KR100704646B1 - Block and the manufacturing of the same - Google Patents

Block and the manufacturing of the same Download PDF

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Publication number
KR100704646B1
KR100704646B1 KR20050123947A KR20050123947A KR100704646B1 KR 100704646 B1 KR100704646 B1 KR 100704646B1 KR 20050123947 A KR20050123947 A KR 20050123947A KR 20050123947 A KR20050123947 A KR 20050123947A KR 100704646 B1 KR100704646 B1 KR 100704646B1
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soil
block
masato
unbaked
hours
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KR20050123947A
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Korean (ko)
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서곤성
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(주) 서호건업
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/001Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/12Waste materials; Refuse from quarries, mining or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/08Producing shaped prefabricated articles from the material by vibrating or jolting
    • B28B1/087Producing shaped prefabricated articles from the material by vibrating or jolting by means acting on the mould ; Fixation thereof to the mould
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/36Inorganic materials not provided for in groups C04B14/022 and C04B14/04 - C04B14/34
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/10Compositions or ingredients thereof characterised by the absence or the very low content of a specific material
    • C04B2111/1037Cement free compositions, e.g. hydraulically hardening mixtures based on waste materials, not containing cement as such
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mining & Mineral Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Processing Of Solid Wastes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

본 발명에 따른 굽지 않은 흙 보도블록의 제조방법은, 중량%로 마사토30~40%, 채석폐토40~50%, 소석회5~10%, 고화재10~20%와 물을 혼합한 후 진동 가압 성형 방식에 의해 성형하고, 이후 1시간 내지 3 시간의 자연 양생을 한 다음 8 시간 내지 12시간 동안 60℃ 내지 100℃ 증기 양생하여 제조하므로, 종래의 1200℃이상의 고열에 의한 소성과정을 거치지 않고서도 고강도의 흙 보도 블록을 제조할 수 있어 소성시 필요한 에너지 절감뿐만 아니라 온난화의 원인이 되는 CO2를 방출하지 않는 이점이 있고, 본 발명에 따른 굽지 않은 흙 보도블록은, 마사토30~40%, 채석폐토40~50%, 소석회5~10%, 고화재10~20%의 중량%에 물을 혼합하여 성형되므로, 시멘트를 사용하지 않으면서도 충분한 강도를 갖고, 산보시 피로감이 감소되며, 친환경적이며 리사이클이 가능한 이점이 있다.Method for producing unbaked soil walkway block according to the present invention, by mixing the weight of Masato 30-40%, quarrying soil 40-50%, calcined lime 5-10%, solidified fire 10-20% and water and vibration Molded by the molding method, after the natural curing of 1 hour to 3 hours and then produced by steam curing 60 ℃ to 100 ℃ for 8 hours to 12 hours, without undergoing a conventional firing process by high heat of 1200 ℃ or more The high-strength soil walkway block can be produced, which has the advantage of not only saving energy required during firing, but also emitting CO 2 which causes warming, and the unbaked soil walkway block according to the present invention is Masato 30-40%, quarrying. It is formed by mixing water with 40 to 50% of waste soil, 5 to 10% of slaked lime, and 10 to 20% of solidified fire. This has a possible advantage.

보도 블록, 마사토, 채석폐토, 소석회, 고화재, 증기 양생 Sidewalk block, Masato, quarry waste, slaked lime, solid fire, steam curing

Description

굽지 않는 흙 보도 블록 및 그 제조 방법{Block and the manufacturing of the same}Unbaked soil walkway block and its manufacturing method {Block and the manufacturing of the same}

도 1은 본 발명에 따른 굽지 않은 흙 보도 블럭 일실시예의 도, 1 is a view of one embodiment of an unbaked soil walkway block in accordance with the present invention;

도 2는 본 발명에 따른 굽지 않은 흙 보도 블록 제조 방법 제 1 실시예가 도시된 순서도,2 is a flow chart illustrating a first embodiment of a method for producing unbended soil footpath block according to the present invention;

도 3은 본 발명에 따른 굽지 않은 흙 보도 블록 제조 방법 제 2 실시예가 도시된 순서도,3 is a flow chart showing a second embodiment of a method for producing unbended soil footpath block according to the present invention;

도 4는 본 발명에 따른 굽지 않은 흙 보도 블록 제조 방법 제 3 실시예가 도시된 순서도이다.Figure 4 is a flow chart illustrating a third embodiment of a method for producing unbended soil walkway block according to the present invention.

