KR100693217B1 - Water resistance, high glossiness and long lasting luminescent coating sheet - Google Patents

Water resistance, high glossiness and long lasting luminescent coating sheet Download PDF

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KR100693217B1
KR100693217B1 KR1020060016263A KR20060016263A KR100693217B1 KR 100693217 B1 KR100693217 B1 KR 100693217B1 KR 1020060016263 A KR1020060016263 A KR 1020060016263A KR 20060016263 A KR20060016263 A KR 20060016263A KR 100693217 B1 KR100693217 B1 KR 100693217B1
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water
photoluminescent
coating layer
resin
weight
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KR1020060016263A
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Korean (ko)
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태인건
김세훈
한양수
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주식회사 한국글로우스타
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00—Layered products comprising a layer of paper or cardboard
    • B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/06—Interconnection of layers permitting easy separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22—Luminous paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7728—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing europium
    • C09K11/7734—Aluminates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Laminated Bodies (AREA)

Abstract

A water resistance and high glossiness photoluminescent coating sheet is provided to secure a long after-glow function by forming a photoluminescent coating layer and to improve ink settling characteristic and glossiness by forming a water resistance gloss coating layer on the surface. The water resistance and high glossiness photoluminescent coating sheet(10) comprises a base material(12) like papers or a polymer film; a photoluminescent coating layer(13) formed on one surface of the base material; and a water resistance gloss coating layer(11) formed on the other surface of the base material. A composition of the photoluminescent coating layer consists of an inorganic pigment of 5~50wt.%, binder resin of 5~84.9wt.%, a diluent of 10~89.9wt.% like an organic solvent or water, and an additive of 0.1~5.0wt.% selected from a wet dispersing agent, an antifoaming agent, and a surface auxiliary agent. The inorganic pigment includes metal oxides of Mal2O4Ln'Ln". M is at least one of calcium, strontium, and barium. Ln' is europium and added about 0.001~10mol.% to M. Ln" is at least one of cerium, ytterbium, dysprosium, praseodymium, and neodymium.

Description

내수 광택성 축광코팅시트 {WATER RESISTANCE, HIGH GLOSSINESS AND LONG LASTING LUMINESCENT COATING SHEET}Waterproof Glossy Photoluminescent Coating Sheet {WATER RESISTANCE, HIGH GLOSSINESS AND LONG LASTING LUMINESCENT COATING SHEET}

도 1은 본 발명의 일실시예에 의한 내수 광택성 축광코팅시트의 개략 구조도.1 is a schematic structural diagram of a water-resistant glossy photoluminescent coating sheet according to an embodiment of the present invention.

도 2는 본 발명의 일실시예에 의한 내수 광택성 축광코팅시트의 개략 구조도.Figure 2 is a schematic structural diagram of a water-resistant glossy photoluminescent coating sheet according to an embodiment of the present invention.

*도면의 주요 부분에 대한 부호의 설명 * Explanation of symbols for the main parts of the drawings

10, 20: 내수 광택성 축광코팅시트 11, 21: 내수광택코팅층10, 20: waterproof gloss photoluminescent coating sheet 11, 21: waterproof gloss coating layer

12: 기재층 13, 23: 축광코팅층12: base material layer 13, 23: photoluminescent coating layer

14: 백색코팅층 24: 백색수지층14: white coating layer 24: white resin layer

15, 25: 점착층 16, 26: 이형지15, 25: adhesive layer 16, 26: release paper

본 발명은 축광코팅시트에 관한 것으로, 특히 내수성 및 광택성이 우수하고 고휘도의 장잔광 특성을 가지는 내수 광택성 축광코팅시트에 관한 것이다.The present invention relates to a photoluminescent coating sheet, and more particularly, to a water-resistant glossy photoluminescent coating sheet having excellent water resistance and glossiness and having high brightness and long afterglow characteristics.

일반적으로 프린터용 시트로서는 일반적인 인쇄용지외에, 종이 기재에 감열 층 및 보호층을 형성하고 열 프린터 헤드에 의해 가열해서 문자 등을 포함한 형상을 발생하도록 하는 감열지가 있다. In general, as a sheet for a printer, there is a thermal paper that forms a thermally conductive head and a protective layer on a paper substrate and heats it by a thermal printer head to generate a shape including a character.

이외에도 그 이면에 점착층을 형성한 지재를 소정 크기의 라벨형태로 구획형성한 후 박리지로 피복한 시일 타입의 프린터용 시트가 있으며, 이는 라벨 등에 이용된다.In addition, there is a seal type printer sheet coated with release paper after partitioning a paper material having an adhesive layer formed thereon into a label of a predetermined size, which is used for a label or the like.

특히, 최근에는 야간이나 정전 등의 비상 시에 어둠속에서 발광하는 축광재료로 되는 축광시트나 축광필름이 적용된 프린터용 시트가 개인용, 사무용, 광고용 등으로 각광을 받고 있다. 더구나, 이러한 프린터 시트에 사용자가 자유로이 인쇄할 수 있도록 하는 기술이 활발히 개발되고 있다. In particular, recently, a photoluminescent sheet or a sheet for a printer applied with a photoluminescent film, which is a photoluminescent material that emits light in the dark in an emergency such as at night or a power failure, has been in the spotlight for personal use, office use, and advertisement. Moreover, technologies for enabling the user to print on such a printer sheet freely are actively developed.

이의 예로서, 국내특허공개공보 제2001-707호는 투명 우레탄과 축광안료를 1:1로 혼합하여 축광인쇄 잉크조성물을 제조하는 기술을 개시하였다. 또한, 국내특허공개공보 제2005-88897호는 투명필름을 이용하여 고휘도 장시간 축광필름을 구현하였으며, 국내특허공개공보 제1999-45829호는 축광인쇄 잉크조성물을 저융점의 열가소성 합성수지 용액에 축광물질, 산화방지기, 안료, 염료를 첨가하여 제조하고, 상기 잉크조성물을 이형면에 그라비나 인쇄한 후 건조하여 제조된 직물질에 침착시키는 제조방법을 개시하였다. As an example of this, Korean Patent Laid-Open No. 2001-707 discloses a technique of manufacturing a phosphorescent printing ink composition by mixing transparent urethane and a phosphorescent pigment in a 1: 1 ratio. In addition, Korean Patent Publication No. 2005-88897 implements a high brightness long time photoluminescent film using a transparent film, and Korean Patent Publication No. 1999-45829 discloses a photoluminescent printing ink composition in a low melting point thermoplastic synthetic resin solution, An antioxidant, a pigment, and a dye are prepared, and the ink composition is disclosed by gravure printing on a mold release surface and then drying to deposit on a fabric produced.

