KR100693521B1 - Ultrahigh voltage electrolyte of aluminium electrolytic condenser - Google Patents
Ultrahigh voltage electrolyte of aluminium electrolytic condenser Download PDFInfo
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- KR100693521B1 KR100693521B1 KR1020040020311A KR20040020311A KR100693521B1 KR 100693521 B1 KR100693521 B1 KR 100693521B1 KR 1020040020311 A KR1020040020311 A KR 1020040020311A KR 20040020311 A KR20040020311 A KR 20040020311A KR 100693521 B1 KR100693521 B1 KR 100693521B1
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- ammonium
- weight
- electrolyte
- ethylene glycol
- high pressure
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- 239000003792 electrolyte Substances 0.000 title claims abstract description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 11
- 239000004411 aluminium Substances 0.000 title 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 45
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002253 acid Substances 0.000 claims abstract description 13
- 239000003990 capacitor Substances 0.000 claims abstract description 13
- 235000019445 benzyl alcohol Nutrition 0.000 claims abstract description 8
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000008119 colloidal silica Substances 0.000 claims abstract description 7
- 239000000539 dimer Substances 0.000 claims abstract description 7
- WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 claims abstract description 7
- 239000004254 Ammonium phosphate Substances 0.000 claims abstract description 6
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims abstract description 6
- 235000019289 ammonium phosphates Nutrition 0.000 claims abstract description 6
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 6
- FOFMIZPXOAUNDQ-UHFFFAOYSA-N azane;2-methylnonanedioic acid Chemical compound N.N.OC(=O)C(C)CCCCCCC(O)=O FOFMIZPXOAUNDQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims abstract description 5
- JKTYGPATCNUWKN-UHFFFAOYSA-N 4-nitrobenzyl alcohol Chemical compound OCC1=CC=C([N+]([O-])=O)C=C1 JKTYGPATCNUWKN-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- YSFZWUJOBANROZ-UHFFFAOYSA-N heptylmalonic acid Chemical compound CCCCCCCC(C(O)=O)C(O)=O YSFZWUJOBANROZ-UHFFFAOYSA-N 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- -1 monobutyl phosphate ester Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/035—Liquid electrolytes, e.g. impregnating materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
- H01G9/042—Electrodes or formation of dielectric layers thereon characterised by the material
- H01G9/045—Electrodes or formation of dielectric layers thereon characterised by the material based on aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/145—Liquid electrolytic capacitors
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
본 발명은 알루미늄 전해콘덴서 초고압용 전해액에 관한 것이다.The present invention relates to an aluminum electrolytic capacitor ultra high pressure electrolyte.
본 발명은 알루미늄 전해콘덴서 초고압용 전해액에 있어서, 용매인 에틸렌글리콜36~65중량%에 암모늄1.7옥탄디카르복실레이트12~15중량%를 첨가하고 콜로이달실리카에틸렌글리콜용액3~10중량%을 첨가하며 파라니트로벤질알콜0.1~3중량%, 다이머산5.7~10중량%, 벤질알콜12~16중량%, 붕산암모늄2~4중량%, 인산암모늄0.1~3중량%, 모노부틸암모늄0.1~3중량%을 혼합하여 구성되는 것을 특징으로 한다.In the present invention, an aluminum electrolytic capacitor ultra high pressure electrolytic solution is added with 12-15 wt% of ammonium 1.7 octane dicarboxylate to 36-65 wt% of ethylene glycol as a solvent, and 3-10 wt% of colloidal silica ethylene glycol solution. Paranitrobenzyl alcohol 0.1-3 wt%, dimer acid 5.7-10 wt%, benzyl alcohol 12-16 wt%, ammonium borate 2-4 wt%, ammonium phosphate 0.1-3 wt%, monobutyl ammonium 0.1-3 wt% It is characterized by comprising a mixture of%.
본 발명은 충분한 내전압을 가지면서 전해액의 전도도가 향상되어 하이리플(HIGH RIPPLE)용 소형화 제품에 적용가능하며 고온에서 특성이 안정하고 사용온도 범위가 확대됨은 물론 장시간 사용 가능한 장점이 있다.The present invention has a sufficient withstand voltage, and the conductivity of the electrolyte is improved, so that it can be applied to a miniaturized product for HIGH RIPPLE.
Description
본 발명은 알루미늄 전해콘덴서 고압용 전해액에 관한 것이다.The present invention relates to an aluminum electrolytic capacitor high pressure electrolyte.
본 발명은 충분한 내전압을 가지면서 전해액의 전도도가 향상되어 하이리플(HIGH RIPPLE)용 소형화 제품에 적용가능하며 고온에서 특성이 안정하고 사용온도 범위가 확대됨은 물론 장시간 사용 가능하도록 한 것이다.The present invention is to improve the conductivity of the electrolyte while having a sufficient withstand voltage, and can be applied to miniaturized products for HIGH RIPPLE, it is stable at high temperatures, extended use temperature range, as well as long-term use.