<도면의 주요 부분에 관한 부호의 설명><Explanation of symbols on main parts of the drawings>

본 발명은 굽지 않는 흙 보도블럭 및 그 제조방법에 관한 것으로서, 특히 소성 과정이나 시멘트의 첨가없이 제조되어 친환경적인 굽지 않는 흙 보도블럭 및 그 제조방법에 관한 것이다.The present invention relates to an unbaked soil sidewalk block and a method of manufacturing the same, and more particularly, to an environment-friendly unbaked soil sidewalk block and a method of manufacturing the same, which are manufactured without a firing process or addition of cement.

종래의 흙 보도블럭은 1200℃이상의 고열에 의한 소성과정으로 점토입자간의 고상반응을 촉진하여 강도를 발현한다.Conventional soil foot block is to express the strength by promoting the solid phase reaction between clay particles in the firing process by high heat of 1200 ℃ or more.

그러나, 종래의 흙 보도블록은 그 소성과정에서 연료의 연소시 유해물질이 대기중에 방출되어 환경오염 및 에너지 소비를 유발하는 문제점이 있다. However, the conventional soil walkway block has a problem in that harmful substances are released into the atmosphere during combustion of fuel in the firing process, causing environmental pollution and energy consumption.

한편, 등록특허공보 10-0495026에는 점토 50~90중량%, 석탄회5~40중량%, 고로슬래그 5~40중량%로 이루어진 혼합물100중량부에 대하여, 나트륨,칼륨 또는 리튬의 수산화물, 황산염 또는 탄산염 중 선택된 일종과 액상 규소화합물의 혼합물로서, 그 혼합비는 중량비로 1:1 내지 3:1 범위인 경화촉진제 15%중량부를 첨가하여 성형 건조시킨 굽지않은 고강도 점토벽돌 및 그 제조방법이 개시되어 있으나, 상기 굽지않은 고강도 점토 벽돌은 건물 등을 짓는데 사용되고, 지면에 놓이는 흙 보도 블록과는 원재료 성분이 달라 압축 강도나 휨 강도가 충분치 못하므로, 그 적용이 곤란한 문제점이 있다.Meanwhile, Korean Patent Publication No. 10-0495026 discloses a hydroxide, sulfate or carbonate of sodium, potassium or lithium, based on 100 parts by weight of a mixture consisting of 50 to 90% by weight of clay, 5 to 40% by weight of coal ash, and 5 to 40% by weight of blast furnace slag. As a mixture of a selected one and a liquid silicon compound, the mixing ratio of the uncured high-strength clay brick is molded and dried by adding 15% by weight of a curing accelerator having a mixing ratio of 1: 1 to 3: 1 by weight, The high-strength clay brick is used to build a building, etc., since the raw material composition is different from the soil walkway block placed on the ground, the compressive strength and the bending strength is not sufficient, there is a problem that its application is difficult.

본 발명은 상기한 종래 기술의 문제점을 해결하기 위하여 안출된 것으로서, 고온의 소성과정을 거치지 않고 생산하므로 저렴한 제조원가와 환경을 보호하는 굽지 않는 흙 보도블럭의 제조 방법을 제공하는데 그 목적이 있다.The present invention has been made in order to solve the above problems of the prior art, it is an object of the present invention to provide a method for producing a non-bending soil footpath block to protect the production cost and environmental protection because it is produced without a high temperature firing process.

본 발명의 다른 목적은 강도를 발현시키기 위해 시멘트를 첨가하지 않은 친환경적인 굽지 않은 흙 보도블럭을 제공하는데 있다.Another object of the present invention is to provide an environmentally friendly unbaked soil footpath block without adding cement to develop strength.

