KR100686830B1 - Fuel cell system - Google Patents

Abstract

A fuel cell system is provided to increase a cooling efficiency of a heat exchanger and to enhance energy efficiency by heating air coming into an inlet of a cathode by using heat of air discharged from a cathode of a stack. The fuel cell system(100) comprises: a stack(20) that has an anode and a cathode and generates electric energy by a chemical reaction of fuel to be supplied; an undiluted solution tank(40) for storing an undiluted solution of fuel; a fuel diluting tank(30) that mixes a fuel supplied from an undiluted solution pump(45) and the undiluted solution tank(40) with water and unreacted fuel discharged from the cathode and anode to prepare diluted fuel; a fuel supply pump(35) that is connected to the fuel diluting tank(30) and supplies fuel to the anode; an air supply unit(50) that supplies air to the cathode; a housing(10) of a box shape in which an air vent(12) and a vent(14) are formed at predetermined positions and the stack(20), undiluted solution tank(40), undiluted solution pump(45), fuel diluting tank(30), and fuel supply pump(35) are provided; and a heat exchanger(60) that sucks air from the air vent(12) and is configured to cool a four pipe(25b) in which water vapor and water discharged from the stack(20) circulate. The air supply unit(50) sucks air discharged from the heat exchanger(60) and supplies the air to the cathode of the stack(20).

Description

Fuel Cell System

1 is a perspective view of a fuel cell system according to an exemplary embodiment of the present invention.

2 is an internal plan view of a fuel cell system according to an exemplary embodiment of the present invention.

3 is a plan view showing the flow of air in the fuel cell system according to an embodiment of the present invention.

<Explanation of symbols for the main parts of the drawings>

10-housing 20-stack

30-Fuel Dilution Tank 35-Fuel Supply Pump

40-Stock Tank 45-Stock Pump

50-Air Supply 60-Heat Exchanger

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fuel cell system, and more particularly to a vent hole formed in a housing of a fuel cell system by forming an air flow path for supplying air used in a heat exchanger to an inlet of a cathode to cool a fluid discharged from an outlet of a cathode. Increase the cooling efficiency of the heat exchanger by increasing the distance between the vent and the air inlet to the heat exchanger by minimizing the number of air and the reactor to the outside, while using the heat of the air discharged from the cathode outlet The present invention relates to a fuel cell system capable of heating energy introduced into an inlet of a cathode to increase energy efficiency.

A fuel cell is a power generation system that directly converts the chemical reaction energy of hydrogen and oxidant contained in hydrocarbon-based materials such as methanol, ethanol, and natural gas into electrical energy.

The fuel cell system is typically a polymer electrolyte fuel cell (PEMFC) system and a direct methanol fuel cell (DMFC) system. Can be mentioned.

In general, a PEMFC system includes a stack that generates electric energy by a reaction of hydrogen and oxygen, and a reformer that generates hydrogen by reforming a fuel. The PEMFC system has the advantages of high energy density and high output, but requires attention to handling hydrogen gas and fuel reformer for reforming methane, methanol and natural gas to produce hydrogen, fuel gas. You will need additional equipment.

In contrast, DMFC systems generate methanol by electrochemical reactions by directly supplying methanol fuel and oxygen as an oxidant to the stack. The DMFC system has a very high energy density and power density, and since it uses liquid fuel such as methanol directly, it does not require any supplementary equipment such as a fuel reformer and has the advantage of easy storage and supply of fuel.

In this DMFC system, a stack that substantially generates electricity includes one unit cell including a membrane electrode assembly (hereinafter referred to as "MEA") and a separator (or bipolar plate). Or one or more laminated structures. The MEA is formed by interposing an electrolyte membrane between an anode electrode and a cathode electrode. In addition, the structure of each anode electrode and the cathode electrode is provided with a fuel diffusion layer (diffusion layer) for the supply and diffusion of fuel, a catalyst layer for the oxidation / reduction reaction of the fuel, and the electrode support. The catalyst layer is a noble metal catalyst such as platinum having excellent properties even at low temperatures, in particular, the anode electrode, such as ruthenium, rhodium, osmium, nickel, etc. in order to prevent catalyst poisoning by carbon monoxide, a reaction by-product Alloy catalysts of transition metals are used. The electrode support is made of carbon paper, carbon fabric, etc., and is used after being water-proofed to facilitate fuel supply and discharge of reaction products. The electrolyte membrane is a polymer membrane having a thickness of 50-200 μm, which is a hydrogen ion exchange membrane containing water and having ion conductivity.

