KR100729503B1 - Environment-friendly board using green tea and wood-based plate-shaped product comprising the same - Google Patents

Environment-friendly board using green tea and wood-based plate-shaped product comprising the same Download PDF

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KR100729503B1
KR100729503B1 KR1020050047878A KR20050047878A KR100729503B1 KR 100729503 B1 KR100729503 B1 KR 100729503B1 KR 1020050047878 A KR1020050047878 A KR 1020050047878A KR 20050047878 A KR20050047878 A KR 20050047878A KR 100729503 B1 KR100729503 B1 KR 100729503B1
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green tea
wood
board
foil
friendly
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KR1020050047878A
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Korean (ko)
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KR20060126168A (en
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예성훈
강석구
김지웅
이민정
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주식회사 엘지화학
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F13/00Making discontinuous sheets of paper, pulpboard or cardboard, or of wet web, for fibreboard production
    • D21F13/10Making discontinuous sheets of paper, pulpboard or cardboard, or of wet web, for fibreboard production using board presses
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/02Material of vegetable origin

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  • Dry Formation Of Fiberboard And The Like (AREA)

Abstract

본 발명은 녹차 또는 녹차박을 이용한 친환경 보드 및 이를 적용한 목질 판상 제품에 관한 것으로, 목섬유(Wood Fiber) 또는 목재 파티클(Wood Particle)에 녹차 또는 녹차박을 2:1 내지 9:1의 중량비율로 혼합하여 제작한 목질계 보드 및 이를 이용하여 제작한 목질 판상제품을 제공한다.The present invention relates to an eco-friendly board using green tea or green tea foil, and a wooden plate-like product to which the green tea or green tea foil is applied, wherein the weight ratio of green tea or green tea foil is 2: 1 to 9: 1 on Wood Fiber or Wood Particle. It provides a wood-based board produced by mixing and a wood-based product produced by using the same.

본 발명의 목질계 보드는 저렴한 순수 천연식물인 100% 녹차 또는 녹차박을 사용하여 제작한 친환경 보드로서, 국내 친환경 규제치인 TVOC 방산량 0.1 ㎎/㎡hr 이하, HCHO 방산량 0.03 ㎎/㎡hr 이하를 만족함으로써, 환경적인 측면과 경제적인 측면을 동시에 해결할 수 있다.The wood-based board of the present invention is an eco-friendly board made using 100% green tea or green tea foil, which is an inexpensive pure natural plant, and satisfies the TVOC emission amount of 0.1 mg / m 2 hr or less, HCHO dispersion amount of 0.03 mg / m 2 or less By doing so, both environmental and economic aspects can be solved at the same time.

녹차, 보드 Green tea, board

Description

녹차 또는 녹차박을 이용한 친환경 보드 및 이를 적용한 목질 판상 제품{Environment-friendly board using green tea and wood-based plate-shaped product comprising the same}Environment-friendly board using green tea and wood-based plate-shaped product comprising the same}

본 발명은 친환경 목질계 보드 및 이를 적용한 목질 판상제품에 관한 것으로, 보다 상세하게는 목섬유 또는 목재 파티클에 녹차 또는 녹차박을 혼합하여 제작한 목질계 보드 및 이를 이용하여 제작한 목질 판상제품에 관한 것이다.The present invention relates to an eco-friendly wood board and a wood plate product applied thereto, and more particularly, to a wood board made by mixing green tea or green tea foil with wood fibers or wood particles, and a wood board product produced using the same. .

최근 들어 오염물질 대량 방출 건축자재의 사용을 제한하고 있다. 보드 제조에 있어서, UF(Urea Formaldehyde) 수지의 저몰비화에 따른 생산성 감소와, TVOC(Total Volatile Organic Compounds: 총휘발성유기화합물) 및 HCHO(포름알데히드)를 제거시키기 위해 사용되고 있는 스캐빈저(Scavenger)의 경우, 대부분이 액체형으로써 제조 공정상 보드의 함수율을 증가시킬 뿐만 아니라, 고가라서 큰 추가 비용이 따른다.Recently, there has been a restriction on the use of building materials that emit large amounts of pollutants. Scavenger used in board manufacturing to reduce productivity due to the low molar ratio of UF (Urea Formaldehyde) resin, and to remove TVOC (Total Volatile Organic Compounds) and HCHO (formaldehyde) In most cases, the liquid form not only increases the water content of the board in the manufacturing process, but also is expensive and carries a large additional cost.