상기한 과제를 해결하기 위한 본 발명에 따른 굽지 않은 흙 보도 블록의 제조 방법은 마사토, 채석폐토, 소석회, 고화재를, 마사토 30~40%, 채석폐토40~50%, 소석회5~10%, 고화재10~20%의 중량%로 믹서기에서 혼합하고 물을 첨가하여 혼합하는 제 1 단계와; 상기 제 1 단계에서 혼합된 혼합물을 진동가압 성형기에 넣어 진동, 가압하여 흙 보도 블록으로 성형하는 제 2 단계와; 상기 제 2 단계에서 성형된 흙 보도 블록을 자연 양생하는 제 3 단계와; 상기 제 3 단계 이후에 상기 제 3 단계에서 자연 양생된 흙 보도 블록을 8 시간 내지 12시간 동안 60℃ 내지 100℃로 증기 양생하는 제 4 단계를 포함하여 구성된 것을 특징으로 한다.Method for producing unbended soil walkway block according to the present invention for solving the above problems is Masato, quarry waste, slaked lime, solid fire, Masato 30-40%, quarry waste 40-50%, slaked lime 5-10%, A first step of mixing in a blender at a weight percentage of 10 to 20% solids and adding water to mix; A second step of putting the mixture mixed in the first step into a vibrating pressure molding machine to vibrate and press to form the soil footpath block; A third step of naturally curing the soil walkway block formed in the second step; After the third step is characterized in that it comprises a fourth step of steam curing the natural cured soil walkway block in the third step at 60 ℃ to 100 ℃ for 8 to 12 hours.

또한, 상기 제 3 단계는, 1시간 내지 3 시간 동안 실시되는 것을 특징으로 한다.In addition, the third step, characterized in that carried out for 1 hour to 3 hours.

또한, 상기 제 4 단계 이후에 10 내지 14 시간 동안 자연 양생하는 제 5 단계를 더 포함하여 구성된 것을 특징으로 한다.The method may further include a fifth step of natural curing for 10 to 14 hours after the fourth step.

또한, 상기 제 5 단계 이후에 흙 보도 블록을 적제하여 8 내지 12일간 자연 양생하는 제 6 단계를 더 포함하여 구성된 것을 특징으로 한다.The method may further include a sixth step of naturally curing the soil walkway block after the fifth step to naturally cure for 8 to 12 days.

본 발명에 따른 굽지 않은 흙 보도 블록은 상기 제조 방법에 의해 제조된 것을 특징으로 한다. The unbaked soil walkway block according to the invention is characterized in that it is produced by the above production method.

상기 굽지 않은 흙 보도블럭은 가로 250mm, 세로 125mm, 높이 60~80mm 인 것을 특징으로 한다.The unbaked soil footpath block is characterized in that the width 250mm, length 125mm, height 60 ~ 80mm.

이하, 본 발명의 실시 예를 첨부된 도면을 참조하여 상세히 설명한다.Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 발명에 따른 굽지 않은 흙 보도 블럭 일실시예의 도이다.    1 is a diagram of an embodiment of an unbended soil walkway block in accordance with the present invention.

본 실시예에 따른 굽지 않은 흙 보도 블록은, 도 1에 도시된 바와 같이, 전체적으로 육면체 형상이나 마름모 형상으로 형성되고, 시멘트를 사용하지 않으며, 마사토, 채석폐토, 소석회, 고화재를, 마사토 30~40%, 채석폐토40~50%, 소석회5~10%, 고화재10~20%의 중량%로 혼합하고 물을 첨가하여 제조된다.As shown in FIG. 1, the uncurved soil walkway block is formed in a hexahedron shape or a rhombus shape as a whole, and does not use cement, and uses masato, quarry waste, slaked lime, and solid fire. It is prepared by mixing 40%, quarry waste 40-50%, calcined lime 5-10%, solids 10-20% by weight and adding water.

상기 소석회는 마사토 및 채석폐토와 반응하여 중화시킴과 아울러 혼합물을 굳게 한다. The slaked lime reacts with masato and quarry waste and neutralizes the mixture.

그리고, 상기 고화재는 상기 마사토, 채석폐토를 굳게 하는 것으로 시멘트계 고화재를 사용하지 않고, 제철발생 슬러지 및 더스트중 철성분의 함량이 낮은 것들이 이용됨이 바람직하다.In addition, the solidified material is to harden the masato, quarry waste, and do not use cement-based solidified materials, and those having low iron content in steel-making sludge and dust are preferably used.