또한, 일본 특허공개공보 평2-113986호는 다공성 알루미나 수산화물을 포함하는 염료 흡수층과 다공성 미세분말 실리카를 포함하는 용매 흡수층을 투명한 지지체 상에 형성하여 지지체를 통하여 이미지를 관찰하는 방법을 개시하였다. 또한, 일본 특허공개공보 소7-117335호는 지지체와, 안료 및 결합제로 구성된 상기 지지 체의 한 층 이상의 잉크 수용층 및 라텍스 안료에서 합성된 폴리머 결합제 및 300nm 이하의 안료로 구성된 광택 발현층을 포함하는 잉크젯 기록시트를 개시한 바 있다.In addition, Japanese Patent Laid-Open No. 2-113986 discloses a method of observing an image through a support by forming a dye absorbing layer comprising a porous alumina hydroxide and a solvent absorbing layer comprising a porous fine powder silica on a transparent support. In addition, Japanese Patent Laid-Open No. 7-117335 includes a support, and a gloss expression layer composed of a pigment binder of 300 nm or less and a polymer binder synthesized from one or more layers of an ink receiving layer of the support composed of a pigment and a binder and a latex pigment. An inkjet recording sheet has been disclosed.

그러나, 이들 종래의 기술들은 별도로 미세 무기입자들을 주로 폴리비닐알콜(PVA)와 혼합하여 기재의 표면에 코팅함으로써 잉크 정착성, 내수성, 축광기능 등이 감소되고, 제조공정이 복잡하며 내구성이 떨어진다는 문제점이 있었다.However, these conventional techniques separately separate the fine inorganic particles with polyvinyl alcohol (PVA) and coat the surface of the substrate to reduce ink fixability, water resistance, photoluminescent function, etc., and the manufacturing process is complicated and durable. There was a problem.

이에, 본 발명은 상기와 같은 문제점을 해결하기 위해 창안된 것으로, 본 발명의 목적은 축광코팅층 및 내수광택코팅층을 함께 형성할 수 있는 각각의 조성물을 제공하고, 이들 축광코팅층 및 내수광택코팅층을 기재 등의 표면에 형성함으로써 고휘도의 장잔광기능, 우수한 특성의 잉크정착성 및 광택성, 내구성을 제공하는데 그 목적이 있다. Accordingly, the present invention was devised to solve the above problems, and an object of the present invention is to provide a respective composition capable of forming a photoluminescent coating layer and a water-resistant gloss coating layer, and to describe these photoluminescent coating layer and a water-resistant gloss coating layer. The purpose is to provide a high brightness long afterglow function, ink fixability and glossiness of excellent characteristics, and durability by forming on the surface of the back and the like.

이와 같은 목적을 달성하기 위하여, 본 발명에 의한 내수 광택성 축광코팅시트는 종이 또는 고분자 필름으로 되는 기재와, 상기 기재의 일면에 형성되는 축광코팅층과, 상기 기재의 다른 일면에 형성되는 내수광택코팅층을 포함할 수 있다.In order to achieve the above object, a water-resistant glossescent coating sheet according to the present invention is a substrate made of paper or a polymer film, a photoluminescent coating layer formed on one side of the substrate, and a water-resistant varnish coating layer formed on the other side of the substrate It may include.

또한, 발명의 다른 특징으로서, 상기 축광코팅층의 일면에는 백색 코팅층이 더 형성되어 이를 포함할 수 있다.In addition, as another feature of the invention, one surface of the photoluminescent coating layer may further include a white coating layer is formed.

또한, 발명의 다른 특징으로서, 본 발명에 의한 내수 광택성 축광코팅시트는백색수지로 되는 백색수지층과, 상기 백색수지층의 일면에 형성되는 축광코팅층과, 상기 축광코팅층의 일면에 형성되는 내수광택코팅층을 포함할 수 있다.In addition, as another feature of the invention, the water-resistant glossy photoluminescent coating sheet according to the present invention is a white resin layer of a white resin, a photoluminescent coating layer formed on one surface of the white resin layer, and a water resistant formed on one surface of the photoluminescent coating layer It may include a gloss coating layer.

또한, 발명의 다른 특징으로서, 상기 백색 코팅층의 일면에는 점착층 및 이형지가 부착될 수 있다.In addition, as another feature of the invention, the adhesive layer and the release paper may be attached to one surface of the white coating layer.

또한, 발명의 다른 특징으로서, 상기 백색수지층의 다른 일면에는 점착층 및 이형지가 부착될 수 있다.In addition, as another feature of the invention, the adhesive layer and the release paper may be attached to the other surface of the white resin layer.

또한, 발명의 다른 특징으로서, 상기 축광코팅층의 조성은 무기계 안료 5 ~ 50중량%와, 바인더 수지 5 ~ 90중량%와, 유기용매 또는 물로 되는 희석제 10 ~ 90중량%와, 습윤분산제, 소포제, 표면조제 중의 적어도 어느 하나로 되는 첨가제 0.1 ~ 5.0중량%를 포함할 수 있다.In addition, as another feature of the invention, the composition of the photoluminescent coating layer is 5 to 50% by weight of inorganic pigment, 5 to 90% by weight of binder resin, 10 to 90% by weight of a diluent consisting of an organic solvent or water, a wet dispersion agent, an antifoaming agent, It may include 0.1 to 5.0% by weight of the additive to be at least one of the surface preparation.

또한, 발명의 다른 특징으로서, 상기 무기계 안료는 MAl2O4Ln'Ln" 조성의 금속산화물을 포함하며, 이때 상기 M은 칼슘, 스트론튬, 바륨 중의 적어도 하나 이상으로 되고, 상기 Ln'는 유로퓸으로 되어 상기 M에 대해 0.001 ~ 10몰% 첨가되며, 상기 Ln"는 세퓸, 이테르븀, 디프로세듐, 프라시튬, 네오디뮴 중의 적어도 하나 이상으로 되어 상기 M에 대해 0.001 ~ 10몰% 첨가될 수 있다.In another aspect, the inorganic pigment includes a metal oxide having a composition of MAl 2 O 4 Ln'Ln ", wherein M is at least one of calcium, strontium and barium, and Ln 'is europium. 0.001 to 10 mol% based on the M, and Ln ″ may be at least one or more of cefem, ytterbium, diprocedium, pracitium, and neodymium, and thus, 0.001 to 10 mol% may be added to the M.