현재 합판 및 목질보드 업계에서는 실내공기질 관리와 관련하여 수지합성기술 개발에 집중하고 있으나, 기존과 동일한 물성의 생산 제품을 확보하려고 함에 따라 유발되는 제조원가 상승이 큰 문제로 남아있다. 또한, 종래 친환경 보드로 개 발되고 있는 숯 첨가형 보드 제품의 경우는 TVOC 및 HCHO의 재방출이 문제되고 있다.Currently, the plywood and wood board industry is focusing on the development of resin synthesis technology in relation to indoor air quality management, but the increase in manufacturing cost caused by securing the production products of the same physical properties remains a big problem. In addition, in the case of a charcoal-type board product that is developed as a conventional eco-friendly board, re-emission of TVOC and HCHO is a problem.

따라서, 본 발명의 목적은 기존의 높은 가격대를 형성하고 있는 스캐빈저 투입 대신 저렴한 천연물질을 사용함으로써, 환경적인 측면과 경제적인 측면을 동시에 해결할 수 있는 목질계 보드 및 이를 적용한 목질 판상제품을 제공하는 것이다.Accordingly, an object of the present invention is to provide a wood-based board and a wooden board product using the same that can solve both environmental and economic aspects by using inexpensive natural materials instead of the scavenger that forms the existing high price range It is.

본 발명은 상기한 목적을 달성하기 위하여, 목섬유(Wood Fiber) 또는 목재 파티클(Wood Particle)에 녹차 또는 녹차박을 2:1 내지 9:1의 중량비율로 혼합하여 제작한 목질계 보드를 제공한다.The present invention provides a wood-based board produced by mixing green tea or green tea foil in a weight ratio of 2: 1 to 9: 1 to wood fiber or wood particles. .

상기 녹차 또는 녹차박은 균일한 혼합을 고려하여 120 Mesh(0.117 ㎜) 이하의 분말형태로 혼합하는 것이 바람직하다.The green tea or green tea foil is preferably mixed in a powder form of 120 Mesh (0.117 mm) or less in consideration of uniform mixing.

본 발명에서 제작하고자 하는 목질계 보드는 MDF(Medium Density Fiberboard), HDF(High Density Fiberboard), PB(Particle Board)와 같은 목질계 보드이다.The wood board to be produced in the present invention is a wood board such as MDF (Medium Density Fiberboard), HDF (High Density Fiberboard), PB (Particle Board).

또한, 본 발명은 상기 목질계 보드를 이용하여 제작한 온돌마루, 강화마루, 벽체 등의 목질 판상제품을 제공한다.In addition, the present invention provides a wooden plate-like product such as ondol floor, reinforced floor, wall made using the wood-based board.

본 발명의 목질계 보드는 저렴한 순수 천연식물인 100% 녹차 또는 녹차박을 사용하여 제작한 친환경 보드로서, 국내 친환경 규제치인 TVOC 방산량 0.1 ㎎/㎡hr 이하, HCHO 방산량 0.03 ㎎/㎡hr 이하를 만족함으로써, 환경적인 측면과 경제적인 측면을 동시에 해결할 수 있다.The wood-based board of the present invention is an eco-friendly board made using 100% green tea or green tea foil, which is an inexpensive pure natural plant, and satisfies the TVOC emission amount of 0.1 mg / m 2 hr or less, HCHO dispersion amount of 0.03 mg / m 2 or less By doing so, both environmental and economic aspects can be solved at the same time.

또한, 본 발명의 목질계 보드는 종래 친환경 보드로 개발되고 있는 숯 첨가형 보드 제품에서 발생할 수 있는 TVOC 및 HCHO의 재방출을 원천적으로 제거시킨 친환경 보드로써, 녹차 또는 녹차박을 이용하여 비점이 낮은 물질도 화학적으로 흡착함으로써 보다 안정적인 친환경 보드를 제작할 수 있다.In addition, the wood-based board of the present invention is an eco-friendly board that eliminates the re-emission of TVOC and HCHO that may occur in the charcoal board products that are developed as a conventional eco-friendly board, a low boiling point material using green tea or green tea foil By chemically adsorption, more stable eco-friendly boards can be manufactured.