그리고, 상기 물은 상기 마사토, 채석폐토, 소석회, 고화재가 혼합된 혼합물의 대략 20~40%의 중량%이 믹서기로 투입된다. In addition, the water is added to the blender of about 20 to 40% by weight of the mixture of the masato, quarry waste, slaked lime, solidified material.

상기 굽지 않는 흙 보도블럭은 가로 250mm, 세로 125mm, 높이 60~80mm 로 이루어진다.The non-baking soil sidewalk block is made of a width of 250mm, length 125mm, height 60 ~ 80mm.

도 2는 본 발명에 따른 굽지 않은 흙 보도 블록 제조 방법 제 1 실시예가 도시된 순서도이다.Figure 2 is a flow chart showing a first embodiment of a method for producing unbaked soil walkway block according to the present invention.

본 실시예에 따른 굽지 않은 흙 보도 블록 제조 방법은 도 2에 도시된 바와 같이, 마사토30%, 채석폐토48%, 소석회5%, 고화재17%의 중량%로 믹서기에서 균일하게 혼합하고, 물을 첨가하여 혼합한다.(S1)As shown in FIG. 2, the method for producing unbended soil walkway block is uniformly mixed in a blender at a weight percent of Masato 30%, Quarry Waste 48%, Slaked Lime 5%, and Solidified Fire 17%, and water. Add and mix. (S1)

이후, 혼합물을 진동 가압 성형기에 넣어 진동 5~6초, 압축 3~5초로 가압하여 흙 보도 블록으로 성형한다.(S2)Thereafter, the mixture is put into a vibration press molding machine and pressurized by vibration 5 to 6 seconds and compression 3 to 5 seconds to form a soil footpath block. (S2)

그런 다음, 진동 가압 성형기에서 성형된 흙 보도 블록을 꺼내 2시간동안 자연 양생한다.(S3)Then, take out the molded soil footpath block from the vibrating pressure molding machine and natural curing for 2 hours. (S3)

상기 자연 양생 이후에 흙 보도 블록을 스팀이 분출되는 양생실로 넣어 10시간 동안 양생온도 60~100℃로 증기 양생한다.(S4)After the natural curing put the soil sidewalk block into the curing chamber where the steam is ejected steam curing at the curing temperature 60 ~ 100 ℃ for 10 hours. (S4)

상기와 같은 증기 양생시, 흙 보도 블록은 강도가 증대되어 굳게 된다. In the above steam curing, the soil walkway block is increased in strength and hardened.

상기 증기 양생 이후에 양생실에서 흙 보도 블록을 꺼낸 후 최종적으로 12시간 동안 자연 양생 시킨다.(S5)After the steam curing, take out the soil sidewalk block in the curing room and finally natural curing for 12 hours. (S5)

상기와 같은 자연 양생시 흙 보도 블록은 강도가 점진적으로 증대되면서 보다 견고하게 굳게 된다.In the natural curing as described above, the soil walkway block is more firmly solidified as the strength is gradually increased.

마지막으로, 상기 12 시간 자연 양생된 흙 보도 블록을 적제하여 10일간 자연 양생 한다.(S6)Finally, the natural cured soil footpath block was cured for 12 hours to naturally cure for 10 days. (S6)

그런 다음, 상기 10일간 자연 양생된 흙 보도 블록은, 상기 증기 양생에서 강도가 충분하게 확보된 상태에서, 상기 12 시간 동안의 자연 양생에서 보다 견고하게 굳게 되므로, 20일 정도 자연 양생할 필요 없이 10일간만 자연 양생하면 제품으로 출시가 가능한 강도를 갖게 된다.Then, the 10-day natural cured soil walkway block is hardened more firmly in the natural curing for 12 hours while the strength is sufficiently secured in the steam curing, so that no natural curing is required for about 20 days. If you cure naturally only for a day, it will have the strength to be released as a product.

