기술을 연계한 동시 복원기술 개발(Development of LTTD system combined with bioremediation to treat oil-contaminated soil and groundwater)"이다.The present invention, in order to restore the contaminated soil by injecting compressed air into the contaminated soil to increase the cracks of the soil to increase the air permeability of the contaminated soil ground, by injecting microbial fluid at high pressure to efficiently clean the contaminated soil The present invention relates to a method and apparatus for underground high pressure liquid phase injection for contaminating soil.
For reference, the present invention is the achievement of the next-generation core environmental technology development project supported by the Ministry of Environment, the unique number of the research and development project is 041-061-039, and the title of the research and development project is "Low temperature heat treatment and biological purification of oil-contaminated soil-ground water". Development of LTTD system combined with bioremediation to treat oil-contaminated soil and groundwater.
산업의 발달과 더불어 초래된 환경 오염은 크게, 대기 오염, 수질 오염 및 토양 오염으로 구분할 수 있는 바, 특히, 이들 중 토양 오염은 식량 생산에 매우 심각한 위협이 되고, 지하수 오염을 통한 수질 오염을 유발시킬 뿐 아니라, 대기 오염이나 수질 오염에 비하여 해결하기가 쉽지 않은 문제가 있다.Environmental pollution caused by the development of the industry can be classified into air pollution, water pollution and soil pollution. Among them, soil pollution is a very serious threat to food production and causes water pollution through groundwater pollution. In addition, there is a problem that is not easy to solve compared to air pollution or water pollution.
따라서, 상기와 같은 오염 토양을 복원하기 위하여 다양한 방법이 연구 개발되었는 바, 오염 토양의 복원 방법은, 지하에서 이루어지는 지중처리법과 지상에서 이루어지는 지상처리법으로 크게 분류할 수 있는데, 지중처리법은, 오염된 토양을 굴착하지 않고 세척 용액 주입정, 세척 용액 배출정, 세척 유출수 처리시설, 펌프 및 계장 시설, 휘발물질 처리 시설 등을 오염된 토양에 설치한 후 처리하고자 하는 오염토양 내에 세척수를 순환시켜 오염토양을 직접 세척하는 방법으로서, 처리 시간이 길고 세척액의 회수가 어려운 단점이 있다.Therefore, various methods have been researched and developed to restore the contaminated soils. The restoration methods of the contaminated soils can be broadly classified into underground treatment methods performed underground and ground treatment methods performed above the ground. Polluted soil by circulating the wash water in the contaminated soil to be installed after installing the washing solution injection well, washing solution discharge well, washing effluent treatment facility, pump and instrumentation facility, and volatile material treatment facility without digging the soil. As a method of directly washing, there is a disadvantage in that the treatment time is long and the recovery of the washing liquid is difficult.
그리고, 지상처리법은 토양내 오염물질의 분포 및 토양의 물리/화학적 특성을 파악하여 처리하고자 하는 범위의 오염된 토양을 굴착한 후, 적절한 세척액이나 화학 약품 등으로 굴착된 오염토양을 세척하는 방법으로서, 오염토양 부지에 각종 시설물이 있는 대다수의 오염 현장의 경우에는 그 적용이 매우 제한적이다.In addition, the ground treatment method is a method of cleaning the contaminated soil excavated with an appropriate cleaning solution or chemicals after excavating contaminated soil in the range to be treated by grasping the distribution of contaminants in the soil and physical / chemical characteristics of the soil. However, the application is very limited in the case of the majority of pollution sites with various facilities on contaminated soil sites.
따라서, 대다수의 오염토양 복원에는 지중처리법이 적용되고 있는 바, 지중처리법은, 생물학적 방법과 화학적 방법으로 대별되는데 지중에 관정을 삽입하여 관정을 통하여 원하는 목적물을 분해하고 추출하는 기술로 바이오밴팅(Bioventing)이나 식물정화법(Phytoremediation) 등은 미생물을 이용한 방법이고, 화학적 산화법이나 토양증기추출법(SVE), 공기주입확산공법(Air Sparging), 바이오슬러핑(Bioslurping)공법 등은 화학적 또는 물리적으로 처리하는 방법이라 할 수 있다.Therefore, the ground treatment method is applied to the restoration of the most contaminated soils, which is classified into biological methods and chemical methods. Bioventing is a technique for decomposing and extracting a desired object through the well by inserting a well into the ground. ) Or Phytoremediation is a method using microorganisms, and chemical oxidation, soil vapor extraction (SVE), air sparging, bioslurping, etc. are chemical or physical treatments. This can be called.
