KR100730577B1 - A multifunction paints for cases of electronic apparatus and a method thereof - Google Patents

A multifunction paints for cases of electronic apparatus and a method thereof Download PDF

Info

Publication number
KR100730577B1
KR100730577B1 KR1020040029621A KR20040029621A KR100730577B1 KR 100730577 B1 KR100730577 B1 KR 100730577B1 KR 1020040029621 A KR1020040029621 A KR 1020040029621A KR 20040029621 A KR20040029621 A KR 20040029621A KR 100730577 B1 KR100730577 B1 KR 100730577B1
Authority
KR
South Korea
Prior art keywords
weight
solvent
intermediate product
mixed
aromatic solvent
Prior art date
Application number
KR1020040029621A
Other languages
Korean (ko)
Other versions
KR20050104244A (en
Inventor
이종철
Original Assignee
이종철
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 이종철 filed Critical 이종철
Priority to KR1020040029621A priority Critical patent/KR100730577B1/en
Publication of KR20050104244A publication Critical patent/KR20050104244A/en
Application granted granted Critical
Publication of KR100730577B1 publication Critical patent/KR100730577B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/06Ethers; Acetals; Ketals; Ortho-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/07Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/45Anti-settling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/47Levelling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

Abstract

본 발명의 플라스틱 재질의 전자기기의 케이스에 도장용 및 건축용 철제에 도장용 도료로서, 아크릴수지, 에폭시수지, 혹은 폴리우레탄 수지 등에 특수 첨가제를 첨가하여 음이온 발생, 냄새제거, 항균 또는 멸균 작용을 하는 기능성 도료와 그 제조 방법을 제공하려는 것이다.  As a coating material for painting and construction iron on the case of plastic electronic devices of the present invention, by adding special additives to acrylic resin, epoxy resin, or polyurethane resin, anion generation, odor removal, antibacterial or sterilization It is to provide a functional paint and a method of manufacturing the same.

본 발명이 특히 전자기기들의 케이스, 예로서 TV 케이스, 핸드폰 케이스 등과 같은 플라스틱 재질의 자전제품 케이스, 또는 금속 재질의 케이스에 건축용 자재에 도장하여 특별한 효과를 내는 도료와 그 제조방법을 제공하려는 것이다.  The present invention is to provide a paint having a special effect by coating a building material on a case of electronic devices, such as a plastic case, such as a TV case, a mobile phone case, or a metal case, and a manufacturing method thereof.

본 발명의 기능성 도료는 아크릴수지, 에폭시수지 또는 폴리우레탄 수지로 된 바인더 20 ~40%와 안료 5 ~ 10%, 600 매시 시상 분쇄한 전기석분말 2 ~ 20%와 레벨링제, 침강방지제, 소포제 등의 기타 첨가제 2 ~ 2%와 용제 (케톤계, 방향족계, 셀루솔브계, 아세테이트계) 40 ~ 60%을 혼합하여 제조한 기능성 도료이다.




The functional paint of the present invention is 20 to 40% of a binder made of acrylic resin, epoxy resin or polyurethane resin, 5 to 10% of pigment, 2 to 20% of tourmaline powder pulverized at 600 hour, and leveling agent, anti-settling agent and antifoaming agent. It is a functional paint prepared by mixing 2 ~ 2% of other additives and 40 ~ 60% of solvents (ketone, aromatic, cellulsolve, acetate).




기능성도료, 원적외선, 항균작용, 음이온발생, 냄새제거Functional paint, far infrared ray, antibacterial action, anion generation, odor removal

Description

전자기기 케이스 도장용 및 금속 재질의 건축용 자재용의 기능성 도료 및 그 제조 방법{A multifunction paints for cases of electronic apparatus and a method thereof}A multifunction paints for cases of electronic apparatus and a method

도료는 유동체를 물체의 표면에 펴 발라 엷은 층을 만들어 단단하게 하는, 물체 표면이 보호와 착색 등을 위해 쓰이는 것이다.  Paint is an object surface that is used for protection and coloring, by spreading fluid on the surface of an object to form a thin layer that makes it hard.

물체는 크건 작건 외적인 영향에 의해 조금씩은 침식작용을 받는다. 또한 소재(素材)만으로는 표면적인 상품 가치가 낮은 경우가 많다. 따라서 외부의 영향으로부터 보호하고, ①물체의 보호.방식(防蝕).내유(耐油).내약품성.방습 ②미화(美化).평활화(平滑化).표지(標識).광택 ③살균.전도성 조절.반사.생물 부착방지 등을 위하여 사용된다.  The object is slightly eroded by external influences, large and small. In addition, the material value alone is often low on the surface alone. Therefore, it protects it from external influences, and ① protects objects, protects against corrosion, oil, chemicals, and moisture. 2. beautification, smoothing, label, gloss, and sterilization. Used to prevent reflection and biological attachment.

도료의 주성분은 크게 나누어 도막(塗膜) 형성 성분인 전색제(展色劑 ; vehicle)와 안료 성분으로 되어 있다. 전색제는 투명도료에 해당하는 것으로, 안료 등을 분산시켜 도료에 유동성을 주는 성분이며, 안료는 도막에 색채를 부여하는 성분이다.  The main components of the paint are broadly divided into a colorant (vehicle), which is a coating film forming component, and a pigment component. The colorant corresponds to a transparent paint, and is a component that disperses a pigment or the like and gives fluidity to the paint.

도료는 분류 방법에 의해 여러 가지 명칭으로 불리는데, 크게 수성 도료와 유성 도료로 분류할 수 있다. 수성 도료는 유기계 용재 대신 물을 사용하여, 경제적이고 취급이 간편하며 안전성이 있다. 건물의 벽 도장이나 석재용.바탕도료에 사용되는 도료로 에멀션 도료.수용성 베이킹 수지도료가 대표적이다. 유성도료는 주로 천연유지 등으로 제조되는 전색제를 이용하는 도료이며, 옻칠.캐슈계도료.유성페인트.유성에나멜 등이 대표적이다.  Paints are called by various names by the classification method, and can be broadly classified into water-based paints and oil-based paints. Water-based paints use water instead of organic solvents, and are economical, easy to handle, and safe. It is a paint used for wall painting, stone, and ground paint of buildings, such as emulsion paint and water-soluble baking resin paint. Oil paints are mainly paints using a colorant made of natural oils, and lacquer, cashew paint, oil paint, oil enamel and the like.

근래에는 합성수지 도료가 급속히 개발되고 있고, 그 용도가 점점 확대되어 가고 있다. 주요한 것으로는 ①알키드 수지도료 ②아미노 알키드 수지도료 ③아크릴 수지도료 ④페놀 수지 도료 ⑤에폭시 수지도료 ⑥불포화 폴리에스테르 수지도료 ⑦폴리우레탄 수지도료들이 있다.  In recent years, synthetic resin paints are being rapidly developed, and their use is expanding. The main ones are: ① alkyd resin paint ② amino alkyd resin paint ③ acrylic resin paint ④ phenolic resin paint ⑤ epoxy resin paint ⑥ unsaturated polyester resin paint ⑦ polyurethane resin paint.

최근에는 또한 종래의 도료처럼 물체 표면의 보호.착색이라는 관점에만 국한되지 않고, 특별한 작용을 하는 이른바 "기능성 도료"들이 많이 개발되고 있으며, 전파 흡수도료.전도성 도료 등이 개발되어 사용되고 있다.  In recent years, as well as conventional paints are not limited to the protection and coloring of the surface of the object, so-called "functional paints" that have a special action has been developed a lot, radio wave absorption paints, conductive paints and the like have been developed and used.

기능성 도료란 미관 및 보호의 일반적인 기능 외에 물리적, 화학적 외부의 자극에 대한 저항성을 극대화(내열성, 내약품성)하거나 입력된 것을 고기능의 질로 변화하여 출력하는 변환기능(전압, 전열계통 등)의 고기능을 목적으로 하는 도료로서 도료의 일반 기능은 물론 도장함으로서 도막의 표면에 관련된 성질을 도막으로 전환하여 표면 개질은 물론 제3의 기능을 포함하는 고성능, 고기능을 함유하는 도료다.  In addition to the general functions of aesthetics and protection, functional paints can be used to maximize the resistance to physical and chemical external stimuli (heat resistance, chemical resistance), or to convert the input into high-quality quality and output the high-function of the conversion function (voltage, electric heating system, etc.). It is a paint containing high performance and a high function which includes not only surface modification but a 3rd function as well as surface modification by converting the property related to the surface of a coating film into a coating film by coating as well as the general function of a coating material as a target coating material.