The electrode reaction in the stack of such a DMFC system consists of an anode reaction in which the supplied fuel is oxidized and a cathode reaction in which oxygen in the supplied air reacts with hydrogen ions moved from the anode to be reduced. therefore,

a. Anode electrode reaction

CH ₃ OH + H ₂ O → CO ₂ + 6H + + 6e- (Scheme 1)

b. Cathode reaction

3 / 2O ₂ + 6H + + 6e- → 3H ₂ O (Scheme 2)

c. Overall reaction

CH ₃ OH + 3 / 2O2 → 2H ₂ O + CO ₂ (Scheme 3)

In the anode electrode in which the oxidation reaction (Scheme 1) occurs, carbon dioxide, hydrogen ions and electrons are generated by the reaction of methanol and water, and the generated hydrogen ions are transferred to the cathode electrode through the electrolyte membrane. In the cathode electrode where the reduction reaction (Scheme 2) occurs, water is generated by oxygen supplied from the outside, hydrogen ions supplied from the anode, and electrons transferred through the external circuit. Therefore, the overall reaction of DMFC (Scheme 3) is a reaction in which methanol and oxygen react to produce water and carbon dioxide. At this time, one molecule of methanol reacts with oxygen to produce two moles of water.

This DMFC system includes a fuel dilution tank for diluting the fuel stock solution to a predetermined concentration. That is, the fuel supplied to the anode electrode is not pure methanol but is mixed with water and adjusted to a predetermined concentration. The fuel dilution tank mixes the fuel stock solution supplied from the fuel stock tank with the unreacted fuel discharged from the anode and the water discharged from the cathode and dilutes the fuel with a predetermined concentration. In addition, the fuel dilution tank has carbon dioxide and air introduced from the anode and the cathode, respectively, and has a vent for discharging carbon dioxide and air at the top.

Since the air discharged from the cathode of the stack is heated to a predetermined temperature, it is necessary to cool the temperature of the air using a heat exchanger for efficient condensation of water. However, when the air intake port of the heat exchanger is located at a close distance to the vent, the heated air discharged from the vent is sucked, and thus the cooling efficiency of the heat exchanger is deteriorated. This phenomenon increases as the overall size of the fuel cell system becomes smaller.

On the other hand, when the air supply means of the DMFC system directly sucks the outside air and supplies it to the cathode of the stack, in order to always manage the stack at an appropriate temperature, the air must be heated to an appropriate temperature for stack operation. There is a problem of this deterioration.

The present invention has been made to solve the above problems, the vent formed in the housing of the fuel cell system by forming an air passage so that the air used in the heat exchanger is supplied to the inlet of the cathode to cool the fluid discharged from the cathode of the stack It is an object of the present invention to provide a fuel cell system capable of increasing the cooling efficiency of a heat exchanger by minimizing the number of air gaps and increasing the distance between the vents and the air inlets to the heat exchanger.

In addition, an object of the present invention is to provide a fuel cell system that can heat the air flowing into the inlet of the cathode by using the heat of the air discharged from the cathode of the stack to increase the energy efficiency.

In order to solve the above problems, the fuel cell system of the present invention is provided with an anode and a cathode, a stack for generating electrical energy by chemical reaction of a supplied fuel, a stock solution tank in which a stock solution of fuel is stored, and a stock solution The dilution tank for supplying the fuel of the tank, the fuel dilution tank which mixes the fuel supplied from the stock solution tank, the water discharged from the cathode and the anode and the unreacted fuel, respectively, and dilutes the fuel with a predetermined concentration, and the fuel dilution tank. A fuel cell system comprising a fuel supply pump connected to and supplying fuel to the anode and air supply means to supply air to the cathode, wherein a vent and a vent are formed at a predetermined position in a box shape, and the stack and the stock solution tank And a housing containing the stock solution pump, a fuel dilution tank, and a fuel supply pump therein, and the vent hole. And a heat exchanger configured to suck air from the stack to cool the fourth pipe through which water vapor and water discharged from the stack flow, and the air supply means sucks air discharged from the heat exchanger to supply the cathode to the stack. It is characterized by being formed. In this case, the housing may have the vent formed on one side and the vent formed on the other side.