상기와 같은 지중처리법은, 오염토양에 관정을 굴착한 후 관정에 관체형 주입정을 삽입하고, 이 주입정으로 약품, 산화제, 미생물 등을 오염된 토양에 주입함으로써, 오염물이 분해되도록 하는 것이 일반적이다.In the underground treatment method as described above, it is common to excavate a well in a contaminated soil, insert a tubular injection well into the well, and inject chemicals, oxidants, microorganisms, etc. into the contaminated soil so that the contaminants are decomposed. to be.
상기 지중처리법은 오염된 토양이나 지하수를 정화하기 위하여 지중에 공기, 약품, 미생물 등을 주입하는 기술로서, 초기에는 관정을 통하여 기상 또는 액상의 물질을 오염된 위치까지 흘려보냈으나, 근래에는 고압주입정을 이용하는 방식으로 발전하였는 바, 국내 실용신안등록 제308522호에 "오염토양 및 지하수 복원을 위한 고압 주입정"이, 국내 실용신안등록 제308522호에 "오염토양 및 지하수 복원을 위한 차량 탑재형 산화제 주입장치"가 각각 게시되어 있다.The underground treatment method is a technique of injecting air, medicine, microorganisms into the ground to purify the contaminated soil or groundwater. Initially, gaseous or liquid substances were flowed through the wells to the contaminated location, but in recent years high pressure injection wells It was developed in the manner of using the Korean Utility Model Registration No. 308522, "High Pressure Injection Well for Restoring Polluted Soil and Groundwater", and Korean Utility Model Registration No. 308522, "In-vehicle oxidant for restoring contaminated soil and groundwater. Injection devices "are each published.
그러나, 상기 실용신안등록의 주입정이나 구입장치 등과 같은 종래의 주입정 을 사용한 정화 방법은, 산화제 등과 같은 액상의 화학약품을 주입하기 때문에 화학약품에 의한 2차 오염의 문제가 있다.However, the conventional purification method using a conventional injection well, such as the injection well or purchase device of the utility model registration, there is a problem of secondary contamination by chemicals because the injection of a liquid chemical, such as an oxidizing agent.
그리고, 고압주입정을 사용하는 경우에도 주입 범위가 제한될 수 밖에 없으며 특히, 투수계수가 낮고 압밀된 오염토양의 경우에는 주입물의 주입 범위가 더욱 축소되어 관정의 수가 더욱 많이 필요하게 됨으로써 처리 비용과 시간이 과다하게 증가하게 된다.In addition, even when using a high-pressure injection well, the injection range is limited, and in particular, in the case of a low permeability coefficient and condensed soil, the injection range of the injection is further reduced, so that the number of wells is required, thereby increasing the processing cost and The time is increased excessively.
또한, 오염토양 내에 있는 지상 시설물들이 있는 경우 정화 작업을 실시할 수 있는 공간이 협소할 수 밖에 없는 바, 주입정을 사용하는 종래의 일반적인 지중처리법은 실시하기 어려운 단점이 있다.In addition, when there are ground facilities in the contaminated soil, the space for performing the purification operation is inevitably narrow, so that the conventional general underground treatment method using the injection well is difficult to carry out.
본 발명은, 주입정을 사용하여 화학약품을 주입하는 종래의 오염토양 정화 방법이 가지고 있는 제반 문제점들을 해결하기 위하여 창안된 것으로, 고압공기만을 우선 충분히 분사하여 오염토양 지반 내에 충분한 크랙을 형성시킨 상태에서 전용 장치를 통해 활성이 유지된 미생물액을 주입함으로써, 미생물액의 주입 범위를 확대하는 동시에 2차 오염의 문제가 없는, 오염토양 정화를 위한 지중고압액상주입 방법과 장치를 제공함에 본 발명의 목적이 있다.The present invention has been devised to solve all the problems of the conventional soil cleaning method using chemical injection wells, and only a sufficient amount of high-pressure air is first sprayed to form a sufficient crack in the soil soil. By injecting the microbial fluid maintained active through the dedicated device in the present invention, to provide a high pressure liquid injection method and apparatus for the purification of contaminated soil, while expanding the injection range of the microbial fluid and without the problem of secondary pollution There is a purpose.
또한, 지상 시설물이 있기 때문에 정화 작업 공간이 협소한 경우 효율적으로 오염토양을 정화할 수 있는 방법과 장치를 제공함에 본 발명의 다른 목적이 있다.In addition, there is another object of the present invention to provide a method and apparatus capable of efficiently purifying contaminated soil when the purification work space is narrow because there is a ground facility.