도 3은 본 발명에 따른 굽지 않은 흙 보도 블록 제조 방법 제 2 실시예가 도시된 순서도이다.Figure 3 is a flow chart illustrating a second embodiment of a method for producing unbended soil walkway block according to the present invention.

본 실시예에 따른 굽지 않은 흙 보도 블록 제조 방법은 도 3에 도시된 바와 같이, 마사토30%, 채석폐토50%, 소석회5%, 고화재15%의 중량%로 믹서기에서 균일하게 혼합하고 물을 첨가하여 재혼합한다.(S1′)As shown in Fig. 3, the method for producing unbended soil footpath block is uniformly mixed in a blender at 30% by weight of Masato 30%, quarry waste soil 50%, calcined lime 5%, and solidified fire 15% and water. Add and remix (S1 ')

이후, 혼합물을 실시예1과 같은 진동 가압 성형기에 넣어 진동 5~6초, 압축 3~5초로 가압하여 흙 보도 블록으로 성형한다.(S2)Thereafter, the mixture is put into a vibrating pressure molding machine as in Example 1, pressurized by vibration for 5 to 6 seconds and compressed for 3 to 5 seconds to form a soil footpath block.

그리고, 상기 성형된 흙 보도블럭은 실시예1과 같은 양생과정을 통해 양생된다.(S3)(S4)(S5)(S6)Then, the molded soil footpath block is cured through the same curing process as in Example 1. (S3) (S4) (S5) (S6)

도 4는 본 발명에 따른 굽지 않은 흙 보도 블록 제조 방법 제 3 실시예가 도시된 순서도이다.Figure 4 is a flow chart illustrating a third embodiment of a method for producing unbended soil walkway block according to the present invention.

본 실시예에 따른 굽지 않은 흙 보도 블록 제조 방법는 도 4에 도시된 바와 같이, 마사토40%, 채석폐토40%, 소석회5%, 고화재15%의 중량%로 믹서기에서 균일하게 혼합하고 물을 첨가하여 재혼합한다.(S1″)As shown in Fig. 4, the method for producing unbended soil walkway block is uniformly mixed in a blender at 40% by weight of Masato 40%, quarry waste soil 40%, calcined lime 5%, and solidified fire 15%, and water is added thereto. To mix again (S1 ″).

이후, 혼합물을 실시예1과 같이 진동 가압성형기에 넣어 진동 5~6초, 압축3~5초로 가압 성형한다.(S2)Thereafter, the mixture is put in a vibration press molding machine as in Example 1 and press-molded with a vibration of 5 to 6 seconds and a compression of 3 to 5 seconds.

그리고, 상기 성형된 흙 보도블럭은 실시예1과 같은 양생과정을 통해 양생된다.(S3)(S4)(S5)(S6)Then, the molded soil footpath block is cured through the same curing process as in Example 1. (S3) (S4) (S5) (S6)

상기 실시예 1,2,3에 따라 제조된 흙 보도 블록의 압축강도와, 힘 강도와 흡수율은 표1에 도시된다.Compressive strength, force strength and water absorption of the soil walkway blocks prepared according to Examples 1, 2 and 3 are shown in Table 1.

<표1><Table 1>

구 분division 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 비교예 2Comparative Example 2 압축강도(kgf/㎠)Compressive strength (kgf / ㎠) 223223 205205 187187 172172 162162 휨 강도(N/㎟)Flexural strength (N / mm2) 6.26.2 5.75.7 5.25.2 4.84.8 4.54.5 흡수율(%)Absorption rate (%) 6.56.5 7.27.2 7.57.5 8.18.1 8.58.5

상기 비교예 1은 마사토35%, 채석폐토50%, 고화재15%의 중량%로 믹서기에서 균일하게 혼합하고 혼합물에 물을 첨가하여 혼합한 다음 진동 가압성형기로 진동 5~6초, 압축 3~5초로 가압 성형하며, 성형된 흙 보도블럭은 실시예1과 같은 양생과정을 거친 흙 보도 블록의 실험치이다.    Comparative Example 1 is uniformly mixed in a blender at 35% of Masato 35%, quarry waste 50%, solids 15% by weight, mixed by adding water to the mixture, and then mixed with a vibration press molding machine for 5 to 6 seconds, compression 3 to Pressurized by 5 seconds, the molded soil footpath block is an experimental value of the soil footpath block undergoing the same curing process as Example 1.