In addition, in the present invention, the heat exchanger has a fan connected to the vent of the housing to suck air, a first hole to which the fan is connected, and a second hole to be connected to the air supply means, and the fourth pipe is inside. It may be formed to include a cooling unit is formed to extend. In this case, the housing may include a second vent on the other surface, and the cooling part may further include a third hole connected to the second vent through a discharge pipe. In addition, the fourth pipe may be formed in a zigzag shape in the cooling unit. In addition, the fuel dilution tank may be formed to be connected to the vent of the housing through the discharge pipe.

In addition, the air supply means in the present invention may be made of any one of the air pump, air blower, fan.

In addition, the fuel cell system in the present invention may be made of a direct methanol fuel cell system.

Hereinafter, a fuel cell system according to the present invention will be described in detail with reference to the accompanying drawings and embodiments.

1 is a perspective view of a fuel cell system according to an exemplary embodiment of the present invention. 2 is an internal plan view of a fuel cell system according to an exemplary embodiment of the present invention.

1 and 2, a fuel cell system 100 according to an exemplary embodiment of the present invention, a stack 20, a fuel dilution tank 30, a fuel supply pump 35, a stock solution tank 40, and a stock solution It is formed including the pump 45, the air supply means 50 and the heat exchanger (60). In addition, the fuel cell system includes a stack 20, a fuel dilution tank 30, a fuel supply pump 35, a feedstock tank 40, a feedstock pump 45, an air supply means 50, and a heat exchanger 60. It is formed including a housing 10 accommodated therein. A fuel cell system according to an embodiment of the present invention will be described based on a DMFC system in which fuel supplied in a liquid state such as methanol and oxygen supplied in an air state generate electric energy by an electrochemical reaction. However, the fuel cell system according to the present invention can be applied to a polymer electrolyte fuel cell (PEMFC) system that generates electric energy using hydrogen generated by reforming fuel as a fuel. However, the PEMFC system is configured to further include a reformer for generating hydrogen by reforming the liquid fuel.

The housing 10 has a plate shape having a predetermined thickness in a substantially box shape, and has a stack 20, a fuel dilution tank 30, a fuel supply pump 35, a stock solution tank 40, and a stock solution pump 45 therein. And the air supply means 50 and the heat exchanger 60 are formed. The housing 10 has a vent hole 12 which is a passage of air introduced into the heat exchanger 60 on one surface 10a. In addition, the housing 10 has a vent 14 on which the discharge pipe 34 through which the exhaust gas such as air and carbon dioxide introduced into the fuel dilution tank 30 is discharged is formed on the other side 10d. Here, the vent 12 and the vent 14 are formed on different surfaces so that the air discharged from the vent 14 does not flow back into the vent 12.

In addition, the housing 10 may be further formed with another second vent 16 on the other surface (10b). The second vent 16 allows a part of the air discharged from the heat exchanger 60 to be discharged to the outside. More specifically, the air sucked into the heat exchanger 60 is partially supplied to the air supply means 50, and the remaining air is discharged to the outside through the second vent 16. The second vent 16 is formed on the other surface 10b to be far from the one surface 10a on which the vent 12 is formed so that air discharged from the second vent 16 is not introduced into the vent 12. do.

On the other hand, the housing 10 may be formed with a separate inlet and outlet (not shown) in which air to cool the stack 20 is introduced.

The stack 20 has a structure in which one or two or more unit cells including a MEA and a bipolar plate are stacked. The MEA is formed by interposing an electrolyte membrane between an anode electrode and a cathode electrode. In addition, the structure of the anode electrode and the cathode electrode is provided with a fuel diffusion layer (diffusion layer) for the supply and diffusion of fuel, a catalyst layer for the oxidation / reduction reaction of the fuel, and the electrode support.

The stack 20 is supplied with fuel diluted to a predetermined concentration from the fuel dilution tank 30 connected to the first pipe 23a through the inlet 22a of the anode, and reacted by-products through the outlet 22b of the anode. Phosphorus carbon dioxide and unreacted fuel are emitted. The reaction byproduct and the unreacted fuel are introduced into the fuel dilution tank 30 through the second pipe 23b connected to the outlet 22b of the anode.