알루미늄 전해콘덴서 중고압용 전해액은 일반적으로 에틸렌글리콜을 주체로한 용매에 붕산계 전해질을 용해시켜 사용하거나 에틸렌글리콜을 주체로한 용매에 아제라인산, 세바틴산 등과 같은 이염기성의 유기산 또는 상기산의 암모늄염을 용해시켜 사용하였다.A high pressure electrolytic solution for aluminum electrolytic capacitors is generally used by dissolving a boric acid-based electrolyte in a solvent mainly composed of ethylene glycol or a dibasic organic acid such as azeline acid, sebacic acid, or an ammonium salt of the acid in a solvent mainly composed of ethylene glycol. It was used by dissolving.
상기 붕산계 전해액은 에스테르화 반응에 의해 다량의 수분이 생성되고 전극박의 열화를 촉진 TANδ 등 특성의 악화와 100℃ 이상의 전해콘덴서에는 수분이 증발되어 콘덴서의 내압을 상승시켜 케이스 방폭변이 작동되어 파양이 되는 결점이 있다.The boric acid-based electrolyte generates a large amount of water by the esterification reaction, promotes deterioration of the electrode foil, deteriorates characteristics such as TANδ, and evaporates moisture to the electrolytic capacitor at 100 ° C. or higher, thereby increasing the internal pressure of the condenser to operate the case. There is a drawback to this.
또한 이염기성산 등의 전해액은 필요한 내전압이 충분치 않고 전해액의 전도 도가 좋지 않아 저손실, LOW ESR용 전해액으로 사용이 어렵고 또한 사용온도범위가 작은 결점이 있다.In addition, electrolytes such as dibasic acids have the disadvantages that the required withstand voltage is not sufficient and the conductivity of the electrolyte is poor, making it difficult to use as a low loss, low ESR electrolyte, and having a small operating temperature range.
이와같은 문제점을 해결하기 위해 디에틸렌글리콜과 같은 다강라콜을 혼합용매로 사용하기도 하나 내전압은 다소 향상이 되나 500WV급 이상의 콘덴서에 적용하기에는 내전압이 충분하지 못하는 결점이 있다.In order to solve this problem, multi-galacol such as diethylene glycol may be used as a mixed solvent, but the breakdown voltage may be slightly improved, but the breakdown voltage may not be sufficient to be applied to a capacitor of 500 WV or more.
본 발명은 충분한 내전압을 가지면서 전해액의 전도도가 향상되어 하이리플(HIGH RIPPLE)용 소형화 제품에 적용가능하며 고온에서 특성이 안정하고 사용온도 범위가 확대됨은 물론 장시간 사용 가능한 알루미늄 전해콘덴서 초고압용 전해액을 제공하는데 목적을 두고 있다.The present invention has a sufficient withstand voltage and improves the conductivity of the electrolyte, so that it can be applied to miniaturized products for high ripple, stable at high temperatures, extended use temperature range, as well as ultra-high pressure electrolyte for aluminum electrolytic capacitors that can be used for a long time. The purpose is to provide.
이를 위해 본 발명은 알루미늄 전해콘덴서 초고압용 전해액에 있어서, 용매인 에틸렌글리콜36~65중량%에 암모늄1.7옥탄디카르복실레이트12~15중량%를 첨가하고 콜로이달실리카에틸렌글리콜용액3~10중량%을 첨가하며 파라니트로벤질알콜0.1~3중량%, 다이머산5.7~10중량%, 벤질알콜12~16중량%, 붕산암모늄2~4중량%, 인산암모늄0.1~3중량%, 모노부틸암모늄0.1~3중량%을 혼합하여 구성되는 것을 특징으로 하는 알루미늄 전해콘덴서 초고압용 전해액을 제공하고자 한다. To this end, the present invention, in the aluminum electrolytic capacitor ultra-high pressure electrolyte, 12 to 15% by weight of ammonium 1.7 octane dicarboxylate is added to 36 to 65% by weight of ethylene glycol as a solvent and 3 to 10% by weight of colloidal silica ethylene glycol solution Paranitrobenzyl alcohol 0.1-3 wt%, dimer acid 5.7-10 wt%, benzyl alcohol 12-16 wt%, ammonium borate 2-4 wt%, ammonium phosphate 0.1-3 wt%, monobutylammonium 0.1- To provide an aluminum electrolytic capacitor ultra-high pressure electrolytic solution, characterized in that by mixing 3% by weight.
본 발명은 알루미늄 전해콘덴서 초고압용 전해액에 있어서, 용매인 에틸렌글리콜36~65중량%에 암모늄1.7옥탄디카르복실레이트12~15중량%를 첨가하고 콜로이달실리카에틸렌글리콜용액3~10중량%을 첨가하며 파라니트로벤질알콜0.1~3중량%, 다이머산5.7~10중량%, 벤질알콜12~16중량%, 붕산암모늄2~4중량%, 인산암모늄0.1~3중량%, 모노부틸암모늄0.1~3중량%을 혼합하여 구성되는 것을 특징으로 한다.In the present invention, an aluminum electrolytic capacitor ultra high pressure electrolytic solution is added with 12-15 wt% of ammonium 1.7 octane dicarboxylate to 36-65 wt% of ethylene glycol as a solvent, and 3-10 wt% of colloidal silica ethylene glycol solution. Paranitrobenzyl alcohol 0.1-3 wt%, dimer acid 5.7-10 wt%, benzyl alcohol 12-16 wt%, ammonium borate 2-4 wt%, ammonium phosphate 0.1-3 wt%, monobutyl ammonium 0.1-3 wt% It is characterized by comprising a mixture of%.
