KR100772331B1 - Method of manufacturing an austenitic stainless steel for decreasing a surface roughness defects - Google Patents

Method of manufacturing an austenitic stainless steel for decreasing a surface roughness defects Download PDF

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KR100772331B1
KR100772331B1 KR20060137075A KR20060137075A KR100772331B1 KR 100772331 B1 KR100772331 B1 KR 100772331B1 KR 20060137075 A KR20060137075 A KR 20060137075A KR 20060137075 A KR20060137075 A KR 20060137075A KR 100772331 B1 KR100772331 B1 KR 100772331B1
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stainless steel
austenitic stainless
hot rolling
manufacturing
bar
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KR20060137075A
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Korean (ko)
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김선구
최점용
이종석
최자용
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주식회사 포스코
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Crystallography & Structural Chemistry (AREA)
  • Metal Rolling (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

A method of manufacturing an austenitic stainless steel with superior surface quality is provided to reduce defects in surface roughness by properly controlling a de-scaling method. A method of manufacturing an austenitic stainless steel with superior surface quality includes the steps of: separating residual scale from casting material during a continuous casting process by submerging the casting material in a water tub for more than 10 minutes; transferring the casting material to a hot rolling process; and additionally removing residual scale by spraying water onto the casting material at a de-scaling pressure over 3 bar when the thickness of a bar ranges from 94mm to 100mm during the hot rolling process.

Description

표면품질이 우수한 오스테나이트계 스테인리스강 제조방법{Method of manufacturing an austenitic stainless steel for decreasing a surface roughness defects}Method for manufacturing an austenitic stainless steel for decreasing a surface roughness defects}

도 1은 일반적인 오스테나이트계 스테인리스강판의 제조방법의 모식도,1 is a schematic diagram of a manufacturing method of a common austenitic stainless steel sheet,

도 2는 본 발명에 관한 면거침에 미치는 열간압연시 디스케일링 방법의 영향을 나타낸 도면,2 is a view showing the effect of the descaling method during hot rolling on the surface roughness of the present invention,

도 3은 본 발명에 의한 면거침 결함 저감 효과를 나타낸 도면이다3 is a view showing the surface roughness defect reduction effect according to the present invention.

본원발명은 표면품질이 우수한 오스테나이트계 스테인리스강 제조방법에 관한 것으로, 더욱 상세하게는 오스테나이트계 스테인리스강 제조시 냉연제품의 면거침 결함을 저감하는 연속주조-열간압연 공정에서의 제조조건으로, 연속주조공정에서의 주편냉각방법, 열간압연시 디스케일링 조건을 적절히 제어하여 냉연제품 표면의 면거침 결함을 저감하기 위한 표면품질이 우수한 오스테나이트계 스테인리스강 의 제조방법에 관한 것이다. The present invention relates to a method for producing austenitic stainless steel with excellent surface quality, and more particularly, to the manufacturing conditions in the continuous casting-hot rolling process to reduce the surface roughness defects of cold-rolled products when manufacturing austenitic stainless steel, The present invention relates to a method for producing austenitic stainless steel having excellent surface quality for reducing surface roughness defects on the surface of cold rolled products by appropriately controlling the descaling conditions during continuous casting process and hot rolling.

일반적으로 스테인리스 냉연제품은 연주 공장에서 중간소재인 주편을 생산하여 열간압연 공장에서 재가열 후 압연하여 블랙코일을 생산, 열연 소둔산세 공장에서 열처리 및 산세공정을 통한 스케일 제거한 후 냉연공장에서 압연 및 냉연 소둔 산세를 통해 생산한다. In general, stainless steel cold rolled products are produced from cast iron, which is an intermediate material, in the casting factory, reheated in a hot rolling mill, and then rolled to produce black coils. Produced by pickling.

이때, 연주주편 표면에 잔류하는 몰드 슬래그 성분이 열간압연 공정에서 제거되지 못하고 잔류할 경우 열연코일 표면에 요철을 형성하고, 최종적으로는 냉연제품 표면에 면거침 결함을 유발하게 되어 미려한 표면이 요구되는 고급용도로의 적용이 제한된다.At this time, if the mold slag component remaining on the surface of the cast slab cannot be removed in the hot rolling process, irregularities are formed on the surface of the hot rolled coil, and finally, surface roughness is caused on the surface of the cold rolled product. Application to advanced applications is limited.