아울러 녹차의 기능을 첨가함으로 인하여 중금속을 제거할 수 있고, 녹차에 포함되어 있는 폴리페놀 성분은 니코틴과 쉽게 결합하여 냄새를 제거하는 역할도 한다.In addition, by adding the function of green tea can remove heavy metals, polyphenols contained in green tea is easily combined with nicotine to remove odors.

본 발명에 적용되는 녹차 또는 녹차박이 함유하는 카테킨(Catechin)은 폴리페놀 중 플라보노이드(Flavonoids)의 한 형태로서 떫은 맛을 내는 성분이며, 화학 구조상 수산기(-OH)를 많이 가지고 있어 여러가지 물질과 결합을 쉽게 할 수 있다. 이러한 성질로 인하여 체내 중금속 제거나 활성산소를 제거하는 항산화작용을 한다.Catechin contained in green tea or green tea foil according to the present invention is a form of flavonoids in polyphenols, which has a rich taste, and has a number of hydroxyl groups (-OH) due to its chemical structure. You can do it easily. Due to these properties, the body has antioxidant activity to remove heavy metals or remove free radicals.

또한, 녹차 또는 녹차박이 함유하는 타닌(Tannin)은 6종류의 카테킨으로 구성되어 있어 차의 색깔과 향기, 맛을 크게 좌우하는 성분으로, 폴리페놀(Polyphenol)이라고도 지칭하며, 비타민류 성분이 존재할 경우 카페인과 낮은 온도에서 결합해서 불용성 화학물을 형성한다.In addition, tannin, which is contained in green tea or green tea leaves, is composed of six kinds of catechins, which greatly influences the color, aroma, and taste of tea, and is also called polyphenol. Combines with caffeine at low temperatures to form insoluble chemicals.

상기 카테킨 또는 타닌은 항산화작용 및 흡착 메카니즘에 의하여 TVOC 또는 HCHO 물질을 물리 화학적으로 제거시키며, 외부 열에 의해 그 반응성이 증가하여 TVOC 및 HCHO 감소에 급격한 기여를 한다.The catechin or tannin physicochemically removes TVOC or HCHO substances by antioxidant and adsorption mechanisms, and its reactivity is increased by external heat, thereby making a drastic contribution to TVOC and HCHO reduction.

본 발명에서 TVOC란 헥산(Hexane)에서부터 헥사데칸(Hexadacane) 사이에 나오는 휘발성 유기화합물들을 일컫는다.In the present invention, TVOC refers to volatile organic compounds appearing between hexane (Hexane) and hexadecane (Hexadacane).

이하, 본 발명에 따른 목질계 보드에 대하여 보다 구체적으로 설명한다.Hereinafter, the wood board according to the present invention will be described in more detail.

본 발명의 친환경 목질계 보드는 목섬유 또는 목재 파티클 원료와, TVOC 및 HCHO의 화학적 흡착기능을 갖는 녹차 또는 녹차박의 분말을 적절한 비율로 골고루 섞어 충분히 혼합하여 제작한 것이다.Eco-friendly wood-based board of the present invention is produced by mixing the wood fiber or wood particle raw material and the powder of green tea or green tea foil having a chemical adsorption function of TVOC and HCHO evenly mixed in an appropriate ratio.

이때 목섬유 또는 목재 파티클 소재와 녹차 또는 녹차박 분말의 혼합비율을 2:1 내지 9:1의 중량비율로 혼합하는 것이 바람직하다. 목섬유 또는 목재 파티클 소재 제조시 녹차 또는 녹차박 분말의 혼합비율이 많아질수록 HCHO의 감소 효과가 우수하지만, 기재층의 비중이 점점 낮아져서 보드 제조에 어려움이 있게 되므로 2:1 이상의 첨가는 불가능하며, 혼합비율이 적을 경우 녹차효과를 기대할 수 없다.At this time, it is preferable to mix the mixing ratio of the wood fiber or wood particle material and the green tea or green tea powder in a weight ratio of 2: 1 to 9: 1. In the preparation of wood fiber or wood particle material, the more the mixing ratio of green tea or green tea powder powder is, the better the HCHO reduction effect, but since the specific gravity of the base layer is gradually lowered, it becomes difficult to manufacture the board, so it is impossible to add more than 2: 1. If the mixing ratio is small, the green tea effect cannot be expected.