2002년 8월 3일자로 공개된 특허 공개 제 2002-0063535호에는 세라믹 재질의 알루미나와 숯을 담체로 한 귀금속 촉매체와, 상온에서 주변의 수분이나 물을 전기 분해하여 발생되는 수소의 산화 작용에 의해 다량의 원적외선과 음이온을 방사.방 출하는 토르말린(tourmaline)을 혼합 조성하여 악취제거, 수분증발, 원적외선 방사, 음이온 발생 등의 특성이 크게 향상된 기능성 세라믹 분말의 제조 방법이 공개되어 있다.  Patent Publication No. 2002-0063535, published on August 3, 2002, discloses a noble metal catalyst body based on ceramic alumina and charcoal, and on the oxidation of hydrogen produced by electrolysis of ambient water or water at room temperature. There is disclosed a method for producing a functional ceramic powder which greatly improves characteristics such as odor removal, water evaporation, far infrared radiation, and anion generation by mixing tourmaline, which emits and emits a large amount of far infrared rays and anions.

또한 2002년 10월 25일자 공고된 특허 등록 제 10-0358326호에는 숯 50 ~70중량%와 접착제 25 ~ 50중량%로 구성되는 혼합물을 통상의 초배지 표면 중 적어도 일면에 100 ~ 300g/㎡의 양으로 도포하고 50 ~ 70℃ 온도의 열풍으로 건조하여 제조된 초배지를 시멘트로 건축된 건축물의 벽면 등에 붙이고 도배를 함으로서 원적외선 방사 기능 및 음이온 방출 기능을 가지며 습도를 조절하고 전자파 흡수 기능을 갖는 숯으로 인하여 시멘트로부터 발생되는 악취를 용이하게 제거할 수 있을 뿐만 아니라 유해 성분의 제거 효율 우수하며 도배지의 접착 또한 용이하게 이루어지도록 할 수 있었다.  In addition, Korean Patent Registration No. 10-0358326 filed on October 25, 2002, contains a mixture of 50 to 70% by weight of charcoal and 25 to 50% by weight of adhesive on at least one surface of a conventional super medium. It is applied to the wall of the building constructed with cement and applied to the super medium produced by drying with hot air at a temperature of 50 ~ 70 ℃ and spreading it through charcoal with far infrared radiation function and negative ion emission function, humidity control and electromagnetic wave absorption function. Not only can the odor generated from the cement be easily removed, the removal efficiency of the harmful components is excellent, and the adhesion of the paper medium can be easily performed.

본 발명은 기능성 도료에 관한 것으로, 원적외선 방사기능 및 음이온 방출 기능을 가지며 습도를 조절하고 전자파 흡수 기능을 갖는 기능성 도료를 제공함에 그 목적이 있다. 이를 위해 구성되는 본 발명의 기능성 도료는 미세분말 숯 30 ~ 60 중량%, 액상 바인더<(메트릭스 폴리머(matrix polymer)>로써 클로로프렌, 폴리초산비닐, 폴리아크릴산 에스테르, 폴리비닐 알콜, 카르복실 메틸 셀룰로스 및 에멀젼형의 수지 중 어느 하나 30 ~ 70중량% 및 색상과 향을 발현시키는 안료 10 ~ 40중량%의 혼합물로 구성된다. 이러한 구성에 의해 건축물의 벽면 등에 도포함으로서 원적외선 방사기능 및 음이온 방출 기능을 가지며 습도를 조절하고 전자파 흡수 기능을 갖는 숯으로 인하여 시멘트로부터 발생되는 악취를 제거할 수 있는 기능성 도 료가 공개되어 있다.  The present invention relates to a functional paint, and has an object to provide a functional paint having far-infrared radiation function and anion emission function, controlling humidity and having an electromagnetic wave absorption function. Functional paints of the present invention configured for this are 30 to 60% by weight of fine powder charcoal, liquid binder <(matrix polymer>) as chloroprene, polyvinyl acetate, polyacrylic acid ester, polyvinyl alcohol, carboxymethyl cellulose and It is composed of a mixture of 30 to 70% by weight of any one of the emulsion-type resin and 10 to 40% by weight of pigments expressing color and scent, and thus it has far-infrared radiation function and anion emission function by being applied to the walls of buildings. A functional paint is disclosed which can control the humidity and remove odor generated from cement due to charcoal having a function of absorbing electromagnetic waves.

본 발명의 목적은 플라스틱에 도포 될 도료로서 특수 아크릴 수지 혹은 우레탄 수지 특수 첨가제를 사용하여 음이온 발생, 원적외선 발생, 냄새제거, 항균 또는 멸균 작용을 하는 기능성 도료와 그 제조 방법을 제고하려는 것이다.  An object of the present invention is to improve a functional paint and a method for producing the same, which produce anion, far-infrared radiation, odor removal, antibacterial or sterilization using a special acrylic resin or urethane resin special additive as a paint to be applied to plastics.

본 발명의 목적은 특히 전자기기들의 케이스, 예로서 TV 케이스, 핸드폰 케이스 등과 같은 플라스틱 재질의 전자 제품 케이스에 도장하여 특별한 효과를 내는 도료와 그 제조 방법을 제공하려는 것이다.  An object of the present invention is to provide a paint and a method of manufacturing the same, which have a special effect by painting on a case of electronic devices, for example, a plastic case such as a TV case, a mobile phone case.

또한 본 발명의 다른 목적은 건축용 철제, 또는 철제품에 사용하기 위하여 특수 에폭시 수지, 아크릴 우레탄 수지, 알키드 수지 등과 특수 첨가제를 사용하여 음이온 발생, 원적외선 발생, 냄새제거, 항균 또는 멸균 작용을 하는 기능성 도료와 그 제조 방법을 제공하려는 것이다.  In addition, another object of the present invention is to use a special epoxy resin, acrylic urethane resin, alkyd resin and the like additives for use in construction iron or iron products, functional anion, anion generation, far infrared generation, odor removal, antibacterial or sterilizing And to provide a method of manufacturing the same.

본 발명은 아크릴 수지, 에폭시 수지, 우레탄 수지 등과 각종 안료 첨가제와 더불어 전기석 원석을 600메시 시상 분쇄하여 혼합함으로서 다양한 기능을 가진 도료를 제조하는 방법이다.  The present invention is a method for producing a paint having a variety of functions by mixing and grinding a tourmaline gemstone 600 mesh sacrificing together with various pigment additives such as acrylic resin, epoxy resin, urethane resin and the like.