In addition, the stack 20 is supplied with air from the air supply means 50 connected to the third pipe 25a through the inlet 24a of the cathode, and reacts with the unreacted air through the outlet 24b of the cathode. By-product water is discharged to the fourth pipe 25b. In addition, the cathode outlet 24b is supplied to the anode and also discharges fuel that cross-overs the electrolyte membrane. In general, when a high concentration of methanol used as fuel in a fuel cell system is used, the methanol is moved to the cathode electrode by a cross-over through the electrolyte membrane. It is diluted with a low concentration of 2 M (2-8 vol.%) Methanol. Water and some fuel discharged from the discharge port 24b of the cathode are recovered to the fuel dilution tank 30 and used to dilute the fuel stock solution to a predetermined concentration.

The first pipe 23a is formed to connect the inlet port 22a of the anode constituting the stack 20 and the fuel supply pump 35 to become a passage of fuel supplied to the inlet port 22a of the anode. The second pipe 23b is formed to connect the outlet 22b of the anode constituting the stack 20 and the fuel dilution tank 30 so that a passage of unreacted fuel and carbon dioxide discharged from the outlet 22b of the anode is provided. do. The third pipe 25a is formed to connect the inlet 24a of the cathode constituting the stack 20 and the air supply means 50 to be a passage of air supplied to the inlet 24a of the cathode. The fourth pipe 25b is formed to connect the discharge port 24b of the cathode constituting the stack 20 and the fuel dilution tank 30 to become a passage of air and water discharged from the discharge port 24b of the cathode. In addition, the fourth pipe 25b is installed such that a predetermined region between the cathode outlet 24b and the fuel dilution tank 30 is located inside the heat exchanger 60 to lower the temperature of steam and water flowing therein. .

The fuel dilution tank 30 is formed in a substantially box shape having a hollow inside, and stores fuel that is diluted to a predetermined concentration therein. The fuel dilution tank 30 is formed so that a predetermined fuel can be stored therein according to the specification of the fuel cell system. The fuel dilution tank 30 is connected to the fuel supply pump 35 through the fuel pipe 32, and is connected to the stock solution pump 45 through the stock solution inlet pipe 47. In addition, the fuel dilution tank 30 is connected to the anode of the stack 20 through the second pipe 23b, and is connected to the cathode of the stack 20 through the fourth pipe 23b. In addition, the fuel dilution tank 30 is formed with a discharge pipe 34 through which carbon dioxide and air introduced through the second pipe 23b and the fourth pipe 24b are discharged. The discharge pipe 34 is connected to the outside through the vent 14 of the housing 10. In addition, the fuel dilution tank 30 may be formed by further comprising a fuel sensor (not shown) installed on the bottom surface to detect the degree of fuel stored therein.

The fuel supply pump 35 is connected to the fuel dilution tank 30 through the fuel pipe 32, and is connected to the inlet 22a of the anode constituting the stack 20 through the first pipe 23a. Accordingly, the fuel supply pump 35 receives the fuel stored in the fuel dilution tank 30 through the fuel pipe 32 and supplies the fuel to the inlet 22a of the anode. The fuel supply pump 35 may be a variety of pumps that can supply a liquid may be used here is not limited to that kind.

The stock solution tank 40 is configured to store the stock solution of the fuel used in the fuel cell system and to store a predetermined amount of the stock solution according to the capacity of the fuel cell system. The stock solution tank 40 is connected to the stock solution pump 45 through the stock solution pipe 42, but may be formed to be directly connected to the stock solution pump 45. The stock solution tank 40 stores fuels such as methanol and ethanol depending on the fuel used.

The stock solution pump 45 is connected to the stock solution tank 40 through the stock solution pipe 42, and is connected to the fuel dilution tank 30 through the stock solution inlet pipe 47. The stock solution pump 45 supplies the stock solution of the fuel stored in the stock solution tank 40 to the fuel dilution tank 30. The stock pump 45 may be used a variety of pumps that can supply a liquid is not limited thereto.