본 발명의 상기 목적은, 오염토양의 지반에 크랙을 형성시키기 위한 고압공기주입기와, 자유로운 이동이 가능한 대차형 미생물액주입기에 의하여 달성된다.The above object of the present invention is achieved by a high-pressure air injector for forming cracks in the soil of contaminated soil, and a bogie-type microbial fluid injector which is freely movable.
본 발명의 오염토양 정화를 위한 지중고압액상주입 방법과 장치는, 오염토양 내에 미생물액을 효과적으로 주입시키기 위한 것으로, 본 발명의 방법은,The underground high pressure liquid phase injection method and apparatus for purifying contaminated soil of the present invention are for effectively injecting the microbial fluid into the contaminated soil.
오염토양에 다수의 주입공을 굴착하는 단계와; 각 굴착공에 고압공기를 주입하는 단계와; 각 굴착공에 미생물액을 주입하는 단계 등으로 이루어지는 바, 미생물액을 주입하기 전 고압공기를 주입함에 본 발명의 기술적 특징이 있다.Digging a plurality of injection holes in the contaminated soil; Injecting high pressure air into each excavation hole; It consists of the step of injecting microbial fluid into each excavation hole, there is a technical feature of the present invention to inject high-pressure air before injecting the microbial fluid.
즉, 미생물액을 주입하기 전 굴착공을 통하여 오염토양 지반에 고압공기를 충분히 주입하여 오염토양 지반에 다수의 균열을 발생시킴으로써, 이후에 주입되는 미생물액의 주입 시 그 확산 범위를 극대화할 수 있게 된다.That is, by injecting enough high-pressure air into the contaminated soil ground through the excavation hole before injecting the microbial liquid, a large number of cracks are generated in the contaminated soil ground, so that the diffusion range of the microbial liquid injected afterwards can be maximized. do.
상기와 같은 본 발명의 방법은 지중처리법으로서, 특히, 오염토양 내에 있는 지상 시설물들의 철거가 어렵거나, 공장 등을 가동하면서 정화하여야 하는 경우, 즉, 오염토양의 굴착이 현실적으로 불가능한 경우를 위한 것으로, 오염토양 경계부 등에 일시적으로 고정 설치되는 미생물액 탱크와; 오염토양 내에 고압공기를 주입하기 위한 이동형 고압공기주입기와; 미생물액 탱크에서 미생물액을 공급받아 오염토양에 주입하기 위한 이동형 미생물액주입기와; 오염토양에 굴착된 주입공으로 삽입되는 주입정 등으로 구성되는 바, 각각을 살펴보면 다음과 같다.As described above, the method of the present invention is an underground treatment method, in particular, when it is difficult to dismantle the ground facilities in the contaminated soil, or to clean it while operating a plant, that is, when the excavation of contaminated soil is practically impossible. A microbial fluid tank temporarily fixed to a contaminated soil boundary; A mobile high pressure air injector for injecting high pressure air into the contaminated soil; A mobile microbial fluid injector for receiving the microbial fluid from the microbial fluid tank and injecting the microbial fluid into the contaminated soil; Consists of injection wells inserted into injection holes excavated in contaminated soil, looking at each as follows.
미생물액 탱크는, 미생물이 함유된 액이 저장되는 탱크로서, 정화 대상 오염토양의 지상 일측에 일시 고정 설치되며, 미생물의 활성도가 최적화된 상태로 유지 될 수 있도록 탱크는 단열처리되고, 온도 유지를 위한 히터가 구비된다.The microbial fluid tank is a tank for storing a microbe-containing liquid. The microbial fluid tank is temporarily fixed to one side of the ground of the contaminated soil to be purified, and the tank is insulated so that the activity of the microorganism can be maintained in an optimized state. A heater is provided.
그리고, 미생물의 활성화에 필요로 되는 영양제를 공급하면서, 미생물액의 산도 조절을 위하여 산과 알칼리를 공급하기 위한 산 탱크 및 알칼리 탱크, 영양제 탱크가 부가적으로 연결될 수도 있다.In addition, an acid tank, an alkali tank, and a nutrient tank for supplying acid and an alkali for controlling acidity of the microbial fluid may be additionally connected while supplying a nutrient required for activation of the microorganism.
고압공기주입기는, 오염토양 지반에 균열을 발생시키기 위한 것으로, 이동이 자유로운 대차와; 대차에 안착된 에어컴프레셔로 구성된다.The high pressure air injector is for generating a crack in the soil soil, and the trolley can move freely; It consists of an air compressor seated on a truck.