본 발명의 실시예에 따른 도료는 에폭시 수지 20 ~ 30중량%, 분산제 0.05 ~ 0.08중량%, 안료 5 ~ 10중량%, 전기석분말 5 ~ 8중량%, 방향족계용제 20 ~ 30중량%, 케톤계용제 25 ~ 38중량%, 비닐수지 4 ~ 8중량%, 니트로셀루로즈 1 ~ 2중량% 및 기타 첨가제 (0.07 ~ 0.15중량%) 포함하는 도료 조성물이다.
본 발명의 다른 실시예에 따른 도료는 에폭시수지 9 ~ 12중량%, 분산제 0.1 ~ 0.3중량%, 방향족계용제 10 ~ 15중량%, 안료 15 ~ 25중량%, 전기석분말 5 ~ 8중량%, 침강방지제, 소포제 또는 레벨링제 1.5 ~ 2.8중량%, 방향족계용제 20 ~ 25중량%와 알콜계용제 10 ~ 13중량%가 혼합되어 포함된 제1중간 제품과, 상기 에폭시수지의 경화제인 폴리아마이드 5 ~ 10중량%에 방향족계용제 10 ~ 15중량%와 셀루솔브계용제 7 ~ 10중량%가 혼합된 제2중간 제품을 포함하여 이루어지고, 도장 작업을 하기 직전에 제1중간 제품과 제2중간 제품을 3 ~ 5 : 1의 중량비로 혼합하여 사용하는 도료 조성물이다.
본 발명의 또 다른 실시예에 따른 도료는 플라스틱제 또는 철제를 포함하는 전자기기의 케이스를 도장하기 위한 기능성 도료로서, 폴리에스테르 폴리올수지 18 ~ 25중량%, 아크릴폴리올 10 ~ 17중량%, 방향족계용제 4 ~ 5중량%, 아세테이트계용제 10 ~ 18중량%, 분산제 0.08 ~ 0.12중량%, 안료 4.5 ~ 6.0중량%, 전기석분말 5 ~ 8중량%, 기타첨가제 1.5 ~ 2.5중량%, 케톤계용제 8 ~ 12중량%, 아세테이트계용제 5 ~ 10중량%를 포함하는 제1중간 제품과, 이소시아네이트 8 ~ 10중량%, 방향족계용제 3 ~ 7중량% 및 아세테이트계용제 10 ~ 15중량%를 포함하는 제2중간 제품을 포함하고, 도장작업 직전에 제1중간 제품과 제2중간 제품을 5 ~ 10 : 1의 중량비로 혼합하여 사용하는 도료 조성물이다.
그리고, 본 발명의 실시예에 따른 전자기기 플라스틱 케이스 도장용 기능성 도료 제조 방법에 있어서, (가) 아크릴수지 20 ~ 30중량%와 분산제 0.05 ~ 0.08중량%를 혼합 믹싱하고, 여기에 안료 5 ~ 10중량%를 혼합 믹싱하여 균일하게 분산한 다음, 전기석분말 5 ~ 8중량%을 혼합하여 균일하게 분산되게 하고, 방향족계용제 10 ~ 15중량%와 케톤계용제 10 ~ 15중량%를 첨가하여 믹싱하고, (나) 별도의 용기에 방향족계용제 10 ~ 15중량%와 케톤계용제 10 ~ 15중량%를 혼합하여 비닐수지 4 ~ 8중량%, 니트로셀루로즈 1 ~ 2중량%를 용해시키고, 상기 (가)에서 제조한 원료를 혼합하여 균일하게 믹싱하고, 기타 첨가제 0.07 ~ 0.15중량%를 첨가하여 균일하게 한 후 기타 용재 5 ~ 8중량%로서 점도 조절한다.
또한, 본 발명의 다른 실시예에 따른 금속 재질의 건축 자재 도장용 기능성 도료 제조 방법에 있어서, (가) 에폭시 수지 9 ~ 12중량%에 분산제 0.1 ~ 0.3중량%와 방향족계용제 10 ~ 15중량%를 혼합하여 균일하게 하고, 안료 15 ~ 25중량%를 혼합하여 균일하게 분산하고, 전기석 분말 5 ~ 8중량%을 첨가하여 균일하게 하고, 기타 첨가제 1.5 ~ 2.8중량%를 혼합하여 믹싱한 후 균일하게 하고, 방향족계용제 20 ~ 25중량%와 알콜계용제 10 ~ 13중량%, 셀루솔브계용제 3 ~ 5중량%를 혼합하여 점도 조절 후 제1중간 제품으로 포장하고, (나) 상기 에폭시 수지 경화제인 폴리아마이드 5 ~ 10중량%에 방향족계용제 10 ~ 15중량%와 셀루솔브계용제 7 ~ 10중량%를 혼합하여 제2중간 제품으로 포장한 후, 사용 시에는 제1중간 제품과 제2중간 제품을 3 ~ 5 : 1의 중량비로 혼합하여 사용하게 하는 도료 제조 방법이다.
그리고, 본 발명의 또 다른 실시예에 따른 전자기기 케이스 도장용 기능성 도료 제조 방법에 있어서 (가) 폴리에스테르 폴리올수지 18 ~ 25중량%와 아크릴폴리올 10 ~ 17중량%에 방향족계용제 4 ~ 5중량%, 아세테이트계용제 10 ~ 18중량%를 혼합하고, 분산제 0.08 ~ 0.12중량%를 첨가하여 믹싱한 후 안료 4.5 ~ 6.0중량%를 첨가하여 균일하게 분산되게 하고, 전기석 분말 5 ~ 8중량%을 첨가하여 균일하게 하고, 레벨링제, 침강방지제, 소포제 등의 첨가제 1.5 ~ 2.0중량%를 첨가하여 균일하게 한 후 케톤계용제 8 ~ 12중량%, 아세테이트계용제 5 ~ 10중량%를 첨가하여 점도 조절 후 제1중간 제품으로 포장하고, (나) 이소시아네이트 8 ~ 10중량%, 방향족계용제 3 ~ 7중량% 및 아세테이트계용제 10 ~ 15중량%를 혼합하여 균일하게 한 후 제2중간 제품으로 포장한 후, 사용 시에 제1중간 제품과 제2중간 제품을 5 ~ 10 : 1의 중량비로 혼합하여 사용하는 도료 제조 방법이다.
Paint according to an embodiment of the present invention is 20 to 30% by weight epoxy resin, 0.05 to 0.08% by weight dispersant, 5 to 10% by weight pigment, 5 to 8% by weight tourmaline powder, 20 to 30% by weight aromatic solvent, ketone A paint composition comprising 25 to 38% by weight of solvent, 4 to 8% by weight of vinyl resin, 1 to 2% by weight of nitrocellulose, and other additives (0.07 to 0.15% by weight).
Paint according to another embodiment of the present invention is 9 to 12% by weight epoxy resin, 0.1 to 0.3% by weight dispersant, 10 to 15% by weight aromatic solvent, 15 to 25% by weight pigment, 5 to 8% by weight tourmaline powder, sedimentation A first intermediate product containing 1.5 to 2.8% by weight of an inhibitor, an antifoaming agent or a leveling agent, 20 to 25% by weight of an aromatic solvent, and 10 to 13% by weight of an alcohol solvent, and polyamide 5 to 5, which is a curing agent of the epoxy resin. 10 wt% of the aromatic solvent and 10-15 wt% of the aromatic solvent and 7-10 wt% of the cellulose solvent are included, and the first intermediate product and the second intermediate product immediately before coating work Is a coating composition used by mixing in a weight ratio of 3-5.
Paint according to another embodiment of the present invention is a functional paint for coating a case of an electronic device including a plastic or iron, 18 to 25% by weight of polyester polyol resin, 10 to 17% by weight of acrylic polyol, aromatic Solvent 4 ~ 5 wt%, Acetate solvent 10 ~ 18 wt%, Dispersant 0.08 ~ 0.12 wt%, Pigment 4.5 ~ 6.0 wt%, Tourmaline powder 5 ~ 8 wt%, Other additives 1.5 ~ 2.5 wt%, Ketone solvent 8 To 12% by weight, a first intermediate product containing 5 to 10% by weight of an acetate solvent, 8 to 10% by weight of isocyanate, 3 to 7% by weight of an aromatic solvent and a 10 to 15% by weight of an acetate solvent. A coating composition comprising two intermediate products and mixing the first intermediate product and the second intermediate product at a weight ratio of 5 to 10: 1 immediately before the painting operation.
In the functional paint manufacturing method for coating an electronic device plastic case according to an embodiment of the present invention, (A) 20 to 30% by weight of acrylic resin and 0.05 to 0.08% by weight of a dispersant are mixed and mixed, and pigments 5 to 10 are added thereto. Mix and mix the weight% uniformly, mix 5 to 8% by weight of tourmaline powder to be uniformly dispersed, mix by adding 10-15% by weight of aromatic solvent and 10-15% by weight of ketone solvent. , (B) 10 to 15% by weight of aromatic solvent and 10 to 15% by weight of ketone solvent are mixed in a separate container to dissolve 4 to 8% by weight of vinyl resin and 1 to 2% by weight of nitrocellulose. The raw materials prepared in a) are mixed and mixed uniformly, and uniformly added by adding 0.07 to 0.15 wt% of other additives, and then the viscosity is adjusted as 5 to 8 wt% of other solvents.
In addition, in the method of manufacturing a functional paint for coating a building material of a metal material according to another embodiment of the present invention, (A) 9 to 12% by weight of the epoxy resin dispersant 0.1 to 0.3% by weight and aromatic solvent 10 to 15% by weight To uniformity by mixing, uniformly disperse by mixing 15 to 25% by weight of the pigment, and uniformly by adding 5 to 8% by weight of tourmaline powder, uniformly mixed by mixing 1.5 to 2.8% by weight of other additives 20 to 25% by weight of an aromatic solvent, 10 to 13% by weight of an alcoholic solvent, and 3 to 5% by weight of a cellulose solvent are mixed and packaged as a first intermediate product after viscosity control, and (b) the epoxy resin curing agent. 5-10 wt% of phosphorus polyamide is mixed with 10-15 wt% of aromatic solvent and 7-10 wt% of cellulsolve solvent, and then packaged as a second intermediate product. Paint that allows the product to be mixed and used in a weight ratio of 3 to 5: 1 It is a manufacturing method.
In addition, in the method of manufacturing a functional paint for painting an electronic device case according to another embodiment of the present invention, (A) 18 to 25% by weight of polyester polyol resin and 4 to 5% by weight of aromatic solvent in 10 to 17% by weight of acrylic polyol %, 10 to 18% by weight of the acetate-based solvent is mixed, and mixed by adding 0.08 to 0.12% by weight of the dispersant, and then 4.5 to 6.0% by weight of the pigment to be uniformly dispersed, 5 to 8% by weight of tourmaline powder Uniformity by adding 1.5 ~ 2.0% by weight of additives such as leveling agent, anti-settling agent, antifoaming agent, and then homogeneous, and after adjusting the viscosity by adding 8 ~ 12% by weight of ketone solvent, 5 ~ 10% by weight of acetate solvent Packed with the first intermediate product, (b) 8 to 10% by weight of isocyanate, 3 to 7% by weight of the aromatic solvent and 10 to 15% by weight of the acetate solvent are uniformly mixed and then packaged with the second intermediate product. First intermediate product in use A coating method using a mixture in a weight ratio of 1: 2 to the intermediate product 5-10.