상기 친환경 소재로 사용되는 녹차 및 녹차박 원료의 혼합을 균일하기 위해서는 소재의 분말화가 중요하며, 이때 입자는 미분쇄하여 약 120 Mesh(0.117 ㎜) 이하로 분말화하면 사용에 어려움이 없다.In order to uniformize the mixing of the green tea and green tea foil raw materials used as the environmentally friendly material, the powdering of the material is important, and when the powder is pulverized to about 120 Mesh (0.117 mm) or less, there is no difficulty in use.

녹차 또는 녹차박의 분말을 첨가할 경우, 탈취 및 각종 독성제거의 기능을 함께 갖게 되어 공기를 신선하게 하는 기능을 한다.When added to the powder of green tea or green tea foil, it has the function of deodorization and various toxic removal together to freshen the air.

파티클보드는 목재 및 기타 식물 섬유질의 소편(Particle), 즉 절삭편 또는 파쇄편 등을 주재료로 하여 합성수지 접착제를 첨가하여 성형, 열압시킨 밀도 0.5 g/㎤ 이상, 0.9 g/㎤ 이하의 판재상 제품이다.Particleboard is a plate-like product with a density of 0.5 g / cm3 or more and 0.9 g / cm3 or less that is molded and hot pressed by adding a synthetic resin adhesive, mainly made of wood and other plant fiber particles, that is, cutting or crushed pieces. to be.

이때 사용되는 접착제의 합성수지는 UF(Urea Formaldehyde), MUF(Melamine Urea Formaldehyde), PUF(Phenol Urea Formaldehyde), MF(Melamine Formadehyde), PF(Phenol Formaldehyde) 군에서 선택되는 1종이다.The synthetic resin of the adhesive used at this time is one selected from the group UF (Urea Formaldehyde), MUF (Melamine Urea Formaldehyde), PUF (Phenol Urea Formaldehyde), MF (Melamine Formadehyde), PF (Phenol Formaldehyde).

MDF는 목질재료를 주원료로 하여 고온에서 해섬하여 얻은 목섬유(Wood Fiber)를 합성수지 접착제로 결합시켜 성형, 열압하여 만든 밀도 0.4 내지 0.8 g/㎤의 목질판상 제품이다.MDF is a wood plate product with a density of 0.4 to 0.8 g / cm 3 made by combining wood fiber obtained by dissolving at high temperature with a wood material as a main raw material with a synthetic resin adhesive.

HDF는 밀도가 900 ㎏/㎥ 이상의 고밀도 섬유판으로, 강도면에서 일반 MDF보다 훨씬 높은 목질 판상제품이다.HDF is a high-density fiber board with a density of 900 kg / m 3 or more, which is a wooden board product much higher than general MDF in terms of strength.

이와 같이 친환경 소재 및 합성수지를 이용하여 제작한 보드를 통해 얻고자 하는 친환경 판상제품의 제조가 가능하다.As such, it is possible to manufacture eco-friendly plate products to be obtained through boards made using eco-friendly materials and synthetic resins.

본 발명에 따른 친환경 목질계 보드의 두께를 최소 3 ㎜에서 최대 15 ㎜까지 다양하게 제작하여 아파트나 주택 바닥 또는 벽체에 시공할 경우, 건설사에서 요구하는 0.03 ㎎/㎡hr 보다 엄격한 일본 HCHO 규제치인 0.005 ㎎/㎡hr도 만족시킬 수 있으며, 일본 최고 등급인 F★★★★을 만족하는 MDF, HDF의 생산이 가능하고, E1 등급의 PB를 안정적으로 생산할 수 있으며, PB의 측면 및 표면도장을 실시할 경우 건설사에서 요구하는 0.03 ㎎/㎡hr를 만족시킬 수 있다.When the thickness of the eco-friendly wood board according to the present invention is manufactured in various thicknesses from 3 mm to 15 mm at least, and applied to an apartment or house floor or wall, Japanese HCHO regulations 0.005, which is stricter than 0.03 mg / ㎡hr, required by the construction company. ㎎ / ㎡hr Fig also meets, enables the production of MDF, HDF that satisfy the highest grade of F ★★★★ Japan, and can produce PB of E 1 rating reliably, and the side surfaces and the surface coating of PB In case of implementation, it can satisfy 0.03 mg / m2hr required by the construction company.