종래에는 열연코일 표면에 잔류하는 면거침 결함을 저감하기 위한 방법으로, 면거침의 원인이 되는 몰드 슬래그를 제거하기 위해 연주 2차냉각대에서 비수량 증대를 통한 탈착 증대, 주편을 1분간 수냉조에 침적하는 방법, 주편표면에 냉각수를 1분간 살수하는 방법, 열연 가열로에 주편을 장입하기 전에 주편표면의 탈착된 잔류 스케일을 브러쉬(Brush)와 에어블로우어(Air Blower)를 이용하여 제거하는 방법, 연주주편에 강구투사기(Shot Blaster)를 이용하여 스케일을 제거하는 방법 등이 보고되고 있다. 그러나 이와 같이 공지된 기술을 살펴보면, 열간압연공정에서의 디스케일링 조건등에 대하여는 보고되고 있지 않다. Conventionally, a method for reducing surface roughness defects remaining on the surface of a hot rolled coil.In order to remove mold slag that causes surface roughness, the desorption is increased by increasing the amount of non-aqueous quantity in the secondary refrigerating cooling basin, and the cast is placed in a water cooling tank for 1 minute. The method of immersion, the spraying of cooling water for 1 minute on the surface of cast steel, the removal of descaled residual scale on the surface of cast steel using brush and air blower For example, there has been reported a method of removing a scale using a Shot Blaster on a cast cast. However, looking at the known technology, there is no report on descaling conditions in the hot rolling process.

본 발명은 상기 요망에 따라 안출된 것으로, 오스테나이트계 스테인리스강 제조시 최종냉연제품에서의 면거침 결함을 저감하기 위한 제조조건으로, 연속주조후 연주주편의 냉각방법, 열간압연시 디스케일링 조건을 적절히 적절히 제어함으로써 냉연제품의 면거침 결함을 저감하여 표면품질이 우수한 오스테나이트계 스테인리스강의 제조방법을 제공하는데 그 목적이 있다.The present invention has been made in accordance with the above requirements, the manufacturing conditions for reducing the surface roughness defects in the final cold-rolled product in the production of austenitic stainless steel, cooling method of the casting cast after continuous casting, descaling conditions during hot rolling It is an object of the present invention to provide a method for producing austenitic stainless steel having excellent surface quality by reducing surface roughness defects of a cold rolled product by appropriately controlling appropriately.

본 발명은 상기 목적을 달성하기 위하여, 중량%로 10%~30% 크롬과 5~15%니켈을 함유하는 오스테나이트계 스테인리스강을 연속주조공정, 열간압연공정, 열연소둔산세고정 및 냉간압연공정으로 제조하는 방법에 있어서, 연속주조공정에서 절단 완료된 열간상태의 주편을 수냉조에서 10분이상 침적하여 잔류스케일을 탈착하고, 상기 주편을 열간압연 공정으로 이송하여 열간압연시의 조질압연 단계에서 바의 두께가 94~100mm에 해당하는 시점에서 상기 바 표면에서의 디스케일링 압력을 3bar 이상으로 살수하여 추가로 잔류스케일을 제거하는 표면품질이 우수한 오스테나이트계 스테인리스강 제조방법을 제공하는 것을 특징으로 한다. In order to achieve the above object, the present invention provides a continuous casting process, hot rolling process, hot rolling annealing and cold rolling process of austenitic stainless steel containing 10% to 30% chromium and 5 to 15% nickel by weight. In the manufacturing method, the hot slab cut in the continuous casting process is immersed in a water cooling tank for 10 minutes or more to desorb the residual scale, and the slab is transferred to the hot rolling process to carry out the temper rolling step at the time of hot rolling. At a time when the thickness of 94 ~ 100mm, the descaling pressure on the surface of the bar is sprinkled to 3 bar or more characterized in that it provides a method for producing austenitic stainless steel having excellent surface quality to further remove the residual scale. .

또한, 본 발명에서 상기 열간상태의 주편의 온도는 600~800℃이다. In the present invention, the temperature of the cast steel in the hot state is 600 ~ 800 ℃.

이하 본 발명을 도면을 참조하여 더욱 상세히 설명하기로 한다. Hereinafter, the present invention will be described in more detail with reference to the drawings.

먼저, 본 발명은 오스테나이트계 스테인리스강 제조시 연주공정에서 주편을 수냉조에 10분이상 침적하여 잔류 몰드 슬래그를 제거한 후 열연 가열로에 장입하고, 열간 조압연시 바(Bar) 두께가 94~100mm일 때, 바 표면에서의 충돌압을 3Bar이상으로 하여 디스케일링을 실시하여 최종 냉연제품에서의 면거침 결함을 저감할 수 있다. First, the present invention is to deposit the cast slab in the water cooling bath for more than 10 minutes in the reproducing process during the production of austenitic stainless steel to remove the residual mold slag, and then loaded into a hot-rolled heating furnace, the bar thickness during hot rough rolling 94 ~ 100mm In this case, descaling can be performed with an impact pressure of 3 bar or more on the surface of the bar to reduce surface roughness defects in the final cold rolled product.