전기석(Tourmaline)은 공개된 특허 공개 제 2002-0063535호에 설명되어 있는 바와 같이 붕소, 알루미늄 따위를 함유한 규산염 광물.육방 정계에 속하는 기둥 모양의 결정으로 스스로 전기가 발생되므로 전기석이라고 불리게 된 공석이다.  Tourmaline is a silicate mineral containing boron, aluminum, etc., as described in published Patent Publication No. 2002-0063535, which is a vacancy known as tourmaline because it generates electricity by itself in columnar crystals belonging to hexagonal system. .

본 발명에서는 이 전기석을 600메시 이상으로 잘 분쇄하여 5 ~ 8중량% 혼합함으로서 전자기기의 플라스틱 또는 철제 케이스 도장용으로 여러 가지 기능성 도료를 얻는다.  In the present invention, the tourmaline is finely pulverized to 600 mesh or more and mixed by 5 to 8% by weight to obtain various functional paints for painting plastic or steel cases of electronic devices.

이하에서 사용하는 비율은 모두 무게 비이고 상온 환경에서 작업한다.  The ratios used below are all weight ratios and work in a normal temperature environment.

각각의 실시 예에 공통적으로, 먼저 전기석을 600 메시 이상으로 잘 분쇄하여 전기석 분말을 준비하여 제조 공정을 진행한다.  Common to each embodiment, first, the tourmaline is pulverized well to 600 mesh or more to prepare a tourmaline powder to proceed with the manufacturing process.

실시 예 1) 전자기기용 플라스틱 케이스 도장용 아크릴 락카 도료  Example 1) Acrylic lacquer coating for plastic case coating

1-1> 아크릴 수지(20-30중량%)와 분산제(0.05-0.08중량%) 혼합하여 mixing한다.  1-1> Acrylic resin (20-30% by weight) and dispersant (0.05-0.08% by weight) are mixed and mixed.

1-2> 위의 1-1에서 mixing한 다음 안료(5-10중량%)를 혼합하여 mixing하여 균일하게 분산한 다음 전기석(tourmaline) 분말(5-8중량%)을 혼합하여 균일하게 분산한다.  1-2> Mix in 1-1 above, mix and disperse the pigment (5-10% by weight) uniformly, and then disperse evenly by mixing tourmaline powder (5-8% by weight) .

1-3> 위의 1-2에서 mixing 한 다음 방향족계용제(10-15중량%)와 케톤계용제(10-15중량%)를 첨가하여 mixing한다.  1-3> Mix in 1-2 above and mix by adding aromatic solvent (10-15% by weight) and ketone solvent (10-15% by weight).

1-4> 별도의 용기에 방향족계용제(10-15중량%)와 케톤계용제(10-15중량%)를 혼합하여 비닐수지(4-8중량%) 니트로셀루로즈(1-2중량%)를 용해한다.  1-4> A vinyl resin (4-8% by weight) nitrocellulose (1-2% by weight) by mixing an aromatic solvent (10-15% by weight) and a ketone solvent (10-15% by weight) in a separate container Dissolve).

1-5> 위의 1-3에서 제조한 원료에 위 1-4에서 제조한 원료를 혼합하여 균일하게 mixing 한다.  1-5> Mix the raw materials prepared in the above 1-4 with the raw materials prepared in the above 1-3 and mix uniformly.

1-6> 위 1-5에서 제조한 원료에 기타 첨가제(0.07-0.15중량%)를 첨가하여 균일하게 한 후 기타용제(5-8중량%)로서 점도 조절한다. 기타 첨가제로는 레벨링제, 소포제 또는 침강 방지제를 필요에 따라 적당량 첨가하며, 기타 용제는 케톤계 용제를 사용하면 된다.  1-6> After adding the other additives (0.07-0.15% by weight) to the raw material prepared in 1-5 above to make it uniform, adjust the viscosity as the other solvent (5-8% by weight). As other additives, an appropriate amount of a leveling agent, an antifoaming agent or an antisettling agent is added as necessary, and other solvents may be ketone solvents.

위와 같은 방법으로 만든 아크릴 락카(실버색상) 도료는 아크릴수지 20 ~ 30중량%, 분산제 0.05 ~ 0.08중량%, 안료 5 ~ 10중량% 전기석 분말 5 ~ 8중량%, 방향족계용제 20 ~ 30중량%, 케톤계용제 25 ~ 30중량%, 비닐수지 4 ~ 8중량%, 니트로셀루로즈 1 ~ 2중량%, 기타첨가제 0.07 ~ 0.15중량% 포함하는 전자제품 케이스 도장용 도료 조성물이 된다. 기타 첨가제로는 레벨링제, 소포제 또는 침강방지제를 필요에 따라 적당량 첨가한다.  Acrylic lacquer (silver color) paint made by the above method is 20 to 30% by weight acrylic resin, 0.05 to 0.08% by weight dispersant, pigment 5 to 10% by weight tourmaline powder 5 to 8% by weight, aromatic solvent 20 to 30% by weight , 25 to 30% by weight of ketone solvent, 4 to 8% by weight of vinyl resin, 1 to 2% by weight of nitrocellulose, and 0.07 to 0.15% by weight of other additives. As other additives, an appropriate amount of leveling agent, antifoaming agent or antisettling agent is added as necessary.

실시 예 2) 전자기기 케이스 도장용 에폭시계 도료로 금속 재질의 건축용 자재 도장용으로도 사용 가능  Example 2) Epoxy-based paint for electronic device case coating, which can be used for metal construction materials

2-1> 에폭시 수지 (9 ~ 12중량%)에 분산제 (0.1 ~ 0.3중량%)와 방향족계용제 (10 ~ 15중량%)를 혼합하여 균일하게 한다.  2-1> Epoxy resin (9-12 wt%) is mixed with a dispersant (0.1-0.3 wt%) and an aromatic solvent (10-15 wt%) to make it uniform.

2-2> 위 2-1에서 제조한 원료에 안료 (15 ~ 25중량%)를 혼합하여 균일하게 분산한다.  2-2> The pigment (15 to 25% by weight) is mixed and uniformly dispersed in the raw material prepared in 2-1 above.

2-3> 위 2-2에서 제조한 원료에 전기석 분말 (5 ~ 8중량%)을 첨가하여 균일하게 한다.  2-3> Tourmaline powder (5 ~ 8% by weight) is added to the raw material prepared in 2-2 above to make it uniform.