또한, 발명의 다른 특징으로서, 상기 바인더 수지는 알키드 수지, 아크릴 수지, 폴리에스테르 수지, 에폭시 수지, 우레탄 수지, 폴리아미드 수지, UV 경화수지, 염화고무 수지, 멜라민 수지, 요소 수지, 폴리비닐알콜 수지, 폴리비닐에테르 수지 중의 적어도 어느 하나 이상을 포함할 수 있다.In addition, as another feature of the invention, the binder resin is an alkyd resin, acrylic resin, polyester resin, epoxy resin, urethane resin, polyamide resin, UV curable resin, rubber chloride resin, melamine resin, urea resin, polyvinyl alcohol resin And at least one of polyvinyl ether resins.

또한, 발명의 다른 특징으로서, 상기 내수광택코팅층의 조성은 무기금속 화합물 5 ~ 50중량%와, 분산제 2 ~ 90중량%와, 유기용매 또는 물로 되는 희석제 5 ~ 90중량%와, 양이온성 계면활성제 또는 붕산으로 되는 첨가제 0.01 ~ 5중량%을 포함하고, 상기 무기금속 화합물은 알루미늄 산화물 또는 알루미늄 수산화물, 실리카, 탄산칼슘, 티타니아 중의 적어도 어느 하나 이상으로 될 수 있다.Further, as another feature of the invention, the composition of the water-resistant gloss coating layer is 5 to 50% by weight of the inorganic metal compound, 2 to 90% by weight of the dispersant, 5 to 90% by weight of the organic solvent or water diluent, and cationic surfactant Or 0.01 to 5% by weight of an additive consisting of boric acid, wherein the inorganic metal compound may be at least any one of aluminum oxide or aluminum hydroxide, silica, calcium carbonate, titania.

또한, 발명의 다른 특징으로서, 상기 축광코팅층은 롤코팅법, 닥터블레이드법, 나이프코팅법, 스프레이코팅법 중의 적어도 어느 하나를 택하여 10 ~ 300㎛의 두께로 형성될 수 있다.In addition, as another feature of the invention, the photoluminescent coating layer may be formed in a thickness of 10 ~ 300㎛ by selecting at least one of a roll coating method, a doctor blade method, a knife coating method, a spray coating method.

또한, 발명의 다른 특징으로서, 상기 내수광택코팅층은 롤코팅법, 닥터블레이드법, 나이프코팅법, 스프레이코팅법 중의 적어도 어느 하나를 택하여 10 ~ 50㎛의 두께로 형성될 수 있다.In addition, as another feature of the invention, the water-resistant gloss coating layer may be formed in a thickness of 10 ~ 50㎛ by selecting at least one of a roll coating method, a doctor blade method, a knife coating method, a spray coating method.

이하, 본 발명을 도면을 참조하여 상세히 설명한다. Hereinafter, the present invention will be described in detail with reference to the drawings.

도 1 및 도 2는 각각 본 발명에 의한 내수 광택성 축광코팅시트의 개략 구조도를 나타낸다.1 and 2 each show a schematic structural diagram of the water-resistant glossy photoluminescent coating sheet according to the present invention.

본 발명의 일 실시예에 의한 내수 광택성 축광코팅시트(10)는 종이나 고분자 필름형태로 되는 기재(12)의 한쪽 면에 축광 조성물로 되는 축광코팅층(13)을 형성하고, 상기 기재의 반대면에 내수광택 조성물로 되는 내수광택코팅층(11)을 형성하는 구조를 포함할 수 있다.Water-resistant gloss photoluminescent coating sheet 10 according to an embodiment of the present invention forms a photoluminescent coating layer 13 of the photoluminescent composition on one side of the substrate 12 in the form of paper or polymer film, the opposite of the substrate It may include a structure for forming a water-resistant gloss coating layer 11 of the water-resistant gloss composition on the surface.

또한, 상기 내수 광택성 축광코팅시트(10)는 상기 축광코팅층(13)의 하부에 백색 코팅층(14)을 형성하고, 필요에 따라 백색 코팅층(14)의 하부에 점착층(15) 및 이형지(16)를 추가하여 형성할 수 있다.In addition, the waterproof gloss photoluminescent coating sheet 10 forms a white coating layer 14 on the lower portion of the photoluminescent coating layer 13, and if necessary, an adhesive layer 15 and a release paper (15) under the white coating layer 14. 16) can be added.

본 발명의 또 다른 일 실시예에 의한 내수 광택성 축광코팅시트(20)는 매트(Matt)지 등으로 되는 백색수지층(24)의 상부에 축광 조성물로 되는 축광코팅층(23)을 형성하고, 축광코팅층(23) 상부에 내수광택 조성물로 되는 내수광택코팅층(21)을 형성하는 구조를 포함할 수 있다.Water-resistant gloss photoluminescent coating sheet 20 according to another embodiment of the present invention forms a photoluminescent coating layer 23 of a photoluminescent composition on top of the white resin layer 24, such as Matt (Matt) paper, It may include a structure for forming a water-resistant gloss coating layer 21 of a water-resistant gloss composition on the photoluminescent coating layer 23.

또한, 상기 내수 광택성 축광코팅시트(20)는 상기 백색수지층(24)의 하부에 점착층(25) 및 이형지(26)를 추가하여 형성할 수 있다.In addition, the waterproof gloss photoluminescent coating sheet 20 may be formed by adding an adhesive layer 25 and a release paper 26 to the lower portion of the white resin layer 24.

본 발명에 있어서, 상기 축광코팅층을 이루는 축광 조성물은 무기계 안료 5 ~ 50중량%, 바인더 수지 5 ~ 90중량%, 유기용매 또는 물로 되는 희석제 10 ~ 90중량% 및 기타 도료용 첨가제 0.1 ~ 5.0중량%를 포함하여 구성된다. In the present invention, the photoluminescent composition constituting the photoluminescent coating layer is 5 to 50% by weight of inorganic pigments, 5 to 90% by weight of binder resin, 10 to 90% by weight of an organic solvent or water, and 0.1 to 5.0% by weight of other paint additives. It is configured to include.

상기 무기계 안료는 전체 상기 축광 조성물에 균일하게 분산됨이 바람직하다. 만일 5중량% 미만으로 사용되는 경우에는 충분한 발광특성을 발현할 수 없고, 만일 50중량% 이상으로 사용되는 경우에는 균질하고 안정된 분산상을 구현하기가 어려워 코팅시 균일한 도막특성을 달성하기가 어렵게 된다.The inorganic pigment is preferably uniformly dispersed in the entire photoluminescent composition. If it is used at less than 5% by weight can not exhibit sufficient light emission characteristics, if it is used at more than 50% by weight it is difficult to achieve a homogeneous and stable dispersed phase it is difficult to achieve a uniform coating properties during coating .