상기 비교예 2는 마사토30%, 채석폐토50%, 석회석 5%, 고화재15%의 중량%로 믹서기에서 균일하게 혼합하고 혼합물에 물을 첨가하여 혼합한 다음 진동 가압성형기로 진동 5~6초, 압축 3~5초 가압 성형하며, 성형된 흙 보도블럭을 3시간 동안 자연 양생하고, 1시간 동안 양생온도 60~80℃ 증기 양생한 뒤 20시간 동안 실온 양생한 흙 보도 블록의 실험치이다.Comparative Example 2 is uniformly mixed in a blender at 30% of Masato 30%, quarry waste 50%, limestone 5%, solids 15% by weight in a blender and mixed by adding water to the mixture and then vibrating with a vibration press molding machine for 5-6 seconds Compressed 3 to 5 seconds of compression, and the cured soil footpath block natural cured for 3 hours, the curing temperature of 60 ~ 80 ℃ steam curing for 1 hour, the room temperature cured for 20 hours, the experimental value of the soil sidewalk block.

상기 <표1>에 도시된 바와 같이, 소석회를 첨가한 실시예 1,2,3은 소석회를 첨가하지 않은 비교예 1보다 압축 강도 및 휨 강도가 높고 흡수율이 낮게 된다.As shown in Table 1, Examples 1, 2, and 3 added with slaked lime had higher compressive strength and flexural strength and lower water absorption than Comparative Example 1 without added slaked lime.

특히, 상기 실시예 1,2,3 들 중에서 고화재가 가장 많이 포함된 실시예 1이 압축 강도 및 휨 강도가 가장 높고 흡수율이 가장 낮으며, 상기 실시예 1,2,3 들 중에서 마사토가 가장 많이 포함된 실시예 3이 압축 강도 및 휨 강도가 가장 낮고 흡수율이 가장 높게 된다.In particular, Example 1, which contains the most solids among Examples 1, 2, and 3, has the highest compressive strength and the flexural strength and the lowest absorption rate, and Masato is the best among the Examples 1, 2, and 3 Example 3, which contains much, has the lowest compressive strength and the flexural strength and the highest absorption rate.

한편, 상기 <표1>에 도시된 바와 같이, 10시간 동안 양생온도 60~100℃로 증기 양생한 실시예 1,2,3은 1시간 동안 양생온도 60~80℃ 증기 양생한 비교예 2 보다 압축 강도 및 휨 강도가 높고 흡수율이 낮게 된다.On the other hand, as shown in Table 1, Examples 1, 2 and 3 steam cured at a curing temperature of 60 to 100 ° C. for 10 hours were compared to Comparative Example 2, which cured steam at a curing temperature of 60 to 80 ° C. for 1 hour. High compressive and flexural strength and low water absorption.

상기와 같이 구성되는 본 발명에 따른 굽지 않은 흙 보도블록의 제조방법은, 중량%로 마사토30~40%, 채석폐토40~50%, 소석회5~10%, 고화재10~20%와 물을 혼합한 후 진동 가압 성형 방식에 의해 성형하고, 이후 1시간 내지 3 시간의 자연 양생을 한 다음 8 시간 내지 12시간 동안 60℃ 내지 100℃ 증기 양생하여 제조하므로, 환경 친화적이고, 종래의 1200℃이상의 고열에 의한 소성과정을 거치지 않고서도 고강도의 흙 보도 블록을 제조할 수 있어 소성시 필요한 에너지 절감뿐만 아니라 온난화의 원인이 되는 CO2를 방출하지 않는 이점이 있다.The method of manufacturing the unbaked soil walkway block according to the present invention configured as described above, by weight percent Masato 30-40%, quarry waste soil 40-50%, slaked lime 5-10%, solid fire 10-20% and water After mixing by molding by vibrating pressure molding method, after the natural curing of 1 hour to 3 hours and then produced by steam curing 60 ℃ to 100 ℃ for 8 hours to 12 hours, environmentally friendly, the conventional 1200 ℃ or more The high-strength soil walkway block can be manufactured without undergoing a high-temperature firing process, which not only reduces energy required for firing, but also does not emit CO 2 which causes warming.