2-4> 위 2-3에서 제조한 원료에 기타 첨가제 (1.5 ~ 2.8중량%)를 혼합하여 mixing 후   2-4> After mixing by mixing other additives (1.5 ~ 2.8% by weight) to the raw material prepared in the above 2-3

균일하게 한다. 기타 첨가제는 레벨링제, 소포제 또는 침강방지제를 필요에 따라 적당량 첨가한다.      Make it uniform. Other additives are appropriately added leveling agents, antifoaming agents or antisettling agents as necessary.

2-5> 위 2-4에서 제조한 원료에 방향족계용제 (20 ~ 25중량%)와 알콜계용제 (10 ~ 13중량%), 셀루솔브계용제 (3 ~ 5중량%)를 혼합하여 점도 조절 후 포장한다.  2-5> Viscosity by mixing the aromatic solvent (20 ~ 25% by weight), alcohol solvent (10 ~ 13% by weight), cellulose solvent (3 ~ 5% by weight) to the raw material prepared in the above 2-4 Pack after adjustment.

2-6> 별도의 용기에 폴리아마이드((에폭시경화제) 5 ~ 10중량%)에 방향족계용제 (10 ~ 15중량%)와 셀루솔브계용제 (7 ~ 10중량%)를 혼합하여 포장한다.  2-6> In a separate container, package polyamide ((5 to 10% by weight of epoxy curing agent)) mixed with aromatic solvent (10 to 15% by weight) and cellulose solvent (7 to 10% by weight).

2-7> 위 2-5에서 제조한 제품과 위 2-6에서 제조한 제품을 별도로 포장하여 사용 시에 이 둘을 혼합한다.  2-7> Package the product prepared in 2-5 above and the product prepared in 2-6 above separately and mix them when used.

이러한 방법으로 제조되는 전자제품 케이스 도장용 도료는, 에폭시 수지 (9 ~ 12중량%), 분산제 (0.1 ~ 0.3중량%), 방향족계용제 (10 ~ 15중량%), 안료 (15 ~ 25중량%), 전기석 분말 (5 ~ 8중량%), 침강방지제, 소포제 및 또는 레벨링제 (1.5 ~ 2.8중량%), 방향족계용제 (20 ~ 25중량%)와 알콜계용제 (10 ~ 13중량%), 셀루솔브계용제 (3 ~ 5중량%) 혼합되어 포함된 제1중간 제품과 폴리아마이드((에폭시경화제) 5 ~ 10중량%)에 방향족계용제 (10 ~ 15중량%)와 셀루솔브계용제 (7 ~ 10중량%)를 혼합된 제2중간 제품을 포함하여 이루어지고, 도장 작업을 하기 직전에 제1중간 제품과 제2중간 제품을 (3 ~ 5) : 1(무게비)로 혼합됨에 의하여 기능성 도료가 된다.  The coating material for electronics case coating produced by this method is epoxy resin (9-12 wt%), dispersant (0.1-0.3 wt%), aromatic solvent (10-15 wt%), pigment (15-25 wt%) ), Tourmaline powder (5 to 8% by weight), sedimentation inhibitors, defoamers and / or leveling agents (1.5 to 2.8% by weight), aromatic solvents (20 to 25% by weight) and alcohol solvents (10 to 13% by weight), Cellulsolve solvents (3 to 5 wt%) Aromatic solvents (10 to 15 wt%) and cellulose solvents (1 to 5 wt%) in the first intermediate product and polyamide ((Epoxy Curing Agent)) 7 to 10% by weight), including a second intermediate product mixed, and the first intermediate product and the second intermediate product (3 ~ 5): 1 (weight ratio) by mixing immediately before the coating work It becomes paint.

실시 예 3) 전자기기 케이스 도장용 우레탄계 도료  Example 3) Urethane paint for painting electronic device case

3-1> 폴리에스테르 폴리올수지 (18 ~ 25중량%)와 아크릴폴리올 (10 ~ 17중량%)에 방향족계용제(4 ~ 5중량%), 아세테이트계용제 (10 ~ 18중량%)를 혼합한다.  3-1> Aromatic solvent (4 to 5 wt%) and acetate solvent (10 to 18 wt%) are mixed with polyester polyol resin (18 to 25 wt%) and acryl polyol (10 to 17 wt%). .

3-2> 위 3-1에서 제조한 원료에 분산제 (0.08 ~ 0.12중량%)를 첨가하여 mixing 한 후 안료 (4.5 ~ 6.0중량%)를 첨가하여 균일하게 분산한다.  3-2> After mixing by adding a dispersant (0.08 ~ 0.12% by weight) to the raw material prepared in 3-1 above, the pigment (4.5 ~ 6.0% by weight) is added to uniformly dispersed.

3-3> 위 3-2에서 제조한 원료에 전기석 분말 (5 ~ 8중량%)을 첨가하여 균일하게 한다.  3-3> Tourmaline powder (5 to 8% by weight) is added to the raw material prepared in 3-2 above to make it uniform.

3-4> 위 3-3에서 제조한 원료에 기타 첨가제 (1.5 ~ 2.5중량%)를 첨가하여 균일하게 한 후 케톤계용제 (8 ~ 12중량%), 아세테이트계용제 (5 ~ 8중량%)를 첨가하여 점도 조절 후 포장한다. 기타 첨가제는 레벨링제, 소포제 또는 침강방지제를 필요에 따라 적당량 첨가한다.  3-4> After adding the other additives (1.5 ~ 2.5% by weight) to the raw material prepared in the above 3-3 to homogeneous ketone solvent (8 ~ 12% by weight), acetate solvent (5 ~ 8% by weight) It is added and packaged after viscosity adjustment. Other additives are appropriately added leveling agents, antifoaming agents or antisettling agents as necessary.

3-5> 별도의 용기에 이소시아네이트((일명 우레탄경화제) 8 ~ 10중량%)와 방향족계용제 (3 ~ 7중량%), 아세테이트계용제 (10 ~ 15중량%)를 혼합하여 균일하게 한 후 포장한다.  3-5> In a separate container, mix isocyanate (aka urethane curing agent) 8 ~ 10% by weight), aromatic solvent (3 ~ 7% by weight), acetate solvent (10 ~ 15% by weight) Pack it.

3-6> 위 3-4에서 제조한 제품과 위 3-5에서 제조한 제품을 별도 포장하여 사용 시에 혼합한다.  3-6> The product manufactured in the above 3-4 and the product prepared in the above 3-5 are separately packed and mixed when used.

이러한 방법으로 제조된 도료는 폴리에스테르 폴리올 수지 (18 ~ 25중량%), 아크릴폴리올 (10 ~ 17중량%), 방향족계용제 (4 ~ 5중량%), 아세테이트계용제 (10 ~ 18중량%), 분산제 (0.08 ~ 0.12중량%), 안료 (4.5 ` 6.0중량%), 전기석 분말 (5 ~ 8중량%), 기타 첨가제 (1.5 ~ 2.5중량%), 케톤계용제 (8 ~ 12중량%), 아세테이트계용제 (5 ~ 10중량%)를 포함하는 제1중간 제품과 이소시아네이트 (8 ~ 10중량%), 방향족계용제 (3 ~ 7중량%) 및 아세테이트계용제 (10 ~ 15중량%)를 포함하는 제2중간 제품을 포함하여 도장 작업 직전에 제1중간 제품과 제2중간 제품을 (5 ~ 10) : 1(무게비)로 혼합됨에 의하여 전자제품 케이스 도장용 기능성 도료가 된다.   Paints prepared in this way are polyester polyol resins (18 to 25% by weight), acrylic polyols (10 to 17% by weight), aromatic solvents (4 to 5% by weight), acetate solvents (10 to 18% by weight) , Dispersant (0.08 ~ 0.12% by weight), pigment (4.5 `6.0% by weight), tourmaline powder (5-8% by weight), other additives (1.5-2.5% by weight), ketone solvent (8-12% by weight), A first intermediate product containing an acetate solvent (5 to 10% by weight) and an isocyanate (8 to 10% by weight), an aromatic solvent (3 to 7% by weight) and an acetate solvent (10 to 15% by weight) The first intermediate product and the second intermediate product (5 to 10): 1 (weight ratio) are mixed with the second intermediate product immediately before the painting operation, and thus, the functional paint for painting the electronics case.