미생물액주입기는, 상기 미생물 탱크로부터 미생물액을 공급받은 후 이를 오염토양 내에 주입하기 위한 것으로, 이동이 자유로운 대차와; 대차에 안착된 액주입펌프로 구성된다.The microbial fluid injector is for injecting the microbial fluid from the microbial tank and then injecting it into the contaminated soil. It consists of a liquid injection pump seated on the truck.
주입정은, 상기 고압공기와 미생물액이 분사되는 노즐의 역할을 하는 상향 개방형의 관체로서, 그 상단부에 상기 고압공기주입기와 미생물액주입기가 함께 배관 연결되며, 외주면에는 다수의 통공이 관통 형성된 구조이다.The injection well is a tube of an upward opening type that serves as a nozzle for injecting the high pressure air and the microbial fluid, and the high pressure air injector and the microbial fluid injector are piped together at an upper end thereof, and a plurality of through holes are formed in the outer circumferential surface thereof. .
상기와 같은 본 발명의 장치는, 고압공기주입기와 미생물액주입기가 이동이 자유로운 대차형인 바, 주입공에 삽입되는 주입정을 고압공기주입기와 미생물액주입기를 함께 이동시키면서 필요로 되는 곳에 미생물액을 주입할 수 있게 된다.The apparatus of the present invention as described above, the high-pressure air injector and the microbial fluid injector is a free-to-move bogie type, the microbial fluid is placed where necessary while moving the injection well inserted into the injection hole together with the high-pressure air injector and the microbial fluid injector. Injectable.
상기 본 발명의 목적과 기술적 구성을 비롯한 그에 따른 작용 효과에 관한 자세한 사항은 본 발명의 바람직한 실시예를 도시하고 있는 도면을 참조한 아래의 설명에 의해 명확하게 이해될 것이다.Details of the effects and the resulting effects, including the object and technical configuration of the present invention will be clearly understood by the following description with reference to the drawings showing a preferred embodiment of the present invention.
도 1에 본 발명 방법의 공정 블록도를, 도 2에 본 발명 장치의 구성도를 도시하였다.The process block diagram of the method of this invention is shown in FIG. 1, and the block diagram of the apparatus of this invention is shown in FIG.
도시된 바와 같이 본 발명의 오염토양 정화를 위한 지중고압액상주입 방법은,As shown, the underground high pressure liquid injection method for the purification of contaminated soil of the present invention,
정화 대상 오염토양 일측에 미생물액 탱크를 설치하는 단계(100)와;Installing a microbial fluid tank on one side of the contaminated soil;
상기 미생물액 탱크에 대차형 미생물액주입기를 배관 연결하는 단계(200)와;Connecting a pipe-type microbial fluid injector to the microbial fluid tank (200);
오염토양 내에 다수의 주입공을 굴착하는 단계(300)와;Excavating a plurality of injection holes in the contaminated soil (300);
대차형 고압공기주입기와 미생물액주입기에 배관 연결된 주입정을 각 굴착공에 삽입한 후 고압공기를 주입하는 단계(400)와;Inserting an injection well connected to the bogie-type high pressure air injector and the microbial fluid injector into each excavation hole and then injecting high pressure air (400);
미생물액을 주입하는 단계(500) 등의 순차적 공정들로 이루어진다.It consists of sequential processes such as the step of injecting the microbial fluid (500).