또한, 상기 무기계 안료는 MAl2O4Ln'Ln" 조성의 금속산화물을 포함할 수 있다. 이때, M은 칼슘(Ca), 스트론튬(Sr), 바륨(Ba) 중에서 적어도 하나 이상 선택되는 금속원소로 되고, Ln'는 유로퓸(Eu) 등으로 되는 활성제(Activator)로서 금속원소 M에 대해 0.001 ~ 10몰% 첨가되며, Ln"는 세퓸(Ce), 이테르븀(Yb), 디프로세듐(Dy), 프라시튬(Pr), 네오디뮴(Nd) 중에서 적어도 하나 이상 선택되는 공활성제(Co-Activator)로서 금속원소 M에 대해 0.001 ~ 10몰% 첨가된다. 특히, 본 발명에 있어서의 상기 무기계 안료는 SrAl2O4 또는 CaAl2O4의 조성을 포함하는 것이 바람직하다.In addition, the inorganic pigment may include a metal oxide of MAl 2 O 4 Ln'Ln "composition, where M is at least one metal element selected from calcium (Ca), strontium (Sr), and barium (Ba). Ln 'is an activator which is europium (Eu) or the like, and is added in an amount of 0.001 to 10 mol% based on the metal element M, and Ln " is sefium (Ce), ytterbium (Yb), and diprocedium (Dy). It is added to 0.001 ~ 10 mol% relative to the metal element M as a co-activator (Co-Activator) is selected from at least one selected from among, pracitium (Pr), neodymium (Nd). In particular, the inorganic pigment in the present invention preferably comprises a composition of SrAl 2 O 4 or CaAl 2 O 4.

상기 무기계 안료는 스핀넬(Spinel) 결정구조를 가지며, 그 최대 발광파장은 440 ~ 580nm, 휘도(Luminosity)가 2 ~ 10cd/m2, 잔광시간이 최대 2,000분, 비중이 3.0 ~ 3.6, 입자의 크기가 1 ~ 100㎛로 됨이 바람직하다. 특히, 상기 무기계 안료는 사용시 인체에 유해한 방사선의 방출이 없고, 내후성 및 내수성을 가짐이 매우 바람직하다.The inorganic pigment has a spinel crystal structure, the maximum emission wavelength is 440 ~ 580nm, the luminance (Luminosity) 2 ~ 10cd / m 2 , afterglow time up to 2,000 minutes, specific gravity 3.0 ~ 3.6, of the particles It is preferable that the size be 1 to 100 mu m. In particular, it is very desirable that the inorganic pigments have no emission of radiation harmful to the human body and have weather resistance and water resistance.

또한, 상기 바인더 수지는 알키드 수지, 아크릴 수지, 폴리에스테르 수지, 에폭시 수지, 우레탄 수지, 폴리아미드 수지, UV 경화수지, 염화고무 수지, 멜라민 수지, 요소 수지, 폴리비닐알콜 수지, 폴리비닐에테르 수지 중의 적어도 어느 하나 이상을 포함할 수 있다. 이들 바인더 수지는 피도물의 종류나 도막의 요구특성에 따라 단독 또는 복합물로서 선택적으로 사용됨이 바람직하다. The binder resin may be selected from among alkyd resins, acrylic resins, polyester resins, epoxy resins, urethane resins, polyamide resins, UV curable resins, rubber chloride resins, melamine resins, urea resins, polyvinyl alcohol resins, and polyvinyl ether resins. It may include at least one or more. It is preferable that these binder resins are selectively used alone or as a composite according to the kind of the workpiece and the required properties of the coating film.

상기 바인더 수지는 만일 전체 축광 조성물에 대해 5중량% 미만으로 함유되는 경우에는 상기 무기계 안료에 대한 바인더 특성을 효과적으로 발현할 수 없게 되고, 만일 90중량% 이상으로 함유되는 경우에는 상대적인 상기 무기계 안료의 함유비율이 낮아지므로 우수한 잔광특성을 기재할 수 없게 된다.If the binder resin is contained in less than 5% by weight relative to the total photoluminescent composition, the binder properties for the inorganic pigment can not be effectively expressed, and if contained in more than 90% by weight, the relative content of the inorganic pigment Since the ratio is lowered, it is impossible to describe excellent afterglow characteristics.

또한, 상기 축광 조성물에는 상기 무기계 안료의 분산 및 습윤 특성을 돕기 위하여 습윤분산제 0.1 ~ 5중량%, 소포제 0.1 ~ 5중량%, 표면조제 0.1 ~ 5중량%를 더 첨가할 수 있다.In addition, the photoluminescent composition may further add 0.1 to 5% by weight of a wet dispersion agent, 0.1 to 5% by weight of an antifoaming agent, and 0.1 to 5% by weight of a surface preparation agent to assist the dispersion and wettability of the inorganic pigment.

본 발명에 있어서, 상기 내수광택코팅층의 내수광택 조성물로는 무기금속 화합물 5 ~ 50중량%, 분산제 2 ~ 90중량%, 유기용매 또는 물로 되는 희석제 5 ~ 90중량%, 기타 첨가제 0.01 ~ 5중량%을 포함하여 구성된다.In the present invention, the water-resistant gloss composition of the water-resistant gloss coating layer is 5 to 50% by weight of inorganic metal compound, 2 to 90% by weight of dispersant, 5 to 90% by weight of organic solvent or water, and 0.01 to 5% by weight of other additives. It is configured to include.

상기 무기금속 화합물은 전체 내수광택 조성물에 콜로이드상 분산상태로 되는 것이 바람직하며, 이는 알루미늄 산화물(Al2O3) 또는 알루미늄 수산화물(AlOOH), 실리카(SiO2), 탄산칼슘(CaCO3), 티타니아(TiO2)에서 적어도 어느 하나 이상을 포함하여 이루어질 수 있다. 본 발명에 있어서는 상기 무기금속 화합물로서 알루미늄 산화물 또는 알루미늄 수산화물을 사용하는 것이 바람직하다. 또한, 상기 무기금속 산화물은 입자의 모양에 관계없이 입자의 크기가 10 ~ 1,000nm이고, BET 비표면적이 50 ~ 500m2/g이며, 동공부피가 0.1 ~ 2.0mL/g로 되는 것이 바람직하다.The inorganic metal compound is preferably in a colloidal dispersion state in the entire water-resistant gloss composition, which is aluminum oxide (Al 2 O 3 ) or aluminum hydroxide (AlOOH), silica (SiO 2 ), calcium carbonate (CaCO 3 ), titania At least one of (TiO 2 ) may be included. In the present invention, it is preferable to use aluminum oxide or aluminum hydroxide as the inorganic metal compound. In addition, the inorganic metal oxide preferably has a particle size of 10 to 1,000 nm, a BET specific surface area of 50 to 500 m 2 / g, and a pupil volume of 0.1 to 2.0 mL / g regardless of particle shape.