본 발명의 도료의 구성비는 위에서 설명한 구성비와는 달리 다소의 가감이 가능하다.The composition ratio of the paint of the present invention can be slightly added or subtracted from the composition ratio described above.

위와 같은 방법으로 제조한 에폭시계 도료 샘플을 Test한 결과는 표1, 표2, 표3, 표4에 나타낸 바와 같다.Test results of the epoxy-based paint samples prepared by the above method is shown in Table 1, Table 2, Table 3, Table 4.

시험 데이터를 보인 표1에서 알 수 있는 바와 같이 음이온이 1cc당 1200개나 발생되는 것을 알 수 있었습니다. As can be seen from Table 1 showing the test data, it was found that 1200 anions were generated per 1cc.                     

<표 1> 음이온 Test 결과 Table 1 Anion Test Results

시료명 항 목Sample Name Item 음이온(ION/cc)Anion (ION / cc) 제조 도료Manufacture Paint 12001200

비고) 1. 시험편 : 40 * 40 * 297(mm)Remark) 1.Test piece: 40 * 40 * 297 (mm)

2. 전하입자 장치를 이용하여 온도 23℃, 습도 41% 대기 중 음이온수 73/cc 조건에서 시험하였으며 측정 대상물에서 방출되는 음이온을 측정하여 단위 체적당 이온(ION) 수로 표시한 결과임.      2. It was tested at the temperature of 23 ℃ and 41% humidity of anion water 73 / cc using charged particle device. The anion released from the object was measured and expressed as the number of ions per unit volume.

같은 시료에 대하여 원적외선 방출량을 시험하여 본 바, 표2에서 보는 바와 같이 흑체 방사 대비 90.4%나 되는 것을 알 수 있습니다.The far-infrared emission was tested on the same sample, which shows 90.4% of the black body radiation as shown in Table 2.

<표 2> 원적외선 Test 결과<Table 2> Far Infrared Test Results

방사율 (5 ~ 20㎛)Emissivity (5 ~ 20㎛) 방사 에너지 (w/㎡)Radiant energy (w / ㎡) 0.9040.904 3.64 * 103.64 * 10

비고) 1. 40℃에서 FT-IR Spectrometer를 이용한 BLACK BODY 대비 측정 결과 임.Remarks) 1. Measurement result compared to BLACK BODY using FT-IR Spectrometer at 40 ℃.

같은 시료에 대하여 탈취 시험을 하여 본 바, 표3에서 보는 바와 같이 암모니아 가스 탈취율이 30분 경과시 32.0%내지 120분 경과시 35.3%로 나타나고 있음을 알 수 있습니다.Deodorization tests were performed on the same samples, and as shown in Table 3, the ammonia gas deodorization rate was found to be 32.0% after 30 minutes to 35.3% after 120 minutes.

<표 3> 탈취 Test 결과<Table 3> Deodorization Test Results

시험 항목 (시험 가스)Test item (test gas) 경과시간(분)Elapsed time (minutes) BLANK농도(ppm)BLANK concentration (ppm) 시료농도(ppm)Sample concentration (ppm) 탈취율(%)Deodorization rate (%) 탈취시험 (NH??)Deodorization test (NH ??) 3030 194194 132132 32.032.0 6060 152152 101101 33.633.6 9090 131131 8585 35.135.1 120120 116116 7575 35.335.3

비고) 1. Blank : 시료를 넣지 않은 상태에서 측정한 것임.Remark) 1. Blank: Measured without sample.

2.시험편 : 40*40*10(mm)       2.Test piece: 40 * 40 * 10 (mm)                     

같은 시료에 대하여 대장균에 대한 항균 시험을 하여 본 바, 표4에서 보는 바와 같이 대장균 농도가 감소하고 있음을 알 수 있고, 도료가 없는 경우에 비하여 시험 전에 1:1의 농도이던 것이 시험 후에는 3.85 : 0.884로서 4.35배의 차이를 보이고 있음을 알 수 있습니다. 즉 본 발명의 도료를 사용한 경우에는 세균이 11.6% 줄어들고 있지만, 본 도료를 사용하지 아니하는 경우에는 세균이 385%로 증가하고 있음을 알 수 있습니다.As a result of the antimicrobial test for E. coli on the same sample, it can be seen that the E. coli concentration is decreasing as shown in Table 4, and that the concentration was 1: 1 before the test compared to the case without paint. : 0.884, showing a difference of 4.35 times. In other words, when the paint of the present invention is used, the bacteria decrease by 11.6%, but when the paint is not used, the bacteria increase to 385%.

또한 같은 조건으로 녹농균에 대한 항균 시험을 하여 본 바, 표4에서 보는 바와 같이 녹농균 농도가 감소하고 있음을 알 수 있고, 도료가 없는 경우에 비하여 시험 전에 1:1의 농도이던 것이 시험 후에는 3.97 : 0.85로서 4.67배의 차이를 보이고 있음을 알 수 있습니다. 즉 본 발명의 도료를 사용한 경우에는 세균이 15% 줄어들고 있지만, 본 도료를 사용하지 아니하는 경우에는 세균이 397%로 증가하고 있음을 알 수 있습니다.In addition, the antimicrobial test for Pseudomonas aeruginosa under the same conditions shows that the concentration of Pseudomonas aeruginosa is decreasing, as shown in Table 4, and that the concentration of 1: 1 before the test was 3.97 after the test compared to the case without paint. : 0.85, showing 4.67 times the difference. In other words, when the paint of the present invention is used, the germs are reduced by 15%, but when the paint is not used, the germs are increased to 397%.

<표 4> 항균 Test<Table 4> Antibacterial Test

시험항목Test Items 시료구분Sample classification 초기농도 (CFU/40P)Initial concentration (CFU / 40P) 24시간 후 농도 (CFU/40P)Concentration after 24 hours (CFU / 40P) 세균농도비Bacterial Concentration Ratio 대장균에 의한 항균 시험Antibacterial test by E. coli BLANKBLANK 421421 16211621 +3.85+3.85 제조도료Manufacture Paint 421421 372372 -0.884-0.884 녹농균에 의한 항균 시험Antibacterial test by Pseudomonas aeruginosa BLANKBLANK 406406 16101610 +3.97+3.97 제조도료Manufacture Paint 406406 345345 -0.85-0.85

비고) 1. Blank : 시료를 넣지 않은 상태에서 측정한 것임.Remark) 1. Blank: Measured without sample.

2. CFU : Colony Forming Unit      2.CFU: Colony Forming Unit

3. 401P : 0.04ML      3.401P: 0.04ML

4. 배지상의 균수는 희석 배수를 곱하여 산출한 것임.       4. The number of bacteria on the medium is calculated by multiplying the dilution multiples.                     

5. 사용균수      5. Number of bacteria used

Escherichia coli ATcc 25922         Escherichia coli ATcc 25922

Pseudomonas aeruginosa ATcc 15442         Pseudomonas aeruginosa ATcc 15442

본 기능성 도료는 플라스틱 케이스에 도포 되기에 적합하지만, 철제 소지에도 코팅 할 수가 있음은 물론이다.This functional paint is suitable for being applied to a plastic case, but of course it can be coated on steel.

이상 설명한 바와 같이 본 발명의 기능성 도료는 음이온 발생, 원적외선의 다량 방사, 탈취작용, 내항균 작용 등의 긍정적인 좋은 효과를 가진 것으로 입증되고 있다.  As described above, the functional paint of the present invention has been proved to have a good positive effect such as anion generation, large-scale radiation of far infrared rays, deodorizing action, antibacterial action and the like.

전자 기기는 보통 사람의 손이 자주 접촉하는 물건들인데, 여기에 본 기능성 도료를 사용하면 세균 번식을 막아 줄 수 있어서 위생적이다. 또 전자기기들은 녹음기, 핸드폰, mp3플레이어 등 인체와 가까이 있는 물건들이 대부분이므로 음이온 발생, 원적외선 방사, 탈취 등의 기능은 건강에 매우 좋은 것이다.Electronic devices are objects frequently touched by human hands. The use of this functional paint is hygienic because it can prevent bacterial growth. In addition, since electronic devices are mostly close to the human body such as a recorder, a mobile phone, and an mp3 player, functions such as negative ion generation, far infrared radiation, and deodorization are very good for health.