도 1은 일반적인 스테인리스강 제조공장 및 단위공정을 나타내었다. 먼저 1 shows a typical stainless steel manufacturing plant and unit process. first

제강공정에서 제조된 용강을 연주기에서 냉각공정을 거쳐 제조된 주편을 열연가열로에 장입·재가열 후 조압연 및 사상압연 공정을 거치게 된다. 이후 블랙코일(Black Coil)은 열연소둔산세 공장에서 소둔 및 기계적/화학적 스케일 제거공정을 거쳐 열연코일이 제조된다. 이렇게 제조된 열연코일은 냉연공장에서 냉간압연 및 냉연소둔산세공정을 거쳐 제조된다.After the molten steel manufactured in the steelmaking process is charged and reheated into a hot-rolled furnace, the cast steel is subjected to rough rolling and finishing rolling. Since the black coil (Black Coil) is a hot rolled coil is subjected to annealing and mechanical / chemical scale removal process in the hot-burning annealing plant. The hot rolled coil thus manufactured is manufactured by cold rolling and cold rolling annealing at a cold rolling mill.

이때, 열연 가열로 장입전 연주주편에 몰드슬래그가 다량 잔류하거나, 열간압연시 디스케일링의 강도 및 균일성이 확보되지 못할 경우, 냉연제품 표면에 면거침 결함이 다발한다.At this time, if a large amount of mold slag is left in the cast slab before charging by hot rolling, or if the strength and uniformity of descaling cannot be secured during hot rolling, surface roughness defects frequently occur on the surface of the cold rolled product.

이에 본 발명에서는 냉연제품 표면의 면거침 결함을 저감하기 위해, 연주주편에서 잔류하는 몰드 슬래그의 탈착방법, 열연 디스케일링 강도 및 균일성 확보방법을 제안하게 된다.Accordingly, in the present invention, in order to reduce surface roughness defects on the surface of the cold rolled product, a method of detaching the mold slag remaining in the cast steel piece, a method of securing hot rolled descaling strength and uniformity is proposed.

이하 본발명을 실시예를 통해 구체적으로 설명한다. Hereinafter, the present invention will be described in detail through examples.

[실시예 1] Example 1

연주주편의Performance 몰드슬래그Mold Slag 탈착방법Desorption method

본 발명에서는 연주주편에 잔류하는 몰드슬래그의 탈착방법으로 연주주편을 수냉조에 침적하여 주편 표층부에서의 냉각시 열팽창계수차이에 의한 스케일 탈착 및 보일링(Boiling)에 의한 스케일 제거효과를 극대화하는 방법을 고안하였으며, 수냉조 침적시간에 따른 몰드 슬래그 탈착강도를 비교하였으며, 그 결과를 표1에 나타내었다.In the present invention, a method of maximizing the scale removal effect by descaling and boiling due to thermal expansion coefficient difference during cooling in the surface layer part of the cast slab by depositing the cast slab in the water cooling tank by the detachment method of the mold slag remaining on the cast steel. The slag desorption strength according to the water cooling bath deposition time was compared and the results are shown in Table 1.

침적시간Deposition time 0분0 min 1분1 minute 5분5 minutes 10분10 minutes 30분30 minutes 몰드슬래그잔류지수Mold Slag Retention Index 44 33 22 1One 1One

상기 표 1에서 알수 있듯이 수냉조 침적시 연주주편에 잔류하는 몰드슬래그 지수는 수냉시간의 증가에 따라 지속적으로 감소하고, 침적시간이 10분이상인 경우에는 몰드슬래그 잔류량은 거의 일정하였다. 이에 따라 연주주편에 잔류하는 몰드슬래그 탈착을 위해서는 수냉조 침적시간을 10분이상으로 설정하여야 한다.As can be seen in Table 1, the mold slag index remaining in the cast pieces during the water cooling bath deposition is continuously reduced with the increase in the water cooling time, the mold slag residual amount was almost constant when the deposition time is more than 10 minutes. Accordingly, in order to remove the mold slag remaining in the cast steel, the water cooling tank deposition time should be set to 10 minutes or more.