[실시예]EXAMPLE

본 발명에 따라 녹차를 이용한 MDF를 다음과 같이 제작하였다.MDF using green tea according to the present invention was produced as follows.

박피공정을 통해 목재의 수피를 제거한 목재원료를 컨베이어를 통하여 칼날이 부착된 회전드럼을 구비한 파쇄기로 파쇄시켜 칩을 만든 다음, 이를 7 내지 10 ㎏/㎠의 포화수증기로 160℃ 이상 고온, 고압하에서 수분동안 증자시킨 후 리파이너(refiner)를 이용해 해섬시켜 목질섬유(Wood Fiber)를 제조하였다.The raw material from which the bark of wood is removed through the peeling process is crushed by a crusher with a rotating drum attached with a blade through a conveyor to make chips, which is then saturated with steam of 7 to 10 ㎏ / ㎠ After steaming for a few minutes under the condition of using a refiner (refiner) to prepare a wood fiber (Wood Fiber).

한편, 녹차를 미분쇄하여 약 120 Mesh 이하의 분말을 제조하였다.On the other hand, green tea was ground to produce a powder of about 120 Mesh or less.

다음, 조제된 목질섬유에 녹차 분말을 중량비 5:1로 혼합한 후, 고속혼합기에서 함지율(목질원료의 전건무게에 대한 접착제 고형분 무게의 비율)이 12%가 되도록, 멜라민 수지 50 중량% 및 요소 수지 50 중량%로 이루어진 접착제를 도포하였다.Next, after mixing the green tea powder with a weight ratio of 5: 1 to the prepared wood fibers, 50% by weight of melamine resin and so that the content ratio (the ratio of the weight of the adhesive solid to the total weight of the wood material) in a high-speed mixer, 12% An adhesive consisting of 50% by weight of urea resin was applied.

이를 건조기 내의 열풍에 의해 건조시켰다. 이때 도포된 섬유 및 녹차 분말의 함수율은 10% 이하가 되도록 건조시켰다.This was dried by hot air in a dryer. At this time, the water content of the applied fiber and green tea powder was dried to 10% or less.

다음, 접착제가 도포된 녹차분말 혼합 파티클을 매트성형장치를 이용하여 매트상의 형태로 성형하였다.Next, the green tea powder mixed particles to which the adhesive was applied were molded into a mat shape using a mat molding apparatus.

다음, 성형된 파티클매트를 연속프레스에서 가열 압체하여 경화시켰다. 이때 열압조건은 압력 30 내지 40 ㎏f/㎠, 온도 180 내지 210℃, 시간 15 내지 28초/㎜로 설정하였다.Next, the molded particle mat was cured by hot pressing in a continuous press. At this time, the thermal pressure conditions were set to a pressure of 30 to 40 kgf / cm 2, a temperature of 180 to 210 ° C., and a time of 15 to 28 seconds / mm.

최종적으로, 열압경화된 파티클매트를 냉각시켜 규격치수에 맞추어 재단하고, 연삭과정을 거쳐 본 발명에 따라 녹차를 이용한 MDF를 제조하였다. Finally, the heat-cured particle mat was cooled and cut to a standard dimension, and after the grinding process, an MDF using green tea was prepared according to the present invention.

[비교예][Comparative Example]

상기 녹차분말을 혼합하지 않은 것을 제외하고는 상기 실시예와 동일하게 제조하였다.It was prepared in the same manner as in Example except that the green tea powder was not mixed.

[시험예][Test Example]

표 1은 상기 실시예 및 비교예의 MDF에 대한 TVOC 및 HCHO 방산량을 비교한 것으로, 이때 TVOC 방산량은 ISO6000-3, ISO6000-6 측정법에 의해 측정하였으며, HCHO 방산량은 KSF3111 유해화합물질 측정법에 의해 측정하였다.Table 1 compares the TVOC and HCHO dissipation with respect to the MDF of the Examples and Comparative Examples, wherein the TVOC dissipation was measured by the ISO6000-3, ISO6000-6 measurement method, HCHO dissipation was measured by KSF3111 hazardous compound measurement method .