상기와 같은 본 발명의 방법을 실시하기 위한 장치는,Apparatus for implementing the method of the present invention as described above,
오염토양(S) 일측에 일시적으로 고정 설치되는 미생물액 탱크(21)와;A
상기 오염토양(S) 내에 고압공기를 주입하기 위한 것으로, 이동이 자유로운 대차(22A)와, 대차(22A)에 안착된 에어컴프레셔(22B)로 이루어진 고압공기주입기(22)와;A high-
상기 오염토양(S) 내에 미생물액을 주입하기 위한 것으로, 이동이 자유로운 대차(23A)와, 대차(23A)에 안착되며 상기 미생물액 탱크(21)에 배관 연결되는 액주입펌프(23B)로 이루어진 미생물액주입기(23)와;It is for injecting microbial fluid into the contaminated soil (S), consisting of a
상기 오염토양(S)에 굴착된 주입공(H)으로 삽입되며, 상단부가 고압공기주입기(22) 및 미생물액주입기(23)에 각각 배관 연결되는 주입정(24) 등으로 구성된다. Inserted into the injection hole (H) excavated in the contaminated soil (S), the upper end is composed of an injection well 24 and the like connected to the high-
이때, 상기 주입정(24)에는 고압공기주입기(22) 및 미생물액주입기(23)가 각 각 배관 연결되는 바, 도 3에 도시된 바와 같이, 하단부가 막힌 상향 개방형의 관체형 몸체(24A)와, 몸체(24A)의 개방 상단부에 결합되는 연결부(24B)로 구성하되, 이 연결부(24B)를 두 방향으로 분기한 후 고압공기주입기(22) 및 미생물액주입기(23)를 각각 배관 연결하게 된다.At this time, the injection well 24 is connected to the high-
그리고, 상기 주입정의 몸체(24A)의 외주면에는 다수의 통공(h)이 상·하 방향으로 관통 형성되는 바, 상기 통공(h)을 원형이나 좌·우 방향으로 형성시킬 수도 있으나, 상·하 일자형 통공(h)이 효율성 측면에서는 바람직하다.In addition, a plurality of through holes h are formed in the outer circumferential surface of the
또한, 미생물의 보존 및 활성도 유지를 위하여, 미생물액 탱크(21)에, 영양제 탱크와, pH 조절을 위한 산 탱크 및 알칼리 탱크를 부가적으로 연결 설치하고, 미생물액의 온도 유지를 위하여 미생물액 탱크를 단열처리하는 동시에 히터를 결합하는 것이 좋다.In addition, in order to preserve microorganisms and maintain activity, the
그 외에, 정화 대상 오염토양의 면적이 넓은 경우 미생물액 탱크(21)와 미생물액주입기(23) 사이의 배관이 지나치게 길어지면서 미생물액 탱크(21)에서 미생물액주입기(23)로 공급되는 미생물액의 활성도가 떨어질 수도 있는 바, 소용량의 미생물액 간이 탱크(도면 미도시)를 대차(도면 미도시)에 안착시킨 미생물액 이송수단을 구비하는 것도 바람직하다.In addition, when the area of the contaminated soil to be purified is large, the microbial fluid supplied from the
즉, 미생물액 이송수단을 미생물액주입기(23)에 인접하도록 배관 연결하고, 미생물액 이송수단을 미생물액 탱크(21)에 연결한 후 미생물액 이송수단의 간이 탱크에 미생물액을 일시 저장할 수도 있다.That is, the microbial fluid transfer means may be connected to the
이때, 상기 간이 탱크 역시 미생물액의 활성 유지를 위하여 위하여 단열처리 하는 동시에 히터를 결합하고, 간이 탱크 이동용 대차에 소용량의 산 탱크, 알칼리 탱크, 영양제 탱크 등을 부가적으로 결합하는 것도 바람직하다.At this time, the simple tank is also insulated for maintaining the activity of the microbial fluid at the same time coupled to the heater, it is also preferable to additionally combine a small capacity acid tank, alkali tank, nutrient tank and the like to the tank for transporting the simple tank.
이상에서 살펴본 바와 같이, 본 발명의 오염토양 정화를 위한 지중고압액상주입 방법과 장치는, 고압공기주입기에 의해 오염토양 지반을 균열시키기 때문에 미생물액의 주입 확산 범위가 확대되어 정화 효율이 향상되며, 미생물액 저장 탱크와 미생물액 주입기로 분리되는 동시에 미생물액 주입기와 고압공기주입기의 자유로운 이동이 가능하기 때문에 협소한 공간에서도 정화 작업을 손쉽게 할 수 있는 장점이 있다.As described above, the method and apparatus for underground high pressure liquid phase injection for contaminating soil soil according to the present invention, since the soil soil is cracked by a high pressure air injector, the injection diffusion range of the microbial fluid is expanded, and the purification efficiency is improved. The microbial fluid storage tank and the microbial fluid injector are separated at the same time, so the microbial fluid injector and the high-pressure air injector can be freely moved.
또한, 미생물액 탱크나 미생물액 이송수단의 간이 탱크가 각각 단열처리되는 동시에, 각 탱크에 히터, 산 탱크, 알칼리 탱크, 영양제 탱크 등이 구비됨으로써 미생물의 활성도가 최적 상태로 유지되기 때문에 정화 효율이 더욱 높아지게 되는 이점이 있다.In addition, the microbial fluid tank or the simple tank of the microbial fluid transfer means are insulated from each other, and each tank is provided with a heater, an acid tank, an alkali tank, and a nutrient tank, so that the activity of the microorganisms is maintained in an optimum state, so that the purification efficiency is improved. There is an advantage to be higher.
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