[실시예2] Example 2

열간압연시During hot rolling 디스케일링Descaling 방법 Way

열연 조압연 구간에서 디스케일링 방법이 면거침에 미치는 영향을 평가하기 위해, 가열로 인출후 디스케일러인 HSB, 첫번째 조압연기 입측 디스케일러인 R1, 두번째 조압연기 입측 디스케일러인 R2의 첫번째, 두번째 및 세번째 압연시 디스케일링(R2-1, R2-2, R2-3)이 조합된 조건으로 제조된 제품에 대한 면거침 결함을 비교 실시 하였으며, 그 결과를 도 2에 나타내었다. In order to evaluate the effect of descaling method on the surface roughness in hot rolling zone, the first, second and second descaler HSB, the first rough rolling inlet descaler R1, the second rough rolling inlet descaler R2 In the third rolling, the surface roughness defects of the products manufactured under the combination of descaling (R2-1, R2-2, R2-3) were compared and performed.

상기 도 2에서 알 수 있듯이 면거침 결함지수는 R2-3 디스케일링 시 가장 우수하게 나타났으며, 타결함을 증가여부를 살펴보기 위한 지표로 M형 결함 지수도 비교한 결과 또한 R2-3에서 가장 우수한 결함지수를 나타내었다. 이에 따라 열간압연시 R2-3 디스케일링에 해당하는 즉, 바(Bar) 두께 94~100mm에서 바의 표면 충돌압을 3bar이상으로 디스케일링을 1회 실시하여야 한다.As can be seen in FIG. 2, the surface roughness defect index was the best when R2-3 descaling, and the M type defect index was also compared to R2-3 as an index to examine whether the defect was increased. Excellent defect index was shown. Accordingly, descaling should be performed once for hot rolling with R2-3 descaling, i.e., bar collision surface pressure of 3 bar or more at bar thickness 94 ~ 100mm.

상기와 같이 구성된 각 인자를 종합 적용하여, 본발명 전/후의 면거침 결함율을 비교하였으며, 그 결과를 도 3에 나타내었다. 그래프에서 알 수 있듯이 본 발명법 적용시 종래방법대비 품질불합격율이 크게 감소하는 것을 알 수 있다.By applying each of the factors configured as described above, the surface roughness defect rate before and after the present invention was compared, the results are shown in FIG. As can be seen from the graph, it can be seen that the quality rejection rate is significantly reduced compared to the conventional method when the present invention is applied.

상술한 바와 같이, 본 발명에 의하면, 연주주편의 냉각방법, 열간압연시 디스케일링 방법을 적절히 제어함으로써 면거침 결함이 저감된 표면품질이 우수한 오스테나이트계 스테인리스강의 연삭 주편을 제조할 수 있는 효과가 있다.As described above, according to the present invention, by appropriately controlling the cooling method of the cast steel and the descaling method during hot rolling, it is possible to produce a grinding cast of austenitic stainless steel having excellent surface quality with reduced surface roughness defects. have.

Claims (2)

중량%로 10%~30% 크롬과 5~15%니켈을 함유하는 오스테나이트계 스테인리스강을 연속주조공정, 열간압연공정, 열연소둔산세고정 및 냉간압연공정으로 제조하는 방법에 있어서, 연속주조공정에서 절단 완료된 열간상태의 주편을 수냉조에서 10분이상 침적하여 잔류스케일을 탈착하고, 상기 주편을 열간압연 공정으로 이송하여 열간압연시의 조질압연 단계에서 바의 두께가 94~100mm에 해당하는 시점에서 상기 바 표면에서의 디스케일링 압력을 3bar 이상으로 살수하여 추가로 잔류스케일을 제거하는 것을 특징으로 하는 표면품질이 우수한 오스테나이트계 스테인리스강 제조방법.In the method of manufacturing austenitic stainless steel containing 10% to 30% chromium and 5 to 15% nickel by weight in a continuous casting process, a hot rolling process, a hot rolling annealing and a cold rolling process, the continuous casting process In the water-cooled water bath, the hot slab cut is immersed in a water cooling tank for at least 10 minutes to desorb the residual scale, and the bar is transferred to the hot rolling process, where the thickness of the bar corresponds to 94 to 100 mm in the temper rolling step during hot rolling. A method for producing austenitic stainless steel having excellent surface quality, characterized in that the remaining scale is further removed by sprinkling the descaling pressure on the bar surface to 3 bar or more. 제1항에 있어서, The method of claim 1, 상기 열간상태의 주편의 온도는 600~800℃인 표면품질이 우수한 오스테나이트계 스테인리스강 제조방법.The temperature of the cast steel in the hot state is 600 ~ 800 ℃ excellent surface quality austenitic stainless steel manufacturing method.
KR20060137075A 2006-12-28 2006-12-28 Method of manufacturing an austenitic stainless steel for decreasing a surface roughness defects KR100772331B1 (en)

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