표 1에 나타난 바와 같이, TVOC 방산량에 있어서 본 발명의 MDF는 비교예 MDF의 1/5 수준에 불과하였으며, HCHO 방산량에 있어서 본 발명의 MDF는 1/11 수준이었다.As shown in Table 1, the MDF of the present invention in the TVOC dissipation amount was only 1/5 level of the comparative example MDF, the MDF of the present invention in the HCHO dissipation amount was 1/11 level.

비교예Comparative example 실시예Example TVOCTVOC 0.15 ㎎/㎡hr0.15 mg / ㎡hr 0.03 ㎎/㎡hr0.03 mg / ㎡hr HCHOHCHO 0.308 ㎎/㎡hr0.308 mg / ㎡hr 0.028 ㎎/㎡hr0.028 mg / ㎡hr

이상 설명한 바와 같이, 본 발명은 친환경 보드를 제조하되, 제작공정 중 합성수지에서 방출되는 유리 HCHO 및 TVOC를 제거하기 위해 목분 또는 목재 섬유 또는 파티클 원료에 녹차 또는 녹차박 분말을 적절한 비율로 혼합한 다음 제품화한 목질계 보드 및 이를 적용한 바닥이나 벽체 제품을 제공함으로써, Free HCHO는 물론 TVOC 방산량을 최소화시킨 친환경 제품의 생산이 가능하다.As described above, the present invention manufactures an eco-friendly board, but after mixing the green tea or green tea powder in an appropriate proportion to the wood flour or wood fiber or particle raw material to remove the free HCHO and TVOC released from the synthetic resin during the manufacturing process and then commercialized By providing a wooden board and floor or wall products using the same, it is possible to produce free HCHO as well as eco-friendly products with minimal TVOC emissions.

Claims (5)

목섬유(Wood Fiber) 또는 목재 파티클(Wood Particle)에 녹차 또는 녹차박을 2:1 내지 9:1의 중량비율로 혼합하여 제작한 목질계 보드.Wood-based boards produced by mixing green tea or green tea foil in a weight ratio of 2: 1 to 9: 1 on wood fibers or wood particles. 제1항에 있어서, 상기 녹차 또는 녹차박을 120 Mesh(0.117 ㎜) 이하의 분말형태로 혼합하는 것을 특징으로 하는 목질계 보드.The wood board according to claim 1, wherein the green tea or green tea foil is mixed in a powder form of 120 Mesh (0.117 mm) or less. 제1항에 있어서, 상기 목질계 보드가 MDF(Medium Density Fiberboard), HDF(High Density Fiberboard) 또는 PB(Particle Board)인 것을 특징으로 하는 목질계 보드.The wood board according to claim 1, wherein the wood board is a medium density fiberboard (MDF), a high density fiberboard (HDF), or a particle board (PB). 제1항 내지 제3항 중 어느 한 항의 목질계 보드를 이용하여 제작한 목질 판상제품.A wood plate product produced using the wood board according to any one of claims 1 to 3. 제4항에 있어서, 상기 목질 판상제품이 온돌마루, 강화마루 또는 벽체인 것을 특징으로 하는 목질 판상제품.5. The wood board product according to claim 4, wherein the wood board product is an ondol floor, a reinforced floor or a wall.
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KR20010078131A (en) * 2000-02-02 2001-08-20 추후제출 Functional composition, functional resin composition, and functional molding
KR20030086146A (en) * 2002-05-03 2003-11-07 대한민국(서울대학교 총장) Agricultural waste-wood particle composite board
KR20050049136A (en) * 2003-11-21 2005-05-25 한우석 Manufacturing method for building panel of yellow earth

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010078131A (en) * 2000-02-02 2001-08-20 추후제출 Functional composition, functional resin composition, and functional molding
KR20030086146A (en) * 2002-05-03 2003-11-07 대한민국(서울대학교 총장) Agricultural waste-wood particle composite board
KR20050049136A (en) * 2003-11-21 2005-05-25 한우석 Manufacturing method for building panel of yellow earth

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