상기 무기금속 화합물은 만일 5중량% 이하로 함유되는 경우 내수특성 및 광택특성을 효과적으로 발현하기가 어렵고 인쇄시 잉크 정착성이 효과적이지 못하며, 만일 50중량% 이상으로 함유되는 경우에는 분산액의 점도가 너무 높아서 효과적인 코팅막을 제조할 수가 없어 코팅시 표면의 크랙과 핀홀이 발생하여 우수한 코팅막을 형성할 수 없게 된다.If the inorganic metal compound is less than 5% by weight, it is difficult to effectively express the water resistance and gloss characteristics, and the ink fixability is not effective in printing. If the inorganic metal compound is contained in the amount of 50% by weight or more, the viscosity of the dispersion is too high. It is not possible to produce an effective coating film due to the high surface cracks and pinholes during the coating can not form an excellent coating film.

상기 습윤분산제는 수용성 콜로이드를 만들 수 있는 폴리비닐알콜(PVA), 변성폴리비닐알콜, 폴리비닐피롤리돈(PVP) 중에서 적어도 어느 하나 이상으로 되며, 만일 그 함량이 2중량% 미만인 경우에는 상기 무기금속 화합물을 효과적으로 분산시킬 수가 없게 되고, 만일 90중량% 이상인 경우에는 내수특성 및 광택성을 확보하기가 어려워진다.The wetting and dispersing agent is at least one or more of polyvinyl alcohol (PVA), modified polyvinyl alcohol, polyvinylpyrrolidone (PVP) capable of making a water-soluble colloid, and if the content is less than 2% by weight of the inorganic It becomes impossible to disperse a metal compound effectively, and if it is 90 weight% or more, it becomes difficult to ensure water resistance and glossiness.

또한, 상기 기타 첨가제로서는 옥타데실트리메틸암모늄 클로라이드(Octadecyltrimethylammonium Chloride), 헥사데실트리메틸암모늄 브로마이드(Hexadecyltrimethylammonium Bromide) 등과 같은 양이온성 계면활성제 또는 붕산 등이 코팅막의 크랙방지를 위하여 첨가될 수 있다.In addition, as the other additives, cationic surfactants such as octadecyltrimethylammonium Chloride, hexadecyltrimethylammonium Bromide, or boric acid may be added to prevent cracking of the coating film.

본 발명에 있어서, 기재(12)는 백상지, 인화지 등의 종이류, 폴리에틸렌테레프탈레이트(PET), 폴리염화비닐(PVC), 폴리에스터(PE), 폴리프로필렌(PP) 등의 수지 등으로 될 수 있다.In the present invention, the substrate 12 may be paper such as white paper, photo paper, resin such as polyethylene terephthalate (PET), polyvinyl chloride (PVC), polyester (PE), polypropylene (PP), or the like. .

본 발명에 있어서, 상기 축광코팅층은 롤코팅법, 닥터블레이드법, 나이프코팅법, 스프레이코팅법 등의 적어도 어느 하나를 택하여 형성될 수 있으며, 바람직하기로는 롤코팅법 또는 닥터블레이드법을 사용할 수 있다. 상기 축광코팅층은 대략 10 ~ 300㎛의 두께로 형성함이 바람직하다.In the present invention, the photoluminescent coating layer may be formed by selecting at least one of a roll coating method, a doctor blade method, a knife coating method, a spray coating method, and the like, and preferably, a roll coating method or a doctor blade method may be used. have. The photoluminescent coating layer is preferably formed to a thickness of approximately 10 ~ 300㎛.

또한, 본 발명에 있어서, 상기 백색수지층은 화이트 안료를 아크릴우레탄계 바인더와 혼합한 조성물을 이용하며, 대략 10 ~ 50㎛의 두께로 형성함이 바람직하다. 상기 백색수지층은 기재가 백색계열의 필름기재로 되는 경우에는 생략될 수 있다.In addition, in the present invention, the white resin layer is preferably formed in a thickness of approximately 10 to 50㎛ using a composition in which a white pigment is mixed with an acrylic urethane binder. The white resin layer may be omitted when the substrate is a white substrate.

또한, 상기 내수광택코팅층은 롤코팅법, 닥터블레이드법, 나이프코팅법, 스프레이코팅법 등의 적어도 어느 하나를 택하여 형성될 수 있으며, 바람직하기로는 롤코팅법 또는 닥터블레이드법을 사용할 수 있다. 내수광택코팅층(11)은 대략 10 ~ 50㎛의 두께로 형성함이 바람직하다.In addition, the water-resistant gloss coating layer may be formed by selecting at least one of a roll coating method, a doctor blade method, a knife coating method, a spray coating method, and the like, and preferably, a roll coating method or a doctor blade method may be used. The water-resistant gloss coating layer 11 is preferably formed to a thickness of approximately 10 ~ 50㎛.

이하, 본 발명의 바람직한 실시예를 첨부한 도면을 참조하여 더욱 상세히 설명한다. 다만, 본 발명이 하술하는 실시예는 본 발명의 전반적인 이해를 돕기 위하여 제공되는 것이며, 본 발명은 상기 실시예로만 한정되는 것은 아니다.Hereinafter, with reference to the accompanying drawings, preferred embodiments of the present invention will be described in more detail. However, the embodiments described below are provided to help the overall understanding of the present invention, and the present invention is not limited to the above embodiments.