The air supply means 50 is connected to the inlet 24a of the cathode constituting the stack 20 through the third pipe 25a to supply air. In addition, the air supply means 50 is connected to the heat exchanger 60 through the air suction pipe 52, and sucks the air discharged from the heat exchanger 60 to supply to the stack 20. That is, the air supply means 50 sucks the air heated to a predetermined temperature in the heat exchanger 60 without supplying the external air directly and supplies it to the stack 20. Therefore, the stack 20 does not need to separately heat the air supplied to the cathode, thereby preventing energy loss and improving the reaction efficiency and performance of the stack. The air supply means 50 may be applied to a variety of air supply means, such as an air pump, air blower (air blower), fan (fan).

The heat exchanger 60 includes a fan 62 and a cooling unit 64 and is installed at a predetermined position inside the housing 10. The heat exchanger 60 is formed such that a part of the fourth pipe 25b connected to the discharge port 24b of the cathode extends inwardly. The heat exchanger 60 sucks external air to cool water vapor and water flowing in the fourth pipe 25b formed to extend into the heat exchanger 60. Since the water vapor and water flowing through the fourth pipe 25b are discharged from the stack and heated to a predetermined temperature, the heat exchanger 60 can be effectively recovered by cooling and condensing it.

The fan 62 includes a propeller (not shown) and a motor for rotating the propeller (not shown) and is installed to be connected to the vent 12 of the housing 10. The fan 62 sucks outside air through the vent 12. The fan 62 is formed on the other side 10a of the vent 14 formed on the other side 10d of the housing 10, so that the heated air discharged from the vent 14 is not sucked. The cooling efficiency of (60) is improved. Of course, the fan 62 may be an air blower or an air pump.

The cooling unit 64 is formed in a substantially box shape having a hollow inside, and includes a first hole 65a connected to the fan 62 and a second hole 65b connected to the air suction pipe 52. . In addition, the cooling unit 64 may include a third hole 65c to which the discharge pipe 66 and the discharge pipe 66 are connected. The discharge pipe 66 connects the third hole 65c and the second vent 16 of the housing 10 to be supplied from the heat exchanger 60 to the air supply means 50 and the remaining air is transferred to the third hole 65c. And through the second vent 16. Therefore, the discharge pipe 66 and the third hole 65c may not be formed when all the air discharged from the heat exchanger 60 is sucked into the air supply means 50.

The cooling unit 64 is formed by extending the fourth pipe 25b therein, and the air supplied from the fan 62 cools the fourth pipe 25b. Accordingly, the cooling unit 64 cools the fourth pipe 25b by the air flowing from the fan 62 of the first hole 65a and discharges it through the second hole 65b and the third hole 65c. Be sure to On the other hand, the cooling unit 64 is formed to have a predetermined volume so that the predetermined length of the fourth pipe (25b) necessary to sufficiently cool the water vapor and the water flowing inside the fourth pipe (25b). In addition, since the fourth pipe 25b is preferably formed in a zigzag shape so that the portion accommodated in the cooling unit 64 can be increased as much as possible, the cooling efficiency of the cooling unit 64 is increased.

Next, the operation of the fuel cell system according to the exemplary embodiment of the present invention will be described. 3 is a plan view showing the flow of air in the fuel cell system according to an embodiment of the present invention. Arrows in FIG. 3 indicate the flow of air sucked from the outside. Hereinafter, a description will be given focusing on the action of the air supply means and the heat exchanger centering on the flow of air generated during the operation of the fuel cell system. However, since a series of components related to the supply of fuel to the operation of the fuel cell system is operated by a method generally known to those skilled in the art having ordinary skill in the art, the detailed description is omitted here.

The heat exchanger 60 sucks external air by the driving of the fan 62 installed in the vent 12 of the housing 10 and supplies the external air to the cooling unit 64. At this time, since the fan 62 is formed at one side 10a of the vent 14 from which the heated air is discharged, the fan 62 sucks air at a lower temperature. The cooling unit 64 cools the fourth pipe 25b that extends into the inside by using the supplied air. The cooling unit 64 supplies the supplied air to the air supply means 50 through the second hole 65b, and the excess air is discharged to the outside through the third hole 65c.

The air supply means 50 sucks air heated to a predetermined temperature to supply the stack 20 through the third pipe 25a, and the stack 20 does not need to separately heat the supplied air. Therefore, the stack 20 is directly supplied with the heated air, thereby improving the efficiency and performance of the stack 20, and it is possible to prevent energy loss since there is no need to consume extra energy to heat the air.