본 발명은 에틸렌글리콜용매에 LONG CHAIN의 측쇄 이염기성산 또는 그 암모늄염과 직쇄의 이염기성산염을 혼합, 전해질로 사용하여 전해액의 전도도와 열적 안정성을 향상시켰다.The present invention improves the conductivity and thermal stability of the electrolyte solution by mixing a side chain dibasic acid of LONG CHAIN or its ammonium salt with a straight chain dibasic acid salt in an ethylene glycol solvent as an electrolyte.
또한 콜로이달실리카(COLLOIDAI SILLICA)의 에틸렌 글리콜 분산 용액 및 다이머산(dimer acid)과 보조용매로 벤질알콜과 붕산암모늄을 첨가하여 완성한 전해액을 사용한 제품은 초고압용이므로 과전압, 과전류, 인가시 내부short, 발화를 일으키기 쉽기때문에 이를 개선하기 위해 인산암모늄과 모노부틸인산에스테르를 첨가하여 난연성(難練性)을 증대시키고 있다.In addition, the products using colloidal silica (COLLOIDAI SILLICA) ethylene glycol dispersion solution, dimer acid and co-solvent finished by adding benzyl alcohol and ammonium borate are used for ultra high pressure. Since it is easy to cause ignition, ammonium phosphate and monobutyl phosphate ester are added to improve the flame retardancy.
본 발명은 에틸렌글리콜 용매에 LONG CHAIN의 측쇄 이염기성산 또는 그 암모늄염인 암모늄1.7옥탄디카르복실레이트(1.7octandecaboxylate)를 주용질로하여 전해액을 완성하였다.
종래기술과 본 발명에 의한 전해액의 구성 및 콘덴서의 적용 예를(85℃용 500V/6.8㎌ : 30Ψ×40ℓ)와 같은 조건으로 실험하여 [표 1]에서와 같은 결과를 나타내었으며 종래예의 전해액은 초기 제품에이징 작업중 파양 발생으로 측정이 불가하다.
The composition of the electrolytic solution and the application example of the capacitor according to the prior art and the present invention were tested under the same conditions as (500 V / 6.8㎌ for 30 ° C .: 30Ψ × 40 L for 85 ° C.), and the results are shown in [Table 1]. Measurement is not possible due to the generation of wave during the initial product aging process.
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본 발명은 충분한 내전압을 가지면서 전해액의 전도도가 향상되어 하이리플(HIGH RIPPLE)용 소형화 제품에 적용가능하며 고온에서 특성이 안정하고 사용온도 범위가 확대됨은 물론 장시간 사용 가능한 장점이 있다.The present invention has a sufficient withstand voltage, and the conductivity of the electrolyte is improved, so that it can be applied to a miniaturized product for HIGH RIPPLE.
Claims (1)
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020040020311A KR100693521B1 (en) | 2004-03-25 | 2004-03-25 | Ultrahigh voltage electrolyte of aluminium electrolytic condenser |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020040020311A KR100693521B1 (en) | 2004-03-25 | 2004-03-25 | Ultrahigh voltage electrolyte of aluminium electrolytic condenser |
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| Publication Number | Publication Date |
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| KR20050095127A KR20050095127A (en) | 2005-09-29 |
| KR100693521B1 true KR100693521B1 (en) | 2007-03-14 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0169779B1 (en) * | 1995-12-29 | 1999-01-15 | 서두칠 | An electrolyte for al electrolytic condenser |
| KR100328262B1 (en) | 2000-04-25 | 2002-03-16 | 이형도 | A method for preparing electrolytes for aluminum electrolysis condensor for high voltage and the electrolyte prepared therefrom |
| JP2002110469A (en) | 2000-09-29 | 2002-04-12 | Nippon Chemicon Corp | Electrolyte for electrolytic capacitor |
| KR20030058356A (en) * | 2001-12-31 | 2003-07-07 | 파츠닉(주) | An electrolyte for high voltage Al capacitor |
-
2004
- 2004-03-25 KR KR1020040020311A patent/KR100693521B1/en not_active IP Right Cessation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0169779B1 (en) * | 1995-12-29 | 1999-01-15 | 서두칠 | An electrolyte for al electrolytic condenser |
| KR100328262B1 (en) | 2000-04-25 | 2002-03-16 | 이형도 | A method for preparing electrolytes for aluminum electrolysis condensor for high voltage and the electrolyte prepared therefrom |
| JP2002110469A (en) | 2000-09-29 | 2002-04-12 | Nippon Chemicon Corp | Electrolyte for electrolytic capacitor |
| KR20030058356A (en) * | 2001-12-31 | 2003-07-07 | 파츠닉(주) | An electrolyte for high voltage Al capacitor |
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| Publication number | Publication date |
|---|---|
| KR20050095127A (en) | 2005-09-29 |
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