실시예 1(축광 조성물의 제조) Example 1 (Production of Photoluminescent Composition )

본 실시예에서는 축광 조성물을 제조하였다. 먼저, SrAl2O4계 무기안료 50.0g(50중량%) 및 폴리우레탄계 바인더 50.0g(50중량%)을 500mL 비이커에서 30분간 교반하여 축광안료가 균일하게 분산되어있는 축광 조성물을 제조하였다. 이때, 폴리우레탄계 바인더는 고형분 30중량%, 용매(물) 69.5중량%, 습윤분산제 0.5중량%로 하였다. 제조된 축광 조성물은 연한 황녹색의 분산상을 형성하였다.In this embodiment, a photoluminescent composition was prepared. First, 50.0 g (50 wt%) of SrAl 2 O 4 based inorganic pigment and 50.0 g (50 wt%) of polyurethane binder were stirred in a 500 mL beaker to prepare a photoluminescent composition in which the photoluminescent pigment was uniformly dispersed. At this time, the polyurethane binder was 30 weight% of solid content, 69.5 weight% of solvent (water), and 0.5 weight% of a wet dispersant. The prepared photoluminescent composition formed a light yellow green dispersed phase.

실시예 2(내수광택 조성물의 제조)Example 2 (Preparation of Water-Resistant Glossy Composition)

본 실시예에서는 내수광택 조성물을 제조하였다. 먼저, 무기금속 화합물로는 평균입경이 100nm이고 보헤마이트(Bohemite) 결정상을 갖는 AlOOH분말을 250g 사용하고, 이를 증류수 750mL에 첨가하고 1시간 동안 교반하여 AlOOH 분산상을 제조하였다. 그리고, 여기에 PVA(MW=12,000) 25g을 첨가하여 교반 및 용해시킨 후, 양이온 계면활성제인 헥사데실트리메틸암모늄 브로마이드 1.06g 붕산 0.8g을 각각 첨가 및 혼합하여 내수광택 조성물을 제조하였다. 제조된 내수광택 조성물은 특이한 침전이나 부유물이 발생하지 않는 반투명상의 균일한 콜로이드 상을 형성하였으며, 최소 3개월 이상의 콜로이드 안정성을 나타내었다.In this example, a water resistant gloss composition was prepared. First, as an inorganic metal compound, 250 g of AlOOH powder having an average particle diameter of 100 nm and having a bohemite crystal phase was used, and this was added to 750 mL of distilled water and stirred for 1 hour to prepare an AlOOH dispersed phase. Then, 25 g of PVA (MW = 12,000) was added thereto, followed by stirring and dissolution. Then, 0.8 g of hexadecyltrimethylammonium bromide, a cationic surfactant, 0.8 g was added and mixed, respectively, to prepare a water-resistant gloss composition. The prepared water-resistant gloss composition formed a uniform colloidal phase in a translucent phase in which no specific precipitation or suspended matter occurred, and exhibited colloidal stability of at least 3 months.

실시예Example 3(내수  3 (domestic 광택성Luster 축광코팅시트의Of photoluminescent coating sheet 제조) Produce)

본 실시예에서는 실시예 1, 2에서 각각 제조된 축광 조성물 및 내수광택 조성물을 사용하여 내수 광택성 축광코팅시트(10)를 제조하였다. 즉, 먼저 상기 축광 조성물을 표면이 코로나 처리된 투명한 PET로 된 기재(12)에 닥터블레이드법으로 코팅하고, 80℃의 건조기에서 10분간 가열하여 두께 60㎛의 축광코팅층(13)을 형성하였다. 그리고, 상기 축광코팅층(13)이 형성된 기재(12)의 이면에 상기 내수광택 조성물을 역시 닥터블레이드법으로 코팅하였고, 80℃의 건조기에서 10분간 가열하여 두께 25㎛의 내수광택코팅층(11)을 형성하였다. 그리고, 상기 축광코팅층(13)의 표면에 백색 반사층으로서 두께 35㎛의 백색코팅층(14)를 형성하였고, 상기 백색코팅층(14) 표면에 각각 점착층(15) 및 이형지(16)를 형성하였다.In this embodiment, using the photoluminescent composition and the water-resistant gloss composition prepared in Examples 1 and 2, respectively, a water-resistant glossy photoluminescent coating sheet 10 was prepared. That is, first, the photoluminescent composition was coated on the substrate 12 of corona-treated transparent PET by a doctor blade method, and heated for 10 minutes in a dryer at 80 ° C. to form a photoluminescent coating layer 13 having a thickness of 60 μm. Then, the water-resistant gloss composition was also coated on the back surface of the substrate 12 on which the photoluminescent coating layer 13 was formed by a doctor blade method, and the water-resistant varnish coating layer 11 having a thickness of 25 μm was heated in a dryer at 80 ° C. for 10 minutes. Formed. Then, a white coating layer 14 having a thickness of 35 μm was formed on the surface of the photoluminescent coating layer 13, and a pressure-sensitive adhesive layer 15 and a release paper 16 were formed on the surface of the white coating layer 14, respectively.

실시예 4(내수 광택성 축광코팅시트의 제조)Example 4 (Preparation of Water-Resistant Glossy Photoluminescent Coating Sheet)

본 실시예에서는 실시예 3과 마찬가지로 내수 광택성 축광코팅시트(10)를 제조하였으며, 다만 축광코팅층(13)을 형성함에 있어 상기 축광 조성물을 2회 반복하여 코팅하여 그 두께가 120㎛로 되도록 하였다. 그 외 나머지 제조방법은 실시예 3과 동일하였다.In this embodiment, as in Example 3, a water-resistant glossy photoluminescent coating sheet 10 was manufactured. However, in forming the photoluminescent coating layer 13, the photoluminescent composition was repeatedly coated twice so as to have a thickness of 120 μm. . The rest of the manufacturing method was the same as in Example 3.

실시예 5(내수 광택성 축광코팅시트의 제조)Example 5 (Preparation of Water-Resistant Glossy Photoluminescent Coating Sheet)

본 실시예에서는 실시예 3, 4와는 달리 기재(12)를 별도로 형성하지 않고, 그 대신에 백색수지층(24)을 매트지로 형성하여 내수 광택성 축광코팅시트(20)를 제조하였다. 그리고, 실시예 1, 2에서 각각 제조된 축광 조성물 및 내수광택 조성물을 사용하였다. 즉, 먼저 매트지 표면에 상기 축광 조성물을 닥터블레이드법으로 코팅하고, 80℃의 건조기에서 10분간 가열하여 두께 60㎛의 축광코팅층(23)을 형성하였다. 그리고, 상기 축광코팅층(23) 상부에 상기 내수광택 조성물을 역시 닥터블레이드법으로 코팅한 후, 80℃의 건조기에서 10분간 가열하여 두께 25㎛의 내수광택코팅층(21)을 형성하였다. 또한, 상기 백색수지층(24) 이면에 각각 점착층(25)과 이형지(26)를 형성하였다.In the present embodiment, unlike Examples 3 and 4, the substrate 12 is not separately formed, and instead, the white resin layer 24 is formed of matt paper, thereby manufacturing a water-resistant glossy photoluminescent coating sheet 20. And the photoluminescent composition and the water-resistant gloss composition which were respectively prepared in Example 1 and 2 were used. That is, first, the photoluminescent composition was coated on the mat surface by a doctor blade method, and heated for 10 minutes in a dryer at 80 ° C. to form a photoluminescent coating layer 23 having a thickness of 60 μm. Then, after coating the water-resistant varnish composition on the photoluminescent coating layer 23 by the doctor blade method, it was heated in a drier at 80 ° C. for 10 minutes to form a water-resistant varnish coating layer 21 having a thickness of 25 μm. In addition, an adhesive layer 25 and a release paper 26 were formed on the back surface of the white resin layer 24, respectively.