본 발명에 따른 굽지 않은 흙 보도블록은 마사토30~40%, 채석폐토20~30%, 소석회5~10%, 고화재10~20%의 중량%에 물을 혼합하여 성형되므로, 시멘트를 사용하지 않으고 충분한 강도를 갖고, 산보시 피로감이 감소되며, 친환경적이며 리사이클이 가능한 이점이 있다.The unbaked soil walkway block according to the present invention is formed by mixing water in the weight percent of Masato 30-40%, quarry waste 20-30%, calcined lime 5-10%, and solid fire 10-20%, and therefore do not use cement. It has the advantage of having sufficient strength, reducing fatigue during walking, and being environmentally friendly and recyclable.

Claims (5)

마사토, 채석폐토, 소석회, 고화재를, 마사토 30~40%, 채석폐토40~50%, 소석회5~10%, 고화재10~20%의 중량%로 믹서기에서 혼합하고 물을 첨가하여 혼합하는 제 1 단계와;Mixing Masato, Quarry Waste, Slaked Lime and Solid Fire, in a blender with Masato 30-40%, Quarry Waste 40-50%, Slaked Lime 5-10%, Solids 10-20% by weight and adding water A first step; 상기 제 1 단계에서 혼합된 혼합물을 진동가압 성형기에 넣어 진동, 가압하여 흙 보도 블록으로 성형하는 제 2 단계와;A second step of putting the mixture mixed in the first step into a vibrating pressure molding machine to vibrate and press to form the soil footpath block; 상기 제 2 단계에서 성형된 흙 보도 블록을 자연 양생하는 제 3 단계와;A third step of naturally curing the soil walkway block formed in the second step; 상기 제 3 단계 이후에 상기 제 3 단계에서 자연 양생된 흙 보도 블록을 8 시간 내지 12시간 동안 60℃ 내지 100℃로 증기 양생하는 제 4 단계를 포함하여 구성된 것을 특징으로 하는 굽지 않은 흙 보도 블록의 제조 방법.And a fourth step of steam curing the naturally cured soil walkway block after the third step at 60 ° C. to 100 ° C. for 8 to 12 hours. Manufacturing method. 청구항 1에 있어서,The method according to claim 1, 상기 제 3 단계는, 1시간 내지 3 시간 동안 실시되는 것을 특징으로 하는 굽지 않은 흙 보도 블록의 제조 방법.The third step is a method for producing unbaked soil walkway block, characterized in that carried out for 1 to 3 hours. 청구항 1에 있어서,The method according to claim 1, 상기 굽지 않은 흙 보도 블록의 제조 방법은, 상기 제 4 단계 이후에 10 내지 14 시간 동안 자연 양생하는 제 5 단계와;The method for producing the unbaked soil walkway block may include a fifth step of natural curing for 10 to 14 hours after the fourth step; 상기 제 5 단계 이후에 흙 보도 블록을 적제하여 8 내지 12일간 자연 양생하 는 제 6 단계를 더 포함하여 구성된 것을 특징으로 하는 굽지 않은 흙 보도 블록의 제조 방법.And a sixth step of naturally curing the soil walkway block after the fifth step to naturally cure for 8 to 12 days. 마사토 30-40 중량%, 채석폐토 40-50 중량%, 소석회 5-10 중량%, 고화재 10-20 중량%로 이루어진 것을 특징으로 하는 굽지 않은 흙 보도블럭.An unbaked soil sidewalk block, which comprises 30-40% by weight of Masato, 40-50% by weight of quarry, 5-10% by weight of lime, and 10-20% by weight of solid fire. 청구항 4에 있어서,The method according to claim 4, 상기 굽지 않은 흙 보도블럭은 가로 250mm, 세로 125mm, 높이 60~80mm 인 것을 특징으로 하는 굽지 않은 흙 보도블럭.The unbaked soil sidewalk block is a 250 mm, 125 mm long, 60 ~ 80 mm height of the unbaked soil sidewalk block.
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