Claims (7)

삭제delete 에폭시 수지 20 ~ 30중량%, 분산제 0.05 ~ 0.08중량%, 안료 5 ~ 10중량%, 전기석분말 5 ~ 8중량%, 방향족계용제 20 ~ 30중량%, 케톤계용제 25 ~ 38중량%, 비닐수지 4 ~ 8중량%, 니트로셀루로즈 1 ~ 2중량% 및 기타 첨가제 0.07 ~ 0.15중량%를 포함하는 전자기기의 플라스틱 케이스에 도장하기 위한 기능성 도료 조성물.  20 to 30% by weight epoxy resin, 0.05 to 0.08% by weight dispersant, 5 to 10% by weight pigment, 5 to 8% by weight tourmaline powder, 20 to 30% by weight aromatic solvent, 25 to 38% by weight ketone solvent, vinyl resin A functional coating composition for coating on a plastic case of an electronic device comprising 4 to 8% by weight, 1 to 2% by weight of nitrocellulose and 0.07 to 0.15% by weight of other additives. 에폭시수지 9 ~ 12중량%, 분산제 0.1 ~ 0.3중량%, 방향족계용제 10 ~ 15중량%, 안료 15 ~ 25중량%, 전기석분말 5 ~ 8중량%, 침강방지제, 소포제 또는 레벨링제 1.5 ~ 2.8중량%, 방향족계용제 20 ~ 25중량%와 알콜계용제 10 ~ 13중량%가 혼합되어 포함된 제1중간 제품과,  Epoxy resin 9-12 wt%, dispersant 0.1-0.3 wt%, aromatic solvent 10-15 wt%, pigment 15-25 wt%, tourmaline powder 5-8 wt%, sedimentation inhibitor, antifoaming agent or leveling agent 1.5-2.8 wt% %, The first intermediate product containing 20 to 25% by weight of aromatic solvent and 10 to 13% by weight of alcohol-based solvent, 상기 에폭시수지의 경화제인 폴리아마이드 5 ~ 10중량%에 방향족계용제 10 ~ 15중량%와 셀루솔브계용제 7 ~ 10중량%가 혼합된 제2중간 제품을 포함하여 이루어지고,  5 to 10 wt% of polyamide, which is a curing agent of the epoxy resin, comprising 10 to 15 wt% of an aromatic solvent and 7 to 10 wt% of a cellulose solvent. 도장 작업을 하기 직전에 제1중간 제품과 제2중간 제품을 3 ~ 5 : 1의 중량비로 혼합하여 사용하는 것을 특징으로 하는 금속 재질의 건축 자재용 기능성 도료 조성물.A functional coating composition for a building material of metal material, characterized in that the first intermediate product and the second intermediate product are mixed at a weight ratio of 3 to 5: 1 immediately before the painting work. 플라스틱제 또는 철제를 포함하는 전자기기의 케이스를 도장하기 위한 기능성 도료로서, 폴리에스테르 폴리올수지 18 ~ 25중량%, 아크릴폴리올 10 ~ 17중량%, 방향족계용제 4 ~ 5중량%, 아세테이트계용제 10 ~ 18중량%, 분산제 0.08 ~ 0.12중량%, 안료 4.5 ~ 6.0중량%, 전기석분말 5 ~ 8중량%, 기타첨가제 1.5 ~ 2.5중량%, 케톤계용제 8 ~ 12중량%, 아세테이트계용제 5 ~ 10중량%를 포함하는 제1중간 제품과,  As a functional paint for coating a case of an electronic device including plastic or iron, 18 to 25% by weight of polyester polyol resin, 10 to 17% by weight of acrylic polyol, 4 to 5% by weight of aromatic solvent, and 10% of acetate solvent ~ 18% by weight, dispersant 0.08 ~ 0.12% by weight, pigment 4.5 ~ 6.0% by weight, tourmaline powder 5 ~ 8% by weight, other additives 1.5 ~ 2.5% by weight, ketone solvent 8-12% by weight, acetate solvent 5-10 A first intermediate product comprising weight percent, 이소시아네이트 8 ~ 10중량%, 방향족계용제 3 ~ 7중량% 및 아세테이트계용제 10 ~ 15중량%를 포함하는 제2중간 제품을 포함하고,  A second intermediate product comprising 8 to 10% by weight of isocyanate, 3 to 7% by weight of aromatic solvent and 10 to 15% by weight of acetate solvent, 도장작업 직전에 제1중간 제품과 제2중간 제품을 5 ~ 10 : 1의 중량비로 혼합하여 사용하는 것을 특징으로 하는 전자기기 케이스 도장용 기능성 도료. Functional paint for electronic device case coating, characterized in that the first intermediate product and the second intermediate product is mixed at a weight ratio of 5 to 10: 1 immediately before the painting work. 전자기기 플라스틱 케이스 도장용 기능성 도료 제조 방법에 있어서,  In the functional paint manufacturing method for painting the electronic device plastic case, (가) 아크릴수지 20 ~ 30중량%와 분산제 0.05 ~ 0.08중량%를 혼합 믹싱하고, 여기에 안료 5 ~ 10중량%를 혼합 믹싱하여 균일하게 분산한 다음, 전기석분말 5 ~ 8중량%을 혼합하여 균일하게 분산되게 하고, 방향족계용제 10 ~ 15중량%와 케톤계용제 10 ~ 15중량%를 첨가하여 믹싱하고,(A) 20 to 30% by weight of acrylic resin and 0.05 to 0.08% by weight of dispersant are mixed and mixed, 5 to 10% by weight of pigment is mixed and uniformly dispersed, and then 5 to 8% by weight of tourmaline powder is mixed. Uniformly dispersed, 10 to 15% by weight of an aromatic solvent and 10 to 15% by weight of a ketone solvent are added and mixed, (나) 별도의 용기에 방향족계용제 10 ~ 15중량%와 케톤계용제 10 ~ 15중량%를 혼합하여 비닐수지 4 ~ 8중량%, 니트로셀루로즈 1 ~ 2중량%를 용해시키고, 상기 (가)에서 제조한 원료를 혼합하여 균일하게 믹싱하고, 기타 첨가제 0.07 ~ 0.15중량%를 첨가하여 균일하게 한 후 기타 용제 5 ~ 8중량%로서 점도 조절하는 것이 특징인 전자기기용 플라스틱 케이스 도장용 기능성 도료 제조방법(B) 10 to 15% by weight of aromatic solvent and 10 to 15% by weight of ketone solvent are mixed in a separate container to dissolve 4 to 8% by weight of vinyl resin and 1 to 2% by weight of nitrocellulose. ) To prepare a functional coating material for plastic case coating for electronic devices, characterized by mixing uniformly by mixing the raw materials prepared in the), uniformly adding 0.07 to 0.15 wt% of other additives, and then adjusting the viscosity as 5 to 8 wt% of other solvents. Way 금속 재질의 건축 자재 도장용 기능성 도료 제조 방법에 있어서,  In the method of manufacturing a functional paint for painting a building material of a metal material, (가) 에폭시 수지 9 ~ 12중량%에 분산제 0.1 ~ 0.3중량%와 방향족계용제 10 ~ 15중량%를 혼합하여 균일하게 하고, 안료 15 ~ 25중량%를 혼합하여 균일하게 분산하고, 전기석 분말 5 ~ 8중량%을 첨가하여 균일하게 하고, 기타 첨가제 1.5 ~ 2.8중량%를 혼합하여 믹싱한 후 균일하게 하고, 방향족계용제 20 ~ 25중량%와 알콜계용제 10 ~ 13중량%, 셀루솔브계용제 3 ~ 5중량%를 혼합하여 점도 조절 후 제1중간 제품으로 포장하고,(A) 9 to 12% by weight of epoxy resin, 0.1 to 0.3% by weight of dispersant and 10 to 15% by weight of aromatic solvent are mixed and uniformly mixed, 15 to 25% by weight of pigment is uniformly dispersed, and tourmaline powder 5 ~ 8% by weight is added to make uniform, and 1.5 to 2.8% by weight of other additives are mixed and uniformly mixed, 20 to 25% by weight aromatic solvent, 10 to 13% by weight alcohol solvent, cellulose solvent 3 to 5% by weight of the mixture after mixing the viscosity of the first product packaging, (나) 상기 에폭시 수지 경화제인 폴리아마이드 5 ~ 10중량%에 방향족계용제 10 ~ 15중량%와 셀루솔브계용제 7 ~ 10중량%를 혼합하여 제2중간 제품으로 포장한 후, (B) After mixing 10 to 15% by weight of the aromatic solvent and 7 to 10% by weight of the cellulsolve solvent to polyamide 5 to 10% by weight of the polyamide of the epoxy resin curing agent, and then packaged as a second intermediate product, 사용 시에는 제1중간 제품과 제2중간 제품을 3 ~ 5 : 1의 중량비로 혼합하여 사용하게 하는 것을 특징으로 하는 금속 재질의 건축자재 도장용 기능성 도료 제조 방법.When using, the first intermediate product and the second intermediate product is a functional paint manufacturing method for painting the building material of a metal material, characterized in that to mix and use in a weight ratio of 3 to 5: 1: 1. 전자기기 케이스 도장용 기능성 도료 제조 방법에 있어서,  In the functional paint manufacturing method for painting the electronic device case, (가) 폴리에스테르 폴리올수지 18 ~ 25중량%와 아크릴폴리올 10 ~ 17중량%에 방향족계용제 4 ~ 5중량%, 아세테이트계용제 10 ~ 18중량%를 혼합하고, 분산제 0.08 ~ 0.12중량%를 첨가하여 믹싱한 후 안료 4.5 ~ 6.0중량%를 첨가하여 균일하게 분산되게 하고, 전기석 분말 5 ~ 8중량%을 첨가하여 균일하게 하고, 레벨링제, 침강방지제, 소포제 등의 첨가제 1.5 ~ 2.0중량%를 첨가하여 균일하게 한 후 케톤계용제 8 ~ 12중량%, 아세테이트계용제 5 ~ 10중량%를 첨가하여 점도 조절 후 제1중간 제품으로 포장하고,(A) 18 to 25% by weight of polyester polyol resin and 10 to 17% by weight of acrylic polyol are mixed with 4 to 5% by weight of aromatic solvent and 10 to 18% by weight of acetate solvent, and 0.08 to 0.12% by weight of dispersant is added. After mixing, add 4.5 to 6.0% by weight of pigment to make it uniformly dispersed, add 5 to 8% by weight of tourmaline powder to make it uniform, and add 1.5 to 2.0% by weight of additives such as leveling agent, antisettling agent and antifoaming agent. After uniformity by adding 8 to 12% by weight of ketone solvent, 5 to 10% by weight of acetate-based solvent, after packaging the first intermediate product after viscosity control, (나) 이소시아네이트 8 ~ 10중량%, 방향족계용제 3 ~ 7중량% 및 아세테이트계용제 10 ~ 15중량%를 혼합하여 균일하게 한 후 제2중간 제품으로 포장한 후, 사용 시에 제1중간 제품과 제2중간 제품을 5 ~ 10 : 1의 중량비로 혼합하여 사용하는 것을 특징으로 하는 전자기기 케이스 도장용 기능성 도료 제조 방법.(B) Uniformly mix 8 to 10% by weight of isocyanate, 3 to 7% by weight of aromatic solvent and 10 to 15% by weight of acetate solvent, package it with a second intermediate product, and then use the first intermediate product. And a second intermediate product in a weight ratio of 5 to 10: 1 by using a functional paint manufacturing method for painting the electronic device case.
KR1020040029621A 2004-04-28 2004-04-28 A multifunction paints for cases of electronic apparatus and a method thereof KR100730577B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020040029621A KR100730577B1 (en) 2004-04-28 2004-04-28 A multifunction paints for cases of electronic apparatus and a method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020040029621A KR100730577B1 (en) 2004-04-28 2004-04-28 A multifunction paints for cases of electronic apparatus and a method thereof