Water vapor and water discharged by heating from the stack 20 are introduced into the fuel dilution tank 30 through the fourth pipe 25b. At this time, since the fourth pipe 25b is partially extended into the heat exchanger, the heated water vapor and air flowing in the fourth pipe 25b are cooled to a predetermined temperature. Therefore, water vapor flowing through the fourth pipe 25b is effectively condensed into water, thereby effectively recovering water. In addition, the air flowing in the fourth pipe 25b is cooled to a predetermined temperature and flows into the fuel dilution tank 30. Air introduced into the fuel dilution tank 30 is discharged to the outside through the discharge pipe 34 and the discharge port of the housing 10. At this time, the air discharged to the outside is cooled and discharged below a predetermined temperature to minimize the influence on the peripheral device.

In addition, the fuel cell system does not need to form a separate hole for the air supply means 50 in the housing 10 because the air flowing into the air supply means 50 is supplied directly from the heat exchanger (60). . Therefore, the noise generated from the air supply means and the pump of the fuel cell system can be reduced to the outside. In addition, since the number of holes formed in the housing 10 is reduced, it is advantageous to select a position for forming vents and vents when the fuel cell system is downsized.

As described above, the present invention is not limited to the specific preferred embodiments described above, and any person having ordinary skill in the art to which the present invention pertains without departing from the gist of the present invention claimed in the claims. Various modifications are possible, of course, and such changes are within the scope of the claims.

According to the present invention, since the air flowing into the air supply means is directly supplied from the heat exchanger, there is no need to form a separate hole for the air supply means in the housing, and the number of holes formed in the housing is reduced to generate the air supply means and the pump. There is an effect to reduce the leakage of the noise to the outside.

In addition, according to the present invention, since the fan of the heat exchanger is formed to be spaced apart from the vent from which the heated air is discharged, there is an effect of preventing the heated air from entering the heat exchanger and reducing the cooling performance of the heat exchanger.

In addition, according to the present invention, since the number of holes formed in the housing is reduced, there is an effect that it is easy to select the position of forming the vent and the vent when the fuel cell system is downsized.

In addition, according to the present invention, since the stack is directly supplied with heated air, efficiency and performance of the stack are improved, and there is no need to consume additional energy to heat the air, thereby preventing energy loss.

Claims (8)

A stack having an anode and a cathode and generating electrical energy by a chemical reaction of the supplied fuel, a stock solution tank in which the stock solution of the fuel is stored, a stock solution pump for supplying fuel from the stock solution tank, and a fuel supplied from the stock tank A fuel dilution tank which mixes water discharged from the cathode and the anode and unreacted fuel and dilutes the fuel with a predetermined concentration, a fuel supply pump connected to the fuel dilution tank and supplying fuel to the anode and air to the cathode In the fuel cell system comprising an air supply means for supplying, A vent hole and a vent is formed at a predetermined position in a box shape, and the stack, the liquid tank, the liquid pump, the fuel dilution tank, and the fuel supply pump are housed therein; A heat exchanger configured to suck air from the vent to cool the fourth pipe through which water vapor and water discharged from the stack flow; The air supply means is a fuel cell system characterized in that it is formed to suck the air discharged from the heat exchanger to supply to the cathode of the stack. The method of claim 1, The housing is a fuel cell system, characterized in that the vent is formed on one side and the vent is formed on the other side. The method of claim 1, The heat exchanger includes a fan connected to the ventilation hole of the housing to suck air, a first hole to which the fan is connected, and a second hole to be connected to the air supply means, and the fourth pipe is formed to extend inwardly. A fuel cell system comprising a cooling unit. The method of claim 3, The housing has a second vent on the other side, the cooling unit is characterized in that the fuel cell system further comprises a third hole connected to the second vent through the discharge pipe. The method of claim 3, The fourth pipe is a fuel cell system, characterized in that formed in a zigzag shape in the cooling unit. The method of claim 1, The fuel dilution tank is formed to be connected to the vent of the housing through a discharge pipe. The method of claim 1, The air supply means is a fuel cell system, characterized in that consisting of any one of the air pump, air blower, fan. The method of claim 1, The fuel cell system is a fuel cell system, characterized in that the direct methanol fuel cell system.

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