이상에서 설명한 바와 같이, 본 발명에 의한 내수 광택성 축광코팅시트는 축광코팅층에 의한 잔광기능을 가지면서, 내수광택코팅층을 포면에 형성함으로써 잉크정착성 및 광택성이 우수하여 잉크젯 방식에 의한 고품질의 인쇄가 가능하다.As described above, the water-resistant glossy photoluminescent coating sheet according to the present invention has an afterglow function by the photoluminescent coating layer, and forms a water-resistant glossy coating layer on the surface to be excellent in ink fixability and glossiness, thereby providing high quality by an inkjet method. Printing is possible.

또한, 본 발명에 의한 내수 광택성 축광코팅시트는 인쇄 표면에 내수성을 부여함으로써 실내뿐만 아니라 실외에서도 내구성이 우수하다.In addition, the water-resistant glossy photoluminescent coating sheet according to the present invention is excellent in durability not only indoors but also outdoors by imparting water resistance to the printing surface.

아울러 본 발명의 바람직한 실시예는 예시의 목적을 위해 개시된 것이며, 해당 분야에서 통상의 지식을 가진 자라면 누구나 본 발명의 사상과 범위 안에서 다양한 수정, 변경, 부가 등이 가능할 것이고, 이러한 수정, 변경, 부가 등은 특허청구범위에 속하는 것으로 보아야 한다.In addition, the preferred embodiment of the present invention is disclosed for the purpose of illustration, anyone of ordinary skill in the art will be possible to various modifications, changes, additions, etc. within the spirit and scope of the present invention, such modifications, changes, Additions and the like should be considered to be within the scope of the claims.

Claims (11)

종이 또는 고분자 필름으로 되는 기재와, 상기 기재의 일면에 형성되는 축광코팅층과 상기 기재의 다른 일면에 형성되는 내수광택코팅층을 포함하는 내수 광택성 축광코팅시트에 있어서,In the water-resistant luster photosensitive coating sheet comprising a substrate made of paper or a polymer film, a photoluminescent coating layer formed on one surface of the substrate and a water resistant gloss coating layer formed on the other surface of the substrate, 상기 축광코팅층의 조성은 무기계 안료 5 ~ 50중량%와, 바인더 수지 5 ~ 84.9중량%와, 유기용매 또는 물로 되는 희석제 10 ~ 89.9중량%와, 습윤분산제, 소포제, 표면조제 중의 적어도 어느 하나로 되는 첨가제 0.1 ~ 5.0중량%를 포함하고;The composition of the photoluminescent coating layer is 5 to 50% by weight of an inorganic pigment, 5 to 84.9% by weight of a binder resin, 10 to 89.9% by weight of a diluent composed of an organic solvent or water, and an additive comprising at least one of a wet dispersant, an antifoaming agent, and a surface aid. 0.1 to 5.0 weight percent; 상기 무기계 안료는 MAl2O4Ln'Ln" 조성의 금속산화물을 포함하며, 이때 상기 M은 칼슘, 스트론튬, 바륨 중의 적어도 하나 이상으로 되고, 상기 Ln'는 유로퓸으로 되어 상기 M에 대해 0.001 ~ 10몰% 첨가되며, 상기 Ln"는 세퓸, 이테르븀, 디프로세듐, 프라시튬, 네오디뮴 중의 적어도 하나 이상으로 되어 상기 M에 대해 0.001 ~ 10몰% 첨가되는 것을 특징으로 하는 내수 광택성 축광코팅시트.The inorganic pigment includes a metal oxide having a composition of MAl 2 O 4 Ln'Ln ", wherein M is at least one of calcium, strontium, and barium, and Ln 'is europium, which is 0.001 to 10 with respect to M. Mol% is added, wherein Ln ″ is at least one of cefem, ytterbium, diprocedium, pracitium, and neodymium, wherein the water-resistant glossescent coating sheet is added in an amount of 0.001 to 10 mol% based on M. 제1항에 있어서,The method of claim 1, 상기 축광코팅층의 일면에는 백색 코팅층이 더 형성되어 이를 포함하는 것을 특징으로 하는 내수 광택성 축광코팅시트.Water-resistant glossy photoluminescent coating sheet characterized in that it comprises a white coating layer further formed on one surface of the photoluminescent coating layer. 백색수지로 되는 백색수지층과, 상기 백색수지층의 일면에 형성되는 축광코팅층과, 상기 축광코팅층의 일면에 형성되는 내수광택코팅층을 포함하는 내수 광택성 축광코팅시트에 있어서,In the water-resistant glossy photoluminescent coating sheet comprising a white resin layer made of a white resin, a photoluminescent coating layer formed on one surface of the white resin layer, and a water resistant gloss coating layer formed on one surface of the photoluminescent coating layer, 상기 축광코팅층의 조성은 무기계 안료 5 ~ 50중량%와, 바인더 수지 5 ~ 84.9중량%와, 유기용매 또는 물로 되는 희석제 10 ~ 89.9중량%와, 습윤분산제, 소포제, 표면조제 중의 적어도 어느 하나로 되는 첨가제 0.1 ~ 5.0중량%를 포함하고;The composition of the photoluminescent coating layer is 5 to 50% by weight of an inorganic pigment, 5 to 84.9% by weight of a binder resin, 10 to 89.9% by weight of a diluent composed of an organic solvent or water, and an additive comprising at least one of a wet dispersant, an antifoaming agent, and a surface aid. 0.1 to 5.0 weight percent; 상기 무기계 안료는 MAl2O4Ln'Ln" 조성의 금속산화물을 포함하며, 이때 상기 M은 칼슘, 스트론튬, 바륨 중의 적어도 하나 이상으로 되고, 상기 Ln'는 유로퓸으로 되어 상기 M에 대해 0.001 ~ 10몰% 첨가되며, 상기 Ln"는 세퓸, 이테르븀, 디프로세듐, 프라시튬, 네오디뮴 중의 적어도 하나 이상으로 되어 상기 M에 대해 0.001 ~ 10몰% 첨가되는 것을 특징으로 하는 내수 광택성 축광코팅시트.The inorganic pigment includes a metal oxide having a composition of MAl 2 O 4 Ln'Ln ", wherein M is at least one of calcium, strontium, and barium, and Ln 'is europium, which is 0.001 to 10 with respect to M. Mol% is added, wherein Ln ″ is at least one of cefem, ytterbium, diprocedium, pracitium, and neodymium, wherein the water-resistant glossescent coating sheet is added in an amount of 0.001 to 10 mol% based on M. 제2항에 있어서,The method of claim 2, 상기 백색 코팅층의 일면에는 점착층 및 이형지가 부착되는 것을 특징으로 하는 내수 광택성 축광코팅시트.Waterproofing photoluminescent coating sheet, characterized in that the adhesive layer and a release paper is attached to one surface of the white coating layer. 제3항에 있어서,The method of claim 3, 상기 백색수지층의 다른 일면에는 점착층 및 이형지가 부착되는 것을 특징으 로 하는 내수 광택성 축광코팅시트.The other surface of the white resin layer is a water-resistant glossy photoluminescent coating sheet, characterized in that the adhesive layer and the release paper is attached. 삭제delete 삭제delete 제1항 내지 제5항 중의 어느 한 항에 있어서,The method according to any one of claims 1 to 5, 상기 바인더 수지는 알키드 수지, 아크릴 수지, 폴리에스테르 수지, 에폭시 수지, 우레탄 수지, 폴리아미드 수지, UV 경화수지, 염화고무 수지, 멜라민 수지, 요소 수지, 폴리비닐알콜 수지, 폴리비닐에테르 수지 중의 적어도 어느 하나 이상을 포함하는 것을 특징으로 하는 내수 광택성 축광코팅시트.The binder resin is at least one of alkyd resin, acrylic resin, polyester resin, epoxy resin, urethane resin, polyamide resin, UV curable resin, rubber chloride resin, melamine resin, urea resin, polyvinyl alcohol resin, polyvinyl ether resin Water-resistant glossy photoluminescent coating sheet comprising at least one. 제1항 내지 제5항 중의 어느 한 항에 있어서,The method according to any one of claims 1 to 5, 상기 내수광택코팅층의 조성은 무기금속 화합물 5 ~ 50중량%와, 분산제 2 ~ 89.99중량%와, 유기용매 또는 물로 되는 희석제 5 ~ 90중량%와, 양이온성 계면활성제 또는 붕산으로 되는 첨가제 0.01 ~ 5중량%을 포함하고, 상기 무기금속 화합물은 알루미늄 산화물 또는 알루미늄 수산화물, 실리카, 탄산칼슘, 티타니아 중의 적어도 어느 하나 이상으로 되는 것을 특징으로 하는 내수 광택성 축광코팅시트.The composition of the water-resistant gloss coating layer is 5 to 50% by weight of an inorganic metal compound, 2 to 89.99% by weight of a dispersant, 5 to 90% by weight of a diluent of an organic solvent or water, and an additive of 0.01 to 5 of a cationic surfactant or boric acid. A weight-% by weight, wherein the inorganic metal compound is at least any one of aluminum oxide or aluminum hydroxide, silica, calcium carbonate, titania. 제1항 내지 제5항 중의 어느 한 항에 있어서,The method according to any one of claims 1 to 5, 상기 축광코팅층은 롤코팅법, 닥터블레이드법, 나이프코팅법, 스프레이코팅법 중의 적어도 어느 하나를 택하여 10 ~ 300㎛의 두께로 형성되는 것을 특징으로하는 내수 광택성 축광코팅시트.The photoluminescent coating layer is water-resistant glossy photoluminescent coating sheet, characterized in that formed in a thickness of 10 ~ 300㎛ by selecting at least one of a roll coating method, a doctor blade method, a knife coating method, a spray coating method. 제1항 내지 제5항 중의 어느 한 항에 있어서,The method according to any one of claims 1 to 5, 상기 내수광택코팅층은 롤코팅법, 닥터블레이드법, 나이프코팅법, 스프레이코팅법 중의 적어도 어느 하나를 택하여 10 ~ 50㎛의 두께로 형성되는 것을 특징으로 하는 내수 광택성 축광코팅시트.The water-resistant gloss coating layer is a water-resistant glossy photoluminescent coating sheet, characterized in that formed in a thickness of 10 ~ 50㎛ by selecting at least one of a roll coating method, a doctor blade method, a knife coating method, a spray coating method.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100801433B1 (en) 2006-10-13 2008-02-05 주식회사 엘지화학 Surface coating apparatus of pro-file, coating method the same
KR100853848B1 (en) 2007-10-09 2008-08-22 서삼상 The radiation film
KR101325728B1 (en) 2012-10-23 2013-11-08 주식회사 넥스필 Ultraviolet and infrared absorbable reiforcement film and manufacturing method therefor
KR101795609B1 (en) * 2010-01-28 2017-12-04 아크조노벨코팅스인터내셔널비.브이. Mirror-color Coating Structure Without Deposition

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050008218A (en) * 2003-07-14 2005-01-21 주식회사 글로얀 Composition of unsaturated poly-ester resin having fluorescent and antibacterical property and the product thereof
KR20050088897A (en) * 2004-03-05 2005-09-07 박광석 High Brightness Long Time Luminous Film Using Transparent Film

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050008218A (en) * 2003-07-14 2005-01-21 주식회사 글로얀 Composition of unsaturated poly-ester resin having fluorescent and antibacterical property and the product thereof
KR20050088897A (en) * 2004-03-05 2005-09-07 박광석 High Brightness Long Time Luminous Film Using Transparent Film

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100801433B1 (en) 2006-10-13 2008-02-05 주식회사 엘지화학 Surface coating apparatus of pro-file, coating method the same
KR100853848B1 (en) 2007-10-09 2008-08-22 서삼상 The radiation film
KR101795609B1 (en) * 2010-01-28 2017-12-04 아크조노벨코팅스인터내셔널비.브이. Mirror-color Coating Structure Without Deposition
KR101325728B1 (en) 2012-10-23 2013-11-08 주식회사 넥스필 Ultraviolet and infrared absorbable reiforcement film and manufacturing method therefor

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