Publications (2)

Publication Number Publication Date
KR20050104244A KR20050104244A (en) 2005-11-02
KR100730577B1 true KR100730577B1 (en) 2007-06-20

Family

ID=37281899

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020040029621A KR100730577B1 (en) 2004-04-28 2004-04-28 A multifunction paints for cases of electronic apparatus and a method thereof

Country Status (1)

Country Link
KR (1) KR100730577B1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100744399B1 (en) * 2005-12-21 2007-07-30 삼성전자주식회사 Coating composition for soft feel coating composition using suface of electronic device and mobile phone and producing method thereof
KR100672758B1 (en) * 2005-12-28 2007-01-22 (주)디피아이 홀딩스 Water-soluble baking enamel paint
KR100840182B1 (en) * 2006-07-13 2008-06-23 주식회사 에스아이 앤 지 The antibiosis ink by nano-silver and using process
KR100880841B1 (en) * 2007-04-02 2009-02-02 부산대학교 산학협력단 Antifouling paint composition
KR101327988B1 (en) * 2013-02-21 2013-11-20 웅진산업 주식회사 Tourmaline containing epoxy resin coating layer with a steel pipe and method of manufacturing the same
KR101327986B1 (en) * 2013-02-21 2013-11-13 웅진산업 주식회사 Tourmaline containing epoxy resin coating layer having a steel pipe
CN104356931B (en) * 2014-11-21 2016-08-17 山东雷帕得汽车技术股份有限公司 A kind of anion antioxidant coating for automobile spring plate and preparation method thereof
KR102575519B1 (en) * 2018-08-27 2023-09-07 삼성전자주식회사 Case of electronic device, electronic device comprising the same and manufacturing method for case of electronic device

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06173162A (en) * 1992-12-01 1994-06-21 Tsuneo Sato Sheet coated with fine tourmaline powder and its production
JPH11350342A (en) 1998-06-08 1999-12-21 Nippon Hanekku:Kk Fabric
KR100310680B1 (en) 1998-11-23 2001-12-17 김순택 Display system coated with ceramic coating material and manufacturing method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06173162A (en) * 1992-12-01 1994-06-21 Tsuneo Sato Sheet coated with fine tourmaline powder and its production
JPH11350342A (en) 1998-06-08 1999-12-21 Nippon Hanekku:Kk Fabric
KR100310680B1 (en) 1998-11-23 2001-12-17 김순택 Display system coated with ceramic coating material and manufacturing method

Also Published As

Publication number Publication date
KR20050104244A (en) 2005-11-02

Similar Documents

Publication Publication Date Title
KR100730577B1 (en) A multifunction paints for cases of electronic apparatus and a method thereof
JP5208728B2 (en) Functional UV paint, building material using the same, and method for producing the paint
KR20090097600A (en) Paint composition of friendly-environmental type and manufacturing method thereof
CN105331268A (en) Low-carbon waterborne coating and preparation method thereof
CN103331791A (en) Novel hard environment-friendly wood wax oil and preparation method thereof
KR101030281B1 (en) Putty for construction
CN104284950B (en) Low VOC glycol ethers coalescent for water based paint
CN101608079A (en) A kind of Wiping colorant for aqueous wooden ware and preparation method thereof
DE602004013041D1 (en) COATING COMPOSITION WITH AN AQUEOUS FILM-FORMING POLYMER DISPERSION AND A POLYETHERSILICONE, THEIR PREPARATION AND USE
CN101735728A (en) Interior activated carbon paint
KR101728751B1 (en) Eco-friendly ceramic high performance coating
KR101725188B1 (en) Eco-friendly ceramic paint composition and method for manufacturing the same
JP2010024391A (en) Water-based paint composition
KR100939078B1 (en) A Closing Material Composition of Building
KR100428589B1 (en) Environmental affinitive functional paint, preparing method thereof and preparing method for vegetable resin utilized in the same
KR100574739B1 (en) The multi-functional finishing coat
CN104559542A (en) Environment-friendly sterilizing interior wall coating
KR20030018026A (en) The functional paint radiating natural anion
EP4074784A1 (en) Composition for producing coatings with improved luminescent material
WO2018008479A1 (en) Coating composition
EP4074783A1 (en) Water-based curable composition for producing coatings with luminescent material
KR102009213B1 (en) Coating Composition Having Cellulose Powder for Blocking Solar Heat
KR100366661B1 (en) Composition for coating materials
KR101473382B1 (en) Lacquer - uv curing type dry paint film and method of forming the same
KR200357558Y1 (en) A case for Electronic products

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee